Surfactant-Enhanced Subsurface Remediation

contaminants from the subsurface due to the significant sorption of strongly ... research, teaching, consulting, and regulatory or management responsi...
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Downloaded by KAOHSIUNG MEDICAL UNIV on June 5, 2018 | https://pubs.acs.org Publication Date: May 5, 1995 | doi: 10.1021/bk-1995-0594.pr001

Preface CHEMICAL R E L E A S E S INTO THE S U B S U R F A C E are pervasive environmental problems. Sources of chemical releases range from abandoned hazardous waste disposal sites (e.g., Superfund sites) to leaking underground storage tanks at the corner gasoline station. Remediation of these releases has proven to be a formidable challenge. Many organizations are investing significant resources into the development of innovative technologies for expediting subsurface remediation. Remediation efforts are frequently inhibited by an inability to extract contaminants from the subsurface due to the significant sorption of strongly hydrophobic chemicals (e.g., poly(chlorinated biphenyl)s) or due to the presence of separate phases of nonaqueous-phase liquids (NAPL; e.g., trichloroethylene). Surfactants may be used to enhance the solubility or to mobilize such contaminants. This approach has shown promise for significantly reducing the time and cost of remediation for sites contaminated with strongly hydrophobic or immiscible organic contaminants. This volume combines a timely review of our current understanding of surfactant-based remediation technologies with an insightful discussion of critical issues that demand future consideration as these technologies move toward full-scale implementation. Contributors include representatives of academia, industry, and the regulatory community; each brings an important perspective that might be overlooked in a less comprehensive volume. Recent research results are presented by leading experts in surfactant-based remediation technologies. The chapters in this volume range from fundamental discussions of physicochemical and biological processes affecting surfactant-based technologies to implementation and optimization issues affecting the widespread, full-scale utilization of these technologies. The last chapter summarizes a panel discussion on the general topic of the future of emerging surfactant-based remediation technologies. This book will thus be invaluable for scientists and engineers with research, teaching, consulting, and regulatory or management responsibilities for environmental remediation. Acknowledgements We thank Mary Walker of the A C S Division of Environmental Chemistry, Inc., for her professional and courteous assistance in organizing the ix Sabatini et al.; Surfactant-Enhanced Subsurface Remediation ACS Symposium Series; American Chemical Society: Washington, DC, 1995.

Downloaded by KAOHSIUNG MEDICAL UNIV on June 5, 2018 | https://pubs.acs.org Publication Date: May 5, 1995 | doi: 10.1021/bk-1995-0594.pr001

symposium upon which this book is based and for her encouragement to produce this volume. We gratefully acknowledgefinancialsupport from the Division of Environmental Chemistry, Inc., for the two-day sympo­ sium in San Diego. We also acknowledge the Division of Colloid and Surface Chemistry for co-sponsoring the symposium. We give special thanks to our invited speakers (Linda Abriola, Gary Pope, Richard Luthy, Abdul Abdul, and John Scamehorn) for their timely and informative presentations. We also acknowledge the presenters at the symposium and the authors of the chapters in this book for their sig­ nificant contributions, their timely submittals, and their patience. We acknowledge the members of the discussion panel (James Greenshields, Linda Abriola, Abdul Abdul, Jeffrey Harwell and Candida Westmoderator) for helping to make it a most profitable exercise. We thank the reviewers of the manuscripts in this volume, who were most coopera­ tive and made valuable contributions to the quality of the chapters despite the short deadlines. We also thank the Schools of Civil Engineering and Environmental Science and Chemical Engineering and Materials Science, the College of Engineering, and the University of Oklahoma for their support of this activity. Finally, we thank the ACS Books Department staff, and especially Rhonda Bitterli, for their assistance, patience, and encouragement in preparing this book and publishing it in a timely manner. We appreciate the professional approach and commitment to excellence of the ACS Books Department; it has once again been a pleasure working with them. DAVID A. SABATINI ROBERT C. KNOX

School of Civil Engineering and Environmental Science JEFFREY H . HARWELL

School of Chemical Engineering and Materials Science Institute for Applied Surfactant Research University of Oklahoma Norman, OK 73019 February 10, 1995

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Sabatini et al.; Surfactant-Enhanced Subsurface Remediation ACS Symposium Series; American Chemical Society: Washington, DC, 1995.