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Letter Cite This: ACS Appl. Nano Mater. XXXX, XXX, XXX−XXX

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Surfactant-Free Synthesis of Cyclomatrix and Linear Organosilica Phosphazene-Based Hybrid Nanoparticles Vanessa Poscher, Ian Teasdale, and Yolanda Salinas* Institute of Polymer Chemistry and Linz Institute of Technology (LIT), Johannes Kepler University at Linz, Altenberger Strasse 69, 4040 Linz, Austria

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ABSTRACT: Novel halogen-free organosilica phosphazene-based hybrid nanoparticles (SiPPz NPs) were prepared by base-triggered sol−gel hydrolysis−condensation of two precursors based on a cyclomatrix and a linear silane-derived polyphosphazenes, synthesized via thiol-ene addition. Spherical and compact particles were obtained (