Syntheses and molecular structures of hexasilylbenzenes and

Anand Dhiman, James Y. Becker, Oliver Minge, Hubert Schmidbaur, and Thomas Müller ... Oliver Minge, Norbert W. Mitzel, and Hubert Schmidbaur...
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Organometallics 1992,11, 2867-2873 Table V. Selected Bond Distances (A) and Angles (deg) for 5

Distances 1.95 (2) 1.94 (2) 1.93 (2) 2.42 (1) 2.35 (1) 1.71 (1) 1.43 (2) 1.51 (2) 1.73 (1) 1.85 (1) 1.804 (8)

c(lO)-o(l) c(20)-0(2) C(30)-0(3) Mo-C(3) Md(5) P(2)-C(3) C(2)-C(3)

1.15 (1) 1.16 (1) 1.17 (1) 2.42 (1) 2.43 (1) 1.73 (1) 1.43 (2)

P(2)-C(5) P(2)4(21) P(2)-C(22)

1.73 (1) 1.821 (9) 1.789 (9)

Angles 164.9 (6) 171.0 (6) 125 (1) 120 (1) 124 (1) 102.6 (7) 112.2 (7) 114.3 (7) 114.1 (7) 109.3 (7) 114.5 (6) 104.1 (5)

C(3)-Mo-C(20)

166.1 (5)

P(2)-C(3)-C(2) C(3)4(2)-C(4)

123 (1) 116 (1)

C(5)-P(2)-C(3) C(5)-P(2)-C(21) C(5)-P(2)4(22)

102.8 (6) 112.1 (6) 115.0 (6)

C(3)-P(2)