Synthesis and Characterization of Molecular Monolayer

Nanoscale Catalysts K i MM t D t tf Ch it Albi C ll Albi MI 49224 ... Sn4+ Pd 1) Sn2 2) Pd+ Pd C O O C O O Sn4+ Pd C O O C O O C OH O C OH O ...
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Synthesis and Characterization of Molecular Monolayer Directed Nanoscale Catalysts K i M Kevin M. M Metz, t D Department t t off Chemistry, Ch i t Albi Albion C College, ll Albi Albion, MI 49224 Our research aims to produce, study, and understand catalytically active metal nanoparticles on carbon substrates. Specifically, our research has focused on the synthesis of uniform metal nanoparticles p over large g areas and the catalytic y activity y of these p particles. This research could have significant impacts on synthetic organic chemistry, changing industrial methods for production.

O

O

Carbon

O C

O C

O

OH C

Carbon

O

OH C

Pd Sn4+ O O C C

Carbon

12x10

6

DUB55 rxn 1

10

Abunda ance

Sn4+

O

Pd

Pd

O

Pd2+

Sn22+ Pd+

1) 2)

254 nm rotection

8 6 4 2 0 5

10

15 20 Retention Time (min.)

25