Synthesis and characterization of Rh [P (CH3) 3] 2 (CO) CH3 and Rh

Gabriela de la Herrán, Miriam Mba, M. Carmen Murcia, Joaquín Plumet, and Aurelio G. Csákÿ. Organic ... New Classes of Insertion Reactions. Christopher Krug ...

Rh(P(CH3)3)2(CO)Cl. The phenyl complex was synthesized by two routes, first by direct ..... (5)Boyd, S. E. Ph.D. Thesis, The University of Sydney, 1992;.

School of Chemistry, University of Sydney, Sydney 2006, New South Wales, Australia. Received November 30 .... 392, 314 nm. vco (pentane): 1948 cm-l. Anal. Calcd for .... Irradiation of. 3 (100 mM) in a THF solution containing benzene-de.

Acidolysis of [ MeC(CH2PPh2)3]Rh(CH3), Compounds: Controlled Creation of Unsaturation. David J. Rauscher, Eric G. Thaler, John C. Huffman, and Kenneth ...

Acidolysis of rhodium complexes [MeC(CH2PPh2)3]Rh(CH3)n: controlled creation of unsaturation. David J. Rauscher, Eric G. Thaler, John C. Huffman, and ...

NHCH,C(CH,),] ]X2. Facile iso- cyanide insertion into the rhodium-tolyl bond occurs upon addition of PMe,. Reduction of [C,(CH,),]. Rh[CNCH,C(C-. H,),]. I, in the ...

monomeric [C&CH3)5]Rh[CNCH2C(CH3)3]X2. (la, X = C1; lb, X = Br; IC, X = I)4 in >95% yield after recrystalli- zation from CH2C12/hexane. Addition of 1 equiv ...

3150, 3146 (1956); Y. Sat0 and N. Ikekawa, J. Org. Chert., in press. for each pair of compounds the lower retention time was found when the 22-H and 25-methyl ...

Density functional theory (DFT) calculations on the geometry and bonding energy of the X- - -I intermolecular interaction of CF3I and (CH3)nX (X ) N, P, n ) 3; ...

May 8, 2014 - Experiments are described for the reliable small-scale glovebox preparation of CpMo(CO)3(CH3) and acetyl derivatives thereof through phosphine-induced migratory insertion. The robust syntheses introduce students to a variety of organome