Synthesis and Structure of Low-Dimensional Gallium

Institut Lavoisier, UMR CNRS 8637, Universite´ de Versailles Saint-Quentin-en-Yvelines,. 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Sc...
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Chem. Mater. 2002, 14, 4448-4459

Synthesis and Structure of Low-Dimensional Gallium Fluorodiphosphates Seen during the Crystallization of the Three-Dimensional Microporous Gallium Fluorophosphate ULM-3 Franck Millange,*,† Richard I. Walton,‡ Nathalie Guillou,† Thierry Loiseau,† Dermot O’Hare,§ and Ge´rard Fe´rey*,† Institut Lavoisier, UMR CNRS 8637, Universite´ de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, School of Chemistry, University of Exeter, Stocker Road, Exeter, Devon EX4 4QD, United Kingdom, and Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom Received June 14, 2002. Revised Manuscript Received July 25, 2002

Two one-dimensional gallium fluorodiphosphates Ga(P2O7)F‚H3N(CH2)3NH3‚3H2O, 1, and Ga(P2O7)F‚H3N(CH2)3NH3‚H2O, 2, have been synthesized under mild conditions (