Kathryn George , C. H. (Kees) de Groot , Chitra Gurnani , Andrew L. Hector , Ruomeng Huang , Marek Jura , William Levason , and Gillian Reid. Chemistr...
Jan 1, 1987 - Next Article · Table of Contents. Synthesis of chelating ditelluroether ligands, RTeCH2CH2CH2TeR (R = Me, Ph). Eric G. Hope, Tim. Kemmitt ...
Tim Kemmitt, William Levason, and Michael Webster. Inorg. Chem. , 1989, 28 (4), ... William Levason, Simon D. Orchard, and Gillian Reid. Organometallics 1999 ...
and MeOH to yield the cationic complexes [LAl(H2O)2]+Cl- (L ) Salen (7), SalenCl (8), Acen (9)) and. [LAl(MeOH)2]+Cl- (L ) Salen (10), SalenCl (11), Acen (12)), ...
Daniel T. Plummer, George A. Kraus, and Robert J. Angelici ... Etienne Baranoff, Jean-Paul Collin, Junko Furusho, Yoshio Furusho, Anne-Chantal Laemmel, and ...
These studies were carried out with a platinum disk electrode in THF solution, and ...... Miriam Mba , Leonard J. Prins , Cristiano Zonta , Massimo Cametti , Arto ...
Department of Chemistry, Wesleyan University, Middletown, Connecticut 06459, and. Department of Chemistry, Yale University, New Haven, Connecticut 06511.
C3-Symmetric Ti(IV) Triphenolate Amino Complexes as Sulfoxidation Catalysts with Aqueous Hydrogen Peroxide. Myriam Mba, Leonard J. Prins, and Giulia ...
methyl groups without metal-ligand bond breaking. Oxo dissociation is not ... we have synthesized a number of primary and secondary phosphines and arsines ...
Both the porphyrin and the TMTAA ligand systems are tetradentate N4-macrocycles that coordinate in the form of dianions. While the porphyrin dianion is a planar 18x-electron aromatic species, TMTAA is a 16~-electron antiaromatic dianion that can significantly deviate from planarity by rotation about the N-C bonds of the ophenylenediamine portion of the macr0cyc1e.l~ Close parallels between the organometallic chemistry of (Rh(TMTAA)), and (Rh(Por)), indicate that the conjugation and planarity of the porphyrin system are not essential features for the unusual reactivity that occurs at the rhodium center. T h e observed reaction of Rh(TMTAA)(py)(H)in pyridine with CO to produce a metallo formyl complex further extends the scope of complexes capable of this type of reaction to include six-coordinate rhodium(II1) hydride species. The general reaction of a metal hydride with CO to produce observable concentrations of an ql-carbon-bonded formyl complex is rare because of the thermodynamic requirement that the (M-HI-(M-C) bond energies must be relatively small (
