Synthesis of Hematite (α-Fe2O3) Nanorods: Diameter-Size and Shape

19 Aug 2006 - on the diameter size and Brunauer-Emmett-Teller (BET) surface areas, ... lithium-ion batteries.2 Its size and shape effect on correspond...
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J. Phys. Chem. B 2006, 110, 17806-17812

Synthesis of Hematite (r-Fe2O3) Nanorods: Diameter-Size and Shape Effects on Their Applications in Magnetism, Lithium Ion Battery, and Gas Sensors Changzheng Wu, Ping Yin, Xi Zhu, Chuanzi OuYang, and Yi Xie* Department of Nano-materials and Nano-chemistry, Hefei National Laboratory for Physical Sciences at Microscale, UniVersity of Science & Technology of China, Hefei, Anhui 230026, China

J. Phys. Chem. B 2006.110:17806-17812. Downloaded from pubs.acs.org by UNIV OF FLORIDA on 01/10/19. For personal use only.

ReceiVed: June 1, 2006; In Final Form: July 16, 2006

We demonstrated in this paper the shape-controlled synthesis of hematite (R-Fe2O3) nanostructures with a gradient in the diameters (from less than 20 nm to larger than 300 nm) and surface areas (from 5.9 to 52.3 m2/g) through an improved synthetic strategy by adopting a high concentration of inorganic salts and high temperature in the synthesis systems to influence the final products of hematite nanostructures. The benefits of the present work also stem from the first report on the