604
Inorg. Chem. 1998, 37, 604
Additions and Corrections 1997, Volume 36 David M. Way, John B. Cooper, Maruse Sadek, Truc Vu, Peter J. Mahon, Alan M. Bond,* Robert T. C. Brownlee, and Anthony G. Wedd*: Systematic Electrochemical Synthesis of Reduced Forms of the R-[S2Mo18O62]4- Anion. Page 4229. Table 1 contains several errors. The text is free of the errors contained in the table. The revised and corrected Table 1 follows. Table 1. E1/2 Values for Reduction of (Hex4N)4[S2Mo18O62] (2.0 mM) in MeCN Solutionsa MeCN [Bu4NClO4] (M)
95/5 MeCN/H2O [HClO4] (M)
nb
0.1c
0.2d
0c
1 2 3 4 5 6 7 8
0.12 -0.12 -0.78 -1.05
0.10 -0.14 -0.80 -1.07 -1.67 -1.92 -2.36f -2.64f
0.12 -0.11 -0.73 -0.90
0.02c
0.2e
0.19
0.31
0.09
0.21
-0.10
0.03
-0.41
-0.28
a Potentials versus Fc+/Fc. b Total number of electrons added at this potential. c Estimated by cyclic voltammetry (glassy carbon disk; d ) 3.0 mm; V ) 100 mV s-1; [Bu4NClO4] ) 0.1 M; 20 °C). d As for footnote c but with V ) 10 V s-1. e As for footnote c except that Bu4NClO4 was absent. f -30 °C.
Page 4230. Equation 7: K7 ) 1.6 × 106 M-1. Page 4231. In Figure 4 (as well as in Figures S1 and S2 in the Supporting Information), E1/2 values are referenced against Ag/AgCl: conversion to the Fc+/Fc scale requires subtraction of 0.44 V. IC9714192
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