Systematics and mechanism of hot halogen reactions. Product

Table 1. Yields (z) of Hot Fluorine Replacement Reactions“. ~. 7. Reactant molecule. -. Reaction ... of the 40-Mev Yale electron accelerator by the ...
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2426 Table 1. Yields ~~

(z)of Hot Fluorine Replacement Reactions“

~

~~~~~

Reactant molecule CHzFz CHFa

7

Reaction type Replacement for Replacement for Replacement for Replacement for Replacement for Other reactions

F or C1 H 2F H and F or C1 2H

z

Total hot yield, Calcd area available for reaction Calcd hot yield, 7; Per cent of total

CH4

CHaF

2 . 6 (CHzFz)

4 . 7 (CH3F) 15.8 (CH3F)

3.4(CH1Fz)

4 . 6 (CHsFI)