Environmental Science & Technology © Copyright 1984 by the American Chemical Society
ES&T CONTENTS
Editor: Russell F. C h r i s t m a n Associate Editor: John H. Seinfeld Associate Editor: Philip C. Singer ADVISORY BOARD Julian B. A n d e l m a n , Kenneth L. Demerjian, Steven Eisenreich, William H . Glaze, Glenn R. Hilst, Michael R. Hoffmann, Lawrence H . Keith, Donald Mackay, Leonard N e w m a n , Eugene B. Welch
Volume 18, Number 11, November 1984
WASHINGTON EDITORIAL STAFF Managing Editor: S t a n t o n S. Miller Associate Editor: Julian Josephson Associate Editor: Bette Hileman MANUSCRIPT REVIEWING Manager: Janice L. Fleming Associate Editor: Monica C r e a m e r Assistant Editor: Yvonne D. C u r r y Assistant Editor: M a r y Ellen Provencher MANUSCRIPT EDITING Assistant Manager: M a r y E. Scanlan Assistant Editor: Ruth A. Linvilte GRAPHICS AND PRODUCTION Production Manager: Leroy L. Corcoran Art Director: Alan K a h a n Staff Artist: Julie K a t z Production Editor: Gail Mortenson BOOKS AND JOURNALS DIVISION Director: D. H. Michael Bowen Head, Journals Department: Charles R. Bertsch Head, Production Department: Elmer M . Pusey Head, Research and Development Department: Lorrin R. Garson ADVERTISING M A N A G E M E N T Centcom, Ltd. For officers and advertisers, see page 350A. Please send research manuscripts to Manuscript Reviewing, feature manuscripts to M a n a g i n g Editor. For author's guide and editorial policy, see the February 1984 issue, page 69A, or write Janice L. Fleming, Manuscript Reviewing Office, ES&T. A sample copyright transfer form, which may be copied, appears on the inside back cover of the February 1984 issue. Environmental Science & Technology ES&T (ISSN 0013-936X) is published monthly by the American Chemical Society at 1155 i 6th Street, N.W., Washington, D.C. 20036; 202-872-4600, TDD 202-872-8733. Secondclass postage paid at Washington, D.C. and at additional mailing offices. POSTMASTER: Send address changes to Membership & Subscription Services, PO Box 3337, Columbus, OH, 43210. SUBSCRIPTION PRICES 1984: Members, $22 per year; nonmembers (for personal use), Î25 per year; institutions, $121 per year. Foreign postage, $8 additional per year/Air freight add $33; multiple year rates available on request. Single issues $10.50 for current year: $12.50 for prior years. Back volumes $ i 46. Rates above do not apply to nonmember subscribers in Japan, who must enter subscription orders with Maruzen Company Ltd., 3-10 Nihon faashi 2-chome, Chuo-ku. Tokyo 103, Japan. Tel: (03) 272-7211. COPYRIGHT PERMISSION: An individual may make a single reprographic copy of an article in this publication for personal use. Reprographic copying beyond that permitted by Section 107 or 108 of the U.S. Copyright Law is allowed, provided that the appropriate per-copy fee is paid through the Copyright Clearance Center, Inc., 21 Congress St. Salem, Mass. 01970. For reprint permission, write Copyright Administrator, Books & Journals Division, ACS, 1155 16th St., N.W., Washington, D.C. 20036. REGISTERED NAMES AND TRADEMARKS, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. SUBSCRIPTION SERVICE: Orders for new subscriptions, single issues, back volumes, and microfiche and microform editions should be sent with payment to Office of the Treasurer, Financial Operations, ACS, 1155 16th St., N.W., Washington, D.C. 20036. Phone orders may be placed, using Visa, Master Card, or American Express, by calling toll free (800) 424-6747 from anywhere in the continental U.S. Changes of address, subscription renewals, claims for missing issues, and inquiries concerning records and accounts should be directed to Manager, Membership and Subscription Services, ACS, P.O. Box 3337, Columbus, Ohio 43210. Changes of address should allow six weeks and be accompanied by old and new addresses and a recent mailing label. Claims for missing issues will not be allowed if loss was due to insufficient notice of change of address, if claim is dated more than 90 days after the issue date for North American subscribers or more than one year for foreign subscribers, or if the reason given is "missing from files." The American Chemical Society assumes no responsibility for statements and opinions advanced by contributors to the publication. Views expressed in editorials are those of the author and do not necessarily represent an official position of the society.
FEATURE 330A Hazardous waste assessment. Geophysical techniques are useful for finding hazardous wastes and evaluating groundwater contamination. Roy B. Evans and Glenn E. Schweitzer, U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nev.
REGULATORY FOCUS
330A
340A Safe Drinking Water Act. Richard Dowd discusses proposed amendments to the 1974 act.
OUTLOOK 341A Acid rain perspective. A comparison of Canadian and U.S. approaches to a common problem. 345A SCOPE. The Scientific Committee on the Problems of the Environment speaks on international scientific problems.
DEPARTMENTS 323A 324A 326A 346A 347A 348A 349A
Editorial Letters Currents Products Literature Classified Consulting Services
ESTHAG 18(11) 321A-350A 811-894(1984) ISSN 0013-936X C r e d i t : Bette Hileman, 341A C o v e r : Courtesy EPA Environmental Systems Laboratory, Las Vegas, Nev.
Monitoring
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RESEARCH 811 Organohalide formation on chlorination of algal extracellular products. Jan K. Wachter and Julian B. An delman* Organohalide-forming potential of algal ECP, derived from a number of algal strains, is determined and com pared under varied environmental con ditions. 818 X-ray analysis of airborne particu lates collected by an Andersen sam pler. Compound and elemental distri butions vs. particle size of laboratory particulates. Masaaki Iwatsuki, Sujith Ε Tillekeratne, Tsugio Fukasawa, and Tsutomu Fukasawa* This method allows X-ray diffraction and fluorescence analyses of soluble and insoluble constituents in the partic ulates sampled. 823 Comparison of a chemiluminescent and a tunable diode laser absorption technique for the measurement of ni trogen oxide, nitrogen dioxide, and nitric acid. James G. Walega,* Donald H. Stedman, Richard E. Shetter, Gervase I. Mackay, Toshio Iguchi, and Harold I. Schiff Comparison of these analytical meth ods supports the widespread use of chemiluminescence for measuring NO in ambient air. 827 Fogwater collector design and char acterization. Daniel J. Jacob, RueenFang T. Wang, and Richard C. Flagan* The rotating arm collector preserves the physical and chemical integrity of the sample at all stages of collection. 834 Evaporation rate of spills of hydro carbons and petroleum mixtures. Warren Stiver and Donald Mackay* A method is developed that uses readily obtainable experimental data for calculating the rates at which oil spills evaporate.
840 Aspects of the polycyclic aromatic hydrocarbon geochemistry of recent sediments in the Georges Bank re gion. Paul D. Boehm* and John W. Farrington PAH concentrations are directly re lated to the total organic carbon (TOC) and the silt/clay content of the sedi ments.
873 Composition and origins of aerosol at a forested mountain in Soviet Georgia. Thomas G. Dzubay,* Robert K. Stevens, and Phillip L. Haagenson The major component of fine particles in the Caucasus is ammonium sulfate from distant sources, but manganese-rich spheres from a smelter also are present.
846 Hydrocarbon and azaarene markers of coal transport to aquatic sedi ments. Robert C. Barrick,* Edward T. Furlong, and Roy Carpenter Molecular markers are used to distin guish significant natural and anthropo genic coal input from other regional fossil sources, such as street runoff and fuel oils.
883 Role of the free metal ion species in soluble nickel removal by activated sludge. Jeppe S. Nielsen,* Steve E. Hrudey, and Frederick F. Cantwell Nickel uptake from typical municipal sewage is directly proportional to free Ni 2+ ion concentration, rather than to total soluble nickel concentration.
855 Rapid conversion of S0 2 (g) to sulfate in a fog bank. Delbert J. Eatough,* R i c h a r d J. A r t h u r , N o r m a n L. Eatough, Max W Hill, Nolan F. Mangelson, Bruce E. Richter, Lee D. Hansen, and John A. Cooper Daytime conversion in the plume of an oil-fired power plant averages 3% S0 2 (g)/h compared with 30% conver sion when the plume is in a fog bank.
NOTES
860 Photoreductive dissolution of colloi dal iron oxides in natural waters. Τ. David Waite* and François M. M. Morel The light-enhanced dissolution of colloid iron oxides under conditions typical of natural waters is investigated, and the major controlling factors are examined. 869 Hydrocarbons in waters adjacent to an oil exploratory site in the western North Atlantic Ocean. Gunter Gassmann and Roger Pocklington* High-resolution GC gives results different from the recommended fluorescence method when the anthropogenic signal is small relative to the natural background of hydrocarbons.
887 Trace element partitioning during the retorting of some Australian oil shales. Leslie S. Dale* and John J. Fardy Comparison of elemental mobilities demonstrates the variability in the degree of partitioning for each of the samples during retorting. 890 Reduction of low molecular weight halocarbons in the vapor phase above concentrated humic acid solutions. Jill Y. Callaway, Kasi V. Gabbita, and Vincent L. Vilker* Humic acid is found to decrease the air-water distribution coefficient of chloroform and trichloroethane. CORRESPONDENCE 894 Comment on "Mass transfer of volatile organic contaminants from aqueous solution to the atmosphere during surface aeration." Paul V. Roberts 894 Correction for "Field compatible calibration procedure for peroxyacetyl nitrate." Michael W. Holdren *To whom correspondence should be addressed. This issue contains no papers for which there is supplementary material in microform.
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Environ. Sci. Technol., Vol. 18, No. 1 1 , 1984