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TECHNICAL PROGRAM & EXPO 225th ACS National Meeting • March 23-27,2003
TECHNICAL PROGRAM
RIVERFRONT SKYLINE Audubon Aquarium of the Americas is the site of Kids and Chemistry LIVE!
NATIONAL MEETING
225TH
New Orleans, March 23-27
Ν
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I AWLINS" —THE CITY OF
jazz, cajun food, languid gardens, and bayous—is the site of the American Chemical Society's 225th national meeting. Thirty of the society's technical divisions, three secretariats, and seven committees will participate in more than 800 technical sessions. More than 8,500 papers will be presented. The technical summary begins on page 96. The exposition, a description of which begins on page 69, will be open Monday March 24, through Wednesday, March 26. More than 280 companies and organizations will display instruments, books, computer hardware and scientific software, and more. As always, opportunities for continuing education are offered through exposition workshops as well as ACS divisional 66
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and other workshops, ACS short courses, and Chemical Abstracts Service seminars. A highlight of the presidential events will be held in the Audubon Aquarium of the Americas on Sunday, March 23, from 3:30 to 5:30 PM. Meeting attendees and the public are welcome to "Celebrating Chemistry: Kids and Chemistry LIVE!"; there, volunteer members, student affiliates, and ACS staff will conduct demonstrations and hands-on activities that illustrate the importance and prevalence of chemistry in everyday life. Other presidential events will feature symposia and poster sessions celebrating the 10th anniversary of the Committee on Minority Affairs (CMA). Cecil B. Pickett, president of Schering-Plough Research Institute, will be the guest speaker at the CMA luncheon; ACS Scholars and Project
CLASSIFICATION OF REGISTRANT
MEMBER ACS member or society affiliate Member (emeritus) Member (retired) Graduate student, less than postdoctoral Undergraduate student Precollege teacher 50-year member Unemployed (NECH waiver) One-day registrant N0NMEMBER Chemical scientist Visitor, nonchemical scientist, or chemical technician Graduate student, less than postdoctoral Undergraduate student Precollege teacher One-day registrant Guest of registrant EXPOSITION VISITORS Adult Student
ON-SITE
$330 170 170 65 45 45 No fee No fee 170 $585 330
330 140 45 330 30 $35 10
HTTP://WWW.CEN-ONLINE.ORG
SEED students will present poster papers at the evening reception and poster session. "Funnel Vision: The Role of the Media in Science Communication," a symposium organized by the Committee on Public Relations & Communications, will discuss how major media oudets communicate science to the public and how chemists can aid the process. After Tuesday evening's ACS awards dinner, Edwin J. Vandenberg will deliver the Priestley Medal Address.
REGISTRATION YOU CAN STILL REGISTER ONLINE EVEN
though advance registration closed on Feb. 26. Attendees who register via the Internet by the cutoff date of March 7 will pay the on-site registration fee but will not have to stand in line on-site to register. Late registrants may proceed to the "preregistration" counters at the Ernest N. Morial Convention Center, HallJ, to pick up their credentials. Please bring a copy of your email confirmation with you on-site for faster processing and to avoid duplicate registrations. Faxed and mailed registration forms are not being accepted. On-site Registration: Attendees may also register on-site in the convention center. As an added service, ACS will provide self-registration counters along with the traditional "attended" registration counters. On-site registration fees apply On-site registration hours at the convention center are as follows: Saturday, March 22,3 to 7 PM; Sunday, March 23, 7:30 AM to7PM;Monday,March24,7:30 AM to 5 PM; Tuesday March 25,7:30 AM to 5 PM; Wednesday, March 26,7:30 AM to 4 PM; and Thursday, March 27,7:30 to 11:30 AM.
HOUSING FOR RESERVATIONS MADE THROUGH ACS,
the deadline for New Orleans was March 3. Refer to the ACS meetings website at http://chemistryorg/meetings/neworleans 2003 and click on "Hotels" or to the Preliminary Program in the Jan. 27 issue of C&EN to contact the ACS hotels directly
TRANSPORTATION ACS HAS NEGOTIATED SPECIAL RATES WITH
American Airlines, Delta Air Lines, and US Airways for the 2003 ACS Meeting Travel Program. All three carriers offer: HTTP://WWW.CEN-ONLINE.ORG
• 5% off any applicable published excursion domestic fares (10% off if purchased 60 days or more before travelspecial conditions apply). • 10% offunrestricted coach fares (15% off if purchased 60 days or more before travel—special conditions apply). • Special domestic zone fares that are less than the unrestricted fares and do not require a Saturday night stay To make your reservation or for more information, call American: (800) 433-1790, 7 AM to midnight EST, refer to Star File No. 16132; Delta: (800) 241-6760,8 AM to 11 PM EST, refer to File No. 176415A; or US Airways: (877) 874-7687 from 8 AM to 9 PM EST, refer to Gold File No. 93692648. CAR RENTAL. Avis and Hertz are offering discounted rates for the 2003 ACS Meeting Travel Program. To make your reservation, or for more information, call: Avis
(800)331-1600 Refer to ID Code B923099
CHANGES AND ADDITIONS TO SCHEDULED EVENTS HONDAYp MARCH 24 Workshop, 4:30 to 5:30 PM Affiliates-to-Membership Faculty Networking Session, New Orleans Hilton Riverside. ACS Student Affiliates faculty advisers and undergraduate research advisers are invited to this session, which will assist you with encouraging graduating seniors to become full members of ACS. In addition, you'll learn about the new membership campaign that will bring you national recognition. Refreshments will be served. Sponsored by the Membership Activities Committee. Reception/NT, 5:30 to 7:30 PM Research Corporation reception honoring recipient of the Award for Research at an Undergraduate institution, Sheraton Reception/NT, 6 to 8 PM University of Arizona, Department of Chemistry, Alumni & Friends, Hotel Inter-Continental TUESDAY, MARCH 25
Hertz
(800)654-2240 Refer to ID Code CV# 02UZ0002 AIRPORT AND GROUND TRANSPORTA-
TION. New Orleans is served by Louis Armstrong International Airport. The airport is located 21 miles northwest of downtown New Orleans. Taxi service from Louis Armstrong International Airport: $2.50 drop charge plus $1.00 for each additional passenger; $3.00 per person for special events or meter rate if greater. The airport flat rate to the downtown area is $28 for up to two people and $12 for each additional passenger, not to exceedfivepeople. Pickup is on the lower level, outside the baggage claim area. There may be an additional charge for extra baggage. Airport Shuttle Service to Downtown
MEETING INFORMATION ON THE WEB The most up-to-date and the official final version of the technical program is the Web version: http://chemistry.org/ meetings/neworleans2003. The information on this site will be updated as the meeting nears. Because some locations may change after C&EN's press time, also be sure to pick up an on-site program booklet at the meeting.
Luncheon/COD, noon to 1:30 PM Alpha Chi Sigma Fraternity, Mulate's Restaurant, 201 Julia St. at Convention Center Blvd. Reception/NT, 5 to 7 PM Tulane University, Department of Chemistry, Hilton Garden Inn DiMMf/nckot No. 125/$35,fc30to*i30PM Division of Cellulose & Renewable Ma» tenais, Anselm Payen Awards, Plimsotl Club, 2 Canal St.
Hotels: $20 per person, round-trip. Three bags per person. Call (866) 596-2699 or (504) 522-3500 for more details. For group reservations or ADA transfers, call (888) 432-7651. Ticket booths are located on the lower level in the baggage claim area of the airport. Advance reservations are required for all ADA accessible transfers. Please call well enough in advance for the specially equipped shuttle to be reserved. Airport Shuttle tickets are nonrefundable. Public Bus (Airport): Fare is $1.50. Departs from the airport outside Entrance 7 on the upper level and goes to the downtown side of Tulane Ave. between Elks Place and South Saratoga St. approximately every 10 minutes during peak hours (6 to 9 AM, 3 to 6 PM.); every 30 minutes otherwise. Buses run 6 AM to 6:30 PM. For information, contact Jefferson Parish Transportation Department at (504) 818-1077 or see the website at http://wwwgcrl.com/jet/. C & E N / MARCH 3, 2003
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EXPOSITION
A
dmission to the exposition is complimentary for all national meeting registrants. While planning your schedule in New Orleans, reserve some time to visit the ACS National Exposition. In addition to functioning as a showcase for the most up-to-date scientific products and services, the exposition also serves as a valuable source of continuing education for national meeting attendees. Located in Halls H/I1 in the Ernest N. Morial Convention Center, the exposition will be open Monday, March 24, 9 AM to 5 PM; Tuesday, March 25,9 A M to 5 PM; and Wednesday, March 26,9 AM to 1 PM. The exposition will consist of over 500 booths representing more than 280 companies and organizations displaying everything from instruments and books to computer hardware and scientific software. Also displayed will be chromatographic and lab equipment, furniture, and safety equipment. Each exhibiting organization
will have technical personnel present to give demonstrations, answer questions, and discuss your needs and interests. VIRTUAL EXPOSITION. Visit the Virtual Expo on the Internet at http://chemistry.org/expoplanner to keep up with the latest happenings and to obtain a complete, up-to-date listing of exhibitors at the ACS National Exposition. Browse the list of exhibitors, perform keyword searches, learn more about a company's products and services, or prepare a customized floor plan to maximize your visit to the exposition. FREE INTERNET ACCESS (INTERNET CAFE). Free Internet access will be provided to meeting attendees during regularly scheduled exposition hours. A total of 45 terminals will be available for attendees inside the exposition. PRIZE & SOUVENIR BOOTHS. In addition to the comprehensive display of prod-
ucts and services of interest to the scientific community, there will be several drawings for prizes and a free meeting souvenir will be available. ADMISSION REQUIREMENTS. Although admission to the exposition is complimentary for all national meeting registrants, a badge is required to enter the exhibit halls. Badges will be mailed to all preregistrants in the U.S. and Canada. International and on-site national meeting registrants can obtain a badge in the main registration area of the convention center. EXPO-ONLY REGISTRATION. Those not registering for the national meeting but interested in visiting the exhibits can obtain an exhibits-only badge for $35. Students with school identification will be charged $10. Exhibits-only badges can be purchased in the main registration area of the convention center.
EXPOSTON (202)776-8258, e-mail:
[email protected], Inter net: http://chemistry.orq chemistry.org, the ACS Website, provides a collection of virtual chemical information doorways for a worldwide audience of professional chemists, teachers, students, policy The following list of exihibitors is the makers, and chemistry enthusiasts. Visitors to property of the American Chemical chemistry.org will fine unique, weekly updated features such as Molecule of the Week, Heart Cut, Society. Any unauthorized use of this and Patent Watch. You can also access the latest in list, or any pan: thereof, either directly chemistry news, education programs and resources, research tools, meeting information, or indirectly, is strictly prohibited. job resources, publications, chemical history, sci ence policy information, and more. Open the ACS AAPS (Amer Assoc, of Pharm Sci.), 2107 Wilson Members door to find descriptions of ACS mem Blvd., #700, Arlington, VA, USA 22201, (703)243ber-only benefits and programs, information on 2800, fax: (703)243-9632, e-mail:
[email protected], technical divisions, local sections, and commit Internet: www.aapspharmaceutica.com More than tees. Construct a personalized chemistry home 11,000 AAPS members look to AAPS for the latest page (my.chemistry.org) configured to display developments in the pharmaceutical sciences, net your information doorways of interest; including working and career advancement opportunities, job information, meetings, publications, "My cutting edge research, meetings, workshops and Favorites" links, and ACS member benefits and symposia. AAPS members interact with the top resources. 1119 scientists in the Industry through sections, focus groups, and discussion groups. A major benefit is ACS Education, 1155 16th St., N.W., Washington, access to our online-only scientific journals, AAPS DC, USA 20036, (202)872-4382, fax: (202)833PharmSci and AAPS PnarmSciTech. AAPS also 7732, e-mail:
[email protected] The Education offers technology throuqh AAPS Pharmaceutic, and International Activities Division of the Ameri to build a Personlized Ε-Journal of relevant articles can Chemical Society has products and programs and citations from over 40 scientific journals. 1336 for kindergarten through professional education. Our booth displays examples of our products and Accelrys, 9685 Scranton Rd., San Diego, CA, USA programs for elementary, middle, high school, col 92121, (858)799-5000, fax: (858)799-5100, Inter lege, graduate education and continuing science net: http://www.accelrys.com Accelrys is a leading education. Students, teachers, and ACS members provider of software for computation, simulation, can all find information that can help their efforts in and the management and mining of scientific data increasing science literacy. Our booth is staffed used by bioloqists, chemists,and materials scien with knowledgeable ACb staff who can answer tists for product design, drug discovery, and questions regarding our wide variety of programs development. Accelrys' platform technology and and products. 1224 consulting services enable enterprise wide solu tions tailored to today's leading research organi ACS Government Affairs, 115516th St. NW, Othzations. The company's three main centers of mer 320, Washington, DC 20036, (202)872-4386, excellence are in San Diego, CA, Princeton, NJ, fax: (202)872-6206, e-mail:
[email protected], and Cambridge, UK. These centers combine Internet: www.chemistry.org/government Stop by research and product development with facilities for your chance at a prize! Working with American to support significant collaborative projects. Chemical Society members, the ACS Office of Accelrys is a subsidiary of Pharmacopeia, Inc. Legislative and Government Affairs promotes pub NASDAQ: PCOP and was launched in June 2001, lic policy that advance the chemical enterprise and combining leading software companies Molecular its practitioners. Strong member participation Simulations Inc., Synopsys Scientific Systems, ensures that chemists are heard in the develop Oxford Molecular, GCG, and Synomics Ltd. 1419 ment of laws, regulations, and key programs. The government affairs booth gives ACb members the Accurion, 935 Hamilton Ave., Menlo Park, CA, opportunity to learn about ACS Legislative Action USA 94025, (650)323-2200, fax: (650)323-2282, Network, ACS Policy Fellowships, and more. 1129 e-mail:
[email protected], Internet: www. accurion.com Accurion Scientific Instruments spe ACS Industry Pavilion, ACS Office of Industry cializes in high-resolution characterization prod Member Programs, 1155 16th St., NW, Washing ucts for a variety of research and industrial ton, DC, USA 20036, (202)872-6281, fax: (202)872applications. We offer AFM, Spectroscopic Imag 6098, e-mail:
[email protected], Internet: http:// ing Ellipsometers, Brewster Angle Microscopes chemistry.org/industry Industry Pavilion 2003 is an (BAM), and Active Vibration Isolation Systems. Our integrated workshop zone for industrial profes newest product, the EP3, is a scanning-free imag sionals to stay competitive in a changing business ina ellipsometry system offering film thickness and scientific world. Visit often to attend 24 free information complementary to the topography sessions on corporate workplace issues, industrial from our modular AFM. The EP3, like all ofAccutrends, and new technologies organized by ACS rion's products, is an excellent tool for a broad Industry Member Programs. Explore dynamic pre range of applications, including R&D, failure analy sentations, network with peers, and enter daily sis and quality control. 19z0 prize drawings: Professional Development in the Industrial workplace: technician advancement, Ace Glass, Inc., 1430 Northwest Blvd., Vineland, multicultural communications, personal creativity, NJ, USA 08360, (800)223-4524, fax: (800)543intellectual property issues, and career alterna 6752, e-mail:
[email protected], Internet: acetives; Medical Technologies and Trends in Indus glass.com Ace will exhibit pressure reaction equip try: pharmacogenomics, programmable drug ment alonq with 'big' pilot plant equipment with delivery, monitoring and sensing materials, and chillers. Also, the new filter reactors with remov speeding drug delivery with industrial-scale bio able filter discs. Packed chromatography columns technology; Emerging Technologies and Industrial with repacking service. Instatherm, the modern Applications: e-textiles, biométrie skin chips, way to heat glassware. The new small volume hybrid gas-electric vehicles, 3-D printers and cusevaporator system, plus many more items of inter tom manufacturing, and display technologies; est. 613 Commercializing New Technologies from Concept to Market; Cultivating a Business Mindset in Acros Organics, 500 The American Road, Morris Chemical Professionals. Workshops will be held Plains, hfj, USA 07950, (973)753-1940, fax: on: Monday and Tuesday (March 24-24) from 9:30 (973)753-1976, Internet: www.acros.com Acros AM to 4:30 PM and Wednesday (March 26) from Organics is a Fisher Scientific Worldwide com 10 AM to 12:30 PM. 833 pany. Our roots lie in the Janssen Chimica and Eastman Organics businesses, which were ACS Membership, 1155 16th St., N.W., Washingacquired and combined in 1994 to form Acros ton, DC, USA 20036, (202)872-4600, fax: (202)872Organics. Today, we offer a comprehensive array 6337, e-mail:
[email protected], Internet: www. of fine chemicals for research and industry in pre chemistry.org/membership There will be special packaged and semi-bulk quantities. Acros Organ events you won't want to miss—exciting presenics continually improving its product range to tations, important information, and an opportunity meet, as well as to anticipate, the changing needs to purchase chemistry-related merchandise. of today's chemists. 216 Browse through a generous selection of t-shirts, tote bags, pens, mugs, "mole" merchandise, and much more! We also have many products displayACS chemistry.org, 1155 16th St., N.W., Wash ing the periodic table. Get your national meeting ington, DC, USA 20036, (800)227-5558, fax:
EXHIBITORS
2-EXPO
commemorative pin—only a limited number produced. Don't Miss Out! 1026 ACS Office of Community Activities, 1155 16th St., N.W., Washington, DC 20036, (202)872-6097, fax: (202)833-7722, e-mail :
[email protected], Internet: chemistty.org/oca This exhibit is designed to support all AfcS local section community activities. Visit this site to learn the latest developments for celebrating NCW-2003 and its theme "Earth's Atmosphere and Beyond!" Find out about the Chemagination, Salutes to Excellence, Chemists in the Library, and Earth Day programs, as well as view and purchase specialty products. Meet representatives of the Office οτ Local Sections and Community Activities. Free give-a-ways! 1125 ACS Publications, 1155 16th St. NW, Washington, DC, USA 20036, (202)872-4600, fax: (202)8724615, e-mail:
[email protected], Internet: http://pubs@ acs.org ACS Publications is privileged to serve the chemical sciences community in publishing the most read, most respected, and most referenced journals and magazines in chemistry. ACS Publica tions also offers the ACS Journal Archives over a century of chemistry on your desktop. Accessible through institutional subscriptions, ACS Journal Archives features an easy-to-search online data base of all ACS journals from the first issue pub lished up to the current subscription, including the Journal of the American Chemical Society back to 1879. ACS Publications is proud to celebrate the 125th volume of J ACS as well as the 80th anniver sary of Chemical & Engineering News. Please join us in the celebration of these important milestones and more. Visit our Today's Chemist at Work and Modern Drug Discovery booths offering compli mentary subscriptions to qualified individuals. Today's Chemist at Work provides industrial chemists with the latest information on the most novel chemical applications and instrument and software reviews to help them in their everyday activities. This magazine covers numerous fields including analytical chemistry, biotechnology, environmental regulations, pharmaceuticals, com puter -aided chemistry, formulations and more. Modern Drug Discovery, a must-read magazine for drug discovery and life science research profes sionals focuses on emerging trends and technolo gies in such areas as: genomics, proteomics, bioinformatics, combinatorial chemistry, and high throughput screening. ACS Publications: High quality, high impact, http://pubs.acs.org. 816,817 Advanced Chemistry Development, 90 Adelaide St., West, Suite 702, Toronto, ON, CANADA M5H 3V9, (800)304-3988, fax: (416)368-5596, e-mail:
[email protected], Internet: www.acdlabs.com Advanced Chemistry Development (ACD/Labs) is a chemistry software company offering solutions that truly integrate chemical structures with ana lytical chemistry information. ACD/Labs creates innovative software packages that aid chemical research scientists worldwide with spectroscopic validation of structures, elucidation of unknown substances, chromatographic separation, medici nal chemistry, preformulation of novel drug agents, and chemical patenting and publication. Combined, ACD/Labs' solutions create an analyti cal informatics system that provides dramatic feed-forward effects on the chemical research pro cess. Founded in 1993, and headquartered in To ronto, Canada, ACD/Labs employs a team of over 100 dedicated individuals whose continual efforts carry ACD/Labs' innovative technologies into pharmaceutical, biotech, chemical, and materials companies throughout the world. Information about Advanced Chemistry Development and its products can be found at www.acdlabs.com. 1506,1508,1510 Advanced ChemTech, 5609 Fern Valley Rd., Lou isville, KY, USA 40228, (800)456-1403, fax: (502)962-5368, e-mail:
[email protected], Inter net: www.advancedchemtech.com Advanced ChemTech provides automated, semi-automated, and manual peptide and organic synthesizers for solution or solid phase chemistry. Prom lead dis covery through scaleup to production, Advanced ChemTech has a synthesizer to fit your scale. Advanced ChemTech is also a leading manufac turer of high quality synthesis resins, scavenger resins, amino acid derivatives, chiral unusual amino acids, and special amino acid derivatives for chiral synthesis. In addition, Advanced ChemTech provides high quality custom peptides. 1601,1603
Agilent Technologies, 2850 Centerville Rd., Wilmington, DE, USA 19808-1610, (302)633-8264, fax: (302)633-8944, Internet: http://www.agilent. com Agilent is a leading provider of life sciences and analytical instrument systems to scientists in life sciences, pharmaceutical, environmental and chemical industries, worldwide. The company offers scientists the range of instruments, systems and services needed for success in acquiring and interpretinq qenetic and chemical information from sample handling, to analysis to data manage ment and reporting. We are committed to provid ing superior standards-based technology, designed for maximum productivity, cost effec tiveness and ease in complying with regulatory requirements. Please visit us at www.agilent.com/ chem. 513,515 Aldrich/Sigma-Aldrich, 3050 Sp ruce St., St. Louis, MO, USA 63103, (314)286-7727, fax: (314)2867817, Internet: http://www.sigmaaldrich.com. 900,902 Alfa Aesar - A Johnson Matthey Co., 30 Bond St., Ward Hill, MA, USA 01835, (800)343-0660, fax: (800)322-4757, e-mail:
[email protected], Internet: www.alfa.com Alfa Aesar, is a leading international manufacturer and supplier of research chemicals, metals and materials. The Alfa Aesar Research Chemicals, Metals and Materials Catalog carries nearly 22,000 products including high purity inor ganics, organics, pure metals, alloys, elements, precious metal compounds and catalysts, rare earths, AA/ICP standards and more. Our complete product line is also available on the Web throuqh our online catalog at www.alfa.com. 1219,1221 Alltech Associates, Inc., 2051 Waukegan Rd., Deerfield, IL, USA 60015, (800)458-3769, fax: (847)948-1078, e-mail:
[email protected], Internet: www.alltechweb.com Alltech design, test and manufacture the world's best chromatography products. We are your one-stop-shopping sup plier for all your chromatography needs. For more than 30 years our experience products and ser vices have solved the touqhest separation chal lenges. This year we are snowing our new ELSD 800 detector, an important development in detec tion that every chromatography lab should know about. 727 American Institute of Physics, 2 Huntington Quadrangle, Suite #1 N O I , Melville, NY, USA 11747, (516)576-2485, fax: (516)576-2374, e-mail:
[email protected], Internet: www.aip.org Now pur chase an AIP Article Pack. Simply prepay for a set number of articles from AlP's core journals and save more than 60 percent off the sinqle-article price. Visit AIP to learn about our Virtual Journals. Save more than 40 percent off our low member rates with online-only journal subscriptions, and take advantage of our 40 percent discount on AIP Conference Proceedings. Sample copies of Jour nal of Chemical Physics, Journal of Physical and Chemical Reference Data, and Journal of Applied Physics will be available. 1819 American Laboratory (Intl Sci Com), 30 Controls Dr., Shelton, CT, USA 06484, (203)926-9300, fax: (203)926-9310, e-mail:www.iscpubs@iscpubs. com, Internet: iscpubs.com American Laboratory is edited for North American chemists and life sci entists who have a professional interest in the application of modern instrumentation analytical chemistry, bioanalysis, and applied spectroscopy. The editorial includes application notes, technical articles, conference reviews, and information on the most current laboratory instrumentation. 1734,1735 Amgen, One Amgen Center Dr., Thousand Oaks, CA, USA 91320, (805) 447-6748, fax: (805) 4471985, Internet: http://www.amgen.com. 329 Analogix, Inc., 133 Industrial Dr., Burlington, Wl, USA 53105, (262)767-9111, fax: (262)767-1879, Internet:
[email protected] 627,629 Anasazi Instruments Inc., 4101 Cashard Ave., #103, Indianapolis, In, USA 46203, (317)783-4126, fax: (317)783-7083, e-mail:
[email protected], Inter net: www.aiinmr.com Eft-Permanent Magnet Pulsed FT NMR The Anasazi Instruments Inc Model Eft-NMR is a high through put, easy-to-use, low-cost, very low maintenance, PC-based FT NMR spectrometer designed for open-access use in teaching laboratories, industrial quality control and process laboratories. With over 200 installed
in North America the Eft has a proven track record for reliability. 1326 Antek Instruments, Inc., 300 Bammel Westfield Rd., Houston, TX, USA 77090, (800)365-2143, fax: (281)580-0719, e-mail:
[email protected], Inter net: www.antekhou.com Antek is a manufacturer of laboratory and process/on-line nitrogenspecific and sulfur-specific detectors for gas, liquid and SFC chromatography. Products are sold to multiple industries, from petrochemical to pharmeceutical industries. 724 Argonaut Technologies, 1101 Chess Dr., Foster Citv, CA, USA 94404, (877)655-4200, fax: (650)655-4300, e-mail:
[email protected], Inter net: www.argotech.com Founded in 1994, Argo naut Technologies provides innovative and reli able chemistry solutions for the life science and chemical industries, including instrumentation, consumables, service and informatics. Argonauts synthesis, purification, sample preparation and analysis tools enable chemists to improve produc tivity and accelerate discovery and development. Organic, medicinal, process and analytical chem ists use our products. Argonaut employs over 235 employees worldwide and has operations in North America, Europe and Japan. Its worldwide head quarters are in Foster City, California. 1010,1011,1012,1013 Array BioPharma, 3200 Walnut St., Boulder, CO, USA 80301, (303)381-6600, fax: (303)381-6697, e-mail:
[email protected], Internet: www. arraybiopharma.com Array BioPharma is a drug discovery company creating new small molecule drugs throuqh the integration of chemistry, biol ogy and informatics. Our experienced scientists use an integrated set of drug discovery technolo gies, which we call the Array Discovery Platform, to invent small molecule drugs in collaboration with leading pharmaceutical and biotechnology com panies and to build our own pipeline of propri etary drug candidates. 1244 Astatech Inc., 1 Deer Park Dr., Suite C, Monmouth Junction, Ν J, USA 08852, (732)355-1000, fax: (732)355-1122, e-mail:
[email protected], Internet: www.astath.com 1000 advanced intermediates for drug discovery and development: Novel building blocks, multifunctional amines, heterocyclic com pounds, chiral amines, unnatural amino acids, boronic acids. Service area: Customer synthesis, contract research and process development with new technologies, such as chiral synthesis, enzy matic reaction, enzyme resolution. 1331 Asylum Research, 341 Bollay Dr., Santa Barbara, CA, USA 93117, (805)685-7077, fax: (805)6855007, Internet: http://www.asylumresearch.com Asylum Research will be demonstrating the MFP-3D AFM. Features include the patentpending Nanopositioning System (NPS) for unprecedented control over position while oper ating in closed loop (all three axes); the first com mercially-available all-digital controller, powerful IGOR Pro open software; and MicroAngelo nanolithography and manipulation capabilities that are standard in every system. Top and bottom optical access make it ideal for optical measurements such as phase contrast, epi/transmission fluores cence, etc. New accessories include the BioHeater and phase illumination optics. 1435 BACHEM, 3700 Horizon Dr., King of Prussia, PA, USA 19406, (800)634-3183, fax: (610)239-0800, e-mail:
[email protected], Internet: www. bachem.com Bachem is a leading manufacturer of peptides and other biochemicals. Our catalog lists more than 8,000 high quality products. Enzyme substrates and inhibitors, amino acid derivatives, peptide antibodies, immunoassays and immunostaining kits are among them. Services include cGMP manufacturing, bulk production, custom peptide and antibody production, and peptide iodination. 1700 Barnstead International, 2555 Kerper Blvd., Dubuque, IA, USA 52001, (563)556-2241, fax: (563)589-0516, Internet: http://www.barnstead. com 1826 Benjamin/Cummings, 1301 Sansome St., San Francisco, CA, USA 94111, (415)402-2500, fax: (415)402-2544, e-mail:bcfeedback.com, Internet: http://www.aw.com/bc College science publisher of textbooks and multimedia products. New for Allied Health Chemistry: GOB Chemistry Platinum Edition for the 2 semester course and Chemistry
8e for the 1 semester course by best selling author Karen Timberlake. New for Liberal Arts Chemistry: Conceptual Chemistry 2e by John Suchocki. For Intro/Prep Chemistry: Introductory Chemistry 2e by Steve Russo, Cornell University and Mike Silver, Hope Colleqe and An Introduction to Chemistry by Mark Bishop, Monterey Peninsula College. 701 Bentham Science Publishing, P.O. Box 1673, Hilversum, THE NETHERLANDS 1200, Internet: www. bentham.org Bentham Science Publishers is a major top ranking journal publishers satisfying the informational needs of the pharmaceutical, chemi cal and bio-medical research community. All jour nals are available in print and online. Following are some of the leading journals: Current Medicinal Chemistry (ranked one in the field of medicinal chemistry), Current Pharmaceutical Design, and Current Drug Targets. Just launched are the fol lowing: Current Medicinal Chemistry-Cardiovas cular and Hematological Aqents, Current Neuro pharmacology, Current HIV Research. For details please visit our web site www.bentham.org 218 Berghof/America, 3773 N.W. 126th Ave., Unit 1, Coral Springs, FL, USA 33065, (954)344-2554, fax: (954)344-2008, e-mail:
[email protected], Internet: www.berghofusa.com The only high pressure reaction vessels with a complete liner of PTFE (Cap & Vessel), for organic synthesis, fluoropolymer acid purification systems for nitric, hydrochloric and hydrofluoric acids. PTFE micro wave digestion vessels for small sample prep in an acid resistant vessel. Distillation apparatus with all exposed parts of fluoropolymers. Fluoropolymer custom machining, fabrication, coating, and liners. Fluoropolymer labware, storage containers, valves, fittings, stirrers, sleeves, gas sampling bags, adapters, filters, heaters, pumps, flow con trollers, tubing, film, sheet, rod. 319 Berry & Associates, 2434 Bishop Circle East, Dex ter, Ml, USA 48130, (734)426-3787, fax: (734)4269077, e-mail:
[email protected], Internet: www.berryassoc.com Berry & Associates, Inc. is a leading source of purine nucleosides, purine nucleoside analoqs, pyrimidine nucleosides, pyrimidine nucleoside analogs, and C-nucleosides. These include a library of minor base nucleosides found in cellular RNA and DNA, and major base DNA damaged/repaired nucleosides. In addition, we offer a variety of heterocycles, biotins, carbo hydrates, linkers, fluoresceins, rhodamines and psoralens, along with other specialty chemicals to advance life sciences. 1245 Biacore, 200 Centennial Ave., Suite 100, Piscataway, NJ, USA 08854, (800)242-2599, fax: (732)885-5669, Internet: www.biacore.com Bia core systems enable direct detection and monitor ing of biomolecular binding events in real-time without labeling using Surface Plasmon Resonance (SPR). Enabling scientists to develop higher con tent assays than from any single technology. Stop by our booth to learn how this technology impacts areas such as proteomics, neuroscience, cancer research, developmental cell biology, structural biology and immunology. 122 Bio-Rad, Informatics Division, 3316 Spring Gar den St., Philadelphia, PA, USA 19104, (215)3827800, fax: (215)662-0585, e-mail:informatics.usa@ bio-rad.com, Internet: http://www.knowitall.com The Informatics Division of Bio-Rad specializes in state-of-the-art software and database solutions for the pharmaceutical, biotech, and chemical industries. As a leader in cheminformatics and ana lytical informatics, Bio-Rad is a leading publisher of fully verified spectral databases, with a collection that contains MS, NMR, IR, and Raman. Bio-Rad Laboratories, Inc. is a multinational manufacturer and distributor of life science research products and clinical diagnostics. It is based in Hercules, California, and serves more than 70,000 research and industry customers worldwide. 1501 Bioanalytical Systems, Inc., 2701 Kent Ave., West Lafayette, IN, USA 47906, (765)463-4527, fax: (765)497-1102, e-mail:
[email protected], Internet: www.bioanalytical.com BASi will display its line of electrochemical instruments and acces sories, including the epsilon potentiostat/ galvanostat, Rotating Disk Electrode and DigiSim Cyclic Voltammetry simulation software. 1500 EXPO-3
EXPOSITION BioPharm Magazine, 485 Route 1 South, Building F, 1st Floor, Iselin, Ν J, USA 08830, (800)933-5354, fax: (732)225-0211, e-mail:tlarranaga@advanstar. com, Internet: www.biopharm-mag.com BioPharm International, one of the largest circulated publi cation in the biopharmaceutical market, provides peer-reviewed editorial to a global audience involved in the development and manufacture of pharmaceutical products throuah biotechnology. Focusing on the entire scope of applied technolo gies, it provides 36,200 subscribers with practical information about areas such as Drug Discover/ Preclinical Development, Investigational New Drug Application, Phase l-IV Clinical Develop ment, Biologies License Application, Scale-Up, Manufacturing, Contract Services and Logistics.
100 BioPro International Inc., 265 Conklin St., Farmingdale, NY, USA 11735, (516) 249-0099, fax: (516) 249-0494, e-mail:
[email protected], Internet: www.biopro.com Exhibiting state-of-the-art pro cessing equipment and instruments for the phar maceutical and biotech industries. Featured are: Kuehner biological shakers; bioengineering fermenters/bioreactors. Aquasant fiber-optics celldensity meters and level controls; Contardi mul tiple laboratory fermenter systems; Christ freeze dryers and vacuum concentrators for sample preparation; Graber vibrating mixers; PCS Control systems; Prior preparative continuous annular chromatography, DrM solid/liquid filters and ESCO biological safety cabinets. 1802 BioQuadrant Inc., 230 Bernard-Belleau St., Suite 212, Laval, PQ, CANADA H7V 4A9, (450)6869 4 4 0 , fax: ( 4 5 0 ) 6 8 6 - 4 9 8 0 , e-mail:info@ bioquadrant.com, Internet: www.bioquadrant.com BioQuadrant Inc. offers the pharmaceutical and biotech industry novel specialty amino acids and building blocks to create the drugs of the future. The company's drug discovery services include hit-to-lead support via the creation and synthesis of targeted libraries centered on BioQuadrant's unique combinatorial templates. The company also offers drug development support, including process optimization, scale-up, HPLC method development and validation. 1540 Biotage, P.O. Box 8006, Charlottesville, VA, USA 22906, (800)446-4752, e-mail:ltomko@biotage. com, Internet: www.biotage.com Come learn how our new tools to be launched at ACS can improve purification and speed drug discovery for medici nal and synthetic organic chemists, turrent High Performance Flash Chromatography (HPFC) prod ucts include: Horizon, Horizon Pioneer and Quad UV parallel purification, cartridges and Samplets. For medicinal and combinatorial chemists, Biotage offers the Parallex Flex, a parallel prepHPLC system with mass characterization. The pro duction-scale FLASH and HPLC (KiloPrep) system and cartridges are available for cGMP production. 1607 BrandTech Scientific, 11 Bokum Rd, Essex, CT, USA 06428, (888)522-2726, fax: (860)767-2563, e-mail:
[email protected], Internet: www. brandtech.com BrandTech Scientific supplies BRAND liquid handling devices, Vacuubrand oilfree vacuum pump systems, and Bochem corrision-resistant, stainless steel lab jacks. The compa ny's line includes the Dispensette III and Dispensette Organic bottle-top dispensers; the ergonomie, accurate Transferpette single- and multi-channel digital pipettes; the accu-jet motor ized pipette controller; the HandyStep electronic repeating pipette; and a full range of pipette tips. Also exhibiting oil-free diaphragm vacuum pumps, mercury-free vacuum gauges and vacuum control lers. 304 Brinkmann Instruments, Inc., One Cantiague Rd., Westbury, NY, USA 11590-0207, (516)334-7500, fax: (516)334-7521, Internet: h t t p : / / w w w . brinkmann.com 706 Brookhaven Instruments, 750 Blue Point Rd., Holtsville, NY, USA 11742-1832, (631)758-3200, fax: (631)758-3255, e-mail:
[email protected], Internet: www.bic.com Brookhaven Instruments is a manu facturer of cjuality instrumentation for colloid and polymer characterization, quality control & research applications. Particle size measurements are obtained utilizing dynamic light scattering or disc centrifugation. Instruments determining zeta 4-EXPO
potential by particle electrophoresis, phase analy sis and streaming potential are also available. Our goniometer/autocorrelator system and molecular weight analyzer, both utilize static light scattering and are offered for polymer solution characteriza tion and absolute molecular weight determina tions. 1418 Brooks/Cole Thomson Learning, 10 Davis Dr., Belmont, CA, USA 94002, (650)413-8825, fax: (650)595-0260, Internet: www.brookscole.com 1201,1203,1205,1207 Bruker AXS Inc., 5465 East Cheryl Parkway, Madi son, Wl, USA 53711, (608)276-3000, fax: (608)2763006, e-mail:
[email protected], Internet: www. bruker-axs.com Bruker Nonius provides Advanced X-ray Solutions in chemistry, life sciences, and materials science. New X8APEX small molecule CCD systems feature highest sensitivity and most flexible kappa goniostat for all types of crystalline samples, including microcrystals and weak diffractors, and handle advanced research problems with twins, strong absorbers, charge density studies, modulated structures and diffuse scattering. Bio logical macromolecule systems feature the most sensitive CCDs and high brilliance generators for high resolution data and high throughput screen ing. 800,802 Bruker BioSpin/Bruker Optics, 15 Fortune Dr., Manning Park, Billerica, MA, USA 01821, (978)6679580, fax: (978)667-0985, e-mail:sales@bruker. com, Internet: www.bruker.com Bruker BioSpin Corporation designs, manufactures and distrib utes enabling life science tools based on magnetic resonance core technology. Our technology plat forms include NMR, EPR, MRI, benchtop process analysis by NMR/EPR, and superconducting mag nets. Bruker Optics, Inc is a leading instrumenta tion company offering a complete line of FT-IR, Raman, FT-NIR and LR-NMR spectrometers for QA/QC, process control, research and life science applications. 801 Bruker Daltonics, 40 Manning Rd., Billerica, MA, USA 01821, (978)663-3660, fax: (978)667-5993, e-mail:
[email protected], Internet: www.bdal. com Bruker Daltonics Inc. is a leading manufac turer of mass spectrometry instruments and acces sories for biotechnology and the life sciences. Our products include a complete variety of FTMS, MALDI-TOF, MALDI- TOF/TOF, ESI-LC/TOF, ESI-Q-q-TOF, and ESI-lon Trap systems, as well as a complete line of automated sample processing systems and productivity-enhancing software for all of your mass spectrometry needs. We are one of the world's market leaders in FTMS technology and a major key supplier for MALDI TOF and ESI Ion Trap systems. 803 Buck Scientific, 58 Fort Point St., East Norwalk, CT, USA 06855, (203)853-9444, fax: (203)8530569, Internet: http://www.bucksci.com 418 C/D/N Isotopes, 88 Leacock St., Pointe Claire, Quebec, PQ, CANADA H9R 1H1, (514)697-6254, fax: (514)697-6148, e-mail:
[email protected], Inter net: www.cdnisotopes.com Over the last 10 years C/D/N Isotopes has developed one of the world's most extensive list of deuterated compounds. We have continued to develop methods of prepara tion, allowing us to offer an expanded range of products and higher quality. Our extensive custom synthesis experience allows us to meet the particu lar requirements of your research. Our product list ing continues to grow daily as a result of the preparation of products at our customers' request. 1429 CAChe Group, Fujitsu, 15244 N.W. Greenbrier Parkway, Beaverton, OR, USA 97006-5733, (503)746-3600, fax: (503)531-9966, e-mail:sales@ cachesoftware.com, Internet: h t t p : / / w w w . cachesoftware.com CAChe Group is a leading provider of computer-aided chemistry software and services for predicting molecular structure, properties, spectra, reactions, thermodynamics, and kinetics. 908,910,912 Calbiochem-Novabiochem Corporation, 10394 Pacific Center Ct., San Diego, CA, USA 92121, (858)450-9600, fax: (858)453-3552, Internet: http://www.novabiochem.com Novabiochem is a leading supplier of resins, amino acids, coupling reagents for solid phase peptide synthesis and
solid or solution phase organic synthesis. New innovative products are now available: Labelled Fmoc amino acids, Unusual amino acids, Deriva tives for synthesis of difficult peptides, Derivatives for chemoselective ligation, A very comprehensive range of scavenger resins and polymer supported reagents. Visit www.novabiocnem.com for addi tional information. Get your copy of the new Nova biochem Catalog at our booth 127. 127 California Pacific Laboratory, 37 Commercial Blvd., Suite 100, Novato, CA, USA 94949, (415)883-2600, fax: (415)532-1662, Internet: http://www.calpaclab.com 1437 Cambridge Crystallographic Data Ctr, 12 Union Rd., Cambridge, UNÎTED KINGDOM CB2 1EZ, +44 1223 336408, fax: +44 1223 336033, e-mail:
[email protected], Internet: www. ccdc.cam.ac.uk The CCDC collates and distributes the Cambridge Structural Database CSD which contains comprehensive crystal structure data for small organic and metal-organic compounds. The CSD system consists of the database itself, and accompanying software for search and retrieval ConQuest, structure visualisation Mercury and statistical analysis Vista. The CCDC also undertakes the development of the structural knowledge bases IsoStar and Mogul and a range of applications software - Gold, buperStar, Relibase Plus and DASH. 224,226 CambridgeSoft Corporation, 100 Cambridge Park Dr., Cambridge, MA, USA 02140, (617)5999100, fax: (617)588-9190, e-mail:jbaronofsky@ c a m b r i d g e s o f t . c o m , Internet: www. cambridgesoft.com CambridgeSoft develops and markets desktop software, enterprise solutions and chemcial databases for scientists in pharmaceutical, biotechnology, chemical industries and academic research organizations. Software products include desktop to enterprise versions of ChemOffice, including ChemDraw for structure drawing; Chem3D for molecular modeling; and Ε-Notebook, for electronic journalinq. Newest additions to ChemOffice suite include: The Merck Index, Ε-Notebook, CombiChem Excel, ChemSAR Excel, and ChemDraw Excel. ChemOffice Web server provides enterprise solutions for Internet, intranet and extranet knowledge management, research and discovery, applied bioinformatics and chemical database applications, including: Ε-Notebook, Document Manager, Discovery LIMS, 21CFR11 Compliance, Registration Sys tems, Inventory Manager, CombiChem, BioAssay HTS, BioSAR Browser and chemical databases, including ChemACX for Available Chemicals, Chemlndex and The Merck Index. Websites include ChemFinder.Com, and ChemNews.Com for indexed database content and news and ChemStore.Com for e-commerce. 601 Carbolite Inc., P.O. Box 7, 110 South 2nd St., Watertown, Wl 53094, (920)262-0240, fax: (920)262-0255, e-mail:
[email protected], Internet: www.carbolite.com Exhibiting a line of laboratory furnace and oven products for the research environment. Product range includes multiple chamber sizes of box and tube furnaces for operation to 1800C, oven products to 600C, and incubators to 80C. Carbolite also provides modified designs or complete custom engineered equipment to meet specific customer process requirements. 1725 Cardinal Health, Pharmaceutical Development, P.O. Box 13341, Res. Triangle Park, NO, USA 27709, (919)481-4855 ext. 2, fax: (919)481-4908, e-mail:
[email protected], Internet: www. cardinal.com/pts The pharmaceutical develop ment business of Cardinal Health provides comprehensive contract resources to the pharma ceutical and biotechnology industry. Our innova tive team of chemists has significant synthetic expertise to address your needs. We can supply milligram to kilogram quantities of your products from our fully equipped R&D laboratories and GMP suites. Other "pharmaceutical development services offered by Cardinal Health include discov ery support, product development, pharmaceuti cal analysis, clinical supply services and manufac turing of any dosage form. 205 CE Elantech, 170 Oberlin Avenue North, Suite 5, Lakewood, NJ, USA 08701, 888-CE-CHNSO (2324676), fax: (732)370-3888, e-mail:sales@
ceelantech.com, Internet: http://www.ceelantech. com The Flash EA1112 Combustion Elemental Analyzer from ThermoFinnigan (formerly Carlo Erba), the latest evolution of combustion elemen tal analyzers, building on the success of our previ ous models will be featured. The Flash EA1112 is available in all configurations (N/Protein, NC SOIL, CHN, CHNS, O, etc.). Capabilities include: large sample size, rapid analysis time, reduced mainte nance, compact, and steamlined design. Also, the new FPD Trace Sulfur System will be displayed for low level sulfur analysis in a wide variety or mate rials. 117 CEM Corporation, 3100 Smith Farm Rd., Mat thews, NC, USA 28104, (704)821-7015, fax: (704)821-5185, e-mail:
[email protected], Internet: www.cemsynthesis.com Optimize reactions, while enhancing molecular diversity and productivity with the first complete line of modular microwave synthesis systems. The fundamental core technol ogy begins with the Discover System for Manual Synthesis. The Explorer PLS Automated Synthesis Workstation and voyager Flow Reactor build upon this basic unit, going from milligrams to kilograms, quickly and easily. Perform atmospheric and pres surized reactions. PowerMAX, CtM's latest pat ented technology, has been shown to double yields in some reactions. 1335,1337 Cerep, Inc., 15318 NE 95th St., Redmond, WA, USA 98052, (425)895-8666, fax: (425)895-8668, Internet: http://www.cerep.com 223 Chemat Technology, 9036 Winnetka Ave., Northridge, CA, USA 91324, (818)727-9786, fax: (818)727-9477, Internet: http://www.chemat.com 322 ChemBridge Corporation, 16981 Via Tazon Dr., Suite G, San Diego, CA, USA 92127, (800) 9646143, fax: (858) 4 5 1 - 7 4 0 1 , e-mail:info@ chembridge.com, Internet: www.chembridge.com CRL and ChemBridqe together represent the industry's largest independent discovery chemis try contract research and outsourcing organization with 400 scientists and professionals worldwide. ChemBridge offers a 300,000+ drug-like molecule collection and another 100,000 compounds can be accessed from the PHARMACophore combina torial library. Also, ChemBridqe possess the indus try's largest proprietary building block collection. CRL (ChemBridge Research Laboratories) focuses on combinatorial chemistry endeavors such as cus tom and focused libraries (GPCR), lead optimiza tion, and collaborative drug discovery projects.
1918 Chemglass, Inc., 3861 North Mill Rd., Vineland, Ν J, USA 08360, (800)843-1794 or (856)696-0014, fax: (800)922-4361 or (856)696-9102, e-mail:
[email protected], Internet: www. chemglass.com Exhibiting our complete line of specialty glassware and equipment. Featured products include our process reactors from 10 to 100 Liters, benchtop reactor systems from 250mL to 4 liters and our Optichem line of sample han dling solutions for combinatorial chemistry. Other products in the display include our hot-plate stir rers, all Teflon diaphragm pumps, Julabo's Presto circulators, Heidolph rotary evaporators, pressure vessels and NMR tubes. 514,516,518,520 Chemical & Engineering News, 1155 16th St., N.W., Washington, DC, USA 20036, (202)8724600, fax: (202) 872-8727, Internet: www.cenonline.org Join Chemical & Engineering News to celebrate 80 years of covering the chemical enter prise. Stop by the Chemical & Engineering News booth and drop off a completed copy of the short survey in your registration package to receive a specially minted coin commemorating this impor tant milestone in the chemical publishing industry. Meet Editor-in-Chief Madeleine Jacobs on Mon day, March 24th from 11:00 to 1:00 p.m., and take part in other special Chemical & Engineering News sponsored events. In addition, take a tour of www.cen-online.orq featuring daily updates of the latest science ana technology, government and policy, and business and industry news. On Tues day, March 25, help us celebrate the launch of chemjobs.org - the new online job site for chemi cal sciences professionals. Chemjobs.orq was cre ated through a partnership between Cnemical & Engineering News Classifieds and JobSpectrum. org. 825
Chemical Abstracts Service, 2540 Olentangy River Rd., Columbus, OH, USA 43202, (614) 4473600, fax: (614) 447-3837, e-mail:
[email protected], Internet: www.cas.org CAS creates and delivers the most complete and effective digital informa tion environment for scientific research and dis covery. CAS provides you with pathways to pub lished research in the world's journal and patent literature plus information in the life sciences and other scientific disciplines back to the beginning of the 20th century. Whether you are beginning a research project, looking for prior art in assessing patentability or uncovering information on other industry, CAS provides a range of information products to meet your needs. CAS products include web, online, CD-ROM services and Print. Specific proiducts include STN, STN on the Web, STN Easy, SciFinder and SciFinder Scholar desk top research tools and CA on CD. To enter the future of research, talk to a CAS representative. 1-800-753-4227 or (614) 447-3731 or by email:
[email protected] 1018 Chemical Computing Group, 1010 Sherbrooke St. West Ste. 910, Montreal, PQ, CANADA H3A2R7, (514)393-1055, fax: (514)874-9538, e-mail:
[email protected], Internet: www.chemcomp. com Chemical Computing Group eases the discovery process with award winning software for the pharmaceutical and biotech industries. MOE, the Molecular Operating Environment is a multiapplication product designed to overcome obstacles facing today's leading researchers. MOE contains a complete range of computational appli cations in drug discovery. These include: Small molecule and Protein modeling, Structure Based Design, High Throughput Discovery and Cheminformatics. Source code to these applications is provided, thus making MOE fully customizable. This unique architecture, coupled with the flexibil ity of platform independence does indeed make MOE the single remedy for the aches and pains of drug discovery. 1211,1311 Chemical Diversity Labs, Inc., 11558 Sorrento Valley Rd., Suite 5, San Deigo, CA, USA 92121, (858)794-4860, fax: (858)794-4931, Internet: http://chemdiv.com Chemical Diversity Labs is introducing a novel family of original CombiSyn reactors a reliable tool for the high speed parallel synthesis of small diverse libraries of pure com pounds with the following advantages: Modular ity; Individual reaction control; Bacldlow condens ers for application of volatile solvents. Central inert gas distribution system with direct passing through; Compatibility with standard laboratory equipment; The temperature range from minus 30 to plus 250 degrees centigrade. 1241 Che m Pacific Corporation, 6200 Freeport Centre, Baltimore, MD, USA 21224, (410)633-5771, fax: (410)633-5808, e-mail:szinkand@chempacific. com, Internet: www.chempacific.com ChemPacific corporation offers contract research, custom chemical, and API manufacturing services. Our state-of-the-art research and development facili ties are located in Baltimore, Maryland and in Shanghai, China. Our China based facility is equipped a kilo lab, pilot plant and an API manu facturing plant. We assure customers flexibility, high quality and cost-effective products and ser vices. ChemPacific is able to handle a wide range of short- and long-term projects up to Kg scale under cGMP conditions in Baltimore ancT largescale production in our China facilities. /21 Chemspeed Ltd., Rheinstrasse 32, Augst, NJ, SWITZERLAND CH-4302, 41618169500, fax: 41618169509, Internet: http://www.chemspeed. com. A global leader in the development of inno vative chemistry instruments ana consumables including manual and fully automated parallel syn thesizers with a wide variety of options including reactors for chemistry under pressure of up to 100 bar and the heating of individual reactors. Newly released Accelerator Dual Dosing Station is the only high throughput instrument that combines solid dispensing and liquid handling on one plat form. Products and services that reduce time-tomarket schedules, increase productivity, and lower costs for biotechnology chemistry laboratories.
Internet: www.combi-blocks.com Combi-Blocks is a major manufacturer and worldwide supplier of a series of chemical compounds called combinato rial building blocks. Its major products include vari ous kinds of boronic acids, imidazoles, indoles, oxindoles, anilines, nitrobenzenes, tetrahydropyrans, as well as resins and scavangers. It also pro vides custom synthesis for other building blocks.
1741 CombiPhos Catalysts, Inc., P.O. Box 220, Prince ton, NJ, USA 08542-0220, (800)659-9793 or (908)281-7168, fax: (908)281-9698, e-mail:info@ combiphos.com, Internet: www.combiphos.com CombiPhos Catalysts, Inc. is a combinatorial tech nology-based application company which devel ops, manufactures, markets a wide variety of com binatorial homogeneous catalysts, which are made with technology licensed from the DuPont Com pany. CombiPhos Catalysts, Inc. is the sole pro vider of highly active, air- and moisture-stable cross-coupling catalysts (POPd, POPdl and POPd2) that have been used in over 100 pharma ceutical, agrochemical, and chemical companies worldwide since 2002. 1726 Comgenex, One Deer Park Dr., Suite I, Monmouth Junction, NJ, USA 08852, (732)438-8001, e-mail:
[email protected], Internet: www.comgenex. com ComGenex, Inc. & ComGenex International, Inc. provide integrated drug discovery chemistry to the pharmaceutical and biotechnology indus tries. ComGenex offers complete discovery solu tions for over 200 worldwide customers and part ners through compound libraries, library design, and synthesis of non-exclusive and exclusive librar ies. Since 1992, ComGenex has had expertise in the pharmaceutical sciences in providing hit-tolead and other synthetic services. We contract out FTE scientists and have long term collaborations with new startups and big pharma. 526 Conflex Corporation, 25 Yamashita-cho, Naka-ku, Yokohama 231-0023, Japan, 81-45-222-6610, fax: 81-45-222-7708, e-mail:
[email protected], Internet: www.Conflex.us CONFLEX2000 software prod ucts allow for fast, automated conformation searching and analysis critical to drug discovery and chemical engineering. Determine conforma tions of large molecules fast with Parallel CONFLEX. Use the results of CONFLEX2000 products for input to ab-initio calculations. Avail able only from Conflex Corporation are the latest versions of CONFLEX2000 and Parallel CONFLEX. CONFLEX2000 software, based on the exhaustive conformational searching algorithms developed by Dr. H. Goto, operates on Windows, Mac OS X, and Linux. 1921 Corning Inc., 45 Nagog Park, Acton, MA, USA 01720, (978)635-2200, fax: (978)635-2476, e-mail:
[email protected], Internet: www.corning. com/Iifesciences With expertise in surface chemis try and materials science in glass and polymers, Corning is a market leader in the manufacture of high-quality, high performance tools for cell cul ture, chemistry, assays and genomics. At ACS Spring 2003, Corning will be highlighting new glassware items plus Corning brand equipment (Hotplates and Stirrers) as well as new products for high throughput screening. 1223,1225 Coy Laboratory Products, 14500 Coy Dr., Grass Lake, Ml, USA 49240, (734)475-2200, fax: (734)475-1846, e-mail:
[email protected], Internet: www.coylab.com For over 30 years Coy Labora tory Products has been manufacturing glove boxes for a wide variety of applications. Including anaerobic and oxygen control atmosphere's and humidity and temperature control glove boxes. Simple inexpensive dry purge and inert gas atmo sphere glove boxes and cabinets. Chemical han dling and weighing, packaging, product develop ment and testing along with auality control applications. Custom designed glove boxes are also available to fit your specific needs. 625 CPC - Cellular Process Chemistry Sys, Hanauer Landstrasse 526/G58, Franfurt, GERMANY 60343, 49 6131973530, fax: 49 6131973526, Internet: http://www.cpc-net.com 1528,1530
1801 Combi-Blocks, 7949 Silverton Ave., Suite 915, San Diego, CA, USA 92126, (858)635-8950, fax: (858)635-8991, e-mail:
[email protected],
CRC Press LLC, 2000 Corporate Blvd. NW, Boca Raton, FL, USA 33431, (561)994-0555, fax: (561)998-2514, e-mail:
[email protected], Internet: www.crcpress.com CRC Press invites you EXPO-*
EXPOSITION to visit Booth #828 and examine our new and established titles including the CRC Handbook of Chemistry and Physics. CRC offers an array of Chemistry, Life Sciences and Pharmaceutical titles as well as the creator of CHEMnetBASE.com, a wealth of chemical information available at your fingertips. CRC is a leader in scientific, engineering, medical, environmental science, technical, and mathematical publishing and produces books, journals, and databases. Please visit http://www. crcpress.com. 828
spectroscopy instruments that solve your analytical problems. Digilab is exhibiting the: FastImagelR, it's affordable infrared spectrochemical imagina system, which consists of its high optical throughput Excalibur rapid-scan spectrometer, proprietary Lancer focal plane array detector, and LIMA 600 FTIR Microscope (designed for both imaging and single point analysis); Portable Raman System - the first complete portable Raman analyzer for the chemical and pharmaceutical marketplace. 1713
Data Trace Publishing Co., 110 West Rd., Suite 227, Baltimore, MD, USA 21204, (410)494-4994, fax: (410)494-0515, e-mail:
[email protected], Internet: www.datatrace.com/chemistry CHEMTRACTS publishes reviews, condensations and commentaries from today's leading scientists. An editorial board identifies topics and experts select the most exciting, groundbreaking research ensuring you'll read about the most important developments, http://www.datatrace.com/ chemistry 1439
Dima Technology, 3850 Finch Ave. East, Unit 306, Scarborough, ON, CANADA M1T 3T6, (416)2993920, fax: (416)299-3684, e-mail:dimacocanada@ aol.com DIMA has a manufactory which provide highest quality laboratory glassware. Main Products consist of Flask, Funnel, Condenser, Adapter, and Chromatograph column. We are also providing OEM business. DIMA provides a range of products to meet the customer needs. 1338
Daylight CIS, Inc., 24701 Los Altos, Suite 360, Mission Vieio, CA, USA 92691, (949)367-9990, fax: (949)367-0990, e-mail:
[email protected], Internet: www.daylight.com Daylight is the forefront of cheminformatics. Continuously providing the highest performance chemical information processing systems since 1987, Daylight is widely regarcJed as one of the leading cheminformatics innovator in the life science industries. Our current product lines are developed for two key market sectors: scientific research and corporate information systems. Daylight Toolkits provide state-ofthe-art cheminformatics functionality to researchers worldwide. DayCart, the fastest and most chemically-intelligent chemistry cartridge in the market, provides the capability to standardize chemical information databases around Oracle. Together, these product lines enable enterprise systems capable of the highest performance chemical information processing. 519 Delta Nu, Physical Sciences, Room 406, University of Wyoming, Laramie, WY, USA 82071, (307) 7662681, fax: (307) 766-2807, e-mail:jessym@uwyo. edu, Internet: www.deltanu.com DeltaNu introduces the Advantage 200A, the world's first low cost, high performance Raman spectrometer. The Advantage 200A is easy to use on aqueous solutions, gels, powders, coatings, and surfaces. Since Raman is a non-destructive, non-invasive optical measurement, the sample can easily be subjected to further analysis. Priced under $10,000, it comes complete ana ready to run. Includes computer, software and accessories! 124 Desert Analytics, 245 South Plumer Ave., Suite #24, Tucson, AZ, USA 85719, (520)623-3381, fax: (520)623-9218, e-mail:thelab@desertanalytics. com, Internet: desertanalytics.com Celebrating 22 YEARS of service. Providing high quality micro analytical service to customers worldwide. Specializing in the analysis for the chemical elements: CHNOSP, halogens and metals. AA, ICP, ion chromatography. Analysis for academia, industry (pharmaceutical, plastics/ polymers, coal/ petroleum; ultimate/ proximate, electronic/ tin/ solder plate) and government. Trace analysis, TOC. (Zustom analysis. We welcome your inquiries. 528 Dialog, 11000 Regency Pkwy, Ste. 10, Cary, NC, USA 27511, 1-800-3DIALOG, fax: (919)468-9890, e-mail:
[email protected], Internet: www. dialoq.com With recent acquisitions NewsEdge and Intelligence Data, Dialog is a worldwide leader in online-based information services to organizations seeking competitive advantages in fields, such as business, science, engineering, finance, medicine and law. Dialog's services, including Dialog, Profound, and DataStar, provide actionable results pulled from more than 1.2 billion unique records to businesses around the globe. Dialog is a business of The Thomson Corporation, a leading provider of integrated information solutions to business and professional markets worldwide. 1007 Digilab, 68 Mazzeo Dr., Randolph, MA, USA 02368, (800) 225-1248, fax: (781) 986-5013, e-mail:
[email protected], Internet: www. digilabglobal.com Digilab is focused on developing, manufacturing, marketing, and supporting 6-EXPO
Dionex Corp., 1228 Titan Way, P.O. Box 3603, Sunnyvale, CA, USA 94088-3603, (800)DIONEX-0, fax: (408)739-8437, e-mail:
[email protected], Internet: www.dionex.com Reagent-Free IC (RFIC), the flagship ICS-2000, along with the ICS-1500, ICS-1000, RFIC Controller, and EG50 Eluent Generator. DX-600 IC System. Summit HPLC system with new P680 HPLC pump. BioLC System. UltiMate Nano LC System with Probot Microfraction Collector for proteomics. New Chromeleon software. MSQ detector for LC/MS and IC/MS. Acclaim Silica HPLC columns, lonPac AS18 hydroxide selective column, and lonPac CS17 for hydrophobic, polyvalent amines. The ASE 100 solvent extractor. 717,719 Division of Small Chemical Business, 1117 Mineral Springs Rd., Charlotte, NC, USA 28262-4911, (704)598-4819, e-mail:
[email protected], Internet: http://membership.acs.Org/b/SCHB/ Small Chemical Businesses represented by members of the division. Consulting services, specialty chemicals, technical software, analytical services, process improvement facilitation. Flexible, responsive small to mid-sized companies to meet your contract needs and niche products. 1238 Eastern Analytical Symposium, 322 South Middletown Rd., Nanuet, NY, USA 10954-3333, (845)623-3019, fax: (845)623-7912, Internet: http://www.eas.org 1824 Eberbach Corp., PO Box 1024, 505 S. Maple St., Ann Arbor, Ml, USA 48106, (734)665-8877, fax: (734)665-9099, e-mail:info@eberbachlobtools. com, Internet: eberbachlabtools.com As a manufacturer of laboratory equipment since 1951, Eberbach is known for its commitment to quality and customer satisfaction. Our shakers, stirrers, homogenizers and blenders are used for preparative and analytical procedures worldwide, serving a myriad of diverse merkets and applications. A newly constructed web site eberbacnlabtools.com guides consumers through our product lines, while enabling a visitor to contact our customer service engineering departments directly. Additionally, the site offers direct links to our distributors. 1427 Elsevier Science, Customer Support Department, P.O. Box 945, New York, NY, USA 10159-0945, (212)633 3730, fax: (212)633- 3680, e-mail:
[email protected], Internet: www.elsevier.com Elsevier Science, one of the leading international science publishers, displays its complete chemistry collection, including titles published under the Academic Press imprint. Visit booth 309 to browse new titles including, The Essence of Chromatography, The Porphyrin Handbook volumes 11-20 and for information about Comprehensive Coordination Chemistry II and other forthcoming multivolume works. Ask for a demo of electronic initiatives such as Online Article Submission, Dymond linking and www.tetrahedron.info. Online journal content, including Backfiles to issue 1:1, is available via ScienceDirect -www.sciencedirect.com. Discover ChemVillage a new solution for chemistry researchers at www.chemvillage.org. ChemWeb. com provides information resources for chemical research. Members can access over 350 journals and 18 databases several are structure searchable from a variety of publishers. Services include the Careers Centre, Conference Centre, Bookstore, daily news from The Alchemist and subject specific Forums. ChemWeb also powers The Chemistry
Preprint Server (CPS) - a freely available, permanent web archive and distribution medium for unpublished research articles in the field of chemistry. 309 EMD Chemicals, 480 South Democrat Rd., Gibbstown, NJ, USA 08027, (856)423-6300, fax: (856)423-6313, e-mail:
[email protected], Internet: www.emdchemicals.com EMD manufactures high purity chemicals & reagents for research & analytical laboratories in industrial, academic & life science markets; high-purity chemicals for R&D, scale-up and production in pharmaceutical and biopharmaceutical industries; TLC plates and silica gel, test strips for environmental testing and microbiology products, including rapid tests, for food, beverage and environmental companies. 129 FIZ CHEMIE BERLIN, Franklinstrasse 11, Berlin, GERMANY D-10587, +49 30 39977 0, fax: +49 30 39977 134, e-mail:
[email protected], Internet: www.chemistry.de FIZ CHEMIE BERLIN is a major scientific information and documentation center for chemistry. Its main activities include the preparation of databases, software packages, books, and printed information services covering synthetic organic chemistry, chemical engineering and polymers. In addition, FIZ CHEMIE maintains specialized Internet search engines for chemistry and scientific publications. 624 Fluorometrix Corporation, 118 Great Rd., Stow, MA, USA 01775-0816, (781)235-8399, fax: (978)461-2515, e-maiI:
[email protected], Internet: http://www.fluorometrix.com The CellPhase Chemical Measurement System is designed for measuring dissolved oxygen, pH and optical density. Key to the design is the non-invasive nature of the system. This non-invasive technique prevents contamination, thereby providing a means for monitoring and controlling chemical reactions in a closed vessel. The Fluorometrix technology enables a robust low-cost measuring device for accessing on-line data that is not available by any other means. 324 Fluorous Technologies, UPARC, 970 William Pitt Way, Pittsburgh, PA, USA 15238, (412)826-3050, fax: (412)826-3053, e-mail:
[email protected], Internet: www.fluorous.com Fluorous Technologies, Inc. is a chemical technology company dedicated to the development and commercialization of fluorous products focused at the life science market. FTI produces and distributes the following FluoroFlash products: reagents, protecting groups, scavengers, SPE cartridges, HPLC columns, and bulk silica gel. Fluorous Technologies uses patented technology to solve synthesis and separation problems spanning the entire drug discovery and development process. FTI further leverages its enabling technology through service contracts, licenses, and collaborations. 1344 FMC Lithium, 449 North Cox Rd., Gastonia, NC, USA 28054, (888)LITHIUM, Internet: www. fmclithium.com Organometallics, including organolithium, organomaqnesium and organozinc compounds, organopnosphines, organosilanes, protecting agents, protected functional synthons, custom synthesis of organic and pharmaceutical intermediates, via organometallics, including directed ortho metallations (DoM), and Iithiation of functionalized pyridines. Hydride reducing agents, custom reductions. Hydroxyl and amine functional lithium polymerization initiators. Lab, Kilo Lab, Semi-Works and full-scale Production capabilities. 1233,1235 Frontier Scientific, P.O. Box 31, Logan, UT 843230031, (435)753-1901, fax: (435)753-6731, e-mail:
[email protected], Internet: www.frontiersci. com Frontier Scientific is a major producer of advanced molecular building blocks for drug discovery and materials science. Frontier Scientific's range of products include boronic acids, organohalides, catalysts, and multi-functional drug-like building blocks. These unique materials act as extremly versatile and powerful synthetic starting materials for organic synthesis. Frontier Scientific also preforms custom synthesis and contract research. Please visit us at www. frontiersci.com or stop by our booth for more information. 1240 GAM Laser, Inc., 6901 TPC Dr., Suite 300, Orlando, FL, USA 32822, (407)851-8999, fax:
(407)850-0700, e-mail:
[email protected], Internet: www.gamlaser.com GAM Laser, Inc. manfactures long lifetime Excimer lasers and 157nm VUV F2 lasers for scientific, medical and industrial applications. Applications in chemistry include time of flight mass spectroscopy, ionization, Raman spectroscopy and fluorescence decay. 1912 Gateway Chemical Technology, 11810 Borman Dr., St. Louis, MO, USA 63146,1314)220-2691, fax: (314)991-1857, e-mail:
[email protected], Internet: www.gatewaychemical.com Gateway offers custom synthesis irom milligram to kilogram scale and early stage process research. We have an experienced staff with diverse skills and modern synthetic laboratories with analytical support that includes broadband 300MHz NMR, GC & LC/MS. Gateway has worked with Fortune 500 pharmaceutical and agricultural companies as well as midsize and small companies. We have prepared key intermediates, analytical standards, competitors drug actives and have conducted process research on new products in the pharmaceutical and agricultural sectors. 4l 6 Gelest, Inc., 11 East Steel Rd., Morrisville, PA, USA 19067, (215)547-1015, fax: (215)547-2484, Internet: http://www.gelest.com 725 General Services Administration, 1941 Jefferson Davis Highway, Suite 503, Arlington, VA, USA 22202, (703)305-7823, fax: (703)305-3380, Internet: http://www.gsa.gov 1729 Genevac, 711 Executive Blvd., Suite H, Valley Cottage, NY, USA 10989, (845)267-2211, fax: (845)267-2212, e-mail:
[email protected], Internet: www.genevac.com Genevac's leading edge centrifugal evaporation systems have been developed to eliminate the solvent drying bottleneck in the drug discovery laboratory. Come see our new EZ2 Personal Solvent evaporator. The ultra compact and user friendly EZ-2 is a fully selfcontained unit with evaporation chamber, condenser and pump. Capable of handling a wide variety of sample formats. Genevac also distribute Radleys and oarnstead Stem equipment for cost effective and efficient parallel synthesis. 1610,1612 Georg Thieme Verlag Thieme Publisher, Ruedigerstrasse 14, Stuttgart, GERMANY 70469, +49 711 8931 772, fax: +49 711 8931 777, e-mail:
[email protected], Internet: www. thieme-chemistry.com Thieme Publishing was founded in 1886. The Thieme Publishing uroup comprises seven active enterprises with a total of more than 500 employees, thus ranking it as one of the largest German specialist, scientific publishinq houses. In addition to chemistry, several spneres of natural sciences - especially medicine round off and complement the publishing program. Great care is lavished on more than 4,000 current book titles, approximately 130 scientific journals, and online activities. 415,417 GFS Chemicals, P.O. Box 245, Powell, OH, USA 43065-0245, (800)858-9682, fax: (740)881-5989, e-mail:
[email protected], Internet: www.gfschemicals.com A specialty organic and inorganic chemical manufacturer strategicaly located in Columbus, OH since 1928. Extensive product catalog including research and bulk quantities. Organic product Une include: Farchan specialty acetylenic, olefinic and silyl intermediates; heteroaromatic dyes and indicators; bipyridines terpyridine ligands, phenanthrolines, and metal complexes; high purity quaternary ammonium compounds. Inorganic product line features perchloric acid and salts; anhydrous rare earth salts, formulations; lithium sodium, magnesium reagents, including catalyst and dry battery grades. ISO 9000 certified, not presently cGMP. Glas-Col, 711 Hulman St., P.O. Box 2128, Terre Haute, IN, USA 47802, (812)235-6167, fax: (812)234-3121, e-mail:
[email protected], Internet: www.glascol.com Labnetix software gives you the flexibility to monitor and control a variety of Glas-Col mixing products. Our Combinatorial/ Biotech products include heating/cooling vortexers, ovens, rotators for microplates, reaction block holders and a full line of concentrator/evaporators from 8 to 384 wells. Glas-Col offers one of the largest selections of standard and custom heating
mantles in the world. Our temperature controls offer precise regulation of mantles. 911,913 Hamilton Company, 4990 Energy Way, Reno, NV, USA 89502, (800)858-3000, fax: (775)856-7259, e-mail:
[email protected], Internet: www.hamiltoncompany.com Hamilton Company specializes in the design and manufacture of products for manual, semiautomated and robotic precision fluid measuring and delivery. The company offers a wide selection of syringes, syringe pump modules, robotic fluid handling systems, diluters, and dispensers. In addition Hamilton Company sells a complete line of precision micro-pipettors. The company is the leader in polymeric phase columns for HPLC and offers columns for analytical to preparative applications. 1434 Harrick Scientific Corp., 88 Broadway, P.O. Box 1288, Ossining, NY, USA 10562, (914)762-0022, fax: (914)762-0914, Internet: h t t p : / / w w w . harricksci.com Exhibting our complete line ofFTIR accessories. Featuring the GATR grazing angle ATR accessory, MVPStar a new low cost single bounce diamond ATR and the Video Meridian a diamond ATR accessory with a viewable monitor and eltronice pressure applicator, DLC2 a new low cost demountable liquid cell for transmission spectroscopy. 1341 Heidolph Instruments, 2615 River Rd., Unit 4, Cinnaminson, NJ, USA 08077, (888)522-0966, fax: (888)622-4644, e-mail:
[email protected], Internet: www.heidolph.com Heidolph Instruments LLC, Cinnaminson, NJ has full warehouse, service, sales and customer support staff available for your assistance. Heidolph Instrumetns LLC is a subsidary if Heidolph Gmbh who has been manufacturing laboratory equipment since 1938. All Heidolph products offer a 3 year warranty and are manufactured with ISO 9001 and CE certifications. Heidolph's product lines include rotary evaporators, vacuum pumps, overhead stirrers, magnetic stirrers, shakers & mixers, homogenizers and peristaltic pumps. 619,621 HEL, Princess Rd. Office Park, 4 Princess Rd., Suite 208, Lawrenceville, NJ 08648, (609)912-1551, e-mail:
[email protected], Internet: www.hel-inc. com HEL offers a comprehensive range of products for the process development and optimization laboratory...our logo says it all....Better chemistry, faster. This includes parallel synthesis systems from a few ml to a few liters and from atmospheric to 1500 psi, and together with options such as calorimetry, raman and particale Size determination. HEL also offers automated reactors, calorimeters and reaction hazard screening tools. 1702 Hellma Cells, Inc., 80 Skyline Dr., Plainview, NY, USA 11803, (516)935-0007, fax: (516)939-0555, e-mail:
[email protected], Internet: www. hellmausa.com Manufacturer of spectophotometer cells, accessories and fiber optic immersion probes. Large selection of stock and custom cells probes for all applications. Probes for lab, high pressure or extreme temperature usage. Cuv-OStir unit allows for mixing of cell within instrument. Distributor of cathodeon light sources including deuterium, hollow cathode, xenon, Hg2, tungstenhaloqen; zeiss MMS/MCS miniature spectrometer modules from 190-2200nm; tec5 interface electronics for readout display of various PDA/CCD devices. All products available for end user and OEMs,custom designs, and assembly for optoelectronic unit. 1513 Hewlett-Packard, 3404 East Harmony Rd., MS 41, Fort Collins, CO, USA 80528, Internet: www.hp. com/go/Iifesciences Hewlett-Packard Company (HP) is a leading provider of computing products, technologies, solutions, and services to consumers and business. HP's basic business purpose is to invent, enqineer, and deliver technology solutions that drivebusiness value, create social value, and improve the lives of customers. HP's commitment is to invest in innovation, technology and business where we can make a valued contribution, and partner for the rest. HP a market leader in solutions for life and materials sciences, www.hp.com/go/ lifesciences 1407 HI-TECH Scientific Ltd., Brunei Rd., Salisbury, Wiltshire, UNITED KINGDOM SP2 7PU, (800)334»· 0724, fax: 44-1722-432324, e-mail:enquiry@hi-
techsci.com, Internet: http://www.hi-techsci.com Hi-Tech Scientific offers the world's most comprehensive range of instruments to study rapid reaction kinetics, from a rapid mixing accessory for use with your spectrometer through stopped-flow systems that will operate at -40 °C or 30 000 psi pressure. These are complemented by our quench flow and temperature jump systems. 1444 Hiden Analytical Inc., 75 Hancock Rd., Suite H, Peterborough, NH, USA 03458-1100, (603)9245008, fax: (603)924-5009, e-mail:info@hideninc. com, Internet: www.Hidenlnc.com Hiden Analytical manufacture precision cjuadrupole mass spectrometers for gas analysis, surface science, catalysis studies and plasma characterization. Showcased will be Hiden's latest laboratory grade integrated microreactor and mass spectrometer system for catalyst characterization and evaluation the CATLAB. Designed specifically for catalysis screening, characterization, kinetic and thermodynamic measurements, the CATLAB incorporates a fast response, low thermal mass furnace with rapid chanqeover catalyst cartridge system, hot zone interface and QKZ-20 precision gas analysis system. Further information at www.Hidenlnc.com 1626 Hirschmann, Inc., 2700 Holloway Rd., Suite 103, Louisville, KY, USA 40299, (502)240-0287, fax: (502)240-0394, e-mail:
[email protected], Internet: www.hirschmann-inc.com Hirschmann offers liauid handling devices with distinct and unique features like bottle top dispensers with micro step volume setting and ceramic plunger, a solar powered digital burette, an electronic liquid handling system for dispensing and titrating and the most modern pipette filler with LCD and stateof-the-art charging technology. These precise and accurate quality instruments are manufactured in Germany. Repair and calibration service and technical information are available from Hirschmann in Louisville, KY. 1339 Hitachi High Technologies, 3100 North First St., San Jose, CA, USA 95134, 800-455-4442, Internet: http://www.hitachi-hhta.com Hitachi product offering includes analytical and The LaChrom Elite, Amino Acid Analyzer, LC/MS spectrometers, High Throughput Purification systems, Fluorescence and UV/Visible spectrophotometers. Hitachi's Separation Systems Group is a full solution vendor with regional offices strategically located across the United States with fully capable labs for customer support and training. 213 Hologent Technologies, Inc., 14180 Live Oak Ave., Suite H, Baldwin Park, CA, USA 91706, (626)472-0126, Internet: http://www.hologent. com 126 Horizon Learning Solutions, 1534 Point Marion Rd., Morgantown, WV, USA 26508, (304)5996621, fax: (304)599-5806, e-mail:jhpennwv@ mail.wvnet.edu, Internet: http://www.we-learnhorizon.com We_Learn is a Web-based homework distribution and grading system. The database contains more than 80,000 questions, answers, and explanations for organic chemistry and for general chemistry. The student completes on-line a series of homework modules which have been adapted to follow the textbook in use in that school. Students submit their answers by clicking an on-screen button. Student performance is significantly enhanced because of the immediate feedback and the large number of examples found in the system. 427 Houghton Mifflin Company, 222 Berkeley St., Boston, MA, USA 02116, (800)733-1717, fax: (800)733-1810, Internet: college.hmco.com Houghton Mifflin Company's College Division is proud to offer a comprehensive line of textbooks, print supplements, and electronic supplements for all levels of chemistry education. From lab manuals to online tutoring, Houghton Mifflin provides the tools that students and instructors need to succeed. Stop by Houghton Mifflin's booth to learn more about our entire range of products and services for chemistry education. 1106 Huber Kaltemaschinenbau, W e r n e r - v o n Siemens-Str. 1, Offenburg, GERMANY D-77656, 0049/781 9603-0, fax: 0049/781 57211, e-mail:
[email protected], Internet: www.huberonline.com Peter Huber Kaltemaschinenbau, one
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ACS National Exposition
New Orleans March 24-26, 2003 ,.*: - ' Morial, · i' ,tConveiitiofl Center^'
*ΌΗΜ American Chemical Society
I l ON MINORITY AFFAIRS
*
Join the American Chemical Society's Committee on Minority Affairs a t the ACS national meeting in New Orleans, LA March 23-27, 2003 SUNDAY, MARCH 2 3 Using M e t a c o g n i t i o n To I m p r o v e Student Learning in Chemistry* Noon-2:00 p.m. Wyndham Riverfront Hotel, Rex A * Workshop and free deli buffet MONDAY, MARCH 2 4 YCC Fun 5-K R u n / 1 . 5 - M i l e W a l k 6:30-7:30 a.m. The race starts at Girod St. and Convention Center Blvd. Sponsored by YCC and cosponsored with CMA, SOCED, and WCC Committee 1 0 - Y e a r Anniversary Celebration a n d Presidential Event Committee Reception and Luncheon 11:30 a.m.-l :30 p.m. Hilton Riverside, Versailles Ballroom Speaker: Cecil Pickett, President, Schering-Plough Research Institute Event #110 $30 Committee 1 0 - Y e a r Anniversary Celebration a n d Presidential Event Celebrating Success and Reaffirming Commitment Symposium and Panel 2:00-5:00 p.m. Hilton Riverside, Magnolia Room Cosponsored with Corporation Associates, ComSci, Project SEED, WCC, and YCC Committee 1 0 - Y e a r Anniversary Celebration a n d Presidential Event Celebrating Success and Reaffirming Commitment Poster Session/Reception * 5:00-6:30 p.m. Hilton Riverside, Napoleon Ballroom Approximately 80 Project SEED participants and ACS Scholars will present their research. *Reception cosponsored by PPG Industries Eminent Scientist Lecture Featuring Isiah W a r n e r mentoring: The Yellow Brick Road From Bunkie, Louisiana 5:30-6:30 p.m. Hilton Riverside, Rosedown Room Sponsored by SOCED
EXPOSITION of the first manufacturers of refrigeration machines for laboratory and industrial use, was established in 1968. On this basis and with innovations in refrigeration technology and electronics a product range exceeding 100 kW of cooling capacity and temperatures down to -120 degrees C is offered. Current product lines include Compatible Control thermostats, Cooling and Heating Baths, Intelligent Chillers, Immersion Coolers, Flow Coolers, Water Baths, Calibration Baths, Oil Coolers, Immersion Circulators, Bridge Thermostats, Industrial Coolers, Unistat Tango and the high power Unistats. 1328
Andover, MA, USA 01810, (978)482-3300, fax: (978)482-3400, e-mail:
[email protected], Internet: www.innocentive.com InnoCentive offers the first online, incentive based platform created specifically for the global R&D community offering solution-seeking companies access to research scientists worldwide by posting their scientific Challenges on the InnoCentive website. InnoCentive's qlobal community of scientists solve these challenges from top science based companies for financial rewaras. For more information, visit the InnoCentive website at www.innocentive.com 1728,1730
Hypercube Inc., Florida Science & Tech Park, 1115 Northwest 4th St., Gainesville, FL, USA 32601, (352)371-7744, fax: (352)371-3662, e-mail:
[email protected], Internet: http://www.hyper.com HyperChem is a sophisticated molecular modeling environment known for its quality, flexibility, and ease of use. Uniting 3D visualization and animation with quantum chemical calculations, molecular mechanics, and dynamics, HyperChem puts more molecular modeling tools at your fingertips than any other Windows program. HyperChem Release 7 is compatible with Windows OS's through XP, and incorporates even more powerful computational chemistry tools, newly incorporated modules, additional basis sets, new drawing capabilities and more. 1229,1227
Innovative Technology, 2 New Pasture Rd., Newburyport, MA, USA 01950, (978)462-4415, fax: (978)462-3338. 906
IBM, IBM Life Sciences, Route 100, Somers, NY, USA 10589, (800)426-4968, e-mail:
[email protected], Internet: www.ibm.com/solutions/lifesciences IBM Life Sciences is dedicated to bringing leading edge technologies out of IBM's laboratories and into the marketplace. The unit brings together IBM capabilities, ranging from high-performance computing and storage offerings to data and knowledge management software, services and research expertise, to address the information technology needs of pharmaceutical, biotechnology, academic research and other life sciences organizations. 217 ICON Isotope Services Inc., 19 Ox Bow La., Summit, NJ, USA 07901, (800)322-4266, fax: (908)2730449, e-mail:
[email protected], Internet: www. iconisotopes.com Exhibitinq a comprehensive range of stable isotopes labeled compounds used in chemical research. Compounds and gases labeled with deuterium,carbon-12,carbon13,nitrogen-14, nitrogen-15, oxygen-16, oxygen17, oxygen-18, sulfur-34, sulfur-36, chlorine-35, chlorine-37, bromine-79, bromine-81. Noble gas isotopes and multiply-labeled compounds are available. Custom synthesis work is undertaken. Products for NMR and MS studies. Full line ofNMR samples tubes including qas-phase studies, micro tubes,quartz and NMR Vi dewars. 706 Indofine Chemical Co., 121 Stryker La., Bldg. 30, Suite 1, Hillsborough, NJ, USA 08844, (908)3596778, fax: (908)359-1179, e-mail:chemical@ i n d o f i n e c h e m i c a l . c o m , Internet: www. indofinechemical.com Indofine, established in 1981, is committed to providing high quality rare organic molecules, biochemicals and natural products for the advancement of science. We provide custom synthesis, contract research and process development and toll manufacturing in the areas of Flavonoids, coumarins, acetophenones, benzophenones, chromones, fluoroorganics, heterocyclics and natural products for the pharmaceutical, agricultural ana life science industries. Please visit our new websites: tollmanufacturing.com, contractresearch.com, flavorsand fragrances.com, rareorganics.com, benzophenones.com, acetophenones.com and coumarins.com for more information. 1634 Industrial Test Systems, Inc., 1875 Langston St., Rock Hill, SC, USA 29730, (800)861-9712, fax: (803)329-9743, e-mail:
[email protected], Internet: www.sensafe.com Industrial Test Systems, Inc., has been producing water quality test strips and test kits since 1989. Settinq new standards in water quality testing, Industrial Test Systems, Inc., offers tests strips for a wide variety of ions. Ultra Low II Arsenic Quick, for example, is the first test strip based kit to detect down to 0. Ippb arsenic in only 14 minutes. Free Chlorine Water Check is the first test strip for free chlorine to be considered for US EPA acceptance for testing drinking water. 1909 InnoCentive, 35 New England Business Center, 8-EXPO
Instec, Inc., 5589 Arapahoe Ave., Suite 208, Boulder, CO, USA 8 0 Î 0 3 , (303)444-4608, fax: (303)444-4607, e-mail:
[email protected], Internet: http://www.instec.com Instec designs, manufactures, and sells optical polarizing microscopes with long working distance polarizing condenser and lonq working distance objectives, precision (up to 0.001 C) temperature controllers, microscope hot and cold stages (from -190C to 700C), C-mount microscope digital cameras with sample temperature overlay, hot and cold chucks (-190C to 600C) with low leakage current and low electrical noise, high voltage (+/-100V) and high frequency (up to 5Mhz) function generators, high voltage (up to 800V) and high current (up to 2.7A) amplifiers. Instruments For Research 8c Industry, 108 Franklin Ave., P.O. Box 159, Cheltenham, PA, USA 19012, (215)379-3333, fax: (215)663-8847, e-mail:
[email protected], Internet: www.i-2-r.com Introducing a new TEMP-O-TROL temperature controller with dual displays and analog output. For use with ovens and reactors. The original THERM-OWATCH for reliable on/off temperature control; Jack-O-Matic, the pneumatic lab jack; Water-Flow Monitor for protection of water cooled set-ups; Spill Alarm & Cut-Off; Reservoir Monitor, a liquid level controller; foam lab brushes for glassware cleaning; the original Lead Donut stabilizers; LabCrier voice alarm; bench top safety shields; inflatable glove chambers; also standard and custom thermocouples. 612,614 Int'l Centre for Diffraction Data, 12 Campus Blvd., Newtown Square, PA, USA 19073, (610)3259814, fax: (610)325-9823, e-mail:
[email protected], Internet: www.icdd.com The International Centre for Diffraction Data (ICDD) presents PDF-4/ Organics 2003, the world's largest X-ray powder diffraction database for organics! Targeted for the pharmaceutical and specialty chemical industries, our megadatabase offers unparalleled data with unprecedented power to data mine 30 plus separate diffraction and physical property oata fields. PDF-4/Orqanics 2003 includes new pharmaceuticals and orug active substances with 2D chemical structure representations and subfile classifications. ICDD is your leading source for all of your material identification needs! 1239 ISCO, 4700 Superior St., Lincoln, NE, USA 68504, (402)464-0231, fax: (402)465-3064, e-mail:info@ isco.com, Internet: www.isco.com Isco CombiFlash separation systems provide rapid purification of organic compounds. CombiFlash Companion offers benchtop automation with PalmTM powered interface controls; OptiX 10 separates ten samples in parallel with on-line UV detection on all channels; CombiFlash Sq 16x sequentially purifies up to 16 samples - liquid or solid. New Isco SWIFT reversed phase and ion exchange Monolithic Columns are 5x to 10x faster than conventional media for separations of proteins, peptides, oligonucleotides, and nucleic acids. 1619 IXRF Systems, Inc., 15715 Brookford Dr., Houston, TX, USA 77059, fax: (281)461-8809, e-mail:
[email protected], Internet: ixrfsystems. com IXRF systems are microanalysis EDS systems. Solely formed from ex-Kevex personnel, IXRF has emerged with the most advanced EDS systems availaole. EDS, digital imaging, feature analysis, and x-ray mapping features, rival the high end systems for a fraction of the cost. IXRF can also use existing EDS detectors for upgrades providing a cost effective solution for existing EDb customers.
IXRF's latest product is the fX-SEM tube providing scanning electron microscopes with x-ray fluorescence analysis. 1812 J-KEM Scientific, 6970 Olive Blvd., St. Louis, MO, USA 63130, (800)827-4849, fax: (314)863-6070, e-mail:
[email protected], Internet: www. JKEM.COM Parallel synthesis solution and solid phase reactors, precision temperature controllers and robotic workstations. Digital temperature controllers regulate any volume 0.1ml to 100L or piece of equipment to 0.1 degree C. Solution phase parallel synthesis reactors have inert atmospheres, glass reactors, multiple temperature zones -78 to 130 C, and evaporator for reaction work-up inside the reactor. Digital vacuum regulator controls vacuum pressures and eliminates mercury. Miniature overhead stirrer has the power of a IO pound stirrer but weighs less than 1 pound! New Eclipse robotic workstations finally make lab automation affordable. From $12,000 the Eclipse automates dissolution, synthesis, reformatting, weighing, and virtually any laboratory task. Weighting workstation with 0. Img balance is $19,400 complete! User programmable. Robotic accessories includes shakers, SPE station, parallel syringe pumps and filter station. 1001,1003,1005 JASCO, 8649 Commerce Dr., Easton, MD, USA 21601, (800)333-5272, fax: (410)822-7526, e-mail:
[email protected], Internet: htt://www.jascoinc. com Jasco manufactures a complete line of spectroscopy and chromatography instrumentation including UV/VIS, UV/VIS/NIR, FTIR, micro-FTIR, fluorescence and raman and circular dichroism dpectrometers. In addition we make a complete line of digital polarimeters. The 2000 series HPLC components include isocratic/gradient solvent delivery systems and detectors including UVA/IS, multi-wavelength, diode-array, fluorescence, chemiluminescence chiral and Hi. All modules are controlled by a 32bit chromatography software package featuring complete control and data acquisition for Windows 2000 or NT. 1228 JEOL USA, Inc., 11 Dearborn Rd., Peabody, MA, USA 01960, (978)536-2310, fax: (978)536-2264, e-mail:
[email protected], Internet: www.jeol.com JEOL will have information on our AccuTOF (LCTOF) mass spectrometer. It features high sensitivity, high resolution and high-throughput capabilities as well as a high dynamic range for both qualitative and quantitative analysis. Also on display will be JEOL's new ECX NMR line of spectrometers encompassing our DELTA software which makes the operation of the ECX incredibly easy and quick to learn. In addition, information will also be available for both SEM and TEMproducts. 808,810 John Wiley & Sons, Inc., 111 River St., Hoboken, NJ, USA 07030, (207)748-6000, fax: (207)74886088, Internet: www.wiley.com John Wiley & Sons, Inc., provides state-of-the art chemical information to students, educators, researchers and scientists worldwide. World-class journals such as Anqewandte Chemie (now weekly) and the Journal of Polymer Science, and superior texts and references such as The Art of Chemistry, March's Advanced Organic Chemistry and Ullmann's Encyclopedia of Industrial Chemistry are just some of the products that comprise Wiley's comprehensive chemistry library. Through Wiley InterScience (http://www.interscience.wiley.com/) we deliver electronic access to hundreds of journals, major reference works, chemical databases, and online books. In Spring 2003, the Wiley InterScience Polymer Backfile Collection will be the largest collection of high-quality polymer science backfiles available. Through our partnerships with 15 European chemical societies and other international chemistry partners, Wiley is able to offer authoritative content from the most respected authors in the field. Wiley is dedicated to serving the chemistry community through the ongoing development of innovative products and services such as the Organic Synthesis/Organic Reactions Chemical database and separationsNOW.com. 1301 Journal of Chemical Education, Department of Chemistry, 1101 University Ave., Madison, Wl, USA 53706, (608)262-5153, fax: (608)265-8094, e-mail:
[email protected], Internet: http:// jchemed.chem.wisc.edu All subscriptions since 2000 include both print and full online access. The Journal brings you 600 peer reviewed articles
every year; a searchable online index 1924 to present; tested demonstrations; innovation laboratories; ready-to-use classroom activities; buyer's guides for books, software, and equipment; lab supplements; reviews of texts, books, software, internet feature columns, supplementary videos; reports from other journals; association reports; and a lot more. Subscriber Services: PO Box 1267, Bellmawr, NJ 08099-1267. 824,826 Julabo USA, Inc., 754 Roble Rd, Suite 180, Allentown, PA, USA 18109, (610)231-0250, fax: (610)231-0260, e-mail:
[email protected], Internet: www.julabo.com JULABO is a worldwide manufacturer of temperature control equipment: Refrigerated and Heating Circulators from -95 degrees C. . .+200 degrees C; Presto's & HT s - High Dynamic Temperature Control; Systems from -85 degrees C.. .+400 degrees C; Water Baths from +20 degrees C. . .+200 degrees C; Recirculating Coolers from -20 degrees C.. .+80 degrees C; Temperature Controllers, Programmer and Software; JULABO instruments cover a wide temperature range from -95 degrees C.. .+400 degrees C. Features include: fast cool-down times, highest temperature stability, small footprint, low noise level, digital and analog interfaces, external temperature control, integrated programmer, 2-Year warranty, etc. .. 1318,1320 Kett, 17853 Santiago Blvd., Suite 10754, Villa Park, CA, USA 92861, (800)438-5388, fax: (714)693-2923, e-mail:
[email protected], Internet: www.kett.com Kett will be displaying their entire line of instant moisture and composition analyzers. This includes the unique handheld KJT100 and the KJT270F fiber-optic composition analyzer for use in laboratory and process applications. Also, displayed, the rM300 Micro-Moisture analyzer provides direct measurement of moisture to Ippm, even in products that have non-aqueous volatiles. 524 Key Organics, Highfield Industrial Estate, Camelford Cornwall, UNITED KINGDOM PL329QZ, +44 (0)1840 212137, fax: +44 (0)1840 213712, e-mail:
[email protected], Internet: www. keyorganics.ltd.uk Key Organics provides custom and contract chemistry services together with follow-up chemistry using expertise in classical organic procedures and heterocyclic synthesis skills. Key Organics has also developed a unique and diverse library of 34,000 screening compounds - 90 percent of which are immediately available in quantities upto lOmg. Our further library of 2100 diverse buildinq blocks, available in multigram amounts, is suitable for combinatorial and other synthetic requirements. Discuss your requirements with us at Booth 1635. 1635 Kimble/Kontes, 1022 Spruce St., P.O. Box 1502, Vineland, NJ, USA 08$60, (888)546-2531, fax: (856)794-9762, e-mail:
[email protected], Internet: www.kimble-kontes.com Kimble/Kontes is an ISO 9000 manufacturer of both standard and custom laboratory qiassware along with OEM products for a variety of industries. Products include reusable and disposable items, along with specialty chemistry and Life Sciences glassware including micro scale kits, airless vacuum and distillation systems, cell culture and tissue preparation items, chromatography columns and HPLC accessories, TLC supplies, environmental testing and filtration glassware, and NMR tubes. Custom and OEM products are made to customer specifications. See our entire catalog online at www.kimble-kontes.com or e-mail to
[email protected]. 1319,1321,1323 Kluwer Academic Publishers, 101 Philip Dr., Assinippi Park, Norwell, MA, USA 02061, (781)871-6600, fax: (781)681-9045, e-mail:
[email protected], Internet: http://www. wkap.nl/book/chemistry Kluwer provides the highest quality information products and services to academic and corporate researchers in chemistry including catalysis, electrochemistry, theoretical and computational chemistry, nanoscience and technology, and crystalography. The Kluwer Online gateway at www.kluweronline.com, reaches millions of researchers, scientists and professionals in more than 50 countries with electronic Journals, eBooks, Custom Books, and eReference Works. Stop by our booth for 20 percent savings off our entire chemistry list. 50 percent off display copies (limited quantities).
1409,1411,1413
KNF Neuberger, 2 Black Forest Rd., Trenton, NJ, USA 08691-1810, (609)890-8600, fax: (609)8908323, e-mail:
[email protected], Internet: www.knf. com/usa.htm LABOPORTdry vacuumpumpsoffer quiet, clean, stable vacuum to 1.5 Torr for your rotovap, oven, concentrator and jobs such as degassing and filtration without messy pump oil or aspirator water hassles. PTFE materials resist aggressive vapors for longest life. Patented valves take the punishment from condensate droplets without performance loss or damage. See KNF's new, economical filtration pumps designed for everyday use with bottle top, disposable, manifold filtration assemblies, dessiccators, degassing and glass filtration assemblies. 1807 knovel Corporation, 13 Eaton Ave., Norwich, NY, USA 13815, (866)303-3336, fax: (607)337-5090, e-mail:
[email protected], Internet: www. knovel.com Knovel Corporation (www.knovel.com) delivers accurate and complete answers to engineering and scientific questions fast. Subscription access via the Web to 400 plus books and databases full text and searchable from trusted sources like McGraw-Hill and Wiley. Search an entire library of engineering scientific information in seconds. Less time searching more time problem solving. 1628 Lab Support, 26651 West Agoura Rd., Calabasas, CA, USA 91302, 800-998-3332, Internet: http:// www.onassignment.com Lab Support is a leading scientific staffing company. We place science professionals on short and long-term assignments in biotech, pharmaceutical, food and beverage, chemical, and industrial laboratories across the country. Forbes named us one of the "200 Best Small Companies in America" for 10 consecutive years- longer than any other company. 1637 LABCONCO, 8811 Prospect Ave., Kansas City, MO, USA 64132, (816)333-8811, fax: (816)3630130, e-mail:
[email protected], Internet: www.labconco.com Founded in 1925, Labconco Corporation manufactures laboratory equipment with worldwide distribution through scientific supply dealers. Ventilation products including laboratory fume hoods, laboratory animal research enclosures, carbon filtered enclosures, laminar flow biological safety cabinets and glove boxes comprise our largest line. Other products include water purification systems, freeze dry systems, glassware washers, rotary evaporators, multiple sample evaporators, centrifugal concentrators, Kjeldahl apparatus and laboratory carts. 103,105
module featuring 25 lab exercises and sophisticated instructor utilities, all based on advanced computer animations and proprietary algorithms. Use simulations to: Add more labs to chemistry courses; Let students explore and discover science in an unrestricted environment; Expand the lab repertoire and save cost. 1907 Leadscope Inc., 1245 Kinnear Rd., Columbus, OH, USA 43212, (614)675-3730, fax: (614)675-3732, Internet: www.leadscope.com LeadScope's mission is to help chemists develop new drugs which improve efficacy and reduce toxicity. It provides cheminformatics software and curated databases to find high quality lead candidates and better design new chemical entities. The informatics methods include recursive partitioning with simulated annealing, structural-feature based clustering, scaffold generation, and R-group analysis. LeadScope's toxicity and known drug content modules integrate structures and data from public sources which can also be integrated with proprietary databases. 321 Leica Microsystems, 3362 Walden Ave., Depew, NY, USA 14043, (716)686-3000, fax: (716)6863085, e-mail:thomas.ryan@leica-microsystems. com, Internet: www.leicams.com Leica Microsystems is a leading provider of surface plasmon resonance and critical angle refractometers for research and auality control. The SR7000 is an affordable surface plasmon resonance enabled refractometer for applied surface chemistry and the study of real-time biomolecular interactions. The SR7000 provides ranking kinetic information on for example protein/protein and nucleotide/ nucleotide binding events. The AR700 bench model and AR200 portable are fully automatic digital critical angle refractometers with computer interface capabilities. 1436 Link-Systems International, Inc., 5035 Savarese Circle, Tampa, FL, USA 33634, (813)674-0660, fax: (813)674-0040, Internet: http://www.link-systems. com Link-Systems International,Inc. provides high quality integrated distance learning, web publishing, and data conversion solutions to organizations worldwide. We specialize in communication of mathematical, scientific, technical and medical material. 1740 Louisiana Alliance for Biotechnology, c/o 2924 Brakley Dr., Suite A-1, Baton, LA, USA 70816, (225)291-4600, fax: (225)291-4606, e-mail:info@ labiotech.org, Internet: http://www.labiotech.org
104,106 Lancaster Synthesis, P.O. Box 1000, Windham, NH, USA 03087, (800)238-2324, fax: (800)5423939, e-mail:
[email protected], Internet: www.lancastersynthesis.com Lancaster Synthesis, Inc., a specialty fine chemical company, is proud to offer a comprehensive product range from basic building blocks to novel intermediates and reagents. Lancaster provides over 14,000 products in catalog and semi bulk capacities in addition in the services of our state-of-the art inhouse manufacturing facilities. Key product strengths include: boronic acids, fluorinated compounds, silanes, heterocycles, chiral compounds, acyl and sulfonyl hafides. Call Lancaster—we'll work harder for you. 807,809 Lancer USA, Inc., 140 State Rd. 419, Winter Springs, FL 32708, (800)332-1855, fax: (407)3271229, e-mail:
[email protected], Internet: www. Iancer.com/acs Laboratory Glassware washers for the industrial, scientific and medical communities. With over 65 standard models ranging from under counter to large scale freestanding production washers, we have a model to meet your most critical cleaning standards. The 820LX under counterwasher and our three level, mid size 1400UP model, both feature on board storage of cleaning chemicals and hot air drying. All models come standard with self diagnostic microprocessor programming, acid rinse capabilities, and deionized water final rinsing. 806 Late Nite Labs, Ltd., 2330 Milton Rd., University Heights, OH, USA 44118, (216)382-6017, fax: +972 9950 6714, e-mail:
[email protected], Internet: www.latenitelabs.com LateNiteLabs provides realistic lab simulations for science education. Our simulations enrich college and highschool courses and are easily accessible on the Web. We now introduce the General Chemistry
Louisiana State University, Chemistry Department, 232 Choppin Hall, Baton Rouge, LA, USA 70803, (225)576-5729, fax: (225)578-3458, Internet: http://iqert.LSU.edu LSU offers a full range of educational·, research and service capabilities in Chemistry and Chemical Engineerinq. A diverse student body of 150 graduate and 500 undergraduate majors share outstanding research equipment, a close working relationship with industry, and meaningful community outreach. Special opportunities include: the only NSF-IGERT project devoted to polymers and biopolymers; a synchrotron storage ring; and, emphasis on biological, environmental and materials research. Highly qualified prospective graduate students are encouraged to apply for qenerous support through the Louisiana Chemical Excellence Fellowship program. 1631 M. BRAUN, Inc., 14 Marin Way, Stratham, NH, USA 03885, (603)773-9333, fax: (603)773-0008, e-mail:
[email protected], Internet: www. mbraun.com M.Braun offers a full line of standard and custom glove boxes and solvent purification systems including vacuum ovens, analyzers, freezers, mini antechambers and much more. With over 25 years of experience in desiqning and manufacturing, M.Braun is able to supply the customer with turnkey solutions for all of their controlled environment needs. M.Braun is pleased to showcase our two new products, Siemens graphical touch panel display and the redesigned freezer. Visit us at Booth #1327/1329. 1327,1329 Mallinckrodt Baker, Inc., 222 Red School La., Phillipsburq, NJ, USA 08865, (908)859-2151, fax: (908)859-6905, Internet: www.mallbaker.com Leading supplier of laboratory chemicals and related products. See a demonstration of our new EXPO-9
EXPOSITION Solv-IT Center. It's specifically designed to answer questions about J. T. Baker products and services, and other industry issues. Reserve your copy of our 2003 catalog ana ask us to explain how our return able solvent delivery system can make it easier to run your equipment. Featuring improved and expanded lines of high purity solvents and acids and ready-to-use anhydrous solvents for organic synthesis. 1701,1703 Malvern Instruments, Inc., 10 Southville Rd., Southborouqh, MA, USA 01772, (508)480-0200, fax: (508)460-9692, e-mail:
[email protected], Internet: www.malverninstruments.com Malvern Instruments is a world leading developer and manufacturer of laboratory-based and in-process systems for particle characterization. Malvern sys tems for automated particle sizing, particle shape and size analysis, specialist spray and aerosol analysis, zeta potential measurement and on-line particle sizing are used throughout industry and academia, across a wide range of applications. 1420 Marcel Dekker, Inc., 270 Madison Ave., New York, NY, USA 10016, (212)696-9000, fax: (212)685-4540, Internet: www.dekker.com Stop by and see our latest chemistry titles including Interfacial Catalysis by Alexander G. Volkov, Semicon ductor Photochemistry and Photophysics by V. Ramamurthy and Kirk S. Schanze, Enzymes in the Environment by Richard G. Burns and Richard Dick, and Handbook of Food Toxicology by S.S. Deshpande, as well as our other outstanding titles.
cartridges for molecule structure and reaction management; and MDL Draw Enterprise Edition, an improved drawing product that greatly simpli fies tne drawing and editing of molecules and chemical reactions. MDL Discovery Knowledge. DiscoveryGate.com integrates, indexes, and links scientific information to give you immediate access to compounds and related data, reactions, original journal articles and patents, and authori tative reference works on synthetic methodolo gies. Essential discovery content from MDL includes CrossFire Beilstein, the world's largest, graphically searchable chemical facts database; Integrated Major Reference Works, which now includes Thieme's Science of Synthesis; and MDL LitLink Direct, which lets you select bibliographic or fDatent references from virtually any source and link directly to the original documents. 401 Me'Cour Temperature Control, 10 Merrimack River Rd., Groveland, MA, USA 01834, (978)3726085, fax: (978)372-8462, e-mail:MAIL@ MECOUR.COM, Internet: WWW.MECOUR.COM MéCour's circulator driven Thermal Blocks offer precise (+/- 0.1 C) temperature distribution over the entire Block; sealed unit eliminates hazards or contamination; operate hot or cold between +/WOC with the same Block. Perfect for laboratory manufacturing and automated systems. Available in standard or custom configurations per specific requirements. All Thermal Blocks easily connect to the circulator. Contact us at 877-398-6085, mail® mecour.com or visit www.mecour.com for more information. 708
718,720 Matec Applied Sciences, 56 Hudson St., Northborough, MA, USA 01532, (508)393-0155, fax: (508)393-5476, Internet: http://www.matec.com
1724 Matrix Scientific, P.O. Box 25067, Columbia, SC, USA 29224, (803)788-9494, fax: (803)788-9419, e-mail:
[email protected], Internet: www. matrixscientific.com Research chemical intermedi ates and building blocks catalog available, con taining over 6800 items, including many novel materials. CD catalog also available with SD file. Featured are boronic acids, fluorine compounds, sulfonyl chlorides, pyrimidines, indoles, (trifluorometnyOpyridines etc. Products find application in pharmaceutical, agrochemical, polymer, coat ings and academic research. Principals have over 3/ years of experience in the manufacture and supply of quality products for research and devel opment. 1624 MBNA America, 1100 North King St., Wilmington, DE, USA 19884, 800-441-7048, Internet: http:// www.mbna.com MBNA America Bank proudly offers the ACS Platinum Plus credit card, a no annual fee MasterCard that provides peerless ben efits, service, worldwide acceptance, and conve nience. 1927 McGraw-Hill Higher Education, Two Penn Plaza, 20th Floor, New York, NY, USA 10121-2298, (800)553-4920, fax: (563)589-4700, e-mail:
[email protected], Internet: http:// www.mhhe.com/chemistry McGraw-Hill publishes best selling textbooks and media products throughout the entire chemistry discipline. We offer textbooks and lab manuals in the following course areas- Liberal Arts Chemistry, Prep. Chem istry, GOB Chemistry, One-semester Organic Chemistry, Biochemistry, General Chemistry, Two semester Organic Chemistry, Physical Chemistry and Advanced Organic Chemistry. Our leading textbook authors include Raymond Chang, Frank Carey, Martin Silberberg and Shoemaker/Garland & Nibler. We also offer the most widely adopted problem-solving program- ChemSkill Builder. 707,709,711 MDL Information Systems, Inc., 14600 Catalina St., San Leandro, CA, USA 94577, (510)895-1313, fax: (510)614-3608, e-mail:
[email protected], Inter net: www.mdl.com Explore innovative solutions from MDL, the pioneering leader in discovery informatics. MDL Discovery Framework. Learn about MDL's next-generation, η-tier discovery informatics architecture for integrated research in chemistry and biology. Explore the enhanced ste reochemistry capabilities of MDL Chemistry Rules Interface, MDL's business rules development envi ronment; MDL Relational Chemistry Server data 10-EXPO
Measurenet Technology, 4242 Airport Rd., Cincinnati, OH, USA 45?26, (513)3^6-6765, fax: (866)209-8111, e-mail:info@measurenet-tech. com, Internet: www.measurenet-tech.com The patented MeasureNet System offers academic laboratories cutting edge electronic data collection while simplifying instrument operation and maintenance. It patented network design gives every student access to high quality measurement capabilities while eliminating bench-cluttering individual PCs. A single controller and network PC support up to 24 students on a 12 station MeasureNet Network performing experiments that include temperature, pH, pressure, voltage, and mass measurement. MeasureNet's Netspec diode-array spectrometer conveniently brings high-precision spectroscopy to all network workstations. 1924,1926 Merck & Co./Merck Publishing Group, PO Box 2000, WBD-120, Rahway, NJ, USA 07065, (732)726-2811, fax: (732)750-2735, Internet: http://www.merck.com Chemistry's Constant Companion—The Thirteenth Edition of The Merck Index. For all the essential information you need in the new millennium... The Thirteenth Edition has been significantly updated and revised, making the information you have come to trust from this best selling reference even better!! Also available in a text and structure-searchable CD ROM and internet accessible products available from CambridgeSoft. The search is over!! Order your copy today. 713 Metrohm-Peak, Inc., 12521 Gulf Freeway, Houston, TX, USA 77034, (800)410-7118, fax: (281)4845001, e-mail:
[email protected], Internet: www.metrohm-peak.com Complete range of ion chromatography instruments, modules, columns, software and accessories. Our products offer superior innovation, affordability, reliability, superior quality backed by unrivaled service and support. Easy to use and maintain, our products set the new standard in IC. 112 Mettler-Toledo, Inc., 1900 Polaris Pkwy, Columbus, OH, USA 43240-2020, (800)METTLER, fax: (614)438-4871, e-mail:
[email protected], Internet: www.mt.com Mettler Toledo offers the most advanced technology for weighing, pH, refractometry, density, and thermal analysis, btop by our booth to see the latest products and to learn about our Direct Laboratory Service offerings. Mettler Toledo is a leading global supplier of precision instruments and is the world's largest manufacturer and marketer of weighing instruments for use in laboratory, industrial and food retailing applications. The Company also is a leading supplier of several related analytical and measurement technologies. Mettler Toledo Direct Laboratory Service supports a worldwide customer
base in more than 100 countries. Additional information about METTLER TOLEDO can be found on the company web site www.mt.com.
200,201,202,203,204 MicroCal, Inc., 22 Industrial Dr. East, Northampt o n , MA, USA 01060, (413)586-7720, fax: (413)586-0149, e-mail:info@microcalorimetry. com, Internet: www.microcalorimetry.com Manufacturer of ultrasensitive VP-lsotermaf Titration and Differential Scanning Calorimeters which are capable of rapidly characterizing binding and structural properties of biomolecules in highly automated, easy to perform experiments. The VP series represents major advances in sensitivity, reproducibility and stability, which translates into smaller sample requirements and greater precision. 328 Microlab, Inc., P.O. Box 7358, Bozeman, MT, USA 59771, (406)586-3274, fax: (406)586-3582, e-mail: i n f o @ m i c r o l a b i n f o . c o m , I n t e r n e t : www. microlabinfo.com Tools for Research, Tools for Learning, MicroLAB places affordable tools of research in the hands of learners. We offer a family of electronic and computer-based data acquisition equipment, supporting software and curriculum that are designed for education and research. Our products are by design, affordable, easy to use, discovery-based, research grade, and very flexible. 119 Micromeritics Instrument Corp., One Micromeritics Dr., Norcross, GA, USA 30093-1877, (770)662-3633, fax: (770)662-3696, e-mail:
[email protected], Internet: www. micromeritics.com Micromeritics manufactures automated analytical laboratory instruments that measure the physical characteristics of powders and solids for R&D, QA/QC, production, and process control applications. Characteristics measured include: particle size, surface area, pore volume, pore size and pore size distribution, absolute density, envelope density, bulk tap density, chemisorption, TPDnPR, and zeta potential. Micromeritics also operates a Materials Analysis Laboratories that provide sample analysis on a contract basis. 1324 MicroPatent, 250 Dodge Ave., East Haven, CT, USA 06512-3358, (800)648-6787, fax: (203)4665054, e-mail:
[email protected], Internet: www. micropat.com MicroPatent is a subsidiary of Information Holdings Inc. (NYSE.IHI) and a leading provider of intellectual property information and related services. MicroPatent's product lines include TOPS, an enterprise solution for patent searching, downloading, and analysis; Aureka, an enterprise solution offering advanced patent analytics and collaboration capabilities; Trademark, com, a premier online search service offering U.S. Federal, State, Common Law, and international databases, plus Domain Names; Faxpat, a leading provider of U.S. and international file histories; and, Woolcott, providers of professional search assistance. 1800 Microsolv Technology Corporation, 103 Brighton Ave., Long Branch, NJ, USA 07740, (732)2293 4 0 0 , fax: ( 7 3 2 ) 2 2 9 - 2 4 0 3 , e-mail:info@ microsolvtech.com, Internet: www.microsolvtech. com Introducing TYPE C Silica based products for HPLC. Stability, Aqueous and Organic Normal Phase Standard RP, and unique liqands such as cholesterol can be used for difficult separations. Discover Multi Mode chromatography. Also on display will be CEIixirOA for the separation of organic acids and anions using CE, Custom CE Buffers, CelerityCE for large protein analysis and the MicroSolv Calibration Kit for HPLC Performance Qualification including dwell volume testing and the MicroSolv Protein Digest Kit for Mass Spec. 529 Microtrac Inc., 12501-A 62nd St. North, Largo, FL, USA 33773, (727)507-9770, fax: (727)507-9774, Internet: www.microtrac.com 1908 Miele, 9 Independence Way, Princeton, NJ, USA 08540, (800)991-9380, fax: (609)419-4241, e-mail:
[email protected], Internet: www. Iabwashers.com Miele is a leading manufacturer of undercounter, medium, and large capacity laboratory glassware washing systems. Miele washers feature high quality stainless steel wash chambers, direct injection cleaning capability, automatic liq-
uid detergent and neutralizer dispensing, and I and NMR services. We provide super conducting HEP A filtered forced hot air drying. Miele's comNMR magnet sales and NMR services for NMR plete approach includes a full line of detergents, spectroscopy and a complete range of NMR prodbaskets and inserts, wash protocol expertise, and ucts and NMR services. NMR Spectrometer Sales fully trained sales and service throughout the USA. and Leasing, NMR Magnet Sales and Services, 325 Customizable NMR Service Agreements, Extensive Range of NMR Field Services, NMR In-House Milestone, Inc., 160-B Shelton Rd, Monroe, CT# Repair and Upgrade Services, Comprehensive USA 06468, (203)261-6175, fax: (203)261-6592, NMR Cryogenic Fill Services and In-depth NMR e-mail:
[email protected], Internet: www. Training Programs. 1825, 1827 milestonesci.com Milestone, the technology leader in microwave chemistry, introduces the NanoDevices, Inc., 5571 Ekwill St., Santa Barbara, newest line of labstations for microwave accelerCA, USA 93111, (805)696-9002, fax: (805)696ated organic synthesis. From combinatorial chem9003, Internet: http://www.nanodevices.com 102 istry and parallel synthesis to batch reactions and photochemistry, Milestone offers the synthetic National Research Council/NAS, 500 5th St., NW, chemist a wide range of instrumentation to draGR322A, Washington, DC, USA 20001, (202)334matically reduce processing time and increase 2760, fax: (202)334-2759, e-mail:
[email protected], product yield. Information will also be available on Internet: www.nationalacademies.org/rap The microwave technology for rapid digestion, extracNational Research Council (NRC) of the National tion, ashing, and clean chemistry. 1534,1536 Academies will offer 350 awards in 2003 for independent postdoctoral and senior research to be conducted in residence at participating US govMillipore Corporation, 80 Ash by Road, Ma il stop ernment laboratories. Applicants design research E6C, Bedford, MA, USA 01730, (781)533-852$, projects to be compatible with the interests of the fax: (781)533-3163, Internet: http://www.millipore. sponsoring laboratory. Awards include a competicom 1727 tive stipend, relocation, professional travel, and health insurance. Application deadlines are FebruMinitab Inc., Quality Way, 1829 Pine Hall Rd., ary 1, May 1, August 1 and November 1. List of State College, PA, USA 16801, (814)238-3280, fax: participating laboratories, other information, and (814)238-4383, e-mail:
[email protected], Interapplication materials can be found on our Web net: www.minitab.com MINITABTM Release 13 is site. 327 a comprehensive and easy to use statistical software package for data analysis and presentation. Features include the ability to store multiple workNature Publishing, 345 Park Ave., South, New sheets and graphs, save graphs in multiple forYork, NY, USA 10010, (212)726-9200, fax: mats, and export graphics to other applications. (212)696-9591, Internet: www.nature.com NPG From start-ups to Fortune 500 companies, quality publishes quality, peer-reviewed research; review professionals worldwide trust MINITAB to provide and reference material; timely news; and essential the methods they need: basic and advanced stacareer and recruitment information in print and tistics, regression andANOVA, SPC, DOE, reliabilonline. The NPG portfolio combines the excelity, Gage R&R, and much more. Free demo: www. lence of Nature, it's associated primary research minitab.com/demo.htm. 116 journals, the recently launched Nature Reviews journals, 28 leading international scientific and medical journals and reference titles. Stop by the MKS Instruments, 6 Shattuck Rd., Andover, MA, Nature Publishing booth to receive a 10 percent USA 01810, (978)975-2350, fax: (978)975-0093, personal subscription discount. 1537 Internet: www.mksinst.com MKS Instruments is a leading worldwide developer and manufacturer of instruments and subsystems to measure, control, Netzsch Instruments Inc., 37 North Ave., Burlingower, and monitor critical parameters in gast o n , MA, USA 01803, (781)272-5353, fax: ased manufacturing environments. MKS prod(781)272-5225, e-mail:
[email protected], Internet: ucts are used throughout advanced manufacturing www.e-Thermal.com Thermal analysis, thermal industries and research facilities. MKS will be conductivity, dielectric analysis for cure monitorexhibiting FTIR (Fourier Transform Infrared) on-line inq, and contract laboratory testing services. We gas analyzers used to detect multiple gas species offer DSC, TGA, true simultaneous DSC-TGA, in a variety of applications, such as catalytic reducDTA-TGA to 2400C, coupling to FTIR & MS for tion performance monitoring, combustion emisevolved gas analysis, dilatometers, TMA, DMA, sions monitoring, bulk gas purity monitoring, and laserflash thermal diffusivity, thermal conductivity process monitoring. 1929 instruments, DEA-dielectric analysis both in-situ and lab-scale, and fully-equipped contract testing capability. 424 Molecular Imaging, 4666 South Ash Ave., Tempe, AZ, USA 85282, (480)753-4311, fax: (480)7534312, e-mail:
[email protected], Internet: www. NIST, 100 Bureau Dr., Stop 2000, Gaithersburg, molec.com Molecular Imaging Corporation is a MD, USA 20899-2000, (301)975-2027, fax: leader in situ SPM imaging under controlled envi(301)975-2183, e-mail:
[email protected], Internet: ronments. We supply an all-in-one solution with www.nist.gov/srm NIST Standard Reference MateSTM/AFM imaging and spectroscopy tools. The rials are well characterized materials certified for 'Gentle-touch' MAC Mode™ AFM offers unprecchemical or physical properties. SRMs are used to edented resolution and ease of use to studies in calibrate or evaluate measurement instruments, fluid. A temperature range of -30 to 250 degree C methods or systems, www.nist.gov/srm NIST Stanoffers the widest control range in the market. Total dard Reference Databases help analytical chemists isolation of the environmental chamber prevents identify materials, characterize substances, cover a possible damage of scanninq electronics from wide range of analytical techniques, including reactive conditions or elevated temperatures. 229 mass spectrometry, x-ray and infrared spectroscopy, surface analysis, single crystal and electron diffraction, www.nist.gov/srd 501,503 Molecular Networks Gmbh, Naegelsbachstr. 25, Erlangen, GERMANY 91052, (+49) 9131-815668, fax: (+49) 9131-815669, e-mail:
[email protected], NRC Canada-Research Press, Bldg. M 55 Room Internet: http://www.mol-net.de. Molecular Net243-C, Montreal Rd., Ottawa, ON, CANADA works specializes in the development and distribuK1A0S2, (613)993-9085, fax: (613)952-9112, tion of software for the chemical and biomolecular e-mail:
[email protected], Internet: www. sciences. The chemoinformatics software of nrc.ca/cisti Stop by for manuscript and subscripMolecular Networks addresses problems and protion information on the Canadian Journal of vides solutions in the fields of rational drug design, Chemistry CJC and the newly launched Journal of combinatorial chemistry, organic reaction and synEnvironmental Engineering and Science. Internathesis planning, process development and optimitional in scope and readership, these are just two zation, data mining, analysis, and warehousing. of 15 peer reviewed scholarly journals published in Molecular Networks is well-known for its 3D Strucprint and online by Canada's foremost scientific ture Generator CORINA, which is installed worldpublisher - NRC Research Press. Inquire about our wide at about 120 different industrial and acamonographs, conference proceedings and pubdemic sites. 1332 lishing services. Enter our draw for your chance to win a one-year, personal electronic subscription to CJC. 326 MR Resources, Inc., 158 R Main St., P.O. Box 898, Gardner, MA, USA 01473, (978)632-7000, fax: (978)630-2509, e-mail:
[email protected], Internet: NuAire, 2100 Fembrook La., Plymouth, MN, USA http://www.mrr.com. MR Resources is a world 55447, (800)328-3352, fax: (763)553-0459, e-mail: leader in NMR spectrometer sales, NMR leasing I
[email protected], Internet: www.nuaire.com
NuAire provides laboratory professionals with reliable products for the most demanding environments: biological safety cabinets, laminar airflow equipment, C02 incubators, air balance enclosures, animal handlinq work stations, glove boxes, ultralow freezers, LNZ cryo-vessels, polypropylene fume hoods and casework. NuAire polypropylene products are an excellent choice for long lasting, highly corrosive resistant, metal-free applications. NuAire products provide personnel, product, and environmental protection. In addition, they are economically designed for safety and convenience. 125 Oakwood Products Inc., 1741 Old Dunbar Rd., West Columbia, SC, USA 29172, (803)739-8800, fax: (803)739-6957, e - m a i I :sales@ o a k w o o d c h e m i c a l . c o m , Internet: www. oakwoodchemical.com Oakwood Products, Inc., a manufacturer and distributor of research organics, has been supplying research chemicals to the pharmaceutical, agrochemical and materials research communities for over 11 vears. Oakwood's new listing contains over 10,000 items, including many unique building blocks and reactive intermediates. Organofluorine, organosulfur and heterocyclic compounds are featured. Oakwood provides custom synthesis services from kilo-lab through pilot plant scale. Oakwood distributes for A5V Innovative Chemie, ChemCollect, Chess, Daikin Chemicals Sales, Dr. Eckert GmbH and Dr. Jagath Reddy's Heterocyclics. 421 Ocean Optics, Inc., 380 Main St., Dunedin, FL, USA 34698, (727)733-2447, fax: (727)733-3962, Internet: http://www.oceanoptics.com For more than a decade, Ocean Optics has delivered cutting-edge analytical instrumentation to chemists and researchers. Our recent innovations include: HR2000CG-UV-NIR—high-resolution 1 nm) spectrometer; 200-1100 nm range. USB2000-FLG— highly sensitive, variable-deîay spectrometer for fluorescence. Externally triggered with 5-500 microsecond delay and 5 millisecond integration. Temperature-regulated Cuvette Holder—controls temperature of1*1-cm cuvette. Dry gas purge limits condensation, removes oxygen. SMA 905 connectors with integrated coflimating lenses couple unit to Ocean Optics light sources and spectrometers. 811,813 Ohaus Corporation, PO Box 2033, Pinebrook, NJ, USA 07058, (973)944-7026, fax: (888)288-5667, Internet: http://www.ohaus.com 1639,1641 OLIS: On-Line Instrument Systems, 130 Conway Dr., Suite A8cB, Bogart, GA, USA 30622-1724, (706)353-6547, fax: (706)353-1972, e-mail:olis@ negia.net, Internet: www.olisweb.com Spectrophotometers in the luxury class! Dual beam absorbance, fluorescence and circular dichroism spectrophotometers and innovative accessories for kinetic and equilibrium studies, optimized for global analysis of time, temperature, and titration dependent studies. Full selection of modernizations offered, too, on Cadillac caliber UV/Vis, NIR, IR, and fluorescence spectrometers. Windows 2000/NT compatible. 222 OpenEye Scientific Software, 3600 Cerrillos Rd., Suite 1107, Santa Fe, NM, USA 87507, (505)4737385, fax: (505)473-0833, e-mail:business@ eyesopen.com, Internet: http://www.eyesopen. com OpenEye develops molecular modeling applications and toolkits that address drug discovery. Applications include structure generation, docking, shape comparison, electrostatics, cheminformatics and visualization. OpenEye software is designed for scientific rigor, speed, scalability and platform independence. OpenEye software runs on Linux, Windows and MacOS, as well as SGI, HP/COMPAQ, SUN and IBM flavors of UNIX. Rather than per computer or per user, OpenEye software is licensed per site to encourage largescale use, including clusters and GRID computing. 1901,1903 Originlab Corporation, One Roundhouse Plaza, Suite 3 0 1 , Northampton, MA, USA 01060, (800)969-7720, fax: (413)586-0176, e-mail:sales@ oriqinlab.com, Internet: www.originlab.com Oriqin 7 from OriginLab Corporation is the scientific graphing and data analysis software that is both powerful and easy to use. A new template library lets you easily create publication-quality 2D and 3D graphs. Advanced analysis capabilities include
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EXPOSITION EXPOSITION WORKSHOPS
Because of space limitations, workshop attendance will be by registration only, even though workshops are being offered without charge by the sponsoring companies. To register in advance and for a "complete/ up-to-date listing" of exposition workshops, please visit the Virtual Expo at http://chemistry.org/expoplanner.The advance registration deadline is March 7. After March 7, you will need to register onsite. To register on-site, please check in with the sponsoring company at their booth to inquire about availability of your chosen workshop. Booth numbers are indicated after each exhibitor listing. All workshops will be held at the Ernest N. Morial Convention Center. SUNDAY, MARCH 23
51. Critical Information for Chemistry Searchers. Sponsor: Thomson Derwent, Booth 507. Instructor: Doug Naugarede. 9 AM to noon. Room: 346. Thomson Derwent is the world's leading patent and scientific information provider. We help companies stay ahead by providing key technical and business information from patents, journals and conferences. Our products designed for chemistry searchers include: Derwent World Patents Index®— data from 40 patent-issuing authorities, including almost 400,000 chemical patents annually; Derwent Innovations Injexsm _ structure searching, seamless links to premium chemical abstracts and fulltext patents, and extended linking from MDL DiscoveryGate; Derwent Chemistry Resource—seamless links to Derwent World Patents Index, Derwent Innovations Index and full-text patents. 52. Theory and Practice of Reagant Free Ion Chromatography (RFIC). Sponsor: Dionex Corporation, Booths 717,719. Instructor: Kirk Chassaniol. 1:30PM to 3:30PM: Room: 346. Breakthroughs in column and detector technology used in ion chromatography (IC) have allowed new standards to be set for performance and ease of use for the average IC user. This workshop will explain what eluent generation is, how it is used in IC, how to develop a method and the benefits of this approach. New advances in eluent purification will be presented. The use of RFIC also includes the use of auto suppression and conductivity detection. This workshop will include a session on suppressor design and the type best suited for various applications. Throughout the presentation, we will pres12-EXPO
research skills are major goals of modern, secondary and college science curricula, affordable laboratory tools seldom have the flexibility and resolution needed for research. The MicroLAB Environmental Interface uses the newest integrated cirMONDAY, MARCH 24 cuit and software technology to make the M1. Integrating Raman Spectroscopy in- student an active participant instead of an to the Undergraduate Curriculum. Spon- observer in research-oriented experiments. sor: Delta Nu, Booth 124. Instructor: Jes- Participants in this "hands-on" workshop sica Messick and Keith Carron. 9AM to will explore the information that can be Noon. Room: 334. Raman spectroscopy gained from quick and inexpensive high is a multifaceted technique useful in all ar- resolution laboratory experiments and flexeas of chemistry It fits naturally into ana- ible analysis software, andfromMicroLAB lytical chemistry as a tool for quantitative ten wavelength scanning colorimeter. and qualitative instrumental analysis. Physical chemistry is encompassed by Raman M4. Exploring the Powder Diffraction spectroscopy in both theory and practice, File™ (PDF®) the World's Largest Maproviding a useful tool for teaching classi- terials Identification Database. Sponsor: cal and quantum mechanical principles. International Centre for Diffraction DaRaman spectroscopic concepts easily fit ta (ICDD), Booth 1239. Instructor: Dr. into organic and inorganic chemistry lab Timothy Fawcett. 1:30PM to 4:30PM. experiments where the products can be Room: 339. The Powder Diffraction File characterized with Raman spectroscopy. (PDF) contains 272,000 entries and has Participants will learn how to acquire Ra- dramatically grown in size and scope due man spectra using low-cost Delta Nu Ad- to improved database technologies and vantage 200A spectrometer. Lecture strategic collaborations. While primarily handouts and proven laboratory experi- focused on the powder diffraction charments will discuss different teaching ap- acteristics of a material, the database also proaches to Raman spectroscopy in dif- contains physical property data, unit cell diferent areas of chemistry mensions, empirical formula and chemical composition data organized in away to M2. Introduction to the Cambridge facilitate rapid search so that a wide variStructural Database System. Sponsor: ety of data can be used to identify materiCambridge Crystallographic Data Centre, als. Two recently released products, PDFBooths 224, 226. Instructors: Karen 4/Full File and PDF-4/Organics, will be Lipscomb and Gary Battle. 1:30PM to demonstrated to show how the database 4:30PM. Room: 334. This workshop will can be mined and used to solve a number aim to provide librarians and information of materials identification problems. providers with a greater knowledge of the Cambridge Structural Database (CSD) and TUESDAY, MARCH 25 its associated software, covering both scientific and technical issues. Demonstra- T1. WindowsDirect Capture of Laboration and discussion sessions will include tory Balance Data. Sponsor: Shimadzu Sciareas such as data acquisition, information entific Instruments, Booths 1300,1302, representation, licensing and widespread 1304,1306. Instructors: Steve Wildberger access. Use of the CSD in teaching, via the and George DeZiel. 9AM to Noon. Room: classroom option in the ConQuest search 334. WindowsDirect enables data from software, will also be presented. Please Shimadzu analytical and top loading balbring along any queries or problems you ances to be transmitted directly into any have relating to the use or operation of the Windows application. Once configured, CSD and associated software so that these the displayed weight is transmitted direcdy can be addressed during the sessions. to a computer just as if it were entered via the keyboard. No additional software is reM3. Integrating Research into Labora- quired. Easily integrated with existing labtory Instruction: A New Look at Labo- oratory or enterprise software, Windowsratory Interfacing. Sponsor: MicroLAB, Direct enables the addition of statistical, Booth 119. Instructors: John Amend, analytical, reporting, and archiving capaMontana State University; Dale Ham- bility to Shimadzu's line of analytical and mond, Brigham%ung University, Hawaii; top loading balances. Workshop includes Sophia Nussbaum, The University of hands-on instruction in set-up procedure British Columbia. 9AM to 11AM. Room: and application development with this 339. While development of inquiry and unique Shimadzu feature. ent applications which use new column technology developed by Dionex. We will show how RFIC is also beneficial in the use of IC-MS for critical trace measurements.
T2. (1) Prediction of Properties, QSAR, and Reaction Modeling; (2) New Protein ADVANCE REGISTRATION/EXPOSITION WORKSHOPS Sequence & Docking Tools Speed Target New Orleans March 23-27 Analysis; and (3) Latest Developments No. Session # Title of workshop(s) desired in MO PAC. Sponsor: CAChe Group, (if applicable) Fujitsu, Booths 908, 910, 912. Instructors: David A. Gallagher, George D. Purvis, Ph.D., and James J.P. Stewart, Ph.D 1PM to 5PM. Room: 334. (1) Prediction of physical, chemical & biologiE-mailName cal properties such as spectra, water solAddress . ubility, reaction kinetics, carcinogenicity, etc. and QSPR & QSAR will be illusTelephone . Fax trated, along with examples of modeling Advance registration will be passed along to sponsoring companies and will ensure a space transition states, calculation of thermofor you in the workshop(s) of your choice. Return the form to ACS Expositions, 1155 16th St., dynamics and kinetics with the CAChe N.W., Washington, DC 20036; fax (202)872-4410; ore-mail:
[email protected]. RegistraWorkSystem. (2) New tools for analyzing tions can be submitted online at our website: chemistry.org/expoplanner. Deadline for adprotein structures, automated docking vanced registration is March 7. If complete information is received, confirmation of workand scoring, and receptor site identifishop(s) will be sent within two weeks of receipt of information. cation will be discussed and illustrated. (3) The latest developments in MOPAC including further enhancements in accuracy will be discussed. ing, and (4) apply analytical tools to use their tion of Solvents. Sponsor: BioPro, Booth ligand pose resultsforrecommendations for 1802. Instructor: Florian Menninger, Jr., T3. Automated FLASH Purification of synthesis or assay LigandFit on bodiCerius2 Ph.D. 9AM to Noon. Room: 334. In the Fluorous Tagged Molecules. Sponsor: Bio (SGI) and Discovery Studio (PC) platforms process of synthesizing, extracting, and putage, Inc., Booth 1607. Instructors: Omar will be demonstrated. rifying new compounds for testing in drug Mneimne, Biotage, Inc., Walt Siegel, Fluodiscovery research, there is a need to rerous Technologies, Inc. Session 1: 9AM- T5. The Ultimate in Productivity Com- move solvents to dry samples. The two 10:15AM, Session 2: 10:30AM-Noon. puting; Scalability and 64-Bit Perfor- methods most commonly used are cenRoom: 339. Come learn about how Fluo- mance Drives the Future for Life and trifugal vacuum evaporation and freeze rous Technologies and Biotage can accel- Materials Science Research. Sponsor: drying. In this workshop we will describe erate the drug discovery process. Fluo- SGI, Booth 1719. Instructors: Dan Stevens, the features and benefits of the Martin rous techniques provide strategic options DMD, Ph.D, Roberto Gomperts, Ph.D., Christ rotary vacuum concentrators and for conducting parallel solution-phase and Bob Murphy. 10:30AM to Noon. Epsilon freeze dryers used for sample consynthesis and for separating the resulting Room: 340. Whether simulating large pro- centration and drying. We will also comreaction mixtures. Fluorous compounds tein structures or delivering predictive pare the equipment requirements, discuss can be separated from organics or each measures of catalysts, 64-bit computing the process of evaporation and sublimaother based onfluorinecontent by chro- and system scalability have become criti- tion and the advantages and disadvantages matography using FluoroFlash™ fluori- cal requirementsfordelivering timely and of both methods. nated silica. These separations capitalize accurate results. This class of calculations on the unique feature of fluorous sta- demonstrates the advantages that large W2. Syntage™ Chemistry Cartridgestionary phases to separate molecules pri- memory in single system image computers Engineering Synthesis and Purification. marily by fluorine content. In combina- (currently up to 128GB in SGI® Altix™ Sponsor: Biotage, Inc., Booth 1607. Intion, synthetic chemists can leverage 3000 systems and up to 1TB for the SGI® structor: Omar Mneimne, Biotage, Inc. powerfulfluoroustechnology and the adOrigin® 3000 server) can deliver. We will 9AM to Noon. Room: 339. Eliminate vantages of Biotage's automated high- present compelling scalability results for aqueous extractions and sample loss usperformance FLASH chromatography computational chemistry applications run- ing Syntage™ chemistry cartridges. These (HPFC) systems. ning on the SGI Origin 3000 server and novel cartridges contain silica-based mewill introduce the SGI Altix family of dia for solid-phase scavenging and fluoT6. Virtual High Throughput Screening servers, which are proving to be the world's rous purification. Syntage sample-loading Workshop. Sponsor: Accekys, Booth 1419. technical computing performance leaders cartridges are available in a preformatted Instructors: Marguerita Lim-Wilby, Ph.D, for 64-bit Linus® OS-based systems. For design that eliminates the need to weigh and Shikha Varma, Ph.D. 1:30PM to technical users seeking to achieve break- loose media and are uniquely encoded for 4:30PM. Room: 339. This workshop will through performance with open-source easy sample tracking. Unlike resin-based highlight recent advances in Accelrys' vHTS computing, the SGI Altix 3000 family technology, Syntage chemistry cartridges capabilities in docking and scoring, with takes Linux to new altitudes of scalability are compatible with a broad range of organic solvents and are reactive with workflow recommendations by protein and performance. swelling. Syntage sample-loading carclasses. Users will learn how to (1) prepare intridges integrate directly with Biotage put for vHTS, (2) obtain the most accurate WEDNESDAYp MARCH 26 FLASH+™ purification cartridges and auresults when using LigandFit, 6) achieve the necessary virtual screening throughput us- W1. Drying Samples in Drug Discovery tomated systems to accelerate compound ing parallelization and distributed comput- Research by Evaporation and Sublima- purification. EXPO-13
EXPOSITION nonlinear curve fitting, signal processing, peak analysis, and statistics. Analysis functions are bolstered by time-tested computational routines from Numerical Algorithms Group - NAG. With its new built in C compiler, Origin 7 serves as a robust development platform for researchers. Visit www. originlab.com. 1322 Oxford Diffraction Ltd., 130A Baker Ave., C o n c o r d , M A , USA 0 1 7 4 2 , ( 9 7 8 ) 3 7 1 5 5 0 6 , f a x : (978)369-8287, e-mail:sales@oxford-diffraction. c o m , Internet: www.oxford-diffraction.com Oxford Diffraction design and manufacture X-ray diffraction equipment for single crystal X-ray diffraction. Our products include the Xcalibur series of small molecule and protein diffractometers. We specialise in kappa goniometers and low noise, high sensitivity COD detectors. Our CCD detectors range in size between our Sapphire CCD 92 mm to our large area Onyx CCD \65 mm. We also manufacture the 15 Kelvin Helijet open flow helium cooler and supply the Oxford Instruments Cryojet nitrogen cooler. 113 Oxford University Press, 198 Madison Ave., N e w Y o r k , N Y , USA 1 0 0 1 6 , ( 2 1 2 ) 7 2 6 - 6 0 7 9 , f a x : (212)726-6446, Internet: http://www.oup-usa.org Please visit booths 1208, 1210, and 1212 to view hundreds of outstanding chemistry titles, including: Comprehensive Desk Reference of Polymer Characterization and Analysis - Brady; Polymer Characterization Techniques and Their Application to Blends - Simon; Advances in Drug Delivery: Science, Technology, and Products - Dinh; Freshness and the Shelf Lite of Foods - Cadwallader; Organic Chemistry, 4th Edition - Loudon; Molecules as Components in Electronic Devices - Lieberman; Wood Deterioration and Preservation: Advances in Our Chanqing World - Goodell; Terrestrial Field Dissipation Studies: Purpose, Design, and Interpretation - Arthur; and Elements of Analytical Chemistry - Higson. ACS members receive a 25 percent discount on all ACS titles. All other books are available at a 20 percent discount. To view ACS and Oxford University Press chemistry titles online, visit www.oup-usa.org/acs and www.oupusa.org/k153. 1208,1210,1212 Paar Physica, 10215 Timber Ridge Dr., Ashland, VA, USA 2 3 0 0 5 , ( 8 0 4 ) 5 5 0 - 1 0 5 1 , fax: (804)5501057, Internet: http://wwwjDaarphysica.com Paar Physica offers a full line of Rheometers and Viscometers for Research and Development as well as QC/QA. Please stop by our booth and speak to one of our experienced Rheologists. We are located in Booth #118. 118 PANalytical, 12 Michigan Dr., Natick, M A , USA 01760, (508)647-1100, fax: (508)647-1115, Internet: http://www.panalytical.com PANalytical Inc., formerly Philips Analytical, is the leading supplier for X-ray diffraction XRD and X-ray fluorescence XRF spectrometry. We provide targeted solutions to customers' applications, from research to process control. X/?D solutions include the versatile X'Pert Pro system with new XML file-based software; CubiX Pro and CubiX Fast, the R&D 100 award winning choice for process control. XRF offerings include MagiX sequential and simultaneous spectrometers, Venus 200 wavelength analyzers and our new Minipal2 benchtop EDXRF. 1538 Parallel Quantum Solutions, 2013 Green Acres R d . , S u i t e A , F a y e t t e v i l l e , A R , USA 7 2 7 0 3 , (479)521-5118, fax: (479)521-5167, e-mail:sales@ p q s - c h e m . c o m , Internet: h t t p : / / w w w . p q s - c h e m . c o m Parallel Quantum Solutions manufactures arallel computers with integrated software for igh performance computational chemistry. Our offerings have an exceptional price performance ratio, and are fully configured tor parallel computations straight out of the box. Our current product is aimed primarily at ab initio modellinq, out also includes semiempirical, molecular mechanics and dynamics methods. For more details including benchmark timinqs please visit our web site at http://www.pqs-cnem.com. 1917 Parr Instrument Co., 211 53rd St., Moline, IL, USA 61265, (309)762-7716, fax: (309)762-9453, e-mail:
[email protected], Internet: www.parrinst.com Laboratory reactors and pressure vessels, stirred and unstirred, used at elevated temperatures and pressures in the catalytic hydrogénation, organic synthesis and the polymerization processes. Oxy-
14-EXPO
gen combustion bomb calorimeters and accessories for the determination of the heat of combustion in solid, liquid and refuse derived fuels. Sample preparation equipment used in the acid digestion process in either microwave or convection ovens for trace metal analysis. 301,303,305 Particle Sizing Systems, 75 A e r o Camino Blvd., #B, Santa Barbara, CA, USA 9 3 1 1 7 , (727)8460866, fax: (727)846-0865, Internet: h t t p : / / w w w . pssnicomp.com Particle Sizing Systems produces a full line of particle size analyzers covering a range of 0.003-5000 microns for wet and dry applications. This includes the Nicomp DLS bubmicron Sizer and the AccuSizer Single Particle Optical Sizer - SPOS. These products offer unprecedented resolution, accuracy and sensitivity with modular accessories including online sampling, batch autosampling, zeta potential, syringe samplinq and pressurized liquid samplers. 812 Paterrra, Inc., 526 Spring Mill Rd., Villanova, PA, USA 19085-1928, (800)430-5727, fax: (610)5272 0 4 1 , e-mail:
[email protected], Internet: www. paterra.com. The Paterra - r Internet Service provides clients with Instant MT - r translation of Japanese patent documents in minutes for only $39 per document regardless of length. Coverage from 1993 for unexamined, 1996 for granted patents. New! Protys(tm) fulitext English database of the latest Japanese patents - one week from publication to search availability, true fulitext searching in English, unique in-context display. 626 PDR-Chiral, 1331 A South Killian Dr., Lake Park, FL, USA 3 3 4 0 3 , (561)841-4195, fax: ( 5 6 1 ) 8 4 1 4196, e-mail:
[email protected], Internet: www.pdr-chiral.com PDR-Chiral manufactures the Advanced Laser Polarimeter - ALP, with more sensitivity and linear dynamic range than any other polarimeter. Flow cells are available for HPLC, SFC, analytical, prep, SMB and Process applications. Other product include: AutoCalc, AutoPrep and AutoSMB Software - automate chiral calculations and control purifications automatically; complete Method Development Stations - MDS and Prep Systems for chiral and non-chiral applications; and Contract Services, including chiral method development, purification, and consulting. 1910 PerkinElmer, 710 Bridgeport Ave., Shelton, CT, USA 06484, (203)402-6878, fax: (203)944-9450, Internet: http://www.perkinelmer.com 300,302 Personal Chemistry Inc., 2 Hampshire St., Suite 100, Foxboro, M A , USA 02035, (508)698-8723, fax: (508)698-9523, e-mail:info@ personalchemistry.com, Internet: www. personalchemistry.com Personal Chemistry develops and markets Coherent Synthesis, a complete solution for faster chemistry development within medicinal and combinatorial chemistry. The company has its headquarters in Uppsala, Sweden and subsidiaries in Foxboro, Massachusetts, Cambridge, U.K and Konstanz, Germany. Come see the latest in knowledge management software for chemists as we present Emrys Knowledge Builder and Emrys PathFinder. 1426,1428 Pharmacopeia Inc., P.O.Box 5350, Princeton, N J , USA 08543, (609)452-3642, fax: (609)452-3672, Internet: h t t p : / / w w w . p h a r m a c o p . c o m 1512 Pittsburgh Conference, 300 Penn Center Blvd., Suite 3 3 2 , P i t t s b u r g h , PA, USA 1 5 2 3 5 - 5 5 0 3 , (412)825-3220, fax: (412)835-3224, e-mail: p i t t c o n i n f o @ p i t t c o n . o r g , Internet: w w w . p i t t c o n .org PITTCON 2004, the largest and most inclusive conference and exposition on laboratory science and instrumentation worldwide, will present Solutions for Better Chemistry at McCormick Place in Chicago, IL, March 7-1 z. Experience it all—the hottest technology, supplies and equipment at the Exposition; outstanding Technical Programming; and incomparable Educational Opportunities at the Short Courses and Poster Sessions. To learn more, stop by our booth, visit our website at www. pittcon.org, call us at (412) 825-3220, or e-mail us at
[email protected]. 1829,1831 Polium Technologies, Inc., 2155 Stonington Ave., Suite 119, Hoffman Estates, IL 60195, (847)3108 7 2 5 , fax: (847)310-8726, e - m a i l : i n f o @ p o l i u m . c o m , Internet: w w w . p o l i u m . c o m Polium Technologies, Inc. focuses on custom synthesis of chiral
compounds, reversibly soluble polymers, and conjugates of reversibly soluble polymers with enzymes and small molecules. Our products can be used in pharmaceutical and fine chemical industries as well as for surface remediation and decontamination. Our services: Organic Chemistry: chiral synthesis, chiral resolution, synthesis of cniral cyanohydrins, fluorine chemistry, biocatalysis, chiral ethanolamines. Polymer Chemistry: responsive smart polymers, protein polymer conjugates. Biochemistry: biomolecule modification, protein purification, enzyme purification, enzyme kinetics. 1640 P o l y m e r L a b o r a t o r i e s Inc., A m h e r s t F i e l d s Research Park, 160 O l d Farm Rd., Amherst, M A , USA 01002, (413)253-9554, fax: (412)253-2476, e-mail:
[email protected], Internet: http://wwwjDolymerlabs.com PL shows its PL XT 20 and PL RS 20 Rapid Analysis GPC instruments; the PL PSDA particle size distribution analyzer; the new enhanced, Cirrus multi-detector - LALS, viscometry software for GPC SEC. PL will show evaporative light scattering detectors for analytical, microbore and preparative HPLC, GPC and HTS; leading organic aaueous GPC SEC columns, hiqhly characterized polymer calibrants, polymeric HrLC columns, preparative process purification media, Stratospheres resins for medicinal and combinatorial chemistry peptide synthesis. 1928,1930 Precision Detectors, 34 Williams Way, P.O. Box 738, Bellingham, M A , USA 02019, (508)966-3847, fax: (508)966-3758, e-mail:info@ precisiondetectors.com, Internet: www. Iightscatter.com Precision Detectors, Inc., manufactures state of the art laser light scattering detectors for the characterization of polymers, macromolecules and nanoparticles in solution. Key information is provided for molecular weight and size 1-1000nm radius. The product line includes flow-cell detectors for HPLC, FPLC, FFF and High-Temp GPC and manual and automated batch systems. 1636 Prentice Hall, 1 Lake St., Upper Saddle River, N J , USA 07458, Internet: www.prenhall.com Prentice Hall is a leading chemistry publisher across the curriculum featuring cutting edge media products to complement our text materials. We display our full line of print resources, ranging from fresnman to graduate level texts, and multimedia products suca as CDROMs, websites, and software. Our key 2003 titles include Brown, LeMay, Bursten's Chemistry: The Central Science, Wade's Organic Chemistry, Burns' Fundamentals of Chemistry, McMurry and Castellion's Fundamentals of general, organic, and biological chemistry, and more. We are proud to introduce Tro's Introductory Chemistry and Introductory Chemistry Essentials, new exciting entries into the introductory preparatory markets. Please visit our booth; we'll be happy to discuss your educational needs and provide a customized solution. 400,402,404 Q-Sense,lnc, 1200 Quail St., Suite 250, N e w p o r t Beach, CA, USA 92660, (949) 250 0273, fax: (§49) 2 5 0 0 3 7 0 , e-mail:
[email protected], Internet: www.q-sense.com Q-Sense offers a new sensor technology; Quartz Crystal Microbalance with dissipation monitoring, QCM-D, that enables real time characterization of surface reactions. The QCM-D technique is a strong tool when investigating: lipids; proteins and polymers. In reactions such as: adsorption, hydration, cross-linking and phase-transitions. For more information please visitwww.q-sense.com. 1630 Q u a n t u m Analytics(frmer LINC Q u a n t u m , 363 Vintage Park Dr., Foster City, CA, USA 94404, (800)992-4199, fax: (650)312-0313, e-mail:Lqa@ lqa.com, Internet: www.Lqa.com Rent, lease or purchase from our multi million dollar inventory of new and reconditioned instruments ready for immediate delivery. Instruments available include: GC, GC MS, HPLC, LC MS, Pyrolysis Systems, Thermal Desorption Systems, Post Column Systems, High Temperature HPLC System, Sample Preparation and Handling, Data Systems and Software, FTIR, GC IR Interface, AA, FL, ICP MS, UV Vis, TOC and XRF; manufacturers include: Aqilent Technologies, Diablo Analytical, Frontier Laboratories, LEAP Technologies, Markes International, Matheson Tri Gas, Metalox, Mulan Laboratory, Tekmar Dohrmann, and more. 525
Quark Enterprises, Inc., P.O. Box 2396, Vineland, NJ, USA 08362-2396, (856)455-0376, fax: (856)455-3373, Internet: http://www.quarkglass. com. 317 Query+f P.O. Box 2927, Santa Clara, CA, USA 95055, (408)394-8200, fax: (408)523-1288, e-mail:
[email protected], Internet: www.queryplus. com Query+ provides knowledge discovery software to the life sciences industry. Our high performance similarity search and clustering tools deliver a unique competitive advantage to users and suppliers of molecular, genomic, experimental, clinical, and image-based data. We offer proven solutions that allow organizations to reduce the time, effort, and cost of creating advanced applications. Our intuitive software works with your existing information technology infrastructure and business processes to help vou quickly and easily exploit your data. 1 v11 Quesant Instrument Corporation, 29397 Agoura Rd., Suite 104, Agoura Hills, CA, USA 91301, (818)597-0311, fax: (818)991-5490, Internet: http://www.quesant.com 1906 Questel Orbit, Inc., 8000 Westpark Dr., McLean, VA, USA 22102, (703)556-7493, fax: (703)8934632, Internet: http://www.questel.orbit.com 123 Rainin Instruments, Rainin Road, Box 4026, Woburn, MA, USA 01888, (800)828-2788, fax: (781)938-8157, Internet: http://www.rainin.com Rainin Instrument, LLC - Pipettes: ergonomie single and multichannel manual and electronic pipettes featuring unique LTS LiteTouch Tip Ejection System that reduces tip ejection forces. Also offering Pipetman manual, Microman positive displacement pipettes and Distriman repetitive dispenser. Tips: Featuring environmental tip rack refills, double 96 racks, and aerosol resistant tips for most pipettes. Pipette Service Programs: Calibration PM and OnSite Service with Preventive Maintenance for minor repairs, and for major repairs, Express Repair at ISO 9001 certified service centers. 607,609 Rapp Polymère GMBH, Ernst Simon Strasse 9, Tuebingen, GERMANY D-72072, +497071763157, fax: +497071763158, e-mail:
[email protected], Internet: rapppolymere.com Over a decade now Rapp Polymère is one of the leading companies of novel resins used in solid phase chemistry and diagnostic applications. TentaGelTM and high quality Polystyrenes are available with a variety of functional groups and size fractions. As new product lines HypoGel TM, a hydrophilic high loaded spacer polymer and the macroporous ScavengePore resins are introduced. The APOS 1200 PS system is the first modular and transportable reaction unit for Automated Parallel Organic Synthesis. 1838 Reed Scientific Group, 301 Gibraltar Dr., P.O. Box 650, Morris Plains, NJ, USA 07950-0650, (973)292-5100, fax: (973)539-3476, e-mail:mlally@ reedbusiness.com, Internet: www.reedscientiTic. com Reed Scientific publishes Bioscience Technology, Drug Discovery and Development, Genomics & Proteomics, Laboratory Equipment, R&D, and Scientific Computing and Instrumentation magazines. Visit our booth to start your free subscription, inquire about having a paper published, or to learn how we can help you market your products. Reilly Industries, 1500 South Tibbs Ave., P.O. Box 42912, Indianapolis, IN, USA 46242-0912, (317)248-6457, fax: (317)248-6528, Internet: http://www.reillyind.com 1746 Rice Lake Weighing Systems, 230 West Coleman, PO Box 272, Rice Lake, Wl, USA 54868, (715)2349171, fax: (715)234-6967, e-mail:prodinfo@ calweights.com, Internet: www.calweights.com Our new strategic partnership with Shimadzu Scientific Instruments enables us to offer a line of balances that exceeds even the most discerning expectations of features, benefits and performance. Featuring the exclusive on board firmware Windows Direct, balances are ready to interface with a computer and export data into virtually any MS Windows based application, turning the balance into a valuable data collection tool. Data can be viewed, graphed, sorted, and reported in any imaginable way. 1627,1629
Ricerca Biosciences, 7528 Auburn Rd., Box 1000, Concord, OH, USA 44077 (440)357-3768, fax: (440)354-6276, e-mail:
[email protected], Internet: http://www.ricerca.com. Ricerca Biosciences is a worldwide drug development partner to biotechnology and pharmaceutical companies that takes lead molecules from the discovery stage through product development. Ricerca has pharmacology and toxicology, medicinal chemistry to scale up production and regulatory support services at one site allowing it to offer an integrated solution that includes discovery lead optimization, preclinical development and drug substance synthesis. Ricerca is also focusing its efforts in the partnered development of new drugs in two therapeutic areas of expertise: oncology and infectious diseases. 1246 Richman Chemical, 768 North Bethehem Pike, Lower Gwynedd, PA, USA 19002, (215) 628-2946, fax: (215) 628-4262, e-mail:clk@richmanchemical. com, Internet: http://www.richmanchemical.com Richman Chemical Inc., a pioneer in the independent outsourcing business model, provides value added services to the chemical, pharmaceutical and life science industries. We use a network of manufacturers and researchers around the world to reliably deliver cost effective, quality products and services on time. We provide one stop shopping for your sourcing needs: project management, process development, small scale synthesis, kilo scale up, commercial production, product sourcing and custom distillation, drying. We have a well deserved reputation for solving problems and delivering results! 1544 Rigaku, 9009 New Trails Dr., The Woodlands, TX, USA 77381, (281)363-1033, fax: (281)364-3628, e-mail:
[email protected], Internet: www. RigakuMSC.com Since its inception in Japan in 1951, Rigaku Corporation has been at the forefront of analytical and industrial instrumentation technology. With hundreds of major innovations to its créait, Rigaku and its subsidiary companies are world leaders in the fields of X-ray fluorescence, X-ray diffraction, X-ray optics, as well as small molecule and protein crystallography. Rigaku MSC also provides contract services. Instrumentation includes: The Miniflex is a compact X-ray diffraction system, The ZSXmini a desktop wavelength despersive WD XRF spectrometer, cryo-cooling devices, x-ray reflectometers, rotating anode generators; and the R AXIS RAPID Imaging Plate Area Detector with a 2theta range of -60 degrees to +144 degrees from a single detector setting. 1232,1234,1236 Ronald T. Dodge Co., P.O. Box 41630, Dayton, OH, USA 45441-0630, (937)439-4497, fax: (937)439-1704, Internet: http://www.rtdodge.com
(520)293-6911, Internet: http://www.specinst.com 211 Schering-Plough, 2000 Galloping Hill Rd., Kenilworth, NJ, USA 07033, (908)298-4000, fax: (908)298-2793, Internet: http://www.scheringplough.com As a worldwide, research based pharmaceutical company, we are engaged in the discovery, development, manufacturing and marketing of new therapies and treatment programs that can improve people's health and extend their lives. For more than 50 years, our success in the worldwide pharmaceutical marketplace has been driven by our company's commitment to innovative research, effective marketing and solid financial management. In fact, growth through research is central to our business strategy our innovation has earned us market leadership positions in many of our key therapy areas. 426 Schrodinger, 1500 Southwest First Ave., Suite 1180, Portland, OR, USA 97201, (503)299-1150, fax: (503)299-4532, e-mail:
[email protected], Internet: www.schrodinger.com We will demonstrate the latest release of the FirstDiscovery suite of software for structure based drug design. The suite includes a core molecular mechanics module, and three advanced modules, Glide, Liaison, and QSite. Glide performs extremely fast flexible docking of multiple ligands, and achieves high enrichment in library screening consistently across a diverse range of receptors. Liaison computes accurate free energies of binding. And QSite is a hybrid QM/MM program, which takes advantage of the extremely fast ab initio engine of Schrôdinger's Jaguar. In addition, we will debut a new protein structure prediction suite - Prime. The Prime suite contains state of the art modules for both Threading and Comparative Modeling, integrated under Schrodinger's Maestro interface. The latest releases of Jaguar, MacroModel, and QikProp will also be on hand for demonstration. 1707 Sci-Tec, Inc., 6660 North High St., Suite 2A, Worthinaton, OH, USA 43085, (614)888-0023, fax: (614)888-0285, e-mail:
[email protected], Internet: www.sci-tec-inc.com Laboratory and process analyzers for powders, dispersions, emulsions and aggregates. Introducing ShearScan, a powder flowability analyzer complete with dynamic yield locus analysis and flow functions. TurbiscanLab analyzes tne stability of concentrated dispersions and emulsions. Turbiscan On-Line monitors mean particle size and volume fraction. New Turbiscan AGS, an automated ageing station. PartAn, a particle size and shape analyzer for laboratory and on-line, employing video imaging to measure particles from 10um to 6 inch liquident, counts, sizes and chemically analyzes exact particle contamination. 1438
120 Royal Society Of Chemistry, Science Park, Milton Rd., Cambridge, UNITED KINGDOM CB4 OWF, +44 (0) 1223 432360, fax: +44 (0) 1223 426017, e-mail:
[email protected], Internet: www.rsc.org The Royal Society of Chemistry, RSC, is the UK Learned and Professional Body for chemical sciences and the Learned Society for chemistry. Through its 46,000 members, including academics, teachers and industrialists, it promotes the interests of chemists and the benefits of chemical science. The RSC publishes primary and review journals, in print and electronic form, and books and databases - in general, applied and environmental chemistry. Please visit www.rsc.org for the full range of RbC products and services. 726,728
Science/AAAS, 1200 New York Ave., Washington, DC, USA 20005, (202)326-6417, fax: (202)8421065, Internet: www.sciencemaq.org Founded in 1880 by Thomas Edison, SCIENCE ranks as one of the world's leading scientific journal. Each week, SCIENCE provides over 148,000 subscribers around the world with peer reviewed original research, scientific research articles, and reports, science and research news as well as policy forums and perspectives on current topics. Scientists can also access the journal online at www. scienceonline.org which includes a comprehensive recruitment site, www.sciencecareers.org, offering iobs, career advice and a resume CV database. 420
RVM Scientific, 5511 Ekwill St, #A, Santa Barbara, CA, USA 93111, (805)964-3368, fax: (805)9642269, e-mail:
[email protected], Internet: www.rvmscientific.com Fast GC modular instrumentation for accelerating analysis and instrument cycle times. Low Thermal Mass, LTM, GC modules are capable of fast temperature programming, including operation at high temperatures and fast cooldown. Modules can incorporate all commercially available capillary columns. Low cost retrofit instrumentation for laboratory GCs provides independent temperature programming of up to 4 modules simultaneously. Systems are designed for ease of installation and maintenance, and offer highly flexible configurations. 1828
Scientific Computing & Modelling NV, Theoretical Chemistry, Vrije Universiteit, De Boelelaan 1083, Amsterdam, The Netherlands 1081 HV, +31-20-4447626, fax: +31-20-4447629, e-mail:
[email protected], Internet: http://www.scm.com/ acs.html ADF is a leading density functional software package for computational quantum chemistry. It allows you to accurately compute your favorite property of any molecule in any chemical environment. ADF treats solvent, solids, and proteins, transition metals and heavy elements, electric and magnetic properties. The ADF2003 version includes new modules that make it easy to set up your calculation and to visualize your results. Join our booth to learn how ADF can help your research. 1913
S.I. Photonics, Inc., 1870 W. Prince Rd., Suite 38, Tucson, AZ, USA 85705, (520)404-3203, fax:
SciTegic, 9665 Chesapeake Dr., #401, San Diego, CA, USA 92123-, (858)279-8800, fax: (858)279EXPO-15
EXPOSITION 8804, e-mail:
[email protected], Internet: www. scitegic.com The Pipeline Pilot software system allows researchers to define and automate complex analysis and processing operations on extremely large data sets in real time. Data Pipelining provides a new avenue in computation and has applications across cheminformatics, bioinformatics, and automated assay data analyses. Major enhancements for newly released Pipeline Pilot v3.0 include, chemistry support for Tautomers, Recursive Smarts, Mo/2 file format, LogD and pKa property calculations, changes to the user interface, and improved administration capabilities. 1811,1813 Semichem, P.O. Box 1649, Shawnee Mission, KS, USA 66222, (913)268-3271, fax: (913)268-3445, e-mail:
[email protected], Internet: www. semichem.com Semichem and Gaussian will show the new 3.0 version of their jointly developed interface GaussView. This GUI is an affordable, full featured interface allowing flexible management and visualization of Gaussian calculations and has a number of new features to support the unique capabilities of Gaussian03. Semichem will also exhibit its rapid and robust semiempirical program AMP AC, now available as Version 7.0 with all new GUI and computational capabilities. CODESSA, a QSAR QSPR program that exploits the information available from AMPAC and Gaussian will also be shown. Gaussian, Inc. will demonstrate the recently released Gaussian03, a complete solution which focuses on the use of ab initio electronic structure methods to model molecular structures and properties of gas and condensed phase systems. 1100,1102,1104 SensoPath Technologies, Inc., c/o M PA Technologies, Inc., 910 Technologies Blvd. Suite AB8, Bozeman, MT, USA 59718, (406)585-8192, fax: (406)556-0969, e-mail:
[email protected] Dendrimer and dendron materials for the design and assembly of self-assembled monolayers (SAMs) for attachment to gold surfaces in surface plasmon resonance (SPR) and quartz crystal microbalance (QCM) detectors; functionalized dendrimers for SPR or fluorescence detection of bioterror, and food- or water-borne pathogens; custom design services for immobilization of antibodies or other biomolecules on gold surfaces. 1638 Serena Software, Box 3076, Bloomington, IN, USA 47402-3076, (812)333-0823, fax: (812)3320877, e-mail:
[email protected], Internet: www.serenasoft.com Showing Pcmodel v8 for Windows, OSX and Linux. Pcmodel is a complete molecular modeling program able to build, edit and manipulate complex organic, inorganic and biomolecules. Pcmodel supports multiple force fields and can export and import files for many QM programs including Gaussian, Gamess,Ampac Mopac.Jaguar, ADF and Turbomole. Also Orbdraw, for displaying molecular orbitals and densities, and vibrate, for normal vibrational modes, will be shown. The latest release of Gaussian will be demonstrated. 508,510 Setaram, 130 Gaither Dr., Suite 116, Mt. Laurel, NJ, USA 08054, (856)778-7600, fax: (586)7787377, e-mail:
[email protected], Internet: www. setaram.com Setaram is one of the world's leading manufacturers of thermal analysis instruments, calorimetry, DTA, DSC, thermogravimetry, thermomechanical analysis. Setaram has built itself a solid reputation as expert specialized in high and low temperature thermal analysis and calvet calorimetry. 428 SGE, Incorporated, 2007 Kramer La., Austin, TX# USA 78758, (800)945-6154, fax: (512)836-9159, e-mail:
[email protected], Internet: www.sge.com Over thirty five years ago SGE started as a syringe manufacturer. SGE manufactures microanalytical syringes, capillary GC columns, ferrules, fittings including SilTite ferrules for GC use, septa, inlet liners, capillary tubing, ProteCol capillary HPLC columns, MS supplies including electron multipliers, NoVent column change system and jet separators. Instrumentation includes Pyrojector II -pyrolyzer- and MDS 6890 - multidimensional GC system. SGE retrofit equipment includes GC Backflush, ms Open Split Interface, and the Olfactory Detector Outlet II. 729 SGI, 1600 Amphitheatre Pkwy, 41-3-405, Mountain View, CA, USA 94043, (650)960-1980, e-mail: 16-EXPO
[email protected], Internet: www.sgi.com SGI has been a leading supplier for the life and chemical sciences market for over 15 years. SGI provides the high performance computing, storage, SAN data management, and visualization tools needed to help scientists solve their most difficult problems. With the high performance, scalable IRIX OS based servers and new SGI servers based on Itanium 2 and Linux, SGI supplies the high performance computing infrastructure necessary to provide the intense computational capabilities that are essential for success in these fields. To help researchers managing large data across their SANs and heterogeneous compute systems, SGI offers both high-performance storage devices and software CXFS mat transfers files across the SAN and to servers running various operating systems at near-local speeds. And to observe, interact, and interpret the data, SGI provides immersive, stereo 3D visualization solutions. 1719 Shimadzu Scientific Instruments, 7102 Riverwood Dr., Columbia, MD, USA 21046, (410)3811227, fax: (410)381-1222, Internet: http://www. shimadzu.com 1300,1302,1304,1306 SibTech, Inc., 705 North Mountain Rd., Newington, CT, USA 06111, (860)-953-1164, fax: (860)953-1317, e-mail:
[email protected], Internet: http://www.sibtech.com SibTech is a leading wordwide provider of custom tritiation services. To date, we have tritiated over 200 of very different research compounds, drugs, hits, and leads. New labeled compounds are delivered in 2-3 weeks. Our success is based on proprietary technology that allows tritiation of any organic molecule, natural or synthetic, low or high molecular weight. Visit our booth to learn more about our technology and to perform a virtual tritiation of your favorite compound. 110 Silicycle, 1200 St. Jean-Baptiste, Suite 114, Quebec City, QC, CANADA G?E 5E8, (418)874-0054, fax: (418)874-0355, e-mail:
[email protected], Internet: www.silicycle.com SiliCycle UltraPure Adsorbents, TLC Plates, SPE Cartridges, Flash Cartridges, HPLC Columns, IMPAQ and more than 50 Functionalized Silcia Gels are manufactured at SiliCycle using unique and specialized methods. Our novel silica immobilized scavengers and reagents are powerful tools for organic synthesis and chromatography. Significant benefits derive from a non-swelling soîid phase, broad solvent compatibility, pH stability, high scavenging capacity unit volume and low non-specific binding. 628 Silk Scientific, Inc., P.O. Box 533, Orem, UT, USA 84059, (801)377-6978, fax: (801)422-0153, e-mail:
[email protected], I n t e r n e t : www. silkscientific.com The UN-SCAN-IT software converts scanned graphs to x,y data at full scanner resolution, and can automatically digitize strip charts, instrumental output, published graphs, old graphs, etc. The UN-SCAN-IT gel software turns your scanner into a high speed densitometer and allows you to automatically analyze electrophoresis gel images at full scanner resolution. Windows and Macintosh versions under $400. 703 Simulations Plus, Inc., 1220 West Avenue J, Lancaster, CA, USA 93534, (661)723-7723, fax: (661)723-5524, e-mail:
[email protected], Internet: www.simulations-plus.com Simulations Plus, Inc., develops advanced ADME software now in use by most major pharmaceutical companies worldwide. GastroPlus simulates absorption and pharmacokinetics for a variety of oral and IV dosage forms of compounds in human and animals. OMPRPIus generates estimates of human jejunal permeability, logP, solubility, diffusion coefficient, BBB penetration, plasma protein binding, volume of distribution, and Rule of 5. Pick up your FREE evaluation CD ROMs of these programs at Booth 1840. 1840 Specs, 6440 Dobbin Rd., Suite D, Columbia, MD, USA 21045, (410)707-3142, fax: (410)772-3206, e-mail:
[email protected], Internet: www. specs.net Specs offers zOOOOO screening compounds, building blocks, natural products, and targeted sets for HiS. Compounds are acquired from Japan, China, Spain, India, Russia and the USA to provide unique bioactive compounds. Specs provides cheminformatics, contract research and custom synthesis. Specs offers sample preparation and handling. Companies compound collections
can be weighed, plated in 96-well or 384 well microtiter plates and rebottles with custom barcodes. This work can be done either at the customers site or at Specs facilities in Holland or the USA. 429 Spectrum Chemicals & Lab. Products, 14422 South San Pedro St., Gardena, CA, USA 90248, (800)772-8786, fax: (800)525-2299, Internet: www. spectrumchemical.com Spectrum Chemicals & Laboratory Products is a customer focused manufacturer and global distributor of over 12,000 fine chemicals and 120,000 laboratory supplies and equipment. Our facilities in California and New Jersey are ISO 9002 certified, FDA registered, and operate under strict current Good Manufacturing Practices - cGMP. 1606,1608 Spex Fluorescence c/o JY Inc., 3880 Park Ave., Edison, NJ, USA 08820, (732)494-8660, fax: (732)549-5157, e-mail:fluorescence@jyhoriba. com, Internet: www.jyhoriba.com New spectrofluorometers, the most sensitive in the world, will be displayed in the Spex Fluorescence JY booth. New products include Pulsed Lamp Fluoromax for Phosphorescence, stop flow system for kinetics, microspectrofluorometer and upgrades for SLM. Also new is a 384 Plate Reader. 101 Spiring Enterprises-Molymod™, Unit 8E, Gillmans Industrial Estate, Natts Lane, Billinghurst, West Sussex, ENGLAND RH14 9EZ, +44 1403 782387, fax: +44 1403 785215, e-mail:molymod@ qlobalnet.co.uk, Internet: www.molymod.com Supplier and Sole manufacturer of the Molymod Molecular model dual scale system of molecular and atomic models, suitable for organic, inorganic and biochemistry at school, college, university and research levels. Wide range of self assembly kits and sets including molecular and atomic orbital kits at www.orbitals.co.uk and the new miniDNA abstract system for modeling DNA and RNA. Approved distributors in the USA and Canada. 1925 Springer-Verlag NY, Inc., 175 Fifth Ave., New York, NY, USA 10010-7858, (212)460-1500, e-mail:
[email protected], Internet: www.springerny.com Enjoy 20 percent off a stunning range of books from Springer, RSC - Royal bociety of Chemistry, ana BIOS. From favorites like The Science of Looking and the Instant Notes series, to heavyweight references, like the new, highly anticipated Atlas of Plastics Additives by Dietrich Hummel. Plus Fall 2002 bestsellers: Molecular Modeling and Simulation (Schlick) and Name Reactions (Li). Sample renowned journals, like Analytical and Bioanalytical Chemistry and Journal of Molecular Modeling, and sample InfoChem software. 409,411 Strem Chemicals, 7 Mulliken Way, Dexter Industrial Park, Newburyport, MA, USA 01950-4098, (978)462-3191, fax: (978)465-3104, e-mail:info@ strem.com, Internet: http://www.strem.com Metals, inorganics, organometallics for research. Metal catalysts for organic synthesis, chiral ligands, ionic liquids, orqanophosphines, metallocenes, metal carbonyls & derivatives, precious metals and rare earths. Volatile precursors for MOCVD. High pressure reactions. Pharmaceutical intermediates under validated cGMP facilities. Bulk manufacturing. Custom synthesis. 1422 Synergix Ltd., Technology Park Malha, Building 1, Jerusalem, ISRAEL 91487, 97226480396, fax: 97226480399, e-mail:info@molecular-conceptor. com, Internet: www.molecular-conceptor.com Molecular Conceptor is the first multimedia courseware for teaching 3D drug design principles. After covering basic information about drug discovery and molecular modeling methods, this CD ROM explains how molecular geometry and computed properties are used to design lead compounds. It reviews strategies to mimic small molecules, design inhibitors and peptidomimetics. Concepts are illustrated with manipulatable views of molecules, pharmacophores, and protein ligand complexes. It aims the education of students and professors, the training of medicinal chemists, and may serve as a refresher course for modelers. 1541 SynPep, 6905 Sierra Court, P.O. Box 2999, Dublin, CA, USA 94568, (925)803-9250, fax: (925)8039301, e-mail:
[email protected], Internet: www.
synpep.com SynPep Corporation is a leader in the production of custom and cataloq peptides for R&D of vaccines, therapeutic and diagnostic products. Other products include: GMP, custom polyclonal antibodies, radiolabeled modified peptides, mass spectroscopy, enzyme substrates and inhibitors, MAPS systems, amino acids, resins & reagents, and manual multiple organic peptide synthesizers. 1431 TA Instruments, 109 Lukens Dr., New Castle, DE, USA 19720, (302)427-4000, fax: (302)427-4001, e-mail:
[email protected], Internet: www.tainst.com TA Instruments is a world leading supplier of thermal analysis and rheology instruments and related software. We offer a complete line of high performance Q Series DSC, TGA, DMA, and now TMA thermal modules. These are complimented by our extensive range of research and quality control rheometers. At ACS, we will display our latest Q 1000 DSC module and our innovative AR 2000 Advanced Rheometer. 111 Taylor and Francis, 29 West 35th St., New York, NY, USA 10001-2299, (203)281-4487x154, fax: (203)230-1186, e-mail:adam_sendroff@garland. com, Internet: www.taylorandfrancis.com Please visit Taylor & Francis Books, Inc., a leading publisher of textbooks, monoqraphs and journals in chemistry at booths 208,210. We invite you to come and see our latest titles and to hear about forthcoming publications. 208,210 TCI America, 9211 North Harborgate St., Portland, OR, USA 97203, (800)423-8616, fax: (503)283-1987, e-mail:
[email protected], Internet: www.tciamerica.com TCI America provides custom synthesis and contract research services for the pharmacuetical, cosmetic, electronic, hi-tech and biotechnology researcher. Most recent catalog lists more than 18,000 high purity special organic chemicals in packaging convenient for reagent usage. Manufacturing facilities offer kilo to ton lot production utilizing many reaction capabilities. Modern facilities can provide cGMP manufacturing and are registered with the FDA. Visit our Web site and online catalog to source, place an order for chemicals or just browse. 1109
polvmer.uakron.edu The University of Akron's College of Polymer Science & Polymer Engineering is the largest academic program for the teaching and research of polymers in the US. With almost one hundred years of expertise to drawn upon, the College offers technical training at all levels, work force certificate training and associates degrees to bachelors, masters and doctoral degrees, and its faculty are leading the field in fundamental and applied research and development. The college also has state of the art analytical and testing laboratories for technical service to industry. 1821 Thermo Electron Corporation, 81 Wyam St., Waltham, MA, USA 02454, 877-Thermo-U (877843-7668), fax: (781)768-6645, e-mail:ACS@ thermo.com, Internet: www.thermo.com A world leading hiqh tech instruments corporation,Thermo Electron Corporation helps laboratory and industrial customers advance scientific knowledge, enable drug discovery, improve manufacturing processes, and protect people and the environment with instruments, scientific equipment, and sample-in knowledge out solutions. Tnermo Electron has revenues of more than $2 billion, and employs approximately 11,000 people in 30 countries worldwide. Our integrated solutions include state of the art instrument systems, advanced software, and consumables, tailored to meet the rigorous demands of lab professionals. Products include AA, ICP, ICP MS spectrometers for elemental analysis; molecular-analysis instruments, including FT IR, near IR, Raman spectroscopy instruments; IR microscopes, sampling accessories, software, and spectral libraries; UV Vis and fluorescence spectrophotometers; ion trap, quadrupole, and magnetic sector mass spectrometers, liquid and gas chromatographs, and hyphenated multi instrument combinations of these products; informatics solutions, including desktop spectroscopy software for data processing, data management, 3D data viewing, spectral searching, and chemometrics; as well as a complete line of temperature control equipment, including heated and refrigerated circulating baths, immersion coolers, and recirculating chillers. 901 Thermo Elemental, See Thermo Electron.
Technology Exchange Corp., 104 Anawan St., 2nd Floor East, Fall River, MA, USA 02721, (508)675-4977, fax: (508)675-3272, e-mail:
[email protected], Internet: txcnology. com Technology Exchange Corporation provides solutions to the analytical problems of industrial, commercial, government, and academic laboratories. Our products include: Rebuilt, refurbished optical emission and atomic absorption instrumentation; Upgrades to direct reading simultaneous spectrometers; Data collection software with report generating features; Hardware and software engineering services, and magnum series digestion systems. We provide field engineering services for most ICP and AA instrumentation and stock a full line of spare parts and consumables for the instruments we support. 225 Thar Technologies, 100 Beta Dr., Pittsburgh, PA, USA 15238, (412)967-5665, fax: (412)967-9446, e-mail:
[email protected], Internet: http://www. thartech.com As The leaders in Supercritical Fluids Thar provides instrumentation and services in the areas of SFC, SFE, and particle formation. Thar also offers cost effective components such as new syringe pumps, reciprocatinq pumps and reaction system for high pressure and supercritical applications. 1440 The Pumpworks Inc., 5508 Commerce Dr., Orlando, FL, USA 32839, (407)523-7867, fax: (407)523-1717, e-mail:swalden@thepumpworks. com, Internet: www.thepumpworks.com The PumpWorks Inc. helps meet the diverse needs for many of your laboratory pump applications ranging from Analytical Instrumentation, Research and Development, Industrial, and Process Manufacturing. Our wide selection of high quality innovative products relate to better value and product application longevity for our customers. We provide complete support which includes equipment services. 1923 The University of Akron, Dept. of Polymer Science, 170 University Ave., Akron, OH, USA 443253909, (330)972-7532, fax: (330)972-5290, e-mail:
[email protected], internet: http://www.
Thermo Finnigan, See Thermo Electron. Thermo Galactic, See Thermo Electron. Thermo Haake, See Thermo Electron. Thermo Neslab, See Thermo Electron. Thermo Nicolet, See Thermo Electron. Thermo Spectronic, See Thermo Electron. Thomson Derwent, 1725 Duke St., Suite 250, Alexandria, VA, USA 22314,1-800-DERWENT, fax: (703)519-5829, e-mail:
[email protected], Internet: http://www.derwentus.com. Thomson Derwent releases Derwent Innovations Index! A Web-based research tool providing unrivalled breath of coverage by combining value-added patent records from Derwent World Patents Index with patent citation information from Derwent Patents Citation Index. See demonstrations and ask about Derwent Analytics! Derwent Analytics is a new user-friendly and intuitive tool, channeling the power of VantaqePoint. It provides the user with a one-click method of converting value-added patent information from the Derwent World Patents Index, into manageable formats. View ISI Web of Knowledge now with Chemistry! This tool helps the chemical researcher combine the wealth of databases available through this powerful platform with a powerful chemical resource. See technology tools, especially the bibliographic management tools from ISI ResearchSoft including EndNote, Reference Manager, ProCite and WriteNote. Stop by the booth and find out about the Champagne receptions! 507 Tripos, Inc., 1699 S. Hanley, Suite 303, St. Louis, MO, USA 63144, (314)647-1099, fax: (314)6471099,
[email protected], Internet: www. tripos.com Tripos' virtual discovery laboratory enables scientists to make knowledge driven research decisions that avoid costly synthesis and testinq of chemical compounds unlikely to be effective. SYBYL computational chemistry tech-
nologies are used by scientists at major research facilities around the world to manage, analyze, and share biological and chemical information. SYBYL UNITY discovery informatics software has been ported to the Linux platform. These premiere computational chemistry applications, previously accessible only on high end UNIX workstations, are available in a PC environment, significantly reducing hardware costs for customers. Recently introduced discovery software technologies include RACHEL, desiqned to streamline combinatorial optimization by performing automated combinatorial optimization of substituents on a lead scaffold; OptDesign, to design combinatorial libraries that take into account the practical aspects of library synthesis; VolSurf, to predict ADME properties using pre-calculated models; updated Molconn-Z works with ChemEnlighten to calculate molecular descriptors based on connectivity, shape, and topology; and hint! TM and ZArTM are now part of Tripos' offerings. 1101 Universal Surface, 2331-B Crownpoint Executive Dr., Charlotte, NC, USA 28227, (704)849-7010, fax: (704)849-7015, Internet: http://www.ntmdt. com 1931 University of Southern Mississippi, SS Box 10076, Hattiesburg, MS, USA 39406, (601)2665047, fax: (601)266-5635, e-mail:
[email protected], Internet: http://www. psrc.usm.edu The Department of Polymer Science in the School of Polymers and High Performance Materials is a nationally ranked program offering the degrees of Bachelor's in Polymer Science and MS and Ph.D. in Polymer Science and Engineering. The department is housed in an 86,000 square foot modem teaching and research facility with state of the art instrumentation for polymer analysis and testing. Faculty, graduate students, and undergraduate students will be on hand to talk about available educational and research opportunities. 1919 University Science Books, 55 D Gate Five Rd., Sausalito, CA, USA 94965, (415)332-5390, fax: (415)332-5393, e-mail:
[email protected], Internet: http://www.uscibooks.com Featuring an excellent line of books and textbooks including Donald McQuarrie's newest title Mathematical Methods for Physical Scientists and Engineers, a new text by David Tannor, Introduction to Quantum Mechanics, A Time Dependent Perspective; Physical Chemistry texts by McQuarrie/Simon and by Raymond Chang; Introduction to Error Analysis by John Taylor; Inorganic Chemistry by Gary Wulfsberg; Organic Chemistry by Tom Sorrell; and more classics by Donald McQuarrie including Statistical Mechanics and Quantum Chemistry. 207 Upchurch Scientific, P.O. Box 1529, 619 Oak St., Oak Harbor, WA, USA 98277, (360)679-2528, fax: (360)679-3830, e-mail:
[email protected], Internet: www.upchurch.com The Upchurch Scientific division of Scivex is an ISO 9001 Certified manufacturer of fittings, tubing and accessories used in liquid transfer applications such as HPLC microbore, analytical and semi-prep, FIA, Mass Spec and Medical Diagnostics. We specialize in injection molding, polymer tubing extrusion and high quality machining. Our product line also includes an expanding array of components for lab on a chip and other micro and nano scale applications. i340 USDOE EM Science Program, 2525 North Freemont Ave., Idaho Falls, ID, USA 83404, (208)5269574, fax: (208)526-4366 228 US DOE, Hydrogen, Fuel Cells, and Infrastructure Technologies Program, U.S. Department of Energy, 1000 Independence Ave., SW, Washington, DC, USA 20585, 1-800-dial-DOE, fax: (202)586-4403, Internet: www.eere.energv.qov/ hydrogenandfuelcells. The Department or Energy's (DOE) Hydrogen, Fuel Cells, and Infrastructure Technologies Program focuses on overcoming the technical, economic, and institutional barriers to hydrogen and fuel cell commercialization, through its support of basic research and development and through the development of public-private partnerships and demonstrations. The program is guided by the vision of a prosperous future where energy is clean, abundant, reliable, and affordable. 1725 EXPO-17
EXPOSITION USEPA-Green Chemistry Program, 1200 Pennsylvania Ave, NW, Mail Code 7406M, Washington, DC, USA 20460, (202)564-8740, fax: (202)5648679, e-mail:
[email protected], Internet: http://www.epa.gov/qreenchemistry EPA's Green Chemistry Program fosters research, development, and implementation of innovative chemical technologies that reduce or eliminate the use or generation of hazardous substances during the design, manufacture, and use of chemical products and processes. The program's four major projects include the Presidential Green Chemistry Challenge, Green Chemistry Research, Green Chemistry Education activities, and Scientific Outreach. 1830 Vacuum Atmospheres Co., 4652 West Rosecrans Ave., Hawthorne, CA, USA 90250, (310)644-0255, fax: (310)970-0980, e-mail:
[email protected], Internet: www.vac-atm.com Vacuum Atmospheres will exhibit the new Omni Lab Stainless Steel glove box and gas purification system. The Omni Lab was designed with quality and performance at an economical price in mind. The system will maintain less than 1 ppm of Oxygen and Moisture in an inert gas. It utilizes a Put with touch screen display. System accessories include Moisture and Oxygen analyzers, freezer, mini antechamber, various Jeedthroughs and much more. We would be happy to discuss custom designs upon request. H 1401,1403 Valco Instruments, P.O. Box 55603, Houston, TX, USA 77255, (713)688-9345, fax: (713)688-3948, Internet: www.vici.com 107 Varian, Inc., 2700 Mitchell Dr., Walnut Creek, CA, USA 94598, (800)926-3000, fax: (925)945-2206, e-mail:
[email protected], Internet: www. varianinc.com Varian, Inc. offers a broad range of instrumentation and related equipment for diverse applications. We will display a comprehensive array of HPLC products, GC MS instruments and a full line of consumable sample preparation products, including solid phase extraction devices for a variety of applications. 1507,1509,1511 VEECO, 112 Robin Hill Rd., Santa Barbara, CA, USA 93117, (805)967-1400, fax: (805)967-7717, e-mail:
[email protected], Internet: www.veeco.com Veeco will be exhibiting its Digital Instruments Scanning Probe Microscopes - SPMs, including the MultiMode and the AutoProbe CP Research, as well as the MultiMode High Temperature Heater Accessory up to 250 degrees C aesiqned specifically for polymer applications. We wiff also feature Digital Instruments bcentris cantilever sensor array research tool, which enables new discoveries to be made in the developing field of chemical sensor applications. 209 Vernier Software & Technology, 13979 SW Millikan Way, Beaverton, OR, US 97005, (888)8376437, fax: (503)277-2440, e-mail:info@vernier. com, Internet: www.vernier.com Stop by the Vernier Software and Technology bootn to learn how to use our exciting LabPro interface with a Macintosh or Windows computer, a Tl graphing calculator, or a Palm Handheld. We will be demonstrating our complete line of auto ID sensors for chemistry. See our Chemistry with Computers and Chemistry with Calculators fab books. 527 Virtis, an SP Industries Co., 815 Route 208, Gardiner, NY, USA 12525, (800)431-8232, fax: (845)255-5338, e-mail:
[email protected], Internet: www.virtis.com The diverse product lines of VirTis are used in the life science, pharmaceutical, biomedical, environmental ana industrial markets. Along with research size, pilot scale, and industrial freeze dryers, we manufacture research equipment such as mechanical homogenizers, ultrasonic cell disrupters, and fermenters. This extensive line of equipment offers our customers complete flexibility for their processing needs. As an ISO 9001 registered manufacturer, our search for technical excellence includes an unwavering commitment to quality, value and service before, during and after installation. 1110,1112 Viscotek, 15600 West Hardy Rd., Houston, TX, USA 77060-3102, (281)445-5966, fax: (281)9314336, e-mail:
[email protected], Internet: www. viscotek.com Viscotek is a leading provider of comprehensive GPC SEC solutions, featuring multiple detection for the characterization of natural 1&-EXPO
and synthetic polymers and proteins. Viscotek's innovative products and technologies are backed by expert level technical service and analytical support. 1625 W.H. Freeman & Company, 41 Madison Ave., New York, NY, USA 1001, (212)576-9400, Internet: www.whfreeman.com W.H. Freeman and Company is recognized worldwide for its quality science textbool
WEDNESDAY MORNING Section A
Synchrotron-Based Analytical Techniques for Nuclear and Environmental Sciences Inorganic Surface-Solution Interactions Cosponsored with Division of Nuclear Chemistry & Technology Advances in Techniques for Analytical Characterization in Fuel Chemistry Cosponsored with Division of Fuel Chemistry
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8:30 1. SPR imaging measurements for the rapid microarray detection of nucleic acids and proteins. R. M. Corn, H. J. Lee, G. J. Wegner, E. A. Smith, T. T. Goodrich, E. Codner 9:00 2. The array biosensor for homeland defense. K. E. Sapsford, J. B. Delehanty, J. P. Golden, C. A. Rowe Taitt, L. C. Shriver-Lake, Y. S. Shubin, F. S. Ligler 9:30 3. Proteomics-based characterization of airborne spores. C. Fenselau, B. Warscheid 10:00 Intermission. 10:10 4. Raman chemical imaging for rapid, noninvasive, and reagentless biothreat detection. P. J. Treado, G. S. Vanni 10:40 5. Finding a needle in a haystack: Detection and identification of microbial contamination. L. Powers, C. Lloyd, H. Y. Mason, C. Estes, A. Duncan, B. Wade, W. Ellis Jr.
1:30 13. Force discrimination biosensor: An automated immunoassay system for the rapid detection of biological agents. C. L Cole, M. P. Malito, J. Rife, R. J. Colton, L. J. Whitman 2:00 14. Wireless microsensors for pollut ants and chemical warfare agents using nanostructured silicon. M. Sailor, T. A. Schmedake, F. Cunin, J. R. Link 2:30 15. The new logic for devices provid ing continuous, real-time in vivo chemi cal monitoring. A. W. Czarnik 3:00 Intermission. 3:10 16. High-sensitivity detection of biological warfare agents with gold nanoparticle probes. S. Maria, P. Bao, H. Mehta, S. Hagenow, J. Storhoff, V. Garimella, A. Lucas, U. Muller
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-11
TEC H H ?CL, 3:40 17. Multifunctional dendritic tethers for detection of bioterror pathogens by surface plasmon resonance. B. D. Spangler, D. A. Hyman. E. S. Tarter. C. W. Spangler 4:10 18. Electrochemical identification of bacterial spores. K. Levon, Y. Zhou, B. Yu, C. L. Tumbough II Synchrotron-Based Analytical Techniques for Nuclear and Environmental Sciences Overviews, New Developments, and Microbial Interactions Cosponsored with Division of Nuclear Chemistry & Technology MALDI and ESI Mass Spectrometry Techniques for Polymers General Papers Cosponsored with Division of Polymeric Materials: Science and Engineering
SUNDAY EVENING Section A Convention Center Hall G Analytical Poster Session J. D. Pinkston, Organizer
7:00-9:00 19. Land-lake breeze effect studies in Chicago. T. Fosco, M. Schmeling, P. Doskey, R. Kotamarthi, H. Ochsner, L. Harris 20. GC-MSD analysis of AFC emission from new building construction on the Middlebury College campus. M. D. Dagan, L. DelNegro 21. Characterization of acridine-adsorbed species on Si0 2 , (NH4)2S04, Al 2 0 3 . and MgO by fluorescence and time-resolved diffuse reflectance spectroscopy. I. Negron-Encarnacion R. Arce 22. Characterization of toxic compounds in atmospheric particulate matter in Cataho, Puerto Rico. L. S. Betancourt, O. Rosario 23. Methyl halide production in Vermont soils. M. F. Clasquin 24. Photochemical processes in UV-irradiated Arctic and Antarctic snow samples. A. M. Grannas, P. B. Shepson, T. Filley 25. Effects of nitrogen limitation on the composition of phytoplankton-derived dissolved organic matter revealed through carbohydrate analysis. A. E. Witter, D. Sharbaugh, D. A. Hutchins 26. About the content of heavy metals in some meat and dairy products. O. F. Faizullaev, O. O. Fayzullaev 27. Stepwise approach to the development of an automated, 96-well plate, protein precipitation extraction method for the determination of drug concentrations in plasma. K. D. Anderson, K. L. Hoffman, B. Wan, G. M. Smith 28. Supercritical C0 2 and high-pressure water extraction of bioactive compounds in St. John's wort. M. Mannila, C. M. Wai 29. Investigation of alcohol dehydration by a cobalt(ll) sulfate-promoted ^-alumina catalyst inside a gas chromatograph injection port. P. J. Skrdla, R. T. Robertson
12-TECH
30. Direct injection of water for GC analysis of trihaloforms using an economical atomic emission detection system. G. W. Rice, T. K. Chen 31. Chemical detection and identification techniques for exobiology flight experi ments. D. R. Kojiro, V. A. Sheverev, N. A. Khromov, N. Takeuchi, R. M. Stimac. W. J. Kaye 32. Systematic approach in GC analysis of organic compounds. N. Q. Mukhamadiev, S M. Sayitkulov. I. M. Ergashev, Q. Khalilov 33. Gas chromatographic study of catalytic steam-phase hydration of acetylene. N. Fayzullaev 34. Study of the fatty-acid composition of fruit stone oils in dependence on thermal processing by gas chromatography. S. M. Sayitkulov, N. Q. Mukhamadiev. M. Khamrakulova, D. Kholmurodova 35. Using a dynamic thermal system to determine what (organic) components are in complex soil samples using Taguchi gas sensors. E. Serago, D. R. Benner 36. Liquid-liquid extraction and GC-MS analysis for acidic drugs. P. K. Yuen 37. Separation and determination of inor ganic and hydroxymethanesulfonate anions in atmospheric liquids by ion-pair HPLC. Y. Zuo. H. Chen 38. Improvements to generic reverse-phase HPLC methods leading to lower cycle times, greater resolution, and reduced mobile-phase consumption. W. M. Barker, B. Martinez-Teipel. R. E. Dolle 39. 2-D stationary phases for HPLC. X. Liu, E. A. Lowe 40. Indirect fluorescence detection of aro matic compounds via a shielding effect on the UV-photolysis of 2-phenylbenzimidazole-5-sulfonic acid. W. Zhang, N. D. Danielson 41. The study of the mechanism of mixedmode retention of a fluorescent dye by reversed-phase liquid chromatography. S. R. Anthony, M. J. Wirth 42. Fluorescence HPLC assay for chloroquine, AQ-13, and their metabolites. H. Deng. H. Liu. O. A. Koita, D. J. Krogstad 43. Analysis of diet pills: Poisons or cures?! G. Zoorob, C. Magee, M. Bingham 44. Determination of enantiomeric excess using the UV-CD and the HPLC-CD methods. L. Chen, Y. Zhao, F. Gao, M. Garland 45. Automated chiral method development. G. W. Yanik 46. Analysis of L-arginine and asymmetrical dimethylarginine concentratrions in plasma by high-performance liquid chromatography. D. K. Potter, R. Hyslop 47. Determination of binding constants between π-delocalized lymphangitic dyes and an anticancer agent by cation exchange chromatography. B. Ham, R. B. Cole 48. Liquid-liquid extraction for quantification of theobromine. P. K. Yuen 49. Analysis of annonaceous extract and preparation of liposomal membrane using phosphatidylcholine. M. Johnson. L. Styger, R. Warren, H. Shimada 50. Determination of the effects of 6-thiopurine on the in vivo conjugation of biliru bin using reverse-phase high-perfor mance liquid chromatography. W. W. Bamhart, R. Hyslop 51. Flow-based, reduced-volume column system for thalassemia screening. S. K. Hartwell, B. Srisawang, P. Kongtawelert, J. Jakmunee. K. Grudpan 52. Simple flow-injection, bead injection system for trace ion determination. S. K. Hartwell, K. Jitmanee, P. Ampan, S. Lapanantnoppakhun, P. Sooksamiti, S. Jayavasti, J. Jakmunee, J. Ruzicka, G. Christian, K. Grudpan
PROGRAM 53. Determination of thiols in plant tissue: Comparison of precolumn derivatization with SBD-F and postcolumn derivatiza tion with Ellman reagent. J. Su, W. Zhang, Y. Cai 54. Elucidation of the degradation pathways of a model lactone compound in propy lene glycol. R. T. Robertson, P. Spence, F. Liu. C. Pan, J. Etse 55. Investigation of the microstructure of acetonitrile/water mixtures using infrared spectroscopy and chemometrics. J. E. Burke, E. Bezemer, S. C. Rutan 56. Stability and performance of HPLC columns under high-temperature condi tions. D. Felix, S. J. Marin, B. Jones 57. Using temperature programming to replace solvent gradients in HPLC. W. D. Felix, S. J. Marin. B. Jones 58. Development of an analytical method for the determination of enzymatic activity of UDP-glucose dehydrogenase and inhibitory activity of synthesized 6-thiopurine analogs. R. J. Rafferty, R. Hyslop 59. Development of a rapid high-perfor mance liquid chromatography-mass spectrometry assay for the inhibition of thermolysin by enantio-enriched ΑΡΤΑ analogs. C. M. Thompson, K. C. Fussell, Τ. Μ. Voelker. P. Tongcharoensirikul, A. I. Suarez 60. A new method for assessing apurinic/ apyrimidimic lesions in DNA. K. P. Roberts, J. A. Sobrino, L. B. Mason, R. J. Turesky 61. Detection of 4-aminobiphenyl adducts in DNA from bladder cancer patients by LC-ESI-MS. B. Zayas. W. G. Stillwell, L. Trudel, Y. Xiang, P. L. Skipper, M. C. Yu, S. Tannenbaum, G. Wogan 62. Sensitive detection of DNA adduct for HPLC/LIF with fluorescence derivatiza tion. H. G. Jang, J. S. Wishinok, C. Ozbal, S. R. Tannenbaum, G. N. Wogan 63. HPLC-MS-MS of enterostatin in human CSF and plasma. Y. Liu, C. Prasad 64. Open-access mass spectrometry tech nologies for enabling discovery. D. Masters-Moore, J. P. Doom 65. In vivo determination of biomarkers for oxidative stress. G. Luta, W. J. Goux. E. D. Moore, B. McAnalley, S. Boyd 66. Comparative study of ligustilide in different parts of Radix Angelicae sinen sis by high-performance liquid chroma tography. S. Wei, M. To, F. Chau 67. A fast method for purification and char acterization of thiols induced under arsenic exposure in an arsenic hyperaccumulator-Chinese Brake fern. W. Zhang, Y. Cai 68. HPLC-UV-MS separation and identifica tion of chlorinated polycyclic aromatic hydrocarbons. S. Xie, Y. Peng, M. Chen, R. Huang, L. Zheng 69. Characterization of structured triacylglycerols by silver-ion HPLC. R. O. Adlof, G. R List 70. Analysis of peroxidation products of polyunsaturated phospholipids with silver-ion coordinated LC-MS. Z. Pan, N. A. Porter 71. Characterization of a novel class of peroxides from autoxidation mixture of polyunsaturated lipids by mass spec trometry. H. Yin, J. D. Morrow, N. A. Porter 72. Solid-phase mini-extraction coupled to nano-electrospray ionization mass spectrometry. L. Qi, N. D. Danielson 73. Determination of antibiotics in surface and groundwater due to poultry litter applications. H. M. Dion. P. M. Bertsch
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
74. Analytical separations using molecular micelles in open-tubular capillary electrochromatography: Morphologic elucida tion of capillaries modified by polyelectrolyte multilayers. C. P. Kapnissi, M. Lowry, B. M. Cedillo, R. A. Agbaria, L Geng. I. Warner 75. Separation of phenols and benzodiaz epines using poly(sodium undecylenic sulfate) in open-tubular capillary electrochromatography. M. W. Kamande, C. P. Kapnissi, X. Zhu, C. Akbay, R. A. Agbaria, I. M. Warner 76. Optimizing differential binding in surfac tant affinity capillary electrophoresis. B. T. Cooper, R. D. Sanzgiri, T. A. McKinnon, A. M. Hamper 77. Use of capillary electrophoresis with cyclodextrin additives for the separation of LSD. LAMPA. and iso-LSD. T. C. Werner, J. M. lannacone 78. Novel, single-isomer, chiral resolving agent, hexakis(2,3-di-0-acetyl-6-0sulfo)-u-cyclodextrin, for capillary electro phoresis. S. Li, G. Vigh 79. Influence of polydispersity of sodium undecenoyl-L-leucinate polymeric surfac tant on enantioselectivity in micellar electrokinetic chromatography. J. Tarus, A. Numan. R. A. Agbaria, I. Warner 80. Study of ethidium bromide effect on dsDNA separation by capillary zone electrophoresis and laser light-scattering. D. Liang. B Chu 81. Detection for capillary electrophoresis using a laser pointer to provide excita tion for laser-induced fluorescence. J. C. Copeland, S. J. Lillard, S. Villa, J. L. Zabzdyr 82. Separation of myoglobin tryptic peptides by slab gel electrophoresis in liquidcrystalline polymers (pluronic gels). M. A. AI Sayah. R. L. Rill 83. Real-time analysis of ammonia and volatile organic compounds from cooking meat: Application of the SIFT-MS tech nique. J. M. Van Doren, P. Spanel, D. Smith 84. Pure-component mass spectrum recon struction with two-band target entropy minimization: Application to mass spec tral data. H. Zhang, Y. Zeng, P. Wu, M. Garland 85. Analysis of emissions from fluidized bed pyrolysis of biomass. A. M. Nosbisch, C. D. Hanson 86. Time-of-flight mass spectrometry using conductive polymers as novel ion optical electrodes. M. F. Appel. W. E. van der Veer, T. Benter 87. Internal energy of MALDI-generated ions. I. Marginean. G. Luo, L. Ye, A. Vertes 88. Laser pulse-length dependence of ionization processes in MALDI mass spectrometry Y. Chen, A. Vertes 89. Two-laser IR/UV matrix-assisted laser desorption ionization. M. W. Little, J. Kim, Κ. Κ. Murray 90. Characterization of IR-DIOS substrates using FTIR-ATR. J. L. Laboy, J. Kim, Κ. Κ. Murray 91. Modifications to a commercial mass spectrometer for IR-DIOS applications. D. J. Rousell, S. M. Dutta, K. K. Murray 92. Influence of sequence and cation choice on the dissociation of gas-phase peptides M. J. Van Stipdonk, E. R. Talaty, V. Anbalagan, A. T. M. Silva, R. Ahrens 93. Investigation of microbial cell lysis using matrix-assisted laser desorption ioniza tion time-of-flight mass spectrometry. J. Dally, F. Oluboyede, P. Patel, C. Bentzley, J. Aon 94. MALDI-TOF detection of spatial addressed phospholipid bilayers. H. Mao. J. Koomen, T. Yang. D. H. Russell. P. Cremer 95. A novel approach to oligosaccharide analysis using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Y. Cai, Y. Jiang, R. B. Cole
ANYL/TECHNICAL PROGRAM
96. Electrochemical methods in the research of electrocolored properties of the film coverings on bases of oxides of transition metals. S. M. Vasina, V. V. Abramova, S. A. Shirova 97. Soluble conducting polymers: Molecu lar-weight determination by vapor pres sure osmometry. S. Oztemiz, E. Bengu, H. B. Mark Jr., S. J. Clarson 98. Electrochemically assisted solid-phase micro-extraction using L-dopa imprinted conducting polymer electrode fibers: Structural aspects. C. S. Schmiesing, R. A. LaRue, Ε. Ε. Brooks, A. Galal, K. R. Temsamani, H. B. Mark Jr. 99. Electochemical studies of thermoresponsive polymeric gels modified with gold colloidal particles. E. Kazimierska, M. Ciszkowska 100. Electrochemical generation of hydro gen peroxide as oxidant for alkene oxidation in aqueous medium. K. P. Ho, K. Y. Wong, T. H. Chan 101. Employing quaternary ammonium salt-extracted Nation and poly(methylene green) in ethanol/oxygen biofuel cells. N. L. Akers, S. D. Minteer 102. Dynamic behaviors of redox mediators and their neighboring hydrophobic lipid layers as important factors for the effec tive microbial fuel cell operation. S. Jung, Y. Choi 103. Electrochemical effects of surfacemodified glass microspheres on polysty rene sulfonate modified electrodes. C. M. Moore, N. J. Torrence, S. D. Minteer 104. Factors governing selectivity of ions partitioned into high-surface-area carbon fibers. A. J. Gotch, J. G. Smith, R. S. Kelly, T. Kuwana 105. Sol-gel encapsulated curcumin cast on a graphite electrode electroxidation. A. D. Adeyemo, M. O. Iwunze 106. Mesoporous platinum for nonenzymatic glucose detection by amperometry and impedance method. S. Park, T. D. Chung, H. C. Kim 107. Comparison of electrochemical detec tion methods for drugs in a blood substi tute. R. E. Barlag, H. B. Halsall, W. R. Heineman 108. Characterization of imazaquin by cyclic voltammetry. H. Z. Msimanga, N. McConnell 109. Catalytic oxidation of NADH at 3,4dihydroxybenzaldehyde modified car bon-paste electrodes. D. J. Weiss 110. Microelectrodes in bead-based sand wich immunoassay detection. N. J. Ronkainen-Matsuno, S. Farrell, H. B. Halsall, W. R. Heineman 111. Electrochemistry of europium(ll/lll) in molten ZrF4BaF2LaF3AIF3NaF and conductivity of vitrified ZBLAN-Eu2+/3+. S. W. Kiley, D. Rauser, M. Plesha, R. H. Terrill 112. Synthesis, characterization, and elec trochemistry of hydrophobic roomtemperature ionic liquids. B. D. Fitchett, T. Knepp, J. C. Conboy 113. Interaction of cytochrome c on a thiol-phosphonate self-assembled mono layer on gold. C. S. Haslag, E. F. Bowden, C. K. Njue 114. Reactive ion-scattering spectrometry: An efficient tool to probe the properties of mixed SAM's. R. Selvan, D. L. Smith, F. Fernandez, Z. Qi, X. Yang, V. H. Wysocki 115. Defined cellular microenvironments for bioassays through surface engineering. J. Lahann, C. Hodneland, A. Raphel, J. Beecher, S. Campbell, G. Kirk 116. Direct photobiotin modification of glass surfaces for antibody patterning applica tions. P. Pantano, S. Chin 117. Surface characterization of polymer and resin in positively charged filters. B. Kang, N. Kattamuri, J. Shawon, C. Sung, J. Lee, J. Shin, S. Park 118. Solvation behavior of micelle-encased HiPco carbon nanotubes in binary sol vents. B. Benedict, A. Awichi, W. Zhao
119. 2-D IR correlation spectroscopy for molecular interactions involving glucose anomers and fluorinated single-walled carbon nanotubes. E. Tee, C. Song, W. Zhao 120. Preparation and application of glycoluminescent CdSe QDs nanospheres. Y. Chen, Z. Rosenzweig 121. Electrochemical sensors based on conductive nanomaterials. Y. Lin, J. Liu, J. Wang 122. Single-molecule electrophoresis in microfabricated glass channels. B. T. Cooper, J. M. Emory, C. M. Carlin 123. Design and development of a centrifu gal microfluidics platform for proteinbased assays. L. G. Puckett, E. Dikici, J. Zoval, M. J. Madou, L. G. Bâchas, S. Daunert 124. Fiber-loop ring-down: Absorption spectroscopy on picoliter samples. H. Loock, Z. Tong, A. Wright, M. Jakubinek 125. Sensor for selective determination of ethanol vapors in gases by thermocatalysis. E. Abdurakhmanov, K. Jalolov 126. Novel optical fiber-based gauge for measuring transient pressures. J. E. Monat, J. R. Carney, G. I. Pangilinan 127. Kinetic behavior of long-period grating fiber-optic sensors. S. W. Buckner, J. Widera, J. R. Gord, C. E. Bunker, G. E. Pacey, V. R. Katta 128. Synthesis, characterization, and application of lipobead-based nanosensors for chloride ion transport measurements in epithelial cells. A. Ma, Z. Rosenzweig 129. Lipobead-based sensors for extracellular measurements in rat cortical neurons. T. H. Nguyen, L. Chen, M. A. DeCoster, N. G. Bazan, Z. Rosenzweig 130. Synthesis of FRET-trap lipobeads for carbohydrate recognition. G. Dumitrascu, Z. Rosenzweig 131. Stimuli-responsive hydrogels with integrated protein recognition for sensing applications. J. D. Ehrick, S. K. Deo, L. G. Bâchas, S. Daunert 132. Chiral surface imprinting: Integrated recognition and transduction. Y. Zhou, B. Yu, K. Levon 133. Molecularly imprinted polymers for organic vapor detection with a quartz crystal microbalance. Y. Fu, Η. Ο. Finklea 134. Surface modification of polymer sub strates and immobilization of antibodies for fabrication of biosensors. S. Wei, R. L. McCarley 135. Biosensing based on layer-by-layer protein architectures on carbon nano tubes. J. S. Lenihan, V. Gavalas, J. Wang, R. Andrews, L. Bâchas 136. Evaluation of environmental contaminants using immunochemical sensors. M. J. Hamill, C. D. Crawley 137. Development of a luminescencebased biosensor for the determination of drug resistance levels in yeast strains. H. L Pang, C. H. Yeung, L M. C. Chow, Κ. Υ. Wong 138. Determination of hydrozin and sym metric dimethylhydrozin of thermocatalytic sensors. M. Sattarova, I. Yunusova, E. Abdurakhmonov 139. Selective thermocatalytic sensors for monitoring of H2S and HF in air. M. Boboeva, E. Abdurakhmonov, E. Ruziev 140. Biosensor for direct determination of organophosphorus pesticides. Y. Lei, P. Mulchandani, W. Chen, J. Wang, A. Mulchandani
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
141. Biosensor for thiol detection and potential application to chemical warfare agent VX sensing. K. A. Joshi, A. Mulchandani, W. Chen, J. W. Wang 142. Reagentless electrochemical biosen sors based on protein scaffolds. S. A. Trammell, S. D. Jhaveri, J. M. Mauro, H. M. Goldston, C. L. Schauer, L. M. Tender 143. Surface functionalization of indium tin oxide and immobilization of DNA and proteins for fabrication of electrically conductive microarrays. J. Zeng, S. H. Park, M. Chacko, U. J. Krull 144. Whole-cell based assay for the highthroughput screening of calmodulin antagonists. E. Dikici, S. K. Deo, S. Daunert 145. Design and development of heavy metal selective chem-FET sensors using conductive, chelating polymers. R. L. Meyer, D. D. Russell, J. Scaggs, W. Knowlton, M. Hill, W. Bauer 146. Chem-FET sensors for heavy metals. J. M. Scaggs, D. D. Russell, W. Knowlton, W. Bauer 147. Synthesis and stereochemical varia tions of soluble MEH-PPV. B. P. Parekh, T. R. Lee, R. Krishnamoorti, S. S. Newaz 148. Monitoring the effect of natural organic matter on membrane structure by 3 Ρ NMR. R. L. Cook, N. Elayan, Z. Zhou 149. Quantitation of neotame polymorphs in formulations using 13C solid-state NMR spectroscopy. C. N. Jones, E. J. Munson, T. J. Offerdahl 150. Method development of capillary isotachophoresis coupled to on-line microcoil NMR. A. Carr, V. Almeida, C. K. Larive 151. Carboxymethylated cyclodextrins and their lanthanide complexes as chiral NMR solvating agents. S. E. Aniagyei, T. J. Wenzel 152. Calix[4]arenes and calix[4]resorcarenes as chiral NMR solvating agents. J. D. Wilcox, T. J. Wenzel 153. Crown ethers and their ytterbium(lll) complexes as chiral NMR solvating agents. B. E. Freeman, T. J. Wenzel 154. Investigation of fluorescence quench ing behavior within room-temperature ionic liquid-based solvent systems. K. A. Fletcher, S. Pandey 155. Fluorescence anisotropy of select probes solubilized within multicomponent room-temperature ionic liquid-based solvent systems. K. A. Fletcher, S. Pandey 156. Determination of the formation of self-assembled molecularly ordered media within select room-temperature ionic liquids. K. A. Fletcher, S. Pandey 157. Characterization and thermodynamic investigation of the enantioselective binding of binaphthyl phosphate with neutral cyclodextrins. Y. Xu, M. E. McCarroll 158. Development of fluorescence anisot ropy as a tool to study chiral recognition. M. E. McCarroll, Y. Xu, J. Stewart 159. Evidence of formation of aqueous ternary Fe(ll)-cyclodextrin-guest com plexes from fluorescence techniques. W. Zheng, M. A. Tarr 160. Development of ultrasensitive high speed biological assays based on the detection of single fluorescent molecules in a 2-D flow. C. W. Hollars, T. R. Huser, C. E. Talley, O. Bakajin, B. C. Olsan, S. M. Lane 161. Time-resolved measurements of intermediates in photoinduced reactions with millisecond resolution using a nanoelectrospray emitter as a photo chemical cell. W. Ding, K. A. Johnson, C. Kutal, I. J. Amster 162. DNA aptamer-based bioanalysis of immunoglobulin Ε using steady-state and time-resolved fluorescence polariza tion anisotropy. G. Gokulrangan, J. Unruh, D. Holub, B. Ingram, C. K. Johnson, G. S. Wilson
163. Expressed protein ligation and FRET to analyze protein oligomerization states. K. A. Scheibner, Z. Zhang, P. Cole 164. Fluorescence-based sensing of fluorene using a molecularly imprinted sol-gel material. P. L. Edmiston, J. A. Lloyd, C. A. Carlson 165. Synthesis and characterization of polymer monolayers using imbedded chromophores. R. M. Bell III, G. J. Blanchard 166. Characterization and spectroscopy of isomerizable adlayer constituents. A. A. Blevins, G. J. Blanchard 167. Investigation of indicators in aerogels and xerogels. R. L. Wolfe, Y. Briones, S. P. Anane, M. K. Carroll, B. M. Gauthier, S. Bakrania, A. M. Anderson 168. Synthesis and evaluation of fluores cent indicators for sodium ions. K. R. Gee, V. V. Martin, A. Rothe, Z. Diwu, R. P. Haugland 169. Determination of drugs with closely overlapping spectra by room-tempera ture phosphorimetry. E. M. Rekharsky, A. G. Borzenko, T. V. Polenova, M. V. Rekharsky 170. Determination of catalase activity in soils by flow-injection chemiluminescence methods. W. Liu, W. Yang 171. Assessing the practicality of ATR-FTIR spectroscopy in characterizing multistep transformations of polypropylene sur faces and subsurfaces: Utility and time savings realized. A. Taralp, M. Kolodzie 172. Using nanostructured MCM silica and hydrogen bonding to calculate available surface area on conventional silicas. M. C. Schalnat, R. K. Gilpin 173. The application of diffuse reflectance infrared Fourier transform spectroscopy for identification of potential diagenesis and crystallinity changes in teeth. E. F. Greene, S. Tauch, E. Webb, D. Amarasiriwardena 174. Probing microstructure of urea-methanol mixtures by 2-D IR correlation spec troscopy. K. Neff, E. Tee, W. Zhao 175. Convenient identification of aqueous H 2 0 2 concentration by Raman spectros copy. L. Haiqiang, L. Huamin, Y. Youzhu, W. Huilin 176. Spectroscopy with surface plasmons. M. R. Zangeneh, R. H. Terrill 177. Application of the optical-beam deflec tion method to the study of a chemical reaction occurring at a single particle. X.Wu 178. Investigation of biomolecular second ary structure at interfaces using counterpropagating second harmonic genera tion. M. A. Kriech, J. C. Conboy 179. Analysis of protein/DNA complexes by X-ray crystallography. S. L. Hovde, J. H. Geiger 180. Predicting XPS binding energies in polymers by AM1 quantum chemical formalism with core-potential model. E. A. Hoffmann, L. S. Korugic-Karasz 181. Analysis of cyanohydrins using sodium borohydride-facilitated conversion to cyanide. M. K. Ogawa, Z. Z. Wu 182. Development of a rapid counting technique for quantification of virus particles. C. Stoffel, M. O. McCabe, K. L. Rowlen 183. Transformation of retinyl palmitate by exposure to UV light. L. Wilcox, D. T. C. Yang 184. Band-target entropy minimization: Novel approach for pattern recognition in chemical spectroscopy. E. Widjaja, M. V. Garland 185. Confidence envelopes and surfaces for multilinear fits in analytical chemistry. P. J. Ogren, I. Kelly 186. Surface-renewal theory for mass transfer coefficient using infinite-order partial differential equation in order to account for non-Fickian diffusion. K. R. Sharma
TECH-13
TECHNICAL PROGRAM 187. Temperature dependence of the retention of alkanes and primary and secondary alkanols in a dioctylether phase. L Sun, C. D. Wick, J. I. Siepmann, M. R. Schure 188. Tensiometry studies on the solution properties of an amyloid aggregation inhibitor. K. A. Rader, J. P. Aucoin, R. P. Hammer, R. L. McCarley 189. Titrimetrical determination of bismuth. O. F. Faizullaev, O. O. Fayzullaev 190. Spectroscopic study of reduction reaction of nitro-blue of titrazole in presence of superoxiddismutaze and CoP. R. V. Toshmatova 191. New analytical science course materials with a workplace focus. J. Kenkel
10:35 202. Flow field-flow fractionationinductively coupled plasma-mass spec trometry: A resourceful method for size-based speciation and identification of trace metals complexed to humic substances and colloidal sediments. D. Amarasiriwardena, A. Sinpinyanond. R. M. Barnes 11:00 203. Investigation of dissolved organic matter conformation/aggregation using flow field-flow fractionation. M. J. M. Wells 11:25 204. Analysis of whole bacterial cells by flow field-flow fractionation and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. S. K. R. Williams, H. Lee, K. L. Wahl, Ν. Β. Valentine
MONDAY MORNING Section A Convention Center Room 384 Present and Future Technologies in Chemical Instrumentation Cosponsored with Division of Physical Chemistry M. B. Denton, Organizer 8:30 Introductory Remarks. 8:35 192. Cavity-enhanced absorption spectroscopies for probing liquids and interfaces. R. N. Zare 9:05 193. Separation science and the new millennium. F. E. Régnier 9:35 Intermission. 9:45 194. Electrochemical multiplexed measurements in biological systems. R. M. Wightman, M. A. Heien, J. Cheer 10:15 195. Present and future technologies in mass spectrometry. R. G. Cooks, Z. Ouyang 10:45 196. "Lighting up" NMR and MRI. A. Pines Section Β Convention Center Room 383 Macromolecules to Bioparticles: Analyses with Field-Flow Fractionation Cosponsored with Division of Polymeric Materials: Science and Engineering, and Division of Polymer Chemistry K. R. Williams, Organizer 8:30 197. Use of quadrupole magnetic fields for separation of biological cells. P. S. Williams, L. R. Moore, D. Leigh, M. Zborowski 8:55 198. Magnetophoretic-dielectrophoretic field-flow fractionation. P. C. Gascoyne, C. Das, J. Vykoukal, R. Weinstein, A. Gandini, D. Parks, R. Sawh 9:20 199. Novel techniques and instru ments for field-flow fractionation of biological materials. Β. Κ. Gale 9:45 200. Sedimentation field-flow frac tionation in the characterization of bioactive nanoparticles. Κ. Η. Fromell, K. D. Caldwell 10:10 201. Size and mass distributions of pharmaceutical proteins by fFALS. G. Cauchon
14-TECH
Evaluation of Column Performance in Preparative Chromatography Cosponsored with Division of Biochemical Technology The Chemistry and Law of Driving-While-lntoxicated Prosecution Part I Cosponsored with Division of Chemistry and the Law Undergraduate Research Poster Session: Analytical Chemistry Cosponsored with Division of Chemical Education MALDI and ESI Mass Spectrometry Techniques for Polymers Polymer Chemistry Cosponsored with Division of Polymeric Materials: Science and Engineering
MONDAY AFTERNOON Section A Convention Center Room 384 Encouraging Disadvantaged Students into Careers in the Chemical Sciences: Symposium in Honor of Isiah M. Warner Cosponsored with Division of Business Development and Management, Division of Chemical Education, Women Chemists Committee, and Younger Chemists Committee J. W. Robinson, Presiding 1:30 Introductory Remarks. 1:40 205. Novel molecular studies of chiral recognition by use of fluorescence methods. B. C. Valle, R. A. Agbaria, I. Warner 2:00 206. Squeezing blood from a turnip: Using multidimensional acquisition and analysis to resolve the fluorescence of multistate microenvironmental probes. S. L. Neal, B. A. Rowe 2:20 207. Chemical probes for measunng hydroxyl radical reaction with mem branes. C. A. Fortier, M. A. Tarr 2:40 208. Fun with G-quartets. L. B. McGown 3:00 209. Characterization of photocycloaddition products in the cyclobutane family using mass spectrometry and nuclear magnetic resonance. A. M. Powe, O. Marcq, N. M. Roscher 3:20 210. How research universities might meet the challenge of drawing upon a larger graduate student population pool. R. N. Zare 3:40 211. From video fluorometry to electroinjection analysis. G. D. Christian 4:00 212. Near-infrared surface-enhanced Raman-scattering mediated identification of single, optically trapped, bacterial spores. T. A. Alexander, J. B. Gillespie, P. Pellegrino 4:20 213. Where urbanization meets the environment: Regional monitoring of the southern California marine ecosystem. S. M. Mathison
4:40 214. Award Address (ACS Award for Encouraging Disadvantaged Stu dents into Careers in the Chemical Sciences, sponsored by Camille and Henry Dreyfus Foundation, Inc). Mentor ing: A novel method for knocking down brick walls. I. M. Warner Section Β Convention Center Room 383 Analytical Chemistry Workforce of the 21 st Century Cosponsored with Division of Chemical Education B. Chase and J. D. Pinkston, Organizers 1:30 Introductory Remarks. 1:35 215. Analytical chemistry careers: Analyze this? M. W. Jordan 2:05 216. Problem-based learning for analytical chemists of the 21st century: The Materials Characterization Project at the University of Arizona. J. E. Pemberton, N. R. Armstrong, T. D. Sims, D. R. Smith 2:35 217. Industrial demand for doctoral chemists: A large-industry perspective. R. Webb 3:05 Intermission. 3:15 218. Integrative Graduate Education & Research Training: A new paradigm for multidisciplinary education. L. G. Bâchas 3:45 219. Knowledge, skills, and abilities of the 21st-century government analytical chemist. W. F. Koch 4:15 Panel Discussion. Microscale Biosensors for Environmental Monitoring Cosponsored with AEESP, and Division of Environmental Chemistry Novel Bioanalyses Using Lab-on-a-Chip Technologies Cosponsored with Division of Biochemical Technology Synchrotron-Based Analytical Techniques for Nuclear and Environmental Sciences Characterization Cosponsored with Division of Nuclear Chemistry & Technology Advances in Chromatography Cosponsored with Division of Biochemical Technology Analytical Chemistry in Nuclear Technology Developments in Nuclear Chemistry and Counting Methods Cosponsored with Division of Nuclear Chemistry & Technology The Chemistry and Law of Driving-While-Intoxicated Prosecution Part II Cosponsored with Division of Chemistry and the Law MALDI and ESI Mass Spectrometry Techniques for Polymers Degradation Cosponsored with Division of Polymeric Materials: Science and Engineering MONDAY EVENING Section A
TUESDAY MORNING Section A Convention Center Room 384 Fundamentals of Electrospray Ionization G. J. Van Berkel, Presiding 8:30 Introductory Remarks. 8:35 220. Electrohydrodynamics: Whence and whither. J. B. Fenn 9:15 221. The electrochemistry of electrospray. G. J. Van Berkel 9:45 222. Measurement of potential gradients near the electrospray capillary exit. Y. Li, B. Pozniak, R. B. Cole 10:15 223. Nanoelectrospray using polyaniline-coated emitters. T. D. Wood, P. M. Bigwarfe Jr., D. R. Smith, T. P. White 10:45 224. Orthogonal control systems for electrospray ionization. G. A. Valaskovic, J. P. Murphy III, M. S. Lee 11:15 225. Solute accounting in the system that is a single droplet with net charge. G. R. Agnes 11:45 226. Evidence for droplet heterogeneity in electrospray mass spectrometry. K. D. Cook, E. J. Portelius, B. S. Prebyl, S. Zhou Section Β Convention Center Room 383 Instrument Miniaturization for Homeland Defense: Progress and Challenges R. J. Cotter, Organizer 8:30 Introductory Remarks. 8:35 227. Micromachined ion mobility spectrometers for detection of chemical weapons in airborne vapors. G. A. Eiceman, E. Krylov, N. Krylova 9:05 228. Miniature cylindrical ion-trap mass spectrometers for detection of chemical warfare agents. L. S. Riter, B. C. Laughlin, A. Guymon, G. Patterson, R. G. Cooks 9:35 229. Field applications of time-offlight mass spectrometers for chemical and biological detection. W. A. Bryden 10:05 230. Development of a miniature personal biodetector. H. C. Ed berg, V. B. Mikheev, M. L. Luna, P. Irving 10:35 231. A miniature MALDI-time-offlight mass spectrometer using nonlinear ion optics for improved performance. B. D. Gardner. R. J. Cotter 11:05 232. Microscale gas-phase analy sis. W. B. Whitten, J. Xu, J. Moxom, P. T. A. Reilly, J. M. Ramsey NMR Spectroscopy of Polymers New or Improved Methodologies Cosponsored with Division of Polymer Chemistry Analytical Chemistry in Nuclear Technology Developments in Waste-Tank Separation and High-Level Sludge Analytical Methods Cosponsored with Division of Nuclear Chemistry & Technology
Convention Center Hall G Sci-Mix Poster Session A. A. Blevins, Presiding J. D. Pinkston, Organizer 8:00-10:00 22, 28, 31, 73, 77, 86, 88, 107,112, 114115, 121-124, 129, 137, 141, 144, 148, 150, 153,156, 160-161, 166, 173, 176, 179. See previous listings.
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
ANYUTECHNICAL PROGRAM
TUESDAY AFTERNOON
WEDNESDAY MORNING
WEDNESDAY AFTERNOON
Section A
Section A
Section A
Convention Center Room 384
Convention Center Room 384
Convention Center Room 384
Fundamentals of Electrospray Ionization
Joint Symposium in Honor of Richard D. Smith (ACS Award in Analytical Chemistry) and of Jesse L. Beauchamp (Field and Franklin Award)
Joint Symposium in Honor of Richard D. Smith (ACS Award in Analytical Chemistry) and of Jesse L. Beauchamp (Field and Franklin Award)
D. W. Koppenaal, Organizer, Presiding
P. B. Armentrout, Organizer,
R. G. Cooks and P. B. Armentrout, Organizers
R. G. Cooks and D. W. Koppenaal, Organizers
8:30 Introductory Remarks. 8:35 246. Guided ion beams and thermodynamics. P. B. Armentrout 9:05 247. Kinetics and dynamics of surface-induced dissociation of complex ions. J. Futrell, J. Laskin, A. K. Shukla 9:35 248. High-throughput ESI-FTICR in the biotech arena: From drug discovery to bacterial taxonomy. S. A. Hofstadler 10:05 249. Primary and higher-order structure in proteins and protein assemblies. A. G. Marshall, G. A. Blakney, M. J. Chalmers, M. R. Emmett, S. J. Gaskell, C. L. Hendrickson, T. T. Lam, J. K. Lanman, H. Li, H. Mischak, P. J. Prevelige Jr., J. P. Quinn, F. Xu 10:35 250. Conformation and hydration of peptides. M. T. Bowers, T. Wyttenbach, D. Liu, S. Bernstein, E. Baker 11:05 251. Award Address (ACS Award in Analytical Chemistry). Analyzing complex biological systems: The roles of separations and mass spectrometry. R. D. Smith
1:30 Introductory Remarks. 1:35 259. Award Address (Frank H. Field and Joe L. Franklin Award for Outstanding Achievement in Mass Spectrometry, sponsored by Bruker Daltonics, Inc). Adventures with mass spectrometry: From cosmochemistry to proteomics. J. L. Beauchamp 2:20 260. Homochiral clustering of serine: Implications for homochirogenesis. R. G. Cooks, S. C. Nanita Sr., Z. Takats, V. Vekey, F. C. Gozzo, M. N. Eberlin 2:50 261. Anhydrous protein and peptide ions: Exploiting structural differences in the gas phase for high-throughput pro teomics analysis. D. E. Clemmer, S. Myung, Y. J. Lee, E. Badman 3:20 262. Gas-phase ion/ion reactions of proteins and oligonucleotides. S. A. McLuckey, P. A. Chrisman, K. A. Newton, E. Badman, J. Wu, J. M. Wells, M. He 3:50 263. Large proteins and their com plexes: A view provided by mass spec trometry. J. A. Loo 4:20 264. Ion source focusing for sensitiv ity enhancement in mass spectrometry. B. Yue, L. Zhou, E. D. Lee, D. V. Deardon, A. Rockwood, M. L. Lee
Environmental Management Science Program Symposium Remedial Science and Technology for Subsurface Contamination Cosponsored with Division of Environmental Chemistry
WEDNESDAY EVENING
G. J. Van Berkel, Organizer 1:30 233. Predicting responsiveness of small molecules to analysis with positive and negative ion ESI. N. B. Cech, T. Henriksen 2:00 234. Structure, morphology, and dynamics of charged nanodroplets. A. Vertes, I. Marginean, V. Znamenskiy 2:30 235. Critical throughput requirements for ESI. C. G. Enke 3:00 236. Electrospray and lop-down" analysis of complex protein mixtures. S. A. McLuckey, P. Pan, R. Amunugama 3:30 237. Improvements in the accumulation, injection, analysis, and dissociation of electrosprayed ions. A. G. Marshall, M. J. Chalmers, H. J. Cooper, M. R. Emmett, K. Hàkansson, C. L. Hendrickson, M. A. McFariand, J. P. Quinn 4:00 238. Evolution of gas-phase structure from electrosprayed ions. D. E. Clemmer, E. Badman, S. Myung 4:30 239. Achieving the ultimate in sensitivity and dynamic range with ESI-MS. R. D. Smith, K. Tang SectionB Convention Center Room 383
SectionB Chromatography Award Symposium in Honor of William S. Hancock B. L. Karger, Organizer 1:30 240. Memory book of HPLC: Evolvement of reversed-phase chromatography of biological substances. C. Horvath 2:00 241. HPLC and the biotechnology industry. J. Frenz 2:30 242. Single-cell manipulation and analysis on a chip. R. N. Zare, A. R. Wheeler, R. J. Whelan, A. Daridon 3:00 243. Protein separations in proteomics strategies. C. Fenselau, K. Shefcheck, K. Reynolds 3:30 244. Integration of separation science and mass spectrometry for proteome analysis. B. L. Karger 4:00 245. Award Address (ACS Award in Chromatography, sponsored by SUPELCO, Inc). Characterization of complex biological fluids using proteomics. W. S. Hancock Analytical Chemistry in Nuclear Technology Developments in Techniques for Organic Compounds and Organic-Bearing Waste Streams Cosponsored with Division of Nuclear Chemistry & Technology NMR Spectroscopy of Polymers Synthetic Polymers: Solid-State Structure and Morphology Cosponsored with Division of Polymer Chemistry
TUESDAY EVENING NMR Spectroscopy of Polymers Poster Session Cosponsored with Division of Polymer Chemistry
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Convention Center Room 383 From Sensors to Functional Instruments J. D. Tate, Organizer 8:00 252. Development and application of gas-sensing technologies for combustion. P. K. Dutta 8:30 253. From chemiresistor sensors to real-time subsurface hydrocarbon monitoring systems: Lessons learned. C. K. Ho 9:00 254. Integrated IR gas-sensor elements for process monitoring. B. R. Kinkade, J. T. Daly, J. Melnyk, E. A. Johnson 9:30 255. Gas chromatographs and GC sensors. K. R. Carney, Ε. Β. Overton, N. Roques 10:00 256. Intelligent ion: Commercializ ing breakthrough technology in miniature mass spectrometry. A. Scheidemann 10:30 257. Banners to commercializing gas-detection sensors to the chemical industry. T. Alligan 11:00 258. Titania-based hydrocarbon sensor with internal zeolite filter for harsh environments. J. A. Trimboli, P. K. Dutta Analytical Chemistry in Nuclear Technology Developments in Techniques for Analyzing Solid Samples Cosponsored with Division of Nuclear Chemistry & Technology NMR Spectroscopy of Polymers Synthetic Polymers: Diffusion and Constrained Geometry Cosponsored with Division of Polymer Chemistry
Environmental Management Science Program Symposium Subsurface Remediation Technology Cosponsored with Division of Environmental Chemistry
Presiding
THURSDAY MORNING
SectionB Convention Center Room 383 Size-Exclusion Chromatography with Multiple Detection Techniques Cosponsored with Division of Polymeric Materials: Science and Engineering, and Division of Polymer Chemistry A. M. Striegel, Organizer 1:30 Introductory Remarks. 1:35 265. Background and applications of multidetector GPC. W. F. Reed 2:05 266. Applications of size-exclusion chromatography with both dynamic and multiangle intensity light-scattering. P. M. Cotts 2:35 267. Size-exclusion chromatography with on-line mass spectrometric detec tion: Techniques and applications. L. Prokai, W. J. Simonsick Jr. 3:05 268. Surprises when probing the oligomeric region with an on-line viscom eter. A. M. Striegel, D. B. Alward 3:35 269. New approaches to close the gap between GPC and rheology. W. W. Yau, C. T. Enos, K. P. Rufener, J. M. Mack 4:05 270. Matrix fluorescence photobleaching recovery for molecularweight distributions of aqueous poly mers. P. S. Russo, G. Doucet, D. B. Neau, D. DeKee NMR Spectroscopy of Polymers Synthetic Polymers: Relaxation and Dynamics Cosponsored with Division of Polymer Chemistry
Section A Convention Center Room 384 Process Analytical Chemistry Cosponsored with Division of Industrial and Engineering Chemistry R. Guenard, Organizer 8:30 Introductory Remarks. 8:35 271. Mission possible: Providing diverse analytical solutions in the chemi cal processing environment. K. Huebert 9:05 272. Optical sensors for concen trated strong acids and bases. Z. B. Xue, L. R. Allain, T. A. Canada, D. L. Rodman 9:35 273. Alternative benchmark for calibration transfer of process analytical techniques. C. M. Wehlburg, R. Guenard, R. Pell, D. K. Melgaard, D. M. Haaland 10:05 Intermission. 10:15 274. Demonstration of a highprecision immersion probe for effective sampling of solids by Raman spectros copy. B. J. Marquardt, D. Veltkamp 10:45 275. Slaying dragons: Big prob lems, real-time data. E. Schmidt, L. Wright 11:15 276. The use of process analytical technology in Pfizer manufacturing plants. S. Hammond, M. Warman Section Β Convention Center Room 383 Capitalizing on Data Diversity: Interfacing Advances in Informatics and Measurements S. L. Neal, Organizer 8:30 Introductory Remarks. 8:35 277. Issues and problems in in silico predictive ADME modeling. T. R. Stouch 9:15 278. Membrane protein microarrays. J. Lahiri 9:55 279. Aspects of ideal mass spectro metric data for protein characterization. A. L. Yergey 10:35 280. Gold nanoparticles in highthroughput bioanalytical assays. Z. Rosenzweig, T. K. Nguyen 11:15 281. High-throughput experimenta tion and chemometrics for discovery of new materials. R. Shaffer NMR Spectroscopy of Polymers Biological Polymers Cosponsored with Division of Polymer Chemistry Radlochemistry at RIA Cosponsored with Division of Nuclear Chemistry & Technology Environmental Management Science Program Symposium Characterization, Fate, and Transport of Subsurface Contamination (Organics, Metals, and Rads) Cosponsored with Division of Environmental Chemistry
Analytical Chemistry in Nuclear Technology General Developments Cosponsored with Division of Nuclear Chemistry & Technology
TECH-15
TECHNICAL PROGRAM THURSDAY AFTERNOON Section A Convention Center Room 384 Microelectrochemical Systems and Arrays I. Fritsch, Organizer 1:30 Introductory Remarks. 1:35 282. Temporal and spatial considerations in developing microelectrochemical systems for small-volume analysis. I. Fritsch, Z. P. Aguilar, W. R. Vandaveer IV, S. R. Gray, E. Pennington, E. Fakunle 2:05 283. Interrogation of multielectrode arrays with scanning electrochemical microscopy. C. G. Zoski 2:35 284. Bioanalytical applications of microchip electrophoresis with electrochemical detection. B. A. Fogarty, N. A. Lâcher, S. Pasas, W. R. Vanadeever IV, R. S. Martin, M. I. Davies, K. Heppert, S. Lunte 3:05 Intermission. 3:15 285. Development and characterization of microbioanodes for alcohol/ oxygen biofuel cells. S. D. Mlnteer, N. L. Akers, T. J. Thomas, C. M. Moore 3:45 286. Micromagnets on electrodes. J. Leddy 4:15 287. Benchtop fabrication of nanoring electrodes: Pushing the limits of measuring electron hopping in solventfree materials. K. Ohr, J. Yartym, M. E. Williams NMR Spectroscopy of Polymers Biological Polymers Cosponsored with Division of Polymer Chemistry Environmental Management Science Program Symposium Environmental Sensing and Monitoring: Effects of Radiation Exposure on Humans and Biota Cosponsored with Division of Environmental Chemistry Radiochemistry at RIA Cosponsored with Division of Nuclear Chemistry & Technology
MALDI and ESI Mass Spectrometry Techniques for Polymers (see Division of Polymeric Materials: Science and Engineering, Sun, Mon) Macromotecules to Btopartfctes: Analyses with Field-Flow Fractionation (see Division of Analytical Chemistry, Mon) Adsorption of Macromotecules at Liquid-Solid Interfaces (see Division of Colloid and Surface Chemistry, Sun, Mon, Tue)
M. R. Marten, Program Chair
OTHER SYMPOSIA OF INTEREST: Gene-Based Medicine: Delivery and Diagnostics (see Division of Polymeric Materials: Science and Engineering, Tue) New Concepts in Blomaterials: Synthesis, Application, Concerns (see Division of Polymeric Materials: Science and Engineering, Sun, Mon) Polymeric Surface Modification: Biomedical Applications (see Division of Polymer Chemistry, Sun, Mon)
16-TECH
9:45 Intermission. 10:05 21. Detoxification of organophosphates by immobilized dual functional biocatalyst in a cellulose hollow fiber bioreactor. A. A. Wang, W. Chen, A. Mulchandani 10:25 22. Two-phase partitioning bioreactors: A new paradigm for xenobiotics destruction in air, water, and soil. A. J. Daugulis, B. G. Amsden 10:45 23. Influence of C0 2 concentration in air on algae respiration in membrane bioreactor L. M. Cao, H. L Chen, C. Y. Gao, L. H. Cheng, J. Y. Feng
Section Β
Biological Applications of Implicit Solvent Models (see Division of Computers in Chemistry, Mon, Wed, Thu)
Convention Center Room 294
Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Polymer Chemistry
Advances in Formulation
SUNDAY AFTERNOON
M kroscate Biosensors for Environmental Monitoring (see Division of Environmental Chemistry, Mon)
S. Sagar and E. J. Fernandez, Organizers
Section A
Biological Applications of Nanomatertals and Nanotechnotogy (sponsored by Advanced Materials & Nanotechnotogy Subdivision) (see Division of Industrial and Engineering Chemistry, Wed, Thu) Informatics Challenges in Pharmacogenomics (see Biotechnology Secretariat, Wed) Processes for Utilization of Agricultural By-Products (see Division of Agricultural & Food Chemistry, Wed, Thu) SOCIAL EVENTS: Annual BIOT Reception: Sun BIOT Business Meeting: Wed BIOT Future Programming Meeting:
Tue Poster Session: Wed
SUNDAY MORNING Section A Convention Center Room 293 Collection, Analysis, and Use of Process Data
DIVISION OF BIOCHEMICAL TECHNOLOGY
10:05 5. Retrospective time-dependent optimization of recombinant E. coli fermentations using historical data and hybrid neural network models. M. C. Coleman, D. E. Block 10:30 6. Use of statistical experimental design methods in developing a highconcentration liquid formulation for a monoclonal antibody. E. Kaisheva 10:55 7. Integrated process optimization for bioparticle production. P. E. Cruz, A. Bengala, L. Maranga, M. J. T. Carrondo
D. E. Block and V. Goetz, Organizers 8:00 Introductory Remarks. 8:05 1. Managing and analyzing bioprocess manufacturing data for process troubleshooting, statistical quality control, and regulatory submissions. S. Illich, N. Gerrior, P. Werth 8:30 2. Critical assessment on the analysis of batch fermentation databases. C. Undey, A. Cinar 8:55 3. On-line monitoring of bioprocesses using multiwavelength fluorescence. A. Eliasson, M. Haack, L. Olsson 9:20 4. Identifying key variables for cell culture process data analysis utilizing principal component analysis and basis transformation. S. Kaneshiro, T. Monica, R. Kiss 9:45 Intermission.
8:00 Introductory Remarks. 8:05 8. Correlation of physical and chemi cal stability of rhDNase with melting temperature. Μ. Ε. Μ. Cromwell, T. Patapoff, S. J. Shire 8:25 9. Development of a stable parenteral formulation for Pemphigus vulgaris tolerizing peptide (PI-0824). J. Ghiorse, L. Waldmann, A. Trischitta, T. Sawyer, E. Clark 8:45 10. Characterization of albutropin fusion protein: A novel, long-acting form of human growth hormone. A. M. Wilcox 9:05 11. Stabilization of an oral rotavirus vaccine. C. Burke 9:25 12. Designing an in vitro cell cell culture model to predict drug pharmaco kinetics and stability. S. F. Khattak, S. C. Roberts 9:45 Intermission. 10:10 13. Characterization of a novel adjuvant/delivery system for plasmid DNA vaccines. R. K. Evans, H. Mach, D. Zhu, R. D. Troutman, D. R. Casimiro, S. Chin, S. Wu, C. Ahn, D. K. Nawrocki, L. A. Isopi, D. M. Williams, D. B. Volkin, J. W. Shiver 10:30 14. Sterilizing filtration of plasmid DNA: Effects of plasmid molecular weight and conformation. M. P. Watson, D. Boyd, J. C. Murphy, S. Sagar, R. K. Evans, A. L Lee, M. Winters 10:50 15. Effects of formulation compo nents on the corrosion of 316L stainless steel. P. Lam, R. Keck, S. Lo, R. Wong, C.Hsu SectionC Convention Center Room 295
Convention Center Room 293 Advances in Expression Systems A. S. Robinson and N. Fong, Organizers 1:30 Introductory Remarks. 1:35 24. Mimicking the cytoplasmic envi ronment of Escherichia coli with cell-free protein synthesis activates oxidative phosphorylation. M. C. Jewett, J. R. Swartz 1:55 25. Cell-free protein synthesis utiliz ing unnatural amino acids. J. Schulte, J. R. Swartz 2:15 26. Export of correctly folded anti bodies from the cytoplasm of Escheri chia coli via the twin-arginine translocator. M. P. DeLisa, D. Tullman, G. Georgiou 2:35 27. NusA fusion protein expression and purification in conventional and high-throughput applications. A. Grabski, M. M. Mehler, K. W. Yaeger, K. Novy Jr., G. D. Davis, R. G. Harrison 2:55 28. Engineering yeast for high-level expression of G-protein coupled recep tors. A. S. Robinson, R. T. Niebauer, J. Butz 3:15 Intermission. 29. Withdrawn. 3:45 30. Modification of the ΛΖ-glycosylation pathway of lower eukaryotes to a mammalian type. R. H. Contreras, W. Vervecken, N. Callewaert, S. Geysens, V. Kaigorodov 4:05 31. Expression of human antibodies for clinical supply using myeloma cells. L. Daramola, R Field Section Β
Environmental Biotechnology T. K. Wood and K. F. Reardon, Organizers 8:00 Introductory Remarks. 8:05 16. Enhanced solubility of TCE and other contaminants due to the presence of biological material. J. W. Barton, S. A. Jones, C. Vodraska, Β. Η. Davison 8:25 17. Use of fluorinated analogs to explore pollutant fate in plant systems. J. M. Tront, F. M. Saunders 8:45 18. Enzymatic treatment of phenol with crude fungal peroxidase from Coprinus species. K. Ikehata, I. D. Buchanan, D. W. Smith 9:05 19. Microbial identification using "signature probes". M. Larios-Sanz, K. D. Kourentzi, G. E. Fox, R. C. Willson 9:25 20. An alternative ecological approach to process control optimization for bioprocesses operated with mixed microbial populations. P. E. Saikaly, D. B. Oerther
Convention Center Room 294 Advances in Protein Folding, Aggregation, and Modification T. Good and A. M. Tsai, Organizers 1:30 Introductory Remarks. 1:35 32. Effect of secondary structure on protein aggregation: A replica exchange on-lattice simulation. D. Bratko, H. W. Blanch 1:55 33. Critical role of hydration in enzyme activity in organic solutions. L. Yang, J. S. Dordick, S. Garde
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
ANYUBIOT/TECHNICAL PROGRAM
2:15 34. Protein folding and proton bind ing are linked: Analysis by capillary electrophoresis and electrokinetic mod els of colloids. J. D. Carbeck 2:35 35. Aggregation during refolding is dependent on the second virial coeffi cient. J. G. S. Ho, A. P. J. Middelberg 2:55 36. Strategies for modulating aggre gation kinetics of amyloid-forming pep tides. R. M. Murphy, J. R. Kim, T. J. Gibson, L. L Kiessling 3:15 Intermission. 3:25 37. Multiple active forms of singlechain antibody: Characterization and folding pathway analysis. A. S. Robinson, J. R. Sinacola 3:45 38. Structure, function, and engineer ing of bacterial disulfide isomerases for enhancing heterologous protein expres sion. L Segatori, G. Georgiou 4:05 39. Exploring the dimer interface as element of kinetic stability in a bacterial starch phosphorylase. B. Nidetzky, R. Griessler, A. Schwarz, F. Tanfani, A. Scire 4:25 40. Analysis of cross-linking hemo globins using variable-length reagents. E. Tarasov, K. M. Bobofchak, G. S. Gawlak, K. P. Normoyle, R. M. Danner, K. W. Olsen Section C Convention Center Room 295 Bioprocess Monitoring and Control C. F. Komives and H. Lam, Organizers 1:30 Introductory Remarks. 1:35 41. Application of the focused beam reflectance measurement method to the characterization of plant cells in suspen sion culture. P. T. Jeffers, S. Raposo, M. E. Lima-Costa, P. Kieran, B. Glennon 1:55 42. Growth sensitivity of microbial populations in mixed cultures is deter mined by a new microrespirometry method. P. G. Stroot, D. B. Oerther 2:15 43. On-line viable cell monitoring during long-term microcarrier cultures. F. Jimenez-Marrero, L. Bonnarens, J. L. Barker, J. E. Fleury, M. A. Forbes, R. N. Pattison, C. W. Buser, C. Hwang 2:35 44. On-line biomass monitoring with scanning dielectric spectroscopy. C. M. Cannizzaro, S. Valentinottι, I. W. Marison, U. von Stockar 2:55 45. A mechanism for glucose pH control. M. A. Alexander, J. G. Hoogerheide, C. M. Campbell 3:15 Intermission. 3:35 46. Novel sensors for cell culture and fermentation. G. Rao, X. Ge, Y. Kostov, L. Tolosa 3:55 47. Adaptive control of a G. xylinus fed-batch fermentation using in situ mid-IR spectroscopy. H. Kornmann, S. Valentinotti, M. H. Rhiel, U. von Stockar 4:15 48. Real-time fault detection, diagno sis, and quality prediction in batch fer mentations. C. Undey, S. Ertunc, E. Tatara, A. Cinar Polymeric Surface Modification: Biomedical Applications Tutorial Cosponsored with Division of Polymer Chemistry
SUNDAY EVENING Section A Convention Center Room 293 David Perlman Memorial Lecture M. R. Marten, Presiding 5:00 49. Title to be announced. T. To Be Announced
Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Polymer Chemistry
MONDAY MORNING Section A Convention Center Room 293 Advances in Polypeptide Production Technology: Accelerating Product and Process Development
Section C Convention Center Room 295 Evaluation of Column Performance in Preparative Chromatography Cosponsored with Division of Analytical Chemistry J. Thômmes and T. M. Larson, Organizers
8:00 Introductory Remarks. 8:05 50. Accelerating product and pro cess development by using cell-free protein synthesis. J. R. Swartz, N. Michelle-Reydellet, K. Knapp, G. Yin, J. Yang 8:30 51. Enhancement of antibody frag ments expression in Escherichia colt A novel cytoplasmic screening approach. R. Levy, B. Iverson, G. Georgiou 8:55 52. Engineering fungal systems to produce human glycoproteins. T. Gerngross 9:20 53. Overexpression of industrial enzymes in Pichia pastoris. J. Li, T. Kaneko, C. Isaac, N. Palackal, J. Wei, J. Sun, B. Steer, A. Vasavada 9:45 Intermission. 10:00 54. Simulation of large-scale envi ronments in the laboratory. T. Dodge, P. Lundqvist 10:25 55. Oxidative stress responses in E. coli fermentations under controlled conditions. C. Lu, W. E. Bentley, H. J. Cha, J. Garcia, G. Rao 10:50 56. Accelerating development of mammalian cell bioprocesses for recom binant protein production. C. Goudar, R. Heidemann, J. Michaels, K. Konstantinov
8:00 Introductory Remarks. 8:05 64. How can you tell if a column is doing its job? E. N. Lightfoot 8:35 65. Monitoring, diagnosis, and troubleshooting of large-scale chromatography. J. Prior, M. Menon, C. Dugopolski. K. Legg 8:55 66. Packing quality and integrity of industrial chromatography columns: From raw data smoothing to performance correlations. A. Sonnenfeld, H. Forrester, J. Thommes 9:15 67. Determination of the parameters governing biomolecule transport in EDTPA-modified zirconia particles. A. Subramanian, S. Sarkar, P. W. Carr 9:35 68. Chemometric analysis of chromatography production data: Integrating principal component analysis into a highly regulated industry. M. M. Mostajo, T. M. Larson, J. O. Davis 9:55 Intermission. 10:10 69. Resin reuse validation and evaluation of performance over resin lifetime. T. S. Taggart, D. J. Dripps, T. Kessler, M. E. Cameron, J. E. Seely, R. J. Todd 10:30 70. Evaluation of algorithms for quantification of packed-bed integrity in production-scale chromatography. J. O. Davis, Τ. Μ. Larson, R. Arnold 10:50 71. Tracking resin dynamic capacity in preparative chromatography. R. S. Blackmore, J. R. Ryland
Section Β
Section D
Convention Center Room 294
Convention Center Room 296
Therapeutic Antibody Issues: Fundamentals and Production Processes
2002 Industrial Biotechnology Awards Presentation and Lecture
H. Meerman and J. Li, Organizers
M. R. Marten, Presiding S. Lee and E. J. Fernandez, Organizers 8:00 Introductory Remarks. 8:05 57. Challenges of securing biologies capacity. E. Bramhall, S. S. Lee, J. Tabor 8:30 58. Development of a robust fedbatch CHO cell culture platform to opti mize monoclonal antibody production. P. A. Garza, C. Kopelev, D. Osborne, M. Reid, J. Torres, M. Gaya, N. Vargas, W. Noe, Y. H. D. Chang 8:55 59. Improved process yields in monoclonal antibody manufacture. A. E. Schmelzer, S. White, E. Tsao, A. Varma 9:20 60. The role of process simulation in the development, evaluation, and debottlenecking of monoclonal antibody production processes. C. Siletti, D. Petrides 9:45 Intermission. 10:00 61. Characterization of a small molecule conjugated antibody. W.Zhang 10:25 62. Development of high-perfor mance IDEC's in-house medium for antibody production. Y. Huang, T. Huynh, L Ly, W. Noé, Y. H. D. Chang 10:50 63. Impacts of glycosylate on antibody effector function. V. Sarantschin 11:15 Panel Discussion.
11:40 72. Title to be announced. T. To Be Announced Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Polymer Chemistry
MONDAY AFTERNOON Section A Convention Center Room 293 Advances in Fermentation Process Development Z. J. Li and I. Blumentals, Organizers 2:00 Introductory Remarks. 2:05 73. Seed train development for production of HIV gag plasmid in E. coli. J. L. Okonkowski, R. Greasham, M. Chartrain 2:30 74. Integrated systems approach for the optimization of recombinant fermen tation processes. K. Bayer, M. Cserjan, G. Striedner, K. Duerrschmid, H. Reischer, F. Clementschitsch
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
2:55 75. Process development by CFD modeling for very large-scale fermenta tions: Development of yeast kinetics for batch processes. C. G. Hébert, C. E. Wyman, L. R. Lynd, A. Bakker 3:20 76. Monitoring cell populations in bioreactors. J. Kacmar, N. Vijayasankaran, F. Srienc 3:45 Intermission. 4:10 77. Production of novel triketide lactone analogs by directed biosynthesis. R. Regentin, J. Kennedy, N. Wu, J. Galazzo, P. Licari, R. Desai 4:35 78. Enhanced protein production by Bacillus subtilis using a dual exponential feeding strategy. H. Huang, D. Ridgway, T. Gu, M. Moo-Young 5:00 79. Improvement in oxygen transfer in submerged fermentation using microbubbles. J. Weber, F. Agblevor 5:25 80. Development and scale-up of Pichia pastoris fermentation and protein recovery processes. D. B. Rudolph, T. Powers, R. Land, S. Pittinger, D. R. Durham Section Β Convention Center Room 294 Therapeutic Antibody Issues: Fundamentals and Production Processes S. Lee and E. J. Fernandez, Organizers 2:00 Introductory Remarks. 2:05 81. Effects of anti-apoptosis genes on mammalian cells producing antibod ies. B. Figueroa Jr., E. Ailor, M. Reff, J. M. Hardwick, M. J. Betenbaugh 2:25 82. Production of proteins with complex glycosylation in insect cells. C. E. Jcosten, M. L. Shuler 2:45 83. Analysis of metabolic decline in batch/fed-batch hybridoma cultures. R. R. Balcarcel, L. M. Clark 3:05 84. Production of antibodies and antibody fragments in Aspergillus niger. H. J. Meerman, H. Wang, C. Lin, D. Victoria, M. Ang, J. Pucci, M. Heng, X. Wang, R. Fong, B. Fox, B. Fryksdale, D. Wong, M. Ward 3:25 85. Engineered antibodies to treat whooping cough. J. Maynard, D. Relman, B. Iverson, T. Merkel, G. Georgiou 3:45 Intermission. 4:05 86. Toward production of therapeutic antibodies with mammalian-type glyco sylation in fungal systems. S. Wildt 4:25 87. Evaluation of a continuous disc stack centrifuge for the clarification of mammalian cell cultures. R. Shpritzer 4:45 88. CE: A rapid analysis tool and an emerging technology. D. L. Beurer, D. J. Roush, K. E. Goklen 5:05 Discussion. Section C Convention Center Room 295 Advances in Chromatography Cosponsored with Division of Analytical Chemistry A. K. Velayudhan and A. S. Rathore, Organizers 2:00 Introductory Remarks. 2:05 89. Chromatography of ultralarge proteins and nanoparticles using mono liths. A. Jungbauer, A. Zoechling, R. Hahn 2:25 90. Stimulus-responsive polymers used in chromatographic separation. R. Palmgren, J. Van Alstine, A. Rudstedt, A. Kjellgren, M. Wulff 2:45 91. Protein and stationary-phase determinants of FGF retention on cation exchangers. A. Lehnoff, P. DePhillips, Y.Yao
TECH-17
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ninderpaduak Social
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*Undergrdduafte Research Poster Sessions I and H
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r u n » juMBi Keporyuran vvnnigaMmuiiuDoiiucnaiige 1 vvonsnop | 1 3 0 - 3 : 1 5 p m , Hilton Riverside, Rosedown |Does your chapter have difficulty preparing its annual report gar writing a proposal for a Student Affiliates Chapter Grant? TThis workshop will discuss the annual report and ^CISA/IAG/Regional Meeting grant processes. Chapter mem bers can exchange information and network. forideolMEveiiK^ 3 3 0 - 5 3 0 pjiL, Aquarium of the Americas HkadrateSdiooJRaaA^ 330-5:00|ΐ 3 3 Q - 5 ^ p w ^ ^ M f y e r s f c f e Magnolia Thissessio This s^esion^Hp^wgppluate schools in the chemical scieiM : n o w ^ ψΕΕ^^*^ * tey m* a n d n o w to S e t o u t · A pdhehpf ^gjMJtpillj^^piiiliiiiiii itrators, faculty» and "Ί^ΗΨ^ΕΕΕΕΕββ^ I ^ > B W ' 1 % | M I J ^ Rosedown
^QJP y4W t e tfgBfe^P r about important soft skills that ^eJBo|MJn^Mp^/4ook for when they hire B.S. chemists.
rcpnjHpN^ tjE/E^^eipj^^htiltonRiversk^Rosed^ JPffçxflting event will help you cope with the challenges of pfëytàng chemistry. Students and professors are encouraged •toetend. Cosponsored by the Division of Chemical Erlii^ÈHrm
In A
9 : 0 0 - 1 1 : 1 5 a m , HUton Riverside, Rosedown
This exciting symposium will discuss opportunities for chemists in the federal government Cosponsored by die Division of Chemical Education, Inc. and the Younger Chemist» Committee. 11:15 ajn.-1:15 p m and 2:00-4:00 p m , Ernest N. Mortal Convention Center, Hail J
Sponsored by die Division of Chemical Education, Inc. «Gradutfe School QftA
4 3 0 - 5 3 0 pjii., HUton Riverside, Rosedown Representativesfromthe Graduate School Recruiters1 Breakfast will answer questions about their programs and related topics. Attiih1 III Ntend*nlÉi fimiy NflMWwtiw TfHiwi 4 3 0 - 5 3 0 p j i u HUton Riverside, Expo Center Sponsored by the ACS Membership Activities Committee, this session will help faculty encourage undergraduates to become full members of the Society after graduation. •Eminent Scientist LecturefeaturingHah Warner, Uuisiana Slate University 5 3 0 - 6 3 0 p m , HUton Riverside, Rosedown
Warner will discuss how mentors can help students reach thengoals. Cosponsored by the Committee on Minority Affairs. *MS Corporation Associates Rwqrtion· Up Close and Personal 6 3 0 - 8 : 0 0 p m , HUton Riverside, Expo Center
The ACS Committee on Corporation Associates will host this reception for undergraduates to participate in roundtable discussions on B.S. versus M.S. degrees, the advantages of co-op/internships, entering the workforce, and many other topics. Sd-MtySucnssM Student AHtfes Chapter Poster Seek» 8 : 0 0 - 1 0 : 0 0 p m , Ernest Mortal Convention Center, Hall G
* Sponsored or cosponsored by the ACS Society Committee on Education, Task Force on Undergraduate Programming at National Meetings (Darryi Prater, Pharmacia Corp., Skokie, IL, program chair; Carmen Colkzo, Pontifical Catholic University, general chair). For more information, contact
[email protected].
Expand Your Mind ^ Equip Your Lab. Be sure t o visit the ACS Expo when you come t o the ACS National Meeting. You'll find hundreds of exhibitors showcasing a full range of equipment, chemicals, software and services—everything t h a t you and your organization need t o support, streamline and improve lab operations. • Explore the exposition featuring the newest products and services from almost 3 0 0 companies. Use the ACS Virtual Expo t o schedule and prioritize the exhibitors you want to see at http://chemistry.org/expoplanner • Sign up for FREE exhibitor-sponsored workshops. Details can be found on the ACS Web site and in the technical program booklet. •
Pick up your ACS Expo souvenir, a FREE pocket radio. Available to the first 7 , 5 0 0 Expo visitors at booth 1 2 8 .
•
Check in at the 45-terminal Internet Cafe for FREE access t o your e-mail and the Web. You'll find the Internet Cafe at the end of Aisle 1 9 0 0 .
• You could win one of three TosNba laptop computers! Just drop off your prize tickets at booth 1 4 4 1 for a chance t o win.
The A C S Expo All «he E l e m e n t s You Need for Success
Mortal Convention Center New Orleans. LA USA Hall H/11 Monday, M a r c h 2 4 9 am - 5 pm Tuesday, M a r c h 2 5 9 am - 5 pm Wednesday, M a r c h 2 6 9 am - 1 pm
^1^,
TECHNICAL PROGRAM 3:05 92. Modeling of breakthrough curves of staphylococcal enterotoxin Β in pep tide affinity chromatography. G. Wang, R. G. Carbonell 3:25 93. Strategies for maintaining chro matographic column performance across scales A. Williams, K. Taylor, K. Dambuleff, R. Kennedy 3:45 Intermission. 4:15 94. Purification of plasmid DNA on a novel matrix using ion-pair chromatogra phy. J. Curling, M. Chambers, L. Smiley, A. Whan, D. Baines 4:35 95. Qualification of large-scale chro matography systems. O. Kaltenbrunner, A. Stokelman 4:55 96. Novel software tools for evaluat ing integration within a downstream process: A case study of expanded-bed adsorption vs packed-bed adsorption. M. A. Mustafa, J. Washbrook, S. Farid, A. C. Lim, N. Titchener-Hooker Section D Convention Center Room 296 Novel Bioanalyses Using Lab-on-a-Chip Technologies Cosponsored with Division of Analytical Chemistry D. M. Spence and R. S. Martin, Organizers 2:00 Introductory Remarks. 2:05 97. Biomediated assembly of functionalized microbeads for capture of microorganisms. T. T. Huang, T. Geng, D. Akin, W. Chang, J. Sturgis, R. Bashir, A. K. Bhunia, J. P. Robinson, M. R. Ladisch 2:25 98. Biomembranes on a microfluidic chip. P. Cremer 2:55 99. Development of a biomimetic circulatory system using chips fabricated from PDMS. D. J. Fischer, N. J. Torrence, D. M. Spence 3:15 100. Microfluidic devices for complex sample analysis: Integrated on-chip sample preparation, cellular, and chemi cal analysis starting from raw samples. B. H. Weigl 3:45 Intermission. 4:05 101. Polymer-based microfluidic devices for PCR amplification of genomic DNA. S. A. Soper, R. L. McCarley, M. C. Murphy 4:35 102. Microreactors without microfab rication: Using microscale steady-state kinetic analysis to study biological inter actions. N. J. Gleason, J. D. Carbeck 4:55 103. Microfluidic sensors for protein analyses. G. Thomas, M. J. Tarlov
MONDAY EVENING Section A Convention Center Hall G Sci-Mix Poster Session Z. J. Li, Organizer 8:00-10:00 223-224, 226, 229-230, 232, 234, 242, 244-245, 253, 255, 258, 260, 262-266, 268-269, 275, 279, 285, 287, 290, 293, 296, 300, 302, 304, 311, 315, 325-328, 331-332, 335. See subsequent listings.
18-TECH
TUESDAY MORNING
Section C
Section A
Convention Center Room 297
Convention Center Room 293 Bioinformatics, Genomics, and Proteomics V. Hatzimanikatis and W. Zhang, Organizers 8:00 Introductory Remarks. 8:20 104. Metabolic flux analysis based on dynamic genomic information. K. San, S. Cox, G. N. Bennett 8:40 105. Metabolite and protein profiling of whole cells using soft-ionization mass spectrometry for rapid microbial charac terization. S. Vaidyanathan, R. Goodacre 9:00 106. Dynamic modeling of the Escherichia coli phosphoenolpyruvateglycose phosphotransferase system. P. Prakash, J. S. Edwards 9:20 107. Transcriptome analysis of ethanologenic Escherichia coli strains: Tolerance to ethanol. R. Gonzalez, H. Tao, K. T. Shanmugam, L. O. Ingram 9:40 Intermission. 9:55 108. A functional proteomics study in neurobiology and the elucidation of signal transduction pathways. W. D. Mo 10:15 109. Glycoside hydrolases from Thermotoga maritima: Physiological and biotechnological aspects. S. R. Chhabra, K. R. Shockley, S. B. Conners, K. Scott, R. D. Wolfinger, R. M. Kelly 10:35 110. Protein classification by ligand binding. M. Farnum, S. Izrailev 10:55 111. A computational framework for the discovery of novel biotransforma tions. V. Hatzimanikatis, C. Li, J. A. lonita, L. J. Broadbelt Section Β Convention Center Room 294
Advances in Vaccine Development, Gene Delivery, and Gene Therapy W. Zhou, W. W. Q. Sun, and P. C. Fusco, Organizers 8:00 Introductory Remarks. 8:05 120. Development and characteriza tion of an improved adenoviral gene therapy manufacturing process. C. K. Murphy, J. M. Keegan, D. McNeilly 8:30 121. Charged poly(lactide-co-glycolide) microparticles can effectively deliver proteins and DNA in vaccines. J. D. Chesko, J. Kazzaz, M. Ugozzoli, M. Singh, D. O'Hagan 8:55 122. Developing an AAV-based vaccine for HIV-1. B. A. Thorne 9:20 123. High-titer production of retroviral vector with suspension-adapted 293GPG cells. A. Gamier, K. Ghani. P. Trudel, A. Kamen 9:45 Intermission. 10:05 124. Protection against anthrax toxin by heteropolymers directed against protective antigen. R. Mabry, C. Maassen, N. Mohamed, K. Brasky, J. Pattersen, G. Spitalny, L. Casey, B. L. Iverson, G. Georgiou 10:30 125. Quantitative comparison of nonviral gene delivery vectors: Model analysis of intracellular trafficking events. C. M. Varga, R. Langer, D. A. Lauffenburger 10:55 126. Development of a manufactur ing process for a cell culture-derived smallpox vaccine. F. Wu, G. Seanez, R. Kiefer, J. Marshall, S. Kodihalli, J. Gilly, D. Fine, D. Clanton Section D Convention Center Room 295-296
Advances in Bioseparations
Marvin J. Johnson Award Presentations and Lecture
A. A. Shukla and M. R. Etzel, Organizers
M. R. Marten, Presiding
8:00 Introductory Remarks. 8:05 112. Biofunctional membranes for Listeria monocytogenes detection. W. Chen, M. R. Ladisch, T. Geng, A. K. Bhunia 8:25 113. Enhanced ultrafiltration: Using electrostatic repulsion to increase yield and throughput. G. Bolton, R. Kuriyel, S. Pearl 8:45 114. Optimization of an osmotic shock procedure for isolation of a protein product expressed in E. coli. A. S. Rathore, R. E. Bilbrey, D. E. Steinmeyer 9:05 115. Purification of a polysaccharide conjugate vaccine using microfiltration membrane in backpulsing mode. E. P. Wen, L. D. D'Silva, D. Murray, S. L. Sagar, A. L. Lee 9:25 116. Membrane adsorber technology for trace impurity removal applications. M. W. Phillips, H. Lutz 9:45 Intermission. 10:15 117. Membrane adsorber process optimization through design of experi ments. J. Pieracci, C. Schifftner, J. Thommes, L. E. Conley 10:35 118. Strategies for optimizing the robustness of viral filtration steps in large-scale biopharmaceutical manufac turing processes. R. Caren 10:55 119. Strategies for improving mam malian cell clarification performance. S. Abraham, N. Bingham, K. Green, J. Kenworthy
4:30 133. Metabolic and evolutionary engineering in the era of genomics: Antibiotic resistance as a model for engineering new microbial behaviors. R. T. Gill, S. Copley, M. Lynch 4:50 134. Functional genomics in tissue engineering: Gene expression profile of engineered skin equivalents subjected to barrier disruption. S. T. Andreadis, P. Koria, D. Brazeau, P. Hayden 5:10 135. Pattern discovery as a generic tool for the analysis of biological data. K. Jensen, G. N. Stephanopoulos Section Β Convention Center Room 294 Advances in Bioseparations M. R. Etzel and A. A. Shukla, Organizers 2:00 Introductory Remarks. 2:05 136. Comparison of strong cationexchange resins for protein purification. A. Sta by. I. H. Jensen, U. Bruus, M. Sand, R. G. Hansen, J. H. Jacobsen 2:25 137. New chromatofocusing meth ods in biotechnology. D. Frey, X. Kang, H. Shen 2:45 138. Practical aspects of large-scale protein crystallization. M. Heng 3:05 139. Effect of support characteristics on the performance of protein A chroma tography media. J. T. McCue, I. Quinones-Garcia, G. Kemp, D. Low 3:25 140. Efficiency of expanded-bed adsorption processes. R. A. Hjorth 3:45 Intermission. 4:15 141. Multiobjective optimization strategies for preparative chromatogra phy. D. Nagrath, A. Messac, B. W. Bequette, S. M. Cramer 4:35 142. Salt effects on protein RPC retention and conformation. E. J. Fernandez, J. M. So ko I, J. O'Connell 4:55 143. Microcalorimetry study of the interactions between poly(/V-isopropylacrylamide) microgels and amino acids. H. Bianco-Peled O. Kimhi Section C
11:40 127. De novo design of protein secretion pathways for profit and for fun. G. Georgiou
TUESDAY AFTERNOON
Convention Center Room 297 Advances in Vaccine Development, Gene Delivery, and Gene Therapy
Section A Convention Center Room 293 Bioinformatics, Genomics, and Proteomics V. Hatzimanikatis and W. Zhang, Organizers 2:00 Introductory Remarks. 2:20 128. Predicting operon and regulon structure in Archaeoglobus fulgidus using transcriptomic data. L Rohlin, C. Sabatti, J. C. Liao 2:40 129. Genome-wide analysis of protein export via the Tat pathway in Escherichia coli. D. Tullman, M. P. DeLisa, Y. Kawarasaki, G. Georgiou 3:00 130. Global effects of oxygen expo sure during recombinant protein produc tion in Escherichia coli. W. B. Perry, C. L. Cooney 3:20 131. Analysis of mRNA and protein expression in Escherichia coli. K. H. Lee, P. S. Lee 3:40 Intermission. 4:10 132. Proteomic analysis of metabolic changes in fed-batch CHO cell cultures. D. E. Pascoe, D. Arnott, W. M. Miller, E. T. Papoutsakis, D. C. Andersen
W. Zhou and W. W. Q. Sun, Organizers 2:00 Introductory Remarks. 2:05 144. Live, oral, attenuated Salmo nella typhi vaccine strains as carriers of heterologous antigens. Ε. Μ. Barry, A. Santiago, M M . Levine 2:25 145. Toll-4 dependent adjuvant activity of emulsan. B. Panilaitis, L. Glickstein, J. Fuhrman, D. L. Kaplan 2:45 146. Antibody responses to encap sulated group C meningococcal polysaccharide-tetanus toxoid conjugates. C. E. Frasch, C. Lee, J. Zhang 3:05 147. Antigen-specific molecular sizing of a multivalent capsular polysac charide vaccine by modem size-exclu sion chromatography and nephelometry. Y. Yang, A. Matukonis, H. Hou, T. Kolachina, N. Kumar, P. McVerry, X.Wu
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
BIOT/TECHNICAL PROGRAM
3:25 148. Strategies of purification process development for bacterial recombinant vaccines. T. Yuan, Y. Yang 3:45 Intermission. 4:05 149. A nicotine conjugate vaccine for the possible treatment and prevention of nicotine addiction. A. Fattom, S. Ennifar, G. Horwith, S. Fuller, P. Pentel, D. Malin, R. Naso 4:25 150. Increase capsular polysaccharide production using fed-batch. Y. He, S. Mindel, E. McGill, D. Anderson, T. Kim, S. Carter, M. Brancieri, A. Lages 4:45 151. Enzymatic versus chemical pretreatment of the fermentation broth of N. meningitidis to improve harvest recovery. A. Lages, S. Ahuja, B. Baibak 5:05 Concluding Remarks.
WEDNESDAY MORNING Section A Convention Center Room 293 Validation of Biopharmaceuticals Processes B. D. Kelley and C. Chen, Organizers 8:00 Introductory Remarks. 8:05 152. An approach to second sourcing of raw materials. S. Abraham, H. Bevan, A. Thomas, A. Westlake 8:30 153. Development and qualification of a scale-down cell culture model for process validation. R. L. deVries, A. Gardner, R. Gerber, P. McAllister 8:55 154. Bioburden monitoring and establishment of bioburden specifications for bioprocesses. C. Z. Chen, P. Yegneswaran 9:20 155. Process validation approach for monitoring the performance of tangential flow filtration membrane devices. J. T. Pétrone, T. Erdenberger, C. Esenther 9:45 Intermission. 10:15 156. Design of a new chromatography column for cleaning effectiveness. G. Kierans, C. Antoniou, H. Carter, T. Dennen, A. Noyes 10:40 157. Impact of column hardware on CIP and resolution during the scale-up in preparative biochromatography. F. Drewe, J. B. Lee Section Β Convention Center Room 294 Advances in Cell Culture Process Development S. S. Ozturk and C. Ranucci, Organizers 8:00 Introductory Remarks. 8:05 158. Optimization of animal-compo nent-free medium for CHO cell growth and recombinant protein production using statistical design. R. Bhatia, C. Robberson, T. Osborne, S. Walfish, J. Zhang 8:25 159. Development of feed concen trates for CHO fed-batch processes. B. Horvath, S. Gu 8:45 160. Enhancing batch efficiency by harvest/fill operations in manufacturing. S. Chen, A. Dadson, K. Cars well, F. Situ, A. Wajid 9:05 161. A challenge with Vera cell attachment in large-scale nunc cell factories. I. Blumentals, C. Ranucci, S. Choudhari, A. Harris, E. Houghton, B. Mowrer, S. Ozuna, R. Scott, J. Whipple, G. Zang, J. Aunins, C. Goochee 9:25 162. Protein glycosylation is con trolled by cell culture conditions. M. Butler, N. Huzel, M. Yang, V. Restelli, J. Kunkel 9:45 Intermission.
10:10 163. Controlling product quality of a recombinant antibody produced in CHO cells by optimizing cell culture condi tions. J. C. Goodrick, S. Kaneshiro, R. Kiss, T. Monica 10:30 164. Bottleneck analysis of the glycosylation pathway for galactose-fed CHO cells. K. J. R. Clark, S. W. Harcum, Κ. Μ. Bailey, F. W. R. Chaplen 10:50 165. Enhanced specific productivity at low culture temperature in recombi nant Chinese hamster ovary cells depends on the integration site of a foreign gene. S. K. Yoon, G. M. Lee Section C Convention Center Room 297 Advances in Metabolic Engineering R. T. Gill and T. Dodge, Organizers 8:00 166. Use of metabolic models in metabolic engineering. J. Forster, J. Nielsen 8:23 167. Large-scale cybernetic model ing of protease production in Bacillus subtilis. J. Varner 8:46 168. What can we learn from sys tems biology? J. S. Edwards 9:09 169. Quantification and characteriza tion of uncertainty in metabolic engineer ing. V. Hatzimanikatis, I. Birol, J. Shi, L. Wang 9:32 170. Numerical innovations in model ing and simulation of carbon bond labeling experiments. G. Sriram, J. V. Shanks 9:55 Intermission. 10:10 171. Metabolic engineering of folic acid production. T. Zhu, R. Koepsel, M. M. Domach, M. Ataai 10:33 172. Designing novel metabolic control in Escherichia coli. W. C. Wong, S. Lee, E. Fung, J. C. Liao 10:56 173. Metabolic engineering of acetyl-CoA node and its effect on meta bolic flux redistribution in chemostat Escherichia coli cultures. R. V. Vadali, G. N. Bennett, K. San Section D Convention Center Room 295-296 2002 Elmer Gaden Award D. S. Clark, Presiding 11:40 174. Scalable bioprocesses for the controlled differentiation of embryonic stem cells. P. W. Zandstra
WEDNESDAY AFTERNOON Section A Convention Center Room 293 Regulatory Science: An FDA Perspective K. Brorson, Organizer 1:45 Introductory Remarks. 1:50 175. Analytical methods develop ment at FDA CBER: Analytical Chemis try staff, Office of Vaccines Research and Review. A. Del Grosso, J. May 2:10 176. FDA CDER's perspective on specifications for peptide maps. S. K. Moore 2:30 177. Product-directed research in the division of monoclonal antibodies. K. Brorson 2:50 178. Regulatory considerations for rapid development of biological prod ucts. P. G. Swann
3:10 179. Substrate specificity studies on recombinant Campylobacter jejuni /V-acetylneuraminic acid synthetase. A. Sundaram, W. Vann SectionB Convention Center Room 294
4:50 193. DNA array-based transcriptional analysis of the Clostridium acetobutylicum differentation and degeneration programs. E. T. Papoutsakis, C. Tomas, K. Alsaker, H. Bonarius, W. Hendriksen, J. Beamish, H. Yang, C. Paredes 5:15 194. A functional protein chip for in vitro metabolic engineering. G. Stephanopoulos, G. Jung
Advances in Biocatalysis Section D R. R. Chen and D. Pollard, Organizers 2:00 180. Pharmaceutical biocatalysis: Challenges of whole-cell bioconversions. D. J. Pollard, K. Telari, C. McWilliams, G. Humphrey, R. Greasham 2:25 181. Ketoreductases in the synthesis of valuable chiral intermediates: Applica tion in the synthesis of statine, phenylstatine, and their analogs. S. Kambourakis 2:50 182. Cofactor regeneration of NAD+ from NADH: Novel water-forming NADH oxidases. B. R. Riebel, P. R. Gibbs, W. B. Wellborn, A. S. Bommarius 3:15 183. Improving redox biocatalysis by engineered cells. J. D. Stewart, A. Z. Walton, I. Kaluzna, B. D. Feske 3:40 Intermission. 4:00 184. Practical biohydroxylation with Sphingomonas sp. HXN-200: A highly active, regie- and stereoselective, and easy-to-handle biocatalyst. Z. Li, B. Witholt 4:25 185. Application of a Baeyer-Villiger monooxygenase from Cunninghamella echinulata NRRL 3655. C. S. Whitcher, J. A. Littlechild, R. Wohlgemuth, J. M. Woodley 4:50 186. Oxygen limitations in the biocatalytic BVMO catalyzed synthesis of lacones. C. V. F. Baldwin, J. M. Woodley
SectionC Convention Center Room 297 Advances in Metabolic Engineering R. T. Gill and T. Dodge, Organizers 2:00 187. Expression profiling and hightemperature pressure adaptation of the hyperthermophilic methanarchaeon, Methanococcus jannaschii. B. B. Boonyaratanakornkit, A. J. Simpson, C. B. Park, C. Fraser, N. M. El-Sayed, D. S. Clark 2:25 188. Carbon flux analysis of meta bolic reactions in cell-free protein syn thesis. K. A. Calhoun, J. R. Swartz 2:50 189. Metabolic engineering of yeast for polyketide biosynthesis. N. A. Da Silva, S. Lee, K. K. M. Lee, C. G. Ching, S. Mutka, J. T. Keasley 3:15 190. Engineering Streptomyces bacteria to overproduce natural prod ucts. C. Kao, A. Lum, J. Huang, S. Cohen, C. R. Hutchinson 3:40 Intermission. 4:00 191. Rewiring cellular circuitry to improve biomanufacturing processes. E. M. Driggers, J. Royer, M. Askenazi, K. Madden, R. Doten, D. Zimmer, T. Feibelman, J. Trueheart, B. Cali 4:25 192. Target hierarchy: The cases for interfering RNA and transient controllers. W. E. Bentley, S. F. Kramer, M. P. DeLisa, R. Srivastava, L. Wang, K. Carter, C. Tsao
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Convention Center Room 295-296 Advances in Tissue Engineering and Cell Therapy J. Ross and T. Ma, Organizers 2:00 Introductory Remarks. 2:05 195. Development of in vitro and in vivo models of wound healing based on engineered tissues: A novel role of fibrin in wound healing. D. J. Geer, D. Swartz, S. T. Andreadis 2:25 196. Use micropattemed biodegrad able materials to control cell behaviors. Y. Wang, C. Ho 2:45 197. Organization of cell-adhesion proteins at surfaces on a subcellularlength scale using colloidal particle assembly. N. J. Gleason, J. D. Carbeck 3:05 198. Mathematical model for the depth-filtration seeding of human mes enchymal stem cells in 3-D nonwoven PET matrices. W. L. Grayson, T. Ma 3:25 199. Physical and mechanical prop erties of porous scaffolds fabricated from a blend of starch and chitosan. A. Su bra mania η, H. Lin, M. Hanna, K.Kim 3:45 Intermission. 4:15 200. Polysaccharide-based compos ite scaffolds for tissue engineering applications. A. Moshfeghian, Y. Huang, A. Sarasam, R. Lanman, S. Madihally 4:35 201. Modeling of cell growth and nutrient consumption in hematopoiesis in a 3-D perfusion bioreactor. P. Pathi, T. Ma, B. R. Locke 4:55 202. Tumor angiogenesis model with scaffold of small intestinal submucosa. H. Yang, R. R. Rivera, T. Ma Section Ε Convention Center Room 293 The Process of Process Development H. Pujar and J. Beck, Presiding 3:40 Introductory Remarks. 3:45 203. Structured decisional-support tool for rapid bioprocess modeling. A. C. Lim, S. Farid, J. Washbrook, N. J. Titchener-Hooker 4:10 204. Principles of fermentation process development and characteriza tion: Application to fermentation develop ment for vaccine manufacture. T. Lee, J. H. Crinean, J. R. Olges-Murphy, B. D. Bahler, S. H. Bauer, R. L. Hopfer, J. L. Cowell 4:35 205. Selection of chromatographic media and conditions for preferred recovery processes. Τ. Ν. Breece, T. M. Nguyen, C. Schmelzer 5:00 206. Using a high-throughput screening system for the development of scalable protein crystallization pro cesses. V. Klyushnichenko 5:25 207. Enabling faster process devel opment: Automation of process monitor ing assays. P. DePhillips, A. Bowman, K. Little, M. Vaccaro, M. Wenger, A. Lee 5:50 Concluding Remarks. Processes for Utilization of Agricultural By-Products Cosponsored with Division of Agricultural & Food Chemistry
TECH-19
TECHNICAL PROGRAM WEDNESDAY EVENING Section A Convention Center Hall J Poster Session Z. J. Li, G. Wei, and F. Agblevor, Organizers 6:00-9:00 208. Novel fluorescent pH indicator. G. G. Yi, Z. Diwu, L. Lavis, Y. Chen, J. Twu 209. Overcoming the barriers to batch process scheduling in the biopharmaceutical industry. D. P. Petrides, C. Siletti 210. Cloning of nattokinase genes and its preliminary studies. J. Ling, W. Du, L. Luo, R. Yang 211. Construction of a vector permitting immobilization and visualization of enzymes on compatible polymeric sur faces. E. Sahin, A. Taralp, Z. Sayers 212. Investigation of expression strength of various antibody gene arrangements in targeted CHO genome using an flpin CHO system. P. Fan, J. Larson, H. Qian, J. zhu 213. Medium characterization and optimiza tion by amino acid screening and design of expenment. J. H. Crinean, J. R. Olges-Murphy, T. Lee, S. H. Bauer, R. L. Hopfer, J. L. Cowell 214. Utilizing microarray technology for rapid identification of influenza A. M. Townsend, K. Rowlen 215. Morphological changes and extent of autolysis in filamentous fungi as a response to pulse-feeding of nutrients. J. Kadarusman, M. R. Marten 216. Characterization and transcnptional analysis of three adjacent Thermotoga maritima genes that show significant similarity to both aminopeptidases and endoglucanases. J. K. Michel, D. E. Ward, S. B. Conners, R. M. Kelly 217. A tool for the rapid evaluation of process limitation using microscale experimentation. F. Ahmed, G. J. Lye, J. M. Woodley 218. Effects of bionanoconjugation on protein-DNA interactions in Lac Repres sor. M. K. Calabretta, B. D. Yuhas, V. L. Colvin, K. S. Matthews 219. Using atomic force microscopy to study micromechanical properties of the model fungus Aspergillus nidulans. L Zhao, M. R. Marten, D. Schaefer 220. Using proteomics to understand how rapidly changing nutrient environments can affect E. coli during fed-batch fer mentation. B. Raman, M. R. Marten 221. A simple process strategy in filamen tous fungal fermentation can significantly improve recombinant protein productiv ity. S. Bhargava, M. R. Marten, K. S. Wenger 222. Engineering of a de novo disulfide bond formation pathway in E. coli. L. Masip, J. Collet, M. P. DeLisa, J. C. A. Bardwell, G. Georgiou 223. Strategic engineering of ft-oxynitrilase from almonds for industrial application. A. Glieder, W. Skranc, P. Poechlauer H. Schwab, K. Gruber, R. Weis, M. Wubbolts, H. Mayrhofer
20-TECH
224. The cDNA-derived amino acid sequence of hemoglobin II from Lucina pectinata. J. Lopez-Garriga, C. L. Cadilla-Vazquez, E. Torres-Mercado 225. Tranfer of nisin gene cluster into the chromosome of B. subtilis 168. J. N. Hansen, S. Yuksel 226. Transchip: A new system for studies of in vitro transcription of whole genomes. T. Wu, H. Yu, C. Churas, S. Zhou, D. C. Schwartz 227. Generation of recombinant influenza virus using baculovirus as a delivery vehicle. R. Grabherr, K. Poomputsa, C. Kittel, L. Toellner, W. Ernst, A. Egorov 228. Increasing acetyl-CoA pool in the presence of overexpressed phosphoenolpyruvate carboxylase or pyruvate carboxylase enhances succinate produc tion in Escherichia coli. H. Lin, R. V. Vadali, G. N. Bennett, K. San 229. Enhanced isoamyl acetate production in Escherichia coli upon manipulation of the acetyl-CoA node. R. V. Vadali, K. San, G. N. Bennett 230. Expression studies of affinity-tailed green fluorescent proteins in Eschericia coli. Batch productivity differences when different immobilized metal affinity chro matography tails are employed. H. Liu, R. R. Beitle 231. Expression and secretion of active lignin peroxidase in the yeast Kluyveromyces lactis. N. A. Da Silva, D. Shah, W. Panuwatsuk 232. An investigation into the size-activity relationship of RNA catalysis. T. M. Coleman, F. Huang, J. Manning 233. Protein engineering for shifting pH optimum of Bacillus circulans xylanase. J. Yang, Y. S. Choi, Y. J. Yoo 234. Interaction of partially folded BPTI analogs with C191/C220A trypsin. I. V. Getun, J. Tulla-Puche, C. Woodward, G. Barany 235. Cofactor metabolic engineering: Com parative study of the effect of increasing NADH availability in E. coli chemostat cultures on minimal and complex medium. A. M. Sanchez, K. San, G. N. Bennett 236. Semiparametric regression analysis on yeast gene regulation prediction. F. Pan, X. Hu, W. Perrizo 237. Probing aromatic amino acid biosyn thesis in Archaeoglobus fulgidus using DNA microarray. L Rohlin, S. Lim, I. Schroeder, H. Monbouquette, J. C. Liao 238. Diagnosing biopharmaceutical fermen tations using transcriptional profiling. J. M. Bonomo, R. T. Gill 239. Metabolic engineering of Saccharomyces cerevisiae for the production of isoprenoids. Ε. Μ. Paradise, G. Y. Wang, J. D. Keasling 240. Withdrawn. 241. Metabolic engineering of yeast for the production of 1,2-propanediol. N. A. Da Silva, W. Lee 242. Metabolomic application of NMR and MS: Tools for broad-screening metabolic pathways. T. W. Fan, R. M. Higashi, A. N. Lane 243. Metabolic modeling for evaluating effects of pressure pulsation on glycerol production by Candida knjsei. W. Huang, G. T. Tsao 244. Monitoring cell culture by LDH mea surements. J. C. Lagos, Y. Tsao 245. Expenmental versus simulated calibra tion mdels for in situ FTIR monitoring of bioprocesses. S. Valentinotti, H. Kommann, M. H. Rhiel, U. von Stockar 246. Bioreactor optimization for the produc tion of a secreted reporter protein in CHO cells using an inducible expression system. D. S. Kompala, M. L. Lipscomb, M. C. Mowry
247. Feeding strategy optimization for mammalian cell culture. S. F. Gorfien, W. C. Paul, J. L. Walowitz. D. A. Judd, L. D. Tescione, S. J. Jacobia, D. W. Jayme 248. A multidimensional Kla model to expedite cell culture process transfer. J. A. Groves, C. Chun, T. Ryll, S. Chamow 249. Adaptation and propagation of A549 cells in suspension culture for the pro duction of an adenoviral vector. Z. Liu, R. Longley, L. Radzniak, M. Santoro, M. Voloch 250. Analytical methods for mammalian cell culture feed streams. D. K. Rice II, J. Zdanowicz, J. S. Goldfuss 251. Applications of red fluorescent protein markers for indicating therapeutic protein expression and pericellular oxygen concentrations. C. W. Yung, Y. Hashimoto, W. E. Bentley, T. A. Barbari 252. Investigation of bivalent antibodies binding on fluid supported phospholipid membranes: The effect of hapten den sity. T. Yang, O. K. Baryshnikova, H. Mao, M. A. Holden, P. S. Cremer 253. A novel heat-shock protein prevents amyloid formation and toxicity. S. Lee, T. Good, K. Carson, A. Rice Ficht 254. Control of temperature and pH enhances human monoclonal antibody production in CHO cell culture. S. Oguchi, H. Saito, M. Tsukahara, H. Tsumura 255. Expression of EGFP reporter protein with a recombinant vaccinia virus: Com parison of microcarrier and cell-suspen sion-based bioreactor systems. N. A. Bleckwenn, W. E. Bentley, J. Shiloach 256. Influence of mixing on phenotypic differences in well and poorly differenti ated prostate cancer spheroids. H. Song, K. O'Connor, C. Giordano, S. Clejan, O. David, H. LeBeau 257. A mini-bioreactor system for acceler ated process development. R. Chen, S. Rajendran, K. Haverty, M. Tomkalski, P. Teplitsky, G. Wei, K. Namdev, R. Chillakuru 258. pH-Sensitive surfactants for water-inoil xanthan fermentation. A. S. Restrepo, L. Ju, J M. Bell, J. Y. Xu 259. Conversion of unsaturated fatty acids by compost bacteria. T. M. Kuo 260. High-throughput screening of heterolo gous P450 expression in yeast. J. A. Morgan, H. Jiang, D. chen 261. Microbubble fermentation of recombi nant Pichia pastoris for human serum albumin production. W. Zhang, F. A. Agblevor 262. Methods for evaluation of composite latex coatings containing Gluconobacter oxydans. Accurate determination of the effectiveness factor for the oxidation of D-sorbitol to L-sorbose in oxygenated microbioreactors. C. W. Solheid, S. P. Charaniya, U. Diel, M. C. Flickinger 263. Control of methanol feed for Bacillus methanolicus fermentation via mass spectrometry. C. F. Komives, C. Wang, S. Rech 264. Biopesticide production through fer mentation and entrapment of metarhizium anisopliae spores. Y. chen, J. Vaughan, F. A. Agblevor 265. Biosynthesis of germanium oxide by marine diatoms. G. L. Rorrer, C. Chang, C. Jeff ryes 266. Continuous pH monitoring during shake flask fermentations using optical sensors. H. R. Kermis, Y. Kostov, P. Harms, G. Rao 267. On-line process monitoring of moisture measurements and reaction kinetics by near-infrared spectroscopy for a polysaccharide vaccine. J. B. Fletcher, E. P. Wen, S. L. Sagar, A. L. Lee
268. On-line cell mass monitoring of Saccharomyces cerevisiae fermentations by multi-wavelength fluorescence. M. Haack, A. Eliasson, L. Olsson 269. Large-scale expression and purifica tion of hemoglobin I from Lucina pecti nata. E. A. Collazo-Santiago, J. Lopez-Garriga, C. L. Cadilla 270. Characterization of fermentation pro cess by design of experimental to reduce project time. J. R. OlgesMurphy J. H. Crinean, T. Lee, S. H. Bauer. R. L. Hopfer, J. L. Cowell 271. The role of computer modeling in bioprocess development and technology transfer. C. Siletti, D. Petrides 272. Design of experiment applied to fer mentation process optimization and charactenzation for validation. B. D. Bahler, T. Lee, S. H. Bauer, R. L. Hopfer, J. L. Cowell 273. Technical and economic feasibility of a novel, low-energy sterilization process. J. Zhang, J. Li, H. Kaiser, G. L. Thomson, T. Thomas, T. Davis, M. Matthews 274. Sample self-displacement purification of an antisense oligonucleotide by anion exchange membrane chromatography. A. Lajmi, T. Warner, Y. Sanghvi 275. Compaction agent clarification of microbial lysates. B. DeWalt, J. C. Murphy, T. Cano, J. Zijffer, G. E. Fox, R. C. Willson 276. Membranes from whey protein isolate: Studies of flux and rejection. J. Y. Teo, R. R. Beitle 277. Alternatives to protein A resin evalu ated for the purification of human anti bodies. R. Alsop, L. Nguyen, G. Zapata 278. Dissolved oxygen affects the accumu lation of recombinant Clostridia peptide fragment in E. coli. N. G. Dalai, J. Geva, R. Fass, J. Shiloach 279. Aromatic thiols as redox buffers: Increasing folding rates for disulfidecontaining proteins. J. D. Gough, W. J. Lees 280. Characterization and optimization of a pseudobioaffinity-based antibody sepa ration method. A. Subramanian, J. Hommerding, S. Roy, C. Mascoli 281. Hydrophobic interaction chromatogra phy: Effect of water, salt types, and process modeling. F. Xia, D. Nagrath, S. M. Cramer 282. Chromatography resin evaluation procedures. M. E. Cameron, R. Seely, K. Sabados, H. Harker 283. Development of a library of cationexchanger salt-tolerant media based on a multimodal interaction approach. J. Maloisel, N. Thevenin, E. Brekkan 284. Purification of 2-gram parenteral, low copy-number plasmid for phase l/ll clinical trials on an ÀKTA purifier chromatography system. S. Herzer, Z. Mei, C. L. DeSombre, X. Zhang, D. R. Rill 285. Scale-down of continuous filtration for rapid bioprocess design. T. S. Reynolds, R. M. Boychyn, M. Bulmer, J. More, M. Hoare 286. Evaluation of filters for the removal of E. coli proteins. C. W. Richey Jr., J. Seely, H. Rushing 287. Streamlining Escherichia coli S30 extract preparation for economical cell-free protein synthesis. D. V. Liu, J. F. Zawada. J R . Swartz 288. The evaluation of column performance over the lifetime of sepharose highperformance resin. D. J. Dripps, T. Taggart, T. Kessler, M. Cameron, R. Todd, J. Seely
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
BI0T7TECHNICAL PROGRAM
289. Topoisomerase-targeting anticancer drug screening by capillary electrophoresis. J. Chen, G. Liu, M. Du, Y. Huang, Y. Ma 290. A new pectate lyase from Bacillus pumilus for bioscouring. B. Klug, W. Schnitzhofer, K. Robra, G. M. Guebitz 291. Differential stability of a monoclonal antibody in acetate, succinate, citrate, and histidine buffer systems. N. Piros, M. E. M. Cromwell, S. Bishop 292. Effect of stainless steel exposure on the stability of a recombinant humanized lgG1 monoclonal antibody. R. Wong, S. Lo, C. Quan, W. Lau, S. Wang 293. Chip devices for CEC of peptides and proteins using various stationary phase materials. R. Jindal, S. M. Cramer 294. Evaluating chromatographic process variability using design of experiments. E. R. Cunningham, D. Myers, C. Bork, L. E. Conley 295. Highly concentrated formulations of the HIV-1 entry inhibitor PRO 542. K. Prakash, L. Zhao, D. Fisch, S. Rosenfield, K. Nagashima, N. Schiilke, W. Olson 296. Bridged diarylmethane fluorescent probes for labeling biomolecules. W. Zhou, Z. An, J. Lavin, S. R. Marder 297. Hydrophobic interaction chromatography: Using design of experiments to determine critical process parameters. M. W. Baillargeon, D. A. Ross, D. Eisenhauer, E. O. Lundell 298. Enzymatic method for detection of specific DNA-protein interactions. G. E. Sroga, J. S. Dordick 299. Preparative continuous annular chromatography: Investigations on the "peak wobbling" phenomenon. R. van Wegen, J. Prior 300. Screening of isolated cells via arrays of impedance sensors. D. Nguyen, H. Xiaoqiu, T. Afentakis, M. Hatalis, M. Domach, D. Grève 301. Characterization of 3-D collagen hydrogels for functional cell-based biosensing. C. Mao, W. S. Kisaalita 302. A novel immunoassay for atrazine using tunable immunosorbent. J. Kim, A. Mulchandani, W. Chen 303. Establishment of efficient systems to quantify human monoclonal antibody for the selection of production cells. T. Nakagawa, Y. Takamatsu, M. Tsukahara, T. Kadoya, H. Tsumura 304. Objective and quantitative method for titration of nonoccluded baculovirus. O. T. Ramirez, J. A. Mena, L. A. Palomares 305. New tissue micro-osmometer. F. Horkay, A. S. Berman, P. J. Basser 306. Direct cell and tissue analysis by infrared DIOS. S. M. Dutta, D. J. Rousell, Κ. Κ. Murray 307. Measurement of the elastic modulus of thin gel layers by the atomic force micro scope. E. K. Dimitriadis, F. Horkay, B. Kachar, R. S. Chadwick 308. Microfluidic chip detection using MALDI mass spectrometry. D. A. Narcisse, H. K. Musyimi, X. Zhang, S. A. Soper, Κ. Κ. Murray 309. Novel assembly platform for integrat ing biological species within MEMS devices. H. Yi, L. Wu, D. A. Small, T. Chen, R. Ghodssi, G. W. Rubloff, G. F. Payne, W. E. Bentley 310. Protein aggregation kinetics: Applica tions to protein A chromatography. P. Gupta, A. A. Shukla 311. Bti toxin CytIA in the lipid bilayer: Aggregation and the membrane dam age. S. D. Manceva, P. S. Russo, M. Pusztai-Carey, P. Butko 312. Biodegradable microparticles as potent delivery systems for vaccines: Experi mental measurement of factors govern ing antigen adsorption and efficacy. J. Chesko, J. Kazzaz, M. Ugozzoli, M. Singh, D. O'Hagan
313. Stable surface attachment and detec tion of fusion proteins. S. B. Brueggemeier, S. P. Palecek 314. Use of biarsenic labels to monitor protein-protein interactions. H. Eliason, M. S. Shekhani, M. Robers, K. W. Vogel, G. T. Hanson, K. L Vedvik, C. Ruttimann-Johnson, N. Qadir 315. Automated docking of phospholipids to the phospholipase D active site: Insight into the catalytic mechanism. C. L Aikens, A. Laederach, P. J. Reilly 316. Effect of molecular weight on the expression and characterization of a self-assembling peptide. W. D. Marner II, N. L. Goeden-Wood, J. D. Keasling, S. J. Muller 317. Synthesis of protein-based artificial transaminase by site-directed mutagen esis and chemical modification. C. Tann, D. Qi, M. D. Distefano 318. Comparison of immunoassay-blocking strategies on metal oxide substrates. A. N. Scribner, C. L. Cole, R. J. Colton, L. J. Whitman 319. Synthesis and biophysical character ization of template-assembled GALA. D. H. Haas, R. M. Murphy 320. Evolvability of random polypeptides through functional selection. A. Yamauchi, I. Urabe, T. Yomo 321. Generation of a semisynthetic oxidoreductase via chemical and genetical medication. C. Tann, M. D. Distefano 322. Elimination of oxygen limitation in enzmetic reactions. A. T. Y. Cheng 323. Hydrolysis of oligosaccharides using strong cation exchange catalyst and cellulase enzymes. Y. M. Kim, N. S. Mosier, R. Hendrickson, J. Goetz, M. R. Ladisch 324. Activity and kinetics of bovine pancre atic ribonuclease in organic-aqueous media. S. Emadi, F. Masdar-al Omour 325. Effect of silicon atom in substrates on (f?)-oxynitrilase-catalyzed enantioselective synthesis of (fl)-ketone cyanohydrin. N. Li, M. H. Zong, C. Liu, H. S. Peng 326. Enzymatic ammonolysis of trimethylsilylmethyl acetate in microaqueous phase. H. S. Peng, M. H. Zong, Y. Q. Xu 327. Enzymatic enantioselective synthesis of (fl)-2-trimethylsilyl-2-hydroxyl ethylcyanide. N. Li, M. H. Zong, C. Liu, H. S. Peng 328. Lipase-catalyzed enantioselective esterification of 1 -(trimethylsilyl)ethanol in organic solvent. H. Wu, M. H. Zong, D. H. Luo 329. Effects of various parameters on the enzymatic degradation of chlorogenic acid in model and sunflower meal sys tems. E. R. Martinez, Z. Duvnjak 330. Enzyme mediated production of free lutein from marygold flowers in nonaque ous media. E. Bérzana, M. J. Mora-Pale, S. Pérez-Munguia, M. Lopez-Vargas, A. Lopez-Munguia 331. Production of biodiesel fuel from soybean oil catalyzed by lipozyme TL in a solvent-free medium. Y. Xu, W. Du, D.Liu 332. Structural differences between bovine and porcine vitreous humor. F. Y. Ohene 333. Studies on coagulation factor Vila autoproteolysis and formation of degradation products. J. C. Krarup, T. B. Hansen 334. Collagen-hydroxyapatite multilayer sheet (fish scale model). K. Yamauchi, T. Tanabe, T. Goda
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
335. Controlled nanostructures assembly based on DNA-protein interactions. G. E. Sroga, J. S. Dordick 336. In vivo gene transfection into rat brain cells: A comparison between viral, polyethyleneimine, and calcium phosphate nanoparticle methods. T. D. Corso, I. Roy, M. Bland, T. Buckley, A. S. Gambino, L. C. Jenkins, B. Cranston, J. Myers, E. Stachowiak, E. J. Bergey, P. N. Prasad, D. Bloom, W. J. Bowers, M. K. Stachowiak 337. Surface characterization and in vitro protein adsorption studies of sol-gel derived ultrathin titanium oxide layers. M. C. Advincula, X. Fan, J. E. Lemons, R. Advincula 338. Binding of perfluorooctanoic acid to rat and human plasma proteins. X. Han, T. A. Snow, R. A. Kemper, G. W. Jepson
THURSDAY MORNING Section A Convention Center Room 293 Advances in Biocatalysis R. R. Chen and D. Pollard, Organizers 8:00 Introductory Remarks. 8:05 339. Accelerated biocatalyst stability testing for process optimization. P. R. Gibbs, U. Neunert, A. S. Bommarius 8:25 340. Multi-enzymatic synthesis of xylulose 5-phosphate. J. Shaeri, Ε. Β. Rathbone, I. Wright, R. Wohlgemuth, J. M. Woodley 8:45 341. Natural vanillin synthesis from com bran. R. R. Chen, N. Win, K. Brunson 9:05 342. Formation of lactobionic acid by a novel biocatalytic process. R. Ludwig, M. Ozga, M. Zamocky, K. D. Kulbe, D. Haltrich 9:25 343. Biocompatible and degradable biocatalytic dextran hydrogels. L. S. Ferreira, A. M. S. Cabrita, A. Rafael, M. H. Gil, J. S. Dordick 9:45 Intermission. 10:15 344. Surface hydrophobicity of silica supports effects activity of immobi lized enzymes in organic reactions. J. P. Lindsay, R. F. Wormsbecher, J. S. Dordick 10:35 345. Optimizing the cell concentra tion in thin, microporous latex biocata lytic coatings containing nongrowing Gluconobacter oxydans for very high oxidation rates of D-sorbitol to L-sorbose. S. P. Charaniya, C. W. Solheid, M. C. Flickinger 10:55 346. Efficient encapsulation of alcohol dehydrogenase in silicate matrix via sol-gel process as biocatalyst. Z. Jiang Sr. Section Β
8:45 349. Protein refolding by continuous chromatography. H. Lanckriet, A. P. J. Middelberg 9:05 350. Continuous matrix-assisted refolding using annular chromatography: A technology for quantitative conversion of unfolded proteins into native proteins. A. Jungbauer, C. Machold, R. Schlegl, W. Buchinger 9:25 351. Kinetics and reactor design for continuous and semicontinuous process ing of cellulosic biomass via simulta neous saccharification and fermentation. X. Shao, C. E. Wyman, L. R. Lynd 9:45 Intermission. 10:10 352. Solvent gradient operation of simulated moving bed processes. M. Mazzotti, S. Abel, L. Aumann, M. Morbidelli 10:30 353. In-line, online optimization of a new SMB technology working as singlecolumn system. P. Poetschacher 10:50 354. Advances toward processscale countercurrent chromatography and the prospect of continuous countercurrent extraction. I. Sutherland Section C Convention Center Room 295 Mechanistic Aspects of Virus-Cell Interactions D. V. Schaffer, G. Maheshwari, Organizers 8:00 Introductory Remarks. 8:05 355. Simulations of virus binding using Brownian adhesive dynamics. D. A. Hammer, T. English 8:25 356. Cell targeting using metabolically biotinylated adenoviral vectors. M. A. Barry, M. B. Parrott, S. Campos, Κ. Ε. Adams 8:45 357. Study of the adsorption effect on the diffusion of recombinant adenovi ruses toward 293S cells. A. Gamier, A. Gilbert, A. Kamen 9:05 358. A controllable gene delivery muscle patch. J. Bonadio, M. Salva 9:25 359. Monitoring viral spread and the development of cellular defensive responses to vesicular stomatitis virus infections in vitro. V. Lam, K. Duca, J.Yin 9:45 Intermission. 10:15 360. Retrovirus gene transfer to epidermal stem cells: The role of integrins and extracellular matrix. S. T. Andreadis, B. Bajaj 10:35 361. Effects of lipid rafts on the dynamics of retrovirus trafficking. K. Lim, J. Yin 10:55 362. Designing a gene therapy to prevent AIDS but maintain HIV. L S. Weinberger, D. V. Schaffer, A. P. Arkin Processes for Utilization of Agricultural By-Products Cosponsored with Division of Agricultural & Food Chemistry
THURSDAY AFTERNOON
Convention Center Room 294
Section A
Continuous Bioprocessing
Convention Center Room 293
J. H. Vogel and A. Jungbauer, Organizers
Advances in Biocatalysis
8:00 Introductory Remarks. 8:05 347. Continuously perfused fluidized bed fermentation for large-scale produc tion of r-protein and monoclonal antibod ies: Process stability and scale-up. G. Blueml, K. Landauer, M. Duerrschmid, S. Wiederkum, H. Klug, O. Doblhoff-Dier, H. Katinger 8:25 348. Quantifying physiology and metabolism of mammalian cells in con tinuous perfusion culture. C. Goudar, R. Heidemann, J. H. Vogel, J. Michaels, Κ. Β. Konstantinov
R. R. Chen and D. Pollard, Organizers 2:00 363. Directed evolution of alkane hydroxylation activity in cytochrome P450 BM-3. F. H. Arnold, M. W. Peters, P. Meinhold, Ε. Τ. Farinas, A. Glieder, C. W. Bugg 2:20 364. Engineering a protein molecular switch by combinatorial domain inser tion. M. Ostermeier, G. Guntas
TECH-21
TECHNICAL PROGRAM 2:40 365. Enzymology of xylose utilization in yeast: Coenzyme specificity of xylose reductase from Candida tenuis analyzed by site-directed mutagenesis and X-ray crystallography. B. Nidetzky, B. Petschacher, M. Klimacek, K. L. Kavanagh, D. K. Wilson 3:00 366. Novel screening method for enzyme activity and enantioselectivity using surface-enhanced resonance Raman scattering. L. C. Stevenson, D. Graham, B. D. Moore 3:20 367. Flow cytometric screening of chimeric glutathione transferase libraries expressed in Escherichia coli. K. E. Griswold Y. Kawarasaki, T. Selzer, J. D. Stevenson, S. Benkovic, B. L. Iverson, G. Georgiou 3:40 Intermission. 4:10 368. Microarray-based enzymatic modification of immobilized substrates for drug discovery. L Santhanam, M. G. Hogg, J. A. Holland, J. S. Dordick 4:30 369. Solid-phase biocatalytic amplifi cation of the natural product bergenin. U. Akbar, J. S. Dordick, D. S. Clark 4:50 370. Comparative thermostability/ thermoactivity analysis of class II xylose isomerases for high-fructose com syrup production at elevated temperatures. K. L Epting, T. V. Pearce Jr., C. Vieille, D. Sriprapundh, J. G. Zeikus. R. M. Kelly Section Β Convention Center Room 294 Separations and Process Technology for Genetic Therapy and Diagnosis Cosponsored with Biotechnology Secretariat J. C. Murphy, Presiding R. C. Willson, Organizer 2:00 Introductory Remarks. 2:05 371. The impact of nanotechnology on the development of cell isolation, separation, and expansion. G. Keller, J. Martinec, D. Richard 2:25 372. Sequence-specific oligonucle otide purification using peptide surfac tants. J. W. Schneider, J. P. Vernille, B. F. Marques 2:45 373. Plasmid purification by environ mentally triggered precipitation. J. Kostal, A. Mulchandani, W. Chen 3:05 374. Plasmid DNA production using compaction agents and immobilized metal-affinity chromatography. T. Cano, J. Murphy, G. E. Fox, R. C. Willson 3:25 375. Purification of supercoiled plasmid DNA by selective calcium sili cate adsorption of closely related impuri ties. M. A. Winters, J. D. Richter, S. L. Sagar, R. J. Lander 3:45 Intermission. 4:05 376. Metabolic biotinylation of pro teins and viral vectors for purification from mammalian cells. M. A. Barry, M. B. Parrott, K. E. Adams, S. Campos, D. Ghosh 4:25 377. Viral vectors for gene therapy: New purification challenges. S. Herzer, R. Morenweiser, N. Brument, P. M. Moore 4:45 378. Review of novel technologies for use as a virus barrier to eliminate adventitious contamination of viral drug products. R. Pearce, H. Lutz
Section C
MONDAY MORNING
Convention Center Room 295
ACS Award in Industrial Chemistry Symposium Cosponsored with Division of Medicinal Chemistry
Advances in Plant Biotechnology
MONDAY AFTERNOON J. V. Shanks and J. A. Morgan, Organizers 2:00 Introductory Remarks. 2:05 379. Expanded- and fixed-bed adsorption in capture of proteins from plant extracts. C. E. Glatz, T. J. Menkhaus, Y. Bai 2:25 380. Metabolic flux analysis of Catharanthus roseus hairy roots using a carbon bond labeling experiment. G. Sriram, B. Fulton, J. V. Shanks 2:45 381. Metabolic flux analysis of halogenated monoterpene biosynthesis in microplantlet suspension cultures of marine red macroalgae. G. L. Rorrer. J. P. Polzin 3:05 382. Study of polyunsaturated fatty acid synthesis in Glossomastix chrysoplastos, a marine microalgae, through optimization of bioreactor conditions and desaturase expression. T. Y. Hsiao, H. W. Blanch 3:25 383. Investigating cell subpopulation dynamics of Taxus cell suspension cultures: A single cell method. M. C. Naill, S. C. Roberts 3:45 Intermission. 4:05 384. Metabolic engineering of indole alkaloid pathways in Catharanthus roseus hairy roots. E. H. Hughes. S. Hong, S. Gibson, J. V. Shanks, K.San 4:25 385. Analysis of theoretical metabolic yields under photo-autotrophic condi tions. J. A. Morgan, O. M. Akpobasah Processes for Utilization of Agricultural By-Products Cosponsored with Division of Agricultural & Food Chemistry
Encouraging Disadvantaged Students into Careers in the Chemical Sciences: Symposium in Honor of Isiah M. Warner Cosponsored with Division of Analytical Chemistry
TUESDAY MORNING Section A Convention Center Hall H/l-1 Commercializing New Technologies from Concept to Market Cosponsored with ACS Committee on Corporation Associates; Commençai Development and Marketing Association (CDMA) T. Justesen, Organizer 9:30 1. Commercializing new technologies: I. S. Crawford 10:30 Intermission. 11:30 2. Commercializing new technologies: I I S . Crawford
TUESDAY AFTERNOON Section A Convention Center Hall H/l-1 Commercializing New Technologies from Concept to Market Cosponsored with ACS Committee on Corporation Associates; Commerical Development and Marketing Association (CDMA) T. Justesen, Organizer
DIVISION OF BUSINESS DEVELOPMENT AND MANAGEMENT
12:30 3. Commercializing new technologies: III. T.White 1:30 Intermission. 2:00 4. Commericalizing new technologies: IV. T. White 3:00 Intermission. 3:30 5. Commercializing new technologies: V. T. White
T. Justesen, Program Chair
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SUNDAY AFTERNOON Section A Convention Center Room 350-351 Nucleosides, Nucleotides, and Nucleic Acids Cosponsored with Biotechnology Secretariat S. F. Wnuk, Presiding M. Manoharan, Organizer 1:00 5. cADPR Analogs: An NMR study on the effect of ribose ring modifications on conformation. S. M. Graham, D. J. Macaya. A. E. Romano, R. N. Sengupta, K. B. Turner 1:20 6. Determination of DNA sequence specificity of a series of doxorubicin analogs based on hydropathic molecular modeling studies. D. J. Cashman. G. E. Kellogg. J. N. Scarsdale 1:40 7. Diels-Alder cycloadditions for synthesis of conjugated oligonucleotides. D. Graham. W. E. Smith, F. Ljiljana, H. Aaron, D. C. Robson, T. Leann 2:00 8. Oligonucleotides with 8-propyne analogs of dA: A potential candidate for antisense molecules. H. Lee, P. Yu, X. Gao 9. Withdrawn. 2:20 12. Synthesis of S-adenosyl-Lhomocysteine analogs with the sulfur atom replaced by "vinyl unit" via crosscoupling reactions. S. F. Wnuk, P. R. Sacasa, J. Lallama, V. J. Lawrence, E. Lewandowska 2:40 10. Synthesis of bioconjugate of H-phosphonates, phosphates, phosphonothioate. and phosphonoselenoate. Y. Ju, Q. Xiao. Y. Zhao 3:00 11. Synthesis of charge-modified dye-labeled dideoxynucleoside triphosphates and their applications in "direct load" DNA sequencing. P. J. Finn. M. G. Bull. L. Sun, J. R. Nelson, H. Xiao, J. A. Mamone. C. W. Fuller, B. F. McArdle, S. Nampalli, S. Kumar, P. Flick, G. Grossmann Biotechnology in the Service of Health Cosponsored with Biotechnology Secretariat
MONDAY MORNING Section A Convention Center Room 350-351
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10:15 3. Synthesis of stable carbohydrates mimics via RCM. M. H. D. Postema. J. L. Piper, L. Liu 11:00 4. Transition metal-catalyzed crosscoupling reactions toward the synthesis of glycomimetics. R. Roy, B. J. Schmor, R. Dominique. B. Liu, F. HernandezMateo. J. M. Juarez-Ruiz, S. K. Das
Convention Center Room 350-351
Hudson Award Symposium Z. J. Witczak, Organizer, Presiding R. Roy, Organizer 8:30 Introductory Remarks. 8:40 13. Award Address (Claude S. Hudson Award in Carbohydrate Chemistry, sponsored by National Starch & Chemical Co). Heparin: Structure and biological activities. R. J. Linhardt
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1. Withdrawn. 9:30 2. Sugar-coated metals: Carbohydrate-derived ligands for asymmetric catalysis in organic and aqueous phases. T. V. RajanBabu
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
BIOT/BMGT/CARB/CELL/TECHNICAL PROGRAM
9:15 14. Diverse biomaterials from simple sugars. J. S. Dordick, L. S. Ferreira, D. Kim, R. J. Linhardt, Q. Wang 9:50 Intermission. 10:00 15. Incorporating structural diversity into acidic polysaccharide libraries: A strategy for identifying novel saccharides that display unique protein-binding profiles. R. J. Kerns, L. Huang, P. M. Vyas 10:35 16. New approaches for analyzing structures and functions of heparan sulfate. B. Kuberan 11:10 17. Remodeling strategies to pre pare natural and unnatural N-linked glycans. K. G. Rice, J. M. Elhalabi 11:45 Concluding Remarks. TUESDAY MORNING Section A Convention Center Room 350-351 Chemistry and Applications of C-Glycosides P. P. Deshpande, Organizer 9:00 18. Synthesis of C-glycosides using glycosyl phosphates. P. Seeberger 9:35 19. A brief route for de novo synthe sis of optically active C-aryl glycosides. F. M. Hauser 10:10 20. Synthesis of aryl C-glycosides by the versatile reverse polarity approach. K. A. Parker 10:45 21. Novel methodologies for the stereocontrolled synthesis of C-aryl glycosides and imino-C-glycosides. O. R. Martin 11:20 22. Synthetic approaches to the construction and functionalization of spirocyclic C-glucoside of papulacandins. C. Hamdouchi TUESDAY AFTERNOON Section A Convention Center Room 350-351 Chemistry and Applications of C-Glycosides P. H. Seeberger, Presiding P. P. Deshpande, Organizer 23. Withdrawn. 24. Withdrawn. 2:00 25. C-Glycosides in antidiabetic agent discovery. J. T. Link 2:35 26. C-Glycoside synthesis via the Ramberg-Backlund reaction. R. W. Franck 3:10 27. Antifreeze glycoprotein analogs: Synthesis, in vitro testing, and applica tions. R. N. Ben 3:45 28. C-Glycoside analogs of diseaserelated carbohydrates. D. R. Mootoo, X. Cheng, R. W. Denton 4:20 29. Syntheses of C-glycosides incorporating 1,3-diketone moieties. N. Merbouh, C. Bruckner Section Β Convention Center Hall G General Poster Session M. Manoharan, Organizer 2:00-5:00 30. Synthesis and biological evaluation of rhizobium sin-1 lipid A derivatives. B. Santhanam, A. Demchenko, G. Boons, M. Wolfert, J. Moore
31. Acetyl glucuronyl trichloroacetimidate as glycosyl donor for efficient synthesis of oligosaccharides. S. E. Soliman, R. W. Bassily, R. I. El-Sokkary, M. A. Nashed 32. New thiodisaccharides as modulators of vascular smooth muscle proliferation. J. M. Culhane, Z. J. Witczak, J. Kukel, M. Remmel, A. Soares, C. Rock, P. M. Dey 33. A general method for predicting the bound conformation and free energy of formation of protein/carbohydrate com plexes. A. Laederach, P. J. Reilly 34. Alternansucrase acceptor reactions with methyl glycosides. G. L. Côté, C. A. Dunlap 35. B3LYP/6-311++G" study of the boat conformations of glucose. M. D. Appell, F. A. Momany, J. L. Willett 36. C-3'-modified nucleosides for the investigation of radical initiated DNA strand scission. G. Lahoud, A. C. BryantFriedrich 37. Chemical synthesis of β-glycosyl-lphosphopolyprenols: Highly stereospecific synthesis of ?p-glycosyl-1-hydrogenphosphonate as a common intermediate. P. A. Illarionov, D. E. Minnikin, D. B. Moody, S. A. Porcelli, G. S. Besra 38. Comparison of molecular mechanics and dynamics studies of D-glucaramide and related derivatives. J. Zhang, S. D. Styron, E. S. Davis, J. M. Gerdes, D. E. Kiely 39. Complexation and chiral recognition thermodynamics of -γ-cyclodextrin with dipeptides possessing two aromatic rings. M. V. Rekharsky, H. Yamamura, S. Araki, M. Kawai, Y. Inoue 40. D-Arabinose-5-phosphate isomerase from E. coli. R. W. Woodard, T. Meredith 41. Interactions of low-energy ionizing radiation with the DNA backbone: Pro duction of a C-2'-radical? C. Trzasko, A. C. Bryant-Friedrich 42. Investigation of orthogonal donor types in glycosylation reactions on a polysty rene resin. J. Ferguson, C. H. Marzabadi 43. Method for thermodynamic character ization of DNA duplexes on microarray. N. B. Vaganay, X. Gao 44. Monte Carlo docking and molecular dynamics simulations of the chiral recog nition of various enantiomers by cyclomaltoheptaose (beta-cyclodextrin). S. Jung, Y. Choi, S. Lee 45. Novel peptide-encoded glycopeptide libraries. L Ying, J. Gervay-Hague 46. Parallel synthesis of N-glycosides. P. Norris, Y. Root, P. Miner, L. Williamson, E. Ickert 47. Preparation and bioactivity investigation of low-molecular-weight carrageenan. W. Mao, Y. Li 48. Preparation and structural characteriza tion of the oligosaccharides derived from Gelidiales polysaccharide. W. Mao, H. Guan, L. Wu 49. Rotamer populations from MD simula tions and quantum-calculated J-couplings. J. Gonzalez Outeirino, S. Kawatkar, R. J. Woods 50. Steps toward the synthesis of C-glycoside-containing dendrimers. M. J. Panigot, J. P. Boggs, S. Kim, A. S. Caldwell, R. R. Carlton, A. L. Bare 51. Structure and mechanism of MIP syn thase. X. Jin, J. H. Geiger 52. Structure-guided design and synthesis of novel substrate mimics as potential inhibitors of M. tuberculosis rhamnose biosynthesis. R. P. Tangallapally, M. R. McNeil, V. C. Jones, J. H. Naismith, R. E. Lee
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
53. Studies toward the total synthesis of (-)-salicylihalamide A from L-rhamnose. G. I. Georg, K. Yang, J. DerryBerry 54. Synthesis of alkynyl-tethered 2'-deoxyuridines and their bicyclic pyrimidine analogues. R. Dembinski, M. S. Rao 55. Use of MM-PBSA in reproducing the binding free energy of NSAIDs to β-cyclodextrin. S. Pricl, M. Ferrone, M. Fermeglia, A. Lodi, A. Mazzurco WEDNESDAY MORNING Section A Convention Center Room 350-351
3:40 70. Development of direct detection assays using ESI-MS for biocatalysts that synthesize and degrade carbohy drate polymers: Steps toward engineer ing novel carbohydrate polymers and synthetic building blocks. N. L. Pohl, K. Ko, Y. Yu, C. Zea 4:00 71. Simulations of polysaccharide dynamics: The role of conformational transitions in determining physical prop erties. M. M. Kuttel, K. J. Naidoo 4:20 72. Mechanistic differences between the metal-dependent and metal-indepen dent phosphatidylinositol-specific phospholipase C: Implications of thio effects. L. Zhao, A. V. Kravchuk, M. Tsai, K. S. Bruzik
General Contributed Papers Synthesis of Carbohydrates G. Eggleston, Presiding M. Manoharan, Organizer 9:00 56. α-Glucosaminides by intramo lecular glycosylation. R. C. Lapo, S. Knapp 9:20 57. Transition-metal complexes of 3-deoxyaldosulose bis(thiosemicarbazones). E. Elliott, K. J. Donaghy, D. Horton 9:40 58. Carbohydrate-based glycodendrimers for the multivalent display of sialic acid. A. Nelson, S. Kalovidouris, S. Vidal, W. B. Turnbull, O. Blixt, J. Paulson 10:00 59. Cyclosophoraoses revisited as a novel functional cyclooligosaccharide. S. Jung, S. Lee 10:20 60. New methods for efficient synthesis of complex glycopeptides. Z. Guo, J. Xue, N. Shao 10:40 61. Novel sulfur ylide-mediated reactions of sugars. C. H. Marzabadi, M. Tamarez 11:00 62. Polymers with carbohydrate moieties as pendent groups. R. Narain, S. P. Armes 11:20 63. Synthesis and immunologic studies of conjugate vaccines made of modified gm3 antigens. Z. Guo, Y. Pan 11:40 64. Synthesis of natural and unnatural /V-glycosyl asparagines and /V-glycopeptides by phototransamidation. K. Michael, A. S. Davis, K. Vizvardi WEDNESDAY AFTERNOON Section A Convention Center Room 350-351 General Contributed Papers Structure, Function, and Biochemistry of Carbohydrates D. C. Baker, Presiding M. Manoharan, Organizer 2:00 65. Solution conformations of three disaccharides of hyaluronic acid. K. T. Welch, S. Hamilton, B. Jiang, D. C. Baker 2:20 66. Solution conformations of monoacylated anthocyanins from Daucus carota. K. T. Welch, D. K. Dougall, D. C. Baker 2:40 67. Cyclodextrin-triiodide host-guest complex. A. Khan, J. W. Minns 3:00 68. Natural polysaccharides and their interactions with dye molecules: Applica tions in effluent treatment. R. S. Blackburn 3:20 69. Molecular dynamics and free energy analyses of the interactions between β-cyclodextrin and some anti cancer drugs. S. Pricl, M. Ferrone, M. Fermeglia, A. Lodi
DIVISION OF CELLULOSE AND RENEWABLE MATERIALS P. Gatenholm, Program Chair
OTHER SYMPOSIA OF MEREST: Polymeric Surface Modification: Biomedical Application· (see Division of Polymer Chemistry, Sun, Mon) Biotechnology In the Service off Health (see Biotechnology Secretariat, Sun) Advances In BtocataJysle (see Division of Biochemical Technology, Wed, Thu) Advance· In Plant Biotechnology (see Division of Biochemical Technology, Thu) Applications off Scanning Probe Mtefoecopy to Polymers (see Division of Polymeric MaterialsScience and Engineering, Mon, Tue, Wed, Thu) MA1XN and ESI Maes Spectrometry Technique· for Potymer» (see Division of Polymeric Materials: Science and Engineering, Sun, Mon) New Concepts m Biomaterials: Synthesis, Application, Concern· (see DMston of Polymeric Materials: Science and Engineering, Sun, Mon) BUSINESS MEETING: Mon SUNDAY MORNING Section A Hampton Inn, Convention Center Antonine Advances in Biodégradation and Biotransformation of Lignocellulosics Biodégradation and Biotransformation of Lignocellulosics K. Hayashi and B. C. Saha, Organizers, Presiding 8:55 Introductory Remarks.
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TECHNICAL PROGRAM 9:00 1. Enzymes in biodégradation and biotransformation of lignocellulosics. B. C. Saha 9:30 2. Chimeric cellulosomes as a basis for efficient degradation of biomass. E. A. Bayer, H. Fierobe, C. Tardif, M. Czjzek, A. Mechaly, A. Belaich, Y. Shoham, R. Lamed, J. Belaich 10:00 3. Cellulose accessibility of cellulases. H. Ding, F. Xu 10:30 Intermission. 11:00 4. Insights from quantitative modeling into the mode of action of fungal cellulases. Y. Zhang, L. R. Lynd, C. E. Wyman 11:30 5. Action of Trichoderma reesei cellulases on oxidized cellulose. M. Tenkanen, A. Nordborg, M. Siika-aho, O. Dahlman 12:00 6. Heterologous expression, purification, and characterization of the glycosyl hydrolase family 7 cellobiohydrolases from Trichoderma reesei and Pénicillium funiculosum. W. S. Adney, Y. Chou, S. R. Decker, J. Ο. Baker, M. E. Himmel 12:30 Concluding Remarks. Section Β Hampton Inn, Convention Center Bienville
1:30 14. Hemicellulose hydrolysis: Deviations from customary first-order kinetic models and subsequent cellulose digestion relationships. C. E. Wyman, M. Brennan, A. Converse, M. Gray, S. Jacobsen, X. Li, C. Liu, T. Lloyd, S. Stuhler, B. Yang 2:00 15. Characterization of the flavocytochrome cellobiose dehydrogenase from wood-rotting and phytopathogenic fungi. D. Haltrich, R. Ludwig, H. Varga, M. Zamocky, C. Peterbauer 2:30 16. Potential of Aspergillus oryzae xylanase produced by solid substrate fermentation for biobleaching of pulp. J. Szendefy, G. Szakacs, L. Christov 3:00 Intermission. 3:30 17. Modification of the physical properties of lignocellulosic materials by laccase. W. R. Kenealy, J. Klungness, M. A. Tshabalala, M. Akhtar, E. Horn, R. Gleisner, G. Buschle-Diller 4:00 18. Laccase: An ancilla to kraft pulping. T. J. Dyer, D. Kim, A. J. Ragauskas 4:30 19. Manufacture of regioselectively substituted cellulose acetates applying acetyl esterases of different origin. J. Puis, C. Altaner, M. Tenkanen, J. Eyzaguirre, C. B. Faulds, P. Biely, L. Viikari, M. Siika-Aho, B. Saake 5:00 Concluding Remarks.
Chemical Modification of Starch Section Β T. J. Heinze, Presiding T. Heinze and B. Billmers, Organizers
Hampton Inn, Convention Center Bienville
8:25 Introductory Remarks. 8:30 7. Channels of starch granules. J. N. BeMiller, J. E. Fannon, K. C. Huber, N. Gunawan, J. A. Gray 9:00 8. The structure of cornstarch and synthesis of CMS by ultrasonic irradia tion. J. Xiong, J. Ye, Y. Chen 9:30 9. Use of chemical-imaging technol ogy to determine chemical-substitution patterns in modified starches. J. T. McDonald Jr., K. R. Anderson, B. Anderson, S. Smith, D. Elmore, C. Leverette 10:00 10. Enzymatic derivatization of starch with lignin. S. Liitkemeyer, A. Huttermann 10:30 11. Cationic-modified starch in a cellulose matrix: Properties and poten tial. A. Nechwatal, C. Michels, B. Kosan, M. Nicolai 11:00 12. Surface modification of starch, amylose, and amylopectin films. P. Gatenholm, A. Westling 11:30 13. Barrier and mechanical proper ties of different modified starches. A. Jansson, L. Jàmstrom
Chemical Modification of Starch
SUNDAY AFTERNOON
Section A
Section A
Hampton Inn, Convention Center Bienville
Hampton Inn, Convention Center Antonine Advances in Biodégradation and Biotransformation of Lignocellulosics Biodégradation and Biotransformation of Lignocellulosics K. Hayashi and B. C. Saha, Organizers, Presiding 1:25 Introductory Remarks.
24-TECH
B. Billmers, Presiding T. Heinze and B. Billmers, Organizers 1:30 21. Starch derivatives of high degree of functionalization. T. J. Heinze 2:00 20. Synthesis of regioselectively functionalized polysaccharide esters avoiding protecting groups. R. Dicke, D. Klemm 2:30 22. Model studies for structure analysis of starch derivatives. P. Mischnick 3:00 Intermission. 3:30 23. Highly functionalized carboxymethyl starch. T. F. Liebert, T. J. Heinze 4:00 24. Properties of hydroxypropyl starch. W. Vorwerg, S. Radosta, A. Kroger 4:30 25. Phase separation behavior of chemically modified starches. A. Jonhed, L. Jàmstrom
MONDAY MORNING
Advances in Biodégradation and Biotransformation of Lignocellulosics Biodedradation and Biotransformation of Lignocellulosics K. Hayashi and B. C. Saha, Organizers, Presiding 8:25 Introductory Remarks. 8:30 26. Bioconversion of lignocellulosic residues into fuel and food products. M. Moo-Young 9:00 27. Separation and conversion of com fiber. K. E. Beery, C. A. Abbas, T. A. Werpy, A. J. Schmidt, R. J. Orth 9:30 28. Metabolic engineering for improved bioethanol production. L. Olsson 10:00 Intermission. 10:30 29. Engineering Zymomonas mobilis for efficient ethanol production from lignocellulosic feedstocks. M. Zhang
11:00 30. Saccharomyces cerevisiae engineered for xylose metabolism does not recognize xylose as a fermentable carbon source. Y. Jin, Y. Mu, J. M. Laplaza, M. H. Kang, T. W. Jeffries 11:30 31. Renewable carbon: Feedstock to industrial chemicals. M. Kumar, J. Pucci, G. K. Chotani, J. Shetty, K. Sanford 12:00 Concluding Remarks. Section Β Hampton Inn Antonine Payen Award Symposium Honoring R. St. John Manley Part I D. S. Argyropoulos, Organizer, Presiding R. H. Marchessault and J. F. Kadla, Organizers 8:15 Introductory Remarks. 8:30 32. Species specificity of structures of native celluloses: The challenge of quantification. R. H. Atalla 9:00 33. Structural study of native cellu lose and cellulose derivatives by solidstate two-dimensional NMR experi ments. T. Erata 9:30 34. Energy surfaces for cellobiose. A. D. French, G. P. Johnson 10:00 Intermission. 10:30 35. Nanoassembly structure and its changes of bacterial cellulose. F. Horii 11:00 36. Symmetry and packing consid erations of cellulosic fibers and model compounds. P. Zugenmaier 11:30 37. The crystal structure and hydro gen bonding of cellulose polymorphs. Y. Nishiyama, H. Chanzy, M. Wada, J. Sugiyama, V. T. Forsyth, P. Langan
Section Β Hampton Inn, Convention Center Antonine Payen Award Symposium Honoring R. St. John Manley Part II P. Gatenholm, Presiding D. S. Argyropoulos, R. H. Marchessault, and J. F. Kadla, Organizers 1:20 Introductory Remarks. 1:30 45. Accelerated light exposure test ing of wood-containing papers: Effects of wavelength and intensity. P. F. McGarry, J. A. Schmidt, C. Heitner 2:00 46. Lignin-based polymer blends: Effect of polymer structure on blend behavior. J. F. Kadla. S. Kubo 2:30 47. Attaching radical scavengers to lignin-rich, wood pulp fibers: Chemistry and progress. T. Q. Hu 3:00 Intermission. 3:30 48. Photodegradation of softwood milled wood lignin. C. Heitner, R. S. J. Manley 4:00 49. Combined effects of polysulfide pulping and ECF bleaching on softwood carbohydrates. J. Bouchard, M. Méthot, L. Lapierre, R. Berry
MONDAY EVENING Section A Convention Center Hall G
Sci-Mix P. Gatenholm, Organizer
8:00-10:00 MONDAY AFTERNOON Section A Hampton Inn, Convention Center Bienville Advances in Biodégradation and Biotransformation of Lignocellulosics Biodégradation and Biotransformation of Lignocellulosics K. Hayashi and B. C. Saha, Organizers, Presiding 12:55 Introductory Remarks. 1:00 38. Development of formaldehydefree wood adhesives from brown-rotfungus-degraded wood. K. Li, X. Geng 1:30 39. Analysis of u-condensed structure in lignin. H. Nagatani, Y. Matsumoto, G. Meshitsuka 2:00 40. Identification of a resorcylate metabolite from Phanerochaete chrysosporium grown on sawdust and synthetic medium. M. D. Mozuch, P. J. Kersten 2:30 Intermission. 3:00 41. Identification of an extracellular pyranose 2-oxidase from Phanerochaete chrysosporium. M. D. Mozuch, T. H. de Koker, D. Cullen, J. Gaskell, P. J. Kersten 3:30 42. Heterogeneity of diastereomeric forms of (i-O-4 structures in lignin. T. Akiyama, Y. Matsumoto, T. Okuyama, G. Meshitsuka 4:00 43. Activating TMP for improved strength with filler addition. J. H. Klungness, R. Gleisner, J. Hess, E. G. Horn 4:30 44. Degradation of lignocellulosic biomass by enzymes from anaerobic fungi. X. Li 5:00 Concluding Remarks.
50. Preliminary investigations on the use of radiation-curable resins for bonding wood. T. G. Rials, G. F. Dorsey, W. L. Griffith, W. W. Moschler, P. Winistorfer, S. Cheng 51. Degradation of starch and carboxymethylcellulose by extracellular enzymes from four bacteria species. J. E. Onah, T. Shambe 52. Effect of cations and sulfhydryl reagents on the activity of enzymes. J. E. Onah, T. Shambe 53. Effect of tannin on modification of polyurethane derived from starch. J. Ge, R. Wu, X. Shi, Y. Liu, M. Wang 54. Analysis of the noncrystalline regions of cellulose using generalized two-dimensional correlation spectroscopy. Y. Hishikawa, S. Inoue, T. Kondo 55. Differential scanning calorimetry of alpaca fibers. S. Shim, K. A. Jakes 56. Analysis of two species of cotton by X-ray diffraction. Z. M. Ford, D. P. Thibodeaux, A. D. French, E. D. Stevens 57. Paper/polymerized vegetable-oil composites: Biodégradation behavior and use as degradable agricultural mulch film. R. L. Shogren, R. C. Hochmuth, R. J. Rousseau 58. Application of chemical imaging to composite wood materials. N. Labbé, T. G. Rials, S. S. Kelley 59. Biodegradable films based on hemicelluloses M. H. Grôndahl, P. Gatenholm 60. Charactenzation of mercerized and acetylated sisal fibers. M. A. Martins, I. Joekes, L. A. Forato, L. A. Colnago, L. H. C. Mattoso
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CELL/TECHNICAL PROGRAM
61. Cloning and characterization of the Xyn11A gene from Lentinula edodes. C. Lee, D. W. S. Wong, G. H. Robertson 62. Damped oscillatory graft length by free-radical scheme. K. R. Sharma 63. Effect of starch composition on structure and properties of foams prepared by microwave treatment. M. A. Sjoqvist, P. Gatenholm 64. Adsorption of purified cellulases on cotton fibers. A. P. Kanchagar, J. N. Etters 65. Temperature-modulated thermogravimetric analysis of isolated lignin. S. Kubo, J. Braun, J. F. Kadla 66. Detection of human neutrophil elastase with selectively modified cross-linked ethoxylate acrylate resins. S. Caston-Pierre, J. V. Edwards, A. F. Bopp, W. Goynes 67. Fractionated lignin-poly(ethylene oxide) blends: Analysis of intermolecular interactions between lignin and PEO. P. J. Cleary, S. Kubo, J. F. Kadla 68. Metabolic profiling of xylem tissue from loblolly pine. C. R. Morris, J. T. Scott, J. F. Kadla, H. Chang 69. Microfibril structure of bacterial cellulose as studied through solid-phase nitration and acetylation. H. Yamamoto, F. Horii, A. Hirai 70. Modified cotton bearing potential antimicrobial and blood-clotting activity. G. Duman, D. Koylu, M. Kolodzie, A. Taralp 71. New method for determining cellulose I crystallinity by means of FT Raman spectroscopy. K. Schenzel, S. Fischer, E. Brendler 72. Parabolic focal conies in self-assembled films of cellulose nanocrystals. M. Grunert, D. G. Gray 73. Pressure and temperature effects on soybean-oil-based composites. Z. Liu, S. Z. Erhan, D. E. Akin, F. E. Barton 74. Pyranose dehydrogenase: A novel quinone-dependent sugar oxidoreductase of lignocellulose-degrading litter fungi. C. Leitner, P. Halada, D. Haltrich, E. Kubâtovâ, M. Kujawa, C. Peterbauer, P. Sedmera, J. Vole 75. Withdrawn. 76. Silk paper. Y. Magoshi, T. Hata, M. A. Becker
SectjonB Hampton Inn, Convention Center Riverside II
Section A Hampton Inn, Convention Center Antonine Modified Fibers with Medical and Specialty Applications Modifications for Medical Applications: Part I Cosponsored with Biotechnology Secretariat Presiding
G. Buschle-Diller and S. C. Goheen, Organizers 8:25 Introductory Remarks. 8:30 77. Biocidal coatings for natural and synthetic fibers. S. D. Worley, J. Lin, C. Winkelmann, J. Kim, C. I. Wei, U. Cho, R. M. Broughton, J. F. Williams 9:00 78. Absorption performance of activated carbon nonwoven. J. Y. Chen, 1.1. Negulescu, L. C. Wadsworth 9:30 79. New biomaterials for medical uses. H. Struszczyk, A. Niekraszewicz, M. Kucharska 10:00 Intermission. 10:30 80. Behavior of cells cultured on Cuprophan. N. Faucheux, J. Gekas, J. Duval, M. Nagel 11:00 81. Use of textile technology for creating novel biomaterial surfaces. M. J. Bide, M. D. Phaneuf, F. W. LoGerfo, W. C. Quist
2:30 96. Crystal structure and biodegradability of natural and synthetic polyes ters. R. H. Marchessault, E. Cranston, J. Kawada 3:00 97. On the morphology of some crystalline polysaccharides. R. S. J. Manley
WEDNESDAY MORNING
WEDNESDAY AFTERNOON Section A Hampton Inn, Convention Center Antonine Composites from Renewable Resources Industrial Composites from Renewable Resources
Section A Payen Award Symposium Honoring R. St. John Manley Part III
S. S. Kelley, Presiding Hampton Inn, Convention Center Antonine
R. H. Atalla, Presiding D. S. Argyropoulos, R. H. Marchessault, and J. F. Kadla, Organizers 8:50 Introductory Remarks. 9:00 83. Chirality and paper. D. G. Gray, M.Yu 9:30 84. Membrane platforms for imaging cellulose synthases and investigating cellulose assembly in vitro. R. M. Brown Jr., A. J. Bowling 10:00 Intermission. 10:30 85. Molten salt hydrates as reaction medium for cellulose. S. Fischer, K. Hettrich 11:00 86. Novel biopolymeric materials based on xylans. P. Gatenholm, M. H. Grondahl, Λ. P. Under, J. P. Roubroeks 11:30 87. Amylose and starch as selfassembly matrices for drug delivery. F. Ravenelle, J. Kawada
TUESDAY AFTERNOON Section A Hampton Inn, Convention Center Antonine Modified Fibers with Medical and Specialty Applications Modifications for Medical Applications: Part II Cosponsored with Biotechnology Secretariat
Composites from Renewable Resources Fiber Composites and Characterization T. G. Rials, Presiding S. Murphy, J. Tomkinson, and S. Shaler, Organizers 7:50 Introductory Remarks. 8:00 98. Relationships between woodfiber properties and composite perfor mance. L. H. Groom 8:30 99. FTIR microimaging of biomassresin interfaces. S. S. Kelley, T. G. Rials, N. Labbé 9:00 100. Deformation micromechanics of natural cellulose composites. S. J. Eichhorn, R. J. Young 9:30 101. Ecocomposites: Cellulose nanocrystal-filled biodegradable polymers. W. T. Winter, D. Bhattacharya 10:00 102. Cellulose-fiber/polystyrene composites: Effects of fiber/matrix compatibility on interfacial microdeformation. W. T. Y. Tze, D. J. Gardner, C. P. Tripp, S. C. O'Neill, S. M. Shaler 10:30 103. Characterization of microcellular foam polyolefin blend composites with wood fiber. P. Rachtanapun, L. Matuana, S. M. Selke 11:00 104. Spectroscopy and multivariate analysis of fibers. T. Elder, S. S. Kelley, L. H. Groom 11:30 105. Invigorating high-κ kraft pulps with laccase. R. P. Chandra, A. J. Ragauskas
S. C. Goheen, Organizer, Presiding
S. Murphy, J. Tomkinson, and S. Shaler, Organizers 1:00 113. Agricultural materials in meltblend processing. D. D. Stokke, J. Ai 1:30 114. Man-made cellulose-fiberreinforced polypropylene compounds for injection molding. J. Ganster, P. Weigel, H. Fink 2:00 115. Role of additives in formulating wood-plastic composites. W. D. Sigworth, R. L. Heck, L. E. Walp 2:30 116. Wood-based, high-purity, cellulose-fiber composites: Challenges from R&D to commercialization. Y. P. Khanna, J. H. Underwood, K. D. Sears, D. B. Pietsch, R. B. Daniel 3:00 Intermission. 3:30 117. Polymer nanocomposites from agriculturally derived cellulose microfibrils. W. J. Orts, M. K. Inglesby, G. M. Glenn, G. Nobes, J. Revol 4:00 118. Wood-fiber surface modification by steam explosion with polyolefins. S. H. Renneckar, R. S. Wright, A. Zink-Sharp, W. G. Glasser 4:20 119. Wood extrusion: An innovative technology. D. R. A. Beyts 4:40 120. Lignin as a base for the design of reinforced cellulose fibers. S. Lutkemeyer, M. Schroter, K. Schindel, A. Huttermann 5:00 121. Novel wood adhesive based on tannin and polyethyleneimine. K. Li, J. Simonsen, N. Masson, J. Karchesy Section Β Hampton Inn, Convention Center Bienville
Section Β J. V. Edwards and G. Buschle-Diller, Organizers
TUESDAY MORNING
J. V. Edwards, Organizer,
11:30 82. Design, preparation, and activity of modified-cotton wound dressings with protease-lowering activity. J. V. Edwards, D. R. Yager, I. K. Cohen, S. C. Goheen, A. Bopp
1:30 88. The capacity of derivatized cotton for serum albumin. S. C. Goheen, K. Gaither, A. Rayburn, J. V. Edwards 2:00 89. Functional modifications of natural and synthetic fibers for biocidal applications. G. Sun, Y. Sun 2:30 90. In-line modifying of lyocell fibers. H. U. Fuchs, C. F. Rohrer 3:00 Intermission. 3:30 91. Investigation of bacterial fermen tations for potential syntheses of tissuecompatible natural-synthetic copolymers. J. Sparks, J. Zanzig, C. Scholz 4:00 92. Use of halamines to produce biocidal surfaces. U. Cho, R. M. Broughton, S. D. Worley 4:30 93. Ultrahigh specific surface fibers for incorporation of proteins and enzymes. Y. Hsieh, Y. Wang, J. Xie Section Β Hampton Inn, Convention Center Riverside II Payen Award Symposium Honoring R. St. John Manley Part IV R. H. Marchessault, Organizer,
Presiding D. S. Argyropoulos and J. F. Kadla, Organizers 1:15 Introductory Remarks. 1:30 94. Miscibility characterization of polyblends with cellulose alkyl esters. Y. Nishio 2:00 95. Electrospinning. D. H. Reneker
Hampton Inn, Convention Center Bienville Modified Fibers with Medical and Specialty Applications Enzymatic Modification of Textile Fibers Cosponsored with Biotechnology Secretariat A. Cavaco-Paulo, Presiding J. V. Edwards, G. Buschle-Diller, and S. C. Goheen, Organizers 8:00 106. Substrate specificities of new polygalacturonases and a pectate lyase with potential for bioscouring. W. Schnitzhofer, B. Klug, M. Calafell, M. Vrsanska, G. M. Guebitz 8:30 107. Treatment of wool by pulse corona discharge and enzymes. T. Takagishi, S. Cho, M. Tahara 9:00 108. Surface modification of cellulosic fibers with kinases and hydrolases. T. Tzanov, A. Cavaco-Paulo 9:30 109. Study on the tactile properties of enzyme-treated yams and fabrics. V. Kasi, R. Parachuru, G. Buschle-Diller, F. L. Cook 10:00 Intermission. 10:30 110. Biomodified regenerated cellulosic fibers with improved proper ties. D. Ciechanska, H. Struszczyk, J. Kazimierczak, K. Guzinska 11:00 111. Enzymatic modification of synthetic fibers. G. Fischer-Colbrie, S. Heumann, A. Cavaco-Paulo, G. M. Guebitz 11:30 112. Cellulose fibers with controlled surface morphology. À. P. Linder, P. Gatenholm
Modified Fibers with Medical and Specialty Applications Modification of Pulp Fibers Cosponsored with Biotechnology Secretariat G. M. Guebitz, Presiding G. Buschle-Diller, J. V. Edwards, S. C. Goheen, and A. Cavaco-Paulo, Organizers 1:30 122. Modification of pulp fibers by laccase treatment. W. R. Kenealy, G. Buschle-Diller, T. J. Elder 2:00 123. Analysis of laccase-modified pulp fibers. G. Buschle-Diller, W. R. Kenealy, Y. Wu, H. ZulaicaVillagomez, T. J. Elder 2:30 124. Parlaying dielectric breakdown discharge for fiber modification. L. C. Vander Wielen, A. J. Ragauskas 3:00 Intermission. 3:30 125. Attraction of magnetically sus ceptible paper. D. G. Mancosky, L. A. Lucia 4:00 126. Cellulose nanocrystal compos ites. J. Simonsen, J. Wang, V. Palaniyandi 4:30 127. Cellulosic fibers as reinforcing agents. M. K. Inglesby, G. Buschle-Diller, M. E. Guttman, G. M. Gray, D. F. Wood, D. A. Bailey
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
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TECHNICAL PROGRAM THURSDAY MORNING Section A Hampton Inn, Convention Center Antonine Modified Fibers with Medical and Specialty Applications Structural Fiber Modifications and Finishing Processes: Part I Cosponsored with Biotechnology Secretariat
DIVISION OF CHEMICAL HEALTH AND SAFETY J. M. Kapin, Program Chair
G. Buschle-Diller, Organizer, Presiding J. V. Edwards and S. C. Goheen, Organizers 8:30 128. Effect of deacetylation condi tions on the properties of CTA fibers. J. Braun, J. F. Kadla 9:00 129. Structure and properties of carbacell-type cellulosic fibers. H. Fink, J. Gensrich, R. Rihm, O. Hanemann 9:30 130. Cellulose fibers formed by electrospinning from solution. M. W. Frey, H. Song 10:00 Intermission. 10:30 131. Ionic liquids as green solvents for the dissolution and regeneration of cellulose. R. P. Swatloski, S. K. Spear, J. D. Holbrey, R. D. Rogers 11:00 132. Rheology and microstructure of cellulose diacetate in mixed solvents. C. Appaw, J. F. Kadla, S. A. Khan 11:30 133. Preparation and liquid-crystal line properties of phenylacetoxylcellulose derivatives. Q. dai, J. F. Kadla, R. D. Gilbert
THURSDAY AFTERNOON SectionA Hampton Inn, Convention Center Antonine Modified Fibers with Medical and Specialty Applications Structural Fiber Modifications and Finishing Processes: Part II Cosponsored with Biotechnology Secretariat E. J. Blanchard, Presiding J. V. Edwards, G. Buschle-Diller, and S. C. Goheen, Organizers 1:30 134. Reaction products of unsatur ated polycarboxylic acids and sodium hypophosphite for improved flame resis tance of cotton-containing materials. E. J. Blanchard, Ε. Ε. Graves 2:00 135. Development of rapid tech niques for assessing physical properties of modified linen fabric. H. S. S. Sharma, R. D. McCall, K. Kemaghan 2:30 136. Thermal insulation properties of cellulosic-based nonwoven composite materials. V. G. Yachmenev, L. Kimmel, C. Delhom 3:00 137. Mercerization of cotton for new properties. A. M. Grancaric, T. Pusic, I. Soljacic 3:30 138. New quaternary ammonium ion reagents from urea for fabric treatment. N. D. Sachinvala, N. T. Prévost, J. H. Campbell, L. A. White, O. D. Dailey Jr., E. E. Graves, J. M. Bland, K. Maskos 4:00 139. Effect of tannin on modification of polyurethane derived from starch. J. Ge, R. Wu, X. Shi, Y. Liu, M. Wang
SOCIAL EVENTS: Dinner: Tue Executive Board Meeting: Sun Programming Meeting: Mon Social Hour: Tue
Function-Based and Other Novel Approaches to Sensors for Homeland Defense Cosponsored with Division of Analytical Chemistry
SUNDAY AFTERNOON SectionA Convention Center Room 222 Alternatives to Thermal Distillation Solvent Purification N. Langerman, Organizer 2:00 Introductory Remarks. 2:10 1. Solvent purification—Issues of science and safety: Thermal and chromatographic purification techniques. J. G. Palmer 2:35 2. Anhydrous solvent kegs as an alternative to thermal distillation. S. N. VanderWel 3:00 3. UC Irvine still fire: Lessons learned for emergency response and recovery. R. R. Lally 3:25 Intermission. 3:35 4. Solvent purification made safe. R. R. Lally, J. M. Kapin 4:00 5. Solvent purification systems: Alternatives to thermal distillation. D. Clay 4:25 Panel Discussion. Teaching Safety at the High School, College, and University Honoring Jay Young's 80th Birthday Cosponsored with Division of Chemical Education Environmental History: The Evolution of Environmental Awareness, Regulation, and Progress Cosponsored with Division of the History of Chemistry Function-Based and Other Novel Approaches to Sensors for Homeland Defense Cosponsored with Division of Analytical Chemistry
MONDAY AFTERNOON SectionA Convention Center Room 222 The Health Hazards of Mercury: An Ongoing Problem Cosponsored with Division of Chemical Toxicology Ε. Β. Segal, Organizer
3:35 27. Teaching safety and safe work practices in academic laboratories. B. L. Foster 3:55 28. Implementing a laboratory-safetytraining program for the research labora tory. D. C. Sharpe 4:15 29. The chemistry-laboratory-survival manual. D. A. Katz 4:35 Discussion. 4:55 Concluding Remarks. Advanced Technologies for Decontaminating and Managing Radioactive Wastes Cosponsored with Division of Industrial and Engineering Chemistry
TUESDAY MORNING SectionA
SUNDAY MORNING
2:00 Introductory Remarks. 2:05 6. Cleanup of mercury spills. R. W. Phrfer 2:25 7. Waste avoidance program for mercury-laden mixed waste. M. C. Cournoyer, T. P. Martinez, J. H. Dare
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2:45 8. Effective replacements for mer cury thermometers in academic chemis try laboratories. B. L. Foster 3:05 9. Practical assessment of mercury exposure: Contamination and cleanup. D. J. Eustace, M. Walters, M. Anderson, S. Riley 3:25 Intermission. 3:40 10. Mad as a hatter? The campaign for a mercury-free NIH. E. H. Rau 4:00 11. Assessment and removal of mercury contamination in laboratory decommissioning activities. Ε. Η. Rau 4:20 12. Managing your risk and liability in disposing of mercury: State-of-the-art recycling. Ε. Β. Segal 4:40 Discussion.
Convention Center Room 346 Incorporating Chemical Safety into the Academic Curriculum: A Tribute to Jay Young Part I Cosponsored with Division of Chemical Education
DIVISION OF CHEMICAL EDUCATION F. J. Torre, Program Chair
G. H. Wahl, Organizer 8:30 Introductory Remarks. 8:40 13. An animated safety video for the undergraduate teaching laboratory. D. A. Straus, G. Wrenn 9:00 14. Teaching safety at the University of Sonora. C. R. Alvarez, M. E. Arce, M. I. Tapia, L. G. Castillon, S. Herrera 9:20 15. WebCT online safety course for academic credit. W. W. Fogleman 9:40 16. Development and delivery of a stand-alone chemistry laboratory safety course: Curriculum, credits, and related conundrums. N. M. Tooney 10:00 Intermission. 10:10 17. Incorporating ACS safety mod ules into academic chemistry laboratory safety training: The Polytechnic Univer sity perspective. Ν. Μ. Tooney 10:30 18. SACHE: 17 years of teaching safety to chemical engineering students. D. C. Hendershot, J. F. Louvar 10:50 19. Proper hazardous chemical waste management in undergraduate organic teaching laboratories at a "Big Ten" school. A. Azadnia 11:10 20. Teaching safety: What, when, where, how? G. H. Wahl Jr. 11:30 Discussion.
TUESDAY AFTERNOON Section A Convention Center Room 346 Incorporating Chemical Safety into the Academic Curriculum: A Tribute to Jay Young Part II Cosponsored with Division of Chemical Education G. H. Wahl, Organizer 1:30 Introductory Remarks. 1:35 21. Jay Young: A lifetime in chemical safety. R. J. Alaimo 1:45 22. An integrated undergraduate laboratory-safety program. W. H. J. Breazeale 2:05 23. What employers want their prospective employees to know about safety. R. H. Hill Jr. 2:25 24. Who provides the safety con tent? K. P. Fivizzani 2:45 25. How can I find out what the hazards are? J. A. Young 3:05 Intermission. 3:15 26. Creating a university laboratorysafety-orientation course: Cantankerous topics and pundit priorities. R. Vernon
OTHER SYMPOSIA OF INTEREST: Incorporating Chemical Safety Into the Academic Curriculum: A Tribute to Jay Young (see Division of Chemical Health and Safety, Tue) Chemical Information Literacy: b It Affordable? (see DMston of Chemical Information, Sun) Librarian Watch: Introduction to New Hot Areas In Chemistry (see Division of Chemkri Information, Sun) SOCIAL EVENTS: Dinner: Sat Luncheon: Sun Social Hour: Sat BUSINESS MEETING: Tue
SUNDAY MORNING SectionA Convention Center Room 218 NSF-Catalyzed Curriculum Development I. B. Nejad, Presiding 8:30 Introductory Remarks. 8:35 1. NSF programs that support under graduate education. A. Grushow, I. B. Nejad, S. H. Hixson 9:00 2. Educational materials for a greener organic chemistry laboratory curriculum. J. E. Hutchison 9:25 3. Online quizzes and tutors for students in basic organic chemistry courses. S. S. Hixson, D. Hart, A. Peterfreund, K. A. Rath, P. Samal, M. Schwartz, W. J. Vining, B. Woolf, C. P. Lillya, S. M. Battisti 9:50 4. Research-inspired writing: A discipline-specific writing course for junior-level chemistry majors. M. S. Robinson, F. Stoller, J. K. Jones
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CELLyCHAS/CHED/TECHNICAL PROGRAM
10:15 Intermission. 10:25 5. Educating teaching assistants in new models for teaching and learning. A. M. Stacy, R. M. Bornick, V. J. Loo, E. L Lewis 10:50 6. Visualizing molecular orbitals, hybridization and resonance, and peri odic trends from the Caltech Chemistry Animation Project. N. S. Lewis 11:15 7. Computer simulations and accompanying guided-inquiry tutorials for general chemistry. T. J. Qreenbowe, R. Vanchiswaran, H. Liu, K. A. Burke, J. Poock, D. Cantonwine, Β. Μ. Hand Section B Convention Center Room 219 Designing and Building New and Renovated Chemistry Labs D. Wink, Organizer 8:30 Introductory Remarks. 8:50 8. Low-cost spectroscopy experi ments for modernizing physical chemis try teaching laboratories. J. E. Whitten 9:10 9. Advantages of networked data collection in the chemistry laboratory. E. D. Sprague 9:30 10. Remodeling: Air distribution and hood design. T. W. Shattuck 9:50 11. Designing labs for a green build ing. A. K. Hovland 10:10 Intermission. 10:30 12. The big things are important; the little things are important. L. Rickard 10:50 13. Renovation of McKinley Hall: Complete gutting and remodeling. D. P. Rillema 11:10 14. By all measures a success: The University of Connecticut's new chemis try building. R. J. Wikholm, A. W. Dimock 11:30 15. The new Penn State University chemistry building. B. J. Garrison SectionC Convention Center Room 217 Chemistry for Nonmajors: Teaching in Never Never Land Chemistry in Context K. Stone, Organizer, Presiding J. Paradis, Organizer 8:30 Introductory Remarks. 8:35 16. So this is what chemistry is about—Wow! C. L. Stanrtski, C. Middlecamp 8:55 17. Reading what nonscience majors write—Wow! C. Middlecamp, C. Stanrtski 9:15 18. Hot topics in science: Teaching chemistry to nonmajors. E. T. Bell-Loncella 9:35 Intermission. 9:45 19. Chemistry by the case: The use of team learning and case study teach ing in an NSM chemistry course. F. J. Dinan 10:05 20. Chemistry for nonmajors in a general education curriculum. T. Jordan 10:25 21. Covertly teaching chemistry: A case history of a course to entice nonscience majors. G. H. Purser 10:45 Intermission. 10:55 22. Topics-based approach to teaching chemistry for nonmajors. S. K. Allen, J. M. Allen 11:15 23. Chemistry, accounting, and theater A real-world trilogy. K. Stone, S. Filling, J. Mayer Chemical Information Literacy: Is It Affordable? Cosponsored with Division of Chemical Information
SUNDAY AFTERNOON SectjonA Convention Center Room 218 Demonstrating Chemical Laws and Principles W. C. Deese and J . J. Fortman, Organizers, Presiding 12:00 24. Weird science: A phenomenological approach to teaching. Presenta tion at the high school teachers' lun cheon. L. R. Marek 1:30 Introductory Remarks. 1:35 25. Demonstrating buoyancy. W.C. Deese 2:05 26. Demonstrating how the gas laws relate to flight. J. J. Fortman 2:35 27. Principles of electrochemistry via the orange juice clock and other demon strations. P. B. KeKer, J. L. Walsh, C. M. CastroAcuna 3:05 28. Arrhenius and electrolytic disso ciation. J. M. Manion, P. F. Krause 3:35 29. Incorporating lecture and prelab demos into the general chemistry cur riculum. V. A. Jouraeva 4:05 30. Exocharmic demonstrations are more than infotainment. L. R. Marek 4:35 31. Chemical principles visualized. D.A. Katz Section Β Convention Center Room 219 Teaching Safety at the High School, College, and University Honoring Jay Young's 80th Birthday Cosponsored with Division of Chemical Health and Safety G. H. Wahl, Organizer, Presiding 1:30 Introductory Remarks. 1:35 32. Thirty years of ignorance and thirty years of learning. J. Kaufman 1:55 33. Illinois "fundamentals of labora tory safety". J. E. Pingel 2:15 34. Favorite high school stockrooms I have seen (you have what in there?). A. J. Banks 2:35 35. Alas, chemicals demand our respect. R. P. Torrey 2:55 Intermission. 3:05 36. Hazards and risks. J. A. Singley 3:25 37. Re-engineering laboratory chemi cal hoods: An exciting new future. D. Walters, R. Ryan, A. Kolesnikov 3:45 38. What do I do with 55 pounds of mercury? An interagency initiative to improve chemical safety in Illinois schools. G. Trammell, J. Davis, J. E. Pingel, G. Pollock, K. Runkle 4:05 39. Funding safe science in second ary schools. H. J. Elston, W. C. Penker SectionC Convention Center Room 217 Chemistry for Nonmajors: Teaching in Never Never Land Technology and Laboratory-Based Approaches J. Paradis, Organizer, Presiding K. Stone, Organizer 1:30 Introductory Remarks. 1:35 40. Assessment of Conceptual Chemistry Alive!, a multimedia lecture series for the nonscience major. J. A. Suchocki, M. T. Reese 1:55 41. Adventures in introductory chem istry for lost boys and girls. R. C. Bauer, J. P. Birk, P. S. Marks 2:15 42. Using the Internet to address chemical issues facing society. P. K. Kerrigan, S. E. Rudnick
2:35 Intermission. 2:45 43. Distance learning chemistry laboratories for nonscience majors: Unintended consequences. D. R. Kimbrough, J. Reeves 3:05 44. Water quality: A project-based laboratory for introductory chemistry. K. M. Carvalho 3:25 45. Problem-based laboratories for nonscience majors: A method for evalu ating student understanding. Β. Β. Harmon 3:45 Intermission. 3:55 46. Building community and excite ment through chemistry labs. J. L Schneider 4:15 47. Forming bonds: Chemistry and community. M. M. Ali, H. R. Patrick, Β. Β. Harmon SectionD Embassy Suites Jean Lafrttee Room James Bryant Conant Award in High School Chemistry Teaching Honoring Linda K. Ford Cosponsored with Women Chemists Committee F. J. Torre, Organizer 1:30 48. Award Address (James Bryant Conant Award in High School Chemistry Teaching, sponsored by Albermarle Corp). Worthwhile lessons from my classroom. L. K. Ford Librarian Watch: Introduction to New Hot Areas in Chemistry Cosponsored with Division of Chemical Information SUNDAY EVENING SectionA Convention Center Hall G General Poster Session J. Miller, Organizer 7:30-9:30 49. Peer-led team learning: Explorations. J. E. Becvar, M. Valdez, V. Almeida 50. Effectiveness of peer-led team learning workshops in organic chemistry instruc tion at Le Moyne College. J. J. Mullins 51. Process-Oriented Guided Inquiry Learn ing Project. R. S. Moog, F. J. Creegan, D. M. Hanson, J. N. Spencer, A. Straumanis, D. M. Bunce, T. A. Wolfskill 52. DNA fingerprinting as an exercise in the undergraduate laboratory. D. D. Jackson 53. TIGERS teaching forensics. G. P. Glaspell II, E. Pyle 54. A short course in forensic chemistry. B. P. Huddle 55. Student-centered chemistry: Modifying laboratory teaching methods to benefit student learning styles. J. A. Zimmerman 56. Seattle Pacific University community outreach activities. G. D. Phelan 57. An evaluation of antioxidants in wine: An experiment for the introductory organic lab. J. M. Simpson, J. A. Lloyd, D. B. Waters 58. An example of a survey in chemical education: From content validity to construct validity. A. Amaya, S. Camarano, L. Crosa, M. Rodriguez Ayan
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
59. An integrated context for introducing research methods in chemistry. T. E. Elgren, I. Rosenstein, R. B. Kinnel, R. Subramaniam, R. J. Palmitesso 60. Acid-base titrations: Where's the salt? S. M. Yochum 61. Assessment of pharmaceutical sciences lab: Effect of pH on partition coefficient of acidic and basic drugs. S. Phadtare, O. Abanah, A. Butler 62. Attempts to meet the challenge of general chemistry placement. A. Jorgensen, D. B. White, L. Yu 63. Basic experimental design: Capstone to first semester organic lab. W. G. Hollis, R. R. Oetgen 64. Chemistry conceptual inventories of first semester chemistry students: Before and after. B. Ramsay, J. Vites 65. Combinatorial chemistry in experimental organic chemistry teaching. E. S. Santos, I. G. Gavilan, C. Sandoval, E. G. Lejarazo 66. Solid-supported β-dicarbonyl com pounds as building blocks for combina torial chemistry experiments. D. M. Ketcha, B. J. Kohane 67. Curricular threads: An experiment connecting extraction, chromatography, and biological transport. K. J. Brown 68. Educational background of students as the same critical problem for two differ ent curricula at the School of Chemistry. E. Soubiron, M. Rodriguez Ayan 69. Educational purposes of natural sci ences teaching: Students' perspective. M. Rodriguez Ayan, L. Crosa, S. Camarano, A. Amaya, D. Gonzalez, M. Sergio 70. A tale of two campuses: Quantifying the group dynamic. R. J. Wikholm 71. Elemental nucleogenesis in stars using the chart of the nuclides. R. J. Schroeder 72. Establishing a molecular modeling education and research project from the ground up. J. M. Purser, E. Dasinger 73. Fitting experimental pH titration data to a theoretical expression: Estimation of analyte concentration K. W. A. Burns, J. A. Burnett 74. Fluorescence polarization as a viscosity probe. J. L. Jenkins, L. E. Welch 75. Withdrawn. 76. Gas-phase 1 H NMR. T. C. DeVore, C. Drahus, T. N. Gallaher 77. Generation, isolation, and characteriza tion of a stable enol from Grignard addition to a bis-ester: A microscale organic chemistry laboratory. O. Nicaise, K. F. Ostrom, B. J. Dalke 78. Georgia HOPE Scholarship Program: Impact on educational opportunities for African-American chemistry majors at Georgia Southern University. C. M. Davis, C. R. Whitlock 79. Getting students involved in industrial chemical analysis and research through CARL. M. S. Sabo 80. Green fluorescent protein reporter gene system to test for D and L isomers of aribinose. F. DiPino, L. D. Pedersen 81. Implementation of PLTL in sophomore organic chemistry at Northeastern Illinois University. Y. Marcano, A. Velez, A. Fraiman 82. Improved retention and student perfor mance through the use of peer mentors. S. Hiley 83. Incorporating broadband NMR into the undergraduate chemistry curriculum. J. M. Manion, R. M. Tarkka, L. Isom 84. Incorporating hands-on environmental chemistry research projects into general education science courses. C. D. Clark, G. Klimbal, L. Hose, W. J. de Bruyn 85. Institute for the study of medicinal plants of Nicaragua. L D. Pedersen 86. Integrated laboratory curriculum at the U.S. Naval Academy. M. J. Schroeder, D. K. Dillner, R. F. Ferrante, J. P. Fitzgerald, W. B. Heuer
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TECHNICAL PROGRAM 87. Integrating service learning in the envi ronmental chemistry laboratory. A. G. Cavinato, R. B. Kelley 88. Interactive green chemistry laboratory database for educators. J. A. Haack 89. Introducing the costs of laboratory operation in an upper-level undergradu ate course. J. C. Schaumlofffel 90. Kinemage authorship project: Studentauthored teaching materials on the structure and function of proteins. S. W. Weiner, S. Bazel, J. Lopchuk, N. Shah 91. Mass spectrometry as a screen for identifying bioactive species in lichen extracts. T. B. Malloy Jr., J. Romagni, L Vincent, D. D. Wuenschel, D. T. Nguyen, E. Bueso, E. A. Early, R. Blanco 92. National Chemistry Week outreach: Family-oriented soapmaking workshop. I. J. Levy 93. Active chemistry: A new high school chemistry curriculum. C. E. Heltzel, A. Eisenkraft, G. Freebury 94. Nontraditional experiments in an honors biochemistry laboratory course. L. Blau, C. Dobin, D. W. Estes, C. S. Rapp 95. Catch 'em early: A novel research opportunity for incoming freshmen and high school students. B. D. Caldwell 96. Professional development for high school chemistry teachers: An innovative M.S. degree in chemistry education research. S. L Bretz, S. Freemyer, M. B. Nakhleh 97. Project ChemBOND: Technologyassisted interactive learning in introduc tory chemistry. J. E. Haky, C. M. Conway, D. W. Louda, C. E. Carraher, D. Huchital, N. Romance 98. REU site for undergraduate research in chemistry at Wichita State University. D. P. Rillema, E. R. Talaty 99. Chemistry in the community: An out reach program to enhance science education in elementary, middle, and high schools. A. L. McDaniel, L. L. Pesterfield, L. W. Shank 100. Role of oxygen storage/oxygen ionconducting materials in automotive emission remediation. D. W. Carpenetti II 101. Role of partition coefficient in absorp tion and distribution: Assessment of pharmacy lab. S. Phadtare, O. Abanah, A. Butler 102. Role of partition coefficient in drug absorption and distribution: Assessment of pharmacy lab. S. Phadtare, O. Abanah, A. Butler 103. ROMP versus radical polymerization in molecular imprinting. F. Allais, R. T. Martin, R. Mohamed, Ε. J. Enholm 104. Science teachers' views about their needs of didactical support for teaching at the university—Part I: Educational subjects most valued by teachers. M. Rodriguez Ayan 105. Science teachers' views about their needs of didactical support for teaching at the university—Part II: Ways of instruction most valued by teachers. M. Rodriguez Ayan 106. New carbohydrate-related experiments for the undergraduate organic labora tory. P. Norn's, D. Baker 107. Seminar. A very important subject in the chemistry curriculum. F. R. Hello Sr., G. M. José Luis Sr., M. S. Jose Manuel Sr. 108. Sharpless asymmetric dihydroxylation in the organic chemistry majors laboratory. C. J. Nichols, M. R. Taylor
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109. Simulating chromatographic separations in the classroom. C. A. Smith, W. Villaescusa 110. Starting undergraduate research at the ultimate beginning: From freshman chemistry lab to original research projects. M. A. Benvenuto, D. J. R. Brook, M. L Caspers, K. C. Lanigan 111. Students' expectations about science teachers' training. S. Camarano, L. Crosa, A. Amaya, M. Rodriguez Ayan 112. Correlation of dye color with structure: Modular organic laboratory experiments. A. C. Friedli, C. K. Gren, E. C. Moll 113. Surface-enhanced photochemistry: A novel experiment for the physical chemistry laboratory. B. D. Gilbert 114. Comparison of zero-order and secondorder derivatives in the analysis of an absorption spectrum: Application to l 2 . J. J. Diamond Jr. 115. Creation of a computation and visualization laboratory for the natural sciences. K. F. Morris, C. M. Rener 116. Using toys to teach quantum mechanics. T. A. Schoolcraft 117. A project-based molecular spectroscopy component in the undergraduate physical chemistry laboratory. C. L Watkins, T. P. Hamilton, M. J. Jablonsky 118. An attenuated total reflectance sensor for copper An experiment for analytical or physical chemistry. T. Shtoyko, I. Zudans, J. N. Richardson, C. J. Seliskar, W. R. Heineman 119. Synthesis of formyl, hydride, and phosphine complexes of iron carbonyls: An organometallic laboratory design. G. A. Holloway, R. L. Keiter, J. R. Hudgins, J. W. Benson, M. Hayner, J. Lukasek, J. Woolever, M. Yin 120. Taking care of the environment while teaching chemistry. A. Alvarez, I. G. Gavilan, E. S. Santos 121. Teaching chemistry concepts through the history of chemistry. S. P. McMaughan, V. W. Williamson, M. L. Peck, A. N. Stranges 122. Technological literacy and information fluency in a senior chemistry seminar. J. M. Purser 123. Terbium luminescence: A quenching study. J. L Jenkins, L. E. Welch 124. The green organic laboratory curriculum at the University of Oregon: Recent advances in experiment development. G. H. Woehrle, L. Huffman, M. G. Warner, L. McKenzie, R. D. Gilbertson, K. M. Doxsee, J. E. Hutchison 125. A unique polymer experiment in an undergraduate organic laboratory. M. D. Menachery 126. Two unconventional periodic tables. G.Gorin 127. Undergraduate research in chemistry. L L. Maria Eugenia, S. S. Elvira, F. R. Helio, M. S. J. Manuel, G. M. José Luis 128. Use of demonstrations in teaching chemistry. E. McKee, V. Williamson, M. L. Peck 129. Using acid-base indicators to study substitution on sp3 hybridized carbon. F. J. Creegan, N. B. Donis 130. Using the local watershed as an outdoor laboratory: A campus-community partnership. S. C. Dorman, L. K. Stultz, E. A. Yost, S. E. Geist 131. Synthesis and isolation of N-tert-butyl2-phenylsuccinamic acid and N-tertbutyl-3-phenylsuccinamic acid. V. 0 . Cesare, I. Sadarangani, J. E. Rollins, D. J. Costello 132. Synthesis and spectral and thermal properties of pyrazine-bridged coordination polymers of copper(ll) nitrate: An experiment for advanced undergraduates. T. Otieno, M. K. Krepps, A. R. Hutchison, D. Atwood
133. Visualization of qualitative analysis steps for cation separations. J. H. Meiser, J. W. Ribblett 134. Wire less is more. J. L Bennett, T. A. Evans, M. M. Fuson 135. Aggregation patterns in neutral gold(l) complexes: Structures and luminescence from (alkylisocyanide) AuCN. D. Rios, S. Attar, R. L. White-Moms, M. Stender, A. L. Balch 136. /v-Thiolated β-lactams: New sources of antifungal agents. M. L Culbreath, E. Turos, T. E. Long, J. M. Leslie, D. TeStrake 137. Probing the genome of photosynthetic algae and dinoflagellates for the reverse hydrogenase gene. D. M. Thompson, J. J. Akin, M. C. Golden 138. Synthesis and stability of 5-diazoacetyl-2'-deoxyuridine-5'-triphosphate for use in ThermoSELEX. S. W. Thorpe, T. R. Denaro, L. K. C. Tammy, M. C. Golden
10:05 150. Utilization of computer movies to illustrate quantum effects and motion in enzyme reactions. S. HammesSchrffer 10:25 151. Turning students on to organic chemistry by major engagement facili tated by technology. K. A. Sandberg 10:45 152. Using computers in an inquirybased organic chemistry laboratory. F. J. Creegan 11:05 153. What undergraduates need to know about cheminformatics. G. D. Wiggins 11:25 154. Web-based writing and home work assignments using Calibrated Peer Review and Mastering Chemistry. M. D. Perry Jr. SectkxiC Convention Center Room 217
MONDAY MORNING
Chemistry for Nonmajors: Teaching in Never Never Land Courses for Poets, Nurses, Teachers, Inmates, and More!
Section A
J. Paradis, Organizer,
Presiding
K. Stone, Organizer
Convention Center Room 218 Can We Talk? Communication in Chemistry Cosponsored with Presidential Event T. Holme, Organizer 8:10 Introductory Remarks. 8:15 139. Community and communication for professional development: High school chemistry teachers and chemistry education research. S. L Bretz, S. Freemyer, M. B. Nakhleh 8:45 140. Computer-supported collabora tive learning: Communication in an online environment. M. H. Towns, L. Slocum, T. J. Zielinski 9:15 141. Communicate or suffocate: Preparing for today's research environ ment. E. Reichmanis 9:45 Intermission. 9:55 142. Writing about chemistry using Calibrated Peer Review. A. A. Russell 10:25 143. The students shall lead us: A university-community college partnership for curriculum reform. D. J. Wink, D. Lehman, J. Ellefson Kuehn, M. Varelas, M. Nishimura 10:55 144. But what did you really mean? Reaching for student understandings of chemistry. J. E. Lewis, R. Bass 11:25 145. Effectiveness of three commu nication formats: Different strokes for different folks. P. B. Keiter, J. L. Walsh
8:30 Introductory Remarks. 8:35 155. Answering the big questions: The role of chemistry in nonmajor sci ence courses. M. D. Wood 8:55 156. Bruises and joys from teaching chemistry to nonscience majors over an 8-year period. M. J. Baird 9:15 157. Chemistry for preservice K-8 teachers: A work in progress. J. A. Paradis 9:35 Intermission. 9:45 158. Chemistry for the consumer Using a student-directed curriculum. L A. Jacob 10:05 159. Less O, more B: The GoB course gets a facelift. L J. D. Frost 10:25 160. Living in a material world: A new materials science course for nonscience majors. G. J. Brust, L. J. Mathias, J. A. Montgomery 10:45 161. Medicinal plants for poets: Scientific and cultural concepts for nonscientists. B. A. Hanson Section D Convention Center Hall J Undergraduate Research Poster Session: Analytical Chemistry Cosponsored with Division of Analytical Chemistry, and Society Committee on Education L. E. Garrison, Organizer
SectionB Convention Center Room 219 The Cutting Edge: Use of Computers in Teaching and Learning Chemistry Computer Technology for Classroom and Laboratory Use C. Muhoro, Organizer,
Presiding
T. A. Schoolcraft, Organizer 8:30 Introductory Remarks. 8:35 146. Student-authored multimedia projects in the instrumental methods course. H. Van Ryswyk 8:55 147. Lab3D: A virtual chemistry and biochemistry laboratory in three dimen sions. C. M. Grisham, J. K. Cheatham, D. A. DelVecchio, T. Ize 9:15 148. MediaChem: A research-driven, e-leaming alternative to the freshman textbook. R. Tasker, D. Hegarty 9:35 149. Taking advantage of technologi cal tools in the SCALE-UP project. M.T.OIiver-Hoyo, D.Allen 9:55 Intermission.
11:15-1:15 162. Photodegradation of carbon tetrachlo ride using modified and unmodified titanium dioxide. K. D. Illg Jr., D. W. Green, L. B. Lewis 163. A comparison of heating and ultrasonication as methods for wool treatment. M. J. Doyle, A. Sheffield 164. A universal pH scale for biological specimens. L. C. Smith, C. P. Beasley, Z. Ishaq, B. J. Tabor, L. N. Roy, R. N. Roy 165. Acyl-coenzyme A dehydrogenase: Preparation and purification. L L Balcerzak 166. An improved HPLC method for deter mination of D-aspartic acid. E. Galindo, T. Goff, K. Peterson, M. Tsesarskaja, G. Fisher
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CHED/TECHNICAL PROGRAM
167. An inexpensive biosensor capable of detecting HER-2/neu protein, a chemical marker for breast cancer. R. Russell, J. Bowen, L J. Noe, B. P. Sullivan, O. Hanson 168. Analysis by Langmuir-Blodgett tech niques of three novel amphiphilic potyoxotungstates. D. H. McAdams, D. E. J. O. Atkinson, R. C. Chambers 169. Analysis of anions by capillary electro phoresis using indirect absorbance detection. C. Hampton, J. Steumagle, E. F. Healy 170. Analysis of photochemical products in sunscreens. D. Banks, C. Grant, D. Moore, K. LaiHing 171. Analysis of phytosterols and fatty acids in raw peanuts, defatted pellets, and a new peanut snack chip. S. N. Komisarow, A. L Alkjood, Y. Huang, B. P. Koehler 172. Analysis of the pyrolysis products of smoked drugs of addiction. T. Naples, J. C. Schaumloffel, J. Miller 173. Analyzing amino acids with capillary electrophoresis utilizing a fluorogenic label. A. M. Carter, J. T. Smith 174. Analyzing amino acids with capillary electrophoresis utilizing NDA as the fluorophore. J. A. Kilgore, J. T. Smith 175. Aspartame: A study about the kinetics of the decomposition of aspartame and its decomposition products in various aqueous solutions. J. F. Belliveau, H. Griffon, E. M. Williams 176. A study of bioconcentrated phthalate esters in the aquatic plants and daphnia of the Snake Lake watershed and a discovery of an unexpected phthalate. G. L Anderson 177. Bradykinin hydrolysis by cyanobacterial cells extracts. C. D. Joseph. J. Sigman, A. Wotfson 178. Buffers for the physiological pH in saline solution of ionic strength 1=0.16 at 25 and 37 °C. Κ. Τ. Robinson, M. P. Cummins, J. G. Grant, C. A. Himes, L. N. Roy, R. N. Roy 179. Can anodic stripping voltammetry measure lead leached from brass fit tings? A. M. Boyd, C. Josefson 180. Capillary and microelectrophoretic technology development for colorectal cancer applications. S. E. Sutton, G. A. Thomas, R. Sinville, H. Farquar, S. A. Soper 181. Capillary electrochromatography with butyl acryiate polymers: Temperature studies and homologous series behav ior. L J. Sondergeld, M. E. Bush, M. M. Bushey 182. Catechol detection by a tyrosinase electrode. M. Durand, D. W. Paul 183. Characterization of clays and 17thcentury bricks from historic St. Mary's City, Maryland. N. Houser, R. A. Armitage 184. Characterization of cross-linked poly mer films for incorporation into spectroelectrochemical sensors. W. Heineman, S. ConWin, L E. Faulkner 185. Characterization of optical probe light penetration depth for noninvasive analy sis. K. Hampton, A. G. Cavinato, D. M. Mayes 186. Classification of gender and maturity status in Chinook and coho salmon by short-wavelength near-infrared pectroscopy. K. Hampton, A. G. Cavinato, T. Hoffnagle, D. M. Mayes 187. Colloidal spheres as building blocks. C. K. Gren, C. R. Allison, A. F. Farmer, A. C. Friedli 188. Comparison of carbohydrate oxida tions at nickel and copper electrodes by cyclic voltammetry. M. N. Baker, C. M. McGuinness, P. D. Voegel 189. Comparison of enzyme-substrate couples for bead-based immunoassays with electrochemical and fluorescence detection. M. V. Boost, S. Farrell, H. B. Halsall. W. R. Heineman, C. J. Seliskar
190. Complexometric titration endpoint detection with an inexpensive laser pointer spectrophotometric probe. A. R. Howard, W. T. Grubbs 191. Computer-aided stationary phase design: Accuracy checks. S. D. Gardner, K. Allen 192. Computerized microscopic particle size distribution analysis. P. K. Veronese, S. Brande, W. K. Nonidez, A. P. Gies 193. Coumaryl crown ether based chemosensors: Selective detection of saxitoxin in the presence of sodium and potassium ions. P. Kele, J. Orbulescu, T. L Calhoun, R. E. Gawley, R. M. Leblanc 194. Coupling fluorescence probes for singlet molecular oxygen with nanoscale separations. D. M. Metcalf, R. E. Milofsky 195. Covalent coupling of antibodies to carboxylated microspheres via the carbodiimide linking method. S. Hopen, S. D. Minteer 196. Cross-validation fallacies vs true predictions in quantitative structure activity/property studies: GC retention times of polychlorinated biphenyls. Y. Caire, W. C. Hemdon 197. Cyclic voltammetry of aminophenol and aminocresol in a pyrazole and imidazole system. D. P. Lydon, F. R. Hilgeman 198. Dendrimer-capped bimetallic nanopartides. H. Nanaie, I. Emenike 199. Detection of antineoplastics in waste and surface waters using GC/MS. K. Price, A. C. Dema, D. RutJedge 200. Detection of protease activity on a quartz crystal microbalance. J. D. Pollard, J. A. Evans, A. Denson, N. Fawcett 201. Determination of catechins in matcha green tea by micellar electrokinetic chromatography. C. R. Anderton, D. J. Weiss 202. Determination of elemental concentra tions and lead isotope ratios in teeth from Solis, Mexico; Kalama, Egypt; and Bronze Age Magan in Tell Abraq, UAE, by inductively coupled plasma-atomic emission spectroscopy and mass spec trometry. E. Webb, S. Tauch, E. Greene, A. Goodman, D. Amarasiriwardena 203. Determination of ionic species in solution by SW-NIR spectroscopy. C. A. Fahlstrom, A. G. Cavinato 204. Determination of melatonin in wheat, Triticum aestivum. C. A. Hansen, J. Ward, M. Rincon-Zachary, J. Weger 205. Determination of PAHs in tobacco smoke. M. P. Kotlarczyk, J. H. MacNeil 206. Determination of the components in water samples along the Appalachian Trail. P. M. Schaber, K. A. Burke, V. Maher, S. Gordon 207. Determination of the viscosities of methanolic surfactant solutions of rel evance to capillary electrophoresis separation of fatty acids. J. M. Sutara, M. E. Johnson 208. Determination of trans fatty acids in French fries and margarines. R. L Gilliam. Ε. Μ. Hairfield, H. H. Hairfield Jr. 209. Development of a GC/MS method for detection of -y-hydroxybutyric acid and its precursors. K. Helwkj, A. C. Dema, L. A. Wetmore 210. Development of a solid-phase extrac tion method for apurinic DNA. L. B. Mason, J. A. Sobrino, K. P. Roberts 211. Development of a thin-film sensor for the detection of nerve agents. J. M. KHa, J. Parker, S. N. Home, J. C. DiCesare 212. Development of a universal method to identify DNA viruses by AFLPs. A. D. Peltier, G. A. Mabbott 213. Development of an enzymatic diges tion procedure for quantification of apurinic sites in DNA. J. A. Sobrino, L. B. Mason, K. P. Roberts
214. Development of automated acid-base titrations using LabVIEW programming and a LabPro interface. M. D. Reagan, K. A. Kneas 215. Early analysis of Fe/Si meteorites in order to determine a connection with asteroids. N. L Hagedorn, D. Sears, P. H. Benoit, M. S. Kareev 216. Effect of methyl viologen in dye solu tions during sonoluminescence. D. E. J. O. Atkinson, J. Murray, K. N. Danskey, D. Hidalgo 217. Electroanalysis of amino acids at diamond thin-film electrodes. A. Jockheck, E. Kara, E. Hamond, K. Miles, G. M. Swain 218. Elucidation of cellular doxorubicin metabolism and metabolite structure using capillary electrophoresis with laser-induced fluorescence detection. J. A. Nielson, E. A. Arriaga, A. Anderson 219. Estrogen regulation of MRP1 in MCF-7 and MCF-7/VP breast cancer cell lines. A. C. Odium, K. Procko, D. Dean 220. Experimental double potential step methods software. V. W. Caruso, T. T. Wooster 221. Expbrations of Brij 30 to modify selec tivity in micellar electrokinetic capillary chromatography. T. Putnal, J. T. Smith 222. Fluorescent derivatization techniques for the analysis of biogenic amines. B. J. Flores, T. L. Whitehead 223. Forensic analysis of -yhydroxybutyrate by headspace SPME-GC. K. L Fish, J. M. Miller 224. FTIR analysis of mouse urine for its urea content. P. Furlan, J. Servey. S. Scott, K. Fesenmyer, A. Mattocks, L. Liu, J. Hartshome, M. Peaslee 225. Fullerene-dibenzo[18]crown-6 conju gates: Synthesis and cation-complexation-dependent redox behavior. N. Y. Nguyen, P. M. Smith, A. L. McCarty, M. E. Zandler, B. S. Sherigara, F. D'Souza 226. GC-MSD analysis of AFC emission from new building construction on the Middlebury College campus. M. D. Dagan, L. DelNegro 227. Hemoglobin electrochemical response at a surfactant covered electrode. C. A. Guessford, C. M. Neal, L H. Rickard 228. Identification of esters in oxidized asphalts. C. Smith, J. Hardee Jr. 229. Influence of the C-terminal amino acid on the formation of (b3+17+Cat)+ prod ucts from tetrapeptides. L C. Pyke, M. VanStipdonk 230. Introducing analytical biochemistry across the curriculum using capillary electrophoresis and the case study approach: The case of the gentleman farmer and the blue baby. P. M. Schaber, K. D. Berchou, S. Szczepankiewicz 231. Investigating single-molecule fluores cence dynamics on surfaces. M. C. Brown, D. L. Burden 232. Investigation of near-infrared optical parameters in fish tissue by photon time-of-flight analysis. J. L Wutzke, C. A. Fahlstrom, A. G. Cavinato, Z. Wang, M. Lin, B. A. Rasco 233. Investigation of soil arsenic concentra tions in the Worcester and Acton com munities. C. Lillie, J. M. Van Doren 234. Investigation of the holding time limits of a number of semivolatile organic compounds. A. S. Arora 235. Investigation of the microenvironment and microviscosity surrounding a model solute randomly dispersed in poly(dimethylsiloxane). K. P. Alter, W. M. Hayter, E. D. Niemeyer 236. Isolation, purification, and identification of biologically active naphthoquinones from heartwood of Thespesia populnea. M. Pacheco, C. A. Smith 237. Laser pyrolysis of cellulose using Fourier transform ion cyclotron reso nance mass spectrometry. K. Leibold, C. D. Hanson
238. Looking anew at the red flash of copper-dimethylglyoxime in a basic, oxidizing medium. A. M. Summey, A. N. Starks 239. Looking at soil as a sink for atmo spheric methyl bromide. D. M. Von Ruden, M. A. Engen 240. Low-cost thin-layer chromatographic analysis for ochratoxin A in green coffee beans: Implementation in developing countries. A. Sly, M. Knoll, H. Luong, S. Jackets 241. Methodological comparison of pesti cide detection using GC-ECD and ELISA. J. A. lera, J. Wallace, T. Greco. S. L. Turchi 242. Micellar liquid chromatography of polycyclic aromatic hydrocarbons: Alkylpyndinium chloride as a mobile-phase modifier and selective fluorescence quencher. K. E. McGill, C. Mao, S. A. Tucker 243. Optimization of an HPLC method for analysis of common OTC drugs. S. M. Puolitaival, D. S. Pinkston, M.S.Sabo 244. Optimizing colloidal silica synthesis and properties. C. R. Allison, M. W. Hobkirk. C. K. Gren. M. R. Wells. A. C. Friedli 245. Origins of methane in human breath. J. R. Aponte, D. R. Blake 246. Photo-efficiencies of different octasubstituted phthalocyanine dyes and tem perature dependence of Ti0 2 surface preparation. C. L Stender, E. J. O. Atkinson, J. F. Scott 247. Plasma patterning of polymer sub strates. W. B. Schwisow. E. R. Fisher 248. Potentiometric investigation of ion activities across Nation membranes. E.E.Wierchowski. S. H. Szczepankiewicz 249. Preparation and characterization of humidity-buffering systems. D. N. LeCrone. K. Wesley. C. Brown. R. Wang 250. Quantification of 4(/V,AWimethyl-/Vtetradecylammonium) methyl(7-hydroxycoumarin) chloride acid/base chemistry in CTAB-heptanol-H20-cyclohexane reverse micelles. R. L Poole, R. E. Rrter 251. Quantitative determination of alcohol levels in herbal supplements. C. Nguyen. H.T.McKone 252. Quartz crystal microbalance and voltammetric studies for the adsorption of benzenethiol on gold. R. J. Castro, E. Garcia, A. Suarez 253. Raman and surface-enhanced Raman scattering of aqueous nitrate and nitrite. B. R. Pappas, B. D. Gilbert 254. Recent developments in the optimiza tion of ultrafast cocatalyzed peroxyoxalate chemiluminescence detection in capillary separations. B. D. Lorenz, R. Milofsky 255. Remediation and toxicity of dyecontaminated water. J. J. Meeks, J. A. Bumpus, L. Beltz 256. Separation of microorganisms via capillary electrophoresis. D. Hamburg. S. Ponder, G. Stone, B. Jones, D. Smith, R. Nevins, T. J. Ward 257. Sitver(l) catalysis of chromium(lll) oxidation with persulfate. E. Finn, J. Friese, S. B. Clark 258. Simulating and analyzing molecular movement in lipid membranes: A key to tissue engineering. D. A. Stults, E. L. Rupp, D. L. Burden 259. Solid-phase extraction and analysis of treated wastewater using GC/MS. S. Adams, S. K. LaiHing, C. Williams, K. LaiHing
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
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TECHNICAL PROGRAM 260. Solution residue analysis in glow discharge spectroscopies. K. R. Hess, J. L. Steinbacher, M. L Hansen 261. Spectroscopic characterization of anion interactions with Indium(lll) octaethylporphyrin dimers: A model for explaining the electrochemical and optical anion selectivity of polymer films doped with this ionophore. Y. V. Kondratenko, Μ. Ε. Meyerhoff, P. G. Parzuchowski 262. Study of pyoverdine-type siderophores newly isolated from Pseudomonas aeruginosa ATCC strain 15152. C.A.Brodnax, D.LHull, L. Eng-Wilmot 263. Supercritical C 0 2 extraction of antioxi dants from herbs and characterization of antioxidative activity using HPLC and UV-vis spectrophotometry. J. C. Schreck, C. Fish 264. Synthesis and immobilization of [Co(diAMsar)]CI3 onto an alkanethiol self-assembled monolayer. A. M. Fond, Τ. Τ. Wooster 265. The application of deuterium NMR to recognition of synthetic vs corn-derived alcohols. L Lowman, Κ. Ε. Clarke, A. D. H. Marchetti, S. Schreiner 266. The effects of fire retardants on the detection of arson accelerants. A. J. Calderone, C. Fish 267. Thermodynamic study of the zwitterionic buffer CABS from 5 to 55 °C. B. R. Lively, L. C. Smith, C. P. Beasley, S. J. Richards, L. N. Roy, R. N. Roy 268. Thermodynamics of a zwitterionic compound "HEPBS" in water from 5 to 55 °C. J. G. Grant, M. S. Lamb, J. M. Denton, R. Singh, L N. Roy, R. N. Roy 269. Using capillary electrophoresis to monitor metabolism in Medicago truncatula. B. Williams, J. T. Smith 270. White-tailed deer antlers as a potential biomarker of atrazine exposure. N. R. Taylor, J. L. Franz Section Ε Undergraduate Research Poster Session: Chemical Education Cosponsored with Society Committee on Education 11:15-1:15 271. An analysis of cylcodextrin inclusion complexes by NMR chemical shift analy ses and pulsed-field gradient diffusion experiments. B. A. Elrff, K. F. Moms 272. Applying innovative evaluation meth ods to a general chemistry course. M. Chandler, J. S. Russell, C. Deibel, P. J. Ogren 273. Bradford assay under fire: A study of common protein assays for the under graduate biochemistry laboratory. L J. DeLong Frost, C. M. Davis, A. Stewart, S. Peart, Ζ. Ν. Spencer 274. Darzens condensation: Structure determination through spectral analysis and understanding substrate reactivity. R. D. Crouch, M. S. Holden, C. A. Romany 275. Determination of Planck's constant using light-emitting diodes. L Diaz, C. A. Smith
276. Development of a "green" aldol con densation project for the organic chemis try laboratory. Z. Ishaq, M. G. Hlatshwayo, E. Stone, J. Bennett 277. Development of experiments for the undergraduate biochemistry laboratory. J. R. Lageman, F. C. Mayville Jr. 278. Development of the laboratory compo nent to physical chemistry for a biologi cal sciences course. R. L Felts, B. Caldwell, M. W. Ducey Jr. 279. Diode laser spectrometers in the undergraduate laboratories. M. Sobansky, D. A. Treichel 280. General chemistry experiments using the LabWorks interface and a Pocket PC. M. E. Morgan, S. D. Vines 281. Gulf Research and Development Co.: Contributions to chemistry. K. J. Stutz 282. Kier Refinery (circa 1850). J. E. Winans, H. A. Figore, T. J. Weismann 283. Learning chemistry and emotional intelligence. R. Baez-Galib, W. Resto, J. Velazquez, D. De Jesus, O. Santos, C. M. Gonzalez, M. Diaz, E. Calderon 284. Mellon Institute: Contribution to ACS Pittsburgh Section Centennial. J. Miller 285. Peer-led team learning: The student leader's perspective. C. S. Cole, B. Blake 286. Photolithography using sunlight: An active learning activity for chemistry undergraduates. E. A. Hernandez, S. P. Hernandez, M. E. Castro 287. Polydimethylsiloxane: A versatile polymer for teaching in the laboratory. C. M. Browning, M. J. Schroeder 288. Project-based forensic experiments for general chemistry. A. M. Thomson, J. M. Goerdt, K. F. Morris 289. Quantitative diffuse reflectance infra red analyses of various commercial solids. A. Urbina, C. A. Smith 290. Rhodium-catalyzed formation of unsymmetrical 5-7-5 ring systems. M. P. Zacharias 291. Roger Williams University students engage high school classrooms in chemistry. J. M. Panos, C. P. Gecewicz, S. K. O'Shea 292. Supplemental instruction for introduc tory chemistry courses at North Dakota State University. A. M. Richter, J. Augdahl 293. Synthesis and thermal analysis of liquid crystals: A new laboratory experi ment for organic chemistry. K. E. Anderson, E. Scharrer 294. Synthesis of biphenyl propargyl ethers as cytochrome P450 1A2 inhibitors. B. L Bowman, T. P. Smith, M. Foroozesh 295. Taking the universal out of the univer sal fix-it: A chemical-forensic analysis of duct tape. J. J. Schmitz, R. A. Pribush, R. P. Walson 296. Thermogravimetric analysis of polymer degradation: A new laboratory experi ment for physical chemistry. J. O'Dea, E. Scharrer, K. Rousslang 297. University of Toledo summer camp for the integrated activities grant. S. M. Scully, E. L. Hannay, R. L. Skiver, D. A. Vodhanel, M. A. Blankenburg 298. Utilization of a trivia-style facilitated review in an introductory chemistry course. C. Gatzki, B. Blake 299. Women in chemistry: Educate and empower. C. P. Higginbotham, R. A. Richards, A. Brackman, S. Hart, L.Lee
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
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SectionF Undergraduate Research Poster Session: Environmental Chemistry Cosponsored with Division of Environmental Chemistry, and Society Committee on Education 11:15-1:15 300. In situ laser studies of chromium interaction with quartz-water interfaces. K. A. Gerth, A. L. Mifflin, Β. Μ. Weiss, F. M. Geiger 301. A chemical transformation laboratory for environmental chemistry. M. Reynolds, F. M. Dunnivant 302. Activity coefficients of HCI + PrCI3 + H 2 0 from 5 to 55 °C. C. A. Himes, M. P. Cummins, L N. Roy, R. N. Roy 303. Analysis of contaminant levels in various tissues of local seals. S. E. Keach, S. K. O'Shea, P. M. Webb 304. Analysis of public water samples for ibuprofen and acetaminophen content. J. J. Beyer, R. E. Berg 305. Analysis of treated wastewater for the detection of triclosan using GC/MS. C. Monroe, K. LaiHing 306. Analysis of wines for pesticides using HPLC. S. Arlington, P. BridwellVallonw, M. Railing 307. Baseline pesticide analysis of stream sediments at the Greene Field Station. M. L Riha, S. M. Brastad, J. J. Piatt 308. Bioaccumulation of heavy metals by plants in the San Gabriel River. K. F. Schrum, H. M. Thorpe 309. Biochemical reduction of nitrate levels in water systems by bacteria in decom posing organic matter. T. M. Schramm, J. J. Becker, D. E. Bartak 310. Characterization of the reaction of aqueous chlorine dioxide with chloramine. T. J. Hoppe, B. C. DeCoursey, G. H. Purser 311. Chemical analyses of the Catawba College ecological preserve. E. M. Keller, J. P. Sandman, D. J. Shissler, M. S. Sabo 312. Comparative analysis of solid-phase extraction media for the rapid isolation of fluorescent whitening agents. J. P. Templet, E.A.Cioffi 313. Comparison study of treated and untreated water by ion chromatography. H. N. Josey, R. Fietkau 314. Desorption kinetics of hydrophobic compounds from lake sediment suspen sions. F. M. Dunnivant J. Wnuk, J. Jacka 315. Determination of metal concentrations in vitrified coal slag by atomic emission spectroscopy. J. A. Teprovich Jr., Ε. Ε. Homing 316. Determination of ozone precursors on airborne fine particulate matter using GC/MS. J. Spencer, M. J. Baird 317. Determination of PCBs in the Housatonic River, MA, by SPME and GC-ECD. J. Wells, J. C. Schaumloffel 318. Determination of the physical proper ties of perfluorinated acids using 19F NMR. K. A. Pratt, D. A. Ellis, T. E. Burrow, S. A. Mabury 319. Determination of tributyltin and stress proteins in Mercenaria mercenaria. D. M. LeBlanc, S. K. O'Shea 320. Developing photocatalytic materials for water purification. N. Why, J. C. DiCesare 321. Effect of temperature, pH, and UV radiation on the stability of tetracycline, a potential antibiotic pollutant in local water systems. S. Inglis, D. Mercer, M. J. Baird 322. Effects of environmental levels of cyclophosphamide on Daphnia magna. S. Staton, A. C. Dema, D. Rutledge
323. Effects of new building construction at Middlebury College on global climate change. M. D. Dagan, L. DelNegro 324. Effects of planned burning upon soil chemistry of restored grasslands. K. A. Koenig, L. Sherman 325. Enantiomeric analysis of chiral pesti cides in indoor air, perimeter soil, and house dust. A. M. Yingling, R. L. Falconer 326. Enantiomeric composition of chiral pesticides in soils from three Midwestern states. K. A. Haslett, R. L. Falconer 327. Environmental sampling and modeling in the undergraduate curriculum. M. A. Rury, N. Gao 328. Environmental water analysis: Pollut ants, standards, and the use of ICP. S. E. Hileman, J. C. Livingston 329. Examination of the interactions of endocrine disrupters with the human chorionic growth hormone using fluores cence spectroscopy. R. J. Lowry, E. J. Billiot, F. Billiot, R. Lowe 330. Extraction and detection of pharma ceuticals and personal care products in North Alabama water using GC/MS analysis. L Melbourne, K. LaiHing 331. GC/MS analysis of MTBE and its metabolites in saltwater. J. E. Fliegler, M. E. Hatcher 332. Ground-level ozone concentrations in southeast Texas. J. D. Ortego, C. Rodriguez, P. Nguyen, L. Blanton, L. Cauthen, J. Walls, K. Hall, J. Iglesias, R. Iglesias, T. Foster, S. Hawkins, S. Quadri, Β. Carrion, Κ. Borel, Κ. Siragosa, Η. Celeste, J. Clark, A. Alleman, D. Middleton, C. Jenkins 333. Identification of toxic chemicals in glue vapors using GC/MS. J. Richer, M. J. Baird 334. Integration of UV radiation into Army small-scale water treatment devices. K. Moon, M. P. Labare, J. A. Starke, M. B. Kelley, M. Talbot, M. A. Butkus 335. Interactions of modified polysaccha rides in natural materials with heavy metal cations. E. Krueger, P. Tomasik, D. S. Karpovich 336. Investigation of PCB contamination in steelhead liver. C. A. Davis, R. S. Thompson, A. G. Cavinato 337. Is there a correlation between soil health and water quality? A. Smisek, J. R. Schultz 338. Lead testing in area secondary schools using anodic stripping voltammetry. A. Louwagie, L. Lundbohm, J. H. Brown 339. Metal binding properties of two marine bacterial isolates. P. A. Thomson, D. E. Riegner, M. P. Labare 340. Methyl halide production in Vermont soils. M. F. Clasquin 341. Nanodots to nanorods: Goethite nanoparticle growth by oriented aggregation. A. P. Mostrom, R. L. Penn, Y. Guyodo 342. PAH concentrations near Chester River boat ramps. D. W. Himmelberger, J. Locker 343. Physiological response to heavy metal exposure in Mercenaria mercenaria. E. L Whitson, S. K. O'Shea 344. Possible causes for the decline of Homarus amencanus of Long Island Sound. T. E. Donovan, S. K. O'Shea 345. Rates of reaction and temperature dependencies for four branched alkanes with the hydroxyl radical. L Gilbert, A. M. Jacoby, S. Kukta, E. W. Wilson Jr. 346. Real-time nutrient mapping in the Mississippi River plume employing an automated multichemistry nutrient ana lyzer. A. N. Paschal, V. Williams, J. W. Ammerman 347. Respiratory-deficient yeast response to paraquat and nitrotyrosine. S. Sherwood, E. Karlin, M. Forszpaniak, J. R. Schultz
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348. Response of a marine bacterium to elevated levels of carbon dioxide. J. Schwartz, M. P. Labare, J. T. Bays 349. Restoring the environment: Cleaning a local stream. N. Viswanathan, A. Shortis, C. Collins, P. Stemple 350. Role of cysteine in the reductive dissolution of ferric oxides and the subsequent transformation of 4-cyanonitrobenzene. D. M. Omiatek, J. M. Smolen 351. Seasonal impact on the water quality of a wildlife pond. M. A. Maher, E. A. AlkhatJb 352. Sediment metal contamination at the West River Memorial Park, New Haven, CT. R. O. Nicholson. D. V. T. Breslin 353. Single-particle analysis of diesel particulate matter A comparison of realtime and integrated measurements. D. S. Gross, A. M. Schmitt, A. M. Silverberg, S. Okada, C. Kweon, J. C. Stetter, M. M. Shafer, C. G. Christensen, D. E. Foster, J. J. Schauer 354. Solution medium effects on the photochemical reactions of pyrene in water. J. Ting, C. D. Clark 355. Sonochemical degradation of naphthol: Effect of H and OH radical scavengers. M. Maurin, W. Zheng, M. A. Tarr 356. Spatial distribution of polycyclic aromatic hydrocarbons in the Sassafras River. S. L Halpin, J. R. Locker 357. System HCI + NdCI3 + H 2 0 from 5 to 55 °C: A study of Hamed's rule. B. J. Tabor, M. P. Cummins. M. Pesek, L. N. Roy, R. N. Roy 358. The continued assessment of Beaver Creek water quality: What are the overall trends and what do they indicate? S. J. Fowler 359. Using the optical properties of colored dissolved organic matter as a tracer for bacteria sources in coastal waters. A. P. O'Connor, C. D. Clark 360. Water quality determination prior to the discharge of reverse osmosis effluent from municipal water treatment. E. Merkel, M. Durand, S. Msinjili, P. D. Voegel 361. Water quality of Iowa's lakes and rivers. E. C. Tsamis, L. Wright, J. A. Bumpus, S. Liégeois, W. Stigliani, M. Clayton, S. Wickman, E. J. Brown, H. M. H. Wood, R. Burks Section G Undergraduate Research Poster Session: Medicinal Chemistry Cosponsored with Society Committee on Education 11:15-1:15 362. /v-(2-naphthylmethyl)-substituted polyamine derivatives as inhibitors of Trypanosoma cruzi trypanothione reductase. J. DeLuca, J. Rose, M. Kobaslija, M. O'Sullivan 363. Analysis of stathmin and MAP-4 content in Taxol-resistant cell lines. J. Josovitz, P. Verdier-Pinard, S. B. Horwitz 364. Bacteriostatic activities of skunk cabbage (Symplocarpus foetidus) plant extracts. D. McDonough, E. Kovalchik, F. DiPino, L. D. Pedersen, J. lirio 365. Cell-type specific induction of apoptosis after influenza A virus infection. M. B. Ortigoza, C. Newby. J. K. Ly, M. McCown, A. Pekosz 366. Cytotoxicity of ethanol extracts of skunk cabbage (Symplocarpus foetidus). E. Kovalchik, D. McDonough. L. D. Pedersen. F. DiPino, J. Lirio 367. Determination of amphiphilicity as a factor in trans-bilayer transport. N. D. Grabher, V. Lukacova, S. Balaz
368. Effects of ionizing radiation on DNA: The role of podophyllotoxin on radiation damage. J. Moss, T. Lien, A. Pezeshk 369. Effects of radiation on DNA: The role of porphyrin-like ligands on radical damage. T. Lien, J. Moes, A. Pezeshk 370. Extraction and determination of relative ellagic acid concentrations in Fragaria ananassa fruit grown in varied light and fertilizer conditions. Ε. Μ. Ashman, M. S. Rice 371. Improving biological activity of certain benzodiazepines through QSAR. M. G. Costner, M. D. Perry Jr. 372. Inhibition of trypanothione reductase and trypanocidal activities of N-(3phenylpropyl) spermine derivatives. A. Bitar, J. DeLuca, M. Kobaslija. C. Bacchi. M. O'Sullivan 373. Interaction of avidin with boric acid gel polymer suspensions. B. J. Bench, J. R. Wright 374. Investigation of the effect that different drying methods have on the mechanism of acetaminophen release from microcrystalline cellulose beads (Part 3). A.T.Neff, F. C. Mayville Jr., R. J. Wigent 375. Isolation and characterization of naphthazarins and pyrrolizidine alkaloids found in Lithospermum multiflorum. R. D. Champion, D. R. Kuenzi, M. F. Auble, R. B. Kelley 376. Isolation and structural elucidation of novel compounds from marine sponges. S. Lopez 377. Isolation of naturally occurring furofurans from Zanthoxylum clava-herculum and their toxic effects on representative gram-negative and gram-positive bacte rial species. R. Collison, T. Everett, L. Stewart, D. M. Solomon, R. Upchurch 378. Laser-induced photochemistry of nickel-substituted phthalocyanine for use in photodynamic therapy. T. Nicholson III, J. Collier, K. LaiHing 379. Molecular recognition of peptoid foldamers targeting the EVH1 domain. N. A. Perry, J. D. Kehlbeck 380. Nonactive site-directed inhibitors of human thymidylate synthase. R. Saunders, L. Lovelace, L. Lebioda, A. W. Williams, S. Johnson 381. QSAR of cholecystokinin. E. L Carpenter, M. D. Perry Jr. 382. Role of PKC isotypes in sphingosine1-phosphate-induced phospholipase D activation and IL-8 secretion in human bronchial epithelial cells. L. M. Ballard, T. Watkins, D. Hong He, R. Cummings, J. G. N. Garcia, V. Natarajan 383. Streptomycin degradation: The hunt for streptobiosamine. E. K. Herrick, J. L Miller. R. P. Norris. L. Stephens 384. Synthesis of a series of isatin-sulfonic acid thiosemicarbazone compounds. E. C. Lisic, T. J. Bell. R. T. Mayes 385. Synthesis of GGPP analogs and their evaluation as GGTase I inhibitors. E. L. Rickert 386. Synthesizing potential anticancer therapeutics based on the 1-benzosuberone. L Craft, J. C. DiCesare 387. Tracking and targeting Τ lymphocytes in spinal cord injury. M. D. Velez 388. Tryptanthrins: A synthetic route to bioavailability. B. Stanton, D. Nichols 389. Validation of microarray-revealed gene expression in human coronary artery endothelial cells. S. C. Araujo, L. Gao, T. Lavoie, B. Rumala, J. G. N. Garcia, S.Ye
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Section Η Undergraduate Research Poster Session: Organic Chemistry Cosponsored with Society Committee on Education 11:15-1:15 390. 3,4,5,6-Tetrahydro-2H-1,3,4-oxadiazin2-ones as chiral auxiliaries: Synthesis and application in the aldol addition reaction and conjugate addition. S. R. Hitchcock, J. Finefield 391. 1 H DNMR determination of the ring-flip barrier in 3,5-dimethyl-1-oxa-3,5-diazacyclohexane. C. DuBray, J. H. Brown 392. A convenient synthesis of 2,3-bis(1,3benzothiazol-2-yl)oxirane-2-carbonitrile. W. J. Hernandez, Κ. Μ. Hernandez, D. Burgos, F. Martos, J. Evans, O. Cox 393. An acid-catalyzed aldol reaction under microwave-induced solvent-free condi tions. T. L Friebe, M. J. Hyde, T. Upan 394. An investigation of the induction capa bilities of oxazolidinones in the enantioselective formation of methyldeoxybenzoin. J. R. Chapman, N. J. Turro, T. Poon, P. Lakshminarasimhan, S. Bosio, W. Adam, S. Jockusch, X. Lei, Z. Liu, V. Ramamurthy 395. An optimization study for the formation of a bidirectional bis-oxamide linked dendrimer. S. A. Henrie, R. D. Cabanaw 396. Anions of 1-substituted-1,2,4-triazoles as nudeophiles. V. C. Reddy, D. R. Haines, C. A. Rabik 397. Annulating agents for construction of bicyclic 1,2,4-triazole systems. P. V. Freedman, Ν. Ε. Savig, D. R. Haines 398. Annulation onto 1,2,4-triazole via a Michael-type reaction. Ν. Ε. Savig, N. Siripong, D. R. Haines 399. Antitoxins for the in vivo catalytic hydrolysis of nerve agents. A. M. Chubb, K. L Keams Jr. 400. Approaches to the synthesis of designer estrogens using twofold extru sion reactions. A. A. Alcaraz, F. S. Guziec Jr. 401. Asymmetric aldol addition reactions of sterically congested 3,4,5,6-tetrahydro2H-1,3,4-oxadiazin-2-ones. S. R. Hitchcock, J. T. Trotter 402. Asymmetric synthesis of Atethanol succinimide derivatives. M. R. Naffziger, P. T. Buonora 403. Atranyl-nucleosides: Synthesis, char acterization, and ribozyme structure application. M. C. Mauck, I. M. Asif, E. E. Fenlon 404. Attempted ring addition to 3,5-dimethyl-1,2,4-triazole. E. G. Mazzarella, D. R. Haines, N. Siripong, A. C. Doran, T. J. Chen 405. Beckmann rearrangement studies on the oximes of 2-methyl-1-indanone and 2-methyl-1-indenone. N. B. Donis, F. J. Creegan, D. R. Rawson 406. Bicyclic ring systems from appropri ately substituted triazoles. C. I. Worrell, D. R. Haines, N. Siripong 407. Borane trifluoride catalyzed borane reduction of O-silylated aromatic oximes. M. Ortiz, L D. Rivera, Ο. Ε. Casanova, M. De Jesus Flores 408. C-3'-DNA conjugates. J. Fancher, A. C. Bryant-Friedrich 409. Chemical analysis of preovulatory female African elephant urine: A search for putative pheromones. W. M. Dill, B. L Davis, A. R. Hicks, T. E. Goodwin, L. E. L. Rasmussen, H. Loizi, B. A. Schulte 410. Chemistry-guided fractionation of plant natural products. C. Monroe, G. Belofsky
411. Chiral induction through axial ligand substitution of ruthenium(ll)-salen com plexes for the cyclopropanation of sty rène. J. M. Bilas, S. Nguyen, J. A. Miller 412. Chiral recognition: Anion receptors derived from isophthaloyl dichloride, 2,6-pyridinedicarbonyl chloride and 1,3-benzenedisulfonyl chloride, and readily available chiral amines. J. M. Rodriguez, P. J. Galarza, A. J. Sabucedo, K. Kavallieratos 413. Chirality: Is there a dependency on activity in herbicides? J. B. Golden, P. P. Dutton, D. C. Forbes, M. R. Perkins, T. D. Sherman 414. Cholesteric liquid crystal displays as optical sensors of barbiturate binding. R. C. Chambers, K. D. Ragan, E. J. Bell 415. Combinatorial libraries using a novel benzothiazine scaffold. J. L Goodman, T. A. Knoerzer 416. Comparative study of fluoxetine synthesis using microwave technologies. E. E. Battin, H. Boylan 417. Comparative study of naphthalimide fluoroionophores: Ligand design toward metal ion specificity. J. Elbert, L. Robinson, S. Elzey 418. Comparing proton-transfer reactions of p-N02C6H4CHCICF3 in methanol» methoxide to other YC6H4CHCICF3. H. F. Koch, A. R. Kurland, G. Lodder, M.SIegt 419. Comparing the preparation of /V-arylenamino ketones with standard reflux conditions to microwave methods. D. R. Dillin, C. H. Chow, W. F. Long, D. G. Watson 420. Comparison of a series of acenaphthoquinone thiosemicarbazone compounds. E. C. Lisic, R. A. Lawson, R. T. Mayes 421. Composition of lipids from sunflower (Helianthus annus) and curia (Justicia pectoralis) medicinal plants collected in Puerto Rico. E. D. Reyes, Y. Ortiz, O. Santos, E. Vazquez 422. Conformational analysis of a covalently cross-linked Watson-Crick base pair model. E. A. Jensen, D. J. O'Leary, B. D. Allen, Y. Kishi 423. Conformational analysis of the ornithine β-turn unit via X-ray crystallogra phy. J. A. Zavaleta 424. Conformational effects of increased hydrogen bonding on a β-hairpin. E. M. Szilagyi, S. N. Gowda, J. H. Miwa 425. Controlling the enantioselectivity of Pd-catalyzed allylic allegations via terpene-derived chiral ligands. C. C. Buchanan, T. A. Evans 426. Convergent synthesis of the dexamethasone-cephem-methotrexate sub strate. J. L Provenzano 427. Creating C10-C14 tertiary alcohols: A Grignard experiment for the organic chemistry laboratory. J. L. Oliver, E. M. Hairfield, H. H. Hairfield Jr. 428. Crystal structure of a C2-symmetric dicyclopentadieneone, a potential new ligand for transition-metal complexes. K. B. O'Keefe, E. P. Roth, N. E. Heimer, G. J. Balaich 429. Degradation of microcystin by ultra sonic irradiation. K. M. Loftis 430. Design and synthesis of new anthrapyrazole derivatives as potential anticancer agents. K. K. Larson, D. Lin, A. Begleiter, F. S. Guziec Jr. 431. Design, synthesis, and conformational analysis of β-hairpin peptides. C. L. Thomas, M. A. Etienne, M. M. Juban, R. P. Hammer 432. Developing a more efficient pathway for the synthesis of anticancer drugs. S. Nguyen, J. C. DiCesare 433. Developing analogs of thioxanthyl moieties as protecting groups for the 5* hydroxyl group of nucleotides. D. J. Fitzgerald, G. Μ. Ζορρ, Μ. Κ. Boyd 434. Diastereoselective reactions of ethyl magnesium alkoxide reagents with 2-phenylpropanal. C. M. Webber, K. J. Brown
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TECHNICAL PROGRAM 435. Effect of ligand structure on lumines cent europium complexes. L Purvis, G. D. Phelan, B. Carlson, L. R. Dalton 436. Effects of a cationic substituent on the rate of a Cope rearrangement. K. D. Becnel, M. H. Montgomery, K. M. Morgan, P. F. Godenschwager, E. N. Hattersley, R. J. Carra 437. Effects of chromophore structure on DNA intercalation. K. Forzley, J. Zimmer, A. C. Bryant-Friedrich 438. Efficient conversion of aldehydes to ketones using a modified Grignard reaction. A. F. Zlto, K. J. Brown 439. Efficient syntheses of heterocyclic compounds. L. S. Gronenberg, M. P. Doyle 440. Efficient synthesis of 3-hydroxymethyl4-phenyl-1,2,4-triazole. D. R. Haines, E. Y. Hyun. M. P. Un 441. Efforts toward the total synthesis of deoxyhelminthosporol. E. Casillas, L M. Delia Greca, L. Clayville, E. E. Pusateri 442. Electronic control of Bergman cyclization. A. Lauer, L. Machado, K. Mousseau, A. Trout, J. Gabbard, K. C. Russell 443. EnantioselectJve synthesis of β amino acids. S. L Hagen, M. Liu, M. P. Sibi 444. Equilibration in alkoxysulfonium inter mediates in the Swem oxidation: Studies of the selectivity of oxidation of primary and secondary alcohols. C. L Muller, D. C. Rogness, J. L. Vanderpoel 445. Ester chiral auxiliaries for the control of stereochemistry in addition reactions of tertiary electrophilic radicals. I. Rosenstein, A. M. Stroud 446. Evaluation of antioxidant activity in Italian wines. C. A. Stephansky, J. M. Simpson 447. Experimental and theoretical study of a β-methoxycarbene. S. Presolski, D. M. Thamattoor 448. Exploration of proline-based ligands for use in stereoselective organocuprate conjugate addition reactions. J. S. Marquess, C. A. Ogle 449. Extent of nucleophilic participation in the solvolyses of 2-thiophenecarbonyl and thiophene-2-acetyl chlorides. M. J. D'Souza, M. E. Stant, R. White, D. N. Kevill 450. Extraction of thiarubrine-A from the roots of ragweed. K. Quinones, Κ. Ε. O'Shea 451. Extracts with antioxidant and antitumor activity from the bark of Croton lechleri. T. L Lamoureaux, C. C. Neto 452. Formation of cobalt-spermine com plexes. C. S. Urig, G. L. Seebach, E. Csuhai 453. Further investigation of an asymmetric reductive amination reaction. C. R. Richardson, J. C. DiCesare 454. Grignard addition to N-ethanolsuccinimide. T. T. Phan, P. T. Buonora 455. H/D exchange on a beta-substitued ketone. L Phillips, J. R. Mohrig 456. H/D exchange stereoselectivity of tert-butyl 3-phenoxybutanoate. J. M. Coughlin, J. R. Mohrig 457. Hexamethylbipyrazinetetraoxide as a donor for DA cocrystal synthesis. J. W. Wackeriy Jr., P. Acharasatian, S. C. Blackstock 458. Hyrdrogen bonding strength in 12-residue peptides. K. E. Lee, J. L. Kahn, J. H. Miwa 459. Identification of flavonoids and other compounds extracted from the fruit of the yellow buckeye tree. J. N. Nash, M. S. Doud, D. L. Stephens
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460. Improved synthetic route to demethylubiquinone-3: A potential precursor in rhodoquinone biosynthesis. M. J. Lenaeus, J. N. Shepherd 461. Independent synthesis of 1-tropylium1,5-hexadiene. D. L Aaron, K. M. Morgan, S. H. Shin, R. J. Carra 462. Initial studies of pentapeptides to investigate the effect of neighboring aromatic amino acids on the α-proton chemical shift of alanine. E. A. Carlisle, A. M. Maranda, S. L. McKay 463. Intercalation of acid/amine lamellar clay mimics. J. L. Mason, A. M. Beatty 464. Investigating ligand-receptor interac tions: Design and synthesis of peptoids recognizing the SH 3 domain. R. A. Misiaszek II, J. D. Kehlbeck 465. Investigating synthetic routes of diolefin ligands. R. R. Ramoutar, W. Pennington 466. Investigation of bioactive compounds in Stylotella aurantium from Guam. S. R. McHugh, R. B. Kinnel 467. Ionic liquid metal conjugate: Prepara tion and use in asymmetric catalysis. K. L T. Tran, J. H. Davis Jr., D. C. Forbes 468. Ionic reactions of halogens with fluorosubstituted terminal alkenes. A. Ryan, D. F. Shellhamer 469. Isolation and characterization of natu ral products from Dalea versicolor (Fabaceae). D. Percivill, G. Belofsky 470. Isolation and identification of antimicro bial compound extracted from a soft coral, Xenia elongate. A. S. Koch, Z. Zaplatynski, J. J. Byrd, R. A. Golombeck, K. Maust 471. Isolation and preliminary structural elucidation of a toxin from the flatworm, Convolutriloba retrogemma. A. S. Koch, E. R. Pettys, W. I. Hatch, A. T. Pau 472. Isolation and structure elucidation of a cytotoxic compound from Pinguiococcus pyrenoidosus. M. R. Maynor, T. Hemscheidt 473. Isolation of fungal metabolites from biologically active extracts of Myrothecium cinctum and Gliocladium sp. K. Azadl, G. Belofsky, D. Wallace 474. Maleic anhydride photodimer as a key intermediate in a combinatorial library. E. J. O'Neil, B. L Miller 475. Manganese-mediated addition reac tions of electron-deficient radicals. I. Rosenstein, A. J. Lin 476. Mechanism for formation of 2,4-dimethylquinoline in the preparation of 4-anilino-3-pentene-2-one. D. R. Dillin, W. F. Long, D. G. Watson, J. Wu 477. Mechanism of electrophilic addition to 1-methoxy-1,3-cyclohexadiene: Carbocation or AdE3? C. K. Bundick, J. V. McClusky, R. A. Rennels, N. Trevino 478. Mechanisms for photocatalytic reac tions of aromatic compounds. W. M. Guffey, N. Oleng, N. Gao 479. Mechanistic study of a new iodolactonizatjon rearrangement reaction via a phenonium ion intermediate. C. K. Ingison, T. Wirth, A. N. French 480. Mechanistic study of palladium-cata lyzed dehalogenation. S. Seweil, K. S. Knight 481. Methylation of carvone using tritylpotassium as a base. A. Adamczak-llg, F. J. Matthews 482. Microscale synthesis and purification of p-tolyl and p-anisyl porphyrins. E. M. DeThomas, C. Kiely, M. Panos, P. K. Kerrigan 483. Microwave synthesis and investigation of some nitrogen heterocycles. C. J. Knight, A. S. Howard 484. Mild one-pot conversion of primary alcohols to α,β-unsaturated ketones: Application to natural product synthesis. T. J. Speed, D. M. Thamattoor 485. Modified McMurry reaction: The "onepof procedure. S. M. Adamus, K. E. Cassidy 486. Modified synthesis of exo-glucal from methyl a-D-glucopyranoside. H. Uu, C. Kvamme, I. Smoliakova
487. New aqueous constituents from the sponge Stylotella aurantium from Palau. J. A. Rizzo, R. B. Kinnel 488. New method for the synthesis of thionucleosides. G. R. Bluemling, A. R. Bressette 489. Non-natural cell surface receptors as tools for drug delivery. R. E. Bringman, S. L. Hussey, B. R. Peterson 490. Novel system producing primarily β-scission products in the reactions of secondary alcohols with aqueous sodium hypochlorite. M. W. A. Gonser, W. Hendrickson, M. Sedenko, R. G. Landolt 491. Nucleophilic additions to 1-chloro-5-(4dimethylamino)pyridiniumanthraquinone. A. S. Koch, J. A. Ryan, K. Borstnik, M. J. Evans 492. Nucleophilic substitution of O-alkylbenzohydroximoyl fluorides by Grignard reagents and enolate anions. D. D. Dolliver, D. D. Delatte, K. Fine, J. E. Johnson, I. A. Atamah, A. J. Jackson, S. J. Bott, J. E. Rowe 493. On the interesting reactivity of orthoesters with amino acids: A convenient procedure for the one-pot esterification and /V-acetylatjon of amino acids. A. S. Gopalan, D. Romero IV, S. Gibson, H. K. Jacobs 494. Optimizing metathesis with electrondeficient olefins: Synthetic efforts toward peloruside A. J. B. Vergin, T. D. Ryba 495. Organic reactions on the surface of a Gain alloy. M. J. Campbell, E. T. Hartman 496. Organic synthesis of multiketone systems for use in UV curing of poly mers. D. Smith, M. A. Meador 497. Oxidation of trialkylboranes using potassium permanganate. J. T. Menig, C. E. Hams 498. Palladium-catalyzed cross-coupling reactions between dihydropyranyiindium reagents and aryl halides. T. G. Minehan, U. Lehmann 499. Partial synthesis of rhododaurichromanic acid A via a formal [3 + 3] cycloaddition. R. Hsung, K. M. Ihlen, J. J. Wang 500. Phenolics from the sea sponge Aplysina fistulans. A. S. Koch, S. H. Herrero, W. I. Hatch, S. J. Hellman 501. Photochemical investigation of organic isothiocyanates. J. L Rafferty 502. Photochemical synthesis of 3,4dimethyttricydo(4.4.0.02i8]dec-3-ene7,10-dione in zeolites. M. K. MacLeod, T. Poon 503. Preparation and characterization of ferrocenes bearing polyfluoroalkoxymodified perfluoroaryl substitueras: A convenient method of introducing fluorous "ponytail" groups. M. G. Poferl, W. G. Hollis. P. A. Deck 504. Preparation and NMR spectroscopic characterization of polyunsaturated lipid bilayer discs. M. B. Mikolaj, P. Adhikari, G. A. Lorigan, R. E. Minto 505. Preparation of 2-bromo-1,3-dienes. H. W. Pinnick, T. R. Tomblin 506. Preparation of a chiral auxiliary: Con version of α-pinene to 2-hydroxy-3pinanone. J. R. Mosier, C. E. Harris 507. Preparation of a nicotinamide nucleo side analog via enzymaticribosidatJonof 1,2,4-triazole. D. R. Haines, H. Chen 508. Preparation of thiophenylalanine in a tripeptide. J. K. Smith, C. L. Hickel, S. M. Schelble 509. Products and mechanism for the addition of dichlorocarbene to 2,3diphenylazirine. H. D. Kondilis, J. O. Currie Jr. 510. Progress in the synthesis of 1,5methylenesemibullvalene. A. Amick, I. D. Reingold 511. Progress toward novel avenic acid conjugates. H. M. Dishmon, M. G. Stocksdale 512. Progress toward the synthesis of a homochiral aliphatic hypervalent iodine reagent. C. N. Streu, A. N. French
513. Progress toward the development of linchpin methodology leading to conju gated all Ε-polyenes. B. H. Lipshutz, D. B. Ball, C. J. Tunned 514. Progress toward the synthesis of a simple template molecule designed for selective ligand attachment. P. A. Bishop, A. Stewart 515. Progress toward the synthesis of model cyclic phosphonates as putative β-lactamase inhibitors. J. Blecha, J. Maung, C. Berkman 516. Proposed total synthesis of (+)sedamine utilizing palladium-catalyzed α-vinylation of ketone enolates. J. M. HatJey, G. A. Sulikowski 517. Qualitative analysis of Tilia americana. J. D. O'Reilly, M. M. Mcintosh, D. L. Stephens 518. Quinolizidine and piperidine alkaloids in Lupinus leucophyllus and L sulphureus. J. S. Shirley, T. L Kaneshiro, A. K. Miller, R. B. Kelley 519. Rapid and efficient synthesis of combi natorial diversity elements. J. L. Cahoon, T. A. Knoerzer 520. Reaction of sodium methoxide in DMSO/methanol mixtures. H. F. Koch, A. M. Ruminski, G. Lodder 521. Reaction of the pentachloride of resorcinol, a model of the humic acids, with various chloramines. N. R. Royer, V. Heasley, P. Baker, Ε. Ε. Herman, S. T. Michaelson 522. Reduction of aromatic nrtro groups of protected amines. N. J. Slodki, G. L. Seebach, E. Csuhai 523. Regio- and stereoselectivity of the ketal Claisen rearrangement. G. W. Daub, M. J. Patten, C. Borner 524. Relative stability of aryl carbanions. D. Hurley, L. D. Pedersen 525. Ring opening of 3-bromo-2-isoxazolines. M. G. Kociolek, K. P. Kalbarczyk 526. Sesquiterpene constituents from Aristolochia satvadorensis. A. J. Tracey, L. G. French 527. Short, scalable route to enantio-enriched IAN-amines. B. R. Kok, S. B. Cortright, J. N. Johnston 528. Silica-gel-supported chromic acid as an alternative to Jones reagent: Sup ported reagents in the undergraduate organic laboratory. D. A. Knight, N. Rupprecht, R. Canizalez, M. H. Ali, C. Wiggin 529. Solution-phase parallel synthesis of a twelve-member library of dithiocarbamate ester analogs of pyrrolidine. S. Osei, O. Bakare 530. Solvatochromism of some thiophene derivatives. M. M. Bader, J. P. Maciejewski, W. Long 531. Spectroscopic analysis of 2-(4-methoxyphenyl)-4,6-dioxocydohexane-1,3dicarboxylate. A. J. Lieber, S. S. Stephens, J. L. Maxwell 532. Spectroscopy and photochemistry of some aryl and alkyl cinnamates. S. A. Dearmon, D. Creed, A. M. Somlai, R. O. Al-Kaysi 533. Steps toward the synthesis of a phos phate hapten and the corresponding carbonate substrate for hydrolysis by polyclonal catalytic antibodies. E. D. Helms, S. L Fleszar, A. J. Tabaczynski 534. Stereoselectivity in intramolecular [2+2] cycloadditions of double bonds to triplet benzenes in the solid state. M. K. Froemming, K. McMahon 535. Structural determination of the pyr rolidine alkaloids from HeUotropium œnvofvulaœum. R. A. Feierabend, J. W. Stoddard, T. L. Ferguson
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CHEDfl"ECHNICAL PROGRAM
536. Studies on the stereochemical fea tures of chemical and biochemical reduction of alkylcycloalkanones. L. S. Ng'alla, F. J. Creegan 537. Study of dihydropyridazinones synthe sis by parallel reactions of bicyclic lac tams and hydrazine. Y. J. Lim, P. T. Buonora 538. Study of steric effects in the synthesis of hydroxamic acids from bicyclic lac tams. P. T. Buonora, O. Oo 539. Substituted naphthalimides as poten tial sub-ppm ftuoroionophores: Fluores cence and absorption studies of PD4. J. Elbert, S. Elzey, L. Robinson 540. Supramolecular complexation of a merocyanine dye by helical amylose. B. F. Visger, W. B. Heuer 541. Synthesis and analysis of 2-(4-methoxyphenyl)-4,6-dioxocyclohexane-1,3dicarboxylate. E. L. Lowther, J. L. Maxwell 542. Synthesis and application of a structur ally novel chiral auxiliary based on D-camphor. S. R. Hitchcock, R. A. Davis, M. D. Squire 543. Synthesis and characterization of three new chiral, nontransferable ephedrine- and norephedrine- based ligands for organocuprate reactions. M. L Williams, Z. Cox. C. A. Ogle 544. Synthesis and characterization of [18]-dehydropyridylannulenes. A. Martinez, S. McAvoy. K. C. Russell 545. Synthesis and comparison of the antimicrobial activity of oxygenated α-pinene derivatives with corresponding methyl cyclohexene derivatives: Study of structure-activity relationships. P. Dhar, T. Snyder-Leiby, U. Ayala, S. Morisseau 546. Synthesis and gelation abilities of naphthol-cholesterol derivatives. H.C.Geiger,J.M.Laakso 547. Synthesis and metallization of diazo compounds with cobalt(ll) ions. T. Falace, G. L. Seebach, E. Csuhai 548. Synthesis and metallization of diazo compounds with nickel(ll) ions. P. Burchett, G. L. Seebach, E. Csuhai 549. Synthesis and modeling of 2,4-pentadienals with 5-(4-piperidinylphenyl) or 5-(5-indolinyl) donors. R. W. Tilford, A. C. Friedli 550. Synthesis and resolution of chiral trisphenols: An approach in stereo chemical control in Lewis acid catalyzed reactions. J. R. Mays, G. E. Hofmeister 551. Synthesis and stability of c/s-alkenes. H. L Spoelhof, J. R. Mohrig 552. Synthesis and study of pentacyclo[4.3.0.024.038.057]non-4(5)ene. M. A. Forman, M. Kerrigan, J. Stairs, E. Chopko, L. Lowchyj 553. Synthesis of (+)-pilocarpine analogs. J. Boulos, S. Singh 554. Synthesis of (5S,6R)-4-ferf-butyloxycarbonyl-5,6-diphenyl-2,3,5,6-tetrahydro1,4-oxazin-2-one. J. A. Brant, U. Oguz, M. L. McLaughlin 555. Synthesis of 2-(4-amino-2-nitrobenzyOpyridine. R. Eliason, J. Jensen 556. Synthesis of 2-iodomethyl and 2-methylene-tetramethoxy-p-te/tbutylcalix[4]arene. J. L. Bennett, L. R. Kuck 557. Synthesis of 6,7-dimethoxy-2-tetralone via a novel 1,2-carbonyl group transposi tion. S. V. Slobodzian, N. D. Egbert, A. E. Hayden 558. Synthesis of a 14-residue cyclic pep tide. L Ventouras, R. Wilson, J. H. Miwa 559. Synthesis of a biotinylated hydroxyproline residue to investigate the formation of a modified collagen triple helix. S. K. Ryan, S. L. McKay 560. Synthesis of a family of naphthyl propargyl ethers. A. T. Kelley, T. P. Smith, M. Foroozesh
561. Synthesis of a monomer for a conju gated hyperbranched polymer. M. O. Parpia, T. M. Chapman 562. Synthesis of a multithiol ligand for Au nanoparticles. C. Avendano, H. Liu, K. Page, T. A. Taton 563. Synthesis of a naphthyl-substituted aliphatic hypervalent iodine reagent: A progress report. J. R. Heinzelmann, A. N. French 564. Synthesis of a new spiroindolinobenzopyran photochromic polymer. E. R. Rolfes, J. T. Ippoliti 565. Synthesis of a series of anthrapyridone dyes: Electronic effects. J. S. Clements, G. L. Seebach, E. Csuhai 566. Synthesis of a tyr-trans-pro dipeptide mimic. B. Cormier, F. Etzkom 567. Synthesis of acyloxynitrobenzoic acids. C. A. Hansen, J. White, R. L. Cate, L. Karber 568. Synthesis of α-silylated and α-alky lated O-ferf-butyldimethylsilyl aromatic ketoximes. M. Ortiz-Marciales, Ε. Μ. Morales, M. De Jésus 569. Synthesis of alternative precursors to pentacyclo[4.3.0.02-4.038.057]non-4(5)ene. M. A. Forman, M. P. Shalaida, C. Kelley 570. Synthesis of amino- and ester-terminated silanes. D. E. Noga, C. R. Allison, A. C. Friedli 571. Synthesis of an allocedrol-based tricyclic alcohol. E. Lee, W. Dasher 572. Synthesis of analogues of folic acid. E. I. Lancaster 573. Synthesis of benzylcyclen from substituted tetraamines. J. Elbert, N. Mente, S. Olson 574. Synthesis of boronated phosphoramidates for potential applications in boron neutron capture therapy. S. C. Ledger, N. S. Hosmane, K. Vyakaranam, G. Rana 575. Synthesis of chiral primary amines. M. Ortiz-Marciales, S. Espinosa Diaz, W. Correa Ramirez 576. Synthesis of D-threo-PDMP analogues: Manipulation of the aromatic region and the acyl chain in order to increase solubility and potency. D. R. Pott, J. Slavish, D. K. Friel, D. L. Oland 577. Synthesis of dye tags for Raman immunoassays. L. M. Weyer, R. C. Corcoran 578. Synthesis of halogenated anthraquinones as model DNA intercalators. S. Abdallah, J. Zimmer, A. C. Bryant-Friedrich 579. Synthesis of heterocyclic selenocyanates. S. A. Rivera, L. A. Jacob 580. Synthesis of highly conjugated liquidcrystalline compounds with low melting points. B. P. Mason, F. Kimura, E. Scharrer 581. Synthesis of juglone using hydrogen peroxide. R. Eliason, J. M. Sexton, K. J. Mueller 582. Synthesis of N- and C-glycoside glycomimetics. P. Norris, M. Bailor, M. Bemardina, A. Finamore, T. Wagner 583. Synthesis of neutral polyhydroxyalkyl species. C. A. Hansen, D. Clopton, T. Topley 584. Synthesis of novel biphenyl-cholesterol compounds and study of their gelation ability. H. C. Geiger, C. Z. Constantine, R. J. Holland 585. Synthesis of novel group IV polymerization catalysts. J. M. Richter, J. J. Esteb 586. Synthesis of novel methoxylated fatty acids. M. Rodriguez, N. M. Carballeira, H. Cruz, C. Miranda 587. Synthesis of novel photocleavable protecting groups for primary alcohols. D. D. Dore, M. Κ. Boyd, G. M. Zopp 588. Synthesis of octa-substituted copper phthalocyanines with n-ethoxy-ethanol side chains. C. A. Rivera, D. E. J. O. Atkinson 589. Synthesis of quinizarin-cored dendrimers and related compounds. J. L. Steinbacher, M. W. Thomsen
590. Synthesis of selectively C-3 and N-4 substituted [1,2,4]-triazoles. A. K. Larkin, D. R. Haines 591. Synthesis of substituted analogs of a molecular tweezer and quantification of their supramolecular binding abilities. D. B. Guthrie, D. H. Fish 592. Synthesis of substituted decadienes using zirconocenes. E. Fielding, K. S. Knight 593. Synthesis of substituted nitroanthracenes: Development of anthracenebased chemosensors. C. G. Toyota, A. B. Dribben 594. Synthesis of substituted pleiadenediones. J. L. Hespell, M. W. Thomsen 595. Synthesis of substituted tetraamines starting from amino acids. J. Elbert, S. Olson, N. Mente 596. Synthesis of the (+)-C27-C32 domain of azaspiracid. O. L. A. Wong, S. T. Ngyuen, C. J. Forsyth 597. Synthesis of the southeast quadrant of the macrolide antibiotic, borrelidin. D. B. Ball, B. R. Taft, M. Mahoney 598. Synthesis of the twisted amide. A. R. Noble, M. N. Montgomery, K. M. Morgan 599. Synthesis of trypanothione reductase inhibitors. M. D. Spalding, D. G. Alberg 600. Synthesizing phosphinate DNA. K. A. Keaton 601. Taming the elusive 310-helix: Synthe sis and conformational analysis of macrocyclic heptapeptides. W. S. Iskenderian, A. K. Boal, B. D. Allen, W. E. Steinmetz, R. H. Grubbs, D. J. O'Leary, H. E. Blackwell 602. The reaction of osmium tetroxide with exo-3,3-diphenyltricyclo[3.2.1.02,4]oct-6ene. D. S. Crumrine, C. J. Thode, T. Ramos 603. The role of water in the catalysis by pendant sulfonic acid ionic liquids. K. J. Weaver, J. H. Davis Jr., D. C. Forbes 604. The synthesis of cyclopenta[d]pyridazines and the cyclooxygenase con nection. R. D. G. Rifle, M. T. Blankenbuehler 605. Total synthesis of an anticancer natu ral product: (-)-18-hydroxyminquartynoic acid using a three-component CadiotChodkiewicz reaction. K. A. Ashton, B. W. Gung, G. Kumi 606. Toward a novel asymmetric synthesis of hennoxazole A. J. L. Roizen, V. D. Bock, E. P. Balskus, T. E. Smith 607. Toward the synthesis of fullerene cage precursors through indium-mediated coupling of benzylic halides and alde hydes. T. M. Mitzel, A. Nath 608. Toward the design and synthesis of kinesin inhibitors. H. J. Frazee, C. Dame, K. Reddie, T. M. Dore 609. Toward the synthesis of novel taxoid analogs. K. Nlkolakeas, B. Aldabagh, J. L Tischler, A. R. Zand 610. Transition metal catalyzed hydrostannations: Use of PMHS/Bu3SnF as a tin hydride source. R. E. Maleczka Jr., W. P. Gallagher, A. L Szymanski 611. Triaryl diolefins as hosts for metals and organoiodides. W. L. Gordon, T. Hanks, W. T. Pennington, W. A. Flomer, E. Gordon 612. Triphenodiathiazine and derivatives: Preparation and characterization. M. M. Bader, J. P. Maciejewski 613. Use of gas chromatography in the elucidation of carbohydrates in the bodily fluids of the gulf pipefish, Syngnathus scovelli. J. Rozelle, C. Partridge, A. Boettcher, D. C. Forbes
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
614. Use of SPME and GC/MS for chemi cal analysis of urine from African elephants in musth. B. L. Davis, W. M. Dill, A. R. Hicks, T. E. Goodwin, J. Hollister-Smith, S. C. Alberts 615. Verification of the mechanism for a visible-light-initiated system for cationic polymerization. J. W. Wackerty Jr., T. W. Nalli 616. Zeolites as catalysts for quaternary carbon formation: Synthesis of cuparene. T. Singa, T. Poon Chemical Careers in the Federal Government Cosponsored with Society Committee on Education
MONDAY AFTERNOON Section A Convention Center Room 218 Can We Talk? Communication in Chemistry Cosponsored with Presidential Event T. Holme, Organizer 1:00 617. Dynamic communications are important for career enhancement. H. M. Free 1:30 618. Literature searching and com munications: Essential skills for chem ists. D. E. Hyatt, J. P. Ferraris, J. H. Reed 2:00 619. Assessment as a form of com munication. E. L Lewis 2:30 620. Communicating with yourself: Reflective practice and the teaching of chemistry. C. B. Freeh 2:55 Intermission. 3:05 621. Providing opportunities for students to communicate science to diverse audiences through a universitymuseum partnership. A. C. Payne, C. G. Widstrand, G. C. Lisensky, G. M. Zenner, T. Derenne, P. Krajniak, W. C. Crone 3:30 622. Strategies for designing and field testing a general chemistry textbook for the 21st century: The ACS Chemistry project. M. A. Scharberg, J. A. Bell 3:55 623. PLTL: Promoting change through communication at all levels of the educational enterprise. P. Varma-Nelson 4:20 624. Getting general chemistry students to read, write, and speak. M. Z. Hoffman, A. D. Crosby SectkxiB Convention Center Room 219 The Cutting Edge: Use of Computers in Teaching and Learning Chemistry Applications L. J. Anna, Presiding T. A. Schoolcraft and C. Muhoro, Organizers 1:30 625. An introduction to molecular structure: Molecular modeling integrated with NMR spectral analysis of common painkillers. D. C. Wiser, J. A. Cody 1:50 626. Browsing on the cutting edge, or just bytes? W. D. Wagner 2:10 627. Dynamic visualization in chem istry: The effect of animations on student learning. R. Morgan, J. P. Birk 2:30 628. How helpful are practice tests in the learning process? J. H. Penn, J. Valari, G. Gozdzik 2:50 Intermission. 3:00 629. Exploring quantum principles with computers. A. D. Crosby, D. Dill, L. S. Garbayo, P. S. Garik, A. Golger, M. Z. Hoffman
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TECHNICAL PROGRAM 3:20 630. Using 60 MHz and 300 MHz H-1 and C-13 FT-NMR FIDs accessed from the Viterbo University NMR website in the teaching of organic chemistry. R. T. Amel, M. J. Collins 3:40 631. Enabling interactive learning using multiple-choice quiz forms in course websites. P. E. Fleming 4:00 632. Initial results from computerized assessment of large freshman chemistry classes at the University of Georgia. C. H. Atwood, G. J. Lautenschlager, R. L. Marsh, J. G. Martin, J. A. Caughran 4:20 633. Computer verification programs for the general chemistry laboratory. L Pence, H. J. Workman 4:40 Concluding Remarks. SectionC Convention Center Room 217
SectionE
Speaking Truth to Power: The Role of Chemists in Government Decision-Making Cosponsored with Committee on Environmental Improvement Κ. Μ. Kulinowski, Organizer,
Presiding
1:00 Introductory Remarks. 1:05 634. Exploring the communication gap. K. L. Parker 1:30 635. Policy in science: A chemist in the Executive Office of the President. M. J. Holland 1:55 636. Risk analysis: Informing the decision-making process. A. K. Courtney 2:20 637. Post-9/11 public perception of risk impacts: Decades-old policy on potassium iodide stockpiling. Κ. Μ. Kulinowski 2:45 Discussion. 2:55 Intermission. 3:05 638. SENCER: Linking science education and civic engagement. T. Jordan 3:30 639. Exploring nanotechnology in the public interest. T. M. Masciangioli 3:55 640. Implications of the genomics revolution for the chemical industry. R. D. Klaper, C. Henry 4:20 641. "You have no business being here, you are a chemistry professor": Becoming an effective force in the politics of energy. J. P. Rybarczyk 4:45 Discussion. SectkxiD Convention Center Room 220 Program Impact of a One-Semester General Chemistry Requirement A. Witter and L. H. Doerrer, Organizers, Presiding 1:00 Introductory Remarks. 1:05 642. Invigorating first-year chemistry. R. Breslow 1:30 643. General chemistry at Barnard. S. Chapman 1:55 644. Thirteen years of "first-year organic chemistry" at the University of Michigan. B. P. Coppola 2:20 645. Textbooks for one-semester general chemistry courses: How much can we leave out and still call it "general" chemistry? J. R. Burdge
34-TECH
2:45 Intermission. 2:55 646. Tailoring general chemistry to fulfill the teaching mission of a land grant university. D. W. Wertz 3:20 647. Studio 130: Design, testing, and implementation. A. C. Gottfried, J. A. Hessler, R. D. Sweeder, J. M. Bartolin, B. P. Coppola, M. M. Banaszak Holl, B. P. Reynolds, I. C. Stewart 3:45 648. The new chemistry curriculum at DePauw University. B. A. Hanson 4:10 649. Structure and properties of inorganic compounds: An introductorylevel descriptive inorganic course at DePauw University. H. J. Eppley 4:35 650. Curricular change: Assessing the impact at DePauw University. B. L. Gourley 5:00 Concluding Remarks.
Convention Center Hall J Undergraduate Research Poster Session: Inorganic Chemistry Cosponsored with Society Committee on Education 2:00-4:00 651. A comparative study of the aqueous syntheses of apatites. N. J. Flora, C. H. Yoder 652. A series of 1,2-naphthaquinone-4sulfonic acid thiosemicarbazone acidbase indicator ligands for complexation of aqueous metal ions. E. C. Lisic, J. W. Carter, R. T. Mayes 653. Adding a thiol group using 2,2'-drthiodibenzaldehyde to a metal complex. V. Bonnie, D. M. Eichhom 654. Aggregation-induced enhancement of photoluminescence in a series of group-14 metalloles. J. Martin, J. Haug, J. L Mullin, H. J. Tracy 655. Alloxazines as Η-atom transfer media tors incorporated into Ti02-coated elec trodes. B. Lutes, M. E. McGuire 656. Anomalous proton NMR of nickel(ll) dithiocarbamate complexes in solution. N.V. Duffy, CWinschel 657. Anthocyanidins as molecular sensors for lanthanide metals. J. B. Nusser, T. D. Millsap, A. J. Sunday, B. C. Byrne, D. A. Huffman, J. N. Woodford 658. Characterization of frethynyl-9-BBN and Z-1-bromo-1-(9-BBN)-2-catecholborylethene. G. M. Edvenson, M. R. Hagen, N. R. Gartin 659. Chirality of sodium bromate and sodium chlorate. M. B. McGinnis, C. Bruce, L. rvey, J. Walker, S. T. Brittain 660. Competitive extraction of toxic metals by disulfonamide chelates derived from ophenylenediamine. A. Andreu, J. M. Rosenberg, K. Kavallieratos 661. Complexation studies of crown thioethers bound to the heavy metal ion mercury(ll). G. P. Helton, G. J. Grant, M. L. Helm 662. Complexation studies: Phosphorus analogs of nitrogen ligands. D. D. Axtell, B. C. Stein, T. J. Underwood, L M. Tu 663. CsLnMSe3 magnetic semiconductors. R. C. Somers, J. A. Ibers 664. Dehydrogenation kinetics of doped sodium aluminum hydride: Evaluation of a promising new hydrogen storage material. C. M. Jensen, T. Kiyobayashi, D. Sun, A. Savara 665. Development of robust iron(lll) com plexes for catalyzing biologically relevant oxidations. E. J. Rohanna, L. D. Vuocolo 666. Dithiocarbamate ligand exchange between indium(lll) and iron(lll) in solu tion. N. V. Duffy, K. Stankiewicz
667. Double dangling tetraphenyldiphosphinomethane carbonyl complexes of group 6. B. J. Bellott, D. A. McMillian, H. M. Anthony, G. A. Holloway. J. S. Southern, E. A. Keiter, R. L. Keiter 668. Electroless deposition of noble metal nanoparticle films. L C. C. Elliott, L. A. Porter Jr., J. Buriak 669. Electronic absorption spectroscopic studies of the coordination of vanadium(IV) ion with tetracycline and its derivatives. M. Mahroof-Tahir, V. Anderson 670. Expanding the delocalized electron system of a ruthenacarborane in pursuit of new nonlinear optical complexes. P. A. Jelliss, D. Subramanian 671. Formation of a homogeneous goldplated polycarbonate membrane using convection. S. F. Newman, V. Smuleac, D. A. Butterfield 672. Hyperaccumulation of cadmium by Helianthus annuus. T. J. Fenus, J. H. MacNeil 673. Incorporation of a Ru(ll) complex containing a phenanthroline-based azo dye into a "Grâtzel-type" solar cell. L. Malinowski, M. E. McGuire 674. Investigation of the haloperoxidase activity of bovine spleen purple acid phosphatase. R. R. Bravo, G. Olivier-Lilley 675. Investigations of lacunary polyoxometalates and heterometallo derivatives. K. L Taylor, M. A. Bolcar 676. Iron-spermine complex formation. E. Y. Wlllhoite, G. L. Seebach, E. Csuhai 677. Kinetics and mechanism of glutathione conjugation of cyanate. B. Forfeke, J. Ji, M. T. Ashby 678. Kinetics of metalloporphyrin-based ligand substitution with surface-confined ligands. R. Gabor, S. Awasthi, H. Van Ryswyk 679. Magnesium diboride substituted YBCO-type superconductors. N. D. McLeod, B. D. Palmer 680. Molecular orientation of F16CoPc on various substrates. P. Leroueil, C. Harris, H. Doodnauth, K. W. Hipps, M. G. Norton 681. Multinuclear NMR investigation of transition-metal-substituted heteropoly anions in nonpolar solvents. E. Rogers, J. Rose, O. Bitar, M. Kozik 682. /V-heterocydic carbene-phosphine complexes as homogeneous catalyst for the hydrogénation of olefins. B. T. Owens, L. D. Vazquez-Serrano, J. M. Buriak 683. New metallomesogens based on 4,5-bis(alkoxy)-1,2-phenylenebis[nitrilomethylidyne(2-hydroxybenzene)]. I: The synthesis of new derivatives with alkyl chains of varying length on the bridging phenyl ring. E. L. Livengood, M. R. Ams, S. M. Malinak 684. NMR study of copper and zinc complexes with amine compounds. M. M. Minix, G. L. Seebach 685. Novel organic substituted dawson polyoxometalates. R. C. Chambers, R. C. Hawk 686. Parallel synthesis and characterization of β-ketoimines for applications in cataly sis. A. G. Matthews, T. Solomon, A. Thomas, J. S. Matthews 687. Platinum(ll) complexes with crown thioether and polypyridine ligands. K. N. Patel, G. J. Grant, M. L Helm 688. Polymer-stabilized copper complexes: Mimicking the oxygen transport protein hemocyanin. R. S. Gibbard, A. A. Goldblum, I. M. Johansson, J. W. Gohdes 689. Potassium polytellurides in nonaque ous solvents. J. R. Andreatta, J. L. McAfee. L. D. Schultz 690. Preparation and characterization of polyoxometalates for Langmuir-Blodgett thin films. R. C. Chambers, S. E. Angell 691. Preparation of aluminum(lll) com plexes for use as ring-opening polymer ization catalysts. Β. Ε. Makl, M. J. Tjosaas, G. E. Hofmeister
692. Preparation of binuclear iron and manganese spin crossover complexes as potential data storage devices. T. H. Watson, L. D. Vuocolo 693. Proposed synthesis and analysis of selenium alkoxides. J. M. Iriarte-Gross, W. E. Lee, S. T. Decha-Umphai 694. Proton NMR of paramagnetic Ni(ll) complexes with an Anasazi NMR instru ment. N. V. Duffy, T. Mehlman 695. Reaction chemistry of chiral titanium complexes. A. R. Johnson, E. J. Duvall 696. Reaction of triphenyl phosphine with fluorenyl-based rhenium complexes. B. A. Baird, R. M. Chin 697. Rhenacarborane complexes with 4,4'-bipyridyl and related ir-conjugated rigid or semirigid fragments. P.A.Jelllss, LM.Phrfer 698. Self-assembly of one-dimensional supramolecular arrays using transitionmetal salts and hexamethylenetetramine. H. A. Darwiche, D. Nyalani, C. V. Gauthier 699. Spectroelectrochemical investigations of ligand-bridged ruthenium complexes based on frans-toans-[CI(pyridine)4Ru(L)-Ru(pyridine)4CI]2+. S. M. Hira, J. E. Minnella, C. J. Timpson 700. Spectroscopy of Cr-acetylacetonate complexes in sol-gel glasses. A. Gardner, W. F. Coleman, A. Mifflin 701. Step-by-step assembly of different!ated-dimetal complexes. S. L. Milam, T. A. Scott, H. Zhou 702. Structural analysis of mixed transitionmetal oxyfluorides with 2,2'-biimidazole. P. M. Secondo, J. P. Kedenburg, R. G. Baughman 703. Structure determination of a mixed dimer-monomer copper(ll) halide stack by X-ray crystallography. N. C. Fonville 704. Studies of ruthenium complex attached to oxide surfaces. C. E. Dedeian, H. R. Nandor, C. J. Timpson, D. D. Von Riesen 705. Studies on naphthalene and anthracene complexes of vanadium. B. E. Kucera, J. Ellis 706. Substitution reactions of doubly bridged triosmium carbonyl clusters OS3(CO)10(X)2 (X=CI. Br, I, OH, OMe, OEt) with bidentate phosphine ligands. M. M. Desko, M. Pearsall 707. Syntheses of silatranes with Si-Si interactions. D. M. Guse, S. Shaikoski, L. M. Sanow 708. Synthesis and analysis of Co-Ge materials. K. J. Johnson 709. Synthesis and characterization of a potential magnetic resonance imaging contrast agent. B. R. Galan, A. J. Jircitano 710. Synthesis and characterization of β-diketone macroligands. R. Zygmontowicz, J. L. Crane 711. Synthesis and characterization of copper chalcogenide compounds using a solvothermal approach. R. Slater, J. A. Cody 712. Synthesis and characterization of hyperconjugated tungstacarboranes for optoelectronic materials. P. A. Jelliss, J. H. Orlando 713. Synthesis and characterization of lanthanide complexes of a thiophenedipicolinic acid derivative. K. Ruddy, A. de Bettencourt-Dias 714. Synthesis and characterization of magnetite-polymer nanocomposites. B. L Scott, Y. A. Bamakov, V. B. Reddy, L. A. Kelly, K. L. Stokes 715. Synthesis and characterization of mesogenic material from nonliquidcrystalline tetracetatodicopper(ll). T. W. Clayton, N. A. Zafiropoulos
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CHEDATECHNICAL PROGRAM
716. Synthesis and characterization of trans-platinum planar amines. A.W.KInuthia, N.Farrell 717. Synthesis and characterizations of crown thioether complexes of cad· mium(ll).LL Hill, G.J. Grant, M. L Helm 718. Synthesis and electrochemistry of methyl polyethylene glycol-based poly mers. J. A. Crisp, J. E. Ritchie 719. Synthesis and luminescence of terbium(lll) macrocycles. S. R. Schayer, M. J. Prushan, G. M. Shalhoub 720. Withdrawn. 721. Synthesis of a new corannulenebased ligand. R. M. Chin, M. Jarosh. D. E. Janzen, K. R. Mann 722. Synthesis of a new corannulene complex. R. M. Chin, M. R. Jeddeloh, J. Russell 723. Synthesis of a titanium(ll) iodide-4picoline complex. D. A. Wasmund, J. R. Thonhoff 724. Synthesis of barium ferrite nanoparticles using organic precursor methods. J. H. Zhang, J. Irving, F. Smith, D. Sampson 725. Synthesis of dipyrromethanes as precursors to sterically hindered transporphyrins. C. W. Schlenker, D. T. J. Reinert 726. Synthesis of silicon-based platforms for heterogeneous catalysis. M. W. Furtz, C. E. Barnes 727. Synthesis of trimeric copper(ll) com plexes: Examples of spin frustration. N. K. Privette, M. J. Prushan, S. Lofland, S. Prertti 728. Synthesis, characterization, and spec troscopic studies of vanadium(IV) com plexes with β-diketonate ligands: Poten tial chemical and biochemical catalysts. M. Mahroof-Tahlr, O. Dovalle 729. Synthesis, characterization, and study of a series of metal complexes based on frans-tCI(pyridine)4Ru-L]+. M. M. Gordon, M. R. Reardon, C. J. Timpson, D. D. Von Riesen 730. Synthesis, characterization, electro chemistry, and spectroelectrochemical studies of diazidobis^5-pentamethylcyclopentadienyl)titanium(IV). D. C. Boyd, B. J. Anderson, C. K. Taylor, W. H. Ojala, M. G. Hill, K. R. Mann 731. Synthesis, structure, characterization, and decomposition of a novel copper cerium two-dimensional polymer with oxalate and picolinate ligands produced exclusively in ionic liquid. A. L Schmftt, H. J. Eppley, J. C. Huffman 732. Synthetic investigation of some chelat ing ligands: Alternatives to β-diketones. A. A. Meheen, J. L Crane 733. Synthetic models of the histidinecysteine bridged dicopper array in pro teins. W. B. Toiman, D. D. Petrovic, W.Lee 734. The synthesis of diamide-diimine manganese complexes for use as nitro gen-atom-transfer reagents. A. L Garner, L. D. Vuocolo 735. The synthesis of transition-metal apatites and related phosphates. N. H. Fédors, C. H. Yoder 736. Thermal neutron bombardment of boron-doped YBCO-type superconductors. J. D. Dilley, B. D. Palmer 737. Ti(ll)-mediated cyclotrimerization of alkynes. R. H. Huyck, M. Carter, C. E. Heltzel, F. Ladipo 738. Titanium amido complexes with amino acid derived ligands. A. R. Johnson, Κ. Ε. Nelson
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
739. Toward the synthesis of berberinium. A. M. Blackburn, C. Siriin, M. Pfeffer 740. Toward the synthesis of new transi tion-metal selenocarbonyl compounds. M.J. Fisher, J. A. Cody Section F Undergraduate Research Poster Session: Physical Chemistry Cosponsored with Society Committee on Education 2:00-4:00 741.1,3-Cydopentadiene dimerization kinetics: A physical chemistry laboratory experiment. T. Gray, K. Parcella, T. Guhan, B. L. Kalra, D. K. Lewis 742. A study of hypervalent ions using flowing afterglow mass spectrometry. M. R. rvanov, L. S. Sunderlin 743. Acid-base properties of the excited state of cyanide-bridged ruthenium(ll)iridium(lll) complexes. C. Hall, C. Lowry, M. Kambouris, J. Fan 744. Activity coefficients of hydrochloric acid in aqueous mixtures with terbium chloride: Application of the Hamed rule. S. B. Clark, M. P. Cummins, R. Gibbons, A. Ford, R. Singh, J. Popek, L. N. Roy, R. N. Roy 745. Adsorption of polyelectrolyte multilay ers as monitored by ATR-FTIR spectros copy. J. D. Hurley, D. Beaman, D. E. Gragson 746. Analysis of 2-aminopurine using steady-state and time-resolved phospho rescence spectroscopy. J. Y. Takayesu, K. Rousslang 747. Application of Pitzer ion-interaction model for thermodynamics of HBr + CoBr2 + H 2 0 and HBr + LaBr3 + H 2 0 systems from 5 to 55 °C. L N. Roy, J. Brainard, A. Nadkami, N. Coffman, R. N. Roy 748. Blue light, heavy leptons, and the SuperBall. W. U. Schroder, B. C. Stein 749. Characterization of organic doped silica sol-gels. A. Marcol, D. R. Huntley 750. Comparison of sterol behavior in phospholipid/sterol Langmuir monolay ers. P. Kpere-Oalbo, A. B. Serfis 751. CoPt and FePt nanoparticles with thiol ligands. N. Wang, E. Watson, X. Sun, D. E. Nikles 752. Destabilization of phospholipid liposo mal bilayers by Yersinia enterocolitica phospholipase A2. K. Borrenpohl, A. B. Serfis 753. Determination of the kinetic param eters for the reversible hydration of pyruvic acid. J. Purdon, J. E. Meany, G. T. Spyridis 754. Determination of the kinetics of the reaction between glucose oxidase and 16-mercaptohexadecanoic acid using surface-enhanced Raman spectroscopy. C. Delaney 755. Determination of the solvatochromic parameters of 1-butyl-3-methylimidazolium hexafluorophosphate, a roomtemperature ionic liquid. J. A. Ingram, R. S. Moog 756. Development of novel reactions and products through polymerization and microemulsions. S. Kiridand, A. Pojman, W. Ainsworth 757. Dissociation equilibria for the amino acid TABS from 5 to 55 °C. A. N. Simon, M. P. Cummins, B. S. Stockdale, B. J. Tabor, L. N. Roy, R. N. Roy 758. Electric field alignment of nanostructured block copolymer thin films. T. P. Lodge, R. Sharma, D. Savin, K. Krishnan 759. Electronic control and high voltage system for manipulating rare ions in a gas-stopping cell. L E. Miller, P. A. Lory, D. J. Monissey, S. Schwarz, G. Bollen
760. Emersion IR studies of the effect of pH on molecular interactions at the interface between water and -NH 2 and -COOH terminated self-assembled monolayer films. V. R. RekJ, K. E. Johnson, J. E. Pemberton 761. Emission spectroscopy: The photodis sociation of methyl formate with 218-nm light. J. A. Mueller, L J. Collier 762. Emulsion and conductivity characteris tics of silicon-containing surfactants. CM.Baldwin, D.H.Akridge 763. Exploration of the vibronic structure of the silver trimer through dispersed fluorescence spectroscopy and quantum calculations. R. J. Clark, G. Tarczay, I. Sioutis, A. Bezant, T. A. Miller 764. Fabrication and characterization of Si-Si02-Au MIM device for production of low-energy electrons. E. C. Reichart, A. Lapfcki, T. L O. Barstis, T. Engstrom, D. C. Jacobs 765. Fullerol doped silica: Powders, glasses, and films for optical applica tions. B. R. White. D. R. Huntley 766. Influence of lauric acid on the adsorp tion of 12-bromododecanoic acid at the liquid-solid interface as studied by STM. A. Cavanagh, G. W. Flynn, K. Kannappan 767. Infrared matrix isolation and theoretical study of the reaction of tetrachloromolybdenum oxide with methanol. E. M. Schierioh, B. S. Ault 768. Inhibition of radiofytic oxidation with Ti0 2 . K. E. Setfert, S. H. Szczepankiewicz, M. R. Hoffmann 769. Intrinsic rotation and molecular struc ture. A. G. Petrovic, P. L Polavarapu 770. Investigation of optimum surface modification in porous silicon for nega tive-ion desorption ionization on silicon mass spectrometry. L C. Jacobson, R. Estler 771. Investigation of polymer electrolyte membranes. B. M. Morian, D. F. Rogers, L S. Ramanathan, B. C. Benicewicz, T. M. Apple 772. Investigation of raft formation in lipid/ sterol Langmuir monolayers. C. Jokerst, A. B. Serfis 773. Investigations into fullerene/porphyrin interactions via NMR relaxation mea surements. V. Kliban, A. A. Rodriguez 774. Investigations of phosphorylation in the MARCKS protein using ESI-FTICR-MS. J.Adcox 775. Kinetic and mechanistic studies of the reaction between myoglobin and docosylmesylate using Langmuir-Blodgett techniques and FTIR. S. Todaro, A. A. Decked 776. Kinetics and mechanisms of reactions of [ferrocenyl(methoxy)carbene]pentacarbonylchromium(O) with primary aliphatic amines in aqueous acetonitrile. K. L Budzinski, C. F. Bemasconi 777. Kinetics of CI atom reactions with naphthalene and alkylnaphthalenes. X. Peng, C. Quant, D. Coulson, M. Luu, S.Hewitt 778. Lipid monolayer phase diagrams: The DMPC-dihydrocholesterol-ceramide system. C. Omura, J. P. Hagen III 779. Magnetite Fe 3 0 4 nanocrystals: Spec troscopic observation of aqueous oxida tion kinetics. J. Tang, M. M. Myers, L E. Brus 780. Mapping a DTAB-SDS-water ternary phase diagram using laser light scatter ing and fluorescence spectroscopy. E. W. Hall, K. K. Karukstis 781. Mapping of liquid-crystalline textures in type-l collagen solutions. J. B. Wolinsky, L. Gower, E. P. Douglas 782. Matrix isolation studies of small C^\m molecules and their anions. B. N. Jones, C. A. Arlington, M. Vala, J. Szczepanski 783. Methyl group dynamics by deuterium NMR. D. Cizmecryan, H. M. Yonutas, M. A. Garcia-Garibay 784. Molecular structure of sec-phenethyl alcohol. E. Chu, K. A. Utzat, R. K. Bonn
785. Near-infrared cavity ringdown spec troscopy of high-molecular overtones. G. A. Haveman, M. Everest 786. NPT Monte Carlo simulation of binary mixtures of Gay-Berne mesogens and Leonard-Jones spheres. K. T. Rodoifa, G. R. Van Hecke 787. Nuclear equilibration in an intranuclear cascade. M. D. Adams, W. U. Schroder 788. P-31 NMR study of polyphosphate hydrolysis. R. P. Robertson, K. A. Robertson, T. Jensen 789. Phase determination of biologically relevant lyotropic liquid crystals. S. L Poe, G. R. Van Hecke 790. Phosphorescence of 3-fluoro-1-ty rosine: A spectroscopic probe for protein local structure. J . L K . Keiki, K. Rousslang 791. Photochemistry of cerium(lll) in aque ous acidic solutions. C. Kimball, H. Altmiller 792. Photophysical studies of AAphenylnaphthylamine in micellar solutions of long-chain alkyltrimethylammonium bromide salts. O. F. Ohene, A. Ducre 793. Preparation and characterization of fibrous protein polypeptides. J. Sinski, B. Compton, E. Y. Chekmenev, R. Wittebort 794. Protein behavior. View from a metal center. E. J. Regel, T. I. Smimova 795. Quantum yield of singlet oxygen 1 0 2 (16g) produced by tetraphenylporphyrin in benzene. C. D. Whrtmore, S. A. Gerhardt, J. Z. Zhang 796. Radiation chemistry of CF2CI2: Impli cations for the ozone hole. L E. Stadelmann, N. Nakayama, S. C. Wilson, C. R. Arumainayagam 797. Raman spectroscopy and nanoindentation hardness studies on hexagonal boron nitride subjected to high pres sures. T. Banks, Y. K. Vohra, N. Velisavljevic 798. Raman spectroscopy study of the effects of space radiation on the microstructural properties and composition of nanocomposite carbon films. N. M. Medina-Emmanueili, K. E. Kristian, A. Gonzàlez-Berrios, Ο. Ο. Ortiz, Ι. Μ. Vargas, J. De Jésus, G. Morell, B. R. Weiner 799. Scanning probe investigation of singlewalled carbon nanotubes as an anode material for nanobatteries. R. D. Leib, A. Layson, D. Teeters 800. Sequential bond dissociation energies ofFe+(C02Mn=1-5). P. B. Armentrout, M. MacKenna, H. Koizumi 801. Silver-tin interactions in glass production. S. G. Ostlund, H. D. Schreiber 802. Single gold nanopartide electrokinetics and spectroscopy in a fluid. K. D. Kloepper. B. Dragnea 803. Size-dependent diffusion of organic solutes in o-alkanes and cycloalkanes. J. B. Jones, J. A. Zahm, C. L Mapes, C. Fuqua, K. T. Sobush, B. A. Kowert 804. SorvatochromatJc behavior of azulene and its derivatives: Developing a solvent polarity scale. A. R. Van Dyke, G. T. Spyridis 805. Spectroscopic characterization of nickel(ll) PAMAM dendrimer complexes. M. D. Moiander, Κ. Κ. Karukstis 806. Structural and hydrogen bonding parameters for 3-(2-hydroxy-1-naphthylmethyleneamino) benzoic acid. A. J. Dobson, A. Donnelly 807. Structure and dynamics of free base and zinc porphyrin containing polyamide dendrimers. C. C. Reese, J. Palma, J. Krause, A. Roitberg 808. Structure and hydrogen bonding of 5-methyl-2-pyrazinecarboxylic acid. A. J. Dobson, C. WlntersGrzegorzewski
TECH-35
ïiiiiïiiïfii Lhemists Ummittee Utters sa sisÏIIH Awards Are you taking on or pursuing a position of leadership? Would you like to develop the skills needed to be successful? If so, you should apply for a YCC Leadership Award! These awards cover the expenses of attending a leadership development workshop at either the 2003 central, western, or southeastern regional meeting. Participants w i l l explore the behaviors and characteristics exhibited by effective leaders at any level. Potential leadership opportunities, both w i t h i n and outside the workplace, w i l l be discussed, and personal plans for i m p r o v i n g leadership skills w i l l be developed. The application deadline is Tuesday, April 1 , 2003.
Application forms and further information about the awards are available at chemistry.org/ycc.
Aiuà spring rMationai Meeting Mrifiiiifirir^riiiirrifiiiir\^i^^iifill ifir illirnr\xι March 23-26, 2003 · New Orleans, LA SUNDAY, MARCH 2 3
9:00 a.m.-12:05 p.m. The Changing Role of Women in STEM Focusing on the training and early career experiences of women in Science, Technology, Engineering, and Mathematics (STEM), this symposium will also discuss the current status of women in these fields and the measures being taken to enhance their presence. Sponsored by WCC and cosponsored by SOCED. 1:30-4:30 p.m. Paving the Way to Career Success: How the ACS Can Help Information is provided about career management, job hunting, and other member services available from the ACS Office of Career Services, committees, divisions, and local sections. Sponsored by PROF and cosponsored by SOCED, WCC, and YCC. 2:00-5:00 p.m. Career Resource Center, Ernest Mortal Convention Center Academic Jobs: A Ph.D. Is Only the Beginning (workshop) Anyone considering a career in academia should attend to learn about all aspects of preparing for such a career, identifying job opportunities, and landing the offer. MONDAY, MARCH 2 4
9:00 a.m.-noon Faculty 101: A Day in the Life of a Faculty Member What does it really mean to be a faculty member day to day? Younger faculty members from community colleges; liberal arts colleges; and comprehensive research, state, and private colleges and universities give their perspectives. Sponsored by YCC and cosponsored by the Council of Undergraduate Research and WCC.
^œŒSF^
For additional
9:00 a.m.-1:15 p.m. Hilton Riverside Hotel Chemical Careers in the Federal Government Speakers from a national laboratory, the U.S. Air Force, and the White House will discuss opportunities for chemists in the federal government. Sponsored by SOCED and cosponsored by CHED and YCC. 11:30 a.m.-1:00 p.m. Ernest Mortal Convention Center, room 346
Presidential Event: Funding Opportunities for Long-Term Research (lunchbox forum) Speakers from the Department of Defense and the National Institute of Standards and Technology will review funding opportunities in their respective organizations while the audience has lunch. Cosponsored by COMSCI.
1:00-3:10 p.m. The TA ...What Am I For? Discussion topics include the training practices provided by universities; experiences of current TAs; and inherent problemsfromthe perspectives of students, TAs, and professors. Sponsored by YCC and cosponsored by the Office of Graduate Education. 1:00-4:00 p.m. Ernest Morial Convention Center, room 336 The Master's Degree—Its Many Faces and Objectives Some of academe's approaches toward designing master's degree programs that meet the needs of the chemical sciences workplace will be discussed. Sponsored by PROF and cosponsored by SOCED, CPT, WCC, and YCC. Organized by the Office of Graduate Education. 2:00-5:00 p.m. Hilton New Orleans Riverside, Versailles Ballroom Presidential Event: Celebrating Success and Reaffirming Commitment Topics include how to address underrepresentation, the progress to date, and the future direction of the minority affairs program. Organized by the Committee on Minority Affairs and cosponsored by Corporation Associates, Project · SEED, COMSCI, WCC, and YCC
TUESDAY, MARCH 2 5 9:00 a.m.-noon Career Resource Center, Ernest Morial Convention Center Writing Excellent Research Proposals (workshop) Robert Rich of the ACS Petroleum Research Fund (a granting agency) will introduce participants to the ins and outs of getting proposals funded. 3:00-5:00 p.m. Career Resource Center, Ernest Morial Convention Center Technical Writing Learn easy techniques to improve the effectiveness of all written documents. WEDNEQDAY, MARCH 2 6
9:30 a.m.-noon Industry Pavilion located in the ACS Exposition, Halls H/l 1, Ernest Morial Convention Center Innovative Approaches to Innovative Science—New Models for Graduate Education Brought to you by ACS Corporation Associates and the Office of Graduate Education, this symposium provides four cuttingedge models of sci-tech graduate programs that offer everything from specialized approaches to entrepreneurship to practical experience in industry while you pursue your graduate degree.
1:00-4:35 p.m. Ernest Morial Convention Center, room 218 Preparing Future Faculty Short-term teaching jobs give postdoctoral students an opportunity to "cut their teeth" before they begin tenure-track positions. The benefits offered by a variety of teaching positions will be discussed. Sponsored by CHED. 1:30-4:30 p.m. Careers in Chemistry and the Law Sponsored by the Division of Chemistry and the Law
These events have been compiled by the Office of Graduate Education. information, please contact Marta Gmurczyk at 202-872-4588 or
[email protected].
MONDAY. MARCH 2 4 1:00-4:00 p.m. Ernest Morial Convention Center, room 336 The Master's Degree— Its Many Faces and Objectives Some of academe's approaches toward designing master's degree programs that meet the needs of the chemical sciences workplace will be discussed. Sponsored by PROF and cosponsored by SOCED, CPT, WCC, and YCC. Organized by the Office of Graduate Education.
ΚA
TECHNICAL PROGRAM 809. Study of the effects of space radiation on the surface chemical composition, bonding structure, and morphology of nanocomposite carbon thin films. K. E. Kristian, Ν. Μ. MedinaEmmanuelli, 0 . 0 . Ortiz, A. Gonzâlez-Bem'os, J. De Jésus, I. M. Vargas, G. Morell, B. R. Weiner 810. Studying dimethyldodecylamine-oxide at the CCI4/H2O interface via vibrational sum-frequency spectroscopy. J. C. Marcum, M. A. Leich, G. L. Richmond 811. Surface-enhanced Raman scattering as a probe of surface-mediated photochemistry. A. N. McFeeley, B. D. Gilbert 812. Synthesis and flash photolysis of water-soluble porphyrins. J. Antunovich, R. Selzer 813. Synthesis and rotational characterization of proline dipeptides. J. M. Bryk, M. J. Tubergen 814. Synthesis of metal particle catalysts via reverse micelles for carbon nanotube growth. B. F. Pierce, T. M. Ticich, R. L. Vander Wal 815. Synthesis of fert-butyl 2R 2R* and 2fl* 3S* 3-trimethylacetoxy-2,3-dideuterobutanoate. L. A. McMartin, J. Mohrig 816. System Η ? 0 + HCI + HOCI3 at 5-55 °C: Application of Pitzer formalism. S. J. Richards, M. P. Cummins, L. N. Roy, R. N. Roy 817. Temperature-dependent changes in GdxY^COB crystals. T. D. McGovern, A. Zoubir, M. C. Richardson 818. The detection of density gradients using the nondestructive method of luminescence. R. P. Valliere, D. R. Huntley, C. Schilling 819. Theoretical and experimental investi gation of the two-photon absorption cross section of flavonoid and anthocyanidin dyes. J. B. Nusser, T. D. Millsap, A. J. Sunday, B. C. Byrne, D. A. Huffman, A. G. Joly, J. N. Woodford 820. Theoretical study on the decomposi tion reaction of hydroxyalkoxy radical derived from oxidation of isoprene initi ated by OH. J. Park, J. C. Stephens, R. Zhang, S. W. North 821. Thermodynamic excess functions in mixtures of anisole and alcohol. S. A. Price, G. R. Van Hecke 822. Thermodynamics of unsymmetrical mixed electrolytes HCI + YbCI3 + H 2 0. M. P. Cummins, B. J. Tabor, C. A. Himes, L N. Roy, R. N. Roy 823. Three-dye combination luminescent solar concentrator. G. E. Lokey, M. S. Hanes, S. T. Bailey, J. D. M. Shearer, Y. Zhang, B. P. Wittmershaus 824. Transmission electron microscopy of aerosol soot nanoparticles. B. Ford, J. Roberts, A. Wensmann 825. Trimetallic nitride template endohedral metallofullerenes. K. R. Fletcher, J. C. Duchamp, E. B. lezzi, T. E. Glass, H. C. Dorn 826. Use of fluorescence spectroscopy to map a CTAB/SOS/water ternary phase diagram. S. A. McCormack, Κ. Κ. Karukstis 827. Using surface plasmon resonance to monitor surface-cell and protein-protein interactions. M. N. Holtz, R. Richmond 828. Vapor-phase Raman spectra and ab initio calculations for 3-methylindole. A. Combs, D. Autrey, Ζ. Αφ, Κ. Haller, J. Laane
36-TECH
829. Zwitterions, salt bridges, and the role of solvent. M. F. Bush, A. S. Lemoff, E. R. Williams SectionG Undergraduate Research Poster Session: Biochemistry Cosponsored with Society Committee on Education 2:00-4:00 830. Protein structure and folding deviations due to changes in the physicochemical properties of neat organic solvents: A circular dichroism study. M. M. Elvekrog, Y. Ferrer, K. Griebenow 831. A mathematical model for tropomyosin 345Zip uncoiling. N. A. Van Gorder 832. Acid-base properties at subzero tem peratures for the dipolar compound HEPPS in 50 mass% dimethylsulfoxidewater mixtures. J. M. Denton, L. Seing, M. Maggard, M. Murphy, H. Craig, J. Wilson, L. N. Roy, R. N. Roy 833. Adenochrome: A novel iron-binding motif from the heart of an octopus. C. M. Davis, A. Stewart 834. Adenochrome: Location and distribu tion in an octopus. C. M. Davis, R. B. Sears 835. Alkaline-earth salts enhancement of quinone-mediated ascorbate oxidation. L Rivas, P. Sanchez-Cruz, A. E. Alegria 836. An HPLC assay to quantify basic sites on DNA. P. Garza, M. Zewail-Foote 837. Analysis of adenoviral-mediated overexpression of wild-type and dominantnegative PKCa in endothelial cells. A. N. Owusu-Sarfo, E. Harrington, J. Brunelle 838. Antimicrobial properties of goldenrod plant extracts. M. T. A. Pieri, M. P. Labare 839. APC localization linked to myosin VI movement through interaction with GLUT1CBP. T. H. Louis, B. Reed 840. At the plant/agrobacterium interface: Chemical approaches to signal percep tion. N. A. Goodman, J. Maresh, J. Zhang, D. G. Lynn 841. Attempts to measure serotonin levels in mouse brain matrixes. I. D. Hensley 842. Automated acquisition of enzyme kinetics data generated in a Spec-20 spectrophotometer via the Lab-Works Learning System. A. Lovold, D. Williams, L. Sreerama 843. Biochemical characterization of Peripherin/rds in the mouse retina. H. A. Welter, X. Ding, M. I. Naash 844. Biochemical investigation of cyto chrome P450 3A27 enzyme induction in response to ρ,Ρ'-DDE exposure in white sturgeon. D. D. Bowe, P. R. Boyle, B. C. Lowell, E. P. Foster, D. T. Gundersen, J. M. Paar 845. Biocompatibility determination of the oxirane dental monomers UNOX-201 and UVR-6105 using sister chromatid exchange assessment. T. Lange, L. A. Wetmore 846. Biosynthesis of a domain of a G protein-coupled receptor. J. Englander, R. Estephan, F. Naider 847. Butyrate-induced apoptosis in HCT8 colon carcinoma cells. I. A. Larson, D. P. Heruth, L. A. Wetmore 848. Cellular rearrangement during the development of the mammalian organ of Corti. E. E. McKenzie, M. W. Kelley 849. Cellular uptake studies of a peptide inhibitor of protein tyrosine phosphatase SHP-2. J. R. Maiolo III, E. A. Ottinger 850. Characterization of 5-nucleotidase from fish gill. K. A. Krone, J. C. Robertson 851. Characterization of Rhodospirillum rubrum ADPGIucose Pyrophosphorylase: Role of Lysine-40. R. Malaguti, J. Hernandez, S. Lieu, C. R. Meyer
852. Characterization of novel monoclonal antibodies generated from early hemato poietic progenitors. S. Nathaniel, K. Choi 853. Characterization of the histone-like HU protein from Helicobacter pylori. C. Chen, A. Grove 854. Characterization of vancomycinresistance properties and proteins in S. aureus strains BB255 and BB255V3. A. Axhemi, B. Davis, M. A. Fisher 855. Collagen-binding studies with AMerminal peptides of osteocalcin. A. Bélanger, R. V. Prigodich 856. Comparative characterization of the two mammalian glutaredoxins. S. L. Gillenberger, D. W. Starke, A. J. Berdis, J. J. Mieyal 857. Comparison of substrate specificity for the zinc-metalloprotease: carboxypeptidase G and prostate-specific membrane antigen. Y. Toriyabe, M. Hosaka, A. Tran, A. Adona, T. A. Girtsman, N. Santiago 858. Comparison of subunit and tetramer paths for the allosteric transition of hemoglobin. A. L Jonsson, F. Torres, T. Hoffman-Zoller, K. W. Olsen 859. Content and activity analysis of a digestive enzyme supplement. S. M. Landers, C. M. Rener 860. Crystallographic studies of a Rhodopsin mimic. E. Mathes, R. M. Crist, C. Vaileiou, B. Borhan, J. H. Geiger 861. Defining domain boundaries in epithelial cadherin. H. A. Levanduski, N. A. Housley, T. Newell, S. Pedigo 862. Denaturation of the protein phycocyanin: An undergraduate biochemistry laboratory experiment. P. J. DeLaLuz 863. Design and methodology of recombinant methods for the production of serine carboxypeptidase II. R. Guerra, M. Kopecki-Fjetland 864. Design and properties of stable trimeric coiled coils derived from the Λ/Lhelices of HIV-1 Envgp41. K. L. Gorres, J. M. Louis, G. M. Clore, C. A. Bewley 865. Design and synthesis of oligomers of /V-substituted glycine that bind to the Yes-associated protein. D. Acker, J. D. Kehlbeck 866. Detection of DNA-protein cross-linking via inhibition of cleavage by endonucleases. P. To, P. Sanchez, A. Reno, E. V. Rivas, L. Vasquez, E. D. A. Stemp 867. Detection of various trace metals in hair using atomic absorption spectros copy. M. R. Jacobs, R. L. Falconer 868. Determination of D-aspartic acid and NMDA in rat subjected to experiment for learning and memory. T. Goff, P. Roody, P. Spinelli, D. A. D'Aniello 869. Determination of the binding affinity of fusarochromanone (FC-101) to bovine serum albumin. C. A. Luces, R. E. Wuthier 870. Determination of the equilibrium affinity for IRP1 binding IRE. R. T. Finley, D. P. Mascotti 871. Determination of the expression of the phenylalanine ammonia lyase gene in VFN8 and diageotropica tomato by reverse transcriptase polymerase chain reaction. W. J. Sparks, S. Tabaie, M. S. Rice 872. Determination of the redox state of a cellular system and the effect of various reductive stresses on this redox state. R. L. Fagan, J. Pong, D. J. Rueland, S. Ganguli 873. Detoxification of chloroacetaldehyde by human aldehyde dehydrogenases. S. S. Ong, W. H. Chan, L. Sreerama 874. Developing RNA catalysts for the carboxylation of biotin. J. Sayes, S. P. Wilkinson, R. M. Strongin, G. L. Waldrop, A. Grove 875. Development and validation of an in vitro model for testing drug toxicity. E. B. Bell, T. L. Macdonald, E. Joshi
876. Development of a methodology for studying the kinetics of yeast enolase. A. Ramos, E. F. Healy 877. Development of a muscle cell-specific expression vector for treatment of hemo philia B. S. M. Rodriguez-Colon, R. W. Herzog Jr., F. Mingozzi, E. Liu 878. Development of a quantitative assay for glutathione reductase. L. Isbell, E. F. Healy 879. Differential effect of inbred strains on meiotic drive at the Om Locus in mice. S. C. Thomas, F. Pardo-Manuel de Villena 880. Differential gene expression in day 12 and day 15 equine embryos. K. Kelly, C. Adam 881. DNA extraction and analysis from buccal cells. M. D. Wolter, B. P. Huddle 882. DNA sequence analysis of the R body protein encoding plasmid from Caedibacter taeniospiralis. A. Johnson, R. L. Maser, J. A. Dilts. D. P. Heruth 883. Drosophila as a model for the study of Batten's disease. C. M. Hessick, Q. Chu-LaGraff 884. Effect of alcohol-containing cosotvents on charged peptide interactions. D. P. Mascotti, M. P. lannetti 885. Effect of ethylenediamine binding to the buried diiron center of E. coli ribo nucleotide reductase. J. J. Potaracke, N. W. Leicht, C. J. McMahon 886. Effects of 4,6-diamidino-2 phenylindole on cell growth and global gene expres sion in HCT8 colorectal cancer cells. T. B. Hawkins, D. P. Heruth, L. A. Wetmore 887. Effects of antioxidants on the reaction of 6-hydroxydopamine and NO: Potential implications for the treatment of Parkin son's disease. M. J. Allen, M. A. Fisher 888. Encouraging apoptosis: Designing inhibitors of the interaction between Bax and Bcl-2. J. D. Pike, D. A. Suffredini 889. Enzyme kinetics by polarimetry: A study of the pH dependence and metal ion inhibition of invertase-catalyzed sucrose hydrolysis. T. L. Harshberger, J. A. Cramer 890. EPR study of the DNA binding of a cisplatin analog. L F. Millemon, B. W. Hicks, K. A. Gardner 891. Evaluation of DNA stability in an ionic liquid. A. C. Robinson, J. H. Davis Jr., N. F. Campbell 892. Evidence of a homoserine ester as a by-product of protein cleavage by cyano gen bromide. M. G. Hlatshwayo, T. H. Morton, J. Bennett 893. Examination of photoactivation in DNA photolyase using difference infrared spectroscopy. M. C. Jonas, L. A. McKee, S. Kim 894. Expression of cyclin B1 in p53-mutant U138MG glioblastoma cells after expo sure to Etoposide (VP16). D. Stroup, L. A. Wetmore 895. Flanking sequences modulate diepoxide cross-linking efficiencies at the 5'-GNC site. G. A. Sawyer, J. T. Millard 896. Formation of disulfide bonds in linkercarrier moieties for use in radioimmunotherapy. R. A. Reuther, S. Z. Lever, M. Lewis 897. Generation of a otenminal his-tag baculovirus transfer vector for the expression of human acetyl-CoA car boxylase 2 (ACC2) in vivo. A. L. Reno, R. L. Coursey Jr., S. Chirala, J. Mao, S. J. Wakil 898. Glycogen accumulation in yeast in relationship to gluconeogenesis. N. L Yohman, M. A. Fisher
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CHED/TECHNICAL PROGRAM
899. Horizontal gene transfer of the Reb locus in Caedibacter taeniospiralis. V. D. Englert, J. Wiegel, R. L. Maser, J. A. Dilts, D. P. Heruth 900. HPLC analysis of catecholamines and indolamines in brains of transgenic mice with a deletion mutation of the tyrosine kinase domain of the FGFR1 growth factor receptor. A. S. Gambino, L. C. Jenkins, J. Myers, M. K. Stachowiak, T. D. Corso 901. Hydrogen bonding in discrete base pairs containing 6-thioguanine. S. U. Dunham, A. H. Moraco 902. Identification of enzyme activities in dusky pygmy rattlesnake (Sistrurus miliarius barboun) venom. K. M. Walosik, J. C. Korody, D. D. Jackson 903. Identification of the activity of rhodanese enzymes in Bacillus subtilis, specifically YtwF. R. V. Mauldin, T. J. Larson, J. L Donahue 904. Identification of the histidine member of the ΗΤΑ catalytic triad. C. A. Roberts, T. L. Bom 905. Influence of calcium on Manduca sexta plasmatocyte spreading and network formation. E. Willott, C.A.Hallberg,H.Q.Tran 906. Infrared study of kinesin Eg5 and monastrol. N. A. Dalrympfe, K. Crosby, E. Wojcik, S. Kim 907. Interphase fluorescence in situ hybrid ization to demonstrate translocation of cyclin Dlgene to chromosome 14 immu noglobulin heavy chain locus with result ant overexpression of cyclin D1 protein in a mantle cell lymphoma cell line. S. O. Reingold, J. Gu, R. Fernandez, R. L Katz 908. Investigating branched-chain amino acid metabolism by analyzing Arabidopsis thaliana knockout mutants. M. S. Hanes, M. A. Campbell 909. Investigating recombinant food-based vaccines for salmonids: Developing strategies to combat whirling disease. S. L Doyle, J. G. Rohrbough, B. W. Hicks 910. Iron chelation drugs: Natural vs syn thetic heterocyclic amines. C. M. Davis, A. D. Bosshart II 911. Isolation and characterization of chitinbinding American mistletoe lectin. R. Balder, P. J. Stein 912. Kinetics and substrate specificity for dipeptidylpeptidase I. S. W. Weiner, R. Kennedy 913. Synthesis of optimal substrates for dipeptidylpeptidase I. S. W. Weiner, M.Lowe 914. Kinetics of the reaction between cisplatin and metallothionein. E. A. Moran, B. A. Hubbard, J. C. Dabrowiak, A. Souid 915. Ligand binding and salt effects on the thermodynamics of protein unfolding. C. L Jones, S. Jivarajan 916. Lipid peroxidation end product, HNE, binds to and alters the conformation and function of histories: Implications for Alzheimer's disease. R. Petroze, J. Drake, D. A. Butterfield 917. Localization and characterization of D82 and J81 promoters in the murine TCR δ locus. M. S. Krangel, J. Carabana, Ε. Β. Ortigoza 918. Localization of PMS2 in meiotic cells. A. Sedletcaia, P. Cohen 919. Measuring snake venom mutagenicity using the Ames Salmonella microsome assay. M. A. C. Crooks, D. D. Jackson 920. Mechanistic characterization of ImiS, a metallo-B-lactamase, using pH depen dence. K. C. Markert 921. Metal-binding studies of mutant DNAbinding domains of the glucocorticoid receptor. A. Tenderholt, B. Rous, H. A. Godwin 922. Microwave-enhanced hydrogen -> deuterium isotope exchange studies in simple glycoconjugates. Β. Ν. Le, E. A. Cioffi
923. Modified assay for chitin deacetylase. H. J. Day, E. W. Blakeney 924. Molecular modeling of unsaturated fatty acids and fatty acid epoxides. L Coney, R. Jenkins, S. Helms, R. Swindell 925. Mutagenesis studies of glutamate 344, serine 198, and tyrosine 401 in firefly luciferase. S. R. Wilkinson, N. F. Khattak, T. L. Southworth, M. H. Murtjashaw, B. R. Branchini 926. Nitric oxide production from newly synthesized ruthenium porphyrins. M. J. Ranaghan, S. K. O'Shea, C. J. Timpson 927. Nitric oxide's role in apoptotic levels of VSMC associated with atherosclerotic plaque. S. D. Fiedler 928. NMR in the study of amino acid and peptide interactions with sugars. K. G. High, M. T. Tran, E. Wigton, E. Musselman 929. Nopp140 expression and interactions. J. H. Fraser, P. J. DiMario 930. Nutrient regulation of the expression of the potential toxin gene, rebd, from Caedibacter taeniospiralis 116. H. A. Steele, D. P. Heruth, J. A. Dilts 931. Optimizing activity assays of tryp tophan 2,3-dioxygenase in mouse liver. S.A.Goetz 932. Overexpression, purification, and characterization of a potential rubredoxin from ANABAENA 7120. J. Traag, M. Kopecki-FjetJand, C. FjetJand 933. Phasing of RNA with two A5 bulges by native gel electrophoresis and transient electric birefringence. P. Kebbekus, A. J. Hodgson 934. Photoallergens: They don't just irritate your skin. A. L. Lane, J. M. Allen, S. K. Allen, E. D. Glendening 935. Physical properties and inhibition of phospholipase D from Streptomyces chromofuscus. D. V. West, J. Arvizu, S. C. Boegeman 936. Preorganization of the chromophoreforming region in immature S147P green fluorescent protein mutants results in their increased maturation efficiency at higher temperatures. M. Zimmer, F.Fedeles 937. Properties of aqueous Λ/ohlorotaurine. R. Gandhi, G. H. Purser 938. Protein modification by the Pechmann condensation in diabetes. L D. Gaddis, L. D. Obradovich, R. Renfro, J. Bennett 939. Protriptyline and dibenzocycloheptene fluorescence quenching by diethyl and triethyl amine: A simple model for drugprotein interaction. J. M. Sirva, C. Garcia, R. Oyola, L. E. Pifiero, X. Calderon 940. Purification of α-synudein and analysis of environmental factors concerning fibrillation and aggregation. J. Henriques, V. Uversky, A. L. Fink 941. Purification of CopY repressor in Enterococcus hirae. S. Tufekcic, C. T. Dameron 942. Purification of glutaminyl cyclase. G. N. Stowe 943. Quantifying isoflavones in hard and soft wood pulp. F. J. Holland Jr., C. D. Gilcrist, S. K. O'Shea, A. Tate 944. Quantitative PCR analysis of diepoxybutane damage within rat liver mito chondrial DNA. J. E. Juskewitch, J. T. Millard 945. Quantitative PCR analysis of diepoxybutane damage within the chicken beta-globin domain. A. M. Pilon, J. T. Millard 946. Rapid self-assembly of K+ stabilized G-DNA nanowires. J. A. Loehr, T. C. Marsh
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
947. Re-engineering photosynthesis in Chlamydomonas to destroy halogenated aromatic pollutants. S. R. Audley, M. Garcia, M. K. McBrayer, K. Redding 948. Reaction of /V-chlorotaurine with human serum albumin. E. R. Moore, D. W. Reading, G. H. Purser 949. Reductive activation and thiol reactivity of benzazolo[3,2-a]quinolinium salts. E. Cordones, W. Flores, L. Rivera, Y. Marcano, M. Cordera, P. Sanchez-Cruz, O. Cox, A. E. Alegria 950. Regioselective reduction of steroids with guidance from bovine serum albu min. D. Dempah, R. Hayashi, X. Liu 951. Regulation of the pyrimidine catabolic pathway. E. C. Boaz, G. M. Meyer, M. F. Santiago 952. Relationship of glutathione levels to proteasome activity in cultured Hep G2 cells. C. T. Hartman, T. M. Donohue Jr. 953. Ribozyme kinetics. J. Manning, T. M. Coleman, F. Huang 954. RNA-protein cross-linking from gua nine oxidation using the flash-quench technique. C. L. Lightfoot 955. Role of metallothionein in cellular zinc metabolism. H. E. Hewitt, S. K. Krezoski, D. H. Petering 956. Role of protein secondary and tertiary structure on enzymatic digestion. J. R. Gallagher, N. J. Odum, R. A. Kopper 957. Stability of allergenic peanut proteins toward enzymatic digestion. N. J. Odum, J. R. Gallagher, R. A. Kopper 958. Role of the Oct-1 POU domain/ SNAP190 complex in activation of snRNA genes. A. C. Brooks, S. L. Hovde, C. S. Hinkley, K. Strong, W. R. Henry, J. H. Geiger 959. Sensitivity of human breast carcinoma cells to ottelione A and its analogues. J. L. Dechaine, H. J. Lewis, S. N. Ayyad, T. R. Hoye, L. Sreerama 960. Sequence dependence on DNAprotein cross-linking. N. Harris, K. Kurbanyan, A. M. Lueras, C. L. Lightfoot, C. Evangelista, E. D. A. Stemp 961. Signal generation and perception in Striga asiatica. W. K. Erbil, D. G. Lynn, W. J. Keyes 962. Solution structure refinement compar ing reference model NOE volumes. M. Mahar, J. S. Anderson, G. Hernandez, D. M. LeMaster 963. Sonochemistry of quinone-containing antitumor drugs. D. Lopez, A. E. Alegria 964. Stereospecific C-H bond activation for deuterium and tritium incorporation into nucleotides. M. L Maier, E. A. Cioffi 965. Strategies for purification of the soluble insulin-like growth factor I l/mannose 6-phosphate receptor. M. A. Montgomery, R. G. MacDonald 966. Structural analysis of the ANABAENA group I intron. E. M. Toth, M. C. Marvin, C. E. Rohlman 967. Structure-function relationships of human serum albumin modified by the dicarbonyl sugar-methyl glyoxal. J. Allport, C. Butts, S. Edeiken, L. Budiansky, R. Subramaniam 968. Studies of the mRNA level for the inducible nitric oxide synthase enzyme in C6 glioma cells. R. Delcampe, D. Dean 969. Substrate specificity of the subtilisinlike proprotein convertases: A role for hydrophobic amino acids adjacent to and within the substrate cleavage recog nition sequence. E. Stamper, A. Y. Fleytman, J. M. Sushynski, E. Lerche, L. D. Tippett, J. R. Hogg, B. A. Ziemba, G. G. Cummings, J. F. Sucic 970. Synthesis and analysis of 2'-o-methylated ADAR2 substrates. M. A. Lancaster, L. M. Easterwood, P. A. Beal 971. Synthesis and cathepsin D inhibition of hydroxyethyl isosteres with Λ/Oiperazine or 4-phenylpiperazine. A. Stefan, S. E. Hatfield, W. E. Godwin, R. M. McConnell
972. Synthesis and cathepsin D inhibition of hydroxyethyl isosteres with Λ/oiperdine or morpholine. N. Myers, S. E. Hatfield, W. E. Godwin, R. M. McConnell 973. Synthesis and cathepsin D inhibition of hydroxyethyl isosteres with /^pyrrolidine or L-proline methyl ester. C. Newton, S. E. Hatfield, W. E. Godwin, R. M. McConnell 974. Synthesis and self-assembly of G-DNA molecular scaffold. B. A. Piras, T. C. Marsh, T. A. Taton 975. Synthesis and toxicity of the dopamine metabolite DOPAL (3,4-dihydroxyphenylacetaldehyde) and its relation to the progression of Parkinson's disease. L. C. Jenkins II, A. S. Gambino, T. D. Corso 976. Synthesis of 18 0 2 , 13 C labeled orotate5'-monophosphate for isotopic studies applicable to orotate-5'-monophosphate decarboxylase. D. J. A. Smiley, A. P. Dota III, M. Stonestreet 977. Synthesis of dex-ceph-mtx: A sub strate for cephalosporinase. E. Sprowl, V. W. Cornish 978. Temperature-induced changes in the hydrophobic regions of a-crystallin. L Y. Campbell, L. B. Hibbard, C. N. Clark 979. The effect of α-tocopherol on the interaction of protein phosphatase 2a and protein kinase Ca. L. E. Mains, M. A. Fisher 980. The effect of yeast strain and contami nation on aroma in home-brewed beer. S. M. Puolitaival. K. N. Fobbs, E. M. Keller, S. J. Coggin, M. S. Sabo 981. The effects of DNA flexibility and curvature on the enzymatic activity of uracil DNA glycosylase. B. Polishak, M. Zewail-Foote 982. The effects of protamine sulfate and heparin on the interaction between human factor Xlla and antithrombin III. C. Fidanza, A. S. Brecher, M. H. Coggin 983. The synthesis and characterization of liposome-encased porphyrins. M. D'Souza, M. F. Roberto, E. M. DeThomas, M. Panos, P. K. Kerrigan 984. The use of water-soluble, unmetallated porphryins as light-absorbing sensitizers in the phototherapeutic treatment of C6 cells. M. F. Roberto, P. K. Kerrigan, J. Haley, J. E. Bradshaw, E. M. DeThomas, M. D'Souza 985. Thermodynamics of 4-[/\Amorpholino]butanesulfonic acid for the biological pH 7.3 to 8.4. L Blackwell, B. R. Lively, M. P. Cummins, C. N. Roy, L N. Roy, R. N. Roy 986. Thymidilate synthase expression in human R163K and M190K using a monoclonal antibody. A. W. Williams, A. Chadee, S. Berger 987. Two-step denaturation of thimet oligopeptidase in urea. T. H. Patwa, J. A. Sigman, A. J. Wolfson 988. Uptake of taurine in cells: Investiga tions into radioprotection. K. R. Horstman, M. Barranger-Mathys, E. Bell, L. Samowski, J. Vanderweele, J. Mesina 989. Use of a band shift assay to analyze cytoskeletal protein interactions at differ ent developmental stages of the soy bean plant. W. J. Jermakowicz III, J. T. B. Collins Section H Undergraduate Research Poster Session: Computational Chemistry Cosponsored with Society Committee on Education 2:00-4:00 990. Ab initio and model investigation of acetylene clustering around hydrogen cyanide. W. P. Schroeder
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TECHNICAL PROGRAM 991. Ab initio study of HN0 3 -water clus ters: HN03(H20)„, η = 1 ^ . R. Figueroa, I. Cao-Berg, A. Debron, D. E. Bacelo 992. Ab initio and DFT survey of sotvated acetonitrile anion lithium complexes. A. Goncher, J. D. Madura, F. F. Fleming 993. Analysis of solvation effects of H 2 0 and CCI4 on uranyl by COSMO and DFT. C. A. Fahlstrom, T. L. Windus, W. A. deJong, D. A. Dixon 994. Assessing antioxidant activity of the carotenoids: Is there a quantitative relationship between theoretical calcula tion of electron affinity and superoxide suppression? W. J. Kelly, K. J. Moore 995. Chemical shielding: A quantum mechanical phenomenon. K. L Weichey, R. J. luliucci 996. Comparisons of helium metal hydride, helium metal halide, and argon metal hydride ab initio potential energy sur faces. R. J. Gates, Β. Κ. Taylor 997. Computation of the proton affinities of phosphorus(lll) compounds and the analysis of the results via quantitative analysis of ligand effects. W. Ansaldo, W. P. Giering, A. Prock 998. Computational analysis of some Knovenagel products. B. J. McCulloch, J. A. Bohmann 999. Computational approaches to antican cer drug design. S. A. Taylor, S. Feldgus, G. C. Shields 1000. Computational studies into the bond ing of [CuUf + ions. Κ. Μ. Glasser, A. C. Goren, A. J. Stace 1001. Computational studies of environ mental pollutants. A. Lewis, J. A. Bumpus, C. J. Cramer 1002. Computational study of cation-rr interactions. C. D. SherriH, R. P. Steele 1003. Computational study of interstitial hydrogen adsorption to models of car bon nanotubes. B. T. Bentley, R. C. Brown 1004. Creation of a class IV charge model for boron based on hybrid density func tional theory. J. M. Brom, B. J. Schmrtz, J. D. Thompson, C. J. Cramer, D. G. Truhlar 1005. Determination of a second stable apo structure of the CopZ copper chaperone using the CHARMM force field. A. R. Hower, J. D. Evanseck, C. T. Dameron 1006. Determination of a working force field and structure for £ coli adenylate kinase closed form. A. Kimple, R. I. Cukier 1007. Development of a new semiempirical quantum chemical method using exact Hamiltonian consistency conditions. A. G. Taube, C. Taylor, K. Runge, R. J. BartJett 1008. Electron affinities of silicon-containing compounds. A. J. Crowell, R. Damrauer 1009. Energetic and geometric insights into methanol clusters (CH3OH)„, for η = 2-20. V. F. DeTuri, M. M. Pires 1010. Exploration of experimental and computed proton affinities of alcohols via quantitative analysis of ligand effect. A. M. Pagano, A. Prock, W. P. Giering 1011. Exploring the QALE model through the computational studies of the proton affinities of thiols and thioethers. J. M. Tourigny, W. P. Giering, A. Prock 1012. Hydrogen bonded clusters. E. K. Pokon, G. C. Shields 1013. Investigation of interactions between chitnase and oligosaccharides. L L Thomas, P. Dalai, N. N. Aronson Jr., J. D. Madura
1014. Mechanism determination of tropospheric ozone degradation by bromine oxides. B. R. Dickerson, W. A. Parkinson 1015. Mechanisms of boron bromide cage cluster ion formation: A computational study. T. P. Tauer, D. A. Hales 1016. Monte Carlo simulated anion solva tion. D. D. Kemp, M. S. Gordon 1017. Nucleophilic attack at the disulfide of a simple dipeptide. S. M. Bachrach, A. Chamberlin 1018. Objective evaluation of model Gauss ian 98 ab initio chemistries for studying energies along a SN2 reaction pathway. A. K. Fuller, D. Carter 1019. Relating structure and function in a series of insect pheromones using molecular mechanics. K. Keith, M. K. Murphy 1020. Solution effects on the proton-bound species [CCI 3 HOCH3r in methanol by ab initio and density functional tech niques. V. F. DeTuri, J. Killeen 1021. Theoretical studies of single electrontransfer mechanisms. N. Svedlanak, E. F. Healy Section I Undergraduate Research Poster Session: Green Chemistry Cosponsored with Society Committee on Education 2:00-4:00 1022. Algae extract for corrosion preven tion. B. A. Griffith, K. Aamer, A. Ludwick, H. Aglan 1023. CO oxidation with nanocompositebased heterogeneous catalysts. R. A. May, H. Lang, B. D. Chandler 1024. Conversion of polyhydric alcohols into hydrocarbons: A search for a coupled reducing agent. J. M. Robinson, P. Nandakumar, T. Millstead, L S. Ornelas 1025. Developing first-semester high school chemistry laboratory exercises that incorporate the principles of green chemistry. S. A. Henrie, R. E. Hall, K. R. Fowler, C. F. Leslie, M. J. C. Newhouse 1026. Developing second-semester high school chemistry laboratory exercises that incorporate the principles of green chemistry. S. A. Henrie, K. R. Fowler, R. E. Hall. C. F. Leslie, M. J. C. Newhouse 1027. Development of a green epoxidation experiment for the introductory organic laboratory. A. R. Hicks, B. L. Davis, W. M. Dill, T. E. Goodwin 1028. Examination of the enforced hydro phobic effect in Diels-Alder reactions: Cydopentadiene dimerization in hightemperature water. I. B. McQueen, L U. Gron 1029. Extraction of metal oxides using supercritical carbon dioxide. S. Postma, C. Phelps 1030. Green Baeyer-Villiger rearrange ments of benzophenone in water. M. Bracciano, J. Root, J. L. Tischler, A. R. Zand 1031. Green chemistry: Zirconium as a substitute for acid catalysis. B. Stanton, D. A. Allen, O. P. Priest 1032. Low-temperature synthesis of colloi dal Cd-based semiconductor nanocrystals and nucleation and growth mecha nism studies thereof. M. E. Gewin, X. Peng 1033. Solvent-free undergraduate organic laboratory experiments. M. J. Campbell, C.Read 1034. Study of the solvent effects on ionic liquids by the use of NMR techniques. H. Siehl, R. S. Adler, C. Freudenberger
1035. Synthesis of several ionic liquids and their use as replacement solvents in typical organic reactions. D. L. Astolfi, F. C. Mayville Jr. 1036. The ACS Student Affiliates chapter at the University of Puerto Rico, Rio Piedras campus has worked on a Commu nity Interaction Grant: Green chemistry essay contest. V. Rodriguez, I. Montes 1037. Toluene hydrogénation with nanocomposite-based heterogeneous catalysts. B. L Iversen, H. Lang, B. D. Chandler 1038. Total synthesis of a naturally occurring antioxidant under environmentally benign conditions. M. H. Kirkman SectionJ Undergraduate Research Poster Session: Polymer Chemistry Cosponsored with Society Committee on Education 2:00-4:00 1039. A preliminary study of selected silicon-containing surfactants in flexible pofyurethane foam production. C. M. Baldwin, J. R. Layton 1040. A study of the degradation of highperformance polyimide foams. D. B. Holland, J. J. Palou, M. K. Williams 1041. Analysis of ring-opening polymerization of L- and D,L-lactide using (Ti(IV)(trisphenolate)(isoproproxide)]2 as the catalyst. C. L Gamble, K. C. Hall, G. E. Hofmeister 1042. Control of an aggregate number of binary mixtures of amphiphilic diblock copolymer. S. M. Baker, B. Lehman 1043. Controlled-size macromoleculemagnetite complexes. J. D. Goff, K. Wilson, J. S. Riffle 1044. CopolymerizatJon of DEAEMA and methylmethacrylate to form antimicrobial surfaces. J. L Marples 1045. Design and synthesis of a macroindicator as a sensitive colorimetric sensor for incorporation into responsive polymeric coatings for surface decontamination. S. Butler, S. Brown, H. N. Gray 1046. Determining reactivity ratios of a silicone acrylate in various copolymer systems. C. M. Baldwin, H. L Thompson 1047. Effects of sodium polyacrylate soil amendment of lead bioaccumulation in Lolium multiftorum, Raphanus sativus, and Agancus blazei. K. Jewell, T. Poon 1048. Evaluation of biocompatibility of silica nanocapsules for drug detoxification application. R. Cuadrado, A. V. Jovanovic, R. S. Underhill, J. A. Flint, T. E. Morey, M. Vert, R. S. Duran 1049. Fabrication of polystyrene latex nanostructures by nanomanipulation and thermal processing. E. Harel, S. Meltzer, A. Requicha, M. E. Thompson, B. E. Koel 1050. Ion-conducting polymer electrolyte interactions. J. Gutshall, R. Freeh 1051. Mesogens with variable geometries: Calamitic and bent-shaped azo mesogens. G. P. Corradino, K. A. Amey, K. N. Wiegel 1052. Murtinudear copper and gadolinium complex syntheses in ethylammonium nitrate. A. M. Dawson, H. J. Eppley 1053. Polydimethylsilane homo and copolymers: Analysis of physical properties and investigation into usage as precursors to ceramic coatings. D. M. Gutowski, T. J. Cleij
1054. Protein-ligand interactions of liver fatty acid-binding protein: NMR studies. S. K. Pettit, X. Yang, H. Wang, R. Estephan, R. E. Stark 1055. Real-time and in-situ atomic force microscopy to quantify polymer biodégradation. B. M. Latuga, J. F. Arceo, S. Rowe, S. F. Baron, D. E. Dennis, Β. Η. Augustine 1056. Solvent-dependent hydrogen bonding in perfluoropolyethers. C. E. Spiese, P. Kasai 1057. Study of polymeric artificial muscles. A. R. Bueno, D. Teeters 1058. Surface behavior of polystyrenepolyethylene oxide) star block copoly mers at the air-water interface. P. Masse, J. Logan, R. S. Duran 1059. Synthesis of a 5,5'-linked biphenol polymer. A. Agrawal, Q. Hu 1060. Synthesis of new polymers with potential antibacterial properties. R. A. Moline 1061. Synthesis of styrene and n-butyl acrylate copolymers by atom transfer radical polymerization. J. Wang, W. T. Grubbs 1062. Synthesis of thiophene/perfluorophenyl-based conducting polymers. M. A. Oar, T. J. Marks, A. Facchetti 1063. Techniques for grafting monomers to environmentally friendly polymers. A. Sodhi, E. A. Nalley, M. Wilson 1064. Theoretical study of 2-furylindenylbased metallocene polymerization cata lysts. J. W. Sevier, K. N. Hogue, A. K. Perry 1065. Toward an IR-transparent polymer. E. Holland, J. Wiseman, K. Beifield, S. Elsheimer 1066. Unexpected effects of concentration on PS-PEO adsorption at the solid-liquid interface. L T. Vo, S. M. Baker Analytical Chemistry Workforce of the 21st Century Cosponsored with Division of Analytical Chemistry Encouraging Disadvantaged Students into Careers in the Chemical Sciences: Symposium in Honor of Isiah M. Warner Cosponsored with Division of Analytical Chemistry
MONDAY EVENING SectionA Convention Center Hall G Sci-Mix F. Torre, Organizer 8:00-10:00 51-53, 55-58, 60, 62, 64, 66, 70-71, 73, 76-77, 81, 84, 87-88, 91-92, 95, 97-98, 103,107-108,110,112,114,116, 126-127,129,133-134,137-138. See previous listings. Section Β Convention Center Hall G Successful Student Affiliates Chapter Posters Cosponsored with Society Committee on Education L. E. Garrison, Organizer 8:00-10:00 1067. Chem club celebrates National Chemistry Week. K. C. Tabanor, S. Gupta
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
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1068.150 Years of chemistry in western Pennsylvania. B. P. Toma, J. Rishel, J. E. Knickelbein 1069. A successful SAACS chapter in a rural two-year college. C. McCollum, J. K. Archer 1070. A successful SA chapter at the College of Saint Elizabeth, Morristown, NJ.G.S.Exy Louis 1071. A variety of activities builds a SAACS team. J. M. Robinson, B. J. Ballew, C. D. Helms, A. J. Smith, K. S. Sprawls 1072. SAACS at the University of St. Thomas, Houston, TX. D. D. Wuenschel, R. J. Oviedo, B. C. Pereira, S. Lakhani, N. Chhotani, T. Tran, T. B. Malloy Jr. 1073. SAACS chapter at Westminster College: Our successes and challenges. L Quintero, N. W. Poulsen, R. C. Welch 1074. Activities for the 2002-2003 SAACS chapter at the University of Puerto Rico, Rio Piedras campus. V. Rodriguez, I. Montes 1075. Activities of SAACS at the University of Central Oklahoma. M. Buckner, C. G. DiEnna, L. Montes, J. Bowen 1076. Activities of the Dairy University SA chapter. J. Thomas, M. Brown, C. Uecker, D. Vestal, B. Watts, S. A. Petrich 1077. Are you ready to rock? Another year of fun in professionalism with the Union College Chemistry Club. D. L Plata, R. W. Herbst, A. L. Payeur, R. L. Wolfe, J. E. Laubisch, J. M. lannacone, E. A. Lax, M. E. Hagerman, M. K. Carroll 1078. Barry University SA: Students reacting and helping "alkynes". E. Galindo, J. Shands, G. Fisher 1079. Bringing chemistry to the community at Texas A&M University. A. R. McMahon 1080. Building future scientists. S. Seelig, J. Butler, M. Rhodes, J. Alderson, R. Anderson-Lederer, R. R. Bravo, C. Guthrie, J. Pease, J. Romero, A. Ryan, H. Shook, S. Singh, R. Unruh, G. Vaughan, J. Youngren 1081. Cajun style chemistry. J. A. Broussard, A. Lacy, L. Stevison, C. D. Taylor, T. M. Tkach 1082. Catalyzing the aloha of chemistry. N. C. Venzon, J. Cheng, T. Fujii, T. Fujii, A. Davis 1083. Catawba College keeps it clean with the C4 lab. E. M. Keller, J. P. Sandman, D. S. Pinkston, S. M. Puotttatval, K. N. Fobbs, A. D. Helms, H. F. Bruce, L. B. Hartis, D. J. Shissler, S. M. Akers, A. L. Goshom, K. C. Prescott, A. R. Small, J. R. Hudgins, J. Beard, C. A. Miderski. M. S. Sabo 1084. Chembowl: Organizing, funding, and maintaining a year-round social activity. D. L Shem, T. A. Girtsman 1085. CHEMCAMP: A summer enrichment program for 4th, 5th, and 6th graders. C. S. Jones 1086. Chemicals between us. T. D. McGovern, E. Holland, P. Armstrong, H. Carias 1087. Chemistry activates reactions between our neighborhoods. B. S. Perez, F. R. Mansnerus, A. J. Mansnerus, M. D. Lovgren, R. E. Peterson, S. W. Griffin 1088. Chemistry and people: The activities of the Manhattan College/College of Mount Saint Vincent SAACS chapter. A. J. Cedrone, N. J. Palma, C. Hall, E. M. DeThomas 1089. Chemistry bubbles through the community. H. A. Darwiche, S. Patel, A. K. Wagner, C. V. Gauthier 1090. Chemistry circus. I. E. Ruiz, A. T. Awad, J. Camacho, D. J. E. Becvar 1091. Chemistry cleans up at Washington College! K. L Taylor, K. A. Swam, K. A. Koenig, J. L. Drummond 1092. Chemistry club of Saginaw Valley State University. J. Markey, R. P. Valliere, K. L. Keams Jr., D. R. Huntley
1093. Chemistry in the community. R. B. Friedman 1094. Chemistry makes cleaning possible: NCW 2002. F. Huertas, J. Suârez 1095. Chemistry on the prairie: Cultivating the seeds of science. R. L Gartner, A. Borgendale 1096. Chemistry outreach project by the Florida International University SAACS. M. L Campbell, P. J. Galarza, M. M. Payares-Olier, A. J. Castillo, A. Andreu, L. Labranche 1097. Chemistry: If s all about balance. T. Motley, J. H. MacNeii, T. J. Fenus, M. P. Kotlarczyk 1098. ChEmory: Emory University's SA chapter. N. A. Goodman, Q. A. Soltow, M. Ranchhod, J. Rienstra-Kiracofe 1099. Chi Epsilon Mu, an ACS affiliate chemistry club at Austin Peay State University. R. P. Robertson, T. Jensen, A. Deering 1100. Community involvment of the North Dakota State University SA chapter. M. K. Zimmerli, C. Boucher 1101. Community outreach and the environment: Central motivations for an active chapter. R. E. Marcotte, J. O. Besinaiz 1102. Community, children, and chemistry: The 3 C's of our success. C. Deer, E. Weiss-Deboer 1103. Connecting campus and chemistry. K. D. Wright, A. K. Gallagher, J. B. Easter 1104. Elementary and high school demonstrations: Promoting chemistry at a young age. C. G. Beeman, A.D.Schaerdel. B.N.Norris 1105. Emory and Henry College SA chapter. K. M. Gilmer, K. R. Fletcher 1106. Expanding the scope of chemical demonstrations: The Chemistry Club at the University of Southern Maine invites middle school and high school students to participate in scientific activities at USM. C. K. Prudente, D. Himing, S. Mayberry, S. Oravrtz, K. Coon, H. Stewart, J. Ford 1107. Expanding young horizons. W. S. Parsons, W. S. Schafer, J. B. Easter 1108. Fun at chemistry. L D. Cruz, R. Caban, I. Rosado 1109. Fund-raising for the North Dakota State University SA chapter. G. Sedo, E. M. Schoep, D. A. Hall 1110. Green chemistry and NCW give UTM SAACS outreach focus. R. Kirkpatrick, M. W. Fultz, S. K. Airee, S. Chris, E. L. Reeves 1111. How to keep your SAACS chapter active, organized, and well funded. J. M. Rose, K. E. Serfert, J. DeLuca, A. Bitar, L. C. Jenkins, S. H. Szczepankiewicz 1112. How to make chemistry grow! J. Adcox, C. Lubner 1113. Ideas that work: Happenings of Butler University's SA chapter. D. L Ronde, A. C. Smith, J. J. Esteb, M. J. Samide 1114. Involving the community of Ponce and Pontifical Catholic University in recycling. D. Garcia, L. Vega, M. Quinones 1115. Kids + Chemistry = Fun, Part 3. S. LaMont, D. T. Chase, S. Sprague, M. Cook, D. Thoreson, L. Knowles, C. Hartman, B. Wong, B. Eby, T. B. Piocher, T. E. Bitterwolf, N. R. Natale 1116. Lake Forest College SAACS CISA and IAG grant activities: Snoozeum and a measure of our success. M. J. Fisher, R. J. Bahde, A. W. Sienkiewicz, C. Regans, D. C. Wiser, E. W. Fischer 1117. Loyola College in Maryland Chemistry Club. P. L Vajda, A. E. Nichols, A. M. Hitchcock, B. N. Bûcher, K. G. Olsen
1118. Masks, beads, and fun with chemistry. K. Haskell, A. Minei, K. Charpentier, M. P. Johnson, B. Eklund, D. Placencia, L Styger, E. Bialecki, R. Warren, K. McGarry, C. Crutchfield, P. Krzyzewski, J. DiStefano, L Farber 1119. Millersville University of Pennsylvania SAACS. J. Boyer, J. A. lera, M. Nguyen 1120. Millikin University ACS: Exceeding expectations. S. E. Ray, M. H. Kirkman, J. L Evans, A. M. Rund 1121. Mole-king our way to great participation. M. L. Rowe, S. M. Kirby, J. B. Easter 1122. National Chemistry Week, ASU style. M. Draganjac, J. Lamb, J. Woodruff, C. Oliver 1123. National Chemistry Week: Hands-on activities presented by University of Southern Maine's Chemistry Club at the Children's Museum of Maine. C. K. Prudente, D. Hirning, S. Mayberry, S. Oravrtz, K. Coon, H. Stewart, J. Ford 1124. NCW 2002: SAACS and women in chemistry alliance at Georgia College & State University. R. A. Richards, C. P. Higginbotham, L. rvey, C. Bruce, M. B. McGinnis 1125. NCW: Catalyst for chapter revitalization. K. D. Holmes, K. L. Givens, B. G. Rackley, G. Pritchett 1126. Penn State's Nittany Chemical Society. K. J. Milks, H. D. Agnew, R. E. Bringman, K. A. Pratt, B. Aldinger, N. T. Hartman, T. Denkenberger, J. Mahoney, R. D. Minard 1127. Promoting chemistry through the Chemistry Club. J. P. Noehre, S. Sorenson, A. Pezeshk 1128. SAACS activities at the University of Colorado-Denver. B. Herbert, C. Jones, A. Crowell 1129. SAACS at Georgia Southern University: A chapter rebuilt. A. Stewart, Ο Μ. Davis 1130. SAACS at UAB: On campus and in the community. N. Thomas, E. Floyd, O. Janik, D. Chappell, A. Alban, H. Durham, S. Ellison 1131. Saint Louis University SA: Chemistry in the community. M. Kovarik, J. Nazzoli 1132. Saint Mary's Affiliates of the Ameri can Chemical Society, Notre Dame, IN. S. K. Kutz, E. A. Moran 1133. San Jose State University SAACS 2001-2002: A time of prosperity and service. J. McVay, C. Crower, S. W. Kiley, E. Horn, R. Terrill, P. E. Fleming, G. B. Dawson, P. Stacks 1134. Science Sundays: Bonding families with chemistry. M. K. Froemming, S. M. Brastad, J. J. Potaracke, M.LRiha, M.D.Schuder 1135. Shaping tomorrow's minds through chemistry. L C. Tracy, E. A. Lowman, S. M. Speck, M. M. Hussey 1136. SHU reacts with you! R. Lees, S. Gillenberger, S. Hileman, T. Harshberger 1137. Small chapter, small school, big success: The activities of the under graduate SA chapter at Tarieton State University. J. R. Andreatta, K. Nance, A. Whisenant, E. Otte, R. Oliver 1138. Southern Oregon University SA Chemistry Club. M. Lange, M. R. Maynor 1139. SSU Chemistry Club: The right catalyst for the job. L Lundbohn, A. Louwagie, J. H. Brown 1140. SA at Morehead State University, Morehead, KY. M. T. Blankenbuehler, J. W. Gullett, J. J. Gullett, B. P. Morgan 1141. SA working with the Vanderbilt com munity and beyond. M. J. Hangauer, C. Khosla
1142. Taking a chance with chemistry: MTSU SAACS activities in 2002. S. T. Decha-Umphai, C. K. Gren, M. J. Cochran, A. Oishi, D. E. Noga, C. R. Allison, R. W. Tilford, M. W. Hobkirk, B. J. Smith, G. D. White, A. C. Friedli 1143. Taking chemistry to our community's children. I. K. Renberg, E. R. Bland, C. M. Baldwin, R. F. Johnston 1144. Taking chemistry to the community. B. R. Rubanka, A. J. Zrinsky 1145. Texarkana College Chemistry Club activity poster. D. J. Dollison 1146. Texas Wesleyan University SAACS: Excellence through science, excellence through service. D. L. Elson, R. E. Rodriguez 1147. The University of Arizona Chemistry Club. D. K. Friel, D. Gross, M. Prior, E. Hazelwood, H. McLaughlin, C. Shannahan 1148. Towson University SA chapter Successful chapter activities. C. N. Boffen, S. R. Hanna, L. S. Alvano, G. Subah, J. W. Mays 1149. Undergraduate programming by SA at the Central Regional Meeting at Eastern Michigan University. M. E. Pratt, R. Beebe, C. Petrok, L. Scobie 1150. UPT-SAACS: Developing the interand intracommunity bonds through chapter activities. P. Furlan, K. Fesenmyer, J. Servey, S. Scott, V. Mayer, B. Parker, A. J. Terwilliger, K. Yi, A. Mattocks 1151. W&J SAACS: Ascending the scale of success. K. M. Ondecko, J. T. Bett, V. L. Mirkovich, E. L Uvengood
TUESDAY MORNING Section A Convention Center Room 218 Advances in Chemical Education Research: Symposium in Honor of George Bodner, 2003 George C. Plmentel Award Winner G. C. Weaver, Organizer 8:30 Introductory Remarks. 8:35 1152. Problem solving with George: Things learned along the way. A. J. Phelps 9:00 1153. Impact of the presentations and publications of George Bodner. M. H. Towns 9:25 1154. Chemical education research and cognitive psychology: Co-construct ing knowledge. M. W. Briggs, G. M. Bodner 9:50 1155. Chemistry students developing understanding of the nature of science. A. Samarapungavan, E. L. Westby 10:15 Intermission. 10:25 1156. Changing the curriculum may not be enough. J. N. Spencer 10:50 1157. Using supplemental instruc tion to improve minority success in gatekeeper science courses. D. L. Maclsaac, K. A. Falconer, C. A. Maglione, C. Maxka 11:15 1158. Developing and classroom testing instructional materials to help students understand chemical concepts: The influence of George Bodner on a chemical educator. T. J. Greenbowe 11:40 Concluding Remarks.
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-39
TECHNICAL PROGRAM SectionB Convention Center Room 219 The Cutting Edge: Use of Computers in Teaching and Learning Chemistry General Papers R. McCann, Presiding T. A. Schoolcraft and C. Muhoro, Organizers 8:30 Introductory Remarks. 8:35 1159. Can we learn to teach chemis try better from computer games? J. M. Grow 8:55 1160. Using Web-based instruction to teach critical thinking and writing skills in general and organic chemistry. C. E. Mewhinney 9:15 1161.24 Web-based, interactive excercises in interpretation of IR spectra with alternate approaches. J. G. Lindberg 9:35 1162. Is it important for undergradu ate students to be exposed to the cut ting edge of computational chemistry? J. B. Foresman 9:55 1163. A website as a visual aid in the undergraduate organic chemistry laboratory. D. A. Straus, B. Burfine, S. DeNardi, O. Rosito, L. Wang, G. Wrenn 10:15 Intermission. 10:25 1164. Putting it all together: Using a laptop-based wireless network to inte grate technology into both lecture and lab for general and organic chemistry. C. E. Mewhinney 10:45 1165. Student conceptions, miscon ceptions, and reconceptions: Using the WWW to evaluate and reconstruct student knowledge. Κ. Ε. Chambers, B. Blake 11:05 1166. Using the Mimio system to make chemistry lecture time more effec tive. A. C. Royer, K. Sanders, C. Salkeld 11:25 1167. Utilizing MeasureNet in large general chemistry laboratory programs. B. J. Stanton SectionC Convention Center Room 217 Research in Chemical Education Investigating Attitudes V. M. Williamson, Organizer,
Presiding
D. Mason, Organizer 8:30 Introductory Remarks. 8:35 1168. Mixed-mode guided inquiry chemistry laboratory: Changing the first-year experience. S. Nussbaum, J. Nakonechny, C. Lomas 9:00 1169. Evaluating attitudes in a stu dent-centered active learning environ ment. M. T. Oliver-Hoyo, D. Allen 9:25 1170. Gender differences in attituderelated variables among students with similar organic chemistry achievement. H. A. Lindsay, R. C. Turner 9:50 1171. Interviews with nontraditional students to explain their success and challenges. J. Vestal, P. B. Kelter 10:15 Intermission.
10:25 1172. Validation of chemistry selfconcept and attitude-toward-chemistry inventories. C. F. Bauer 10:50 1173. What makes chemistry difficult: The perspective of a female, preprofessional major. K. S. Lyle, W. R. Robinson 11:15 1174. Why should chemistry departments offer graduate courses for high school teachers? T. J. Jose, V. M. Williamson 11:40 1175. Images of scientists. D. L. Brode. V. M. Williamson Section D Convention Center Room 220 State of the Art in Environmental Chemistry Cosponsored with Division of Environmental Chemistry
2:20 1188. Eavesdropping on students as George taught me. M. P. Doherty 2:45 1189. Cheating in the chemistry classroom laboratory and suggestions on how to prevent it. D. I. Del Carlo, G. M. Bodner 3:10 1190. George, I have an argument for you. B. Blake 3:35 Intermission. 3:45 1191. The role of qualitative research methods in the search for an understanding of the factors that influ ence student performance in physical chemistry. F. B. Patron 4:10 1192. Student learning in quantum mechanics. D. Gardner, G. M. Bodner 4:35 1193. Photoelectron spectroscopy: Adding new topics to the general chem istry curriculum. W. J. F. Hunter 5:00 Concluding Remarks. SectionB
C. M. Lee and M. M. Cooper, Organizers, Presiding
Convention Center Room 219
A. Elzerman, Organizer
The Cutting Edge: Use of Computers in Teaching and Learning Chemistry Molecular Modeling and Computational Chemistry
Section D
A. H. Predecki, Presiding
ACS Award for Encouraging Women into Careers in the Chemical Sciences Honoring Madeleine Jacobs Cosponsored with Women Chemists Committee
8:10 1176. Environmental chemistry: Molecular vision, the world around us, and education. A. W. Elzerman 8:30 1177. Development of general chem istry laboratories with an environmental chemistry theme. M. M. Cooper, T. Bethea, S. Sewell 8:50 1178. Advanced laboratory exercises for environmental chemistry. F. M. Dunnivant 9:10 1179. Integrating analytical results in an aquatic chemistry course. J. P. Hassett, K. A. Lowe 9:30 1180. Incorporation of field-portable XRF into the environmental chemistry lab: A pilot study. S. J. Bachofer 9:50 Intermission. 10:00 1181. EnviroChemLibrary: How to put "state-of-the-art environmental chem istry" in the hands of your students. C. M. Lee, M. M. Cooper, A. W. Elzerman 10:20 1182. Multimedia tool for teaching chemistry based on a story of environ mental remediation technology develop ment. P. G. Tratnyek 10:40 1183. In situ transformation of deuterated toluene and xylene to benzylsuccinic acid analogs in BTEX-contaminated aquifers. J. A. Field, D. E. Reusser, H. R. Beller, J. D. Istok 11:00 1184. Catching pesticides "right"handed: Using enantiomers to determine pesticide sources. R. L. Falconer 11:20 1185. Current research in the atmospheric degradation of isoprene. T. S. Dibble 11:40 1186. Role of deciduous trees in the improvement of air quality. V. A. Jouraeva, D. L. Johnson, J. P. Hassett, D. J. Nowak Incorporating Chemical Safety into the Academic Curriculum: A Tribute to Jay Young Part I Cosponsored with Division of Chemical Health and Safety
TUESDAY AFTERNOON Section A
T. A. Schoolcraft and C. Muhoro, Organizers 1:30 1194. Cold fusion and SQL to dynamically display learning objects on the Internet. A. Kabi Satpathy 1:50 1195. Computers across the chemis try curriculum at Millersville University. L J. Anna, L. Rickard, M. lannone 2:10 1196. Applications of Spartan in the teaching of inorganic chemistry. T. Gardner 2:30 1197. Molecular modeling in the organic chemistry laboratory: Comparing the theoretical and experimental results of electrophilic addition to 4-fert-butyl-1methylcyclohexene. R. W. Morrison 2:50 Intermission. 3:00 1198. Visual regression. M.Kim, M. S. Kim 3:20 1199. Development of a computa tional materials science course at the University of Virginia: Initial progress and challenges. L V. Zhigilei 3:40 1200. Use of computer simulations and modeling software to support stu dent construction of mental models. J. P. Suits, M. Diack 4:00 1201. Enhancing computational capabilities in chemistry at UNCW. N. H. Martin 4:20 1202. Integrating molecular modeling into the general and organic chemistry curriculum. I. B. Nejad 4:40 Concluding Remarks. 5:00 Division Business Meeting. SectionC Convention Center Room 217
V. Barrett, Organizer,
Presiding
1:45 Introductory Remarks. 1:55 1211. Award Address (ACS Award for Encouraging Women into Careers in the Chemical Sciences, sponsored by Camille and Henry Dreyfus Foundation Inc). Opening the doors for women in chemistry: Why we need keys to the doors. M. Jacobs 2:15 1212. The door in the dream": The unfinished agenda. E. R. Wasserman 2:35 1213. Graduate education and early career choices of chemistry doctorates from top universities. V. J. Kuck, C. H. Marzabadi, J. P. Buckner, S. A. Nolan 2:55 1214. Opportunities for women chemists as faculty in research universi ties. R. Breslow 3:15 1215. Propping the door open: Mentoring the next generation of women academic leaders. M. A. Cavanaugh 3:35 1216. High expectations. J. K. Barton 3:55 1217. Strategies for success in industry. J. Spence 4:15 1218. The road to success: From academics to editing. S. N. Collins 4:35 Concluding Remarks. Incorporating Chemical Safety into the Academic Curriculum: A Tribute to Jay Young Part II Cosponsored with Division of Chemical Health and Safety
WEDNESDAY MORNING Section A
D. Mason, Organizer,
Convention Center Room 218
Presiding
Convention Center Room 218
V. M. Williamson, Organizer
Advances in Chemical Education Research: Symposium in Honor of George Bodner, 2003 George C. Pimentel Award Winner
1:30 Introductory Remarks. 1:35 1203. Informing practice through research: Examination of a high school chemistry poster session. J. L. Ball
1:30 Introductory Remarks. 1:35 1187. Award Address (George C. Pimentel Award in Chemical Education, sponsored by Dow Chemical Co). Twenty years of learning how to do research in chemical education. G. M. Bodner
Hilton Riverside Belle Chasse Room, 3rd Floor
Research in Chemical Education Learning Through Applied Chemistry
G. C. Weaver, Organizer
40-TECH
2:00 1204. Development of alternative discussion sections for introductory chemistry. K. Gilbreth, B. Blake 2:25 1205. Closing the loop in theorypractice learning. H. R. Patrick, M. M. Ali, B. B. Harmon, L. R. Parker 2:50 1206. Use of a demonstration labo ratory in teaching chemistry. E. McKee, V. M. Williamson, M. L. Peck 3:15 Intermission. 3:25 1207. Chemical communication as part and parcel of understanding chem istry. J. Bond-Robinson 3:50 1208. Understanding arrow-pushing formalism from the students' perspec tive. R. L. Ferguson, G. M. Bodner 4:15 1209. Synthesizing synthetic chem ists: How do students learn to solve organic synthesis problems? G. Bhattacharyya, G. M. Bodner 4:40 1210. Using spectral analysis to examine problem-solving ability among organic chemists. D. P. Cartrette, G. M. Bodner
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
Distance Learning in Chemistry D. R. Kimbrough, Organizer, Presiding 8:30 Introductory Remarks. 8:35 1219. Learning objects to customdesign chemistry courses. A. Kabi Satpathy 9:00 1220. Dual credit: An innovative model for teaching general chemistry. M. W. Ducey Jr., G. L. Zweerink, L. J. Archer 9:25 1221. Advanced-placement chemis try teacher development through an online course. M. L. Rodgers, M. Readnour
CHED/TECHNICAL PROGRAM
9:50 1222. Industrial scientist teaching courses by satellite and online-based distance learning at Lehigh University. F. J. Waller, M. Kercsmar-Portz 10:15 Intermission. 10:25 1223. Comparison of student per formance in equivalent distance learning and traditional chemistry courses. L. L. Munchausen, M. J. Robertson 10:50 1224. Distance learning general chemistry for science majors: Solving the laboratory dilemma. J. Reeves, D. Kimbrough, B. Heath 11:15 1225. Distance learning laboratories for nonscience majors: Assessment and dissemination. D. R. Kimbrough, J. Reeves, L. Walsh
11:15 1238. Facilitators and barriers to teacher implementation of molecular visualization. L M. Brown, V. M. Williamson, M. L. Peck 11:40 1239. Measurement of student attitude and understanding in the chem istry classroom: Investigation of the solubility of ionic compounds using molecular visualization. T. J. Jose. E. Restivo, V. M. Williamson
Convention Center Room 219
A. Russell. Organizer, Presiding
J. G. Stevens, Organizer 8:30 Introductory Remarks. 8:40 1226. Fifteen years of REU and its impact on undergraduate research. J. G. Stevens, R. Kuczkowski, Ν. Ε. Levinger 9:00 1227. Looking backward and forward in the development of a flourishing undergraduate research program at Western Washington University. M. E. Bussed 9:20 1228. Overview of the comprehen sive metropolitan university: Challenges and opportunities for developing a productive research program. J. Pesek 9:40 Intermission. 9:55 1229. Interdisciplinary research as a tool for career development. C. M. Friend, R. G. Graham, G. Tucci 10:15 1230. Research beyond the bubble: Rewards and perils of collaborating with industrial, government, and academic laboratories. T. W. Hanks 10:35 1231. The Science Initiative at the University of Richmond. J. T. Gupton 10:55 Panel Discussion. Ν. Ε. Levinger. 11:50 Concluding Remarks. Section C Convention Center Room 217
General Oral Papers Laboratory Experiences
Research in Chemical Education New Strategies To Improve Student Learning
K. R. Birdwhistell, Organizer,
1:00 Introductory Remarks. 1:05 1240. Teaching/research postdoc toral training as preparation for an aca demic career. N. Mills 1:25 1241. Striking a balance, the Dreyfus Scholar-Fellow Program as preparation for a career at a PUI. J. R. Vyvyan 1:45 1242. Choose a postdoc wisely: Pick something that sounds fun. J. E. Lewis 2:05 1243. Benefits of teaching during a research-focused postdoc. Κ. Τ. Kuwata 2:25 1244. Chemistry career paths inter sect with the UNH graduate programs for preparing future faculty. C. F. Bauer 2:45 Intermission. 2:55 1245. Doctor of Arts in chemistry at Middle Tennessee State University: A terminal degree for college teachers. A. J. Phelps, M. V. Stewart 3:15 1246. Peer leader training: A model for preparing future faculty. J. A. Kampmeier, L. T. Tien, V. Roth 3:35 1247. Doing what we do best (already): Broadening professional development for students seeking aca demic positions. B. P. Coppola. M. C. Frost. N. W. Ockwig 3:55 1248. Preparing future faculty for students at all levels of the education process: Studio 130. J. A. Blunt, R. D. Sweeder, J. M. Bartolin. A. C. Gottfried, B. P. Coppola. Μ. Μ. Banaszak Holl 4:15 1249. Integrating future faculty into the general chemistry program at UAB. J. L March, L. K. Krannich 4:35 1250. A look at the ACS Preparing Future Faculty Project. A. K. El-Ashmawy
D. Mason and V. M. Williamson, Organizers 1:30 Introductory Remarks. 1:35 1256. Investigating degree and quality of implementation of the NSF Systemic Curricular Reforms through the MID Project. D. M. Bunce, J. E. Lewis, D. L. Gabel, E. L. Lewis 2:00 1257. Investigation of demographic factors among chemistry faculty attend ing MID Project workshops. B. D. Barker, J. E. Lewis 2:25 1258. An evaluation of ChemConnections workshops. S. E. Lewis, J. E. Lewis 2:50 1259. Effects of preclass preparation and reading quizzes on student study and learning. M. A. Teichert, D. Luning-Prak 3:15 Intermission. 3:25 1260. Improving students' problemsolving strategies with cooperative grouping and the IMMEX system. E. L. Case, M. M. Cooper. T. Vendlinski. R. H. Stevens 3:50 1261. Impact of a learning commu nity environment on success in general chemistry. D. M. Hanson 4:15 1262. Studio 130: Evaluation. R. D. Sweeder, J. M. Bartolin, J. A. Hessler. A. C. Gottfried. B. P. Coppola. Μ. Μ. Banaszak Holl, W. J. McKeachie. J. R. Stewart
SectkxiC
Section A
Convention Center Room 217
Convention Center Room 218
Presiding
Research in Chemical Education Conceptual Understanding/Inquiry
Alternative Assignments: Assessment and Evaluation
D. Mason. Organizer, Presiding
D. Bautista, Organizer,
V. M. Williamson, Organizer
Presiding
D. Mason, Organizer 8:30 Introductory Remarks. 8:35 1232. Enhancing student discussion with an interactive student response system. C. R. Ward, J. Reeves, B. Heath 9:00 1233. Effect of computer-mediated collaboration on conceptual understand ing. B. A. Gaddis, D. R. Anderson, A. M. Schoffstall 9:25 1234. Identifying characteristics of successful online chemistry students. A. M. Schoffstall. B. A. Gaddis, D. R. Anderson 9:50 1235. Students' use of Web-based tutorial materials and understanding of chemistry concepts. W. J. Donovan, M. B. Nakhleh 10:15 Intermission. 10:25 1236. Comparison of achievement in the use of static, dynamic, and inter active visualization tools. J. Pasos, V. M. Williamson, M. L. Peck, K. C. Williamson III 10:50 1237. Use of video demonstrations and particulate animations in the chem istry classroom. A. Velazquez-Marcano, V. M. Williamson
SectonB Convention Center Room 219 New Models for Conducting Research at Undergraduate Institutions T. J. Wenzel, Presiding J. G. Stevens, Organizer 1:30 Introductory Remarks. 1:40 1251. Undergraduate research: How to do it, where are we going, and why did it become a dominant paradigm? T. R. Tritton 2:10 1252. Industrial and community partnerships as an alternative route to enhancing the campus research envi ronment. D. W. Husic 2:30 Intermission. 2:45 1253. Several irons in the fire. Ε. Μ. Spain 3:05 1254. Undergraduate research: The value to industry. C. Hollinsed 3:25 1255. Undergraduate research participation increases minority retention and success in chemistry. C. G. Gutierrez, L. M. Tunstad, A. Fratiello, S. L. Nickolaisen
Presiding
8:30 Introductory Remarks. 8:35 1272. Problem-based learning in a polymer chemistry laboratory. J. Bonilla-Rios. J. A. ValenciaGallegos 8:55 1273. Teaching students a manage able first approach to infrared interpreta tion. J. G. Llndberg, H. A. Trujillo, T. A. Mobley 9:15 1274. Benefits of a project-based general chemistry laboratory course at the University of the Virgin Islands. J. Carroll, R. Isovitsch, F. Rinehart, M. Whitten 9:35 1275. Pyrolysis GC/MS experimenta tion for the undergraduate analytical instrumentation laboratory. R. D. Redfeam, B. D. Pendley, D. J. Lemme, E. C. Mathews, J. K. Roberts 9:55 Intermission. 10:05 1276. Unknown cobalt complexes: An inquiry-based inorganic lab. K. R. Birdwhistell. T. G. Spence 10:25 1277. NMR kinetics of the SN2 mechanism of the Finkelstein reaction: Teaching kinetics in the organic labora tory. T. A. Mobley. H. A. Trujillo. J. G. Undberg 10:45 1278. Using proton FT-NMR to determine the fat and water content of diet margarines: An undergraduate experiment. M. J. Collins 11:05 1279. General chemistry: A wholly laboratory-based course. J. I. Selco, J. L. Roberts. D. B. Wacks. J. H. Acquaye. J. A. Bartz. T. L. Longin. D. P. Schrum
THURSDAY MORNING
A. Parrill-Baker, Organizer
Research in Chemical Education New Technologies That Aid Learning V. M. Williamson, Organizer,
Convention Center Room 217
Section A
Preparing Future Faculty
S. M. Baker, Presiding
Convention Center Room 219
J. E. Lewis, Presiding
Convention Center Room 218
SecfonB
Section C
WEDNESDAY AFTERNOON
Section Β
Best Practices in Undergraduate Research
3:45 Panel Discussion. R. L. Uchter. 4:40 Concluding Remarks.
8:30 Introductory Remarks. 8:35 1263. Humorous exams as an alter native assessment tool in teaching general chemistry. V. A. Jouraeva 8:55 1264. Improving learning through clicking. D. R. Anderson, B. A. Gaddis, A. M. Schoffstall 9:15 1265. Two biochemistry writing assignments: The biochemistry of drugs and disease. D. Dean, C. J. McMahon 9:35 1266. Posters, presentations, and proposals for the young and the old. K. J. Donaghy 9:55 Intermission. 10:05 1267. Using lab report grading rubrics with Calibrated Peer Review. J. P. Hagen III, L. Volaric 10:25 1268. Using progressive template assistance to improve scientific writing. L. Volaric. L. A. Benkowski. T. L. Austell 10:45 1269. Beyond the analysis. Η. Μ. Boylan 11:05 1270. Seeing is believing: Design ing undergraduate organic laboratory experiments to incorporate new science and all the senses. N. L. Pohl 11:25 1271. Inquiry-based laboratory manuals. V. M. Williamson
8:30 Introductory Remarks. 8:35 1280. Common sense chemistry: The root of misconceptions. V. Talanquer 9:00 1281. Assessment of the impact chemistry text and figures have on visually impaired students' learning. P. M. Mayo, G. Bodner 9:25 1282. What they don't know and why: Improving the teaching of chemis try through misconceptions. A. J. Phelps 9:50 1283. Is that like the fundamental laws of nature? Graduate students' conceptions of the nature of science. A. F. Johnson, G. Bhattacharyya, G. M. Bodner 10:15 Intermission. 10:25 1284. Remediating students' par ticulate nature of matter misconceptions in middle school, high school, and col lege. E. J. Yezierski. J. P. Birk 10:50 1285. Who's teaching your kids? Improving conceptual understanding of elementary education majors. L. S. Miller, M. B. Nakhleh
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECKM1
TECHNICAL PROGRAM 11:15 1286. Evaluating the effectiveness of implementing inquiry and the science writing heuristic in the general chemistry laboratory: Teaching assistants and students. K. A. Burke, J. Poock, D. Cantonwine, T. J. Greenbowe, Β. Μ. Hand 11:40 1287. Effectiveness of guided inquiry learning. R. S. Moog, J. N. Spencer, A. Straumanis
THURSDAY AFTERNOON Section A Convention Center Room 218 General Oral Papers T. G. Spence, Presiding K. R. Birdwhistell, Organizer 1:00 Introductory Remarks. 1:05 1288. Interpretation for the chemical reaction and catalysis in textbooks for the XXI century http://www.itchem.com. Y. Gankin, V. Gankin 1:25 1289. Three-center, four-electron bond in hexacoordinated AB6-type main group molecules: An alternative model of bonding without d-orbital participation in the central atom. X. Sun 1:45 1290. Development and use of case studies in the instruction of physical chemistry. M. D. Pacheco 2:05 1291. Predicting students atriskin general chemistry: A risky endeavor. S. C. Bhatia, D. H. Hylton 2:25 Intermission. 2:35 1292. Integrating the general chem istry and organic chemistry curricula: A structural presentation of relative acidi ties and basicities. R. W. Morrison 2:55 1293. Interpretation for chemical bonding in textbooks for the XXI century http://www.itchem.com. Y. Gankin, V. Gankin 3:15 1294. Introducing Monte Carlo simulations using Mathcad. T. G. Spence, L. E. Sass Section Β
SUNDAY MORNING Section A
SectionA
Convention Center Room 275
Convention Center Room 275
SectionC
Chemical Information Literacy: Is It Affordable? Cosponsored with Division of Chemical Education
Last Wave? Reference Books Go Digital
Convention Center Room 217
E. Kajosalo, Organizer K. Porter and E. Kajosalo, Organizers
General Oral Papers W. F. Walkenhorst, Presiding K. R. Birdwhistle, Organizer 1:00 Introductory Remarks. 1:05 1302. Preparing chemistry GTAs. R. A. B. Rodriques, J. B. Robinson 1:25 1303. Three suggestions for improved student understanding of solubility and precipitation reactions. B. Blake 1:45 1304. Simulating chromatographic separations in the classroom. C. A. Smith, W. Villaescusa 2:05 1305. Undergraduate research at two-year colleges: Is it doable? M. M. Bader 2:25 Intermission. 2:35 1306. Biotechnology education at Houston Community College SystemNortheast College. C. K. Mrttal, J. K. Galiotos 2:55 1307. Overcoming challenges of integrating molecular biology/genomics research into the environmental engi neering classroom: A case study. D. B. Oerther 3:15 1308. Using Lewis dot structure vacancies for compounds beyond the octet. R. J. Schroeder
DIVISION OF CHEMICAL INFORMATION O. F. Giiner, Program Chair
General Oral Papers
OTHER SYMPOSA OF INTEREST:
M. A. Tarr, Presiding
Nuoi unties vnMenge· si
K. R. Birdwhistell, Organizer
Biotechnology Sec/etefet Wed)
1:00 Introductory Remarks. 1:20 1295. NSF GK-12 fellows at SMSU: The role of the fellows. C. Wood, T. S. Jahnke, B. E. Breyfogle, G. Saunders 1:40 1296. NSF GK-12 fellows at SMSU: Building bridges. T. S. Jahnke, B. E. Breyfogle, G. Saunders 2:00 1297. Chemistry outreach to second ary schools with a mobile chemistry laboratory. G. L Long, Β. Β. Bunn 2:20 1298. Bringing polymer science to the 9-12 classroom. T. J. Smith, L. J. Mathias 2:40 Intermission. 2:55 1299. Organic chemistry for younger students. D. A. Heller, J. Hutchinson
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SUNDAY AFTERNOON
Section Β
SectionA
Convention Center Room 276
Convention Center Room 275 Librarian Watch: Introduction to New Hot Areas in Chemistry Cosponsored with Division of Chemical Education
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1:30 Introductory Remarks. 1:35 7. Green chemistry: Sustaining a high-technology civilization. T. J. Collins 2:20 8. Biological engineering: From blue roses to space suits. C. Craig 2:50 9. Nano nonet: Nine things chemistry librarians need to know about nanoscience. F. B. Culp 3:20 10. Chemoinformatics, cheminformatics, chemical informatics: What is it? G.D. Wiggins, W.Shreve 3:50 11. Combinatorial materials research: Opportunities, challenges, and successes. L A. Harmon Section Β
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HHBuavsig Movanca· w\ nfonrancs and M—surements (see DMsion of Anatytical Chemistry, Jhu) ACS Award for Computers in CherntcsJ and PitSfitiecsutfcsJ n e — r c h (see DMsion of Computes in Chemistry, Tue) Hit» to Lead: Selecting for PrugWw Properties (see DMsion of MedktasJ Chemistry, Wed) SOCIAL EVENTS: Luncheon: Tue Πβιβμϋοιι. Sun
8:30 Introductory Remarks. 8:35 1. The ACS Committee on Profes sional Training's Library Survey: Is there a future for modem chemical information as a central component of education in chemistry? J. E. Pemberton 9:05 2. Evolving doors of access to ACS Web Editions. D.J.Smith 9:35 3. Serving academia: Adapting to the needs of scientific students and faculty. C.Stephens 10:05 4. Affordable tools for teaching undergraduates at small institutions and community colleges. P. Kirkwood 10:35 5. How much is enough? CPT Guidelines and chemical information access in research universities. D. Flaxbart 11:05 6. Chemical information and chemi cal informatics literacy at a research university. G. D. Wiggins
8:25 Introductory Remarks. 8:30 18. Chemical handbooks: Glorious past, questionable future. F. B. Culp 9:00 19. CRC Handbook of Chemistry and Physics: From paper to web. F. Macdonald, D. R. Ude 9:30 20. The next 100 years: The evolu tion of The Merck Index toward a fully electronic publication. I. Schreiman, B. Solomon, J. Brecher, A. Smith 10:00 21. Science of Synthesis/HoubenWeyt Conversion of a major reference work in organic synthetic chemistry (print) into an interactive, highly acces sible electronic product. M. F. Shortt de Hernandez 10:30 22. The knovelized e-reference. R. R. Brand 11:00 23. Building a virtual reference collection in chemistry. P. Kirkwood 11:30 24. The next step at major refer ence works. C. Pick, P. Loew, J. Eiblmaier, H. Kraut
K. Porter and E. Kajosalo, Organizers
Convention Center Room 219
42-TECH
MONDAY MORNING
3:15 1300. Using science olympiad in the preparation of preservice chemistry teachers. Β. Ε. Breyfogle 3:35 1301. Summer outreach program for high school students and teachers. M. A. Tarr, C. J. O'Connor, I. De Leon
Convention Center Room 276 Knowledge Discovery and Scientific Numerical Databases J. Rumble Jr., Organizer 1:30 12. Recent developments in OpenURL (SFX) linking at the University of Chicago. A. B. Twiss-Brooks 2:00 13. Preserving data: The role of databases in future scientific discovery. J. Rumble Jr. 2:30 14. Knowledge discovery in a data base of biochemical pathways. J. Gasteiger, M. Reitz, O. Sacher 3:00 15. Dynamic data evaluation: Algo rithm development and analysis for thermodynamic properties of pure organic compounds. V. V. Diky, R. D. Chirico, X. Yan, R. C. Wilhoit. M. Frenkel 3:30 16. A self-organizing algorithm for extracting the intrinsic dimensionality of large high-dimensional data. D. Agrafiotis. H. Xu 4:00 17. From gene to lead: An architec ture for cooperative drug discovery. S. A. Baum, S. Varma
Informatics Challenges in Toxicology and Environmental Cosponsored with Division of Environmental Chemistry, and Division of Chemical Toxicology S. Lee, Organizer 8:30 25. Capitalizing on the value in in vitro hepatotoxicity data. P. R. N. Wolohan, R. D. Clark 9:00 26. Computational models for pre dicting chemical toxicity. J. E. Penzotti, G. A. Landrum 9:30 27. Facing database mining chal lenges in ecotoxicity. J. R. Chretien, M. Pintore, N. Piciin, F. Ros, E. Benfenati 10:00 28. In silico methodologies for predictive evaluation of toxicity based on integration of databases. C. Yang, A. Richard 10:30 29. Mining molecular fragments with MoFa: Finding relevant substruc tures in sets of molecules. M. R. Berthold, H. Hofer, C. Borgelt MONDAY AFTERNOON SectionA Convention Center Room 275 Current Status of XML in Chemistry Cosponsored with CSA Trust B. A. Vickery, Organizer 1:30 30. Compressed Chemical Markup Language for compact storage and inventory applications. M. Karthikeyan, D. Uzagare, S. Krishnan
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
CHED/CINF/TECH/TECHNICAL PROGRAM
2:00 31. New chemical information inter change standards based on CML: A submission for the Object Management Group. M. A. Miller, S. S. Market, J. C. Esteva, W. L. Sharp 2:30 32. Novel applications of XML in chemistry. P. Murray-Rust, H. S. Rzepa 3:00 33. The family of XML languages in chemistry. H. S. Rzepa, P. Murray-Rust 3:30 Intermission. 4:30 Open Meeting. Committees on Publi cations and on Chemical Abstracts Services. MONDAY EVENING Section A Convention Center Hall G Sci-Mix Cheminformatlcs Posters O. F. Guner, Organizer 8:00-10:00 4,12,23. See previous listings. 77. See subsequent listings. 34. Web-based tools for cheminformatics and drug design. M. C. NickJaus, W. Ihlenfeldt, J. H. Vokjt. F. Oellien 35. Marked photoconductivity enhancement of poly(2,5-dialkoxy-p-phenylene vinylene)-perylene derivative composites film upon annealing. W. Feng Sr., H. Yu, Y. U, A. Fujii, K. Yoshino 36. Quantitative structure-activity relation ship study of histone deacetylase inhibi tors. A. Xie, C. Liao, B. U, Z. U, Z. Ning, W. Hu, X. Lu, J. Zhou, L Shi 37. Ultrafast optical Kerr effect of poly{thiophene-2,5diyl[(2-carboxy-4-A/,/Vdimethylamino) azobenzylidene]}(ptcmaabe). W. Feng Sr., W. Yi, H. Yu, H. Wu 38. Use of Barnard and Daylight finger prints in ligand-based virtual screening. S. K. Yeap, M. Snarey, C. Federico
TUESDAY MORNING Section A Convention Center Room 275 Patent Searching for Nonexperts A. H. Berks, Organizer 8:30 Introductory Remarks. 8:35 39. Patent fundamentals for nonex perts. E. S. Simmons 9:05 40. Patent information resources for nonexperts. A. H. Berks 9:55 41. Patent term, expiries, and exten sions. S. R. Adams 10:25 42. Patentability, infringement, or validity: What kind of search? B. A. Hurwitz 10:55 43. Demystifying the patent-search process. R. K. Ward, B. J. Ikeler 11:25 44. Patents sell, but who's search ing? The rise of the nonexpert in the patent-searching arena. K. Hancox, G.Cross
TUESDAY AFTERNOON Section A Convention Center Room 275 Michael O'Hara Memorial Symposium Cosponsored with PIUG, ACS Committee on Patents and Related Matters, and Division of Chemistry and the Law A. H. Berks, Organizer 1:00 Introductory Remarks. 1:10 45. History of the DARC system. J. Dubois
2:00 46. Substance handling at Chemical Abstracts Service. W. Fisanick 2:25 47. Creating the MARPAT file: Prac tical and philosophical issues in patent analysis and database building. D. E. Connolly 2:50 48. Back for the future 2: Cool codes, marvelous Markush, and hot interfaces. G. Cross, K. Hancox 3:15 49. Tips and tricks for searching MMS. S. Burcham 3:40 50. Marketing chemical information in a research organization. D. S. Saari 4:05 51. Protys: A full-text English index of new Japanese patents. A. Engel 4:30 52. Postprocessing of merged Markush service results. J. M. Terlizzi
3:45 66. Iterative experiment design. S. G. Schlosser. A. J. Vayda, E. J. Eriandson, M. Bricker, R. Gillespie, J. W. A. SachtJer 4:15 67. Machine-learning models for high-throughput materials discovery. G. A. Landrum, J. E. Penzotti 4:45 68. Computer-aided discovery of compounds with combined mechanism of pharmacological action in large chemical databases. A. A. Lagunln, O. A. Gomazkov, D. A. Filimonov, N. I. Solovyeva, V. V. Poroikov Informatics Challenges in Pharmacogenomics Cosponsored with Biotechnology Secretariat
SOCIAL EVENTS: 2003 Technician of the Yew Award Dinner: Tue Dinner: Sun
WEDNESDAY MORNING
THURSDAY MORNING
hiiliiMilrial IÏBIIIIIIIHI Ε*±**Λ*****Α»Ε*±. -,
Section A
Section A
Convention Center Room 275
Convention Center Room 275
Combinatorial Chemistry and Laboratory Automation Cosponsored with Division of Laboratory Automation
The Scientific Article in the Digital World: Where Are We and Where Should We Be Going?
MONDAY MORNING
D. A. Evans, Organizer
D. P. Martinsen, Organizer,
Section A
8:00 53. A life preserver for the data flood. G. A. Landrum, E. Evensen, J. E. Penzotti, S. Putta 8:30 54. AIMS: Array information man agement system. D. S. Hartsough 9:00 55. DirectedDrversity(r) informatics: A status report. V. S. Lobanov, D. K. Agrafiotis 9:30 56. ASPECT: A lims system for characterization of combinatorial librar ies. B. Deneau 10:00 57. GeminiChemistry: Automating rapid analog synthesis. J. B. Brohan, R. Fortin 10:30 58. High-throughput chromato graphic method selection and structure verification. M. McBrien, E. Kolovanov 11:00 59. REACTOR: Software system for reagent selection, analysis, and inventory management. D. A. Gschwend 11:30 60. ChemoinformatJcs tools for combinatorial chemistry. M. Karthikeyan, S. Krishnan, D. Uzagare
8:30 69. Citation linking: How important is it? S. Fedunok 9:00 70. Global submission and validation of experimental thermodynamic data using Guided Data Capture software: Benefits to authors, journals, and data users. R. D. Chirico. V. V. Diky, R. C. Wilhoit, M. Frenkel 9:30 71. Concept of metadata in scientific publications and the way from data to information. H. Bogel 10:00 72. Now that even/thing can be published, should we really publish everything? A. W. Czarnik 10:30 73. Chemistry journals: How I want to read in 2012. S. M. Bachrach 11:00 74. Some stumbling blocks on the road to publishing chemistry on the web. D. P. Martinsen, L R. Garson, J. E. Yurvati
Social HOUR Sun
Presiding
Intellectual Property Law Series Part IV: An Interactive Look at Obtaining U.S. Patents—Preparing the Patent Application Cosponsored with Division of Chemistry and the Law
THURSDAY AFTERNOON Section A Section A
High-Throughput Experimentation Cosponsored with Division of Industrial and Engineering Chemistry
Convention Center Room 275 General Papers O. F. Guner, Organizer
L. A. Harmon, Organizer 1:00 Introductory Remarks. 1:05 61. Combinatorial informatic systems at the NIST Combinatorial Methods Center. C. H. Davis, W. Zhang, A. Karim, E. J. Amis, M. J. Fasolka 1:35 62. Data-management system for catalyst discovery via combinatorial techniques. G. Fitzgerald, J. Hill, G. Lowenhauser, J. Tucker, M. J. Doyle 2:05 63. Data storage and evaluation tools for high-throughput experimenta tion applied to heterogeneous catalysis. W. Strehlau 2:35 64. Rational design: An alternative to the combinatorial explosion. F. Gilardoni, A. Graham, B. McKay, B. Brown 3:05 Intermission. 3:15 65. Increasing the efficiency of high-throughput experimentation by use of experimental design and data-analy sis techniques. A. L Ohrenberg, A. Schuppert
I. Henson, Program Chair
nKNJSnrai rWfnmrn VfWflSmmMm Mon
WEDNESDAY AFTERNOON
Convention Center Room 275
DIVISION OF CHEMICAL TECHNICIANS
2:00 75. Nanoworid in chemical abstracts. F. S. Sirovski, N. Krukovskaya, V. Efremenkova 2:30 76. Building an Internet chemistry business. S. G. Hutton 3:00 77. Tools of Research" course for chemistry graduate students. P. Muisener, Κ. Μ. Whitley 3:30 78. Classification of mass spectra using fuzzy logic inference engine. J. R. Scott, T. R. McJunkin, P. L. Tremblay Intellectual Property Law Series Part IV: An Interactive Look at Obtaining U.S. Patents—From Application to Patent: The Examination Process Cosponsored with Division of Chemistry and the Law
BUSINESS MEETINGS: Sun, Mon, Wed
Convention Center HaJIH/l-1 Be All That You Can Be .. as a Technician in Industry! J. Engelman, Organizer 9:30
MONDAY EVENING Section A Convention Center Hall G Sci-Mix General Poster Session M. Miller, Organizer 8:00-10:00 1. Withdrawn. 2. Atomic absorption spectroscopy cap stone scenarios for chemical laboratory technology education. M. All III, K. M. Perry, Κ. Ε. North, V. Reese-Guseva, S. A. Jackson, J. K. Galiotos 3. Business ventures between industries and chemical laboratory technology programs: The incorporation of gas chromatography in the industrial analysis of gasoline by chemical laboratory technology students. M. Ali III, J. A. Baca, R. L. Pointer, T. H. Hamvatan, J. K. Galiotos 4. Contextual laboratory curriculum for chemical technology. J. Braun, C. L. White 5. Equipment and process development for fabricating plutonium primary analytical chemistry standards. G. Coriz, J. D. Olivas 6. Industrial process plant applied science education for chemical laboratory and process technicians I: Feedback control of oil flow. J. K. Galiotos, B. Nguyen 7. Infrared spectroscopy forensic identifica tions of plastics by chemical laboratory technology students. M. All III, K. L. Burrell, D. E. Turner, Β. Υ. Brown, J. K. Galiotos 8. Solvent free: Water-based polyurethane dispersion. M. A. Chartier
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-43
TECHNICAL PROGRAM 9. Synthesis and performance of nanoscale tungsten oxides in metastable intermo lecular composite materials. B. L Smith, W. L Perry, C. J. Bulian, J. R. Busse, Κ. C. Ott, R. C. Dye, S. F. Son 10. The benefits and sacrifices of working a rotating shift schedule. E. T. Gradney, A A Atkinson 11. What is a TAG? D. M. Butterfleld, A. M. Lanzafame, M. J. Witkiewitz
DIVISION OF CHEMISTRY AND THE LAW W. R. Johnson, Program Chair
MONDAY AFTERNOON
TUESDAY MORNING
Section A
Section A
Convention Center Room 299
Convention Center Room 299
The Chemistry and Law of Driving-While-Intoxicated Prosecution Part II Cosponsored with Division of Analytical Chemistry
Brownfields: A Paradigm Shift for Environmentally Impacted Asset Management Cosponsored with Division of Environmental Chemistry, and Division of Small Chemical Businesses
TUESDAY MORNING Ε. Β. Overton, Presiding
SectjonA Convention Center Room 341
SOCIAL EVENTS: Executive Board Matting (Open to AI): Sun
The Lawyers are in: Meet Members of CHAL K. Colton, Organizer
Section Β
10:00 Introductory Remarks.. 10:10 Preview of CHAL technical program/ Discussion. 1. Withdrawn.
Convention Center Hall H/l-1
Recaption: Mon, Tue S. Bloxom, Organizer
SUNDAY MORNING
8:00 12. Changing players in a successful alliance: From program to pilot plant to open doors! J. M. Sabourin, R. L. Good 8:20 13. A rose by any other name: The advisory committee as an alliance. K. P. Hunter 8:40 14. ACS/CTPAS approval: The importance of a strong alliance. E. Fisher, S. Stevenson 9:00 15. Alliances between college and industry: Local and regional. G. D. Hicks 9:20 16. Alliances today for the jobs of tomorrow. J. Kile 9:40 Intermission. 9:50 17. Bidwell Training Center and successful partnerships. M. A. Blanken, Y. Rhodes, M. Kriss 10:10 18. Local pollution prevention group focuses on microscale chemistry in high school laboratories. W. Tallmadge, M. M. Homan 10:30 19. Sharing a cab: The American Chemistry Council-American Chemical Society Presidential Task Force, 2002. W. F. Carroll 10:50 20. Supporting the development and enhancement of successful alli ances: ChemTechLinks. S. Stevenson, D. E. Jones
SectkxiA
Section A Convention Center Room 341 General Papers M. Miller, Organizer, Presiding 9:00 21. Contextual laboratory curriculum for chemical technology: Phase III. C. L White. J. Braun, R. Madyun 9:20 22. High-throughput research: An evolving capability within The Dow Chemical Co. R. Krystosek 9:40 23. New curriculum and materials for training chemical laboratory technicians. J. Kenkel 10:00 24. Training innovations: Inexpen sive simulation-based training. M. Ansari, J. K. Galiotos 10:20 25. The benefits and sacrifices of working a rotating shift schedule. A. A. Atkinson, Ε. Τ. Gradney
Convention Center Room 299
Intellectual Property Issues for the Industrial Workplace
SUNDAY AFTERNOON K. Colton, Presiding
9:00 27. Brownfields primer. T. Hackenberg 9:30 28. Brownfields redevelopment: A regulatory perspective. R. Gingles 10:00 Intermission. 10:15 29. The liability transfer mechanism as a catalyst for Brownfields redevelop ment. J. M. Redwlne 10:45 30. Insurance archeology tools for Brownfields redevelopment. N. Champagne 11:15 31. Use of environmental insurance policies in Brownfields redevelopment. P. McCoy
TUESDAY AFTERNOON SectionA Convention Center Room 299
SectkxiA Convention Center Room 299
2:00 14. Intellectual property issues for the industrial workplace. K. Colton Section C
Intellectual Property Law Series Part I: Your Lawyer and You
Convention Center Hall H/l-1
H. D. Hart III, Organizer 1:30 2. Our patent lawyer called and wants me to help with a due-diligence investigation. S. F. Sherry 2:05 3. Our patent lawyer called and wants me to help collect records of prior work for a patent interference. M. B. Hariin 2:40 4. Our patent lawyer called and wants me to help decide where to file foreign patents. R. W. Fleseler 3:15 5. Our patent lawyer called and wants me to help evaluate a competi tor's product to determine whether it infringes our patent. H. D. Hart III 3:50 Question and Answer Session. MONDAY MORNING Section A Convention Center Room 299 The Chemistry and Law of Driving-While-Intoxicated Prosecution Part I Cosponsored with Division of Analytical Chemistry J. C. Carver and Ε. Β. Overton, Organizers 9:00 6. Analytical considerations for analysis of gaseous samples for trace organic compounds including breath volatiles such as ethanol. Ε. Β. Overton, N. Roques, K. R. Carney 9:45 7. Overview of concerns. C. M. Childers 10:30 Intermission. 10:45 8. Physiology of breath test for alcohol. J. McGartty 11:30 9. Testing protocols for alcohol analysis used by law-enforcement agen cies. S. T. Chustz Biotechnology in the Service of Health Cosponsored with Division of Small Chemical Businesses
44-TECH
J. C. Carver, Organizer 1:30 10. Dosing of volunteers. S. T. Chustz, J. C. Carver 1:45 11. The role of the prosecutor in alcohol-related criminal trials. B. J. Brock 2:00 12. Defending DWI cases. J. P. Calmes Jr. 2:20 Intermission. 2:40 13. Introduction to mock trial. J. C. Carver, B. J. Brock, J. P. Calmes Jr. 2:50 Mock trial.
Successful Alliances
WEDNESDAY MORNING
T. Hackenberg, Presiding J. C. Carver, Organizer
Surviving Corporate Investigations and Reclaiming Industrial Property E. J. Berns, Organizer 3:30 15. Surviving corporate investiga tions. E. J. Berns 4:30 16. Reclamation of contaminated industrial property. T. Hackenberg Biotechnology in the Service of Health Cosponsored with Division of Small Chemical Businesses MONDAY EVENING Section A Convention Center Hall G Sci-Mix H. M. Peters and J. C. Carver, Organizers 8:00-10:00 10. See previous listings. 17. ACS's highest award: The Priestley Medal. H. M. Peters 18. Corporation Associates Award for creative invention. S. B. Radding 19. Corporation Associates Award for Team Innovation. C. Meyer 20. Alfred Nobel and the Nobel Prize in Chemistry. J. F. Riley 21. Norbert Rillieux: Sugar chemist. H. M. Peters 22. Death by chocolate: A brief history of chocolate. H. M. Peters 23. Dr. George Washington Carver Peanut products, U.S. Patents 1.522,176; 1,541,478; and 1,632,365. H. M. Peters 24. Inventure place. A. M. Ehrllch 25. National Inventors Hall of Fame (www.invent.org). H. M. Peters 26. National Medal of Technology and National Medal of Science. B. L Lences
Intellectual Property Law Series Part II: The Spectrum of Intellectual Property Cosponsored with Louisana State Bar Association-Intellectual Property Law Section M. Esman, Organizer, Presiding 12:30 Introductory Remarks. 12:35 32. Digital Millenium Copyright Act: Disseminating research in the digital age. M. Esman 1:25 33. Trade secrets: A legal primer and practical pointers. M. Breaux 2:15 Intermission. 2:25 34. The ABC's of patent prosecution. R. L. Waddell 3:15 35. The second patent examina tion—Patent infringement litigation: Perspectives on enforcement and defense. J. Lizarraga 4:05 Intermission. 4:15 36. Think globally, advise locally: Avoid loss of client IP rights. M. E. Andrews Michael O'Hara Memorial Symposium Cosponsored with PIUG, ACS Committee on Patents and Related Matters, and Division of Chemical Information WEDNESDAY MORNING SectionA Convention Center Room 299 Intellectual Property Law Series Part III: The Wide World of Intellectual Property—Getting Worldwide Value for Your Innovation W. R. Johnson, Organizer 9:30 Introductory Remarks.
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
TECH/CHAL/COLL/TECHNICAL PROGRAM
9:40 37. Innovation is nothing without protection: How to gain the European protection that you need. D. Brown 10:10 38. A German perspective on protecting your invention in Europe. G. Leissler-Gerstl 10:40 39. A Canadian perspective on protecting your intellectual property. G. N. Manning 11:10 40. Protecting your invention: A perspective from the U.S. J. G. Actorman
WEDNESDAY AFTERNOON SectionA Convention Center Room 299 Careers in Chemistry and the Law Cosponsored with Younger Chemists Committee
Section Β
DIVISION OF COLLOID AND SURFACE CHEMISTRY R. Nagarajan, Program Chair
OTHER SYMPOSIA OF NTEREST: Planus Technology end Catalysis (see Catalysis & Surface Science Secretariat Mon. Tue, Wed) Advances In rrotuln roldlnti, Aggregation, ana Moonicsnon (see Division of Biochemical Technology, Sun)
B. L. Lences, Presiding 1:30 41. From chemist to lawyer, or how I decided what I wanted to do when I finally grew up. A. M. Ehrlich 2:00 42. Chemist become litigator Toxic tort and other trials. J. C. Carver 2:30 43. Patent agent man—From chemistry to law: What could be stranger? D.W.Ladner 3:00 44. A career in food and drug law. D.Robertson 3:30 45. Chemistry and the law in académie: A technology transfer perspective. V. L McDevrtt 4:00 46. An exquisite integration: Science and the law. K. Cotton
THURSDAY MORNING SectionA Convention Center Room 299 Intellectual Property Law Series Part IV: An Interactive Look at Obtaining U.S. Patents—Preparing the Patent Application Cosponsored with Division of Chemical Information B. C. Meadows, Organizer 9:30 47. Introduction to an interactive role-playing panel discussion including an inventor and an attorney. B. C. Meadows 9:35 Panel Discussion. Preparing an invention disclosure. 10:05 Panel Discussion. Preexamination search. 10:35 Panel Discussion. Application preparation. 11:05 Question and Answer Session.
THURSDAY AFTERNOON
Computational Nanotschnotony (BOO Division of Computers in Chemistry, Sun, Mon) MuM^ple Lsngtii and Tims Scats· In MQwctRar Mooswig (see UNrston or Computers In Chemistry, Sun)
Intellectual Property Law Series Part IV: An Interactive Look at Obtaining U.S. Patents—From Application to Patent: The Examination Process Cosponsored with Division of Chemical Information B. C. Meadows, Organizer 1:00 48. Introduction to an interactive role-playing panel discussion including an "Examiner" and a "Patent Attorney". B.C. Meadows 1:05 Panel Discussion. The examination process. 1:35 Panel Discussion. Interviewing examiners. 2:05 Question and Answer Session.
Nanoscale Imaging of Biological Systems DNA and Cells
Nanofiaredee (see DMsion of Physical Chommty. Sun, Mon, Tus, W e i Thu)
J. W. Schneider and J. Green, Organizers
Pojyuisr Orushsss ftoni ^n^iselsto Ftincliorial MkxostiudUMNi (see DMsion cf Polymer Chem&ry, Tua, Wed, Thu)
of Polymer Chemistry, Sun, Mon) Pofyrosr Surfacss end Werlaoee(see DMsion of Polymeric Materials: Science antfByrwer*TftTue,Wecl,Thu) β^ΜΜ^Λ^^^Λ
fu^MMfii^wfa^tMt
Mill
AppfeatioflofMiallDrtaeeand Composas Matsrtala (see DMsion of Polymeric Materials: Science and Engineering, Sun, Mon> SOCIAL EVENTS: DMston Luncheon: Toe Opstt Buslnsis Mseflrae Mon Uoctof itTMirjToslsr ilssslnn" Mrm
AOTSMOI!» IfanSflQn, ΟΠΟ IWUUWI
Fonnstlon (see DMskmof Environmental Chemistry, Sun, Mon)
SUNDAY MORNING SectionA
&tffaeAaAAAdi^Mf Pin i#i yhiMwhml Propsssesln EnvfeoiMiMtitsJ Chemistry (see Division of Environmental Chemistry, Tue, Wed) Advanoss m MiMDfifMMt for energy and Fwf Appftoattons (ww QMufcn of Fuel Chemistry, Tue, Wed, Thu) Envtronmsntal Catalysis by Metal Sulfides, Carbides, and M o i d * · lor UHraclean Fuels (see DMskm of Fuel Chemistry, Sun, Mon) I m i u n t βΛ M m nn « t i n t * fUnmitl» mntt
«npact or fmnopejnxm m w w i i anq TrSTiSforfMllOft ProOSSSSSOn Contanwuini QsoctMNtMcsi Cycling (see Division of Geochemistry, Thu) Μ Λ 1 Α Μ Ι ( Μ Ι AiwtBnMllnMM jif
Nanomatsriali and NaiKrtaohnotogy wanoiscnnoiogy wsicsvisionj (see Division of InAtstriai and Engineering Cftemfe&y,Wed,Thu) Qenei al Papers In Advanced i ^ y ^ i ^ ^ «lui ΜΜΜΜ^^ΜΊ4ΜΜΙΙ^ΜΜ#
ftp oniofed by Advanced Materials & Nanotachnotogy Subdhriaton) (see Division of trxkistriai and Engineering Chemmy,Sm) NanoscsJé Ssrtsfcig Tecftnotogy: Why and Howx (spotMKirsd by Advanced Materials A NaiK)tschnoiogy 8ubdiwsipijf (see Division of Industrial and Engineering Chemistry, Mon)
Convention Center Room 289
Synthesli; Spectroscopy,
MotatôsiHLevai Aspects of;Bicteriai
SectionA Convention Center Room 299
8s#Aisefnb1y(8ee DMsion ofOrganic, Chemfewy,lhu)
Convention Center Room 288 ACS Award in Colloid and Surface Chemistry Symposium Honoring Clay Radke Interfacial Phenomena in Microstructured Fluids A. R. Kovscek, A. Chauhan, H. Wong, and V. Bergeron, Organizers 8:30 1. Novel surfactant mixtures. E. W. Kaler, G. Frtiz, B. Baser 8:50 2. Structural studies of lamellar/ inverse hexagonal and lamellar/cubic phase transitions of palmitoyl-oleoylphosphatidylethanolamine. A. Hickel, M. Rappott, F. Bringezu, K. Lohner 9:10 3. Block copolymers in supercritical carbon dioxide: Predictive calculations of micellization. R. Nagarajan 9:30 4. Study for mixed surfactant micelles, using analytical ultracentrifuge. P. Somasundaran, R. Zhang 9:50 5. Surfactant gel phases: Metastable states with long relaxation times. G.J.T.TWdy 10:10 6. Reproducing microemulsion phase behavior with the net-average curvature model. J. H. Harwell, E. Acosta, E. Szekeres, D. A. Sabatini 10:30 7. Engineering the synthesis of molecular networks. A. McCormick 10:50 8. Extended test-particle method for predicting the inter- and intramolecular correlation functions of polymeric fluids. J. Wu, Y. Yu 11:10 9. Modeling of second-generation derivatives: Ideal and nonideal inter faces. E. S. Reiner
8:30 10. Scanning probe microscopy of biomolecular systems and pharmaceuti cal materials: The fate of DNA-dendrimer complexes exposed to degrada tion enzymes. C. J. Roberts, M. C. Davies, S. Allen, P. M. Williams. S. J. Tendler 9:00 11. Engineering fractalkine-targeted drug-delivery systems through biomimetic surface science. R. Kasinskas, E. Kokkoli 9:30 12. Real-time observation of HIV-1 nudeocapsid protein-induced TAR DNA melting at the single-molecule level. G. Cosa, E. J. Harbron, D. B. O'Connor, K. Musier-Forsyth, P. F. Barbara 9:50 13. Surface biology by atomic force microscopy and molecular pulling. H. G. Hansma, R. Golan, E. Mateescu, R. Steinberger, P. A. Holden, E. Oroudjev 10:20 14. Templates for guided assembly. A. Ivanisevic, H. Hernandez, M. Yu, N. Dorjderem 10:40 15. DNA compaction by yeast mitochondrial packing protein ABF2. R. W. Friddle, R. J. Baskin, A. Noy 11:00 16. Molecular mechanisms of organization in the neuronal cytoskeleton. S. Kumar, R. Mukhopadhyay, M. E. Paulaitis, J. H. Hoh 11:30 17. Nuclear envelope: A biological nanoarray of nuclear pores imaged by atomic force microscopy. H.Oberlerthner Section C Convention Center Room 290 Adsorption of Macromolecules at Liquid-Solid Interfaces Surface Modification with Dendrimers W. Chen, Organizer, Presiding K. Queeney, Organizer 8:30 Introductory Remarks. 8:35 18. Chemically sensitive dendrimermodified high-surface-area SAW sen sors for the detection of volatile organic compounds. G. P. Perez, R. M. Crooks, W. G. Yelton, R. W. Cemosek, R. J. Simonson 9:05 19. Modifying the adsorption of PAMAM dendrimers by end-group deriviatization for use as nanoscale diffusion probes. K. S. McCain, P. Schluesche, J. M. Harris 9:35 Intermission. 9:45 20. Novel dendrimer-like and star architectures of polyethylene oxide)fctocfr-polystyrene copolymers as mono layers at the air/water interface. J. Logan, P. Masse, A. Skolnik, R. Francis, S. Angot, D. Taton, Y. Gnanou, R. S. Duran
waiiufswaioiogy ano we E^nvtronrnsrit (see Division of Industrial end Einghooring QhomJstry, Sun, Mon, Tue, Wed, Thu) iuynmsui or raaiopafDcis· ami Nanostructured Matériau (see Division of Inorganic Chemistry, Sun, Mon, Tue, Wed, Thu)
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECKM5
TECHNICAL PROGRAM 10:05 21. Mobility and adsorption geom etry of carbosilane dendrons containing up to 81 SiCI3 groups on mica. C. Cai, Z. Xiao, A. Mayeux, C. M. Yam, X. Deng 10:25 22. Adsorption behavior of PS(PBd)2 and PS(PBd)3 miktoarm star copolymers with zwitterionic group, using quartz crystal microbalance. M. Park, G. Sakellariou, S. Pispas, Ν. Hadjichnstidis, R. Advincula Section D Convention Center Room 291 Molecular Tribology From Crystalline to Bloinspired Lubrication S. C. Street and S. H. Kim, Organizers 8:30 23. Surface chemistry of chlorineand sulfur-containing extreme-pressure lubricant additives. W. T. Tysoe 9:00 24. Surface chemistry of metal carbides with lubricant analogs. H. I. Kim, P. Frantz, S. V. Didziulis 9:20 25. Chemical modification influence on the frictional properties of small model lubricant molecules adsorbed on VC(100). L C. Fernandez-Torres, X. Zhao, B. Kim, S. S. Perry 9:40 26. Direct observation of the tribochemical restructuring of mica surfaces on the atomic scale. J. D. Batteas, J. M. Helt 10:00 27. Friction anisotropy at crystalline interfaces. A. J. Gellman, C. Mancinelli 10:20 28. Atomic friction and wear on ionic crystals. E. Gnecco, R. Bennewitz, T. Gyalog, E. Meyer 10:40 Intermission. 10:50 29. Bioinspired aqueous lubrication schemes probed on the macro level. N. D. Spencer, M. Muller, S. Lee 11:20 30. Bioinspired aqueous lubrication schemes probed on the molecular level. S. S. Perry, X. Yan Section Ε Convention Center Room 292 Surface Chemistry on Carbonaceous Materials Properties of Diamond and Amorphous Carbon Materials A. V. Teplyakov and T. P. Beebe Jr., Organizers 8:30 Introductory Remarks. 8:35 31. Electrically conducting diamond: An advanced material for electrochemi cal technologies. G. M. Swain 9:35 32. Reactive adsorption on the diamond(IOO) surface. J. N. Russell Jr., M. P. Schwartz, D. E. Barlow, J. E. Butler, M. P. D'Evelyn, R. J. Hamers 10:00 Intermission. 10:20 33. Investigation of plasma ion immersion implantation (PHI) deposited tetrahedral amorphous carbon (ta-C) films by XPS and Raman spectroscopy. D. H. C. Chua, W. I. Milne, T. Carney, R. G. White, D. Sheeja, Β. Κ. Tay
Molecular-Level Aspects of Bacterial Adhesion, Transport, and Biofilm Formation Cosponsored with AEESP. and Division of Environmental Chemistry
4:10 49. Static and dynamic AFM studies of β-amyloid aggregates and processes leading to their formation. T. Kowalewski, J. Legleiter 4:40 50. Interplay between β-amyloid (1-40) and a peptide-based β-amyloid aggregation inhibitor. J. P. Aucoin, M. A. Etienne, R. P. Hammer, M. L. McLaughlin, P. S. Russo, R. L. McCariey 5:00 51. X-ray and neutron scattering from model membranes with β-amyloid peptides. C. Ege, J. Majewski, G. Wu, K. Kjaer, S. K. Satija, K. Y. C. Lee
SUNDAY AFTERNOON
Section C
Section A
Convention Center Room 290
10:45 34. Covalently bonded adducts of biomolecules with diamond thin films: Synthesis, biochemical properties, and bioelectronic characterization. W. Yang, O. Auciello, J. E. Butler, W. Cai, J. A. Carlisle, J. Gerbi, D. M. Gruen, T. Knickerbocker, T. L. Lasseter, J. N. Russell Jr., L. M. Smith, R. J. Hamers
Convention Center Room 288 ACS Award in Colloid and Surface Chemistry Symposium Honoring Clay Radke Interfacial Phenomena in Biological and Biomedical Systems
T. J. McCarthy, Presiding K. Queeney and W. Chen, Organizers
A. R. Kovscek, A. Chauhan, H. Wong, and V. Bergeron, Organizers 2:00 35. Probing the mechanisms of the electrophoretic separation of DNA. H. W. Blanch, S. M. Ferrée 2:20 36. Effect of physical modification on the interfacial properties of whey proteins. G. Narsimhan 2:40 37. Influence of protein on the spontaneous curvature and self-assembly of surfactant monolayers in oil/water systems. S. R. Dungan, J. W. Shimek, C. M. Rohloff 3:00 38. Protein aggregation and adsorption at the oil/water interface: Role of interaction energies in 3-D-lattice dynamic MC simulations. K. O. Leonhard, J. M. Prausnitz, C. J. Radke 3:20 39. Effect of solvation on biological processes. B. L Trout, J. Chu, Β. Baynes 3:40 40. Evaporative dehydration from soft contact lenses during wear. F. Fornasiero Jr., J. M. Prausnitz, C. J. Radke 4:00 41. A novel ophthalmic drug delivery vehicle: Dispersion of nanoparticles in soft contact lens. D. Gulsen, A. Chauhan 4:20 42. New silicone hydrogel contact lens materials for extended wear. C. McKenney, J. McNally 4:40 43. Tear exchange under soft con tact lenses: An interdisciplinary approach to clinical problem solving. K. A. Poise, M. C. Un, Κ. Miller, C. J. Radke
2:00 52. Structure and dynamics in poly electrolyte multilayer films. G. Decher 2:30 53. Motivating with multilayers: Functional surfaces from polyelectrolyte thin films. J. B. Schlenoff 3:00 54. Fabrication of fluorescence nanosensors by a layer-by-layer adsorp tion of polyelectrolytes on gold nanopar ticles. N. T. K. Thanh, Z. Rosenzweig 3:20 55. Ambipolar organic field effect transistor behavior of water-soluble phthalocyanines fabricated using the layer-by-layer deposition technique. J. Locklin, K. Onishi, K. Shinbo, Z. Bao, R. Advincula 3:40 Intermission. 3:50 56. Discontinuous swelling transi tions, molecular memory, and pH-gated nanoporosity in polyelectrolyte multilay ers. M. Rubner 4:20 57. Surface modification with poly electrolyte multilayers: A protein adsorp tion control. D. S. Salloum, J. B. Schlenoff 4:40 58. Coating with pH-responsive polyelectrolyte multilayers for the control of surface charge in capillary electro phoresis. Z. Sui, J. B. Schlenoff 5:00 59. Controllable response of poly electrolyte multilayers. S. A. Sukhishvili SectionD Convention Center Room 291 Molecular Tribology Theory and Experiment
Section Β S. C. Street and S. H. Kim, Organizers Convention Center Room 289 Nanoscale Imaging of Biological Systems Proteins J. W. Schneider and J. Green, Organizers 2:00 44. Biomolecular self-assembly at interfaces: Investigations by scanning probe microscopy. C. M. Yip 2:30 45. Growth of insulin crystals fol lowed by atomic force microscopy at high resolution. I. Reviakine, P. Vekilov 2:50 46. Protein-mediated bacterial adhe sion as monitored by atomic force microscopy. A. Razatos, R. Kou, L. Palmer, J. Schwartz 3:20 47. Nonspecific interactions between human serum albumin and poly(ethylene oxide) via high-resolution force spectros copy. M. A. Rixman, D. Dean, C. Macias, C. Ortiz 3:50 48. Protein aggregates responsible for interfacial gelation. D. K. Schwartz, G. Bantchev
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Adsorption of Macromolecules at Liquid-Solid Interfaces Polyelectrolyte Adsorption
2:00 60. Molecular dynamics investiga tions of the atomic-scale friction and wear at hydrocarbon interfaces. J. A. Harrison, G. M. Chateauneuf, G. Gao, P. T. Mikulski 2:30 61. Friction of aromatic monolayers: Comparison between measurements with AFM and SFA. M. Ruths, N. Alcantar, J. Israelachvili 2:50 62. In situ vibrational spectroscopy of thin organic films confined at the solid/ solid interface. S. A. Haydock, C. D. Bain 3:10 Intermission. 3:20 63. Scaling issue in nanofriction measurement. S. Hsu 3:50 64. Measuring the size-dependent mechanical properties of nanostructures, using atomic force microscopy. W. J. Price, G. Uu, P. Kuo 4:10 65. QCM-STM studies of the nano scale dynamics of "model system" and "real-world" lubricants. M. Abdelmaksoud, J. Bender, J. Krim 4:30 66. Adhesion in elastic-plastic spheri cal microcontact. L Kogut, I. Etsion
SectionE Convention Center Room 292 Surface Chemistry on Carbonaceous Materials Chemistry and Properties of Carbon Nanotubes A. V. Teplyakov and T. P. Beebe Jr., Organizers 2:00 67. Surface chemistry of singlewalled carbon nanotubes. J. T. Yates Jr., A. Kuznetsova, D. B. Mawhinney, 0 . Byl. P. Kondratyuk, S. FitzGerald, S. Forth, L Chen, J. K. Johnson 3:00 68. Chemical force microscopy of single-walled carbon nanotubes. L. A. Bottomley, M. A. Poggi, P. T. Lillehei 3:25 Intermission. 3:40 69. Spinning carbon nanotube fibers. P. Poulin, S. Badaire, C. Zakri, M. Maugey, P. Launois 4:40 70. Biologically modified carbon nanotubes: Synthesis, biochemical binding, and nanoscale assembly. R. J. Hamers, S. Baker, T. Lasseter SectionF Convention Center Room 298 Electrochemistry and Surface Science Symposium in Memory of Mike Weaver Vibrational Analysis: IR, Raman, SFG E. Borguet, Presiding B. A. Parkinson, Organizer,
Presiding
A. Wieckowski, J. L. Stickney, and J. T. Hupp, Organizers 2:00 Introductory Remarks. 2:05 71. Michael J. Weaver remembered. F. C. Anson, A. Wieckowski 2:25 72. Use of sum frequency generation vibrational spectroscopy to monitor the structure of adsorbates with changing electrode potential. G. A. Somorjai, K. Chou 2:45 73. Nanoparticle optics: Surfaceenhanced spectroscopy. C. L. Haynes, R. P. Van Duyne 3:05 74. Strategies for probing pathways in the electrochemical oxidation of methanol and related small molecules at nanometer-scale metal catalysts. C. Korzeniewski, G. Vijayaraghavan, W. Zhou, L. Gao, P. Inkaew 3:25 75. UV resonance Raman studies of protein structure and dynamics. S. A. Asher 3:45 76. In situ vibrational spectroscopic investigation of solid/liquid catalytic interfaces. R. J. LeBlanc, 1. Ortiz-Hernandez, M. R. Strunk, C. T. Williams 4:05 Intermission. 4:15 77. Methanol electro-oxidation on platinum studied by surface-enhanced infrared spectroscopy. M. Osawa, A. Miki, Y. X. Chen, H. Sakai, S. Ye 4:35 78. New applications of overlayer surface-enhanced Raman spectroscopy. S.Zou 4:55 79. Extending SERS study to transi tion-metal electrode and nanoparticle surfaces. Z. Tian, B. Ren, Z. Yang, J. Hu, J. Hu, S. Sun
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
COLL/TECHNICAL PROGRAM
5:15 80. Electrochemical infrared charac terization of CO domains on rutheniumdecorated platinum nanoparticles. S. Park, P. K. Babu, A. Wleckowski, M. J. Weaver Molecular-Level Aspects of Bacterial Adhesion, Transport, and Biofilm Formation Cosponsored with AEESP, and Division of Environmental Chemistry
11:00 96. Second harmonic generation as a structural probe of biological systems. G. J. Simpson 11:30 97. Measuring the dynamic behav ior of biomolecules with neutron scatter ing. A. M. Pivovar, S. Takata Section C Convention Center Room 290
MONDAY MORNING Section A Convention Center Room 288 ACS Award in Colloid and Surface Chemistry Symposium Honoring Clay Radke Interfacial Phenomena on Fluid/Fluid Interfaces A. R. Kovscek, A. Chauhan, H. Wong, and V. Bergeron, Organizers 8:30 81. Dilatation rheology of surfactant adsorption layers. R. Miller, J. Kragel, V. B. Fainerman, V. I. Kovalchuk 8:50 82. Interfacial rheology of silicone polyether copolymers at an oil/water interface. R. M. Hill, J. Anseth, G. G. Fuller 9:10 83. Interfacial rheology of 2-D sus pensions. E. Stancik, J. Vermant, G. G. Fuller 9:30 84. Surface tension measurements of lung surfactant under physiologically relevant conditions. A. W. Neumann 9:50 85. Dynamics of surfactant sorption at fluid/fluid interfaces by continuous flow tensiometry. T. F. Svttova, C. J. Radke 10:10 86. Defining the constitutive behav ior of interfacially adsorbed polypeptides. D. B. Jones, A. P. J. Middelberg 10:30 87. Theory and experiment on dynamic tension relaxations for surfac tant adsorption to an initially clean air/water interface from micellar solu tions. C. Maldarelli, A. Couzis, P. Somasundaran, Q. Song 10:50 88. Direct probing and mechanisms of adsorption of lipids, soaps, and pro teins at air/water interfaces. E. I. Franses, X. Wen, Ε. Μ. Hernandez, Y. Liao, S. J. McClellan, T. Phang, A. J. Prosser, A. Pinazo 11:10 89. Effect of adsorption time scales on interfacial dynamics. R. Y. Ofoli 11:30 90. Rates of solubilization of pure and mixed oils in solutions of nonionic surfactants. A. Pefia, J. C. Lim, C. A. Miller Section Β Convention Center Room 289 Nanoscale Imaging of Biological Systems Instrumentation J. W. Schneider and J . Green, Organizers 8:30 91. 3-D thermal noise imaging with the photonic force microscope. E. Florin 9:00 92. Nano- and micromechanical spectroscopy of cytoskeletal and extra cellular matrix polymers. E. M. Furst, B. S. Chae 9:30 93. Combinatorial approaches to force measurements. J. Green, S. Chan, A. Idowu, A. Musgrove, R. Zheng 10:00 94. Positioning and imaging of proteins on surfaces using scanning probe lithography. G. Uu, N. A. Amro, V. Komanicky, G. Yang 10:30 95. Imaging single biomolecules with carbon nanotube probes. J. H. Hafner
Adsorption of Macromolecules at Liquid-Solid Interfaces Attachment and Adsorption of Biomolecules K. Queeney, Organizer, Presiding W. Chen, Organizer 8:30 98. SPR imaging measurements of DNA, peptide, and protein microarrays. R. M. Com, H. J. Lee, G. J. Wegner, T. T. Goodrich, E. A. Smith 9:00 99. Sequence-dependent effects on surface-immobilized DNA probe-target interactions: A model oligomer study. R. M. Georgiadis, L. K. Wolf 9:30 100. Effect of immobilized probe density on DNA hybridization onto solid supports. M. G. Bajaj, P. E. Laibinis 9:50 101. Covalent attachment of DNA to surfaces. C. W. Thomas, A. V. Saprigin, C. H. Patterson, C. S. Dulcey, M. S. Spector 10:10 102. Water reorganization upon protein biofouling. P. Cremer 10:40 103. Tuning dynamics of adsorbed macromolecules for biofunction and recognition. M. M. Santore 11:10 104. Adsorption of bacterial cells at liquid/solid surfaces mediated by cell surface macromolecules. T. A. Camesano, N. I. Abu-Lail 11:40 105. Fibronectin adsorption and cell adhesion to self-assembled monolayers of tri(ethylene glycol)- and methyl-termi nated alkanethiols. J. R. Capadona, D. M. Collard, A. J. Garcia 12:00 106. Topology and surface func tional groups manipulated in preformed plastics: Eppendorf tubes modified for protein binding. A. Taralp, D. Demirgoz, M. Kolodzie, H. T. Vakos, W. Voelter Section D Convention Center Room 291 Molecular Tribology Complex Interfaces S. C. Street and S. H. Kim, Organizers 8:30 107. Adhesion and friction mecha nisms of polymer-on-polymer surfaces. N. Maeda, N. Chen, M. V. Tirrell, J. Israelachvili 9:00 108. Synthesis and tribological behavior of nanocomposite polymer layers. V. Tsukruk 9:30 109. Physical and mechanical char acterization of dendrimer-metal nanocomposites. M. Curry, F. T. Xu, J. A. Barnard, S. C. Street 9:50 Intermission. 10:00 110. Shearing molecularty thin lubricant films at high speeds. C. M. Mate, P. C. Amett. Q. Dai. B. E. Knigge, F. C. Lee, O. J. Ruiz, R. J. Waltman 10:30 111. Lubricant molecules patterning on magnetic hard disks. J. Zhang, Z. Guo, R. Ji, T. C. Chong
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
12:00 579. Electrical and electronic prop erties of chemically modified silicon surfaces. N. S. Lewis, D. J. Michalak, J. A. Haber, W. J. Royea, L. J. Webb
10:50 112. Atomic force microscopebased analysis of monolayer failure under the influence of tribological stress ing, surface temperature, and electro static force. J. J. Nainaparampil, K. C. Eapen, J. S. Zabinski 11:10 113. Effects of applied load and sliding velocity on thermal gradients and energy dissipation at the interface of sliding hydroxylated α-alumina surfaces. W. L Hase, H. Xie 11:30 114. Frictional rate and temperature dependence in lubricated nanocontacts. S. E. Sills, R. M. Ovemey
Molecular-Level Aspects of Bacterial Adhesion, Transport, and Biofilm Formation Cosponsored with AEESP, and Division of Environmental Chemistry
Section Ε
Convention Center Room 288
Convention Center Room 292
MONDAY AFTERNOON SectionA
Surface Chemistry on Carbonaceous Materials Particles and Clusters
ACS Award in Colloid and Surface Chemistry Symposium Honoring Clay Radke Interfacial Phenomena on Fluid/Solid Interfaces
A. V. Teplyakov and T. P. Beebe Jr., Organizers
A. R. Kovscek, A. Chauhan, H. Wong, and V. Bergeron, Organizers
8:30 115. Chemical reactions of S0 2 with carbon clusters. A. J. Leavitt, W. T. Wallace, R. B. Wyrwas Jr., M. G. Arredondo, D. L. Doby, R. L. Whetten 8:55 116. Formation of nanocarbon par ticles in combustion systems. A. Violi, A. F. Sarofim, G. A. Voth 9:20 117. Nonlinear optical studies of the N0 2 hydrolysis reaction on brown soot. A. B. Voges, J. A. Methipara, F.M.Geiger 9:45 Intermission. 10:05 118. Structural features of magnetic activated carbons and their significance in adsorption processes. G. A. Munoz, S. Duyvesteyn, J. D. Miller 10:30 119. Cyclic voltammetry and in situ AFM behavior of heteropolyanions containing copper. T. Hernandez-Perez, S. Hoiguin, A. Moreno, M. Rivera 10:55 120. Role of surface chemical and topological heterogeneity on adsorption on carbonaceous surfaces. E. Borguet, S. Kwon, R. Vidic
2:00 128. Surface mobility of atoms and molecules is the key ingredient of their chemical acitivty. G. A. Somorjai, K. Hwang 2:20 129. Adsorption of amphiphiles at interfaces between thermotropic liquid crystals and aqueous phases. N. Abbott, J. Brake 2:40 130. Coupled reflectometer/streaming potential apparatus to study polyelectrolyte-surfactant adsorption onto solid surfaces. O. Theodoly, C. J. Radke, V. Bergeron, T. F. Svitova, R. C. Crooks 3:00 131. Adsorption of fibronectin onto polyelectrolyte multilayers. P. R. Van Tassel, A. P. Ngankam 3:20 132. Regimes of adsorbed polyelec trolyte dynamics governed by segmental binding. M. M. Santore 3:40 133. Effect of aqueous alkylpyridium surfactants on the interfacial behavior of quartz. D. W. Fuerstenau, R. Jia 4:00 134. Fabrication of surfaces with nanoislands of chemical functionality by controlling the phase behavior of selfassembling surfactants. A. Couzis, C. Maldarelli, N. Kumar, F. Fan
SectkxiF Convention Center Room 298
Section Β
Electrochemistry and Surface Science Symposium in Memory of Mike Weaver Fuel Cells and Small-Particle Reactivity
Convention Center Room 289
J. Leddy, Presiding
Nanoscale Imaging of Biological Systems Biomembranes
J. L. Stickney, Organizer,
Presiding
A. Wieckowski, J. T. Hupp, and B. A. Parkinson, Organizers 8:30 121. Elucidating the electrocatalytjc oxidation of CO over bimetallic surfaces. M. Neurock, S. K. Desai, J. Filhol 9:00 122. A theory-guided design of catalysts for fuel cell applications. Y. Ishikawa 9:30 123. Structure and activity of Ptbased fuel cell catalysts: Investigations of simple mixtures. C. Roth, D. Zimmermann, N. Martz, H. Fuess 10:00 124. Reactivity of ethanol on plati num and platinum-rhodium bimetallic electrodes. F. Nart, J. F. Gomes, J. P. I. Souza, K. Bergamaski 10:30 Intermission. 10:40 125. Mechanism of dioxygen reduc tion on metal monolayer modified elec trode surfaces. A. A. Gewirth, I. Oh, X.U 11:10 126. Self-organized patterns during bulk CO electro-oxidation on Pt. A. Bonnefont, H. Varela, K. Krischer 11:40 127. Pt and other transition metals as catalysts for electrodes of the solid oxide fuel cell. J. Wan, J. B. Goodenough
J. W. Schneider and J. Green, Organizers 2:00 135. Use of polymers to promote membrane fusion at the molecular level. T. L Kuhl, S. A. Safran, J. N. Israelachvili 2:30 136. Self-assembly of polymerizable peptide-amphiphiles. H. Bianco-Peled, R. Biton, R. Tu, Y. Talmon, M. Tirrell 2:50 137. Nonequilibrium blister formation in lipid bilayer-bilayer junctions. R. Parthasarathy, B. L. Jackson, T. J. Lowery, A. P. Wong, J. T. Groves 3:10 138. An AFM study of cholesterol crystallization from model bile solutions. J. A. Swift, M. C. Frincu 3:30 139. Detection and size determina tion of cholesterol nanodomains in biological membranes. S. P. Wrenn, G. M. Troup, S. P. Lee, T. N. Tulenko 4:00 140. Direct measurement of receptor-ligand binding on the surface of living cells. A. W. Feinberg, A. B. Brennan 4:20 141. 3-D tracking of secretory vesicles in vivo to 10 nm accuracy. J. C. Weisshaar, M. Konopka 4:40 142. Detection of saxitoxin by coumaryl-crown sensors. P. Kele, J. Orbulescu, T. L Calhoun, R. E. Gawtey, R. M. Leblanc 5:00 143. Protein patterning on phospho lipid membranes. P. Cremer
TECH-47
TECHNICAL PROGRAM Section C Convention Center Room 290 Adsorption of Macromolecules at Liquid-Solid Interfaces Fundamental Processes in Polymer Adsorption T. A. Camesano, Presiding K. Queeney and W. Chen, Organizers 2:00 144. Adsorption of charged macromolecules on a gold electrode. M. A. Cohen Stuart 2:30 145. Detection of molecular struc tures of interfacial proteins by sum frequency generation vibrational spec troscopy and isotope labeling. J. Wang, Z. Paszti, Z. Chen 2:50 146. Measuring biomolecule adsorp tion to solid/liquid interfaces with second harmonic generation. J. C. Conboy, M. A. Kriech 3:10 147. Density-functional theory of inhomogeneous mixtures of polymeric fluids. J. Wu, Y. Yu 3:30 Intermission. 3:40 148. Infrared spectroscopy as a tool for monitoring the adsorption and reor ganization of films on surfaces. M. Kalaji 4:10 149. Polymer adsorption on cellulose substrate visualized by transmission electron microscopy. H. Nanko, S. Pan, M. McNeal 4:30 150. Infrared spectroscopic studies of polysaccharide adsorption. K. T. Queeney, C. Royce, J. Clemens 5:00 151. Investigation of preferential adsorption of humic substances on activated carbon. M. J. M. Wells Section D Convention Center Room 291 Colloidal and Molecular Electro-Optics Advances in Methodology Cosponsored with Division of Physical Chemistry, and Division of Polymer Chemistry Z. A. Schelly and S. Stoylov, Organizers 2:00 Introductory Remarks. 2:05 152. Colloidal electro-optics in nanotechnology research: Characterization of composite nanoparticles. S. P. Stoylov, M. Buleva, G. Bila, I. B. Petkanchin 2:35 153. Frequency-domain electric birefringence study on the deformation dynamics of microemulsion droplets. T. Shimomura, K. Ito 2:55 154. Wide-band spectroscopy of dynamic electrophoretic mobility and its application to microrheology. D. Mizuno, Y. Kimura, R. Hayakawa 3:15 155. Electro-optic and electrophoretic research of colloid dispersions of high electric conductivity. O. Kolesnikova, A. Trusov, A. Voitylov, V. Vojtylov, T. Zemova 3:35 Intermission. 3:45 156. Quantitative approach to molecular electro-optics: Combined structure-dipole analysis. D. Porschke
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4:15 157. Laser temperature jump experi ments with nanometer space resolution using rhodamine 101 anti-Stokes fluo rescence from nanoseconds to millisec onds for precise measurements of temperature changes in liquid microenvironments. J. F. Holzwarth, S. Couderc, A. Beeby, I. P. Clark, A. W. Parker 4:35 158. Development of a micronized electrical field-flow fractionation instru ment with an improved electrode sys tem. R. ter Veen, M. Jonsson, J. Gantelius, U. Lindberg, K. D. Caldwell 4:55 159. Polarization of the gas/liquid interface. S. P. Stoylov, M. Buleva
4:10 172. Heterogeneous electron-transfer kinetics through alkanethiol monolayers on gold. J. F. Smalley, S. W. Feldberg, M. D. Newton 4:30 173. Electron transfer at Pt nanostructured film electrodes. D. J. SchWfrin, S. Horswell, I. A. O'Neil 4:50 174. Solvation dynamics accompanying charge transfer in bulk and confined liquids. Β. Μ. Ladanyi 5:10 175. Prediction of electron transfer rates in metalloproteins based on spin diffusion. S. D. Minteer, J. Leddy
MONDAY EVENING
Section Ε
Section A
Convention Center Room 292
Convention Center Hall J
Surface Chemistry on Carbonaceous Materials Adsorption, Desorption, and Reactions
Adsorption of Macromolecules at Liquid-Solid Interfaces Poster Session K. Queeney and W. Chen, Organizers
A. V. Teplyakov and T. P. Beebe Jr., Organizers 2:00 16% Dynamics of oligomer desorp tion from surfaces. A. J. Gellman, K. R. Paserba 2:25 161. Adsorbate functionalization and self-assembly on carbonaceous sur faces: Scanning tunneling microscopy and temperature-programmed desorp tion studies of n-alkane derivatives on graphite. T. Muller, Κ. Τ. Rim, G. W. Flynn, A. T. Mathauser, A. V. Teplyakov 2:50 162. First-principles simulations of carbon gasification reactions. Τ. Ν. Truong, A. Montoya, F. Mondragon 3:15 Intermission. 3:25 163. Adsorption and abstraction of Η and D atoms on the (0001) graphite surface. J. Kuppers, T. Zecho, A. Guttler 3:50 164. Eley-Rideal reactions of Η atoms with Η adsorbed onto graphite surfaces. B. Jackson 4:15 165. Growth of graphene layers on HOPG. M. Kappes, R. Wellmann, A. Bôttcher, U. Kohl, H. Niehus 4:40 166. Interaction of atomic oxygen and chlorine with carbonaceous films. H. Fairbrother, J. Torres, C. Perry, S. Bransfield SectionF Convention Center Room 298 Electrochemistry and Surface Science Symposium in Memory of Mike Weaver Charge-Transfer Reactions E. Borguet, Presiding B. A. Parkinson, Organizer,
Presiding
A. Wieckowski, J. L. Stickney, and J. T. Hupp, Organizers 2:00 167. Mechanism of charge transfer at film-modified electrodes. M. D. Newton 2:30 168. Theory of electron-transfer reactions: What may be missing? G. A. Voth 3:00 169. Theoretical calculation of activation energies for Pt + H+(aq) + e-(U) -bis(epoxy)perfluoroalkylpentasik)xanes. W. P. Weber, J. M. Mabry, M. A. Grunlan, J. A. Finlay, M. E. Callow, J. A. Callow 9:10 706. Syntheses and structures of "naked" azolides, indolide, and carbazolide. R. Mews, T. Borrmann, E. Lork, M. Muller, W. Stohrer, J. Wessel
9:30 707. Crystal engineering and coordi nation chemistry of perfluoroalkyltriazapentadienes. A. R. Siedle, R. J. Webb, M. Brostrom, G. Caldwell, F. E. Behr, V. G. Young Jr. 9:50 708. Selectfluor and DeoxoFluor: Safe and effective selective fluorinating agents. G. Pez, G. S. Lai, R. G. Syvret 10:10 Intermission. 10:20 709. Strategy for fluorination of aryl triazolinone herbicides: Selective intro duction of fluorine at just the right time. R. G. Syvret, W. J. Casteel Jr., G. S. Lai 10:40 710. Halogenated fullerenes: Syn thesis, structure, reactivity. O. V. Boltalina 11:00 711. Hypervalent oxyphosphoranes as a model for phosphoryl transfer enzymes. R. R. Holmes, A. Chandrasekaran, N. V. Timosheva, R. O. Day 11:20 712. Neutron diffraction studies on rubredoxin. R. Bau, I. Tsyba, N. Moiseeva, M. W. W. Adams, F. E. Jenney Jr., K. Kurihara, T. Chatake, N. Niimura 11:40 713. IR detection of inorganic anions in water at ppb concentrations. S. H. Strauss SectkxiB Convention Center Room 261 Synthesis of Nanoparticles and Nanostructured Materials Hierarchical Structures D. R. Rolison and P. K. Dutta, Presiding S. L. Suib, S. L. Brock, and M. Hampden-Smith, Organizers
8:50 722. Understanding factors neces sary for rac/meso selectivity in the chelate-controlled synthesis of rac-ansazirconocene complexes: A computa tional exploration. D. C. Wiser, L. E. Sweet, A. R. Dunn, T. Z. Gunter, R. F. Jordan, M. D. LoCoco 9:10 724. Characteristics of weakly coor dinating chlorinated anions for catalysis: ^ C l NQR spectroscopic studies of chloroacetates and trichloromethanesulfonates ("trichlates"). G. P. Wulfsberg, M. J. Cochran, J. Wilcox, D. J. Jackson, J. C. Howard 9:30 725. Synthesis, structures, and reactivity of Zr(IV) chlorobenzene com plexes. F. Wu, A. D. Dash, R. F. Jordan 9:50 726. Interactions between ferrocene and main-group metals. M. Wagner, M. Schelbitz, S. Scholz, H. Lemer 10:10 727. Characterization of the lowenergy electronic excited states of benzoyl-substituted ferrocenes. C. Kutal, W. Ding, C. T. Sanderson, R. Conover, M. K. Johnson, I. J. Amster 10:30 728. Intervalence charge transfer in mixed-valence ferrocene and cobaltocene systems with group 4 element bridging groups. S. Barlow, S. C. Jones, D. O'Hare 10:50 729. Isomerization of phosphametallocenes. T. K. Hollis, Y. J. Ann 11:10 730. Mixed-cydopentadienyl/arylsulfide titanium dichlorides. A. E. Fenwick, P. E. Fanwick, I. P. Rothwell 11:30 731. Ring-borylated ansa-chromocene complexes. P. J. Shapiro, P. Sinnema, B. Twamley Section D Convention Center Room 265-266 Catalysis
8:30 714. Multicompositional assembly and function. G. D. Stucky 9:00 715. Hierarchically growing, pattern ing, and aligning self-assembled nano structured materials. Z. R. Tian, J. Liu, J. A. Voigt, H. Xu, M. McDermott, B. McKenzie, C. M. Matzke 9:20 716. Colloidal crystal templating of porous solids for applications in photon ics and beyond. A. Stein, H. Yan, S. Sokolov, M. Al-Daous, J. C. Lytle 9:50 717. Fabrication of nanostructured metal oxide films by 3-D replication of structured organic templates in super critical fluids. R. A. Pal, J. J. Watkins 10:10 718. Templating synthesis of hierar chical nanowire and nanomesh thin films. D. Wang, J. He, B. F. McCaughy, J. E. Hampsey, X. Ji, Y. Jiang, H. Xu, W. L Zhou, J. Tang, R. Schmehl, C. J. O'Connor, C. J. Brinker, Y. Lu 10:30 719. Nucleation, growth, and selforganization of gold nanorods/nanowires. P. Yang, F. Kim 11:00 720. Regioselective chemistry and reaction dynamics of silica-gold coreshell-type nanoparticle composites. F. E. Osterloh, H. Hiramatsu 11:20 721. Using an interface to direct the synthesis of nanostructured magnetic materials. D. R. Talham, J. T. Culp, M. W. Meisel, J. Park Section C Convention Center Room 262 Organometallic Metallocenes C. Kutal, Presiding 8:30 723. Broadening the scope of chelate-controlled rac-ansa-zirconocene synthesis. M. D. LoCoco, R. F. Jordan
W. D. Jones, Presiding 9:00 733. Adduct studies of the superelectrophilic ruthenium cation CpRu(dfepe)+. D. M. Roddick, J. L. Butikofer 9:20 732. Combinatorial electrochemical synthesis and screening of transitionmetal-doped zinc oxides as watersplitting photocatalysts for hydrogen production. T. F. Jaramillo, K. Choi, S. H. Baeck, G. D. Stucky, E. W. McFariand 9:40 734. Facile catalytic alkane dehydrogenation and aziridination in Cu-pyridinophane systems. A. N. Vedemikov, K. G. Caulton 10:00 735. Design and catalytic properties of metallobis(benzimidazole)s: Pringles with a twist. M. K. Chan, T. Fekner 10:20 736. Synthesis and characterization of MAPO-11. B. Xu Sr., Z. Yan Sr. 10:40 737. In situ FT-IR study of the acid-free nitration of benzene and tolu ene in NaZSM-5. S. J. Kirkby 11:00 738. Homogeneous hydroformyla tion of cyclopentene catalyzed by mixedmetal carbonyls: On bimetallic syner gism in homogeneous catalysis. C. U, E. Widjaja, L Guo, M. Garland 11:20 739. Late transition-metal imino complexes: Inert gas formalism viola tions. A. N. Vedemikov, K. G. Caulton 11:40 740. Metal peroxide initiated direct sulfonation of methane to methanesulfonic acid at low temperature with S0 3 or S0 2 - S. Mukhopadhyay, A. T. Bell 12:00 741. Selective metal-catalyzed sulfonation of methane to methanesulfonic acid with S0 3 or S0 2 in the presence of molecular 0 2 . S. Mukhopadhyay, A. T. Bell
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
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TECHNICAL PROGRAM 12:20 742. TPD-FTIR investigation of alcohols adsorbed on poorly crystalline alumina. T. C. DeVore, P. A. Claybome, T. C. Nelson 12:40 743. Unraveling the role of each metal in hydrogen-assisted 1,2-dichloroethane dechlorination catalyzed by R-Cu/SJ02 catalysts. V. Y. Borovkov, D. R. Luebke, V. I. Kovalchuk, J. L. d'ltri Section Ε Convention Center Room 263 From Mixed-Valency to Single-Molecule Magnets Mixed-Valency and Electron Transfer G. Christou, Presiding J. K. McCusker, Organizer 9:00 Introductory Remarks. 9:10 744. Charge localization and dereal ization in organometallic mixed-valence complexes. C. P. Kubiak, C. H. Londergan, M. Sponsler 9:30 745. Intramolecular electron transfer in transition-metal complexes containing o-quinone ligands. C. G. Pierpont 9:50 746. Luminescent polysilole and polygermole sensors for TNT. W. C. Trogler, H. Sohn, S. Uu, S. Toal 10:10 747. C-H bond activation: Catalysis by hydrogen tunneling? M. J. Knapp 10:30 748. Single-molecule spectroscopy of electron transfer. D. M. Adams, R. Liu, M. W. Holman, L. Zang 10:50 749. Muftistep electron tunneling in blue copper proteins. Η. Β. Gray, A. J. Di Bilio, J. E. Miller, A. K. Museth, W. A. Wehbi, J. R. Winkler 11:10 750. Probing the spin-state depen dence of electron transfer. J. K. McCusker, J. J. Bodwin
10:10 756. Structure of sdvated Fe(CO)5: FTIR measurements, X-ray absorption measurements, and density functional theory calculations. T. Lee, Y. Jiang, C. Rose-Petruck 10:30 757. Time-dependent density functional theory calculations of Pt(ll) complexes for interpretation of emission behavior. S. R. Stoyanov, D. P. Rillema 10:50 758. Unsaturation in homoleptJc binuclear chromium carbonyls as studied by density functional theory. R. B. King, H. F. Schaefer III, S. Li, N. A. Richardson 11:10 759. Structure and reactivity of [N(Si(CH3)2CH2P(,Bu)^2]RuCI: The first 4-coordinate, planar, ]pyrazines. D. J. Sattler, K. A. Mitchell, S. C. Rasmussen 556. Substituted tris(bipyridyl)mthenium complexes as selective photosensitizes for electron transfer in organic chemistry. F. S. Lee, S. Van Rooy, N. P. Schepp 557. Synthesis and characterization of a model electron donor/acceptor system based on a peptide nucleic acid duplex. I. Dilek, B. A. Armitage 558. Synthesis of photocleavable protecting groups for primary alcohols with applica tions in the construction of DNA microarrays. G. Μ. Ζορρ, Μ. Κ. Boyd
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
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ORGN/TECHNICAL PROGRAM
559. Electrocyclization reaction of /V-alkylpyridones inside chirally modified zeo lites. S. Karthikeyan, V. Ramamurthy 560. Bergman cyclization: Ortho effect in benzannelated enediynes. T. A. Zeidan, I. V. Alabugin 561. Molecular orientation effects on hydro gen transfer rates under diffusional constraints. M. K. Kidder, A. C. Buchanan III, P. Britt 562. NMR studies of the cleavage of highly substituted epoxides with organoalane reagents. J. A. Prieto, G. Torres 563. Equilibrium lithium and cesium ion-pair acidities of some β-diketones: Aggrega tion of lithium and cesium ion pairs of their enolate mono- and dianions. A. Facchetti, A. Streitwieser 564. Influence of methyl substitueras on the stability and reactivity of 1-aza-2-adamantanone, Kirby's most twisted amide. K. M. Morgan, M. L. Rawlins, M. Montgomery 565. Conformational studies of cyanoformate (HC02CN) and related com pounds. D. Davis, D. Pawar, E. Noe 566. Dimethylstannylene: Generation and trapping reactions. D. Zhou, P. P. Gaspar 567. Photochemical behavior of a-azoxy ketones. P. S. Engel, K. P. Tsvaygboym, W. B. Smith 568. Mechanism of dichlorocarbene addi tion to benzocydopropene. E. Zelenova, D. C. Merrer 569. Dichlorocarbene addition to cyclopro penes: A computational study. D. C. Merrer 570. Mechanistic investigations of the aqueous breakdown of substituted /V-(hydroxymethyl)benzamide com pounds as a function of pH. R. W. Nagorski, W. J. Term III 571. Novel regiochemistry in the aqueous singlet oxygen ene reaction of carboxylic acid salts: A comparison of substrate structure. K. L. Stensaas, A. Bajaj, A. Al-Turk 572. The location effect of substituents on the Bronsted apha for hydride transfer reactions. I. H. Lee, K. H. Suh 573. Density functional theory investigation of deprotonation of 2,3-dihydrofuran. Z. Yan, J. F. Sebastian 574. Cobalt-catalyzed reductive dimerization of conjugated alkenes: Application to the synthesis of macrocyclic di- and tetralactones. C. Wang, C. Cheng 575. Novel Rh-catalyzed cyclization via rhodacycle intermediates: Hydroacylation of dienals and cycloisomerization of trienes. Y. Sato, Y. Oonishi, M. Mori 576. Umpolung palladium- and indiummediated allylations. J. W. Giraldes, G. R. Cook 577. New developments in palladium- and indium-mediated allylation. G. R. Cook, R. Kargbo, J. Hallman 578. The contribution of prior-coordination to ortho-lithiation: Regiospedfic metallation of ortrio-methylanisole and dimethylbenzylamine. D. W. Slocum, M. Timmons, S. Wang, A. Watson, C. Friesen, D. Smith, R. LeMastus, P. Shelton, G. Jackson, R. W. Holman 579. TrisubstJtuted olefin synthesis by reaction of benzylic zinc reagents with β,β-disubstituted alkenyl(phenyl)idonium triflates. N. D. Utvinas, R. J. Hinkle 580. Vinyl aryl ethers from copper-cata lyzed coupling of vinyl halides and phenols. Z. Wan, T. M. Koenig, Y. J. Pu, D. Mitchell 581. Palladium-catalyzed synthesis of isatins and 2-haloisatogens. C. R. Howerton, B. C. G. Soderberg, S. W. Dantale 582. Synthesis of 2-alkylbenzimidazoles. J. M. Wallace, B. C. Soderberg 583. Synthesis of indanes through coupling of ethynylstyrene derivatives with carbene complexes. L Zhang, J. W. Herndon
584. Synthesis, characterization, and elabo ration of endo[n.n.n.n] (n = 3 or 4) metacyclophanes. D. H. Bums, C. L Jayne, S. A. Kularatne 585. Rhodium-catalyzed cross-coupling of allylic alcohols with aryl- and vinylboronic acids in ionic liquids. G. W. Kabalka, G. Dong, B. Venkataiah 586. Rhodium(l)-catalyzed tandem hydrosilylation aldol reaction: Synthesis of carbocyclic natural products. M. Freiria, W. B. Motherwell, A. J. Whitehead 587. Metalloporphyrin-based catalytic systems for olefination of aldehydes and ketones with diazo compounds. X. P. Zhang, Y. Chen, L. Huang 588. Novel Rh-catalyzed [2+2+2+1] cydoaddition reaction of enediynes. M. Fujiwara, V. C. Vassar, I. Ojima 589. Palladium-catalyzed Heck-type reac tions using haloalkenes in place of alkenes in reactions with organic iodides. H. A. Dieck, T. M. Perry, P. Xia, B. P. Harting 590. Palladium-catalyzed cleavage of aryl propargyl ether. M. Pal, K. Parasuraman, K. R. Yeleswarapu 591. Ligand-controlled asymmetric induction at a transition-metal-bonded stereogenic carbon: Diastereoselective synthesis of oxapalladacycles and development of their synthetic applications. H. C. Malinakova, J. L. Portscheller, S. E. Lilley 592. Highly efficient Suzuki coupling reac tions of aryl bromides and arylboronic acids catalyzed by Pd(OAc)2/amines under mild conditions. B. Tao, D. W. Boykin 593. Indium-promoted couplings leading to enediyne formation and oxy-cope rear rangements. T. M. Mitzel, A. Troutman 594. Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines. Y. Zhang, K. Forinash, L. McElwee-White 595. Synthesis of lactones and related bicyclic heterocycles by palladium(ll)catalyzed 1,4-oxidation of conjugated dienes. R. C. Verboom, A. Persson, J. Bâckvall 596. Toward highly air-stable palladium catalysts for the cross-coupling reactions with unactivated aryl chlorides. G. Y. Li 597. Isoquinolone synthesis via modium(ll)catalyzed intramolecular aromatic C-H insertion of a-phenylsulfonyl-a-diazoacetamides. K. W. Jung, A. S. Nagle, C. H. Yoon, C. Chen 598. Efficient synthesis of triols via Rhcatalyzed regioselective intramolecular silylformylation of alkynes. B. D. Chapsal, C. Jiang, S. Lee, I. Ojima 599. Effect of solvent on the lithium-iodine exchange of primary alkyl iodides: Reaction of f-butyllithium with 1-iodooctane in heptane-ether mixtures. W. F. Bailey, J. D. Brubaker, K. P. Jordan 600. A new titanium tetrachloride mediated synthesis of polysubstituted naphthalenes. G. W. Kabalka, Z. Wu, Y. Ju 601. Asymmetric hydrogénation of arylalkenes using iridium imidazol-2-ylideneoxazoline complex. K. Burgess, X. Cui, M. C. Perry 602. A facile reaction of (Z)-(1-bromo-1alkenyl)boronate esters with cyclopropylmagnesium bromide: An easy access to alkyl cydopropyl ketones. N. G. Bhat, L. E. Garcia, V. Tamez Jr. 603. A novel synthesis of capillin and capillen via organoboranes. N. G. Bhat, E. T. Chu 604. An efficient and environmentally friendly synthesis of C-aryl glucals via palladium(0)-catalyzed cross-coupling reactions of triorganoindium(lll) reagents and aryl halides. T. G. Minehan, S. Awasthi 605. Palladium-catalyzed Suzuki crosscouplings of aryl chlorides in the presence of a triarylphosphine. G. C. Fu, S.Liu 606. A general method for the formation of diaryl selenides using copper(l) catalysts. R. Gujadhur, D. Venkataraman
607. Highly efficient epoxidation of cyclic alkene catalyzed by ruthenium complexes. J. Y. Qi, C. W. Yip, Ζ. Υ. Zhou, A. S. C. Chan 608. Synthesis and characterization of cobalt complexes containing 2-pyridinecarboxamide ligands and their applica tion in catalytic oxidation of ethylbenzene with dioxygen. J. Y. Qi, X. Li, Ζ. Υ. Zhou, M.C.K. Choi, A.S.C.Chan, Q. Y.Yang 609. Synthesis of benzylic boronates via palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with benzylic halides. A. Giroux 610. Pd-catalyzed cycloisomerization of 1.6-dienes. G. C. Lloyd-Jones, P. A. Stafford, I. J. S. Fairiamb, J. P. H. Charmant 611. Synthesis of 7-substituted indoles via directed ortho metallation and SuzukiMiyaura cross-coupling. C. Hartung, A. Fecher, B. Nolte, V. Snieckus
WEDNESDAY AFTERNOON Section A Convention Center La Nouvelle Ballroom A/B Nakanishi Prize C. A. Townsend, Organizer, Presiding 2:00 612. DNA-templated synthesis as a basis for the evolution of synthetic molecules. D. R. Uu, Z. J. Gartner, M. W. Kanan, C. T. Calderone 2:40 613. RNA-catalyzed replication of RNA. G. F. Joyce, K. E. McGinness, N. Paul, D. Kim 3:20 614. Ribozyme engineering and evolution. D. H. Burke, V. Sakmerprome, S. Hati 4:00 615. Award Address (Nakanishi Prize, sponsored by Nakanishi Prize Endowment). Genetically programmed synthesis of natural products. A. I. Scott Section Β Convention Center La Nourvelle Ballroom C New Reactions and Methodology S. S. Hall, Presiding 1:00 616. Tandem allylation-reduction of aryl aldehydes and ketones: Synthesis of 4-aryl-1-butènes. S. S. Hall, W. Uu 1:20 617. Preparation of differentially 1,3-disubstJtuted indolines by anionic cyclization. W. F. Bailey, M. R. Luderer, M. J. Mealy, M. B. Sommer 1:40 618. Regioselective epoxide cleavage using alkynyl alanes: Application to polypropionate synthesis. J. A. Prieto, G. Torres, W. Torres, R. Tirado, L. Castro 2:00 620. P-Heterocyclic building blocks: Application to the stereoselective synthesis of phosphono sugars. D. Stoianova, A. Whitehead, P. R. Hanson 2:20 619. Reinvestigation of mucohalic acids, versatile and powerful building blocks for highly tunctionalized a, β-unsaturated -y-butyrolactams and -y-butyrolactones. J. Zhang, P. G. Blazecka, D. Belmont, J. G. Davidson 2:40 621. Ring-opening reactions of tetrahydro-4H-furo[2,3-6]pyran-2-ones. S. Polat Cakir, Κ. Τ. Mead 3:00 622. Inverse electron demand DielsAlder reactions with allenamides. C. R. Berry, R. P. Hsung, C. Rameshkumar, L. Wei 3:20 623. Novel asymmetric halo aldol reaction. X. Xu, D. Chen, C. Timmons, A. Headley, G. U 3:40 624. Application of a stereoelectronic model developed to predict stereoselec tive nudeophilic additions to tetrahydrofuran oxocarbenium ions. K. A. Woerpei, D. M. Smith. M. B. Tran
4:00 625. Carbon-carbon bond formation by carbene and radical chemistry of iodoform. J. L Bennett, P. A. Hill 4:20 626. A novel approach to the MoritaBaylis-Hillman lactones via the Lewis acid-promoted couplings of α,β-unsaturated lactones and aldehydes. S. Karur, J. Harding, A. Headley, G. U 4:40 627. Acetonitrile derivatives as carbonyl synthons: One-pot syntheses of heterocyclic amides and diaryl ketones from heterocyclic halides. Z. Zhang, Z. Yin, N. A. Meanwell, J. F. Kadow, T. Wang Section C Convention Center Room 356-357 Lipids, Biosynthesis, Enzyme Inhibitors, and Mimetics Ν. Μ. Carballeira, Presiding 1:00 628. Biosynthesis of kwastatin: Putative polyketide intermediates and post-PKS transformations. J. L. Sorensen, J. C. Vederas 1:20 629. Isolation, structural character ization, and properties of bacterially produced antimicrobial peptides with unique structural features. N. I. Martin, J. C. Vederas 1:40 630. Semisynthesis of 14β-ΟΗ baccatin 111-1,14-carbonate from 10-deacetyl baccatin III. A. Battaglia, E. Baldelli, E. Bombardelli, D. Carenzi, M. L. Gelmi, A. Guerrini, G. Fontana, D. Pocar 2:00 631. Enzymatic studies on type II thioesterase of methymydn/picromycin synthase. H. Lu, D. E. Cane 2:20 632. Withdrawn. 2:40 633. Syntheses of small estrogenic carboxylic acids for a study of their in vivo and in vitro activities. S. Xle, Y. Hou, C. Y. Meyers, P. D. Robinson 3:00 634. Synthesis of a novel ureidopeptide inhibitor of HIV-1 protease. A. C. Myers, M. A. Upton 3:20 635. Synthesis of racemic 3-[3-(1,7dihydroxynaphthyl)]-2,2-dimethylpentanoic acid, a bacterial metabolite of hydroxyvallestril. Y. Hou, M. N. McCain, C. Y. Meyers 3:40 636. Synthesis of regioselectively deuterated linoieic acids. L Zhu, R. E. Minto 4:00 637. New pathways that generate oxidatively truncated lipids. M. Sun, R. G. Salomon 4:20 638. Synthesis and characterization of ceramides from Porphyromonas gingivalis. M. B. Smith, F. Nichols, J. Mun Section D Convention Center Room 352 Materials, Devices, and Switches C. J. Abelt, Presiding 2:00 639. Perfluorophenylthiophene versus phenyithiophene oligomeric semiconductors: Synthesis, characteriza tion, and electrical properties. A. Facchetti, M. Yoon, H. E. Katz, T. J. Marks
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
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TECHNICAL PROGRAM 2:20 640. Semiconductor nanocrystals (CdS and CdSe) for the photocatalytic reduction of aromatic azides. M. V. Warrter, F. K. Lo, C. Radhakrishnan, M. Garcia-Garibay, H. Monbouquette 2:40 641. Synthesis and magnetic proper ties of the perchloro-2,5,8-triazaphenalenyl radical and its dimer. S. Zheng, J. D. Thompson, S. I. Khan, Y. Rubin 3:00 642. Unidirectional ring rotation in a noncovalently linked molecular structure. D. A. Leigh 3:20 643. Thin-film transistors and capaci tors with a ROMP polymer as the dielec tric layer. O. A. Scherman, I. M. Rutenberg, Z. Bao, R. H. Grubbs 3:40 644. Toward faster molecular switches. S. A. Vignon, J. F. Stoddart 4:00 645. From molecular recognition and self-assembly to molecular electronics. H. Tseng, J. F. Stoddart 4:20 646. Rational synthesis and novel applications of chiral macrocycles. H. Jiang, A. Hu, W. Un 4:40 647. C-shaped pyrroles for siteisolated conducting polymers: Modula tion of conductivity via tight coupling between acid-base and redox chemistry. D. Lee, T. M. Swager
THURSDAY MORNING Section A Convention Center Room 297 Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High-Energy Species R. W. Darbeau, Presiding 8:00 648. The /V-nitrosoamide-mediated Ritter reaction. R. W. Darbeau, R. E. Gibble, R. S. Pease, E. V. Perez 8:20 649. Introduction of persistent steric ("persisteric") and pi*-acceptor agostic type interactions. R. W. Darbeau, R. S. Pease, R. E. Gibble, E. V. Perez, L. M. Siso, F. Ayo, A. Sweeney 8:40 650. Fomenting proton anisochronicity in the CH2D group: Realizing an improved method for assigning the CHDT group via NMR. B. D. Allen, D. J. O'Leary 9:00 651. Rapid-injection NMR study of iodo- and cyano-Gilman reagents with 2-cyclohexenone: Observation of ΊΓπ-complexes and their rates of forma tion. M. D. Murphy, H. P. Seagle, S. H. Bertz, C. M. Carlin, C. A. Ogle 9:20 652. Mechanistic studies of the unexpected anti-Markovnikov addition to 1 -alkoxy-1,3-cyclohexadienes. R. A. Rennels, J. V. McClusky, S. L. Emery 9:40 653. Effects of pore confinement on the pyrolysis of 1,3-diphenylpropane in mesoporous silicas. A. C. Buchanan III, M. K. Kidder, P. F. Britt, Z. Zhang, S. Dai 10:00 654. Reaction of tetracydopropylethylene with 4-methyl-1,2,4-triazoline3,5-dione: Novel rearrangement of intermediate product. D. K. Kim, K. E. O'Shea, A. J. Sabucedo
10:20 655. Unequivocal determination of the stereochemistry of reactions involv ing sterically hindered, rotationally restricted 9-fluorenyl anions, radicals, and cations. C. Y. Meyers, Y. Hou 10:40 656. Solvolysis-decomposition of 2-adamantylchloroformate: Evidence for two reaction pathways. D. N. Kevill, J. B. Kyong, J. Yoo 11:00 657. Acetylacetone in solutions of lithium perchlorate-diethyl ether. Y. Pocker, G. T. Spyridis 11:20 658. Benzocyclobutenone vs cyclobutanone: Acidity differences in strained ring systems. R. W. Nagorski Section Β Convention Center Room 296 New Reactions and Methodology N. G. Bhat, Presiding 8:00 659. Synthesis of benzoxocanes via regioselective 8-endo-phenol epoxide cydizations. J. R. Vyvyan, R. E. Looper. S. T. Staben 8:20 660. A study of ring cleavage reac tions of hexahydro-2H,5H-pyrano[2,3b]pyran-2-ones: A potential strategy for use in the synthesis of blepharocalyxin D. W. Li, Κ. Τ. Mead 8:40 661. β-Silyl arènes: Novel substrates for the arene-olefin photocyclization reaction. J. A. Mathews, M. A. deLong, S. L. Cohen, F. C. Wireko, A. L. Ritter, A. D. Gudmundsdottir 9:00 662. Nucleophilic addition of organozinc reagents to activated pyridines: Progress toward catalytic enantioselective synthesis of 2-substituted dihydropyridines. A. B. Charette, J. Martel 9:20 663. Expedient preparation of halogenocyclopropanes by stereoselective cyclopropanation of electron-deficient allylic ethers. A. B. Charette, M. Laçasse 9:40 664. Nucleoside analogs derived from 1,5-dioxaspiro[3.2]hexanes. R. C. Taboada, A. R. Howell 10:00 665. Investigation of the unusual reactivity of bridgehead lactams. A. D. Wrobleski, J. E. Golden, A. Albright, J. Aube 10:20 666. Diastereoselective syntheses of di- and trisubstituted cyclic ethers via tandem cyclization-addition reactions. R. J. Hinkle, P. A. Evans, J. Cui, B. Delouvrié 10:40 667. Halogenation of deactivated aromatics: /V-Halosuccinimide-BF3-H20 as an efficient electrophilic halogenating agent. G. K. S. Prakash, T. Mathew. D. Hoole, P. M. Esteves, Q. Wang, G. Rasul, G. A. Olah 11:00 668. Heliquinomycin: A linchpin approach for a model study. C. C. Undsey, S. J. Mercede, T. R. R. Pettus 11:20 669. Stereogenic quaternary carbon centers from the Lewis acid-catalyzed allylboration of aldehydes. J. W. J. Kennedy, N. Zhu, D. G. Hall 11:40 670. A Diels-Alder route to the phenanthridone alkaloid skeleton via 2-dienylphenacyloxazolones. M. B. Smith, C. Guo, M. Azab, P. Chen, Y. Zhang, M. Salem Section C Convention Center Room 271 Molecular Recognition and Self-Assembly R. S. Clegg, Presiding 8:00 671. Cryptands: Powerful hosts for paraquat derivatives. F. Huang, L. N. Zakharov, A. L. Rheingold, H. W. Gibson, J. W. Jones
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8:20 672. Supramolecular control of reactivity using linear templates. L. R. MacGillivray, T. Friscic, G. S. Papaefstathiou, D. B. Varshney 8:40 673. Toward polyhedral molecules in template-directed solid-state synthesis. D. B. Varshney, L. MacGillivray, G. S. Papaefstathiou 9:00 674. Shape tolerance in templatedirected solid-state synthesis. T. Friscic, L. MacGillivray 9:20 675. Synthesis and solid-state characterization of highly functionalized macrocydic ligands. K. Campbell, R. R. Tykwinski 9:40 676. Self-assembly squared: Nanografting metal-assembled modular proteins into C18 monolayers. M. A. Case, G. L. McLendon, G. Scoles, T. K. Vanderlick, Y. Hu 10:00 677. Self-organization of (auto)catalytic peptides into chemical networks. G. Ashkenasy, R. Jagasia, M. R. Ghadiri 10:20 678. Supramolecular chemistry of mellitic triimides. D. G. Hamilton 10:40 679. Supramolecular chemistry of nitrogen oxides. D. M. Rudkevich, G. V. Zyryanov, Y. Kang, S. P. Stampp 11:00 680. Molecular association of polynitriles and silver salts. K. V. Kilway, S. Deng, G. Marquez, D. M. Ho, J. R. VanScoy, J. W. Vincent 11:20 681. Dynamics of guest binding to bile salt aggregates. C. Bonne 11:40 682. Metal rotaxanes under thermodynamic control. D. A. Leigh Section D Convention Center Room 273 Materials, Devices, and Switches M. A. Garcia-Garibay, Presiding 8:30 683. Persistent photo induced states in functionalized pentacene. J. S. Brooks, D. L. Eaton, J. E. Anthony, E. S. Choi, D. E. Graf, X. Wei 8:50 684. Pure infrared electroluminescence from conjugated polymer host/ guest blends. M. R. Robinson, G. C. Bazan, A. J. Heeger, J. C. Ostrowski, M. J. Therien 9:10 685. Raman and far-infrared spectroscopy of substituted pentacenes. D. L Eaton, J. S. Brooks, J. E. Anthony, B. Van De Burgt 9:30 686. Two-photon absorption and mixed-valence properties of dioxaborine derivatives. S. Barlow, J. Brédas, V. Coropceanu, C. Grasso, H. Marcus, S. R. Marder, J. W. Perry, C. Risko, F. Stellacci, W. Wenseleers, E. Zojer 9:50 687. Sensitizing trivalent europium using dendritic β-diketone ligands. P. J. Case, A. W. Harper 10:10 688. Harvesting triplet energy from conjugated polymers by europium ter nary complexes: Tuning the energy of complexes to achieve higher energytransfer efficiencies. A. B. Padmaperuma, A. W. Harper 10:30 689. Understanding the role of solvent on two-photon materials: Chemi cal environment effects on a family of new two-photon engineered alkylaminosubstituted styryl pyrazine dyes. J. Collette, A. W. Harper 10:50 690. All-optical processing with molecular switches. S. Giordani, F. M. Raymo 11:10 691. Synthesis of novel nearinfrared dyes for optical switching at 1.3 μπι. M. Tian, S. Tatsuura, M. Furuki, Y. Sato, I. Iwasa, L. S. Pu 11:30 692. Appropriate economic mea surement techniques for organic lightemitting diodes. M. R. Robinson
THURSDAY AFTERNOON SectionA Convention Center Room 297 Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High-Energy Species K. D. Belfield, Presiding 1:00 693. Fine-tuning regioselectivity of 1,3-dipolar cycloaddition by catalytic antibody 29G12. Y. Hu, K. N. Houk 1:20 694. Controlling the benzocydobutene-oxylylene equilibrium by OH-O and OH-F interactions. P. S. Lee, Κ. Ν. Houk 1:40 695. Computational study to eluci date the extraordinary reactivity of threemembered heterocycles in nucleophilic substitution reactions. H. D. Banks 2:00 696. Spiro vs planar transition struc tures in the epoxidation of simple alkenes: A reassessment of the level of theory required. R. D. Bach, O. Dmrtrenko 2:20 697. Quantum yields and mecha nism for new two-photon-absorbing singlet oxygen photosensitizers. K. D. Belfield, Ο Ο Corrector 2:40 698. Diels-Alder trapping of photoenols generated from 3,6-dibenzoyl-1,2dimethylbenzene: A photochemical approach to the synthesis of substituted phenanthrenes. M. A. Meador, F. Ilnan, J. D. Kinder, D. A. Scheiman 3:00 699. Synthesis and characterization of photogenerated reagents: Photogenerated piperidine and hydrazine and their applications in peptide synthesis. W. Yao, J. P. Pellois, N. Vaganay, X.Gao 3:20 700. Synthesis and photophysical properties of a linearly noncovalently linked porphyrin-fullerene dyad. S. MacMahon, F. T. Tat, D. I. Schuster, S. R. Wilson 3:40 701. Photophysics of mono- and dipyrenyl perfluoroalkanes. D. Wiedenfeld, S. Niyogi, W. Xu 4:00 702. Charge-transfer transitions in solutions of lithium perchlorate-diethyl ether. Y. Pocker, G. T. Spyridis Section Β Convention Center Room 296 New Reactions and Methodology D. C. Dittmer, Presiding 1:00 703. Tellurium-triggered opening of cyclopropanemethanol tosylates. D. C. Dittmer, M. G. Malusare, E. Arslancan 1:20 704. Use and reuse of ionic-liquid technology. D. C. Forbes, J. H. Davis Jr., D. W. Morrison, K. L. T. Tran, K. J. Weaver 1:40 705. Acceleration of Diels-Alder reactions in fluorous solvents. K. E. Myers, K. Kumar 2:00 706. New fluorous tag strategy for solution-phase parallel synthesis. W. Zhang, C. H. Chen 2:20 707. Lewis acid and Lewis base catalysts on nonpolar soluble polymer supports. C. Li, J. D. Frels, D. Bergbreiter
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
ORGN/PETFVTECHNICAL PROGRAM
2:40 712. Molybdenum pentachloride: A powerful oxidative coupling reagent for electron-rich aryls. S. R. Waldvogel, B. Kramer, A. Averhoff, E. Aits, D. Mirk 3:00 709. Novel synthesis of tetrahydrofuran derivatives: Ceric ammonium nitrate mediated annulation of nitroethanoJ onto alkenes. J. Bae, G. A. Kraus 3:20 710. A novel route to alkyl allenyl ketones via organoboranes. N. G. Bhat 3:40 711. Pd-catalyzed reactions using N-heterocydic carbenes as a ligand: Allylic substitution and bismetallative cyclization. Y. Sato, T. Yoshino, N. Imakuni, M. Mori 4:00 708. Studies toward the total synthe sis of the callipeltosides. A. Meyer, R. D. M. Davies, A. Heimann, R. Marquez, I. Paterson 4:20 713. Alkyne migration in alkylkJene carbenoid species: A new method of polyyne synthesis. S. Eistor, A. L. K. Shi Shun, R. R. Tykwinski 4:40 714. Synthesis and chemistry of new donor-acceptor glucal-derived cyclopro panes. Β. L Pagenkopf, M. Yu Section C
DIVISION OF PETROLEUM CHEMISTRY K. W. Plumlee, Program Chair
OTHER SVMP06KOF MTERtST: Plasma Technology and Catslyele (see Catalysis & Surface Science Secretariat, Mon, Tue, Wed) Advances In Msfnbrsnes for Energy sjid Fuel AppRosHons (see DMsion of Fuei Chemistry, Tuet Wed, Thu) Advances bi TechnkRjss for AnalytlcsJ Chafsctsrizston In Fuel Chemtetry (see DMsion of Fuel Chemistry, Sun)
Convention Center Room 271 Molecular Recognition and Self·/ C. Bohne, Presiding 1:00 715. Using "oxa-bowls" to study the molecular recognition of alkali metal ions. S. L Richardson, M. R. Pederson 1:20 716. ESI-MS evaluation of the metal cation complexation behavior of cageannulated aza crown ethers. A. P. Marchand, Ζ. Huang, H. Lai, J. S. Brodbelt, S. Williams 1:40 717. Synthesis, characterization, and biological evalution of carbohydratefunctjonalized nanoparticles. J. Gervay-Hague, B. Notting, J. Yu, G. Uu, S. J. Cho, S. M. Kauzlarich 2:00 718. Oligosaccharides as novel molecular scaffolds. S. N. Lam, J. Gervay-Hague 2:20 719. Resorcinarenes as templates for the synthesis of large crown ethers. X . U . T . Upton, C.LD.GIbb, B.C.GIbb 2:40 720. Characterizing self-assemblies with probability trees. C. L D. Gibb, B. C. Gibb 3:00 721. Interdigitated and extended calix[4]arene dimers as molecular cap sules. K. L Caran, L Reyes, S. Marek, S. B. Shuker 3:20 722. Dimerization and encapsulation studies of calix[4]arene derivatives in polar solvents. J. S. Saslne, S. B. Shuker 3:40 723. Cooperative host/guest interac tions via counterion-assisted chelation: Pseudorotaxanes from supramolecular cryptands. J. W. Jones, F. Huang, H. W. Gibson, L N. Zakharov, A. L Rheingold 4:00 724. First example of reversible enantiofacial discrimination on heterocycles. C. Siering, M. C. Schopohl, S. R. Waldvogel 4:20 725. Interlocked architectures through versatile ligands suitable for coordination of divalent metal ions. A. Morelli, D. A. Leigh, P. J. Lusby. K. R. West, L J. Hogg
Chemlcsls from CosJ (see DMsion of Fuel Chemistry, Sun) Chemistry of Fuels and Emerging Fuel Technologies (see DMsion of Fuel Chemistry, Thu) rmrti onmontnl Cntatysli by Metal «MMKN·» varoKies, ana rNviaesfor UHitlssii Fusle (see DMsion of Fuel Chemistry, Sun, Mon) Heavy Hydrocarbon Resources: UtMfcuaon (see DMsion of Fuel Chemistry, Sun, Mon) HsMtat of Natural Qes withsQUH of Mexico: From Source to Reservoirs to Sssps and Hydrates (see DMsion c4Qeoctemistiy,lbu)
Environmental Catalysis by Metal Sulfides, Carbides, end Nitrides for Ultrsclesn Fuels Simulation and Characterization Cosponsored with Division of Fuel Chemistry MONDAY MORNING
urgente oowos in rswosiurii Production (see DMsion, of Geochemistry, ^βφ The QuJf Oosst Environment (see DMsion of Envhonmental Chemistry, Wed, Thu) SOCIALEVENT8: Dinner: Tue Social HOUR Tue
BUSINESS MEETING: Tue SUNDAY MORNING Environmental Catalysis by Metal Sulfides, Carbides, end Nitrides for Ultraclosn Fuels HDS end HDN Cosponsored with Division of Fuel Chemistry SUNDAY AFTERNOON Section A Convention Center Room 395
J. F. Schabron, Organizer 1:30 Introductory Remarks. 1:35 1. Coke predictability maps. J. F. Schabron, J. F. Rovani Jr., A. T. Pauli
MONDAY AFTERNOON Section A Convention Center Room 395 Bio-upgrading of Petroleum L. J . Nash, Organizer 1:30 Introductory Remarks. 1:35 15. Isolation and characterization of thermophilic bacteria from Venezuelan hot spring: Prospects for their application in bioconversion processes. M. Gonzalez, C. Rodriguez, M. G. Gomez, I. E. Ranson 1:55 16. Denitrogenation of carbazole by combined biological and catalytic treat ment. D. C. Brassier, L. A. Kirkpatrick, J. M. Foght, P. M. Fedorak, M. R. Gray 2:15 17. Biocatalytic ring opening of dibenzothiophene and phenanthrene as model substrates dissolved in crude oil. Q. Wu, M. R. Gray, M. Pickard, P. M. Fedorak, J. M. Foght 2:35 18. Investigating the potential of enzymatic PAH oxidation for upgrading oil. A. P. Borate. C. L Cheng, Β. Η. Davison 2:55 Intermission. 3:05 19. Bioprocessing for heavy crude-oil viscosity reduction. K. M. Klrkwood, S. Ebert. D. Kharbanda, J. M. Foght, P. M. Fedorak, M. R. Gray 3:25 20. Bioconversion of aromatics in light gas oil in a continuous bioreactor system. H. K. Kotlar, K. Rasmussen, S. Markussen, A. Winnberg, S. Zotchev, M. Gimmestad 3:45 21. Strong acidic synthesis and characterization of mesoporous silica SBA-3. S. Yu, R. Zhao 4:05 Concluding Remarks.
Section A Convention Center Room 395 Alternative Countermeasures for Oil Spills W. Nichols, Organizer
Stability end Compatibility of Heavy Oils end Residue
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
2:00 2. Oxidation of heavy petroleum streams at ambient temperature. B.Chawla 2:25 3. Preliminary assessment of the TaBoRR process and the stability and compatibility of its products. L E. Brocher, P. Rahimi, T. deBruijn, G.Flaherty 2:50 4. Surface energy studies of SHRP asphalts by AFM. A. T. Pauli, W. Grimes, S. C. H. Huang, R. E. Robertson 3:15 Intermission. 3:25 5. Surface morphological stability modeling of SHRP asphalt. A. T. Pauli, W.Grimes 3:50 6. Acting mechanism of heavy crude-oil fractions on stability of oil-inwater emulsions I: Isolation of functional fractions from heavy crude oil and study of their elemental properties. W. Fan, S. Chen, G. Nan, J. Xiao, S. U 4:15 7. Acting mechanism of heavy crude-oil fractions on stability of oil-inwater emulsions II: The film properties of heavy crude functional components and water system. W. Fan, S. Chen, G. Nan, Y. Song, F. Zhao 4:40 8. Acting mechanism of heavy crude-oil fractions on stability of oil-inwater emulsions III: Effects of pH value on the interfacial properties of heavy crude functional fractions and water system. S. Chen, W. Fan, G. Nan, Y. Menglong, L Shuiping 5:05 Concluding Remarks.
8:00 Introductory Remarks. 8:25 9. Oil-spill dispersants do make some sense: What s all the fuss about? R. Lessard, J. Clark 8:55 10. Development of a testing proto col to determine surface-washing-agent effectiveness. Κ. Μ. Koran, A. T. Venosa, G. A. Sorial 9:25 11. Shoreline surface-washing-agent test and evaluation protocol. D. R. Robertson, L. J. H. Maddox 9:55 Intermission. 10:05 12. Dispersant effectiveness on three oils under various simulated envi ronmental conditions. S. Chandrassksr, G. A. Sorial, J. Weaver 10:35 13. Comparison of the propensity of five oil-dispersion products to disperse and suspend crude oil in the upper uphotic zones of marine environments. M. Bentley 11:05 14. Hydrophobic aerogels for oilspill cleanup. J. G. Reynolds, P. R. Coronado 11:35 Concluding Remarks. Environmental Catalysis by Metal Sulfides, Carbides, end Nitrides for Ultrsclesn Fuels Mechanisms Cosponsored with Division of Fuel Chemistry Plasma Technology snd Catalysis Plasma Catalytic Processes Cosponsored with Catalysis & Surface Science Secretariat
Environmental Catalysis by Metal Sulfides, Carbides, snd Nitrides for Ultrsclesn Fuels New Catalysts Cosponsored with Division of Fuel Chemistry Plasma Technology snd Catalysis Plasma Preparation of Catalysts Cosponsored with Catalysis & Surface Science Secretariat TUESDAY MORNING Section A Convention Center Room 395 Fuel Cleanup Considerations for Fuel Cells S. P. Katikaneni and J. Lamport, Organizers 8:30 Introductory Remarks. 8:35 22. Desulfurization of natural gas and LPG for fuel-cell-reformer applica tions. J. K. Lamport 8:55 23. Catalytic conditioning of sulfurous hydrocarbon fuels for fuel-cell applications. N. Z. Muradov 9:15 24. Development of selective adsor bents for removing sulfur from gasoline for fuel-cell applications. V. Subramani, S. Watanabe. X. Ma, L Sun, C. Song 9:35 Intermission. 9:45 25. Fuel-cell-grade gasoline produc tion by selective adsorption for removing sulfur. V. Subramani, X. Ma, L. Sun, C. Song 10:05 26. Sulfur removal from reformate. X. Wang. T. Krause. R. Kumar 10:25 27. Hydrotreating of cracked naph tha over Ni/HZSM-5 catalyst. C. Yin. R. Zhao, C. Liu
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TECHNICAL PROGRAM 10:45 Concluding Remarks.
WEDNESDAY MORNING
Plasma Technology and Catalysis Plasma Catalytic Processes Cosponsored with Catalysis & Surface Science Secretariat
SectionA
TUESDAY AFTERNOON
General Papers
Section Β
K. W. Plumlee, Organizer
Convention Center Hall H/l-1
9:00 Introductory Remarks. 9:05 43. Evaluation and measurement of tetraethyl lead and impurities by lead207 nuclear magnetic resonance. M. A. Al-Ghamdi, G. D. Martinie, H. Perzanowski, M. A. Jabar 9:25 44. Study of oxygenate and metallane octane enhancers in Saudi Arabian gasolines. F. M. AkShahrani, G. D. Martinie, B. O. Dabbousi 9:45 45. Kinetics of carbonyl sulfide hydrolysis: Studies in propane and other o-alkanes. W. C. Andersen, T. J. Bruno 10:05 46. Visualization of equilibrium FCC catalyst surface by AFM and SEM-EDS. O. Bayraktar, G. Erdogan, E. L. Kugler 10:25 Intermission. 10:35 47. Desulfurization study on an advanced FCC additive. Y. Uu 10:55 48. Novel FCC catalyst for lower naphtha olefin and more diesel yield. C. Liu, Y. Deng, X. Gao, Z. Tan, W. Ding 11:15 49. Interactions between heavy metals and day matrix. C. Liu, Y. Deng, X. Gao, Z. Tang 11:35 Concluding Remarks.
Convention Center Room 395
SectionC Convention Center Room 286
DIVISION OF PHYSICAL CHEMISTRY
Spectroscopy and Dynamics in Liquids Quantum Phenomena B. Bagchi, Presiding
Poster Session K. W. Plumlee and R. D. Gonzalez, Organizers 1:00-4:00 28. Effect of promoters on Pi catalysts for the dry reforming reaction in the pres ence of oxygen. S. M. Stagg-Williams, B. Pant, J. Daniels 29. Fuel cell: SOFC division. S. E. Weiss, J.Y.Ying 30. Composition changes in the cocarbonization of FCC slurry and VR. Q. Zha, Y. Guo, Z. Ye, M. Wu, Y. Zhang 31. 1 7 0 Solid-state NMR studies of faujasite-type zeolites. L. Peng, J. E. Readman, N. Kim, C. P. Grey 32. Aggregate asphaltene structural mod els. J. H. Pacheco-Sénchez, F. Alvarez Ramirez, J. Martinez-Magadan 33. Oxidation of sodium mercaptide with sulfonated cobalt phthalocyanine as catalyst. R. Uu, D. Xia, Y. Xiang, L. Luo 34. Evidence for CO disproportionation over ceria and ceria-zirconia: In situ Raman spectroscopic study· V. V. Pushkarev, V. I. Kovalchuk, J. L. d'ltri 35. Foam characteriztion for underbalanced drilling using optical transmission and interfacial reflection. C. Redden, L. Volk, N. E. Takach, T. Reed, S. Miska 36. Investigation of single-crystalline ZnO surfaces on the atomic level. O. Dulub, U. Diebold 37. Molecular dynamics simulation study of the catalytically active a-AIF3 phase: Structure-property-dynamics relationships from atomistic simulations. S. Chaudhuri, P. Chupas, P. Madden, M. Wilson, C. P. Grey 38. Palladium-group IB sol-gel catalysts for selective hydrodechlorination of 1,2dichloroethane into ethylene. S. Arsenault, R. D. Gonzalez 39. Scanning-tunneling-microscopy study of the anatase(100) surface. N. J. Ruzycki, G. S. Herman, L. A. Boatner, U. Diebold 40. Scanning-tunneling-microscopy study of the effect of subsurface dopants on the adsorption of Chlorine at TiO2(110). B. Katsiev, M. Batzill. U. Diebold 41. Surface structure of Sn02(110). T. Beck, B. Katsiev, M. Batzill, U. Diebold 42. Synthesis of mesoporous metal/Si02 nanoparticles and their catalytic applications. J. E. Hampsey, Q. Hu, S. Arsenault, D. Wang, B. F. McCaughey, Y. Lu Plasma Technology and Catalysis Plasma Preparation of Catalysts Cosponsored with Catalysis & Surface Science Secretariat
Organic Solids in Petroleum Production Cosponsored with Division of Geochemistry Plasma Technology and Catalysis Plasma Catalytic Processes Cosponsored with Catalysis & Surface Science Secretariat
WEDNESDAY AFTERNOON SectionA Convention Center Room 395 General Papers K. W. Plumlee, Organizer 1:30 Introductory Remarks. 1:35 50. Effects of the zeolite framework on the structure and energetics of active site of H-ZSM-5/C6H6 complexes: A QM/MM method. C. Raksakoon, J. Limtrakul 1:55 51. The studies on adsorption states of dibenzothiophene. Y. Xu, C. Liu 2:15 52. Hydrocracking of atmospheric residue by two-stage suspended bed. C. Guan, Z. Wang 2:35 53. Hydrodenitrogenation of quinoline over Ni-Mo/AI203 catalyst modified with fluorine and phosphorus. C. Liu, Y. Yu, H. Zhao 2:55 Intermission. 3:05 54. Hydrodenitrogenation of quinoline over Ni-Mo/AI203 catalyst modified with zinc and zirconium. C. Liu, Y. Yu, H.Zhao 3:25 55. Hydrodenitrogenation of quinoline over Ni-Mo/AI203 catalyst modified with zinc, zirconium, and phosphorus. C. Liu, Y. Yu, H. Zhao 3:45 56. The synthesis and characterization of hexagonal mesoporous silica SBA-3. S. Yu, R. Zhao, C. Guan, C. Yin 4:05 Concluding Remarks. Organic Solids in Petroleum Production Cosponsored with Division of Geochemistry
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J. L. Skinner, Program Chair SUNDAY MORNING SectionA Convention Center Room 283 Iterative Methods in Quantum Mechanics and Applications to Chemical Problems Dynamics Cosponsored with Division of Computers in Chemistry S. K. Gray, Organizer,
Presiding
H. Guo, Organizer 8:30 1. Improved convergence of polynomial representations of Green's operators. D. J. Kouri, A. Vijay 9:10 2. On harmonic inversion of crosscorrelation functions by the filter diagonalization method. V. Mandelshtam 9:50 3. Scalable iterative implementations of the boundary inhomogeneity approach to quantum scattering. D. Reignier, H. Zhang, S. C. Smith 10:30 Intermission. 10:50 4. Recent applications of iterative methods. E. M. Goldfield, Y. He, T. Lu, S. K. Gray 11:30 5. Calculation of resonance emission spectra using a single Lanczos propagation method. D. Xu, R. Chen, D. Xie, H. Guo 11:50 6. Effect of spectral range on the convergence of Lanczos eigenvalues. R. Chen, H. Guo Section Β Convention Center Room 284 New Electronic Structure Methods: From Molecules to Materials Large-Scale Methods and Calculations Cosponsored with Division of Computers in Chemistry M. P. Head-Gordon, Organizer, Presiding E. A. Carter, Organizer 8:30 7. Linear scaling self-consistent-field theory: From molecules to materials. M. Challacombe 9:10 8. Electronic structure studies of semiconductor surface chemistry. K. Raghavachari, M. D. Halls 9:50 9. Combining plane waves and Gaussians in accurate molecular calcu lations. P. Pulay, L. Fusti-Molnâr, J. Baker 10:30 Intermission. 10:50 10. Linear scaling quantum-chemistry methods for periodic systems: Applications to polymers, surfaces, and solids. G. E. Scuseria 11:30 11. Linear scaling indirect diagonalization methods in density functional theory calculations. Y. Shao, C. Saravanan, M. Head-Gordon 11:50 12. Data parallel computation of the exchange-correlation matrix. C. K. Gan, M. Challacombe
B. M. Ladanyi and M. Maroncelli, Organizers 8:30 13. Coupling of environmental and electronic dynamics in excited-state relaxation. P. J. Rossky 9:10 14. Experimental and theoretical studies of model two-electron systems in liquids. B. J. Schwartz 9:50 15. Resonance Raman studies of solvent effects on second-order nonlinear optical chromophores. A. M. Kelley 10:10 16. Migration lengths and reaction rates of the excited states of the hydrated electron. P. F. Barbara 10:30 Intermission. 10:50 17. Dynamics of charged-defect transport in water and methanol from ab initio molecular dynamics. M. E. Tuckerman 11:30 18. New methods for the calculation of spectra and dynamics in condensed-phase quantum environments. D. Reichman Section D Convention Center Room 287 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Synthesis and Fabrication N. Halas and S. K. Buratto, Organizers 8:30 19. Liquid-crystalline phases of anistropic inorganic nanocrystals. A. P. AIMsatos 9:10 20. Seed-mediated growth approach to the synthesis of metallic nanorods and nanowires in aqueous solution. C. J. Murphy 9:50 21. Synthesis and characterization of monodisperse transition-metal-oxide nanocrystals. T. Hyeon, J. Park, J. Joo, S.Kim 10:30 Intermission. 10:50 22. Metal nanoparticle formation in poly(aminohexyl-aminopropyl)silsesquioxane colloids. L. M. Bronstein, C. N. Linton, R. Karlinsey, E. Ashcraft, B. D. Stein, D. I. Svergun, M. B. Kozin, J. W. Zwanziger 11:10 23. Nanoparticles, filaments, fibers, and treelike assemblies prepared by laser-vaporization-controlled condensation. M. S. El-Shall, V. M. Abdelsayed 11:30 24. Laser-induced shape changes in metallodielectric concentric sphere nanoparticles. C. Aguirre, C. Radloff, C. E. Moran, N. J. Halas 11:50 25. Update on Met-Cars: Production, structure, and spectroscopy. M. Lyn, T. Barauh, M. R. Pederson, A. W. Castleman Jr.
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
PETR/PHYS/TECHNICAL PROGRAM
Section Ε
Section Β
Convention Center Room 285
Convention Center Room 284
VUV Probes of Dynamics and Spectroscopy Photodissociation Dynamics
New Electronic Structure Methods: From Molecules to Materials Density-Functional Theory Cosponsored with Division of Computers in Chemistry
T. P. Softley, Presiding A. G. Suits and C. Ng, Organizers 8:30 26. Two-photon photodissociation of NO through Rydberg levels in the 265278-nm region: Spectra and photofrag ment angular distributions. P. L Houston, B. R. Cosofret, H. M. Lambert 9:10 27. Η-atom product channel in the photodissociation of vinoxy radical via the B2A state. J. Zhang 9:50 28. Core-level photoemission spec troscopy: Kinetics of cluster formation during femtosecond laser ablation. E. Glover, G. Ackerman, R. Schoenlein 10:10 29. DC slice imaging. D. Townsend, M. P. Minitti, A. G. Suits 10:30 Intermission. 10:50 30. High-resolution photofragmenta tion studies of hydride molecules and molecular ions. M. N. R. Ashfold 11:30 31. Relativistic effects and intriguing photochemistry in H2Te. J. Underwood, D. Chastaing, S. Lee, P. Boothe, T.C. Flood, CWIttig Integrating Diverse Computational Approaches to Complex Problem Solving Diverse Computational Approaches Cosponsored with Division of Computers in Chemistry Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Cosponsored with Division of Computers in Chemistry
SUNDAY AFTERNOON Section A Convention Center Room 283 Iterative Methods in Quantum Mechanics and Applications to Chemical Problems Electronic Structure Cosponsored with Division of Computers in Chemistry W. H. Thompson, Presiding H. Guo and S. K. Gray, Organizers 1:30 32. Applications of the SPAM itera tive diagonalization method. R. Shepard, A. F. Wagner, M. Minkoff, Y.Zhou 2:10 33. Iterative optimization approach to the calculation of orbital functional in density functional theory. W. Yang, Q.Wu 2:50 34. Large-scale multigrid simulations of novel materials and nanoscale devices. J. Bemholc 3:30 Intermission. 3:50 35. Efficient multiscale methods for solving the Kohn-Sham equations in real space. N. Wljesekera, G. Feng, T.LBeck 4:30 36. Muttiresolution solution of an integral formulation of density functional theory. R. J. Harrison 4:50 37. Ab initio linear scaling electronic structure. R. Baer, M. Head-Gordon, C. Saravanan, W. Z. Liang
G. E. Scuseria, Presiding M. P. Head-Gordon and E. A. Carter, Organizers 1:30 38. The analog of Koopmans' theo rem in DFT. E. J . Baerends 2:10 39. Optimized effective potential made simple. J. P. Perdew, S. V. Kuemmel 2:50 40. The importance of current in time-dependent density functional theory. K. Burke, Ν. Τ. Maitra, R. J. Magyar, E. Sim 3:30 Intermission. 3:50 41. Hartree-Fock calculations on plum pudding. P. M.W. Gill, S. N. Ghosh 4:30 42. Kohn-Sham exact-exchange for atoms and clusters. S. V. Kuemmel, J. P. Perdew 4:50 43. Current-dependent generalization of the Perdew-Burke-Emzerhof func tional: The degenerate term problem. S. N. Maxlmoff, M. Emzerhof, G. E. Scuseria
2:10 53. Dilute magnetic quantum dots. G. F. Strouse 2:50 54. Formation and characterization of linear and branched nanoassemblies of gold nanoparticles on DNA scaffolds by electrostatic assembly in solution. M. G. Warner, E. W. Foster, J. E. Hutchison 3:10 55. Multilayer structures of polyelectrolytes and nanoparticles based on layer-by-layer assembly and LangmuirBlodgett deposition. G. M. Lowman, M. Berrettini, G. A. Khitrov, S. Nelson, G. F. Strouse, S. K. Buratto 3:30 Intermission. 3:50 56. Producing discrete and more complex nanoparticle arrangements using asymmetric branched DNA trimers. S. C. Williams, S. L. Goh, C. M. Micheel, D. Zanchet, W. J. Parak, D. Gerion, A. P. Alivisatos 4:10 57. Mask-free passivative stamp lithography: Fabrication and optical properties of large-area periodic submicron metal structures. N. Halas, C. E. Moran, J. M. Steele, C. Radloff. C. Aguirre Section Ε Convention Center Room 285 VUV Probes of Dynamics and Spectroscopy Photoionization Spectroscopy
MONDAY MORNING Section A Convention Center Room 283 Iterative Methods in Quantum Mechanics and Applications to Chemical Problems Dynamics Cosponsored with Division of Computers in Chemistry R. Chen, Presiding H. Guo and S. K. Gray, Organizers 8:30 64. A two-grid Maxwell wavepacket approach for photonic crystals. D. Neuhauser, R. Baer 9:10 65. Calculation of highly excited vibrational states: Use of the Davidson algorithm. F. Ribeiro, C. lung, C. J. Leforestier 9:50 66. A preconditioned projection method for the numerical solution of large-scale eigenvalue problems. R. Lehoucq, J. S. Warsa 10:30 Intermission. 10:50 67. Two-layer Lanczos iterative diagonalization. H. Yu 11:30 68. Theoretical and computational approaches for solving the coupled quantum/classical equations of motion in studies of reaction dynamics. A. B. McCoy, F. Chen
E. R. Grant, Presiding Section Β
Section C A. G. Suits and C. Ng, Organizers Convention Center Room 286 Spectroscopy and Dynamics In Liquids Solvation and Solute Dynamics J. Cao, Presiding B. M. Ladanyi and M. Maroncelli, Organizers 1:30 44. Spectroscopy and dynamics of polarizable chromophores in molecular solvents. D. Matyushov 2:10 45. Solvent dynamics in the excitedstate evolution of transition-metal com plexes. J. K. McCusker 2:30 46. Solvent control of intramolecular electron-transfer rates. C. H. Londergan, C. P. Kubiak, M. Maroncelli 2:50 47. Solvent influence on intramolecu lar charge transfer. S. M. Harrel, G.M. Turner, M.C. Beard, C. A. Schmuttenmaer 3:30 Intermission. 3:50 48. Direct ultrafast probing of the local environment during dynamic events in solution. D. A. Blank, D. F. Underwood 4:10 49. Resonance Raman spectroscopy as a tool for studying solvent dynamics. J. L McHale, X. Zhao, J. A. Burt 4:30 50. Long-lived solute rotational excitation in room-temperature liquids. A. C. Germaine Moskun, S. E. Bradforth 4:50 51. Short-time dynamics of reaction kinetics. G. Goodyear
1:30 58. A divertimento in thermochemis try: From photoionization spectroscopy of radicals to active tables. B. Rueclc 2:10 59. Examining cation-potential energy surfaces using ΜΑΤΙ and PIRI. P. M. Johnson, A. B. Burrill 2:50 60. A new route to the dissociation energy of ionic and neutral HCI via lineshape analysis of single-rotational transitions. K. Wertzel, M. Michel, M. V. Korolkov 3:10 61. Vacuum ultraviolet laser-pulsed field-ionization photoelectron spectros copy of ds/trans~C2H2®2 and C2HCI3. H. Woo, K. C. Lau, J. Zhan, C. Ng. Y. Cheung, W. U 3:30 Intermission. 3:50 62. Autoionization-detected infrared spectroscopy of bare molecular cations. A. Fujii 4:30 63. Mass-analyzed threshold ioniza tion spectroscopy of selected aromatic molecules: Isotopomers, rotamers, and structural isomers. W. Tzeng Integrating Diverse Computational Approaches to Complex Problem Solving Toward Higher Accuracy: Development and Applications Cosponsored with Division of Computers in Chemistry Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Excited-State Geometries from TDDFT: Multlreference TDDFT Cosponsored with Division of Computers in Chemistry
Convention Center Room 284 New Electronic Structure Methods: From Molecules to Materials Molecular Problems Cosponsored with Division of Computers in Chemistry V. A. Rassolov, Presiding M. P. Head-Gordon and E. A. Carter, Organizers 8:30 69. Electron correlation methodology from a basis set perspective. A. K. Wilson 9:10 70. Assessing the performance of quantum chemical methods for bond breaking. C. D. Sherrill 9:50 71. How diradicaloid is a stable diradical? Y. Jung, M. Head-Gordon 10:10 72. Parallel analytic gradient imple mentation for open-shell perturbation theory using the distributed data inter face. C. M. Aikens, M. S. Gordon 10:30 Intermission. 10:50 73. The computation of chiroptical properties bytime-dependentdensity functional theory. T. Ziegler, J. Autschbach 11:30 74. Predicted energetics, kinetics, and dynamics of dimethyl ether's lowtemperature autoignition. A. Andersen, E. A. Carter 11:50 75. Electronically excited states of CH2CI: Rydberg-valence interactions and their effect on photodissociation yield. S. V. Levchenko, A. I. Krylov Section C
Section D Convention Center Room 286
Convention Center Room 287
Physical Chemistry of Biomolecular Motors Rotatory Motors Cosponsored with Division of Computers in Chemistry
Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Synthesis and Fabrication N. Halas and S. K. Buratto, Organizers 1:30 52. PbSe quantum dots and quan tum cubes. C. B. Murray, K. L. Stokes, K.Cho
Q. Cui, Organizer,
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Presiding
C. Bustamante, Organizer 8:30 76. Development of the concept of rotational catalysis by the ATP synthase. P. D. Boyer
TECH-113
TECHNICAL PROGRAM 9:10 77. The rotary mechanism of ATP synthase. J. E. Walker 9:50 78. How F^TPase functions: Some insights from simulations. M. Karplus 10:30 Intermission. 10:50 79. Chemo-mechanical coupling in F r ATPase revealed by single-molecule physiology. K. Kinosita Jr. 11:30 80. Asymmetry in the binding site explains the observed pauses in the power-stroke of F r ATPase. S. Sun Section D Convention Center Room 287 Spectroscopy and Dynamics in Liquids Solute-Solvent Dynamics in Complex Environments R. A. Walker, Presiding B. M. Ladanyi and M. Maroncelli, Organizers 8:30 81. Solvation and rotation dynamics at liquid interfaces. K. B. Eisenthal, A. V. Benderskii, X. Shang 9:10 82. Microscopic dynamics of liquid mixtures. J. T. Fourkas, A. Scodinu 9:30 83. Diffusional sampling of the energy landscape: Polar solvation dynamics in Zn(ll)-substituted cyto chrome c. S. Lampa-Pastirk, R. C. Lafuente, K. L. Dillman, E. A. Carson, K. R. Shelly, W. F. Beck 9:50 84. Water dynamics in the hydration layer of biomolecules and self-assembly. B. Bagchi 10:30 Intermission. 10:50 85. Friction, dynamics, and length scales in hydrophilic polymers. E. W. Castner Jr., B. J. Lee, E. G. Diken, H. Shirota, M. DeRitter, P. P. Wiewior, J. W. Locasale 11:30 86. Solvation dynamics in oligo nucleotides. M. A. Berg, M. Somoza, D. V. Khudyakov, L Gearheart, R. S. Coleman, C. J. Murphy Section Ε Convention Center Room 285 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Enhanced Raman Spectroscopy N. Halas and S. K. Buratto, Organizers 8:30 87. Nanoparticle optics: Single silver nanoparticles as chemical sensors. R. P. Van Duyne, A. D. McFarland 9:10 88. Raman spectroscopy of single molecules using the help of gold and silver nanoparticles. K. Kneipp 9:50 89. Nanoparticle surface-enhanced Raman spectroscopy as local probes of biomolecular properties. T. R. Huser, C. E. Talley, C. W. Hollars, S. M. Lane 10:30 Intermission. 10:50 90. Controlling the surface-en hanced Raman effect on nanoshells in a film geometry. J. B. Jackson, N. J. Halas 11:10 91. Concentric nanoshells and hybridized plasmons. N. J. Halas, C. Radloff
114-TECH
11:30 92. Tip-enhanced Raman spectros copy from metal nanoclusters formed by nanosphere lithography. J. P. Schmidt, S. K. Buratto
4:30 103. Time propagation of the density matrix for dissipative dynamics: Photodesorption by femtosecond pulses. D. A. Micha, A. Santana
Section F
Section Β
Convention Center Room 277
Convention Center Room 284
VUV Probes of Dynamics and Spectroscopy Photodissociation Dynamics
New Electronic Structure Methods: From Molecules to Materials Hybrid Methods and Condensed-Phase Problems Cosponsored with Division of Computers in Chemistry
D. M. Neumark, Presiding A. G. Suits and C. Ng, Organizers 8:30 93. Coherent control of the photodis sociation of vinyl chloride. V. Barge, A. Khachatrian, R. Billotto, J. C. Willig, L. Zhu, R. J. Gordon 9:10 94. Photodissociation of CS2 as a function of wavelength: Vacuum ultravio let state-selective ionization and velocity map imaging. W. M. Jackson, D. Xu, J. Huang 9:50 95. Deflection and deceleration of hydrogen Rydberg molecules. T. P. Softley, S. Procter, Y. Yamakita, F. Merkt 10:10 96. Photophysics of uracil and thymine bases in the gas phase. Y. He, C. Wu, W. Kong 10:30 Intermission. 10:50 97. UV photodissociation dynamics of atmospheric species using VUV detection. S. W. North 11:30 98. VUV probing of ion-pair photodissociation. J. W. Hepburn, Q. Hu Integrating Diverse Computational Approaches to Complex Problem Solving Kinetics, Dynamics, and Reactivity Cosponsored with Division of Computers in Chemistry Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Evaluation of TDDFT for UV-vis: Computation of NMR Coupling Constants Cosponsored with Division of Computers in Chemistry Protein Flexibility Theory Cosponsored with Division of Computers in Chemistry Present and Future Technologies in Chemical Instrumentation Cosponsored with Division of Analytical Chemistry MONDAY AFTERNOON Section A Convention Center Room 283 Iterative Methods in Quantum Mechanics and Applications to Chemical Problems Mixed Cosponsored with Division of Computers in Chemistry J. T. Muckerman, Presiding H. Guo and S. K. Gray, Organizers 1:30 99. Using contracted basis functions with a Lanczos eigensolver to compute vibrational levels of methane. T. Carrington Jr., X. Wang 2:10 100. Lanczos algorithms and crosscorrelation functions. H. O. Karlsson 2:50 101. Reaction dynamics with the Gray-Balint-Kurti approach. C. Petrongolo, P. Defazio, S. K. Gray, F. Santoro 3:30 Intermission. 3:50 102. Preconditioning iterative quan tum chemistry methods by exploiting the weak coupling of different length scales. S. Goedecker
A. I. Krylov, Presiding M. P. Head-Gordon and E. A. Carter, Organizers 1:30 104. Exploring free-energy surfaces for biological systems. Q. Cui 2:10 105. Incorporation of nuclear quan tum effects in electronic structure calcu lations: Multiconfigurational nuclearelectronic orbital method. S. Hammes-Schiffer 2:50 106. Using novel sampling, parallel computers, and new algorithms to advance ab initio molecular dynamics. G. Martyna 3:30 Intermission. 3:50 107. Toward charge transfer across QM/MM boundaries. T. J. Martinez, A. Toniolo, J. A. Morales, B. Levine 4:30 108. Full vibrational averaging of computed NMR chemical shieldings. G. S. Harbison, Y. Kye, X. Zhao, C. Guo, X. Wu 4:50 109. Toward the reliable computation of weak interactions in large chemical and biochemical systems with integrated quantum mechanical methods. G. S. Tschumper Section C Convention Center Room 286 Physical Chemistry of Biomolecular Motors Processive Motors Cosponsored with Division of Computers in Chemistry S. Sun, Presiding Q. Cui and C. Bustamante, Organizers 1:30 110. Energetics of the kinesin cycle. R. Cooke 2:10 111. Mechanisms of kinesin motility. R. Fletterick 2:50 112. Structure and dynamics of macromolecular machines revealed by signal processing of multiresolution data. W. Wriggers, Y. Cong, P. Chacon, J. Kovacs 3:30 Intermission. 3:50 113. New computational method for simulating large molecular complexes. J. Ma 4:30 114. Stochastic models with waitingtime distributions for translocatory motor proteins. A. B. Kolomeisky, M. E. Fisher Section D Convention Center Room 287 Spectroscopy and Dynamics in Liquids Liquid Interfaces and Confined Liquids
2:50 117. Solvent polarity across liquid/ liquid interfaces. R. A. Walker, W. H. Steel, C. Beildeck 3:10 118. Spectroscopy and reactivity in nanoconfined solvents. W. H. Thompson 3:30 Intermission. 3:50 119. Spectroscopy and dynamics in nanobeakers. N. E. Levinger 4:30 120. Vibrational energy relaxation of aqueous azide ion confined in reverse micelles. J. C. Owrutsky, Q. Zhong, A. P. Baronavski 4:50 121. Hydrophobic and hydrophilic effects in confined systems. J. C. Rasaiah, A. Waghe, S. Vaitheeswaran, J. P. Noworyta, G. Hummer Section Ε Convention Center Room 285 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Excited-State Dynamics N. Halas and S. K. Buratto, Organizers 1:30 122. Relaxation dynamics of photogenerated electrons and holes in quan tum dots and applications to photon conversion in quantum dot solar cells. A. J. Nozik, R. J. Ellingson, J. L Blackburn, O. I. Micic, G. Rumbles 2:10 123. Dynamics of dendrimer metal nanocomposites and metal nanopar ticles. T. Goodson III 2:50 124. Pseudopotential theory of electronic processes in colloidal CdSe quantum dots. M. Califano, A. Zunger 3:30 Intermission. 3:50 125. Probing interparticle interaction and doping in nanomaterials. J. Z. Zhang 4:30 126. Spectroscopy and relaxation dynamics in GaSe nanoparticles. D. F. Kelley, V. Chikan 4:50 127. Directed energy flows in engi neered quantum dot assemblies. M. Achermann, J. A. Hollingsworth, M. A. Petruska, S. A. Crooker, V. I. Klimov Section F Convention Center Room 277 VUV Probes of Dynamics and Spectroscopy Photoionization Spectroscopy A. G. Suits and C. Ng, Organizers 1:30 128. Complete two-electron spectra from photoionization of atoms and molecules. J. H. D. Eland 2:10 129. Recent developments in vector correlation studies of dissociative photo ionization of polyatomic molecules induced by VUV-polarized synchrotron radiation. D. Dowek, M. Lebech, J. C. Houver, R. R. Lucchese 2:50 130. Wagging the dog: Mode speci ficity in vibrationally resolved polyatomic photoionization. E. D. Poliakoff 3:30 Intermission. 3:50 131. Multiple ionization of clusters by intense VUV radiation from a freeelectron laser. T. Moeller 4:30 132. Double-resonance studies of photoionization dynamics in small mol ecules. S. T. Pratt
J. Fourkas, Presiding B. M. Ladanyi and M. Maroncelli, Organizers 1:30 115. Dynamics at polar liquid sur faces. I. Benjamin 2:10 116. Understanding molecular inter actions at liquid surfaces: Spectroscopy and simulations. G. L. Richmond
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
PHYS/TECHNICAL PROGRAM
Protein Flexibility Coupling Motion and Catalysis Cosponsored with Division of Computers in Chemistry Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods TDDFT Spectra of Inorganic Complexes Cosponsored with Division of Computers in Chemistry
Section Β Convention Center Room 283 New Electronic Structure Methods: From Molecules to Materials Many-Body Theory Cosponsored with Division of Computers in Chemistry A. K. Wilson, Presiding
Integrating Diverse Computational Approaches to Complex Problem Solving Biological Applications Cosponsored with Division of Computers in Chemistry Colloidal and Molecular Electro-Optics Advances in Methodology Cosponsored with Division of Colloid and Surface Chemistry MONDAY EVENING Section A Convention Center Hall G Sci-Mix J. L. Skinner, Organizer 8:00-10:00 242, 257-259, 262, 264-266, 271, 274-276, 278-279, 283, 285-286, 289-290, 292, 297, 300, 302-304, 313, 315, 320-321, 326, 328-329, 342, 347, 349, 353-354, 370, 373, 381, 383, 386-389, 395, 398-401, 405, 408-409, 413-415, 417418, 421, 427, 430, 433, 437, 439, 442, 444, 450, 455-457, 460-461, 465. See subsequent listings. Colloidal and Molecular Electro-Optics General Poster Sessions Cosponsored with Division of Colloid and Surface Chemistry
TUESDAY MORNING Section A
Section Ε 8:30 138. New alternatives for accurate electronic-structure calculations of molecular potential energy surfaces. P. Piecuch, K. Kowalski, I. S. O. Pimienta, P. Fan 9:10 139. Advanced electronic structure methods and redundant localized orbitals. M. Nooijen, A. Auer 9:50 140. Occupation restricted multiple active space-CI/SCF. J. Ivanic 10:10 141. Analytic energy gradients for GVVPT2 multireference perturbation theory. T. J. Dudley, Y. G. Khait, M. R. Hoffmann 10:30 Intermission. 10:50 142. Breaking the curse of the nondynamical correlation problem: The spin-flip method applied to diradicals and triradicals. A. I. Krylov, L V. Slipchenko 11:30 143. Fast local active space coupled cluster approximations. G. J. O. Beran, M. Head-Gordon 11:50 144. Local correlation in the virtual space in multireference configuration interaction. A. Venkatnathan, D. Walter, E. A. Carter Section C Convention Center Room 286 Physical Chemistry of Biomolecular Motors Rotatory Motors Cosponsored with Division of Computers in Chemistry
Iterative Methods in Quantum Mechanics and Applications to Chemical Problems Mixed Cosponsored with Division of Computers in Chemistry Presiding
S. K. Gray, Organizer 8:30 133. Molecular vibrations: Iterative solution with energy-selected bases. J. C. Light, H. Lee 9:10 134. Using optimized preconditioning to greatly reduce the number of itera tions for quantum calculations at high energies. L. W. Poirier 9:50 135. Quantum-dynamics calculations based on a polyspherical parametrization of the N-atom system. F. Gatti, C. lung 10:30 Intermission. 10:50 136. Time development of popula tion inversion in a chemical laser reac tion. R. S. Dumont, W. Sedik 11:30 137. Iterative density-matrix strate gies in linear scaling first principles electronic structure calculations. A. M. N. Niklasson
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Convention Center Room 285 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Single-Nanoparticle Spectroscopy N. Halas and S. K. Buratto, Organizers 8:30 155. Semiconductor nanocrystals: From blinking to lasing. V. C. Sundar, H. Eisler, M. G. Bawendi, K. T. Shimizu, W. K. Woo 9:10 156. Power law fluorescence behav ior in single semiconductor quantum dots. D. J. Nesbitt 9:50 157. Auger processes in nanosize semiconductor crystals. A. Efros 10:30 Intermission. 10:50 158. Nonlinear chemical imaging microscopy of nanoparticles. R. J. Saykally 11:30 159. Spectroscopy and AFM char acterization of individual nanoscale aggregates of conjugated molecules. S. Lim, T. G. Bjorklund, C. J. Bardeen 11:50 160. Theory of time-dependent fluctuations in single-molecule spectros copy. E. J. Barkai, Y. Jung, R. J. Silbey Section F Convention Center Room 277
J. Ma, Presiding Q. Cui and C. Bustamante, Organizers
Convention Center Room 282
H. Guo, Organizer,
M. P. Head-Gordon and E. A. Carter, Organizers
9:50 151. Solvation in water and ionic liquids. H. J. Kim 10:30 Intermission. 10:50 152. Solvent control of intramolecu lar charge transfer in ADMA. J. F. Kauffman, N. Saleh, M. Khajehpour 11:30 153. Hydrogen bond dynamics in supercritical water. A. Luzar 11:50 154. Photoisomerization of diphenylpolyenes: A prototype unimolecular reaction? J. Schroeder, C. Grimm, C. Miiller, T. Steinel, J. Zerbs
8:30 145. On what governs sequential firing of catalytic sites when F r ATPases hydrolyzes ATP. W. S. Allison, S. Bandyopadhayay, H. Ren 9:10 146. Protein-nucleotide and proteinprotein interactions in ATP synthase. J. Weber, A. E. Senior 9:50 147. The energetics of ATP syn thase: Conversion of the conformational changes to electrostatic energies. M. Strajbl, A. Shurky, A. Warshel 10:30 Intermission. 10:50 148. "Grabbing the cat by the tail": studies of DNA packaging by single 29 bacteriophage particles using optical tweezers. C. Bustamante Section D Convention Center Room 287 Spectroscopy and Dynamics in Liquids Supercritical Fluids and Density Dependence M. Maroncelli, Organizer,
Presiding
Β. Μ. Ladanyi, Organizer 8:30 149. Chemical equilibrium in super critical fluids: Solvent effects on the dimerization equilibrium constant. S. Egorov 9:10 150. Intra- and intermolecular vibra tional energy flow in bridged azulenearyl compounds. D. Schwarzer
VUV Probes of Dynamics and Spectroscopy Reaction Dynamics M. Ahmed, Presiding A. G. Suits, L Balbes, and C. Ng, Organizers 8:30 161. C-C and C-H bond activation in neutral transition-metal-hydrocarbon reactions. H. F. Davis, R. Z. Hinrichs, J. J. Schroden 9:10 162. Pulsed-field ionization photoelectron spectroscopy of metal com plexes. D. Yang 9:50 163. Imaging Η abstraction dynamics with single-photon ionization. A. G. Suits, X. Liu, R. L. Gross 10:10 164. Gas-phase kinetics and dynamics at extremely low tempera tures: Obtaining data for astrochemistry using VUV techniques. I. R. Sims 10:30 Intermission. 10:50 165. Crossed-molecular-beam studies on F + CD4 -> DF (v) + CD3 (v2) by a 3-D ion velocity imaging technique. J. J. Lin, J. Zhou, W. C. Shiu, K. Liu 11:30 166. VUV probes of photoinduced reactions on metal surfaces. M. G. White, M. Tan Colloidal and Molecular Electro-Optics Theoretical Aspects Cosponsored with Division of Colloid and Surface Chemistry
Integrating Diverse Computational Approaches to Complex Problem Solving Biological Applications Cosponsored with Division of Computers in Chemistry Protein Flexibility Inhibitor Discovery Techniques Cosponsored with Division of Computers in Chemistry
TUESDAY AFTERNOON Section A Convention Center Room 283-285 Physical Chemistry Award Symposium Cosponsored with Women Chemists Committee J. L. Skinner, Organizer, Presiding 1:30 167. Award Address (E. Bright Wilson Award in Spectroscopy, spon sored by Rohm and Haas Co). Shed ding light on neutral and ionic combus tion reaction intermediates. M. E. Jacox 2:10 168. Award Address (ACS Award in Theoretical Chemistry, sponsored by IBM Corp). Quantum chemistry in the 21st century. H. F. Schaefer III 2:50 169. Award Address (ACS Award for Research at an Undergraduate Institution, sponsored by Research Corp). Electronic states of long poly enes. R. L. Christensen 3:30 Intermission. 3:50 170. Award Address (Peter Debye Award in Physical Chemistry, sponsored by E. I. du Pont de Nemours & Co). Using semiclassical theory to add quan tum effects to classical molecular dynamics simulations. W. H. Miller 4:30 171. Award Address (Joel Henry Hildebrand Award in the Theoretical and Experimental Chemistry of Liquids, sponsored by ExxonMobil Research and Engineering Co. and ExxonMobil Chemi cal Co). Scaling and charged fluids: From simple electrolytes to the hydrogen fuel cell. L. Blum Colloidal and Molecular Electro-Optics Rigid Particles Cosponsored with Division of Colloid and Surface Chemistry
WEDNESDAY MORNING Section A Convention Center Room 283 Physical Chemistry of Biomolecular Motors Processive Motors Cosponsored with Division of Computers in Chemistry A. B. Kolomeisky, Presiding Q. Cui and C. Bustamante, Organizers 8:30 172. Understanding kinesin's proces sive motility. L. M. Klumpp, A. Hoenger, J. M. Rosenberg, S. P. Gilbert 9:10 173. Describing the dynamics of kinesin and myosin-V. M. E. Fisher 9:50 174. Mechanism of the microtubulestimulated ATPase of the kinesin superfamily member BimC and its implications for processivity. D. D. Hackney 10:30 Intermission. 10:50 175. Bridging the gap: From micro scopic theory to phenomenological models of motor proteins. H. Qian 11:30 176. Molecular simulations of molecular motors. Q. Cui
Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Cosponsored with Division of Computers in Chemistry
TECH-115
TECHNICAL PROGRAM Section Β
Section D
Convention Center Room 284
Convention Center Room 287
Sequence-Dependent Curvature and Deformation in Nucleic Acids and Protein-Nucleic Acid Complexes RNA Folding/Structure
Structure-Function Correlation for Biological Ion Channels
N. L. Greenbaum, Presiding
A. Warshel, Organizer
N. C. Stellwagen and U. Mohanty, Organizers
8:30 190. Modeling ionic permeation in narrow channels. P. C. Jordan, V. L. Dorman, S. Garofoli 9:10 191. Computer simulations of selec tivity and permeation of ions in physi ological membrane channels. D. Henderson, D. D. Busath, Y. Yang, D. Boda 9:50 192. Microscopic free-energy calcu lations on ion permeation, selectivity, and blocking in potassium channels. J. Aqvist, V. B. Luzhkov 10:30 Intermission. 10:50 193. Simulating ion current and selectivity in realistic models of the KcsA potassium channel. A. Burykin, M. Kato, A. Warshel 11:30 194. Ion transport in restricted environments. A. Nitzan, M. Kumikova, P. Graf, R. D. Coalson, W. Dieterich
8:30 177. Monovalent cations mediate formation of native tertiary structure by the Tetrahymena thermophila ribozyme: Implications for the folding kinetics. M. Brenowitz, K. Takamoto, S. Morris, T. Uchida, I. Shcherbakova, M. R. Chance 9:10 178. Folding of catalytic RNA mol ecules. D. M. J. Lilley 9:50 179. Physical basis for the selfchaperoning activity of an RNA col lapsed state. Κ. Μ. Weeks, K. L. Buchmueller 10:30 Intermission. 10:50 180. Biophysical studies of telomerase RNA structure and mutations linked to disease. J. Feigon 11:30 181. Structure of the spliceosomal pre-mRNA branch site duplex defined by a conserved pseudouridine residue. N. L. Greenbaum, M. I. Newby 11:50 182. Structural perturbations in disease-related human tRNAs. S. O. Kelley, L. M. Wittenhagen, M. D. Roy Section C Convention Center Room 286 Spectroscopy and Dynamics in Liquids Coherent Spectroscopies: Vibrational Dynamics A. M. Kelley, Presiding B. M. Ladanyi and M. Maroncelli, Organizers 8:30 183. Two-color three-pulse photon echo spectroscopy. G. R. Fleming, B. S. Prall, M. Yang, D. Y. Parkinson 9:10 184. What fifth-order Raman spec troscopy tells us about molecular motion in liquids. R. M. Stratt, A. Ma 9:50 185.1-D and 2-D polarization response spectroscopy studies of solva tion. S. Park, J. Kim, N. F. Scherer 10:30 Intermission. 10:50 186. Nonlinear spectra of liquids. J. Wu, S. Yang, J. Cao 11:10 187. Vibrational dynamics of liquid water observed by vibrational echo peak shift spectroscopy. C. J. Fecko, J. J. Loparo, J. D. Eaves, P. L. Geissler, A. Tokmakoff 11:30 188. Novel approaches to vibra tional energy relaxation in liquids. E. Geva, Q. Shi 11:50 189. Vibrational energy relaxation of selectively excited aromatic molecules in solution: The effect of a methyl rotor and its chemical substitution. B. Abel
B. Eisenberg, Presiding
10:30 Intermission. 10:50 204. Narrowband XUV lasers and the study of molecular hydrogen. W. Ubachs 11:30 205. Spectroscopic studies of small hydrides and their ions by high-resolu tion threshold ionization. F. Merkt, S. Willitsch, U. Hollenstein, R. Seiler, T. P. Softley Colloidal and Molecular Electro-Optics Polymers and Polyelectrolytes Cosponsored with Division of Colloid and Surface Chemistry
Section C Integrating Diverse Computational Approaches to Complex Problem Solving Materials and Diverse Approaches Cosponsored with Division of Computers in Chemistry Protein Flexibility Large Systems Cosponsored with Division of Computers in Chemistry
WEDNESDAY AFTERNOON Section A
Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Single-Nanoparticle Spectroscopy
Convention Center Room 283 New Electronic Structure Methods: From Molecules to Materials Alternative Approaches Cosponsored with Division of Computers in Chemistry P. M. W. Gill, Presiding
N. Halas and S. K. Buratto, Organizers 8:30 195. Spectroscopy of single isolated polymer chains and the dynamics of delocalized charges in organic thin films. P. F. Barbara 9:10 196. Photon antibunching from single nanoparticles. D. Bussian, D. Sirbuly, M. Michael, M. Summers, G. Strouse, S. Buratto 9:30 197. Dark excitons in CdS nanocrystals. Z. Yu, D. B. O'Connor, P. F. Barbara, J. Li, L. Wang 9:50 198. Electronic and optical properties of metallic nanoshells. P. J. Nordlander, E. Prodan 10:30 Intermission. 10:50 199. Localized charge properties of individual CdSe quantum rods. T. D. Krauss, R. Krishnan, M. A. Hahn, P. M. Fauchet 11:30 200. Quantitative noncontact elec trostatic force imaging of nanocrystal charge and polarizability. O. Cherniavskaya, L. Chen, L. E. Brus Section F Convention Center Room 277 VUV Probes of Dynamics and Spectroscopy High-Resolution Spectroscopy
M. P. Head-Gordon and E. A. Carter, Organizers 1:30 206. Model chemistry based on strongly orthogonal geminals. V. A. Rassolov 2:10 207. Auxiliary field Monte Carlo for electronic structure. R. Baer, S. Jacoby, D. Neuhauser 2:50 208. Multiresolution quantum chem istry in multiwavelet bases. R. J. Harrison, G. Beylkin, G. I. Fann 3:30 Intermission. 3:50 209. Quantum chemistry without wave functions: Direct determination of the two-particle reduced density matrix. D. A. Mazziotti 4:30 210. Natural orbital functionals and the Hartree-Fock-Bogoliubov method. V. N. Staroverov, G. E. Scuseria 4:50 211. Ab initio simulations of Raman and hyper-Raman spectra. B. Champagne Section Β Convention Center Room 284 Physical Chemistry of Biomolecular Motors Supermolecular Assemblies Cosponsored with Division of Computers in Chemistry W. Wriggers, Presiding
K. Weitzel, Presiding Q. Cui and C. Bustamante, Organizers A. G. Suits and C. Ng, Organizers 8:30 201. Laser-synchrotron radiation combination studies of molecular ioniza tion and dissociation. K. Mitsuke 9:10 202. Spectroscopy and dynamics of triatomic molecular ions: Experimental and theoretical investigations. M. Hochlaf, C. Y. Ng, J. Liu 9:50 203. Two-color photoionization spectroscopy using high-resolution vacuum-ultraviolet synchrotron radiation and an infrared optical parametric oscil lator. A. Kung, X. Qian, T. Chang, C. Ng
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Convention Center Room 286 Sequence-Dependent Curvature and Deformation in Nucleic Acids and Protein-Nucleic Acid Complexes DNA and Ions/Bending N. C. Stellwagen, Organizer,
Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Cosponsored with Division of Computers in Chemistry
Section Ε Convention Center Room 285
3:30 Intermission. 3:50 215. Probing the enzymatic activity of a single molecular motor on DNA with a novel flow-stretching technique. A. M. van Oijen, X. S. Xie 4:10 216. Single-molecule study of the mechanism of pausing and arrest during continuous elongation by E. coli RNA polymerase. D. Izhaky, N. R. Forde, G. Woodcock, C. Bustamante 4:30 217. Statistics in single-molecule protein folding and reaction dynamics. J. Wang
1:30 212. Molecular interactions of biomo lecular motors. J. A. McCammon 2:10 213. Exploring large-scale structural rearrangements in viruses, the ribosome, and other molecular machines. C. L Brooks III, F. Tama 2:50 214. Conformational rearrangments in DNA polymerase β-related to fidelity in DNA synthesis. T. Schlick
Presiding
U. Mohanty, Organizer 1:30 218. DNA: All bent out of shape. L. D. Williams 2:10 219. DNA bending and flexibility in simple and not-so-simple systems. L. J. Maher III 2:50 220. DNA-cation interactions in crystal structures of nucleic acid duplexes. M. Egli 3:30 Intermission. 3:50 221. Tiny telomere DNA. J. B. Chaires, J. Li, J. O. Trent 4:30 222. NMR studies of sequencespecific binding of counterions to β-DNA. F. Cesare Marincola, V. P. Denisov, B. Halle 4:50 223. DNA sequence-dependent curvature and flexibility in stability and organization of nucleosomes. P. De Santis, M. Savino, A. Scipioni, C. Anselmi Section D Convention Center Room 287 Spectroscopy and Dynamics in Liquids Vibrational Dynamics and Spectra J. L. McHale, Presiding B. M. Ladanyi and M. Maroncelli, Organizers 1:30 224. Ultrafast motion of water mol ecules near ions. H. J. Bakker 2:10 225. Vibrational dynamics in liquid water. J. L. Skinner 2:50 226. Multidimensional coherent infrared spectroscopies: Femtosecond snapshots of vibrational coherence. S. Mukamel, A. M. Moran, T. Hayashi, R. Venkatramani, J. Dreyer 3:30 Intermission. 3:50 227. Hydrogen bond dynamics in alcohols. M. D. Fayer, K. J. Gaffney, I. R. Piletic 4:30 228. Coherent vibrational dynamics of coupled hydrogen bonds in carboxylic acid dimers in the liquid phase. K. Heyne, N. Huse, E. T. J. Nibbering, T. Elsaesser 4:50 229. Determination of the hydrogen bond volume from Raman spectra of HDO in H 2 0 to 10 kbar. G. E. Walrafen
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
PHYS/TECHNICAL PROGRAM
Section Ε Convention Center Room 285 Structure-Function Correlation for Biological Ion Channels A. Nitzan, Presiding B. Eisenberg and A. Warshel, Organizers
WEDNESDAY EVENING Section A Convention Center Hall J Physical Chemistry Poster Session Theoretical Methods and Algorithms J. L. Skinner, Organizer
7:30-10:00 1:30 230. Mechanism for large-ion selec tivity in ion channels. W. F. Nonner, D. Gillespie, B. Eisenberg, D. Henderson 2:10 231. The role of dielectric self-energy in ion permeation through narrow protein channels. R. D. Coalson, M. Kumikova, A. Nitzan, A. Mamonov 2:50 232. Spanning multiple time scales in ion-channel dynamics by atomistic molecular simulations combined with electrodiffusion theory. M. Kurnikova, A. Mamonov, A. Nitzan, R. D. Coalson 3:30 Intermission. 3:50 233. Computing ion flux in biological ion channels using drift-diffusion and density functional theory. D. Gillespie, W. F. Nonner, B. Eisenberg 4:30 234. Ion selectivity in ion channel as a challenge for electrostatic modeling of proteins. A. Warshel Section F Convention Center Room 277 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Luminescence and Lasing N. Halas and S. K. Buratto, Organizers 1:30 235. Spectroelectrochemistry of semiconductor nanocrystals. P. Guyot-Sionnest, C. Wang, B. Wehrenberg 2:10 236. Excitons and biexcitons con fined in three dimensions: From funda mental photophysics to lasing applica tions of semiconductor nanocrystals. V. I. Klimov 2:50 237. Lasing in disordered nanopar ticles. H. Cao 3:30 Intermission. 3:50 238. Harnessing Ag nanocluster dynamics for nanotechnology. R. M. Dickson, T. Lee 4:30 239. Efficient luminescence from stabilized Ag nanoclusters. T. J. Kempa, R. A. Farrer, J. T. Fourkas 4:50 240. Novel II—VI semiconductor gain media: From ASE to lasing. V. C. Sundar, H. Eisler, M. G. Bawendi, T. Deng, E. L. Thomas 5:10 241. Nanocrystal quantum dot assemblies: Controlling electronic and photonic interactions. M. A. Petruska, A. V. Malko, H. Htoon, M. Achermann, J. A. Hollingsworth, V. I. Klimov Recent Developments and Applications of Time-Dependent DFT and Related Ab Initio and Semiempirical Methods Cosponsored with Division of Computers in Chemistry Colloidal and Molecular Electro-Optics Vesicles and Membranes Cosponsored with Division of Colloid and Surface Chemistry Integrating Diverse Computational Approaches to Complex Problem Solving Materials and Surfaces Cosponsored with Division of Computers in Chemistry Protein Flexibility Theory Cosponsored with Division of Computers in Chemistry
242. Predicting molecular hyperpolarizabilities: Is semiquantitative the best we can do? S. B. Allin 243. Semiclassical dynamics with quantum trajectories: Formulation and comparison with the semiclassical initial value repre sentation propagator. S. Garashchuk, V. A. Rassolov 244. The adiabatic connection in DFT simulated to the infinite interaction strength limit. K. Burke 245. Theory of the electronic structure in solution with quantum solute-solvent interactions. T. Yamazaki, H. Sato, F. Hirata 246. Local hybrid functionals. J. Jaramillo, G. E. Scuseria 247. Electronic and nuclear molecular orbitals method: A critical assessment. A. D. Bochevarov, E. F. Valeev, C. D. Sherrill 248. New meta-generalized gradient approximation for exchange and correla tion. J. Tao, J. P. Perdew 249. Screened Coulomb potential hybrid functionals. J. Heyd, G. E. Scuseria 250. Toward the complete basis set limit: Massively parallel implementation of MP2-R12 methods. E. F. Valeev, M. L. Leininger, C. L. Janssen, C. D. Sherrill 251. Full-configuration interaction bench marks and potential energy curves using natural orbitals. M. L. Abrams, C. D. Sherrill 252. Full-configuration interaction potential energy curves for bond breaking: An assessment of single-reference correla tion methods. A. Dutta, C. D. Sherrill 253. Developing inexpensive theoretical methods for breaking chemical bonds. J. S. Sears, C. D. Sherrill 254. Development of a multicentered inte grated QM/QM technique and applica tions to multiply hydrogen-bonded sys tems. B. W. Hopkins, G. S. Tschumper 255. Adiabatic connection in DFT simulated to the infinite interaction strength limit. R. J. Magyar, K. Burke 256. Assessment of exchange-correlation functionals dependent on the Laplacian of the electron density. S. N. Maximoff, G. E. Scuseria 257. A direct INDO/SCI method for excitedstate calculations. A. L. Tomlinson, D. Yaron Section Β Physical Chemistry Poster Session Gas-Phase Dynamics and Structure
7:30-10:00 258. Effects of H 2 0 on gold cluster adsorp tion activity. W. T. Wallace, R. L. Whetten 259. Photodissociation dynamics of ethyl ethnyl ether: A new ketenyl radical precursor. M. J. Krisch, J. L. Miller, L R. McCunn, L. J. Butler, H. Su, R. Bersohn, J. Shu 260. Photoelectron imaging spectroscopy of molecular and cluster anions. E. Surber, A. Sanov, R. Mabbs
261. Photodissociation of acryloyl chloride excited at 193 nm. D. E. Szpunar, L J. Butler, F. Qi 262. Photodissociation of CF2CIBr at the 267-nm region. J. Huang, D. Xu, J. S. Francisco, W. M. Jackson 263. Testing the morphed potential of Ar:HBr using frequency and phasestabilized FASSST with a supersonic jet. B. A. McElmurry, S. P. Belov, J. Bevan, R. R. Lucchese, I. Leonov 264. Toward more accurate computational methods to predict C-13 chemical shifts: A study of 2,2,4-trimethylpentane-1,3diol. A. Pisarenko, J. B. Foresman, D. Clarke 265. Infrared diode laser spectroscopy of jet-cooled organometallics. S. W. Reeve, W. A. Bums, K. S. Trauth 266. Products of high-velocity O-ethylene collisions detected via time-resolved FTIR emission spectroscopy. J. A. Dodd, K. J. Castle, E. S. Hwang, G. D. DeBoer 267. Pulsed supersonic flow kinetic studies of radicals at interstellar temperatures. C. Mullen, M. Smith 268. Molecular modeling of hydrogenbonded interactions. Β. Η. Nordstrom 269. Radical photoionization studies with VUV synchrotron radiation. C. Nicolas, D. S. Peterka, M. Ahmed, L Poisson, B. Ruscic, X. Tang, T. Zhang, M. L. Morton 270. Quantum Monte Carlo study of the electronic structure of free-base porphy rin. O. El Akramine, A. Aspuru-Guzik, J. C. Grossman, W. A. Lester Jr. 271. Quasiclassical state-selected trajectory study of the Ο + H3+ reaction. C. W. Eaker 272. Near-infrared laser spectroscopy of Col. A. L Wong, W. W. S. Tarn, J. W. H. Leung, A. S. C. Cheung 273. Raman spectra of vapors at elevated temperatures. J. Laane, D. Autrey, Ζ. Αφ, Κ. Haller, Κ. Morris, A. Combs 274. Reaction kinetics of the isomerization of 1,1,2,2-tetramethylcyclopropane. K. Parcella, T. Gray, B. L. Kalra, T. Guhan, D. K. Lewis 275. Reconstruction of superexcited-state potential energy curves of HCI. H. Loock, S. Manzhos, C. Romanescu, D. Boldovsky 276. Response-surface geometry optimiza tion in quantum Monte Carlo: Application to formaldehyde. C. A. Schuetz, M. Frenklach, A. C. Kollias, W. A. Lester Jr. 277. Rydberg fingerprint spectra of mono cyclic and bicyclic molecules. N. Kuthirummal, J. L. Gosselin, P. M. Weber 278. SOX on VOX: Oxidation-state tuning of the adsorption of S0 2 on vanadiumoxide cluster anions. R. B. Wyrwas Jr., R. L. Whetten, A. J. Leavitt 279. Spectroscopic and electrical properties of ground state NaH: Extrapolation to the complete basis set limit. Β. Κ. Taylor 280. Spectroscopy of NiCI: Identification of a [9.1]2ΐΓ3/2 state. S. Tumturk, L C. O'Brien 281. The kinetics of methyl loss from ethylbenzene and xylene ions: The tropylium versus benzylium story revisited. K. Weitzel, M. Malow, M. Penno 282. Theoretical study of the noble-gas compounds HKrF and HKrCI. J. J. Seals III, S. Yockel, A. K. Wilson 283. Thermochemistry of hydrocarbon ions, CnHm+ (n = 3-9), in the gas phase. S. Williams, T. M. Miller, A. Midey, A. A. Viggiano 284. Unimolecular rate constant for the HF elimination from chemically activated CF3CHFCF3. B. M. Sibila, M. Roach, G. L. Heard, Β. Ε. Holmes 285. Velocity map imaging of the photodis sociation of CF3I: Vibrational energy dependence of the recoil anisotropy. F. Aguirre, S. T. Pratt
286. Vibrational excitation mechanism for HCN in a pulsed-IR laser field using Floquet and Fourier analyses. M. A. Rickard, B. L. Gourley 287. Vibrational overtone transitions of hydrofluoropropanes and ethanes. J. S. Leith, A. H. Steeves, J. R. Apgar, B. G. Saar, S. Bhattarai, J. W. Thoman Jr. 288. Dynamics of charge-transfer-to-solvent precursor states in halide-solvent clus ters. Q. K. Timerghazin, G. H. Peslherbe 289. Electronic spectrum of dimethylcadmium cations in a free-jet expansion. F. J. Grieman, R. M. Stephenson, B. G. Riffel 290. Quantum Monte Carlo Study of the pi-pi transition in ethylene. O. El Akramine, A. C. Kollias, W. A. Lester Jr. 291. Separation of conventional and distonic radical cations of CH3-X using nitrogen-cooled ion mobility time-of-flight mass spectrometry. G. F. Verbeck, D. H. Russell 292. Estimates of the ab initio limit for pi-pi interactions and their role in molecular recognition. M. O. Sinnokrot, E. F. Valeev, C. D. Sherrill 293. Experimental rate constants and branching ratios for unimolecular decom position of chemically activated C(CH3)3CH2CI and C(CH3)3CD2CI: Evidence for 1,1-DCI and 1,3-HCI elimi nations. C. E. Lisowski, K. E. Krumpe, G. L. Heard, Β. Ε. Holmes 294. Experimental rate constants, branch ing ratios, and kinetic isotope effects for unimolecular decomposition of chemi cally activated CHF2CH2CI and CHF2CD2CI. M. R. Beaver, Β. Ε. Holmes 295. Finite temperature properties of (C0 2 ) n clusters. H. Liu, K. D. Jordan 296. First direct measurement of the rate constant for the reaction CI + CH 3 and a reexamination of its role in perturbing laboratory measurements of the impor tant stratospheric reaction of CI + CH4. J. K. Parker, L. J. Stief, W. Payne, R. Cody, F. Nesbitt 297. Fourier transform emission spectros copy of the [12.3]V - X π · ^ transition of NiCI. C. A. Rice, L C. O'Brien 298. HOC+ + H2 isomerization rate at 25K: Implications on the observed [HCO+]/ [HOC+] ratios in the interstellar medium. M. Smith, S. Schlemmer, J. von Richthofen, D. Gerlich 299. Imaging studies of helium nanodroplets. D. S. Peterka, L. Poisson, A. Lindinger, M. Ahmed, D. M. Neumark 300. In search of covalently bound tetraand penta-oxygen clusters. Β. Μ. Elliott, A. I. Boldyrev, L. Wang, H. Zhai, X. Yang, X. Wang 301. Internal temperature of laser-evapo rated liquid aerosol droplet measure ments with VUV photoionization using a "chemical thermometer.". T. Baer, R. E. Miller, E. Woods III 302. Investigating hydrogen-bonding sys tems using computational methods. K. R. Mitchell, A. S. Borovik, W. H. Thompson 303. Ion pair imaging spectroscopy with DC slice maging. M. P. Minitti, D. Townsend, A. G. Suits 304. IR-VUV and VUV-IR photoinduced Rydberg ionization of Ar and C2H2. X. Qian, A. Kung, C. Y. Ng 305. Isomerization of benzene radical cation: Binding energies and structures of benzene cluster ions. M. S. El-Shall, M. J. Rusyniak, Y. M. Ibrahim
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-117
TECHNICAL PROGRAM 306. Kinetics of CI atom reactions with cyclic ethers. M. Quant, R. Kelley, S. Hewitt 307. Kinetics of the CCO + NO reaction. D. Thweatt, M. A. Erickson, J. F. Hershberger 308. Kinetics of the reactions of CI atoms with naphthalene and alkylnaphthalenes. C. Quant, X. Peng, D. Coulson, M. Luu, S. Hewitt 309. Kinetics of the SiH3 + H 2 0 2 and SiH3 + 0 2 reactions. J. P. Meyer, J. F. Hershberger 310. Laplace transform perturbative triples correction ansatz: Application to organometallic compounds. P. Constans, G. E. Scuseria 311. Mode-dependent vibrational autoionization in nitrogen dioxide. P. Bell, F. Aguirre, E. R. Grant, S. T. Pratt 312. Computational study of the 1,1 -HX and -DX (X = F, CI, and Br) elimination from halomethanes. M. Roach, G. L Heard, Β. Ε. Holmes 313. Conformational studies of benzyl compounds. K. A. Utzat, R. K. Bohn, H. H. Michels 314. Convergence of CCSD(T) and full CI spectroscopic constants for BH, CH+, and NH. B. Temelso, C. D. Sherrill 315. Dependence of the catalytic activity of the 3-D transition-metal sulfides on their electronic structure. R. Oviedo-Roa, L. A. Perez, J. Martinez-Magadan, O. Novaro 316. Different bonding behavior of nitrogen vs phosphorus: A density functional theory study. B. Adams, W. C. Chai, K. Kavulla, D. Y. Zhang 317. Dissociation channels of the 1-buten2-yl radical: An experimental and ab initio study. J. L Miller, M. J. Krisch, L J. Butler, J. Shu 318. Dissociation pathways of nitrogenoxygen molecules. D. L. Strout, L. Y. Bruney 319. Dissociative photoionization dynamics in ethane studied by velocity map imag ing. W. Li, L. Poisson, D. S. Peterka, M. Ahmed, A. G. Suits 320. Computational ground-state structures of benzene-13: A reconsideration. D. C. Easter 321. Atomic oxygen beam source for inves tigating high-energy Ο + hydrocarbon reactions. S. D. Chambreau, E. S. Hwang, J. A. Dodd 322. Energy barriers to [1,3]hydrogentransfer reactions found using valency interaction formulas compared to MO theories and experiment. J. D. Alia 323. Calculating the atomic mass of bro mine. N. P. Larson, F. Hilgeman 324. CF3CFHO vs CH 3 CH 2 0: An ab initio molecular orbital study of mechanisms and kinetics of C-C bond scission and reaction with 0 2 . J. E. Stevens, O. Radkevich, J. Brown 325. Aromaticity and antiaromaticity in small boron clusters and related compounds. A. N. Alexandrova, A. I. Boldyrev, H. Zhai, L. Wang 326. A TDDFT study of the low-lying excited states of coumarins 102, 152, 153, and 343. R. J. Cave, E. W. Castner Jr. 327. A theoretical study of the reactions of carbonyl oxide with water and water dimer. A. B. Ryzhkov, P. Ariya
118-TECH
328. Identification of Se substitution location in 6648986!4- clusters using ab initio vibrational calculations and FT-Raman spectroscopy. S. J. Kirkby 329. Ab initio studies of β-aminocyclopropane carboxylic acids. J. L. Meeks, K. L. Adams, H. B. Fannin 330. Cation-£k interactions in substituted aromatic complexes: An experimental and theoretical study of Ag(l)-alkylbenzenes and substituted naphthalenes. Y. P. Wong, H. M. Lee, I. N. L Ma, C. W. Tsang 331. Calculation of molecular electron affinities of small molecules using elec tron correlation and sigma pi interac tions. E. S. Chen, E. C. M. Chen 332. Full-dimensional inelastic scattering between H2 using Chebyshev propaga tion. S. Lin, H. Guo 333. Multiconfiguration time-dependent Hartree method applied to intramolecular and intermolecular energy redistribution of molecules. F. Gatti, C. lung, H. Meyer Section C Physical Chemistry Poster Session Condensed-Phase Dynamics and Structure
7:30-10:00 334. Thermodynamics of charge-asymmet ric lattice electrolytes. V. Kobelev, M. N. Artyomov, A. B. Kolomeisky 335. Redox thermodynamics of plastocyanin in aqueous solution. D. LeBard, D. Matyushov 336. Resolution of spectral peak congestion in an infrared investigation of the deter mination of thermodynamic parameters for hydrogen bond formation in lactams. S. G. Lieb, J. N. Hohman 337. Resonance Raman studies of solvent effects on intramolecular charge transfer in betaine-30 dye. X. Zhao, J. L. McHale 338. Separating rotations and translations in solvation computer experiments. A. Milischuk, D. Matyushov 339. Simulation of alkanes and perfluoroalkanes: A study on the combining rules. W. Song, M. Maroncelli 340. Simulation of the polarization response of room-temperature ionic liquids. V. S. Znamenskiy, M. N. Kobrak 341. Simulations of vibrational energy relaxation in solution. S. Li, W. H. Thompson 342. Solvation in water at elevated tem peratures. J. Duan, H. Kim 343. Spiral-wave nucleation and finite bands of stable wavelengths in excitable systems with anomalous dispersion. C. T. Hamik, O. Steinbock 344. Structural investigation of crystalline and solution phases of monoglyme:LiSbF6. V. A. Seneviratne, J. E. Furneaux, R. Freeh 345. Temperature dependence of outersphere reorganization free energy in dielectric continuum description. H. J. Kim, S. R. Manjari 346. Thermodynamic properties of nitrogen. L Biolsi, P. M. Holland 347. Ultrafast infrared spectroscopy of vibrational and rotational relaxation of pseudohalide ions in reverse micelles. Q. Zhong, A. P. Baronavski, J. C. Owrutsky 348. Ultrafast photodissociation dynamics of ketones at 195 nm. Q. Zhong, D. A. Steinhurst, A. P. Baronavski, J. C. Owrutsky 349. An FT-IR study of crown ether complexation with water in liquid and super critical C0 2 . A. F. Rustenholtz, J. L Fulton, C. M. Wai 350. Chiral fluids: Simulation and theory of discrimination. N. M. Cann
351. Effect of solute concentration on solvation. H. J. Kim, S. Dorairaj, J. T. Hynes 352. On the multiple time scales in solva tion dynamics: A mode-coupling theory approach. S. Egorov, R. A. Denny, D. Reichman 353. Control of intermolecular electrontransfer reactions in liquid-crystalline solvent at the point of phase transition. M. Lilichenko, D. Matyushov 354. Dynamics of ultrafast proton transfer in 1 -acylaminoanthraquinones. S. J. Schmidtke, D. F. Underwood, D. A. Blank 355. Solution approach of selenium trans formation from micro- to nanoscale. S. Xie, C. Wang, X. Zhang, Z. Jiang, R. Huang, L Zheng 356. Excited-state proton transfer of photoacids studied with ultrafast infrared spectroscopy. M. Rini, J. Dreyer, A. Kummrow, B. Magnes, E. Pines, Ε. Τ. J. Nibbering 357. Excited-state proton transfer in chiral environments. K. M. Solntsev, L M. Tolbert, B. Cohen, D. Huppert, Y. Hayashi, Y. Feldman 358. Fiber-loop ring-down spectroscopy. H. Loock, Z. Tong, A. Wright, M. Jakubinek 359. High-pressure supercritical fluid reac tions. J. M. Zaug, A. F. Goncharov, L. E. Fried, D. W. Hansen 360. Ultrasensitive measurement of optical absorption efficiency of continuous and discontinuous phases in concentrated suspensions using multiple light scatter ing with diffusion approximation. Y. Huang, Z. Sun, E. M. Sevick-Muraca 361. Hydrogen bonding in acetone-water liquid mixtures: An IR study. C. Chapados, J. Max 362. Identity, energetics, dynamics, and environment of interfacial water mol ecules in a micellar solution. S. Pal, S. Balasubramanian, B. Bagchi 363. Influence of intermolecular structural variables on the ultrafast vibrational dynamics of water. J. D. Eaves, C. J. Fecko, J. J. Loparo, A. Tokmakoff, P. L. Geissler 364. Intermolecular spectrum of oriented liquid crystals: Optically heterodynedetected Raman-induced Kerr spectros copy of 4-octyl-4'-cyanobiphenyl. E. L. Quitevis, B. Hyun 365. Magnetic field effect on the viscosity of ion-solvent interactions in aqueous CoCI2 at different temperatures. S. A. Ghauri, M. A. Khan 366. Nonadiabatic simulations of the solva tion dynamics of photoexcited sodide. C. J. Smallwood, W. B. Bosma, R. E. Larsen, B. J. Schwartz 367. Nonperturbative calculation of vibra tional line shapes. S. Yang, J. Cao 368. On the incromulence of linear response. M. J. Bedard, R. E. Larsen, B. J. Schwartz 369. Photodetrapping of the hydrated electron via the conduction band and p-states. Y. J. Lee, T. W. Kee, P. F. Barbara 370. Influence of pressure on liquid-liquid immiscibility in n-alkane/n-perfluoroalkane/carbon dioxide mixtures. L. Zhang, J. I. Siepmann 371. Spectroscopic characterization of K+ bound and unbound crown ether in various solvents. T. Buthelezi 372. Structure of solvated Fe(CO)5: FTIR/Xray absorption measurements and their correlation with density functional theory calculations. C. Rose-Petruck, Y. Jiang, T.Lee 373. Terahertz spectroscopy of crown ethers in solution. T. M. Korter, M. C. Beard, W. T. Lotshaw, L. K. Iwaki, E. J. Heilweil 374. Terahertz-time-domain spectroscopy on electron-donor-acceptor complex in solutions. K. Yamamoto, K. Tominaga
375. The influence of inertial solvent response on absorption and resonance Raman profiles. J. A. Burt, J. L. McHale 376. Withdrawn. 377. Vibrational phase relaxation along the critical isochore and in binary mixtures. B. Bagchi, S. Roychowdhury 378. Measurement of the lifetime and the electron-transfer scavenging time of the p-state hydrated electron. T. W. Kee, D. H. Son, P. F. Barbara 379. Molecular dynamics simulation study of imidazolium halides. Y. Shim, H. J. Kim 380. Molecular simulation of the shearinduced changes in the transport proper ties of anisotropic molecules. P. Vieira, D. J. Lacks 381. Computer simulation studies of fluorosurfactant-based reverse micelles in supercritical carbon dioxide. S. Senapati, M. L. Berkowitz 382. Modeling the density dependence of electronic spectra in liquids and super critical fluids. M. Maroncelli, N. Patel, N. Ito 383. Brownian dynamics simulation of model PDC109 in water. H. J. Kim, H. J. Kim, Y. Shim, M. Y. Choi, M. Llinas Section D Physical Chemistry Poster Session Surfaces and Interfaces
7:30-10:00 384. Photoemission studies of organic-thiol self-assembled monolayers on gold surfaces. C. Zangmeister, S. Robey, R. van Zee 385. Resonance Raman study of interfacial electron transfer in dye-sensitized semi conductors. J. A. Pollard, J. L. McHale, S. Doan 386. Quantum molecular dynamics simula tion of the interaction between α-hema tite surface and imidazoline molecules. F. Alvarez Ramirez, I. Garcia-Cruz, G. Tavizon, J. Martinez-Magadan 387. Study of the interaction between FeS surface and Mullins and Zajac asphaltene models. F. Alvarez Ramirez, I. Garcia-Cruz, G. Tavizon, J. Martinez-Magadan 388. Surface-enhanced Raman spectra of aqueous cyanide adsorbed onto metal colloids. M. B. Jacobs, P. W. Jagodzinski 389. Surface-enhanced Raman spectra of pyridine using different metal surfaces: Evidence for the formation of â-pyridyl at ambient conditions. C. Zuo, P. W. Jagodzinski 390. Surface-enhanced Raman spectroscopy for localized sensing in biological systems. C. E. Talley, T. R. Huser, C. W. Hollars, S. M. Lane 391. Transition-metal-assisted borohydride reduction of aromatic and aliphatic nitriles on copper colloids. C. M. Coyle, G. Chumanov, P. W. Jagodzinski 392. New interpretations of chirality in surface second harmonic generation. G. J. Simpson, A. J. Moad 393. Interactions of CH4 adsorbates with MgO(100) surfaces. R. J. Hinde, P. J. Stimac 394. Morphology of thin organic films in field-effect transistor geometry. A. Gesquiere, D. Y. Kim, S. Khondaker, D. Fine, A. Dodabalapur, P. F. Barbara
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
PHYS/TECHNICAL PROGRAM
395. Patterned electrodes for the fabrication of controlled-movement polymer trans ducers. L. Supriya, R. 0 . Claus 396. Predicting the adsorptive properties of strained metal surfaces. R. G. S. Pala, T. Truong, F. Liu 397. Structural and electronic properties of redox-addressable molecules selfassembled on Au(111). W. Haiss, D. Bethell, R. J. Nichols, D. J. Schiffrin 398. Structure-property studies of conju gated oligomers: From single molecules to films. M. A. Summers, M. T. Bowers, G. C. Bazan, S. K. Buratto Section Ε Physical Chemistry Poster Session Materials and Polymers
7:30-10:00 399. Photoelectrochemical water splitting from spray pyrolytically fabricated nanocrystalline p-Fe203. W. B. Ingler Jr., S. U. M. Khan 400. Screening for Ge4Xi04- (X = S, Se) adamantanoid cluster synthesis using ab initio vibrational calculations and FTRaman spectroscopy. S. J. Kirkby 401. Spectroscopy of single-fluorene copolymers. R. K. Lammi, P. F. Barbara 402. Physical methods for probing the electronic structures of d 2 and d 8 transi tion-metal complexes. J. K. Grey, I. S. Butler, C. Reber 403. Ultrafast isomerization dynamics of trans, frans-distyrylbenzene: Coherent phenomena and S2 contribution. F. Hsu, M. Hayashi, S. H. Lin, J. Wang 404. Preparation and surface modification of monodisperse submicrometer silica spheres for near-infrared photonic crys tals. W. Wang, B. Gu 405. Vibrational quenching of fluorescence in zeolites by adsorbed dihydrogen and hydrogen deuteride: Chemical hole burning. R. L. Sweany, J. M. Bono 406. XPS studies with external voltage bias for probing nanoparticle-substrate inter action. S. Suzer 407. Fullerenes production promoted by chlorine. S. Xie, F. Gao, R. Huang, L. Zheng 408. Molecular polarizabilities of model carbon nanotubes from atomic incre ments. F. Torrens 409. Self-assembly of semiconductor nanoparticles into superlattice. D. L. Akins, W. Xu, S. P. O'Brien, L Huang, M. Yin 410. NMR investigation of halogen, alkylterminated silicon nanoclusters. R. S. Carter, S. M. Kauzlarich, P. P. Power, M. P. Augustine 411. Self-organizing chemical reactions meet soft photolithography. Β. Τ. Ginn, O. Steinbock 412. Distinguish fullerenes precursors from the side products of graphite arc dis charge in low-pressure He-CCI4 by appraising their yield correlations. S. Xie, F. Gao, R. Huang, L Zheng 413. Catalytic activity of molybdenum disulfide nanotubes inferred from their electronic structure. L. A. Perez, R. Oviedo-Roa, J. Martinez-Magadan 414. Si-29 MAS NMR and XRD studies of solid-state cation migration through zeolite materials. S. M. Neugebauer Crawford, J. R. Houston 415. Si-29 studies of Ni(ll)and Cu(ll)cation migration through zeolites ZSM-5 and mordenite. S. M. Neugebauer Crawford, Ν. Μ. Leonard 416. Synthesis and characterization of colloidal InP quantum rods and dots. J. M. Nedeljkovic, O. I. Micic, S. P. Ahrenkiel, A. Miedaner, A. J. Nozik
417. Synthesis of cobalt nitrate hydrate nanoparticles using laser vaporization controlled condensation. G. P. Glaspell II, P. W. Jagodzinski, A. Manivannan 418. The catalytic cracking of />dodecane in the supercage of the HUSY zeolite. J. Martinez-Magadan, F. Alvarez Ramirez, O. Novaro 419. VUV photoionization studies of metal and metal oxide clusters. L. Poisson, J. Shu, D. S. Peterka, C. Nicolas, M. Ahmed 420. Chemistry and photochemistry on the surface of MgO nanocubes. E. Knôzinger, O. Diwald, M. Sterrer 421. Dynamics of the capillary rise in nanocylinders and nanoporous materials. L D. Gelb, A. C. Hopkins 422. Electron and ion transfer through multilayers of gold nanoclusters covered by self-assembled monolayers of alkylthiols with ferrocene and carboxylate groups. T. Kondo, M. Okamura, W. Song, K. Uosaki 423. Four-leg zinc oxide nanostructure growth in microwave plasma from zinc powder. S. Xie, X. Zhang, R. Huang, Z. Jiang, J. Kang, T. Sekiguchi, L Zheng 424. Phase stability of nanocrystalline ZnS by thermodynamic analysis and experimental study. H. Zhang, F. Huang, B. Gilbert, J. F. Banfield 425. Electric-field-controlled synthesis of biocompatible HPMA hydrogels with self-organized arrays of microchannels. T. D. Campbell, R. P. Washington, B. T. Ginn, L. J. Blakemore, P. Q. Trombley, O. Steinbock 426. Preparation of novel silica-coated cadmium sulfide nanoparticles having adjustable void space by size-selective photoetching. T. Torimoto, J. P. Reyes, K. Iwasaki, B. Pal, B. Ohtani 427. Self-assembled FePt nanoparticles for granular thin-film magnetic recording media. D. E. Nikles, J. W. Harrell, S. Kang, X. Sun 428. Energies and kinetics of electron and hole processes on the surface of MgO powders. M. Sterrer, O. Diwald, E. Knôzinger 429. SPEEK-PVA photoactive polymer blends for the generation of nanosized metal particles. A. Korchev, M. Sartin, B. L Slaten, G. Mills 430. EPR studies of [Os2(hpp)4CI2](PF6), the first structurally confirmed M27+ padd le wheel. A. C. Stowe, N. Dalai, P. Huang, C. A. Murillo, X. Wang, F. A. Cotton 431. Surface-state-controlled nanocrystalline ZnS structure transformation. F. Huang, H. Zhang, B. Gilbert, J. F. Banfield 432. Synchrotron analysis of ZnS nanoparticle structure and surface-driven structural transitions. B. Gilbert, H. Zhang, F. Huang, J. F. Banfield 433. Synthesis, self-assembly, and magnetic properties of FePtCu nanoparticles. X. Sun, D. E. Nikles, J. Li, Z. Wang 434. Growth silver nanowires using electrochemical deposition in the dilute solution without supporting electrolytes. Z. Xie, S. Zhang, Z. Jiang, H. Ke, L. Zheng 435. Hydroboration and hydrogénation of single-walled carbon nanotubes: A ONIOM2 study. X. Lu, F. Tian, N. Wang, Q. Zhang 436. Raman studies of hydrothermal zeolite synthesis. P. H. J. M. Knops-Gerrits 437. Ab initio molecular dynamics simulation of the interaction between α-hema tite surface and different asphaltene molecular models. F. Alvarez Ramirez, I. Garcia-Cruz, G. Tavizon, J. Martinez-Magadan 438. Molecular dynamics simulations of the decomposition of energetic materials at extreme conditions. M. R. Manaa, L E. Fried, M. Elstner 439. Inelastic neutron spectroscopy of organic hydrocarbons. J. A. Ciezak, B. S. Hudson, T. A. Jenkins, D. Allis
440. Near-field spectroscopic investigation of carrier trapping and energy diffusion in pentacene-doped tetracene. D. Y. Kim, J. D. McNeill, P. F. Barbara 441. Characterization and reaction studies of laboratory-generated Titan aerosol precipitates (Tholins). M. Smith, C. J. Welch, J. I. Lunine 442. Colloidal Ill-nitride quantum dots: Synthesis and characterization. P. G. Van Patten, G. Pan 443. Effect of cross-linkers, particle size, and film thickness on conductivity and optical transparency of nanocomposite self-assembled films. J. C. Huie, B. Lepene, J. K. Hoyt 444. Symmetric hydrogen bonds. T. A. Jenkins, B. S. Hudson 445. Electron trapping in low-water-content zeolites χ and Υ. Ε. Η. Ellison 446. Study of FTIR-TPD of benzene, tolu ene, and ethylbenzene from H-ZSM-5 and Η-β zeolites. R. M. RoqueMalherbe, R. Wendelbo Section F Physical Chemistry Poster Session Biophysical Chemistry
7:30-10:00 447. Potential energy barriers to conformationally gated QB binding in the photosynthetic reaction center of Rhodobacter sphaeroides. A. Rahaman, R. A. Wheeler 448. Solvation effects and interpeptide interactions on the amide I mode vibra tional frequency. S. Ham, J. Choi, K. Kwac, M. Cho 449. Spectroscopic study of the heat effect on ovalbumin. K. Yokoyama 450. Time-resolved infrared studies of RecA. J. A. Bailey, G. MacDonald 451. Ultrafast studies of hemerythrin excited-state decay dynamics. A. Kennedy, M. D. Edington 452. ATP synthase: An energy-based insight. A. Shurki, M. Strajbl, A. Warshel 453. Dynamics of bent DNA sequences. A. Spasic, U. Mohanty 454. Structural disorder of native horserad ish peroxidase C probed by resonance Raman and low temperature optical absorption spectroscopy. Q. Huang, K. Szigeti, J. Fidy, R. Schweitzer-Stenner 455. Net charge center: A new physicochemical model of protein function for structural genomics and bioinformatics. I. Y. Torshin, R. W. Harrison, I. T. Weber 456. Polyproline-ll conformation of alanine dipeptide determined by liquid-crystal NMR. J. C. Weisshaar, C. Weise 457. Infrared studies of nucleotide binding to RecA. C. M. Schwartz, J. A. Rudnick, G. MacDonald 458. Large-scale density functional investi gation of arginase: A binuclear manga nese metalloenzyme. I. Ivanov, M. L. Klein 459. Measurement of charge-density distri bution of Mesulergine, a dopamine agonist, by X-ray diffraction. C. L. Klein Stevens, N. Zhu, E. D. Stevens 460. Modeling cyclic dipetides and calcula tions of their UV CD spectra. K. L. Carlson, M. R. Hoffmann, K. A. Thomasson 461. Conformational analysis of histamine tautomers. A. A. DeFusco III, K. D. Jordan 462. Dual-frequency 2-D-IR spectroscopy in peptides. I. Rubtsov, J. Wang, R. M. Hochstrasser 463. Brownian dynamic simulations of glyceraldehyde-3-phosphate dehydroge nase mutants binding F-actin. V. F. Waingeh, S. L. Lowe, K. A. Thomasson
464. Atomic force microscopy studies of the F r ATPase rotary motor. C. L. Berrie, J. E. Headrick, S. Kodeboyina, M. L. Richter 465. Thermodynamics of metabolism from the point of view of semigrand partition functions. R. A. Alberty
THURSDAY MORNING Section A Convention Center Room 283 New Electronic Structure Methods: From Molecules to Materials Metals, Materials, and Multiscale Modeling Cosponsored with Division of Computers in Chemistry M. Challacombe, Presiding M. P. Head-Gordon and E. A. Carter, Organizers 8:30 466. A new method for the calcula tion of the energies and lifetimes of excited species near surfaces. P. J. Nordlander 9:10 467. Prediction of crystal structure and phase stability with first-principles methods. G. Céder 9:50 468. Modeling molecular electronic devices: Challenges for electronic structure theory. S. N. Yaliraki 10:30 Intermission. 10:50 469. Nanoscale self-assembly and pattern formation on surfaces: Quantitative first-principles methods. V. Ozolins 11:30 470. Wavelet basis calculation of Wannier functions. B. R. Johnson, S. D. Clow 11:50 471. Multiscale modeling of shockinduced phase transitions: Using density functional theory and the finite element method to describe the Fe bcc to hep martensitic phase transition. K. Caspersen, A. Lew, M. Ortiz, E. A. Carter Section Β Convention Center Room 284 Physical Chemistry of Biomolecular Motors Rotatory Motors Cosponsored with Division of Computers in Chemistry T. J. Minehardt, Presiding Q. Cui and C. Bustamante, Organizers 8:30 472. Engine and brakes of ATP synthase. M. Yoshida 9:10 473. Elastic power transmission between two rotary motors of ATP synthase. W. Junge 9:50 474. Nanoseconds molecular dynamics simulation of primary mechani cal energy-transfer steps in F r ATP synthase. R. A. Bôckmann, H. Grubmiiller 10:30 Intermission. 10:50 475. Coupling proton movements to c-ring rotation in F^o-ATP synthase: Aqueous access channels and helix rotations at the a-c subunit interface. R. H. Fillingame 11:30 476. Conformational transitions between high- and low-pH forms of subunit c of the ATP synthase: A computational study. P. Maragakis
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-119
TECHNICAL PROGRAM Section C Convention Center Room 286 Sequence-Dependent Curvature and Deformation in Nucleic Acids and Protein-Nucleic Acid Complexes DNA bending U. Mohanty, Organizer, Presiding N. C. Stellwagen, Organizer 8:30 477. The bending authors. R. E. Dickerson 9:10 478. Α-tracts, G-tracts, and generic DNA: A unified view of sequence-di rected curvature. N. V. Hud 9:50 479. Recent studies on Α-tracts and sequence-dependent DNA curvature. T. E. Haran, A. Merling, N. Sagayadakova, I. Cohen 10:30 Intermission. 10:50 480. High-throughput approach for detection of DNA bending and flexibility based on cyclization. Y. Zhang, D. M. Crothers 11:30 481. Measuring protein-induced DNA bending by cyclization of short DNA fragments. A. V. Vologodskii 11:50 482. DNA structure without packing or bound protein. D. Macdonald, P. Lu Section D Convention Center Room 287 Structure-Function Correlation for Biological Ion Channels M. R. Gunner, Presiding A. Warshel and B. Eisenberg, Organizers 8:30 483. Transport mechanism in bacteriorhodopsin. J. K. Lanyi 9:10 484. Proton transfer in bacterial reaction centers. M. Y. Okamura 9:50 485. Clusters of buried acidic resi dues play important roles in transmem brane proton-transfer proteins. M. R. Gunner, Y. Song, Z. Zhu 10:30 Intermission. 10:50 486. Structure of the pore region of the nicotinic-acetylcholine receptor ion channel: A molecular dynamics-simula tion study. L. Saiz, M. Kline 11:30 487. Computer simulation of proton channels. G. A. Voth
9:50 490. Smart dust: Photonic crystals derived from nanocrystalline porous Si. M. J. Sailor, F. Cunin, J. R. Link, S. N. Bhatia, Y. Y. Li, J. Dorvee, T. A. Schmedake, J. Koh 10:30 Intermission. 10:50 491. Fluorescent nanocrystal probes for cell surface receptors. S. J. Rosenthal, I. Tomlinson, J. Burton, J. Grey, J. Mason, P. Gresch, E. Sanders-Bush, L. DeFelice, R. Blakely 11:30 492. Gas sensors based on metal oxide nanowires. A. Kolmakov, Y. Zhang, G. Cheng, M. Moskovits Section F Convention Center Room 277 VUV Probes of Dynamics and Spectroscopy Reaction Dynamics M. Smith, Presiding A. G. Suits and C. Ng, Organizers 8:30 493. State-selected ion-molecule reaction studies using the synchrotronbased pulsed-field-ionization method. X. Qian, T. Zhang, Y. Chiu, D. J. Levandier, J. S. Miller, R. Dressier, C. Ng 9:10 494. State-to-state dynamics of elementary ion-molecule interactions. X. Yang, D. Dai, C. C. Wang, S. A. Harich 9:50 495. VUV probing of nascent reac tion products. H. Su, R. Bersohn 10:30 Intermission. 10:50 496. Measuring the kinetics of radical-radical reactions using repetitive time-of-flight mass spectrometry. C. Fockenberg 11:30 497. Vacuum ultraviolet photoionization probing of flame chemistry. A. Mcllroy, F. Qi, T. A. Cool, P. R. Westmoreland Colloidal and Molecular Electro-Optics Biomolecular Systems Cosponsored with Division of Colloid and Surface Chemistry Protein Flexibility Inhibitor Discovery Techniques Cosponsored with Division of Computers in Chemistry Integrating Diverse Computational Approaches to Complex Problem Solving Materials, Surfaces, and Fluids Cosponsored with Division of Computers in Chemistry
Section Ε Convention Center Room 285 Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Applications N. Halas and S. K. Buratto, Organizers 8:30 488. Bioconjugated nanoparticles for biological sensing and imaging. S. Nie, W. E. Doering, D. J. Maxwell 9:10 489. Optically responsive nanoshell composites. J. L. West, N. Halas, S. R. Sershen
THURSDAY AFTERNOON Section A Convention Center Room 283 Physical Chemistry of Biomolecular Motors Processive Motors III Cosponsored with Division of Computers in Chemistry
Section Β Convention Center Room 284 Sequence-Dependent Curvature and Deformation in Nucleic Acids and Protein-Nucleic Acid Complexes DNA/RNA Protein/Ligand M. L. Kopka, Presiding N. C. Stellwagen and U. Mohanty, Organizers 1:30 503. Ligand-induced deformations of the DNA duplex. W. K. Olson 2:10 504. DNA bending and gene regula tion. Z. Shakked 2:50 505. Hidden Markov models from molecular dynamics simulations of DNA deformations. D. L. Beveridge 3:30 Intermission. 3:50 506. Strain-induced TBP-DNA con formational change. J. D. Kahn, S. S. Majee, J. S. Byun, R. Cheong 4:30 507. An unusual sugar conformation in the crystal structure of the first 10 bases of the RNA/DNA hybrid polypurine tract of HIV-1 can affect recognition. M. L. Kopka 4:50 508. Cyclobutylpyrimidine dimer base flipping by DNA photolyase. R. J. Stanley, K. S. Christine, K. Yang, A. W. MacFarlane IV Section C Convention Center Room 286 Structure-Function Correlation for Biological Ion Channels D. Henderson, Presiding B. Eisenberg and A. Warshel, Organizers 1:30 509. Ion-channel simulations: The importance of conformational flexibility as viewed by MD simulations. M. Sansom 2:10 510. Solvation of atomic metal cat ions within benzene and water clusters. E. Alsharaeh, M. S. El-Shall 2:50 511. Detection of ion selectivity in hydrated systems that model biological ion channels and ionophores. T. D. Vaden, P. Tarakeshwar, K. S. Kim, J. M. Lisy 3:10 512. Ion channels as devices: Engi neering analysis of protein function. B. Eisenberg Section D Convention Center Room 287
2:50 516. Molecular dynamics of electron transfer in dye-sensitized Ti0 2 . G. R. Loppnow, L. C. T. Shoute 3:10 517. Photocatalytic properties of organic nanoparticles in aqueous solu tion. A. Kim, T. G. Bjorklund, S. Lim, C. J. Bardeen 3:30 Intermission. 3:50 518. Self-assembled films of Pt and CdS nanocrystallites in polyelectrolytes: Parameters determining the kinetics of assembly and photoelectrochemical behavior. S. Ghannoum, M. Markarian, Y. Xin, J. Jaber, L. I. Halaoui 4:10 519. Mechanical properties of nanocomposites with long-range order. G. B. McGonigle, S. H. Foulger 4:30 520. Measurement of condensedphase reaction kinetics in nanoparticles using single-particle mass spectrometry. D. Lee, H. Sakurai, R. Mehadavan, M. R. Zachariah 4:50 521. Nanoexplosives: The role of nanoparticles in β RDX polymorphs. P. Torres, N. Mina, S. P. Hernandez, M. E. Castro, R. T. Lareau, R. T. Chamberlain Section Ε Convention Center Room 285 VUV Probes of Dynamics and Spectroscopy Photoelectron Spectroscopy P. Guyon, Presiding A. G. Suits and C. Ng, Organizers 1:30 522. Photoelectron spectroscopy of solvate ions in aqueous solutions, using EUV/VUV radiation. M. Faubel 2:10 523. Femtosecond photoelectron spectroscopy of dissociating molecules. S. R. Leone 2:50 524. Dynamics of Rydberg-excited 1,3-cyclohexadiene. N. Kuthirummal, J. L. Gosselin, P. M. Weber 3:10 525. Photoionization and photoelec tron spectroscopy of He nanodroplets. D. M. Neumark, D. Peterka, L. Poisson, M. Ahmed 3:30 Intermission. 3:50 526. Inner-shell photodetachment of negative ions. N. Berrah 4:30 527. PEPICO studies with velocity focusing of threshold electrons. T. Baer, B. Sztaray Colloidal and Molecular Electro-Optics Crystalline Systems and Gels Cosponsored with Division of Colloid and Surface Chemistry Integrating Diverse Computational Approaches to Complex Problem Solving Fluids and Soft Materials Cosponsored with Division of Computers in Chemistry Protein Flexibility Inhibitor Discovery Techniques III Cosponsored with Division of Computers in Chemistry
C. Bustamante, Organizer, Presiding Q. Cui, Organizer 1:30 498. Functional and structural insights into the mechanisms underlying processivity and directionality in the myosin superfamily. H. L. Sweeney 2:10 499. Computer simulations of molecular recognition and catalysis in biomolecular systems. J. Aqvist 2:50 500. Car-Parrinello simulations of ATP hydrolysis in myosin. T. J. Minehardt, R. Cooke, N. Marzari, R. Car, E. F. Pate 3:30 Intermission.
120-TECH
3:50 501. Molecular kinematics simulation of the power stroke in myosin. S. Fischer 4:10 502. Dynamics of molecular motors investigated by normal-mode analysis. F. Tama, K. A. Taylor, C. L. Brooks III
Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles Applications N. Halas and S. K. Buratto, Organizers 1:30 513. A theoretical study of the mechanism of propene epoxidation on Au/Ti02. H. Metiu 2:10 514. Photonic band gap composites. S. Foulger 2:30 515. Nanoscale Ni growth on clean W(111 ) and S(4x4)/W(111 ): Faceting, site specificity, and reactivity. Q. Wu, H. Wang, T. E. Madey
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
PHYS/POLY/TECHNICAL PROGRAM
DIVISION OF POLYMER CHEMISTRY C. Smith, Program Chair
OTHER SYMPOSIA OF INTEREST: Biotechnology in the Service of Health (see Biotechnology Secretariat, Sun) From Sensors to Functional Instruments (see Division of Analytical Chemistry, Wed) Function-Based and Other Novel Approaches to Sensors for Homeland Defense (see Division of Analytical Chemistry, Sun) Macromolecules to Bioparticles: Analyses with Field-Row Fractionation (see Division of Analytical Chemistry, Mon) Microelectrochemical Systems and Arrays (see Division of Analytical Chemistry, Thu) Size-Exclusion Chromatography with Multiple Detection Techniques (see Division of Analytical Chemistry, Wed) Advances in Tissue Engineering and Cell Therapy (see Division of Biochemical Technology, Wed)
High-Throughput Experimentation (see Division of Chemical Information, Wed) Be All That You Can Be.. as a Technician in Industry! (see Division of Chemical Technicians, Mon) Intellectual Property Issues for the Industrial Workplace (see Division of Chemistry and the Law, Mon) Adsorption of Macromolecules at Liquid-Solid Interfaces (see Division of Colloid and Surface Chemistry, Sun, Mon, Tue) Colloidal and Molecular Electro-Optics (see Division of Colloid and Surface Chemistry, Mon, Tue, Wed, Thu) Molecular-Level Aspects of Bacterial Adhesion, Transport, and Biofilm Formation (see Division of Environmental Chemistry, Sun, Mon)
Modified Fibers with Medical and Specialty Applications (see Division of Cellulose and Renewable Materials, Tue, Wed, Thu) Undergraduate Research Poster Session: Polymer Chemistry (see Division of Chemical Education, Mon)
Cooperative Research Award Honoring Craig Hawker and Tom Russell (see Division of Polymeric Materials: Science and Engineering, Sun)
General Papers (see Division of Polymeric Materials: Science and Engineering, Sun)
ACS Award in Separations Science and Technology sponsored by IBC Advanced Technologies, Inc. (see Division of Industrial and Engineering Chemistry, Tue)
In Situ Characterization of Polymerization Processes (see Division of Polymeric Materials: Science and Engineering, Tue, Wed)
Nanotechnology and the Environment (see Division of Industrial and Engineering Chemistry, Sun, Mon, Tue, Wed, Thu) Materials Properties (see Division of Inorganic Chemistry, Tue, Wed)
Synthesis of Nanoparticles and Nanostructured Materials (see Division of Inorganic Chemistry, Sun, Mon, Tue, Wed, Thu)
Composites from Renewable Resources (see Division of Cellulose and Renewable Materials, Wed)
Chemistry of Materials Award Symposium in Honor of Larry Datton (see Division of Polymeric Materials: Science and Engineering, Mon)
Hydrogen Energy for the 21st Century (see Division of Fuel Chemistry, Tue, Wed)
Plasma Technology and Catalysis (see Catalysis & Surface Science Secretariat, Mon, Tue, Wed)
Chemical Modification of Starch (see Division of Cellulose and Renewable Materials, Sun)
Applications of Scanning Probe Microscopy to Polymers (see Division of Polymeric Materials: Science and Engineering, Mon, Tue, Wed, Thu)
Gene-Based Medicine: Delivery and Diagnostics (see Division of Polymeric Materials: Science and Engineering, Tue)
Materials Synthesis (see Division of Inorganic Chemistry, Sun, Mon, Tue)
Advances in Biodégradation and Biotransformation of Lignocellulosics (see Division of Cellulose and Renewable Materials, Sun, Mon)
Advances in Polymers and Polymerization (see Division of Polymeric Materials: Science and Engineering, Wed, Thu)
Advances in Membranes for Energy and Fuel Applications (see Division of Fuel Chemistry, Tue, Wed, Thu)
Bioinformatics, Genomics, and Proteomics (see Division of Biochemical Technology, Tue)
Commercializing New Technologies from Concept to Market (see Division of Business Development and Management, Tue)
Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles (see Division of Physical Chemistry, Sun, Mon, Tue, Wed, Thu)
Award Symposium for Robert Grubbs (see Division of Inorganic Chemistry, Sun) Organometallic Polymers (see Division of Inorganic Chemistry, Tue)
Joint PMSE/POLY Poster Session (see Division of Polymeric Materials: Science and Engineering, Tue) MALDI and ESI Mass Spectrometry Techniques for Polymers (see Division of Polymeric Materials: Science and Engineering, Sun, Mon)
Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Hydrogels and UV Cationic Crosslinked Systems C. E. Hoyle, Organizer,
Presiding
R. K. Pinschmidt Jr., Organizer 8:00 1. Intelligent amphiphilic co-networks and gels based on crosslinking with methacrylate-telechelicpolyisobutylene macromonomers. M. Haraszti, G. Erdôdi, Β. Ivân 8:30 2. Crosslinked polyacrylate hydrogels: Osmotic and neutron-scattering properties. F. Horkay, P. J. Basser, A. Hecht, E. Geissler 9:00 3. Induced mesophase stability in polymer/Pluronic LLC composites using crosslinking acrylate monomers. D. T. McCormick, K. D. Stovall, C A. Guymon 9:30 4. Photopolymerization of maleimide/ /V-vinylpyrrolidone hydrogels. S. E. Jonsson, V. Kalyanaraman, K. Lindgren, S. Swami, L. Ng 10:00 Intermission. 10:10 5. Water-based radiation-curable polyurethane acrylate coatings. Y. Heischkel, K. Menzel, W. Paulus, C. Decker, R. Schwalm 10:40 6. Combined thermal and radiation curing for multilayer coil coating. P. Sundell, T. Bergman, H. Fagerholm, M. Hautala, A. Ranta-Eskola, C. Filthaut, M. Ferreira 11:10 7. Photoinitiated cationic polymerization using 5-arylthianthrenium salts. J. V. Crivello, F. Jiang, J. Ma 11:40 8. The development of anthracene photosensitizers for photoinitiated cationic polymerization. M. Jang, J. V. Crivello
New Concepts in Biomaterials: Synthesis, Application, Concerns (see Division of Polymeric Materials: Science and Engineering, Sun, Mon)
Section Β
Sci-Mix (see Division of Polymeric Materials: Science and Engineering, Mon)
General Papers Polymer Synthesis
Polymer Surfaces and Interfaces (see Division of Polymeric Materials: Science and Engineering, Tue, Wed, Thu)
Materials, Devices, and Switches (see Division of Organic Chemistry, Wed, Thu)
Synthesis, Characterization, and Application of Multiphase and Composite Materials (see Division of Polymeric Materials: Science and Engineering, Sun, Mon)
Molecular Recognition and Self-Assembly (see Division of Organic Chemistry, Thu)
True Stories of Small Chemical Businesses (see Division of Small Chemical Businesses, Tue)
Fuel Cleanup Considerations for Fuel Cells (see Division of Petroleum Chemistry, Tue)
Hybrid Materials (see Materials Chemistry Secretariat, Sun, Mon, Tue)
New Electronic Structure Methods: From Molecules to Materials (see Division of Physical Chemistry, Sun, Mon, Tue, Wed, Thu)
SUNDAY MORNING
Corporate America's Contribution to Science: Successful Women Chemists (see Women Chemists Committee, Mon) SOCIAL EVENTS: Reception: Mon Social Hour Sun, Tue
Alternatives to Thermal Distillation Solvent Purification (see Division of Chemical Health and Safety, Sun)
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
Hilton Riverside Grand Salon C16/C13
M. R. Buchmeiser, Presiding D. Garcia, Organizer 8:00 9. Free-radical polymerization of 2,3-bis(dimethylaminomethyl)-1,3-butadiene. Y. Yang, V. V. Sheares 8:20 10. A high-throughput approach for poly(2-oxazoline) research: Application of an automated synthesizer. R. Hoogenboom, M. W. M. Fijten, U. S. Schubert 8:40 11. Synthesis of liquid-filled poly meric nanocapsules: Morphology analy sis, role of surfactant and the use of living polymerization techniques. A. J. P. Van Zyl, D. De Wet-Roos, R. D. Sanderson, B. Klumperman 9:00 12. Synthesis of metal-complexing polysiloxanes using the sol-gel process. S. Gallagher 9:20 13. Reversible addition-fragmentation polymerization in heterogeneous media. J. B. McLeary, M. P. Tonge, R. D. Sanderson, B. Klumperman 9:40 14. Controlled-living polymerization by fast-initiating ruthenium catalyst. T. Choi, R. H. Grubbs 10:00 15. Synthesis and characterization of novel oxetane macromonomers. T. Fujiwara, U. Makal, J. Uilk, K. J. Wynne 10:20 16. Synthesis and polymerization chemistry of PEG- and peptide-functionalized cyclooctene for biomaterials applications. K. Breitenkamp, D. M. Junge, E. Jin, T. Emrick
TECH-121
TECHNICAL PROGRAM 10:40 17. Synthesis and properties of polysiloxane-polypropylene graft copoly mers. P. Fu 11:00 18. Monolithic polymeric supports for heterogenized metathesis catalysts. M. R. Buchmeiser, M. Mayr, J. Krause, O. Nuyken, S. Lubbad 11:20 19. Synthesis and electrospinning of branched polyesters. M. G. McKee, T. E. Long, G. L. Wilkes 11:40 20. Alternating radical copolymerization of phenylacetylene with cyclooligoarsines. K. Naka, T. Umeyama, A. Nakahashi, Y. Chujo Section C Hilton Riverside Grand Salon C18/C15 Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Biochemical Technology B. D. Ratner, Organizer, Presiding 9:00 21. Surface modification of polymeric biomaterials: A brief tutorial and over view. B. D. Ratner 9:45 22. Surface modification: Cartoons or reality? D. G. Castner 10:15 23. Surface structure and protein adsorption behavior of polyurethane modified with plasticizers or nitric oxide release agents. M. L. Clarke, J. Wang, Z. Chen 10:45 24. Investigating the adsorption of DNA on polymer-modified surfaces: Block copolymers, dendrimers, and polyelectrolytes. R. Advincula, M. Park, X. Fan, M. A. Advincula 11:15 25. Cloud point PEGylation of titanium biomaterials using a biomimetic anchor. J. L. Dalsin, S. Tosatti, M. Textor, P. B. Messersmith Section D Hilton Riverside Grand Salon B9/B12 The Polymer Science of Everyday Things Cosponsored with The Royal Society of Chemistry and Intersociety Polymer Education Council, Division of Industrial and Engineering Chemistry, and Presidential Event D. Bott, Organizer, Presiding C. Pugh, R. S. Moore, K. J. Wynne, and A. B. Salamone, Organizers 8:30 26. Cooking with plastics. P. J. Barham 9:10 27. Polymers in your food? P. J. Lillford 9:50 28. Polysaccharides from field to fork and factory. A. M. Donald 10:30 29. Contact lens material technol ogy. J. F. Kunzler, J. C. Salamone 11:10 30. Polymers in wound care. D. H. Lucast 11:50 Presidential Symposium Remarks. The Transatlantic Connection. Royal Society of Chemistry Executive Director David Giachardi.
SUNDAY AFTERNOON Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes UV Free-Radical Crosslinked Systems S. E. Jonsson and T. M. Roper, Presiding R. K. Pinschmidt Jr. and C. Hoyle, Organizers 1:30 31. Crosslinking in thiol-acrylate photopolymerizations. Ν. Β. Cramer, C. N. Bowman
122-TECH
2:00 32. Radiation-induced polymerization of monomers from renewable resources. M. Johansson, J. Samuelsson, P. Sundell, U. Bexell, M. Olsson 2:30 33. Synthesis, photopolymerization, and coatings evaluation of novel vinyl esters. T. Y. Lee, C. E. Hoyle, K. A. Lowery, C. A. Guymon, S. E. Jonsson 3:00 34. Kinetics and modeling of thiolene photopolymerizations. N. B. Cramer, T. Davies, A. K. O'Brien, C. N. Bowman 3:25 Intermission. 3:35 35. Ultrafast synthesis of crosslinked materials by photoinitiated polymeriza tion. C. Decker, K. Studer 4:05 36. Integrated approach to studying the development and final network properties of urethane acrylate coatings. S. M. Gasper, D. N. Schissel, L. S. Baker, D. L. Smith, R. E. Youngman, L. Wu, S. M. Sonner, S. R. Givens, R. R. Hancock 4:35 37. Design of low-shrinkage methacrylate polymers. J. Ge, M. Trujillo, J. W. Stansbury 5:05 38. Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties. E. R. Beckel, K. A. Berchtold, J. Nie, H. Lu, J. W. Stansbury, C. N. Bowman Section B Hilton Riverside Grand Salon C16/C13 General Papers Polymer Synthesis C. G. Miller, Presiding D. Garcia, Organizer 1:00 39. Olefin copolymerization using atom transfer radical polymerization: Determination of reactivity ratios. R. Venkatesh, S. Harrison, B. Klumperman, D. M. Haddleton 1:20 40. Olefin copolymerization using atom transfer radical polymerization. R. Venkatesh, B. Klumperman 1:40 41. Structure control of star microgels by ATRP. P. Gurr, G. G. Qiao, D. H. Solomon, M. Mills 2:00 42. Synthesis of novel controlledstructure sugar methacrylate polymers by ATRP under mild conditions without protecting group chemistry. R. Narain, S. P. Armes 2:20 43. Unexpected transesterification of tertiary amine methacrylates during methanolic ATRP at ambient tempera ture: A cautionary tale. X. Bories-Azeau, S. P. Armes 2:40 44. Controlled synthesis and mor phological characterization of nanom eter-sized ionic crosslinking domains in PMMA. S. Karanam, H. Goossens, P. Lemstra 3:00 45. l-(PIB-6-PS)3 star block copoly mers using living carbocationic polymer ization and a trifunctional initiator. R. F. Storey, S. J. Taylor 3:20 46. Photoinitiated group transfer polymerization of methyl methacrylate. C. T. Sanderson, C. Kutal, R. L. Lavallee 3:40 47. Synthesis and characterization of telechelic polymers prepared by RAFT. V. G. R. Lima, J. Brokken, B. Klumperman, G. van Benthem-van Duuren, R. van der Linde
4:00 48. New multiblock copolymers of sulfonated para-phenylenes and ether sulfone for proton-exchange membrane. H. Ghassemi, G. Ndip, J. E. McGrath 4:20 49. Synthesis and photophysical properties of poly(/>phenylene vinylene) via ruthenium-based acyclic diene me tathesis polymerization. C. G. Miller, A. W. Harper 4:40 50. Synthesis of thiophene endfunctionalized polyisobutylene. J. C. Cho, M. H. Acar, R. Faust Section C Hilton Riverside Grand Salon C18/C15 Polymeric Surface Modification: Biomedical Applications Tutorial Cosponsored with Division of Biochemical Technology and Polymeric Materials: Science and Engineering B. D. Ratner and P. L Valint, Organizers, Presiding 1:30 51. Polyelectrolyte multilayer-engi neered surfaces. G. Decher 2:00 52. Thiolipids for tethered bilayer membranes. S. Schiller, R. Naumann, K. Lovejoy, W. Knoll 2:30 53. Surface modification of polymeric nanocomposite thin films. A. C. Balazs 3:00 54. The bio/materials interface. G. M. Whitesides 3:30 55. Site-specific conjugates of smart polymers and engineered proteins on surfaces. A. S. Hoffman, P. S. Stayton 4:00 56. Strategies for polymer surface modification: Sum frequency generation vibrational spectroscopy and atomic force microscopy studies. G. A. Somorjai, J. Kim, T. Koffas 4:30 57. Interfacial structure and dynam ics of perfluoropolyether hard disk. C. Frank, L. E. Bailey, G. Tyndall
1:20 64. Characterization of conducting polymers, polyaniline by inverse gas chromatography. Ζ. Υ. Al-Saigh, A. Al-Ghamdi 1:40 65. Bimolecular polymer chain end reaction rates measured by gel perme ation chromatography with fluorescence detection. A. J. Maliakal, H. Greenaway, N. J. Turro 2:00 66. Detection of free radicals by radical trapping and 15N NMR spectros copy in copolymerization of methyl acrylate and styrene. P. Kelemen, B. Klumperman 2:20 67. Segment orientation and confor mational behavior of polydiethylsiloxane guest chains in uniaxially stretched polydiethylsiloxane elastomers: 2H NMR and SANS. A. Batra, P. Schofield, T. M. Duncan, C. Cohen 2:40 68. Temperature-modulated DSC and FT-IR analysis of solvent cast lignin/PEO films. S. Kubo, P. J. Cleary, J. F. Kadla 69. Withdrawn. 3:00 70. Potentiometric study of surface characteristics of latex particles prepared by emulsifier-free emulsion polymeriza tion of styrene. X. Li, R. Salovey 3:20 71. Mechanical behavior of caulks and sealants. D. L. Hunston, C. C. White 3:40 72. Two-photon absorption in a new symmetrical series of diphenylaminofluorene-based structures. K. D. Belfield, A. R. Morales, V. M. Chapela, J. Percino 4:00 615. Study of the accelerating effect of water in the copolymerization of acrylonitrile with methyl acrylate in emulsion and solution processes. V. A. Bhanu, M. Bortner, T. Mukundan, T. E. Glass, D. G. Baird, J. E. McGrath 4:20 74. Stereoselective incorporation of unsaturated amino acids into proteins in vivo. M. Mock, T. Michon, D. A. Tirrell SUNDAY EVENING
Section D
Section A
Hilton Riverside Grand Salon B9/B12
Convention Center Hall G
The Polymer Science of Everyday Things Cosponsored with The Royal Society of Chemistry and Intersociety Polymer Education Council, Division of Industrial and Engineering Chemistry, and Presidential Event
Crosslinking Materials and Processes Poster Session
C. Pugh, Organizer, Presiding D. Bott, R. S. Moore, K. J. Wynne, and A. B. Salamone, Organizers 1:30 58. Diapers and materials mechan ics. T. L. Mansfield 2:10 59. Dental polymers: Something to chew on. M. T. O'Connor Jr. 2:50 60. Transdermal patches: Not just for control freaks? P. B. Foreman, S. H. Jacobson 3:30 61. Importance of polymers in home and personal care products. E. Khoshdel 4:10 62. Silicones in hair products, cos metics, and clothes: You are closer to silicones than you think. M. D. Butts Section Ε Hilton Riverside Grand Salon D21/D24 General Papers Polymer Characterization
R. K. Pinschmidt and C. Hoyle, Organizers 6:00-8:00 75. Effect of double bond position on the reactivity of alkenes with a monofunctional thiol and its applications to thiolene crosslinking reactions. T. M. Roper, C. E. Hoyle, C. A. Guymon 76. Carbon yield optimization of acetylene resins. H. Zengin, S. Hudson, K. P. U. Perera, D. W. Smith Jr. 77. Carbonylbiscaprolactam: A versatile reagent for the synthesis of reactive oligomers. S. Maier, T. Loontjens, B. Scholtens, R. Mulhaupt 78. Characterization and coating properties of POSS formed by the hydrolytic con densation of GPMS. L. Hu, H. You, J. Liu, X. Zhang, Y. Huang, D. Sun 79. Crosslinking kinetics of fî-(a-hydroxymethyl)acrylates: Effect of crosslinker type and functionality. T. J. Smith, B. S. Shemper, J. S. Nobles, A. M. Casanova, C. Ott, L. J. Mathias 80. Effect of addition of polyol on cure kinetics and viscoelastic properties of UV-curable coating formulations containing cycloaliphatic epoxide and oxetane. H. A. Nash, H. J. Docktor, D. C. Webster
D. L. Hunston, Presiding D. Garcia, Organizer 1:00 63. Structural formation of amor phous poly(ethylene terephthalate) under uniaxial deformation using syn chrotron radiation. D. Kawakami, B. X. Fu, S. Ran, I. Sics, B. S. Hsiao
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
POLY/TECHNICAL PROGRAM
81. Effect of crosslinking point distribution on properties of controllable crosslinking poly(ether ether ketone)s. X. Liu, C. Chen, Z. Gao, H. Cao, X. Zhao, T. Ben, W. Zhang 82. Efficient synthesis of sol-gel materials for nonlinear optical applications. D. W. Smith Jr., D. Perahia, B. K. Spraul, S. Suresh, J. Ballato 83. Electrochemical crosslinking of polyvinylcarbazole onto carbazole-SAM modified ITO substrates for organic lightemitting diode devices. K. Onishi, R. Advincula 84. EPR investigation concerning cyclopolymerization of bis-orf/70-diynyl arene monomers. V. Mellon, N. Mifsud, P. Perera, L Echegoyen, D. W. Smith Jr. 85. Linking poly-L-arginine to poly-DL-lysine using pentosidine linkages (the Maillard reaction). J. R. Wright, A. Standefer, A. Dawson 86. Modification of bisphenol-A BMI resin (BPA-BMI) with allyl-terminated hyperbranched polyimide (AT-PAEKI). H. Qin, P. T. Mather, J. Baek, L. Tan 87. Network-encapsulated self-assembled colloidal spheres: Sensory applications. P. Jiang, D. W. Smith Jr., S. H. Foulger 88. Photopolymerization of urethane dimethacrylates synthesized via a nonisocyanate route. H. J. Assumption, L. J. Mathias 89. Properties of high-resilience polyurethane flexible foams synthesized by novel polyether grafting starch copolymer. S. Chen, L Chen 90. Spacer length and structural effects on oxygen inhibition of dimethacrylates. T. Y. Lee, C. E. Hoyle, C. A. Guymon, S. E. Jonsson 91. Strain-induced crystallization in poly(isobutylene) elastomers in elongation or shear. H. Sun, G. S. Sur, J. E. Mark 92. Synthesis and characterization of glycidyl carbamate functional oligomers. P. A. Edwards, J. Erickson, D. C. Webster 93. Synthesis and polymerization of a new nitrogen-containing bis-ortftodiynylarene monomer. H. Zengin, D. W. Smith Jr. 94. Synthesis of novel interpenetrating polymer networks based on hydrolyzable polyesters. D. Grande, N. Lacoudre, P. Guérin, S. Boileau 95. Synthesis of pH-responsive shell crosslinked micelles and their use as nanoreactors for the preparation of gold nanoparticles. J. V. M. Weaver, S. Liu, S. P. Armes 96. Templated sol-gels, a neutron-scattering study. D. W. Smith Jr., D. Perahia, B. K. Spraul, X. Jiao, R. Traiphol, K. P. U. Perera 97. Thermal and rheological properties of low molecular weight polymers. D. R. Bloch 98. Anisotropic liquid-crystal gels: Selfassembled nanocomposites as solidstate soft actuator materials exhibiting high electromechanical responses. C. Huang, A. Jakli, Q. M. Zhang 99. A new crosslinking chemistry based on a 5-membered dithiocarbonate group. T. Murayama, I. Hotta, B. D. Hanrahan 100. Pyrolysis GC-MS and transmission electron microscopy in the characterization of crosslinked UHMWPE microstructure. R. D. Redfearn, C. W. Carlson, A. M. Viano, K. E. Spence, A. K. Ray Section Β General Papers Polymer Characterization D. Garcia, Organizer 6:00-8:00 101. Infrared interpretation tools for polymer spectroscopy. M. Boruta, J. Chalmers, G. M. Banik 102. Polymer adsorption on nano-heterogeneous surfaces. Y. Huang, V. K. Gupta
103. Preparation and properties of nylon1010/montmoriHonite by melt intercala tion. Z. Liu, D. Yan 104. Nanopatteming of fibrous proteins. D. L. Wilson 105. Poly(methyl methacrylate)-clay nano composites by bulk, solution, and sus pension surface initiated polymerization. X. Fan, C. Xia, R. Advincula 106. Preparation of acrylonitrile-butadienestyrene triblock copolymer electrospun nanofibers. Y. Hong, Z. Yang, Q. Yang, Z. Li, C. Wang 107. Properties of polyvinyl alcohol)/montmorillonite nanocomposite fibers. Y. Wang, Y. Wang, D. Yan 108. Doping effect of carbon nanotubes on polyaniline. H. Zengin, W. Zhou, J. Jin, R. Czerw, D. W. Smith Jr., L A. Echegoyen, D. Carroll, S. H. Foulger, J. Ballato 109. Morphology and mechanical behavior of styrene-based block copolymer/ silicate nanocomposites. T. Kwee, K. A. Mauritz 110. Motion of two electrons on a cylindrical nanoparticle. S. K. Knudson, M. D. Barnes, B. G. Sumpter, D. W. Noid 111. Novel polyimide-nickel oxide nano composite materials with magnetic property via in situ chemical processing. Z. Bai, S. C. Tan 112. Design of nanoporous polymeric materials using reactive encapsulation of a chemically inert solvent. V. I. Raman, G. R. Palmese 113. Preparation and characteristics of biodegradable aliphatic polyester-poly(epichlorohydrin) blend/organoclay nanocomposites. S. T. Lim, C. H. Lee, H. B. Kim, H. J. Choi, M. S. Jhon 114. Preparation and characterization of transparent polypropylene oxide)/silica composites. G. S. Sur, T. J. Lee, H. Sun, J. E. Mark 115. Microcellular foams from aminated polysulfone/polybenzimidazole molecular composites. H. Sun, N. Venkatasubramanian, M. D. Houtz, J. E. Mark, F. E. Arnold 116. Electrical properties of organogermanium nanocluster film. A. Watanabe, M. Unno, F. Hojo, T. Miwa 117. In situ nanocomposites via solid-state modification in porous polymers. S. H. Jain, H. Goossens, F. Picchioni, M. van Duin 118. Synthesis of functionalized triblock copolymers and their applications in dispersing magnetic nanoparticles. K. D. Belfield, Y. Wang 119. Structural investigations of Surlyn ionomer/titanate nanocomposites formed by an ionomer in situ sol-gel process. P. R. Start, M. A. Sharp, K. A. Mauritz 120. Atomic force microscopy study of the morphology of a triblock copolymer (BCP), sulfonated BCP, and a BCP/silicate hybrid produced by a templated sol-gel process. R. I. Blackwell, K. A. Mauritz 121. In situ precipitation of ferrous (hydrous oxide) and iron oxide particles in poly(dimethylsiloxanes). S. Murugesan, G. Beaucage, J. Mark 122. Analysis of an order-order transition of a triblock copolymer (BCP), sulfonated BCP (sBCP), and sBCP/silicate hybrid by dynamic mechanical analyses. R. I. Blackwell, K. A. Mauritz 123. Pyrolitic preparation of porous C/C composite from coal tar pitch-based thermosetting resin and activated carbon powder. M. Ota, H. Ohmiya, Y. Aoyagi, J. Kametani, H. Tomosaka, K. Hiraishi, S. Otani 124. Semiconductor nanoparticle/polystyrene latex composite materials. R. L. Sherman Jr., W. T. Ford 125. Preparation of poly(trimethylene terephthalate)/montmorillonite nanocom posite by melt intercalation. Z. Liu, D. Yan, K. Chen 126. Poly(trimethylene terephthalate)montmorillonite nanocomposite made by in situ polymerization. Q. Duan, D. Yan
127. Phase behaviors in solution-processed perfluorosulfonate ionomers. A. K. Phillips, R. B. Moore 128. Correlations between bulk mechanical relaxations and spin diffusion times in perfluorosulfonate ionomers: Molecular origins of mechanical relaxations. K. A. Page, R. B. Moore 129. Influence of ionomeric compatibilizers on the morphology and properties of amorphous polyester/polyamide blends. G. C. Gemeinhardt, A. A. Moore, R. B. Moore 130. Ionic conductivity studies of methyl polysiloxane polymer electrolytes with oligo(oxyethylene) side chains. J. J. Jin, L. J. Lyons, Q. Wang, R. West 131. Ion-containing acrylamide copolymers with pH- and salt-responsive behavior. M. J. Fevola, R. G. Ezell, J. K. Bridges, C. L. McCormick 132. Study on crystalline transition in eveneven nylons based on hexadecane diacid. W. Li, D. Yan 133. Water transport through poly(styrenefc-isobutylene-6-styrene) ionomers via ATR-FTIR spectroscopy. D. A. Mountz, J. G. Kopchick, K. A. Mauritz 134. Diffusion of water in epoxy resins cured by active ester: ATR-FTIR studies. S. Li, M. Liu, P. Wu, Y. Ding 135. Broadening light reflection band in cholesteric liquid-crystal films. K. Song, Y. Kwon, H. Lee, J. Lee, I. Kim 136. Hyperbranched polyphenylenes: Synthesis, light emission, and opticallimiting properties. H. Peng, J. W. Y. Lam, R. Zheng, M. HauBler, J. Luo, K. Xu, B. Z. Tang 137. Perfluorocyclobutyl copolymers for electro-optics. D. W. Smith Jr., S. Suresh, S. Chen, C. M. Topping, J. Ballato 138. A new low-bandgap conducting poly mer. I. T. Kim, S. W. Lee, J. Y. Lee 139. Novel two-photon absorption chromophore and its incorporation into silicones. S. Oztemiz, M. C. Jobanputra, S. J. Clarson 140. Polymer light-emitting diode properties of polyfluorene and electrochemically polymerized polyvinylcarbazole (PVK). K. Onishi, R. Advincula 141. Fluorescence image pattern using a chemically amplified diphenylmaleimide dye. N. C. Yang, Y. M. Yoo, J. K. Kim, D. H. Suh 142. Self-assembled heterocyle-based films: Properties of novel pyridine-pyrrole chromophores anchored to functional ized siliceous substrates. A. Facchetti, A. Abbotto, L. Beverina, M. E. van der Boom, T. J. Marks, G. A. Pagani 143. Self-assembly and photovoltaic prop erty of multilayer film based on partially doped polyaniline and poly(4-carboxyphenyl) acetylene. Y. Guijun, W. Boqiu, D. Yuping, Z. Maofeng, Y. Zhaohui, Y. Qiaoling, J. Wing Yip Lam, T. Benzhong 144. Fluorescence studies of hydrophobic association of fluorocarbon-modified poly(/V,/V-dimethylacrylamide). S. J. Tomczak, T. E. Hogen-Esch 145. Synthesis, thermal stability, and optical properties of hyperbranched polyarylenes containing carbazole moieties. M. HauBler, J. W. Y. Lam, H. Peng, R. Zheng, Β. Ζ. Tang 146. DNA capillary electrophoresis using polyvinyl alcohol) I: Inner capillary coating. T. Moritani, K. Yoon, B. Chu 147. Kinetics and radical characterization of aryl trifluorovinyl ether polymerization using ESR spectroscopy. V. Mellon, N. Mifsud, C. M. Topping, L. Echegoyen, D. W. Smith Jr. 148. Detection of immobilized protein on latex microspheres by IR-visible sumfrequency generation and friction force microscopy. T. Koffas, J. Kim, G. A. Somorjai 149. Rheological behavior of lyotropic (acetyl)(ethyl)cellulose solutions. Q. Dai, J. F. Kadla, R. D. Gilbert, S. A. Khan
150. Crystallization and melting behaviors of freeze-dried isotactic polypropylene. L. Chen, X. Zhu, D. Yan 151. Positron annihilation studies in poly carbonate and polystyrene at the glass transition induced either by temperature or pressure changes. R. Kirchheim, J. Bohlen 152. Investigation of rheological properties of a polyacrylate thickening agent. J. Wang, Q. Tian, J. Wang, S. Yu, D. Liu 153. Investigation of rheological properties of a polyacrylate thickening agent pre pared by inverse emulsion polymeriza tion. J. Wang, X. Li, S. Yu, D. Liu 154. FT-IR studies of stereoregular PMMA adsorbed on silica: Effects of the drying process. B. Zhang, S. Suriyaphongse, K. Suriyaphongse, F. D. Blum 155. Solution properties of emeraldine base form of polyaniline by recording mem brane osmometry. H. Zengin, H. G. Spencer, R. V. Gregory 156. Studies of the supramolecular organi zation of amphiphilic copolymers into nanomicelles by light-scattering tech niques. M. H. Chen, R. Kumar, K. Yang, V. S. Parmar, L. A. Samuelson, J. Kumar, A. C. Watterson 157. Thermal properties of the liquid silk for the domestic and wild silkworms by DSC measurement. T. Tanaka, M. Kobayashi, H. Tsuda, S. Inoue, J. Magoshi 158. Effect of surface energy on the crystal line microstructure near the interface and its effect on interfacial adhesion. K. Cho, D. Kim 159. Morphology and structure of nylon 2 22 lameller crystal. G. Zhang, W. Li, D.Yan 160. Conformational change of high-density polyethylene during the crystallization from the melt. Y. Xiao, X. Zhu, L Yan, D.Yan 161. Chiral liquid-crystalline phases and transition behavior of a synthetic mainchain polyester with molecular asymme try. X. Weng, C. Y. Li, S. Jin, J. Z. Zhang, D. Zhang, F. Bai, F. W. Harris, S. Z. D. Cheng, B. Lotz 162. Polyvinyl alcohol) cryogels employed for cell immobilization of Rhodococcus rhodochrous and their properties. D. Zaragoza, J. Romero, Μ. Ε. Calixto, A. Ledezma 163. Enzyme immobilization via electrospinning of polymer/enzyme blends. Y. Wang, Y. Hsieh 164. Silkworm regulates the fibroin liquid gel using a gradient of concentration of calcium and potassium ions. H. Tsuda, T. Tanaka, S. Inoue, Y. Magoshi, J. Magoshi 165. Degradation of PET under supercritical methanol. H. Wang, X. Zhao, X. Liu, Y. Zheng, Z. Wu, Y. Zhou 166. Degradation of PBT under supercritical methanol. H. Wang, Y. Zheng, Z. Wu, Y. Zhou 167. Modification of cellulose by graft copolymerization of comonomers using eerie ammonium nitrate as the initiator. K. C. Gupta, S. Sahoo 168. Purification of cyclic poly(oxyethylene) by inclusion complexation of linear by-products with a-cyclodextrin. S. Singla, T. Zhao, H. W. Beckham 169. Postcoupling of enzymatically synthe sized phenolic polymers for sensing hazardous and explosive type species. V. Kumar, A. Dhawan, X. Wang, V. S. Parmar, L. Samuelson, J. Kumar, A. Cholli 170. Polynaphthalene network polymeriza tion kinetics of substituted BODA deriva tives. P. U. Perera, M. W. Perpall, D. W. Smith Jr.
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-123
TECHNICAL PROGRAM 171. Surface modification of porous silicon dioxides achieved using conventional solution-phase reagents under solventfree conditions. A. Taralp, D. Demirgoz, H. T. Vakos, G. A. Urbina, W. Voelter 172. Molecular modeling of penetrants in aromatic polyimides. D. L. Hudson, J. A. Hinkley, T. C. Clancy, M. S. Reeves 173. Monte Carlo simulation for confine ment-induced molecular alignment. C. Shew 174. Pressure-induced cis to trans isomerization of poly(para-methylthiophenylacetylene) prepared by a [Rh(norbomadiene)CI]2 catalyst. K. Huang, Y. Mawatari, M. Tabata, T. Sone, Y. Sadahiro 175. Sulfonated poly(thioether ketone)s with high oxidation resistance to peroxides. G. Xiao, G. Sun, D. Yan 176. UV-Vis studies of nylon degradation. R. Bernstein, D. K. Derzon, K. T. Gillen 177. Macromolecular helicity induction in poly(phenylisocyanate) derivative bear ing crown ether. R. Sakai, T. Satoh, R. Kakuchi, H. Kaga, T. Kakuchi 178. Effect of surface charge on acid dye uptake by nylon-6,6. S. Michielsen, M. Bahkshaee 179. Rheological properties of polyethersulfone with polyetherimide-modified epoxy resins. X. Tang, S. Li 180. Materials for high-energy radiation shielding in space. R. L. Kiefer, D. R. McGlothlin, J. L Chapman, S. A. Thibeault 181. Viscoelastic effects on the late stages of phase separation in thermoplasticthermoset blends. W. Gan, Y. Yu, M. Wang, Q. Tao, S. Li 182. Monte Carlo simulations combined with micromechanics to predict effective elastic moduli of elastomeric nanocomposites filled with unidirectional rigid inclusions. M. A. Sharaf, I. M. Jasiuk, K. I. Jacob 183. Studies of aqueous polymerization of 2-acrylamido-2-methyl-1-propanesulphonic acid initiated by peroxydiphosphate/Ag(l) redox pair: A kinetic study. R. Kumar, A. Srivastava, K. Behari 184. Improvement of production of β-cyclodextrin complexes using a high-concen tration coprecipitation method. Ζ. Η. Qi 185. Methanol permeation of sulfonated poly(arylene ether sulfone) copolymers. Y. S. Kim, L Dong, M. Hickner, J. E. McGrath, B. Pivovar 186. Modeling random crosslinking of polymer chains. L Shiau 187. Computer simulations on the chain deformations of poly(ethylene) by ran domly oriented prolate filler particles arranged on a cubic lattice. M. A. Sharaf, R. H. Abouhussein 188. Polyurethane/acrylic composite poly mer latex interpenetrating network hybrid emulsions. L. Chen, S. Chen 189. Properties of polyether polyols cata lyzed by Fe/Zn double metal cyanide complex catalysts. S. Chen, N. Xu, J.Shi 190. Properties of self-crosslinking acrylate latex films containing fluorine. Y. Chen, Y. Wang, P. Chen, S. Cheng, C. Zhang 191. Amphiphilic secondary structure in phenylene ethynylenes. G. N. Tew, L. Amt, T. Jones
124-TECH
192. Investigation of the structure-morphol ogy-property behavior of thermoplastic polyurea copolymers based on polyether and polydimethylsiloxane soft segments. I. Yilgor, E. Yilgor, G. E. Atilla, A. Ekin, Y. Utku, P. Kurt, J. P. Sheth, G. L. Wilkes 193. Mechanism of fiber formation of mul tiple spinning by silkworm. J. Magoshi, T. Tanaka, S. Inoue, H. Tsuda, Y. Magoshi, T. Hâta, M. A. Becker, B. Lotz 194. Stereoselection in the formation and folding of β-helical polyisocyanopeptides. J. J. L. M. Cornelissen, G. A. Metselaar, N. A. J. M. Sommerdijk, A. E. Rowan, R. J. M. Nolte 195. Helical crystal twist sense and two levels of crystal twinning in a chiral main-chain liquid-crystalline polyester. X. Weng, C. Y. Li, S. Jin, D. Zhang, J. Z. Zhang, F. Bai, F. W. Harris, S. Ζ. D. Cheng, B. Lotz 196. Catalytic properties of PPI dendrimers on ester hydrolyses. M. Chai, D. He, R. J. Morgan, A. Christen Section C General Papers Polymer Synthesis D. Garcia, Organizer 6:00-8:00 197. Low-generation dendritic mesogenic disc-rod hybrids. C. D. Foytik, M. R. Korn 198. Nonlinear optical polyimide containing hyperbranched chromophores. J. Y. Do, S. K. Park, S. Park, J. Ju, M. Lee 199. Synthesis and characterization of bis(edot)-aryl photoluminescent materi als. R. V. Gregory, S. S. Hardaker, M. F. Pepitone, K. Eaiprasertsak 200. Synthesis and some properties of hyperbranched polyaryleneetherketoneco-polybenzobisthiazole-co-hyperbranched polyaryleneetherketone ABA triblock copolymers. J. Baek, C. B. Lyons, L. Tan 201. Synthesis and characterization of novel PPE-m-PPV hybrid polymers. Q. Chu, Y. Pang 202. Ti(lll)-catalyzed living radical polymer ization of styrene initiated by benzoyl peroxide. A. D. Asandei, I. W. Moran, M. A. Castro 203. Ti(lll)-catalyzed radical ring opening of styrene oxide and living radical polymer ization of styrene. A. D. Asandei, I. W. Moran 204. Living radical polymerization of styrene catalyzed by silver(ll) and copper(ll) tetraphenylporphyrins. A. D. Asandei, I. W. Moran, C. Bruckner 205. Synthesis and properties of aliphatic spirodilactam diphenol containing poly esters. E. Bucio, J. W. Fitch III, L. Martinez, S. Venumbaka, P. E. Cassidy 206. Synthesis and properties of polyurethane gels for stress-distributing func tion. G. C. Cha, K. H. Kim, M. S. Mun, S. Lee 207. Synthesis of a heterogeneous rotaxanated polymer: Polypseudo(methyl methacrylate)-rotaxa-(dimethylsiloxane). B. M. White, W. P. Watson, H. W. Beckham 208. Synthesis of poly(vinylamine) copoly mers by the ROMP of temporarily strained cyclic olefins. J. P. Jordan, O. A. Scherman, R. H. Grubbs 209. Toward poly(3- and 3,4-alkoxythiophenes). E. E. Sheina, S. M. Khersonsky, E. G. Jones, R. D. McCullough 210. AB + Cn approach to aliphatic hyper branched polyamides. C. Gao, Y. Xu, H. Zhang, D. Yan
211. Novel poly(ester-amide)s from lactide and depsipeptides. D. W. Smith Jr., N. K. Abayasinghe, S. Suresh 212. Sulfonated poly(arylene ether sulfones) containing hexafluoroisopropylidene unit: Influence of sulfonic acid position on stability and other properties. W. L. Harrison, F. Wang, K. O'Connor, N. Y. Arnett, Y. S. Kim, J. E. McGrath 213. 2-Alkyl-2-oxazoline lipopolymers for the construction of polymer-tethered lipid bilayers. A. Foertig, R. Jordan, O. Purrucker, M. Tanaka 214. Solventless polymerization to grow thin films on solid substrates and its applications. H. Gu, D. Fu, C. Xu, J. Tang, B. Xu 215. Synthesis and dielectric constants of polymers with cyclic carbonate pendant groups. A. P. Purdy, E. Levien, A. Hwang 216. Synthesis and micelle formation of dumbbell-type amphiphilic block copoly mer. C. G. Cho, S. An, J. E. McGrath 217. A study of the A2 + B3 reaction of fumaric acid and trimethylolpropane. H. Lusic, E. Fossum 218. Core-shell acrylate latex containing fluorine and silicon in the shell. P. Chen, Y. Chen, Y. Wang 219. Hyperbranched poly(arylene arylene phosphine oxide)s via an A2 + B3 approach. E. Fossum, L. Tan 220. Heating characteristics and polymer ization of ε-caprolactone under micro wave irradiation. L. Liao, L. Liu, C. Zhang, R. Zhuo 221. Preparation of hyperbranched poly(arylene ether phosphine oxide)s via A2 + B3 approach. M. M. Czupik, E. Fossum 222. Microwave irradiation effect on the polymerization of ε-caprolactone with benzoic acid as the initiator. Z. Yu, L. Liu, Y. Song, R. Zhuo 223. Preparation of sulfoxide-containing polymers and their potential use as substantive skin moisturizing agents. R. D. Fossum, M. A. deLong, R. M. McCorkle, L. J. Smith, G. R. Fuentes 224. Comparative assessment of methods for the preparation and characterization of polymer-supported sulfonyl chloride resin. A. Cusak, C. Charlesworth, K. J. Bedregal, D. M. Ketcha 225. Microwave-assisted ring-opening polymerization of trimethylene carbon ate. C. Zhang, L. Liu, L. Liao, R. Zhuo 226. Concise synthesis of the polyrotaxane from α-cyclodextrin and polyethylene glycol). T. Zhao, H. W. Beckham 227. Organo-soluble aromatic polyimides from 3,3' ,5,5'-tetrabromo-2,2-bis[4-(4aminophenoxy)phenyl]propane. R. C. Tsiang, K. Hung 228. Emulsion polymerization of novel vegetable oil macromonomers. C. C. Blackwell, S. N. Shah, O. W. Smith, S. F. Thames 229. Polymerization of Λ/,/V-methylenebisacrylamide by potassium peroxydiphosphate in the presence of Mn(ll) and Ag(l). R. Kumar, A. Srivastava, K. Behari 230. Facile method for preparation of ultralow dielectric constant polymer films. H. Zhou, V. M. Mannari, S. Venumbaka, J. W. Fitch III, P. E. Cassidy 231. Controlled polymerization of a methacrylamido monomer in aqueous media via RAFT. Y. A. Vasilieva, D. B. Thomas, P. Hennaux, C. L. McCormick 232. Preparation of hyperbranched polyes ters from benzene-1,2-4-tricarboxylic1,2-anhydride and dihydroxy alcohols. K. Wang, C. Gao, W. Huang, D. Yan 233. Design and synthesis of a new fluorinated polyphenylenevinylene "SF-PPVII". J. Haliburton, S. Sun 234. Synthesis and characterization of a new polythiophene with fluorinated substituents. S. Thomas, S. Sun
235. Synthesis and characterization of conjugated polymers incorporating an amino acid analog. D. W. Flanagan, D. A. Tirrell 236. Synthesis and characterization of dendrons with energy gradients. K. Bronk, S. Thayumanavan 237. Synthesis and characterization of novel poly(azomethine urethane)s. J. Ismail, I. Ahmed 238. Synthesis and polymerization of a diaminodiol containing a phosphineoxide linkage. W. A. Feld, M. J. Dalton, T. D. Dang, N. C. Thiesing, S. C. Sims, Κ. Μ. McGinty 239. Synthesis of hexafluoroisopropylidenelinked benzophenone polymers. D. D. Andjelkovic, V. V. Sheares 240. Synthesis of hyperbranched polymers by self-condensing vinyl oxyanionic polymerization. Z. Jia, D. Yan 241. Synthetic methodologies leading to multifunctionalized dendritic surfaces. K. Sivanandan, D. Vutukuri, S. Thayumanavan 242. Thermal solid-state polymerization of 4-ethynylbenzoic acid. J. M. Njus, L. Yang, B. M. Foxman, D. J. Sandman 243. Versatile route to polybenzophenone triblock copolymers. E. C. Hagberg, V. V. Sheares 244. Controlled initiation of polymerization reactions using microencapsulation techniques. Β. Η. McFarland, J. A. Pojman 245. Molecular design and synthesis of a novel aromatic macrocycle with a [1,1']binaphthalenyl moiety and a p-chlorophenyl substituent. G. Dang, W. Yang, C. Chen, Y. Wei, W. Zhang, Z. Wu 246. Living polymerization of Λ/,/V-diphenyl acrylamide with triisobutyl aluminum. Y. C. Kim, S. Y. Kim 247. Precision synthesis of organic/inor ganic hybrid nano-architectures by living radical polymerization. K. Koh, K. Ohno, Y. Tsujii, T. Fukuda 248. Synthesis of sulfur-containing poly(ether ether ketone ketone) copolymers. X. Zhao, X. Liu, Z. Gao, C. Chen, W.Zhang 249. ATRP grafting reactions on poly(methylphenylphosphazene). P. Wisian-Neilson, J. N. Cambre 250. New materials derived from polyphosphazenes. P. Wisian-Neilson, T. Kmecko 251. Perfluorocyclobutyl copolymers con taining polyhedral oligomeric silsesquioxanes for potential optical application. D. W. Smith Jr., W. Zhou, S. Suresh, S. Chen, J. Ballato 252. Poly(methylphenylphosphazene)-Q7aftpoly(ester) copolymers. P. Wisian-Neilson, P. S. Kumar 253. Polymerization of 3-phenoxybenzoic acid in the presence of vapor-grown carbon nanofiber. J. Baek, C. B. Lyons, LTan 254. Sulfo-pendent poly(p-phenylenebenzobisazole) rigid-rods: Synthesis and fiber structural studies. T. D. Dang, H. Koerner, M. J. Dalton, A. lacobucci, N. Venkatasubramanian, F. E. Arnold 255. Synthesis and characterization of germole-containing hyperbranched polyphenylenes. C. W. Law, J. Chen, Β. Ζ. Tang 256. Synthesis, characterization, and prop erties of poly(p-phenylene) derivative. I. T. Kim, S. W. Lee, H. S. Park, T. H. Kwak, C. M. Lee, S. Y. Kim
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POLY/TECHNICAL PROGRAM
257. Gel formation in organic solvents: Synthesis and association of copolymers of /V,/V-dimethylacrylamide and methacrylates having perfluorocarbon pen dent groups connected through polyethyleneoxide spacers. J. Da, T. Hogen-Esch 258. Mechanistic aspects of catalytic chain transfer by a cobalt(ll) porphyrin in the radical polymerization of MMA. Y. Li, B. B. Wayland 259. Microwave-assisted synthesis of poly(e-caprolactone) with acid as initiator and a novel method in preparation of drug-release systems. Y. Song, L. Liu, Z. Yu, X. Weng, R. Zhuo 260. Synthesis and complexation of ligands useful for structure-activity relationships in ATRP. J. M. Goodwin, M. M. Olmstead, T. E. Patten 261. New insights in Ru-catalyzed acyclic diene metathesis polymerization. F. C. Courchay, J. C. Sworen, K. B. Wagener 262. Novel organosoluble cardo poly(amide-imide)s derived from 2,2-bis[4-(4trimellitimidophenoxy)phenyl]norbornane: Synthesis and characterization. D. Liaw, W. Chen 263. Novel polynorbornene with crosslinkable groups derived from methacryloyloxyethyl isocyanate via ring-opening metathesis polymerization. D. Liaw, C. Huang, S. Hong 264. Preparation of new diblock polymeric materials with carbazole groups derived from the combination of living ringopening metathesis polymerization and atom transfer radical polymerization. D. Liaw, C. Huang 265. Olefin isomerization promoted by olefin metathesis catalysts. S. E. Lehman Jr., P. M. O'Donnell, J. E. Schwendeman, Κ. Β. Wagener 266. Peroxidase-catalyzed polymerization of 4-aminothiophenol on surfaces via dip-pen nanolithography. P. Xu, D. L. Kaplan 267. Synthesis and characterization of a novel soluble fluorescent polyimide from 1,3-bis(4-piperidino-1,8-naphthalic anhydride)propane. W. Huang, D. Yan, Q. Lu 268. Synthesis of regioregular and stereoregular ethylene vinyl alcohol copoly mers via ROMP of a protected cylcooctene-5,6-(c/s and frans)-diol. 0. A. Scherman, R. Walker, R. H. Grubbs 269. Synthesis, chirality, and liquid crystalunity of poly(phenylacetylenes) contain ing stigmasterol pendants. L. M. Lai, J. W. Y. Lam, K. K. L. Cheuk, Β. Ζ. Tang 270. Synthesis and properties of hyperbranched polyarylenes prepared by niobium-catalyzed polycyclotrimerization of diacetylenes. R. Zheng, H. Peng, J. W. Y. Lam, J. Chen, M. HâuBler, Β. Ζ. Tang 271. Synthesis, helicity, and mesomorphism of ergosterol-containing poly(phenylacetylene)s. L. M. Lai, J. W. Y. Lam, K. K. Cheuk, Β. Ζ. Tang 272. The synthesis and characterization of carbazolyl azomethine. M. Sun, F. Liao, Y. Meng, H. Zhang, H. Li, D. Wang, J. Wang 273. A new highly versatile water-soluble dithioester for RAFT polymerization. D. B. Thomas, A. Convertine, C. L. McCormick 274. Block copolymers of 2-(A/-piperidylmethyl)-1,3-butadiene with styrene. L. A. Rusch-Salazar, V. V. Sheares 275. Ν, Ν, Ν', Ν', ΛΓ- pentamethyldiethylenetriamine as a model compound for linear poly(N-methylethylenimine). R. A. Sanders, S. E. Boesch, R. Freeh, A. G. Snow, L. R. Hu, R. A. Wheeler, D. T. Glatzhofer
276. Sodium formate as a chain transfer agent in acrylamide polymerization: Determination of chain transfer constant. M. J. Fevola, C. L. McCormick, R. D. Hester 277. Synthesis and characterization of efficient two-photon acid generators for 3-D microfabrication. J. Wang, W. Zhou, K. L. Braun, S. Barlow, S. M. Kuebler, J. W. Perry, S. R. Marder 278. Synthesis and spectroscopic studies of macrocyclicpoly(9,9-dimethyl-2-vinylfluorene). R. Chen, T. E. Hogen-Esch 279. A synthetic strategy for the preparation of a polyphosphonate ester containing L-dopa for the treatment of Parkinson's disease. D. M. Chamely, C. E. Carraher Jr., J. E. Haky 280. Novel synthesis of polybutylacralate with thiocarbamide metal complex (Cu2+). Y. Jiang, R. Duan, K. Zhang, H. Li, J. Wang 281. One step to synthesize monodisperse core-shell nanoparticles of polystyrene and silica. Z. Yang, G. Gao, Y. Hong, L. Cheng, Y. Sun, H. Jin, M. Zhang, F.Liu 282. Modeling precise branching in polyeth ylene using metathesis chemistry. J. C. Sworen, J. A. Smith, Κ. Β. Wagener 283. Synthesis and properties of novel through-space p-conjugated polymers having [2.2]paracyclophane in the main chain. Y. Morisaki, Y. Chujo 284. Synthesis and properties of poly(aryl ether ketone)s with (3-methyl)phenyl and (3-trifluoromethyl)phenyl side groups. W. Hu, Y. Jin, C. Zhu, B. Liu, Z. Jiang, Z.Wu 285. Synthesis of nanomaterials using nanoporous polymer templates. M. A. Hillmyer, J. H. Wolf 286. Amino acid and peptide branched polyolefins by ADMET. T. E. Hopkins, Κ. Β. Wagener 287. Controlled synthesis of AB and ABC block copolymers containing fluorophilic, hydrophilic, and lipophilic segments. T. Komenda, R. Jordan 288. Synthesis and aqueous solution prop erties of a well-defined thermo-responsive schizophrenic diblock copolymer. J. V. M. Weaver, S. P. Armes 289. Activation of enamido zirconium com plexes for ethylene polymerization: Electrophilic addition versus electrophilic abstraction reaction. Y. H. Kim, T. H. Kim, E. S. Cho, B. Y. Lee, Ν. Υ. Kim 290. Direct synthesis of isotactic polypro pylene containing a terminal functional group via metallocene catalysis. J. Y. Dong, T. C. Chung 291. Dye-amine conjugates as novel photoinitiators for polymerization. I. A. Banerjee, G. A. Epling 292. Effect of adipic acid impurities on the oxidation of benzene phosphinic acid to benzene phosphonic acid during a nylon 6,6 polymerization process. K. K. Balasubramanian 293. Enzymatic synthesis of multicomponent copolymers and their structural characterization. R. Kumar, R. Tyagi, V. S. Parmar, L A. Samuelson, A. C. Watterson, J. Kumar 294. First water-soluble azosulfonate homopolymer by enzymatic polymeriza tion. J. P. Robert, H. Uyama, S. Kobayashi, R. Jordan, O. Nuyken 295. Fulvene having substituents only on 1, 4, and 6 positions: A key intermediate for novel ansa-metallocene complexes. Y. C. Won, H. Y. Kwon, B. Y. Lee 296. Homo- amd copolymerization of sty rene with 4-chloromethyl styrene by nickel-diimine complex catalysts. G. J. Jiang, W. Yang, K. Chuang 297. Incorporation of efficient NLO-phores into cross-linked poly(amino-amide) matrixes. A. Abbotto, L. Beverina, A. Facchetti, P. Ferruti, E. Chilberti, G. A. Pagani
298. Influencing factors of dicyclopentadiene conversion on preparation of DCPDmodified offset ink resin. J. Wang, L. Fan, D. Liu 299. Investigation of nitroxide-mediated radical polymerization of methacrylates initiated by a PS-TEMPO adduct. C. Cheng, N. Yang 300. Laser photochemical process of a diazonaphthoquinone photopolymer. J. Wei, W. Wang, Y. Huang 301. Polypropylene-polysiloxane block copolymers via hydrosilation of monovinylidene capped isotactice polypro pylene. P. Fu, S. Glover, R. K. King, C. Lee, M. R. Pretzer, M. K. Tomalia 302. Preparation and characterization of PVA-based polyelectrolyte complexes. B. Sun Sr., J. Zou II 303. Preparation of the uniform and wellorganized polyelectrolyte mutilayer films using salt annealing. S. Qin, H. Teng, Y. Shi, X. Jin 304. Radical polymerization mediated by a stable carbon radical. C. Cheng, N. Yang 305. Ring-opening polymerization of /-lactide in supercritical chlorodifluoromethane. J. W. Pack, S. H. Kim, Y. H. Kim, S. Y. Park, Y. W. Lee 306. Soluble polyimides based on alkyl groups. Y. Tsuda 307. Synthesis and characterization of amphiphilic linear-dendritic diblock copolymers for functional micelle forma tion. K. K. Stokes, S. H. Ibrahim, P. T. Hammond 308. Synthesis and characterization of polyethylene glycol) grafted on pullulan. Y. Jiao, Y. Fu, Z. Jiang 309. Synthesis and characterization of pullulan derivative-bearing grafted azobenzene groups. Y. Jiao, Y. Fu, Z. Jiang 310. Synthesis and liquid-crystalline proper ties of side-chain liquid-crystalline polymethacrylate containing DR-1 moieties. G. Fan, E. Zhou, X. Zhao, Y. Tian 311. Synthesis and microwave polymeriza tion of single-sized macrocyclic monomeric precursors of poly(ethylene isophthalate). R. Nagahata, J. Sugiyama, Y. Nakao, H. Hirata, T. Hagiwara, M. Asai, K. Takeuchi 312. Synthesis of a 5,5'-linked poly(2,2'biphenol). Q. Hu, A. Agrawal, Y. Lu, Ζ. Tang 313. Synthesis of an optically active poly mer with planar ferrocenyl units for asymmetric catalysis. H. Yu, Q. Hu 314. Synthesis of poly(silsesquioxane) by catalytic dehydrocoupling polymerization. M. Seino, I. Imae, Y. Kawakami 315. Synthesis of super high molecular weight copolymer of AM/AA/AMPS and its salt by new initiators in inverse sus pension polymerization. F. Yang, K. Liu, H.Wu Section D
318. Effect of bound water structure on the protein-substrate interaction and protein adsorption behavior. K. Cho, E. C. Cho, Y. D. Kim 319. Improving the blood compatibility of polyethylene tubing by plasma polymerization of tetraglyme. K. J. Kitching, L. Cao, B. D. Ratner, T. A. Horbett, K. Solen 320. Investigation of immobilized-type 1 collagen as an affinity coating to bind osteopontin to poly(2-hydroxyethyl methacrylate). S. M. Martin, J. L. Schwartz, C. M. Giachelli, B. D. Ratner 321. Layer-by-layer assembly of hydrolytically degradable thin films. M. S. Terrot, L. Abrishamian-Garcia, E. Vâsquez, P. T. Hammond, D. M. Lynn 322. Living radical photopolymerizations to modify surfaces in microfluidic devices for biological applications. R. P. Sebra III, J. B. Hutchison, Κ. Τ. Haraldsson, K. S. Anseth, C. N. Bowman 323. Loading and releasing of methylene blue in stable polyelectrolyte multilayer films based on DNA, diazoresin, and water-soluble polyacetylene. Y. Guijun, W. Caiqi, W. Peng, D. Yuping, J. Wing Yip Lam, T. Benzhong 324. Modification of protein microspheres for biomedical applications. F. Jean-Jacques Toublan, K. S. Suslick, S. A. Boppart, Τ. Μ. Lee, A. Oldenburg 325. Polymer surface modification for cell adhesion. D. Delmar-Greenberg, M. Azam Ali, Κ. Ε. Gonsalves 326. Preparation of protein- and cell-resis tant surfaces on Si0 2 surfaces by polyether-grafted poly(acrylic acid) thin films. J. Seong, H. Choi, G. D. Moeser, P. E. Laibinis 327. Synthesis and characterization of polyethylene glycol) end-capped poly ethylene terephthalate) with decreased protein adhesion. Q. Lin, S. Unal, A. Fomof, Y. Wei, T. Long 328. Synthesis of a thrombin-responsive drug delivery coating for cardiovascular stents. K. S. Walline, K. VanBuren, B. D. Ratner 329. Synthesis of low thrombogenic coating with horseradish peroxidase. A. Mueller, A. Haas, A. M. Benson, Ε. Μ. Graves 330. Thermo-reversible swelling of plasmaimmobilized hydrogel films. D. Schmaljohann, M. Nitschke, D. Beyerlein, C. Werner
MONDAY MORNING Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes High-Performance Elastomers, Thermosets, and Composites
Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Biochemical Technology
A. McCormick and T. E. Hopkins, Presiding
B. D. Ratner, Organizer
R. K. Pinschmidt and C. Hoyle, Organizers
6:00-8:00 316. Constructive nanolithography: Arrang ing gold nanoparticles and proteins on surfaces. D. Wouters, B. Kôsters, U. S. Schubert 317. Covalent-attached self-assembly film based on diazoresin and DNA/poly(4carboxyphenyl)acetylene and the cell culture on its surface. Y. Guijun, W. Peng, D. Yuping, C. Yujing, D. Enkun, J. Wing Yip Lam, T. Benzhong
8:00 331. Novel cyclosiloxane-based networks. P. Kurian, J. P. Kennedy 8:30 332. Isocyanate crosslinked silica: Structurally strong aerogels. G. Zhang, A. M. M. Rawashdeh, C. SotiriouLeventis, N. Leventis 9:00 333. Syntheses of elastomeric poly(carborane-siloxane-acetylene)s. M. K. Kolel-Veetil, T. M. Keller 9:30 Intermission.
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-125
TECHNICAL PROGRAM 9:40 334. Polycarbosilane elastomers via chain-internal and chain-end latent crosslinking. K. B. Wagener, P. P. Matloka, F. Zuluaga, J. C. Sworen 10:10 335. Acyclic diene metathesis polymerization of unsaturated thermotropic polyesters. H. Qin, B. J. Chakulski, P. T. Mather, G. S. Constable, E. B. Coughlin 10:40 336. Synthesis of phthalonitrile monomers and networks. M. J. Sumner, M. Sankarapandian, U. Sorathia, J. E. McGrath, J. S. Riffle 11:10 337. Design of porous materials from partially hydrolyzable interpenetrating polymer networks. D. Grande, J. Pastol, P. Guérin, S. Boileau
10:00 348. Endothelial cell traction forces on RGD-derivatized polyacrylamide substrate. D. A. Hammer, C. Reinhart, M. Dembo 10:30 349. Polyethylene glycol) diacrylate hydrogels on covalently attached eosin surface: Contact angle measurements of the surface. S. Kizilel, V. H. Perez-Luna, F. A. Teymour 11:00 350. Toward understanding the effects of surface modification on the biointerface in biosensors. J. J. Hickman, K. Lenghaus, J. Dale, D. Henry, S. Sundaram, J. W. Jenkins, L E. Locascio, M. J. Tarlov, J. Evju
Section Β
Hilton Riverside Grand Salon B9/B12
Hilton Riverside Grand Salon C16/C13 Structural Determination of Polymers via NMR Η. Ν. Cheng, Organizer,
Presiding
Section D
The Polymer Science of Everyday Things Cosponsored with The Royal Society of Chemistry and Intersociety Polymer Education Council, Division of Industrial and Engineering Chemistry, and Presidential Event
A. D. English, Organizer
A. B. Salamone, Organizer, Presiding
8:25 Introductory Remarks. 8:30 338. Multidimensional NMR of syn thetic macromolecules. P. L. Rinaldi 9:15 339. Characterization of acrylate copolymers by 2-D NMR spectroscopy. A. S. Brar 9:40 340. NMR-guided design of end caps with improved oxidation resistance. M. A. B. Meador, A. A. Frimer 10:05 341. Detailed information on ethyl ene polymers as revealed by 1 H and 13 C NMR. G. van der Velden, H. Linssen 10:30 Intermission. 10:45 342. Real-time NMR: How fast can we do it? V. M. Litvinov, A. A. Dias 11:10 343. NMR applications for sulfidosilane material characterization. M. Backer, C. Buesing, J. Gohndrone, W. Maki, S. Mealey, B. Thomas, H.Yue 11:35 344. Solution 1 7 0 NMR investiga tions of hydrolysis and oxidation in nylon. T. M. Alam, S. T. Winters, R. Bernstein, D. K. Derzon
D. Bott, C. Pugh, R. S. Moore, and K. J. Wynne, Organizers
Section C Hilton Riverside Grand Salon C18/C15 Polymeric Surface Modification: Biomedical Applications Cosponsored with Division of Biochemical Technology D. G. Castner, Presiding B. D. Ratner, Organizer 8:30 345. Temperature-responsive poly meric surface modifications by plasma polymerization: Cell and protein interac tions. B. D. Ratner, X. Cheng, Y. Wang, Y. Hanein, K. Bohringer 9:00 346. Microgradient mechanically compliant polyacrylamide gels to probe cell response. N. Zaari, P. Rajagopalan, S. K. Kim, J. Y. Wong 9:30 347. Preparation and characteriza tion of area-selectively assembled multicomponent organosilane monolayers. A. Takahara, T. Koga, H. Sakata, M. Morita, H. Otsuka
126-TECH
9:10 351. Material science and material selection in athletic footwear. Ε. Ν. Thomas 9:50 352. The pole vault—to the heights with polymer materials. M. J. Jenkins, S. N. Kukureka 10:30 353. Evolution of golf ball design and materials. R. A. Weiss, T. J. Kennedy III 11:10 354. Racquets to race cars: The use of carbon fibers in sports and recre ation. S. Smith 355. Withdrawn. 11:50 Presidential symposium remarks from ACS President Eisa Reichmanis. Section Ε Hilton Riverside Grand Salon D21/D24 2003 ACS Award in Polymer Chemistry Honoring Maurice S. Brookhart (sponsored by ExxonMobil Chemical Co.) J. M. DeSimone, E. T. Samulski, and J. E. Bercaw, Organizers 8:00 356. Recent advances in DuPont's Versipol® technology: New polar olefin copolymerizations with late-metal cata lysts. L. Johnson, A. Bennett, P. Butera, Κ. Dobbs, Ν. Drysdale, E. Hauptman, A. lonkin, S. Ittel, E. McCord, S. McLain, C. Radzewich, A. Rinehart, R. S. Schiffino, K. J. Sweetman, J. Uradnisheck, L. Wang, Y. Wang, Z.Yin 8:30 357. New class of nickel-catalyzed polar olefin copolymerizations. C. E. Radzewich, L. K. Johnson, S. J. McLain, K. J. Sweetman, P. Butera, S. D. Ittel, J. Uradnisheck, E. F. McCord 9:00 358. GavilanSM single-site catalyst technology: Adventures in polyolefin catalyst design and development. C. M. Killian, P. B. Mackenzie, L. S. Moody, J. A. Ponasik Jr., G. G. Lavoie, J. C. Pearson, L. A. Tucker, M. R. Moore, A. K. Farthing, G. A. King, M. D. Meadows, E. P. Savitski 9:30 359. Late transition metal catalysis in controlled/living radical polymerization. K. Matyjaszewski
10:00 360. Nonbiological macromolecules with biological functions. V. Percec 10:30 361. Discovery and development of catalysts for the synthesis of defined polymer architectures. G. W. Coates 11:00 362. Styrene and ethylene polymer ization with titanium catalysts: Role of oxidation state and coordination geom etry. R. M. Waymouth, M. Mahanthappa, K. Huang 11:30 363. Kinetic resolution of chiral α-olefins via asymmetric polymerization catalysis. J. E. Bercaw, C. Baar, E. Min, T. Agapie Macromolecules to Bioparticles: Analyses with Field-Flow Fractionation Cosponsored with Division of Analytical Chemistry
Section C Hilton Riverside Grand Salon C18/C15
MONDAY AFTERNOON
2003 ACS Award in Polymer Chemistry Honoring Maurice S. Brookhart (sponsored by ExxonMobil Chemical Co.)
Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Advances in Precursors for Crosslinked Systems and Powder Coatings S. Kobayashi and R. Advincula, Presiding R. K. Pinschmidt Jr. and C. Hoyle, Organizers 1:00 364. Catalysis in polyisocyanate manufacture. F. U. Richter, J. Schmitz, H. J. Laas, R. Halpaap 1:30 365. Aliphatic polyurea coatings based on polyaspartic esters. E. P. Squiller, R. R. Roesler 2:00 366. Novel urethane oligomers from cyclic carbonates: Moving beyond reac tive diluents. D. A. Wicks, R. R. Gutierrez 2:30 367. Acetoacetate chemistry for high-solid coatings resins. S. J. Marsh 3:00 Intermission. 3:10 368. Synthesis and self-crosslinking of glycidyl carbamate functional oligo mers. D. C. Webster, P. A. Edwards, J. Erickson 3:40 369. Superdurable powder coatings and the effect of crosslinking chemistry. D. Foster 4:10 370. Catalysis in uretdione powder coatings enables innovative processing lines. M. Gedan-Smolka, F. Lehmann, D. Lehmann 4:40 371. Crosslinking in powder coat ings: Epoxy wrinkle. V. R. Reichert, S. K. Basu, L E. Scriven, L. F. Francis, A. McCormick Section Β Hilton Riverside Grand Salon C16/C13 Structural Determination of Polymers via NMR A. D. English, Organizer,
2:45 375. Thin-film perfluoropolyether dynamics on silica: 13C NMR studies. Y. Kim, C. A. Klug, C. G. Wade, C. W. Frank 3:10 Intermission. 3:25 376. N-dimensional NMR techniques for studying hydrocarbon-based polymer structures. P. L. Rinaldi, M. Monwar, E. F. McCord, D. R. Marshall, M. Buback, H. Latz 3:50 377. Super-high solids coatings: Reactive monomer molecular structure. A. J. Beeler, A. D. Burri, A. D. English, P. W. Uhlianuk, D. Paquet Jr. 4:15 378. Compositional heterogeneity in NMR polymer analysis. H. N. Cheng
Presiding
Η. Ν. Cheng, Organizer 1:30 372. Structural control in polyethyl ene-like polyesters by regularly spaced "defects": A solid-state NMR study. M. G. Menges, J. Penelle, K. Schmidt-Rohr 1:55 373. Solid-state NMR investigation of polymers with some interesting optoelec tronic properties: Biocatalytically synthe sized polyaniline. A. L. Cholli, S. Sahoo, J. Kumar, R. Nagarajan, S. Roy 2:20 374. New techniques for NMR spec troscopy of monomer-thin liquid polymer films. M. H. Sherwood, B. Schwickert
J. M. DeSimone, Ε. Τ. Samulski, and J. E. Bercaw, Organizers 1:00 379. Late transition metal catalysts as the new frontier in copolymerization of α-olefins and polar monomers with ethylene: A computational exploration. T. Ziegler, A. Michalak 1:20 380. Where are the chain ends in semicrystalline polyethylene? C. Wutz, Ε. Τ. Samulski, M. S. Brookhart, M. Tanner 1:50 381. Homogeneous and heteroge neous polymerizations in C0 2 . J. M. DeSimone 2:20 382. Award Address (ACS Award in Polymer Chemistry, sponsored by ExxonMobil Chemical Co). Olefin poly merization and copolymerization reac tions catalyzed by Ni(ll) and Pd(ll) complexes of bulky aryl-substituted α-diimines. M. S. Brookhart Section D Hilton Riverside Grand Salon B9/B12 The Polymer Science of Everyday Things Cosponsored with The Royal Society of Chemistry and Intersociety Polymer Education Council, Division of Industrial and Engineering Chemistry, and Presidential Event R. S. Moore, Organizer, Presiding D. Bott, C. Pugh, K. J. Wynne, and A. B. Salamone, Organizers 1:30 383. Aramids in protective materials. V. Gabara 2:10 384. Body armor. A. J. Ryan, S. A. Van Natta 2:50 385. Polycarbonate in consumer applications. D. G. Hamilton, J. B. McDermott 3:30 386. Polymers in the mountains. R. A. L. Jones 4:10 387. The science of tires: History and current technology. L. J. Mathias, G. J. Brust, A. Adams
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
POLY/TECHNICAL PROGRAM
Section Ε Hilton Riverside Grand Salon D21/D24 2003 ACS POLY Division Carl S. Marvel Award in Creative Polymer Chemistry Honoring James Hedrick (sponsored by the Dow Chemical Co. Foundation) J. E. McGrath, Organizer, Presiding 1:00 388. Hard segment connectivity in low molecular weight "tri-segmenf polyurethanes based on monols. G. L Wilkes, A. Aneja 1:30 389. Macromolecule-magnetite complexes. J. S. Riffle, A. Y. Carmichael, L. A. Harris, K. R. Wilson, J. D. Goff, T. G. St. Pierre 2:00 390. Biodegradable polymers for in vivo integration. J. G. Hilborn, B. Atthoff, F. P. J. Nederberg, T. Bowden 2:30 391. Chemistry at the nanoscale interface: Surface functionalization of nanoimprinted features. K. R. Carter 3:00 392. Stepping toward living polymer ization: Potential synergies of branching and functionality. T. E. Long, B. J. Love, J. R. Lizotte, D. T. Williamson, S. R. Trenor, C. L. Elkins, L. Kilian 3:30 Intermission. 3:40 393. Controlled polymerization meth ods for the synthesis of novel polymer architectures and materials. R. M. Waymouth, Ν. Β. Bowden, K. A. Willets, F. J. Gomez, R. Chen, G. Gavranovic, G. G. Fuller, H. Dai, J. L. Hedrick, C. J. Hawker 4:10 394. Polymeric nanogels as agents for gene and antisense delivery. J. M. DeSimone 4:40 395. Reactive engineering thermo plastic tougheners for thermosets. J. E. McGrath 5:10 396. Award Address (ACS POLY Division Carl S. Marvel Award in Cre ative Polymer Chemistry, sponsored by Dow Chemical Company Foundation). From spin-on to self-assembly: Current and future opportunities for polymer science in advanced microelectronics. J. L. Hedrick Colloidal and Molecular Electro-Optics Advances in Methodology Cosponsored with Division of Colloid and Surface Chemistry MONDAY EVENING Colloidal and Molecular Electro-Optics General Poster Sessions Cosponsored with Division of Colloid and Surface Chemistry TUESDAY MORNING Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Theory and Methods in Crosslinked Systems T. Nguyen and H. A. Nash, Presiding R. K. Pinschmidt Jr. and C. Hoyle, Organizers 8:20 397. Design of polymer networks by variation of precursor structure and crosslinking regime. K. DuUek, M. DuÙkovâ-Smrèkovâ, J. Huybrechts 8:50 398. Modeling the polymerization behavior of crosslinking, afunctional monomers via computer simulation. K. L. Diamond, R. B. Pandey, S. F. Thames 9:20 399. Networks of polyvinyl alcohol) chemically crosslinked in the solid state I: Crosslinking density, sol fraction, gel point, and size of sol molecules. T. Moritani
9:50 Intermission. 10:10 400. Microheterogeneity and stress development in curing coatings. V. Rajamani, L. F. Francis, A. McCormick, L. E. Scriven 10:40 401. High-throughput screening methodologies for coating formulations. H. Bach, C. A. Gambino, L. K. Gindin, R. M. Konitsney, P. D. Lunney, K. G. Spitler 11:10 402. New insights into the molecular weight distribution of structural elements in reactive polyurethanes. A. M. Heintz, A. De Silva, S. L. Hsu Section Β Hilton Riverside Grand Salon C16/C13 NMR Spectroscopy of Polymers New or Improved Methodologies Cosponsored with Division of Analytical Chemistry A. D. English, Organizer, Presiding Η. Ν. Cheng, Organizer 8:30 403. Local order in polycarbonate glasses by REDOR. J. Schaefer, R. D. O'Connor, B. Poliks, K. L. Wooley, Τ. Κ. Weldeghiorghis 9:15 404. NMR studies of rotaxanated polymers. H. W. Beckham, K. Nagapudi, T. E. Girardeau, T. Zhao, J. Leisen 9:40 405. NMR studies of polymers formed in and within supercritical C0 2 . A. K. Whittaker, D. J. T. Hill, K. Thurecht 10:05 406. High-field Aluminum-27 MAS NMR of methylaluminoxane. L G. Butler, L. S. Simeral, J. L. Eilertsen, P. Bobadova-Parvanova, R. W. Hall 10:30 Intermission. 10:45 407. Deuterium NMR of deformed elastomers. M. E. Ries 11:10 408. Stress relaxation of polyisoprene and polvisoprene nanocomposites monitored by Ή NMR. G. M. Poliskie, K. K. Gleason, R. E. Cohen 11:35 409. Rheological NMR investiga tions of polymer melts. U. Scheler, A. Gottwald Section C Hilton Riverside Grand Salon C18/C15 Polymer Design Using Non-covalent Methods I T. E. Long and V. Rotello, Organizers, Presiding R. A. Gross and E. W. Meijer, Organizers 8:30 410. Tutorial on self-assembling polymers and organic nanotechnology. S. I. Stupp 9:15 411. Supramolecular polymer chem istry: New hydrogen bonding modules and new polymer architectures. S. C. Zimmerman 9:40 412. Hydrogen-bonded bis-2-pyridone liquid-crystalline main-chain asso ciation polymers. A. C. Griffin, P. J. McMullan 10:05 413. Synthesis and characterization of self-complementary multiple hydrogen bonding poly(isoprene) star polymers. C. L. Elkins, K. Yamauchi, T. E. Long 10:30 414. Design and synthesis of noncentrosymmetric hydrogen bonded main chain liquid-crystalline polymers: Toward polar order in organic thin films. D. J. Dyer, J. Wolf, C. Li, C. Landorf, B. Brown, J. Maas, E. Conlin 10:55 415. Supramolecular chirality. D. N. Reinhoudt
11:20 416. Preparation and properties of dendritic polyamides-poly(4-vinylpyridine) complexes via multiple hydrogen bond ing. M. Jikei, T. Koketsu, K. Yokomachi, M. Kakimoto 11:45 417. Synthesis and characterization of hyperbranched polyesters with termi nal hydroxyl groups from A* and B3 type monomers. K. Wang, C. Gao, W. Huang, D. Yan Section D Hilton Riverside Grand Salon B9/B12 2003 ACS Award in Applied Polymer Science Honoring Lloyd M. Robeson C. D. Smith, Organizer,
Presiding
M. T. Shaw, Organizer 8:00 418. Gas separation using polymer membranes. B. D. Freeman 8:25 419. Diffusive size selectivity in a low free volume rubbery polymer. T. A. Barbari, C. H. Huang 8:50 420. Random polyamide-imides for gas separation membranes. M. Langsam, D. Laciak 9:15 421. Molecular structure versus phase behavior of materials in carbon dioxide. E. J. Beckman 9:40 422. Organic-inorganic hybrid mem brane materials for gas separation. W. J. Koros, T. T. Moore 10:05 423. Advances in lithography: Taking nanoscale structures from micro electronics to biotechnology. C. K. Ober 10:30 424. Step polymerization modeling of chain propagation polymers: An examination of branched and functionalized polyethylene. Κ. Β. Wagener, J. C. Sworen, S. E. Lehman Jr., J. A. Smith, M. D. Watson, J. Schwendeman, D. Valenti, K. Brzezinksa 10:55 425. Emulsion polymerization stabilized by blends of anionic and cationic surfactants. C. D. Smith, P. Zhang 11:20 426. Fluoropolymer synthesis and processing. J. M. DeSimone 11:45 427. Recent advances in enhancing the properties of polyesters. S. R. Turner In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymeric Materials: Science and Engineering Colloidal and Molecular Electro-Optics Theoretical Aspects Cosponsored with Division of Colloid and Surface Chemistry TUESDAY AFTERNOON Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Theory and Performance in Epoxy Systems/Crosslinking and Electronics E. P. Squiller and T. J. Smith, Presiding R. K. Pinschmidt Jr. and C. Hoyle, Organizers 1:00 428. Molecular modeling for predict ing epoxy reactivity. N. G. Rondan, M. J. Marks, S. H. Hoyles, H. Pham 1:30 429. Surface and interface properties of crosslinked amine-cured epoxies. T. Nguyen, X. Gu, M. Vanlandingham, J. Martin 2:00 430. Study of UV degradation in epoxy polymer by using slow positron annihilation spectroscopy. R. Zhang, X. Gu, H. Chen, Y. Li, J. Zhang, T. Nguyen, Y. C. Jean
2:30 Intermission. 2:50 431. Crosslinked conjugated polymer ultrathin film networks via the precursor polymer approach: Synthesis, character ization, and application. R. Advincula, C. Xia, K. Onishi, P. Taranekar, S. Deng, A. Baba, W. Knoll 3:20 432. Oxidative solid-state crosslink ing for patterning intrinsically conductive polymers. G. A. Sotzing, S. Jang, M. Marquez 3:50 433. Synthesis and photochemistry of stilbene dicarboxylate polyesters that are liquid-crystalline at room tempera ture. D. Creed, A. M. Somlai, C. E. Hoyle, K. A. Page 4:20 434. Synthesis and characterization of a new photo crosslinkable polyester for photonic applications. Z. Roz, S. Sun, S. Maaref Section Β Hilton Riverside Grand Salon C16/C13 NMR Spectroscopy of Polymers Synthetic Polymers: Solid-State Structure and Morphology Cosponsored with Division of Analytical Chemistry R. Kimmich, Presiding H. N. Cheng and A. D. English, Organizers 1:30 435. Supramolecular structure and function from solid-state NMR. H. W. Spiess, I. Schnell 1:55 436. Biaxial deformation of polymer networks and deuterium quadrupolar interactions. P. T. Callaghan, E. T. Samulski 2:20 437. Morphology of alkoxysilane/ acrylate latex particles synthesized by miniemulsion copolymerization as inferred by proton NMR spin diffusion experiments. J. E. Roberts, I. Marcu, V. L. Dimonie, E. S. Daniels, M. S. El-Aasser 2:45 438. Ordering of apolar and polar solutes in nematic phases as deter mined by NMR spectroscopy. C. Wutz, E. T. Samulski, T. Dingemans, D. J. Photinos, A. F. Terzis 3:10 Intermission. 3:25 439. NMR studies of polymer inter faces in ordered hydrophobic organic/ inorganic hybrids. P. A. Mirau, S. Yang 3:50 440. NMR studies of polymers included in and coalesced from their inclusion compounds formed with host cyclodextrins. A. E. Tonelli 4:15 441. Proton NMR characterization of room-temperature aging in isotactic polypropylene and ethylene/octene copolymers. D. L. VanderHart, C. R. Snyder, R. G. Alamo Section C Hilton Riverside Grand Salon C18/C15 Polymer Design Using Non-covalent Methods II S. C. Zimmerman, Presiding R. A. Gross, Organizer,
Presiding
T. E. Long, V. Rotello, and E. W. Meijer, Organizers 1:30 442. Engineering with macromolecules: From supramolecular chemistry to defined nanomaterials. U. S. Schubert, B. G. G. Lohmeijer, J. Gohy
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-127
TECHNICAL PROGRAM 1:55 443. Folded structure of oligoamides derived from aza-aromatics. I. Hue 2:20 444. Polymerization of 1-D columnar assemblies made up of sorbate contain ing trialkyl-1,3,5-benzenetricarboxamide. M. Masuda, P. Jonkheijm, R. P. Sijbesma, E. W. Meijer 2:45 445. From "plug and play" to "bricks and mortar": Recognition-mediated assembly of polymeric systems. V. M. Rotello 3:10 446. Design and single-molecule studies of titin-mimicking modular macromolecules having precise secondary structures formed by hydrogen bonding. Z. Guan, J. Roland, S. X. Ma, X. Kong, T. M. Mclntire, D. A. Brant 3:35 447. Synthesis and folding properties of isomeric m-phenylene ethynylene oligomers containing short amide sequences. K. Goto, J. S. Moore 4:00 448. Hexameric cycles from hydro gen-bonded ureido-pyrimidinones. H. M. Keizer, A. Ramzi, R. P. Sijbesma, E. W. Meijer 4:25 449. Designed intramolecular hydro gen bonds stabilizing antimicrobial amphiphilic polymers. R. J. Doerksen, B. Chen, D. Liu, W. F. DeGrado, M. L Klein 4:50 450. Synthetic duplex oligomers defined via covalent casting of a 1-D hydrogen bonding motif. M. J. Krische, E. A. Archer
2:05 461. From monolayers to polymer brushes. R. Jordan, J. Kang, A. Ulman, W. Eck, A. Golzhauser, M. Grunze 2:40 462. Patterned polymer brushes via surface-initiated photopolymerization on self-assembled monolayers structured by chemical lithography. R. Jordan, U. Schmelmer, A. Paul, W. Eck, A. Golzhauser, M. Grunze, A. Ulman 3:05 Intermission. 3:20 463. Functional polymer brushes. J. Ruhe, O. Prucker, B. Peng, S. Golze, H. Murata 3:55 464. Recent advances in the synthe sis and rearrangement of block copoly mer brushes. S. G. Boyes, A. M. Granville, B. K. Mirous, B. Akgun, W. J. Brittain 4:30 465. Synthesis of functional inter faces using irregularly hyperbranched grafts. D. Bergbreiter 5:05 466. Nickel-mediated grafting from polymerization of α-amino acid-Ai-carboxyanhydrides. H. Menzel, P. Witte
Section D
TUESDAY EVENING
Hilton Riverside Grand Salon B9/B12
Section A
2003 ACS Award in Applied Polymer Science Honoring Lloyd M. Robeson M. T. Shaw, Organizer,
Presiding
C. D. Smith, Organizer 1:00 451. Phase behavior of polymer blends. D. R. Paul, S. Zhu 1:25 452. Polymeric sensors: Sensing materials for liquid/vapor environments based on electrically conductive polymer blends. M. Narkis, E. Segal, R. Tchoudakov, H. Cooper, A. Siegmann 1:50 453. Unusual phenomena in ionomer blends. R. A. Weiss, L. Xu, H. Lee 2:15 454. Polymers and blends from cyclic oligomers of polyesters. W. J. MacKnight, A. Tripathy 2:40 455. Proton exchange membranes based on engineering thermoplastics. J. E. McGrath 3:05 456. Conductivity enhancement of sulfonated polystyrene blends using electric field structuring techniques. J. V. Gasa, M. T. Shaw 3:30 457. Functional polyesters: From soft drink containers to electrospun fibers and bioadhesives. T. E. Long, Q. Lin, M. G. McKee, A. S. Karikari, S. Unal, A. R. Fomof, R. H. Colby 3:55 458. Electro-optical properties of polymer blends. F. E. Karasz 4:20 459. Award Address (ACS Award in Applied Polymer Science). Structure/ property studies on polymeric materials. L. M. Robeson Section Ε Hilton Riverside Grand Salon D21/D24 Polymer Brushes: From Synthesis to Functional Microstructures Synthesis Cosponsored with Division of Polymeric Materials: Science and Engineering R. C. Advincula, Organizer,
Presiding
W. J. Brittain, J. Ruhe, and K. Caster, Organizers 1:20 Introductory Remarks. 1:30 460. Polymer brushes by ATRP. K. Matyjaszewski
128-TECH
Colloidal and Molecular Electro-Optics Rigid Particles Cosponsored with Division of Colloid and Surface Chemistry In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymeric Materials: Science and Engineering
Convention Center Hall G Polymer Brushes: From Synthesis to Functional Microstructures Cosponsored with Division of Polymeric Materials: Science and Engineering W. J. Brittain, R. Advincula, J. Ruhe, and K. Caster, Organizers 6:00-8:00 467. A novel method for the synthesis of amphiphilic core-shell polymer nanospheres. P. Li, J. Zhu, P. Sunintaboon, F. W. Harris 468. Conductive polymer-based nanomolecular wire: Selective connection to various solid surfaces. H. Nakashima, K. Furukawa, Y. Kashimura, K. Torimutsu 469. LCST phase behavior of end-grafted poly(/V-isopropylacrylamide). S. Mendez, B. Subramanian, S. S. Balamurugan, M. J. O'Brien II, G. P. Lopez 470. Micromechanical properties of glassy and rubbery polymer brushes grafted to functionalized silicon surfaces. D. Julthongpiput, M. C. LeMieux, V. Tsukruk 471. Modification of gold films with watersoluble (co)polymers prepared via aque ous RAFT. B. S. Sumerlin, P. A. Stroud, A. B. Lowe, C. Scales, C. L McCormick 472. Nanomechanical properties of switchable binary polymer brush films. M. C. LeMieux, S. Minko, D. Usov, M. Stamm, V. Tsukruk 473. Nanoporous materials for the faster circuit: A single-molecule template. E. Conner, L Sundberg, J. Hedrick, R. Miller
474. Nanostructure of amphiphilic diblock copolymer monolayer at an air-water interface by X-ray and neutron reflectometry. H. Matsuoka, E. Mouri, K. Matsumoto 475. Recent advances in contact molding for nanoscopic pattern transfer. K. R. Carter, T. A. von Werne, D. Germack, E. C. Hagberg, C. J. Hawker, M. Beinhoff 476. Study of the grafting reaction of maleic acid onto PP fiber in a medium of water solution. X. Zhang, S. Tong, J. Li, J. Chen 477. Surface micropatteming of biomolecules through photolithography on block copolymer polymer brushes. F. Pan, K. Lee, P. Wang, N. J. Turro, J. T. Koberstein 478. The influence of shearing parameters on the frictional forces measured between polymer brushes. A. M. Forster, S. M. Kilbey II 479. Well-defined brush polymers based on a fully rodlike backbone: Synthesis and properties. M. Ree, S. W. Lee, B. Lee, W. Choi, B. Chae, S. B. Kim, K. H. Lee, J. C. Jung 480. Characterization of stimuli-responsive semifluorinated polymer brushes. A. M. Granville, S. G. Boyes, W. J. Brittain 481. Copolymers with spontaneous gradi ent structure by ATRP of PEO (meth)acrylate macromonomers with TMSethyl (meth)acrylates. D. Neugebauer, K. Matyjaszewski 482. Densely heterografted brush copoly mers by combination of "grafting through" and "grafting from" ATRP. D. Neugebauer, Β. Ε. Carson, S. S. Sheiko, K. Matyjaszewski 483. Double-grafted brushes via ATRP. D. Neugebauer, Y. Zhang, T. Pakula, K. Matyjaszewski 484. Effect of initiator deposition technique and spacer length on monolayer and polymer brush formation. B. Akgun, S. G. Boyes, A. M. Granville, W. J. Brittain, M. D. Foster 485. Effect of initiator structure on photo chemical polymerization of styrene from self-assembled monolayers on gold. J. Feng, D. J. Dyer 486. Electrostatic effects in surface-initiated aqueous ATRP: Synthesis of hydrophilic polymer brushes from charged surfaces. J. N. Kizhakkedathu, R. Norris-Jones, D. E. Brooks 487. Functionalization of deacetylated cellulose acetate membrane by poly(acrylic acid) brushes. H. Chen, Y. Hsieh 488. Gradient polymer brushes. B. Zdyrko, V. Klep, I. Luzinov, A. Sidorenko, L. lonov, S. Minko, M. Stamm 489. Hairy dendronized polymers: Highdensity polymer brushes via ROMP. A. Zhang, A. D. Schluter 490. Linear-hyperbranched nonionic PPOpolyglycerol surfactants. H. Frey, H. Kautz, V. Istratov, R. Schubert, Y.Kim 491. Macromolecular interlayer for anchor ing of high-density brushes by "grafting to" method. K. S. Iyer, V. Klep, J. Pionteck, H. Malz, I. Luzinov 492. Morphological studies of model poly mer-layered silicate nanocomposites. M. Kurian, M. Galvin, P. Madison, F. L. Beyer 493. Nanopatterned surface morphology of well-defined mixed homopolymer brushes fabricated by living radical polymerization. M. Ejaz, K. Ohno, Y. Tsujii, T. Fukuda 494. Novel polymer brush architectures: Linear hyperbranched block copolymers. H. Frey, A. Garcia Marcos, T. Pusel, B. de Juan de Castro, S. Geppert, R. Thomann, W. Gronski 495. Polyelectrolyte complexes and multi layers at a solid surface via polymer brushes. H. Zhang, J. Ruhe 496. Polymer brushes grafted from macroinitiator by controlled/living polymeriza tion. V. Klep, B. Zdyrko, I. Luzinov
497. Polyzwitterions in polyelectrolyte multilayers: Formation and applications. H. H. Rmaile, C. B. Bucur, J. B. Schlenoff 498. Preparation of silica-poly(norbomene) nanocomposites by surface-initiated polymerization. M. Jordi, T. A. P. Seery 499. Spontaneous curvature of polymer brushes. S. S. Sheiko, M. da Silva, D. Shirvaniants, C. A. Rodrigues, K. L. Beers, K. Matyjaszewski, 1.1. Potemkin, M. Moeller 500. Swelling behavior of weak polyelectro lyte brushes. R. Konradi, J. Ruhe 501. Synthesis and application of gold nanoparticles coated with well-defined, high-density polymer brushes. K. Ohno, K. Koh, Y. Tsujii, T. Fukuda 502. Synthesis and characterization of octafunctional block poly(ethylene oxide)-£>/oc/r-polystyrene based on a calixarene core. J. Logan, D. Taton, Y. Gnanou, R. S. Duran 503. Synthesis and characterization of polyelectrolyte brushes. S. G. Boyes, B. K. Mirous, W. J. Brittain 504. Synthesis of an a-siloxy-(o-amino poly(ethylene glycol) for use in ligating biological molecules to nanoparticles. P. J. Costanzo, T. E. Patten, R. Smith 505. Synthesis of functionalized polymer brushes, Part I: Dipeptide brushes. J. Ruhe, H. Murata 506. Synthesis of functionalized polymer brushes, Part II: Active ester brushes. J. Ruhe, H. Murata 507. Synthesis of functionalized polymer brushes, Part III: Amino brushes. J. Ruhe, H. Murata 508. Synthesis of patterned polymer brushes via surface-initiated polymeriza tion on self-assembled monolayers. U. Schmelmer, R. Jordan, A. Paul, W. Eck, A. Golzhauser, M. Grunze, A. Ulman 509. Synthesis of polymer brushes by surface-initiated ATRP: Effect of initiator density. Y. Liu, V. Klep, I. Luzinov 510. Synthesis of polymer dielectric layers via ROMP for use in organic circuit devices. I. M. Rutenberg, 0 . A. Scherman, Z. Bao, R. H. Grubbs 511. The synthesis and properties of spherical brushes by living ATRP. C. Li, M. Schmidt, Y. Chen 512. Wettability and morphology of a mixed polymer brush prepared by simulta neous polymer addition. J. Draper, 1. Luzinov, L. lonov, S. Minko, S. K. Varshney, M. Stamm Section Β Polymer Design Using Noncovalent Methods T. E. Long, R. A. Gross, V. Rotello, and E. W. Meijer, Organizers 6:00-8:00 513. 3,6-Bis-(2-pyridyl)-pyridazine as supramolecular (co)initiator for DLlactide polymerization. R. Hoogenboom, U. S. Schubert 514. A straightforward method to synthe size cyclodextrin-based hyperbranched polymer from natural cyclodextrin. L. Chen, X. Zhu, D. Yan, X. He 515. Adsorption of a macromolecule as a release trigger of a small molecule from polymer multilayers. S. A. Sukhishvili, E. Kharlampieva
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
POLY/TECHNICAL PROGRAM
516. Aggregation studies of novel, facially amphiphilic phenylene ethynylenes. R. B. Breitenkamp, G. N. Tew 517. All-organic high-/c composite materials as actuators and artificial muscles. C. Huang, M. Poh, H. Xu, Z. Cheng, Q. M. Zhang 518. Development and characterization of polyvinyl alcohol)-amino acid hydrogels for use as biomaterials. M. S. Boeckl, J. Perry, E. R. Leber, P. Nair, B. D. Ratner 519. Efficient biological construction of repetitive polypeptides for interconnect applications by block copolymerization. S. Higashiya, S. C. Ngo, K. S. Bousman, X. Jin, J. T. Welch, R. P. Cunningham, E. T. Eisenbraun, R. E. Geer, A. E. Kaloyeros 520. Electrochromic properties of LBL thin films containing polyviologens. N. Zacharia, P. T. Hammond 521. Facially amphiphilic phenylene ethy nylenes. L. Arnt, G. N. Tew 522. Hydrogen bond crosslinking-induced micellization of polyvinyl phenol)-6/oc/epolystyrene and polyvinyl phenol-ranstyrene). E. Yoshida, A. Hironaka, M. Ohta 523. Investigation of nucleobase-assembled supramolecular mesogenic polymers. S. J. Rowan, S. Sivakova 524. J-Aggregate formation onto polyelectrolytes and their energy/electron trans fer quenching. J. Je, L. Lu, D. Whitten, O.Kim 525. Metal/ligand-induced formation of metallo-supramolecular polymers. S. J. Rowan, J. B. Beck, J. M. Ineman 526. Micelle formation of poly(4-pyridinemethoxymethylstyrene)-/>polystyrene in nonselective solvents using dicarboxylic acids. E. Yoshida, M. Ohta 527. Microphase separation induced by sparsely distributed pendant side-chain groups. R. Shenhar, O. Uzun, V. M. Rotello 528. Noncovalent association of polyhedral oligomeric silsequioxane modifiers in a polymeric system: Thymine-based "plug and play" polymers. J. B. Carroll, H. Nakade, V. M. Rotello 529. Polymer-mediated self-assembly of iron oxide nanoparticles. A. K. Boal, B. L. Frankamp, O. Uzun, M. Tuominen, V. M. Rotello 530. Self-assembly of nanoparticles by using diblock copolymers. O. Uzun, B. L. Frankamp, V. M. Rotello 531. Self-assembly of nonhelical and helical metallo-supramolecular polymers. P. R. Andres, U. S. Schubert 532. Self-assembly of randomly functionalized rigid copolymers. U. Drechsler, R. J. Thibault, V. M. Rotello 533. Stamping of fluorinated copolymers for microfluidic applications. J. Park, P. T. Hammond 534. Supramolecular polymers based on poly(ethylene glycol)-terpyridine ruthe nium systems. H. Hofmeier, S. Schmatloch, U. S. Schubert 535. Supramolecular polymers containing terpyridine complex and hydrogen bond ing units. H. Hofmeier, A. El-ghayoury, U. S. Schubert 536. Surface alignment of hydrogenbonded main chain liquid-crystalline polymers. D. J. Dyer, C. Li, J. Wolf, T. Zhao, C. Landorf 537. Surface modifications using molecular recognition at interfaces. A. Sanyal, T. B. Norsten, E. Jeoung, R. J. Thibault, Ο. Uzun, Η. Nakade, V. M. Rotello 538. Synthesis and characterization of interphase-modified polyurethanes. G. S. Pollock, L T. James-Korley, G. H. McKinley, P. T. Hammond 539. Synthesis of end-group —modified m-phenylene ethynylene oligomers to investigate guest binding. M. T. Stone, J. S. Moore
540. Synthesis of polyamide dendrons and dendrimers bearing multiple hydrogenbonding parts on the periphery. T. Koketsu, K. Yokomachi, M. Jikei, M. Kakimoto 541. Synthesis of polymer scaffolds con taining one molecular recognition site. H. Nakade, K. Das, V. M. Rotello 542. Synthesis of polyphosphazenes with sulfonic acid functionalities using nonco valent protection methods. A. K. Andrianov, A. Marin, J. R. Sargent, J. Chen 543. Synthesis of titin-mimicking polymers having modular structures by using noncovalent interactions. J. T. Roland, S. X. Ma, M. Nguyen, Z. Guan 544. T-shaped supramolecular liquidcrystalline complexes self-assembled by double hydrogen bonding. D. Chen, Y. Lu, X. Wang, X. Yu 545. Toward the "universal" polymer back bone: Optimization of norbornene mono mers possessing terminal hydrogenbonding receptors or metal-coordinating units. J. M. Pollino, L. P. Stubbs, M. Week 546. Uptake and release of complementary guests by recognition-induced polymersomes. R. J. Thibault, E. Turnberg, P. Hotchkiss, V. M. Rotello Section C Advances in Polycarbonates D. J. Brunelle and M. R. Korn, Organizers 6:00-8:00 547. Synthesis and characterization of 2,2,4,4-tetramethylcyclobutanediolbased polycarbonates. A. E. Acar, D. J. Brunelle 548. New aliphatic poly(ester-carbonates) based on 5-methyl-5-allyloxycarbonyl1,3-dioxan-2-one. B. D. Mullen, C. N. Tang, R. F. Storey 549. Effectiveness of sPETG as a compatibilizer for PC/PETG blends. P. L. Hopson, R. B. Moore 550. Synthesis of bis[4-(4-hydroxyphenyl)phenyl]propane and novel polycar bonates prepared therefrom. T. S. Filipova, D. Boyles, J. T. Bendler, M. J. Schroeder Section D NMR Spectroscopy of Polymers Poster Session Cosponsored with Division of Analytical Chemistry H. N. Cheng and A. D. English, Organizers 6:00-8:00 551. A comparison of NMR measurements of residual dipolar couplings in aged silica-PDMS composite materials. R. Maxwell, S. Chinn, B. Balazs, R. Gee 552. Deuterium NMR studies of bulk and silica-adsorbed polystyrene. M. O. Okuom, J. Yang, F. D. Blum 553. Dynamics and morphology of adsorbed and filled amorphous poly mers. V. Nasreddine, T. GenereuxVincent, L. Reven 554. Dynamics of disordered styreneisoprene tetrablock copolymers: From heterogeneous segmental dynamics to homogeneous global dynamics. Y. He, T. R. Lutz, M. D. Ediger, T. P. Lodge 555. Fast-MAS NMR studies of polyelectrolyte multilayer films. M. McCormick, R. N. Smith, R. Graf, C. J. Barrett, L. Reven, H. W. Spiess
556. Mobility studies of polyelectrolytes adsorbed onto silica surfaces. R. N. Smith, M. McCormick, L. Reven, C. J. Barrett 557. Polymer/MCM-41 nanocomposites obtained by in situ polymerization as characterized by solid-state NMR. S. Bracco, A. Comotti, R. Simonutti, P. Sozzani 558. Real-time observation of the crystalli zation of natural rubber through NMR spin-diffusion experiments. J. Leisen, M. A. Sharaf, H. W. Beckham 559. Rapid polyethylene oxide) segmental dynamics in blends with poly(methyl methacrylate). T. R. Lutz, Y. He, M. D. Ediger, H. Cao, G. Lin, A. Jones 560. CP/MAS solid NMR spectra of a compound of cellobiose and n-octadecylsuccnic anhydride. L. Yang, T. Endo, T. Hirotsu 561. Evaluating crosslink density in model polyurethane acrylate coatings with 1 H and 13C NMR relaxation measurements. R. E. Youngman, D. N. Schissel, S. M. Gasper 562. Diffusional inhomogeneities in polymer gels as studied by the 1H pulsed highfield-gradient NMR method. Y. Yamane, M. Matsui, H. Kimura, S. Kuroki, I. Ando 563. Effective size and charge of polyelec trolytes. U. Scheler, U. Bohrne 564. Self-diffusion of water in sulfonated poly(arylene ether sulfone) copolymers by pulse-field-gradient NMR. L. Dong, Y. S. Kim IV, F. Wang, M. Hickner, T. E. Glass, J. E. McGrath 565. Diffusional behavior of poly(diethylsiloxane) in the liquid-crystalline phase studied by field-gradient NMR. S. Kanesaka, H. Kimura, S. Kuroki, S. Fujishige, I. Ando 566. Molecular mass and dynamics in PMA-d3 in the glass transition region. B. Metin, F. D. Blum 567. Mobility of linear polymer chains in TPP nanochannels. R. Simonutti, M. Mauri, S. Bracco, A. Comotti, P. Sozzani 568. Variable-temperature solid-state NMR investigation of the structure, molecular motion, and morphology of naphthalenecontaining poly(ether-ester) thermoplas tic elastomers. Μ. Μ. Guo 569. Variable-temperature NMR spectra and relaxation studies of polyelectrolytes in poor solvents. M. M. Guo 570. NMR characterization of polyvinyl alcohol) films. S. A. Myers, L. Tsou, D. J. Heiler 571. Expanding the detection limit for side-chain branches in polyethylene: C-13 NMR spin-lattice relaxation and NOE buildup directly in the melt. M. A. Pollard, M. Wilhelm, H. W. Spiess, O. Sperber, C. Piel, W. Kaminsky 572. Analysis of long-chain branching in polyethylene using high-field 13C NMR. C. B. Conboy, A. A. Taha, E. S. Hsi, M. S. Johnson, O. D. Redwine, J. J. Xiong, S. Zhang, D. Gorenstein, F. Lin, V. V. Mainz 573. Tacticity analysis of poly(ethylene-cobutene) copolymers by multidimensional NMR. S. K. Sahoo, D. V. Reddy, T. Zhang, P. L. Rinaldi, L. H. Mcintosh, R. P. Quirk 574. Carbon-13 NMR study of propyleneethylene-butene-1 terpolymers. Y. Zhang, C. Wu 575. Fractionation and characterization of a propylene-ethylene-butene-1 terpolymer. Y. Zhang, C. Wu, J. Zhang, W. Wang 576. Chain end-group analysis of ethene homo- and copolymers prepared with metallocene catalysts at high tempera ture. V. Van Axel Castelli, A. L. Segre, V. Busico, N. Friederichs, G. van der Velden 577. NMR analysis of polymers through kinetic modeling. Η. Ν. Cheng, L. J. Kasehagen 578. Encapsulation of fluorescein dye within a PPI-3/adipic acid self-assembly. A. K. Holley, M. Chai, R. J. Morgan
579. Investigation of microstructure of /V-vinylcarbazole and methacrylic acid copolymers by NMR spectroscopy. A. S. Brar, M. Kaur 580. Microstructure determination of glycidyl methacrylate/butyl acrylate copolymers by NMR spectroscopy. A. S. Brar, A. Yadav, M. Kaur 581. Structure and aggregation studies of porphyrin-based dendrimers by multidi mensional NMR. D. Banerjee, G. J. Capitosti, S. J. Cramer, D. A. Modarelli, P. L. Rinaldi 582. pH-Responsive complexes and asso ciations of linear poly(methacrylic acid) containing polyethylene glycol) grafts. G. D. Poe, C. L. McCormick, W. L. Jarrett Jr. 583. Structural analysis of PFSI in the solution state studied by 19F PFG NMR spectroscopy. K. H. Min, K. Yamamoto, A. Watakabe, S. Yonemori, I. Ando 584. Quantitation of kollidon in an acrylatebased copolymer adhesive by proton NMR. J. Wu, S. V. Pathre 585. Rapid injection NMR study of the reaction of sec-butyllithium with styrene and isoprene in toluene. C. Z. Carlin, M. D. Murphy, C. A. Ogle 586. Simulations of methylaluminoxane synthesis from monomeric trimethylaluminum + water. R. W. Hall, L. Negureanu, P. Bobadova-Parvanova, J. L. Eilertsen, L. G. Butler, L. S. Simeral 587. Stuctural properties of methylalumi noxane from DOSY NMR, solution Aluminum-27 NMR, and solid-state proton spin-lattice relaxation times. J. L. Eilertsen, W. D. Treleaven, R. W. Hall, L G. Butler, L S. Simeral 588. Wheat protein and its polymer blends studied by solid-state high-resolution NMR spectroscopy. X. Zhang, I. Burgar, M. D. Do, E. Lourbakos, H. Beh 589. Polyblends containing starch and vinyl polymers. A. Biswas, J. L. Willet, Η. Ν. Cheng 590. NMR study of thermal transition of /V-isopropylacrylamide/methacrylated pullulan hydrogels. R. Lamanna, A. P. Sobolev, G. Masci, D. Bontempo, V. Crescenzi, A. L. Segre 591. 1 H NMR study of a kind of aromatic macrocycle with two isomers. G. Dang, C. Chen, W. Yang, F. Li, W. Zhang, Z.Wu 592. 1 H NMR study of a novel aromatic macrocyclic oligomer with a manacle-like structure. G. Dang, C. Chen, W. Yang, F. Li, W. Zhang, Z. Wu
WEDNESDAY MORNING Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Reversible/Renewable Resources/ Recyclable Crosslinked Systems J. W. Taylor, Presiding R. K. Pinschmidt Jr., Organizer, Presiding C. Hoyle, Organizer 8:20 593. New thermally re-mendable highly crosslinked polymeric materials. F. Wudl, X. Chen 8:50 594. Synthesis and characterization of cleavable epoxy compounds. H. K. Shobha, G. G. Hougham, N. C. LaBianca, J. D. Gelorme, C. Feger, S. L. Buchwalter
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-129
9:20 595. Supramolecular terpolymers for covalent and noncovalent crosslinking. H. Hofmeier, U. S. Schubert 9:50 596. Synthesis of cleavable branched poly(2-ethylhexyl acrylates) as deactivatable adhesives. L. Kilian, M. D. Perry, R. R. Dick, T. E. Long 10:20 Intermission. 10:30 597. Learning from a natural curing system: Development of an environmen tally benign coating. S. Kobayashi, R. Ikeda, T. Tsujimoto, H. Uyama 11:00 598. Dispersability of phosphated bio-based hyperbranched polyols. V. M. Mannari, Y. Guo, J. L. Massingill Jr. 11:30 599. Dynamic vulcanization of the SRP/HDPE/POE thermoplastic elas tomers. Y. Li, Y. Zhang Section Β Hilton Riverside Grand Salon C16/C13
8:55 608. Catalytic macromolecuiar rotaxanes: Toward mimicking nature's pro cessive catalysts. A. E. Rowan, P. Thordarson, R. G. E. Coumans, E. Bijsterveld, R. J. M. Nolte 609. Withdrawn. 9:20 610. Synthesis of (poly)rotaxanes that lack an enthalpic driving force for threading. C. Pugh, K. Xu 9:45 611. Self-assembly with macromo lecuiar building blocks. H. W. Gibson, Z. Ge, J. W. Jones, A. Farcas 10:10 612. The reorganization of poly mers by processing with their cyclodextrin inclusion compounds. A. E. Tonelli, C. C. Rusa, T. A. Bullions, M. Wei, X. Shuai 10:35 613. A new class of semipolyrotaxanes: Multiple-arm inclusion complexes with a hyperbranched core. X. Zhu, D. Yan, L. Chen, J. Hou, J. Li, Q. Chen, Y.Yao 11:00 614. Design and properties of topological gels. Y. Okumura, K. Ito
NMR Spectroscopy of Polymers Synthetic Polymers: Diffusion and Constrained Geometry Cosponsored with Division of Analytical Chemistry
Section D
A. K. Whittaker, Presiding
General Papers Polymer Characterization
H. N. Cheng and A. D. English, Organizers 8:30 600. Understanding diffusion in entangled polymer blends. E. D. von Meerwall, S. Wang, S. Wang 9:15 601. Diffusion in transient polymer networks: Solvent, solute, and polymer. P. M. Macdonald, X. X. Zhu, Y. Uemura 9:40 602. Industrial applications of diffu sion NMR to polymer problems. E. F. McCord, J. Vargeson, H. Dai, A. J. Vega, E. U. Lozada 10:05 603. Diffusion in an ultrapermeable nanocomposite membrane by pulsefield-gradient NMR. A. A. Jones, J. Zhong, W. Wen 10:30 Intermission. 10:45 604. Polymer chain dynamics in nanopores. R. Kimmich, E. Fischer, U. Beginn, N. Fatkullin, A. Denissov, M. Kroutieva 11:10 605. Extended polymeric interfaces studied by 1H-13C HETCOR applying Lee Goldburg homonuclear decoupling. P. Sozzani, R. Simonutti, S. Bracco, A. Comotti 11:35 606. HRMAS NMR: A new approach to polymer interactions in blends and composites. W. T. Winter Section C Hilton Riverside Grand Salon C18/C15 Polymer Design Using Non-covalent Methods III I. Yilgor and J. C. M. van Hest, Presiding T. E. Long, R. A. Gross, V. Rotello, and E. W. Meijer, Organizers 8:30 607. Toward supramolecular daisychainlike polymers. J. F. Stoddart, T. Chang
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Hilton Riverside Grand Salon B9/B12
R. Freeh, Presiding D. Garcia and C. A. Guymon, Organizers 8:00 73. Influence of stereochemistry on cocrystallization in partially cycloaliphatic copolyamides. C. Koning, B. Vanhaecht, R. Willem, M. Biesemans, Β. Goderis, Β. Rimez 8:20 616. Origin of the stress-induced rate acceleration in the photochemical degra dation of polymers. D. R. Tyler, R. Chen 8:40 617. Determination of the propaga tion rate constant in the carbocationic polymerization of styrène. P. De, M. V. Munavalli, R. Faust 9:00 618. Analysis and characterization of initiation in quasiliving cationic polymerization of styrene and isobutylene. R. F. Storey, Q. A. Thomas 9:20 619. Characterization of the kinetics of the adiabatic photopolymerization of dodecyl acrylate. W. J. Ainsworth, Y. A. Chekanov, J. A. Pojman, V. T. Wyatt 9:40 620. Analysis of the aggregation behavior of ionic oligomers in the aqueous phase during emulsifier-free emulsion polymerization. X. Li, R. Salovey 10:00 621. Systematic study of the synthesis and characterization of 3,3'sulfonylbis(6-chloro benzene sulfonic acid) disodium salt monomer for protonconducting polymeric membranes in fuel cell applications. M. Sankir, V. A. Bhanu, H. Ghassemi, K. B. Wiles, M. L Hill, W. Harrison, M. Sumner, T. E. Glass, J. Riffle, J. E. McGrath 10:20 622. Novel PEEK membranes for fuel cell applications. M. P. Gil, X. Ji, X. Li, H. Na, J. E. Hampsey, Y. Lu 10:40 623. Preparation of modified polyetherketone membranes. P. J. Brown, D. A. Baker, M. A. Hafeez 11:00 624. Mechanism of disordering in lithium salt complexes of poly(ethylenimine). M. Buckner, S. S. York, R. Freeh, D. T. Glatzhofer 11:20 625. Single-ion block copolymer electrolytes for solid-state lithium rechargeable batteries. S. Ryu, P. E. Trapa, D. R. Sadoway, A. M. Mayes 11:40 626. Poly(arylene thioether sulfone) copolymers for PEM-based fuel cell systems. Κ. Β. Wiles, V. A. Bhanu, F. Wang, M. A. Hickner, J. E. McGrath
Section Ε
Section Β
Hilton Riverside Grand Salon D21/D24
Hilton Riverside Grand Salon C16/C13
Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Mechanism/Nanoparticles Cosponsored with Division of Polymeric Materials: Science and Engineering
NMR Spectroscopy of Polymers Synthetic Polymers: Relaxation and Dynamics Cosponsored with Division of Analytical Chemistry P. M. Macdonald, Presiding
W. J. Brittain, Organizer, Presiding R. C. Advincula, J. Ruhe, and K. Caster, Organizers 8:30 627. Methods for grafting polymer brushes from various nanoparticle sur faces. T. E. Patten 9:05 628. Characterization of polymer brushes on nanoparticle surfaces. T. A. P. Seery, M. Jordi, Q. F. Adkins 9:40 629. Grafting of polymers onto carbon nanofiber surfaces and applica tion to sensing materials. N. Tsubokawa, J. Chen, G. Wei, M. Mikuni, K. Fujiki 10:15 Intermission. 10:30 630. Polymer brushes by living anionic surface-initiated polymerization: Synthesis, mechanism, and block copolymers. R. Advincula, M. Park, J. W. Mays, G. Sakellariou, S. Pispas, N. Hadjichristidis 11:05 631. Photoinitiated polymerization of styrene from alkylthiolate self-as sembled monolayers: Kinetics and grafting density. D. J. Dyer, J. Feng, R. Paul, R. Schmidt, T. Zhao 11:30 632. Surface-grafted hyper branched polymers by self-condensing vinyl (co)polymerization via ATRP. H. Mori, A. H. E. Muller 11:55 633. Macromolecuiar anchoring layer for synthesis of polymer brushes. I. Luzinov, K. S. Iyer, V. Klep, B. Zdyrko, J. Draper, Y. Liu Colloidal and Molecular Electro-Optics Polymers and Polyelectrolytes Cosponsored with Division of Colloid and Surface Chemistry In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymeric Materials: Science and Engineering
WEDNESDAY AFTERNOON Section A Hilton Riverside Grand Salon D19/D22 Crosslinking Materials and Processes Waterborne Crosslinked Systems D. A. Wicks, Presiding R. K. Pinschmidt Jr. and C. Hoyle, Organizers 1:15 634. Crosslinking and polymer diffu sion in latex films. M. A. Winnik 1:45 635. Latexes with allyl functionality: An approach for designing thermosetting latex films. J. W. Taylor, M. Collins 2:15 636. Defect-free coatings from twopack isocyanate-curable acrylic disper sions. T. Nabuurs, A. Overbeek 2:45 637. Heterogeneous crosslinking of waterborne polyurethanes: Internal reflection IR imaging approach. D. B. Otts, M. W. Urban 3:15 638. Green nanocomposites from renewable resources. H. Uyama, T. Tsujimoto, M. Kuwabara, S. Kobayashi 3:45 639. Kinetic study of vegetable oil macromonomers for low-VOC coating applications. K. L. Diamond, S. N. Shah, S. K. Mendon, O. W. Smith, S. F. Thames
H. N. Cheng and A. D. English, Organizers 1:30 640. Multiple-component chain dynamics as pictured from NMR in polybutadiene. J. Cohen Addad, A. Guillermo 1:55 641. Dynamics in single-phase polymer mixtures. M. D. Ediger 2:20 642. Dynamics of bulk and adsorbed polyvinyl acetate). F. D. Blum, R. D. O'Connor 2:45 643. Observation of molecular mobil ity in poly(di-n-octylitaconate). F. Lauprêtre, A. C. Genix 3:10 Intermission. 3:25 644. Polyolefin blend miscibility: Interrogation of mixing in simple polymers by magnetic resonance. J. L. White, E. O. Stejskal, J. Wolak, X.Jia 3:50 645. Motional studies of deuterated polysilaethylene by 2H NMR. C. J. Wiegand, L. V. Interrante, T. Apple 4:15 646. Monitoring the condition of aged polymers by NMR relaxation measurements. R. A. Assink, M. C. Celina, K. T. Gillen Section C Hilton Riverside Grand Salon C18/C15 Polymer Design Using Non-covalent Methods J. F. Stoddart, Presiding T. E. Long, R. A. Gross, V. Rotello, and E. W. Meijer, Organizers 1:00 647. Nucleobase-induced supramolecular polymerization. S. J. Rowan, P. Suwanmala, S. Sivakova 1:25 648. Hydrogen-bonded supramolecular polymers with tunable material properties. A. T. ten Cate, D. J. M. van Beek, A. J. H. Spiering, P. Y. W. Dankers, R. P. Sijbesma, E. W. Meijer 1:50 649. Reversible crosslinking of polysiloxanes by cooperative hydrogen bonds. L. Bouteiller, O. Colombani, L. Fomperie, J. Bonetti-Riffaud, C. Barioz 2:15 650. Understanding the hydrogen bonding in polyurethanes: Quantum mechanical calculations and experimental studies on model systems. I. Yilgor, G. E. Atilla, V. Ediz, E. Yilgor, E. Yurtsever 2:40 651. Stabilization of core-shell polymeric assemblies through reversible nucleoside interaction. T. Glauser, M. Ranger, B. Kalra, W. Gao, J. Hedrick, R. A. Gross 3:05 652. Polyvinyl alcohol)/amino acid noncovalent hydrogels for biomedical applications. B. D. Ratner, E. R. Leber, C. A. Irvin, E. E. Donaldson, M. S. Boeckl, J. Perry, P. Nair, J. Bonadio, M. Zhang, K. D. Hauch
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
POLYflTECHNICAL PROGRAM
3:30 653. Biomolecular building blocks for well-defined polymer architectures. J. C. M. van Hest, H. Spijker, L. Ayres, J. Opsteen, J. Smeenk, H. Adams 3:55 654. Investigation of crystallinity using differential scanning calorimetry: Polyvinyl alcohol hydrogels in biomedical applications. L. Tsou, S. A. Myers, D. J. Heiler 4:20 655. Rigid dendrimers which mimic protein hierarchical structure. F. M. MacDonnell, K. L. Wouters, H. Zeng 4:45 656. Self-assembling peptide amphiphile nanofiber networks for insuloma culture. J. C. Stendahl, X. Chen, K. L. Niece, M. S. Baker, D. B. Kaufman, S. I. Stupp 5:10 657. Self-assembled vancomycin nanofibers confer antibacterial hydrogels. B. Xing, C. Yu, K. Chow, P. L Ho, D. Fu, Y. Zhang, B. Xu
Colloidal and Molecular Electro-Optics Vesicles and Membranes Cosponsored with Division of Colloid and Surface Chemistry Size-Exclusion Chromatography with Multiple Detection Techniques Cosponsored with Division of Analytical Chemistry
Section D Hilton Riverside Grand Salon B9/B12
9:40 681. Quantitation of different C-polysaccharide populations in pneu mococcal polysaccharide powders with NMR diffusion measurements. Q. Xu, C. Abeygunawardana 10:05 682. 13 C- 1 H and 13C-13C scalar couplings in isotopically labeled mono-, di-, and trisaccharides: NMR and DFT studies of O-glycoside and hydroxymethyl group conformation. A. S. Serianni, I. Carmichael 10:30 Intermission. 10:45 683. Structure of silk fibroin from a wild silkworm, Samia cynthia ricini, studied with solid-state NMR. T. Asakura, Y. Nakazawa 11:10 684. Diffusion of rodlike polypep tides in the thermotropic and lyotropic liquid-crystalline phases as studied by high-field-gradient 1 H NMR spectros copy. I. Ando, Y. Yin, C. Zhao, S. Kuroki 11:35 685. Determining stereodefect locations in polylactide using solid-state NMR spectroscopy. E. J. Munson, L. K. Carlson, J. E. Jorvig, Μ. Τ. Zell, J. Abbott, M. A. Hillmyer Section C
Advances in Polycarbonates D. J. Brunelle and M. R. Korn, Organizers, Presiding 1:00 Introductory Remarks. 1:05 658. Generation of polypropylene carbonate) from propylene oxide and C0 2 : Challenges and opportunities. E. J. Beckman 1:35 659. Alternating copolymerization of epoxides and carbon dioxide: Advances in β-diiminate zinc catalysts. D. R. Moore, S. D. Allen, G. W. Coates 2:05 660. Polycarbonates grafted with oxytetramethylene chains: Synthesis and properties. J. A. Moore, R. Zhang 2:35 661. Chemical recycling of polycar bonates with (supercritical) ammonia. W. Mormann, D. Spitzer 3:05 Intermission. 3:20 662. Evolution of polycarbonate process and product chemistries. D. J. Brunelle, P. M. Smigelski Jr. 3:50 663. Reactions and polymerization in polycarbonates: How can theory help our understanding? R. O. Jones, P. Ballone, J. Akola 4:20 664. Solid-state polymerization of poly(bisphenol A carbonate) facilitated by supercritical carbon dioxide. C. Shi, S. M. Gross, J. M. DeSimone, G. W. Roberts, D. J. Kiserow Section Ε Hilton Riverside Grand Salon D21/D24 Polymer Brushes: From Synthesis to Functional Microstructures Physisorption/Characterization Cosponsored with Division of Polymeric Materials: Science and Engineering K. Caster, Organizer,
3:40 Intermission. 3:55 669. Nanomechanics of polymer brush layers. V. Tsukruk 4:30 670. Off-specular X-ray scattering study of polystyrene brush interfaces. H. Kim, M. D. Foster, P. MuellerBuschbaum, H. Zhang, O. Prucker, J. Ruhe 5:05 671. Shape changes of statistical copolymacromonomers: From wormlike to horseshoe- and meanderlike struc tures. M. Schmidt, T. Stephan 5:30 672. Organization of silica nanoparticles on diblock-copolymer and mixed brushes. S. Prokhorova, A. Kopyshev, A. Ramakrishnan, H. Zhang, J. D. J. S. Samuel, J. Ruhe
Presiding
W. J. Brittain, R. C. Advincula, and J. Ruhe, Organizers 1:30 665. Study of polyelectrolyte brushes formed from adsorption of amphiphilic diblock copolymers using the surface forces apparatus. M. V. Tirrell 2:05 666. Model systems for flat, dense polyelectrolyte brushes from self-as sembled amphiphilic diblock copolymers. D. Bendejacq, V. Ponsinet, M. Joanicot 2:40 667. Structure and scaling of poly mer brushes formed from branched polymer amphiphiles. S. M. Kilbey II, P. Tian 3:15 668. Tethering of end-functional polymer chains in the presence and absence of segmental adsorption: Differ ences in process and outcome. L. Penn, H. Huang, R. P. Quirk, T. Cheong
THURSDAY MORNING Section A
Hilton Riverside Grand Salon C18/C15
Hilton Riverside Grand Salon D19/D22
Polymer Design Using Non-covalent Methods
Advances in Polycarbonates
M. Week and K. J. Shea, Presiding
D. J. Brunelle, Organizer, Presiding
T. E. Long, R. A. Gross, V. Rotello, and E. W. Meijer, Organizers
M. R. Korn, Organizer 8:30 Introductory Remarks. 8:35 673. Economic relevance of advances in polymer structure modifica tion: Reviewed for bisphenol A polycar bonate. W. Paul, K. Horn, H. Laue 9:05 674. Weatherable polyarylate-copolycarbonate engineering thermoplas tic. J. A. Suriano, T. M. Siclovan, J. E. Pickett, D. J. Brunelle, G. A. O'Neil, H. Zhou 9:35 675. Morphology and supramolecular structure of 4,4'-dihydroxydiphenyl-copolycarbonate. A. Karbach, D. Drechsler, U. Wollborn, M. Erkelenz, M. Moethrath, J. Mason, K. Horn 10:05 Intermission. 10:20 676. 2,5-Dihydroxyphenyldiphenylphosphine oxide/BPA copolycarbonate: Monomer and copolymer synthesis and characterization. G. C. Davis, D. R. Joyce, E. M. A. Gijzen 10:50 677. Synthesis of 1,1 -dichloro-2,2bis[4'-(4-hydroxyphenyl)phenyl]ethene and its incorporation into homo- and heteropolymers. D. Boyles, T. S. Filipova, J. T. Bendler, M. J. Schroeder 11:20 678. High-heat polycarbonates containing bisaryl units: Theory and modeling. J. T. Bendler, D. A. Boyles Section Β Hilton Riverside Grand Salon C16/C13 NMR Spectroscopy of Polymers Biological Polymers Cosponsored with Division of Analytical Chemistry
8:30 686. Supermolecular associates of polyamidines with low molecular weight proton donors. B. I. Voit, K. Sharavanan, F. Bôhme 8:55 687. Designing topological^ unique macromolecular architectures by electrostatic self-assembly and covalent fixation. Y. Tezuka 9:20 688. Effects of salt and temperature on aggregation stability of block ionomer complexes. S. V. Solomatin, T. Bronich, V. Kabanov, A. Eisenberg, A. V. Kabanov 9:45 689. Layer-by-layer polyelectrolyte film/oligoethylene glycol dicarboxylic acid composite film as a solid-state polyelectrolyte for electrochemical photovoltaic devices. H. Tokuhisa, P. T. Hammond 10:10 690. Reversible pH-induced complexation of polyelectrolyte and watersoluble silica nanoparticles as intelligent colloidal hybrids. H. Mori, A. H. E. Muller, J. E. Klee 10:35 691. Polymer-protein giant amphiphiles by metal-to-ligand coordination. K. Velonia, P. Thordarson, P. R. Andres, U. S. Schubert, A. E. Rowan, R. J. M. Nolte 11:00 692. Multihue electrochromism in polymer/inorganic composites from layer-by-layer assembly. D. M. DeLongchamp, P. T. Hammond 11:25 693. "Holy Trinity" of micelles in aqueous solution at ambient temperature: Unprecedented self-assembly behavior from a binary mixture of a neutral-cationic diblock copolymer and an anionic polyelectrolyte. J. V. M. Weaver, S. Liu, S. P. Armes
T. Asakura, Presiding H. N. Cheng and A. D. English, Organizers 8:30 679. Studies of the structure of novel natural polysaccharides. J. F. G. Vliegenthart 9:15 680. NMR methods in the study of polysaccharides. A. L. Segre, D. Capitani, L. Mannina
Section D Hilton Riverside Grand Salon B9/B12 Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Applications/ Characterization Cosponsored with Division of Polymeric Materials: Science and Engineering T. E. Patten, Presiding W. J. Brittain, R. C. Advincula, J. Ruhe, and K. Caster, Organizers 8:30 694. Preparation of thick polymer brushes for separation applications. M. L. Bruening, M. D. Miller, A. M. Balachandra, W. Huang, G. L. Baker 9:05 695. Gradient polymer brushes: Preparation and applications. M. R. Tomlinson, T. Wu, K. Efimenko, J. Genzer 9:40 696. Photochemical strategies for the preparation, micropatteming, and modification of polymer brushes. J. Ruhe, O. Prucker, J. Habicht, I. Park 10:05 Intermission. 10:20 697. Swelling behavior of surfaceattached neutral and charged brushes. M. A. Biesalski, J. Ruhe 10:45 698. "Bottle brush" brushes. G. L. Baker, J. Kim, Z. Bao, C. Wang, W. Huang, M. L. Bruening 11:10 699. Hyperbranched polyglycidol brushes. W. T. S. Huck, M. Khan 11:45 700. Responsive mixed polymer brushes for patterning of surfaces. S. Minko, D. Usov, V. Luchnikov, M. Mueller, L. lonov, A. Scholl, G. Pfuetze, M. Stamm Colloidal and Molecular Electro-Optics Biomolecular Systems Cosponsored with Division of Colloid and Surface Chemistry
THURSDAY AFTERNOON Section A Hilton Riverside Grand Salon D19/D22 Advances in Polycarbonates K. L. Wooley, Presiding D. J. Brunelle and M. R. Korn, Organizers 1:00 Introductory Remarks. 1:05 701. Behavior of small molecules in polycarbonates. R. Kirchheim 1:35 702. Synthesis and characterization of mechanically linked polycarbonate. C. Bailly, G. Clarkson, P. De Groote, C. A. Fustin, T. H. Galow, D. A. Leigh, D. Robertson, A. M. Z. Slawin, J. Κ. Υ. Wong 2:05 703. The synthesis and study of isomeric linear and hyperbranched polycarbonates. K. L. Wooley, D. H. Bolton, J. Byers, D. Gan, J. Goetz, B. Poliks, J. Schaefer 2:35 Intermission. 2:45 704. Carbon nanotube-filled polycar bonate composites produced by melt mixing and their use in blends. P. Potschke, A. R. Bhattacharyya 3:15 705. Electrospinning of polycarbon ate nanofibers with THF and DMF. N. Kattamuri, J. Shawon, C. Sung 3:45 Concluding Remarks.
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-131
TECHNICAL PROGRAM Section Β Hilton Riverside Grand Salon C16/C13 NMR Spectroscopy of Polymers Biological Polymers Cosponsored with Division of Analytical Chemistry Η. Ν. Cheng, Organizer, Presiding A. D. English, Organizer 1:30 706. Structural determination of oligo- and polysaccharides by NMR spectroscopy. H. van Halbeek, S. Sheng, R. Chemiak 1:55 707. Recent studies of the chondroitin sulfate/dermatan sulfate polymer systems using NMR spectroscopy. T. N. Huckerby, R. M. Lauder, I. A. Nieduszynski 2:20 708. NMR application to the charac terization of chitosan and chitosan self-assemblies. R. Auzely, M. Rinaudo Section C Hilton Riverside Grand Salon C18/C15
2:40 719. Fabrication of surface-confined, stimulus-responsive polymer nanostructures using dip-pen nanolithography. S. Zauscher, A. Chilkoti, S. Ann, J. Hyun, W. Lee 3:05 Intermission. 3:20 720. A versatile method for tuning the chemistry and size of nanoscopic features by living free-radical polymer ization. C. J. Hawker, K. R. Carter, D. Germack, T. A. von Werne 3:45 721. Spherical polyelectrolyte brushes as synthesized by photoemulsion polymerization. A. Wittemann, M. Ballauff, B. Haupt, T. Narayanan, N. Dingenouts 4:10 722. Synthesis of well-defined organic-inorganic nanocomposites using living cationic surface-initiated polymer ization. S. Chen, I. Kim, R. Faust 4:35 723. Structure and properties of high-density polymer brushes. Y. Tsujii, S. Yamamoto, M. Ejaz, T. Fukuda 5:00 Concluding Remarks. Colloidal and Molecular Electro-Optics Crystalline Systems and Gels Cosponsored with Division of Colloid and Surface Chemistry
T. E. Long, R. A. Gross, V. Rotello, and E. W. Meijer, Organizers 1:00 709. Recent developments in molecular imprinting. K. J. Shea 1:25 710. New methods of synthesizing and characterizing molecularly imprinted polymers. K. D. Shimizu 1:50 711. Side- and main-chain functionalized copolymers via multistep selfassembly. M. Week, J. M. Pollino, L. P. Stubbs, A. Meyers, J. R. Carlise, M. N. Higley, M. Crne 2:15 712. Shape selectivity in noncovalently imprinted polymers. D. A. Spivak, R. Simon, J. Campbell, M. Sibrian-Vazquez 2:40 713. 2-D oligomers for light-emitting diodes. Z. I. Niazimbetova, A. Menon, M. E. Galvin 3:05 714. Influence of template-monomer ratio on binding sites within molecular imprinted polymers. D. A. Spivak, H.Kim 3:30 715. Equilibrium and dynamic prop erties of main-chain reversible polymers. S. Craig, W. C. Yount, E. A. Fogleman, J.Xu 3:55 716. Synthesis and properties of conjugated polymer networks formed by noncovalent interactions. C. Weder, A. Kokil, C. Huber, I. Shiyanovskaya, W. R. Caseri, K. D. Singer Section D Hilton Riverside Grand Salon B9/B12 Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Applications Cosponsored with Division of Polymeric Materials: Science and Engineering J. Ruhe, Organizer, Presiding W. J. Brittain, R. C. Advincula, and K. Caster, Organizers 1:30 717. Highly aromatic polymer brushes: Toward molecular masks. L M. Tolbert, C. X. Chen, D. W. Hess, J. Ruhe 2:05 718. Passive and active nonfouling polymer grafts. A. Chilkoti, H. Ma, J. Hyun, N. Nath
132-TECH
Adsorption of Macromolecules at Liquid-Solid Interfaces (see Division of Colloid and Surface Chemistry, Sun. Mon, Tue) Nanoscale Imaging of Biological Systems (see Division of Colloid and Surface Chemistry, Sun. Mon) Hybrid Materials (see Materials Chemistry Secretariat, Sun. Mon, Tue) Synthesis, Spectroscopy, Characterization, and Applications of Nanoparticles (see Division of Physical Chemistry, Sun. Mon. Tue. Wed. Thu) SOCIAL EVENTS: Breakfast: Sun. Mon. Tue. Wed. Thu Executive Meeting: Sun Luncheon: Mon, Tue Reception: Mon Social Hour Tue BUSINESS MEETING: Wed
Polymer Design Using Non-covalent Methods B. I. Voit and Y. Tezuka, Presiding
Adamson Award Symposium Honoring Dave Allara and Ralph Nuzzo (see Division of Colloid and Surface Chemistry, Tue, Wed, Thu)
DIVISION OF POLYMERIC MATERIALS: SCIENCE AND ENGINEERING A. J. Dias, Program Chair
Biotechnology in the Service of Health (see Biotechnology Secretariat, Sun) From Sensors to Functional Instruments (see Division of Analytical Chemistry, Wed) Fundamentals of Electrospray Ionization (see Division of Analytical Chemistry, Tue) Macromolecules to Bioparticles: Analyses with Field-Flow Fractionation (see Division of Analytical Chemistry, Mon) Size-Exclusion Chromatography with Multiple Detection Techniques (see Division of Analytical Chemistry, Wed) Advances in Tissue Engineering and Cell Therapy (see Division of Biochemical Technology, Wed) Separations and Process Technology for Genetic Therapy and Diagnosis (see Division of Biochemical Technology, Thu)
Section C Hilton Riverside Grand Salon B7 Synthesis, Characterization, and Application of Multiphase and Composite Materials Fibers and Tubes
SUNDAY MORNING
M. A. Sharaf and P. R. L. Malenfant, Presiding
Section A
A. J. Dias, Organizer
Hilton Riverside Grand Salon A3
8:00 15. Controlled alignment of carbon nanotubes on curved substrates. M. Spotnitz, D. Ryan, H. A. Stone 8:30 16. Electrospun nanofibers hybrid ized with metal nanoparticles. H. Hou, D. H. Reneker 9:00 17. Fabrication of Au nanowires on peptide nanotubes by tuning sequenced peptide conformations. H. Matsui, R. Djalali, Y. Chen 9:30 18. Nanoscale titanium dioxide coatings applied to electrospun nanofi bers. C. Drew, D. Ziegler, X. Wang, F. F. Bruno, L Samuelson, J. Kumar 10:00 19. Observation of clay particles in electrospun fibers and other matrices. Z. Sun, D. H. Reneker 10:30 20. Biochemical sensor via combi nation of electrospinning with electro static layer-by-layer assembly. X. Wang, Y. Kim, C. Drew, B. Ku, J. Kumar, L. A. Samuelson 11:00 21. Study of the relationship between jet diameter and interference color during electrospinning. H. Xu, D. C. Galehouse, D. H. Reneker 11:30 22. Reinforcement and matrix chain deformation in fiber-filled poly(ethylene) nanocomposites. M. A. Sharaf, K. B. Mashali, M. Hammam, S. A. Abdel-Ghani, K. Jacob
General Papers L. L. Lewis and A. B. Padmaperuma, Presiding
OTHER SYMPOSIA OF INTEREST:
9:40 10. Gel permeation chromatography coupled to Fourier transform mass spectrometry for polymers. W. J. Simonsick Jr., W. Zhong, L. Prokai, M. D. Soucek 10:20 11. Investigation of copolymers by liquid chromatography and matrixassisted laser desorption/ionization. F. J. Mayer-Posner, H. Kaminski, V. Sauerland, S. Ndoni, W. Badsberg Petersen, S. Hivdt, P. Kingshott 10:50 12. Synthesis and MALDI MS study of discrete mass poly(butylenene glutarate) oligomers. J. B. Williams, T. Chapman, D. M. Hercules 11:20 13. Characterization of implantable device materials using GPC-ESI MS and GPC with triple detection. X. M. Liu, E. P. Maziarz, W. J. Simonsick, D. J. Heiler, G. L Grobe 11:50 14. Thermal field-flow fractionation as a separation method for MALDI-TOF MS. K. R. Williams, G. E. Kassalainen
A. J. Dias, Organizer 8:30 1. Behavior and limitations of isother mal frontal polymerization of methyl methacrylate systems. L. L. Lewis, A. Perryman, J. Pojman Sr. 9:00 2. Effect of phosphonic acid anion structure on the corrosion inhibition of steel by polyaniline. Y. Idlibi, T. Schuman, J. Stoffer 9:30 3. Viscoelastic effects on dynamics of concentration fluctuations in polymer solutions. M. Takenaka, M. Miyazawa, T. Hashimoto 10:00 4. Correlation of material and processing time scales with structure development in isotactic polypropylene crystallization. A. Elmoumni, H. Fruitwala, H. H. Winter 10:30 5. Cross-linking studies on polyeth ylene terephthalate-co-1,4-phenylene bisacrylate). H. Ma, M. Vargas, D. M. Collard, S. Kumar, D. Schiraldi 11:00 6. Effect of molecular orientation on polymer free volume distribution: An atomistic approach. H. Dong, K. Jacob 11:30 7. Plasticization of liquid-crystalline and nonl-iquid-crystalline epoxies. J. Feng, E. P. Douglas Section Β Hilton Riverside Grand Salon A6 MALDI and ESI Mass Spectrometry Techniques for Polymers Chromatography-MS Cosponsored with Division of Analytical Chemistry
Section D Hilton Riverside Grand Salon A4 New Concepts in Biomaterials: Synthesis, Application, Concerns Bioinspired Materials and Composites L. Tsou and J. G. Hilborn, Presiding A. J. Dias, Organizer 8:00 23. Biomimetic synthesis of silica structures. S. V. Patwardhan, S. J. Clarson
M. E. Bier, Organizer, Presiding R. P. Lattimer, Organizer 9:00 8. Introduction to mass spectrometry of polymers. R. P. Lattimer 9:20 9. The basics of MALDI and ESI mass spectrometers for polymer analy sis. M. E. Bier
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
POLY/PMSE/TECHNICAL PROGRAM
8:25 24. Nature-inspired method for protein-polysaccharide conjugation. T. Chen, D. A. Small, W. E. Bentley, G. F. Payne 8:50 25. Withdrawn. 9:15 26. Controlling mammalian cell adhesion on patterned weak polyelectrolyte multilayers. M. C. Berg, S. Y. Yang, J. D. Mendelsohn, P. T. Hammond, M. F. Rubner 9:40 27. Synthesis of shell cross-linked nanoparticles that present surfaceattached biotin. K. Qi, Q. Ma, E. E. Remsen, K. Wooley 10:05 28. Effect of acidic comonomers on methacrylate conversion and mechanical strength of bioactive composites based on amorphous calcium phosphate. J. M. Antonucci, W. G. McDonough, D. Liu, D. Skrtic 10:30 29. Novel biocompatible supramolecular materials for tissue engineering. P. Y. W. Dankers, D. J. M. van Beek, A. T. ten Cate, R. P. Sijbesma, E. W. Meijer 10:55 30. A biomolecular approach to polymer encapsulation in mesoporous materials. C. D. Ford, L. Liu, M. Singh, J. He, V. T. John, G. McPherson, M. Sennett, A. Bose 11:20 31. Biocomposites from engineered kenaf natural fibers and unsaturated polyester resin for low-cost housing applications. G. Mehta, A. K. Mohanty, L. T. Drzal, M. Misra 11:45 32. Renewable plastics: Synthesis and properties of PHB nanocomposites. P. Maiti, C. A. Batt, E. P. Giannelis 12:10 33. Nano reinforcements of biobased polymers: The hope and the reality. A. K. Mohanty, L. T. Drzal, M. Misra Nanotechnology and the Environment Overview: Environmental Applications and Implications Cosponsored with Division of Industrial and Engineering Chemistry
SUNDAY AFTERNOON Section A Hilton Riverside Grand Salon A3 Cooperative Research Award Honoring Craig Hawker and Tom Russell S. R. Turner, Presiding J. M. J. Fréchet and K. L. Wooley, Organizers 12:55 Introductory Remarks. 1:00 34. Metal nanodots and nanoporous metal films via sacrificial polymer thinfilm templates. T. P. Russell 1:30 35. Toward commodity plastics by molecular design. A. M. Mayes, M. H. Acar, J. A. Gonzalez-Leon 2:00 36. Nanoscience to nanotechnology: An example from the microelectronics industry. R. D. Miller, E. Connor, C. Hawker, J. L. Hedrick, E. Huang, H. Kim, V. Y. Lee, T. Magbitang, L. K. Sundberg, M. Toney, W. Volksen 2:30 37. ATRP at surfaces. K. Matyjaszewski 3:00 38. The breadth and depth of olefin metathesis chemistry. R. H. Grubbs 3:30 39. Synthetic macromolecules in therapeutics: Design, synthesis, and functional testing of polymers for protein and DNA transport and delivery. J. M. J. Fréchet, Ν. Murthy, M. Dubber, S. Goh, S. Schuck, M. Xu
4:00 40. Kinetically trapped segregated mixtures of hyperbranched fluoropolymers and linear polyethylene glycoljs: Treacherous terrain to inhibit biofouling. K. L Wooley, C. Gudipati, J. Johnson, D. Gan 4:30 41. Polymeric opportunities at the nanotechnology frontier: From micro electronics to biotechnology. T. P. Russell, C. J. Hawker Section Β Hilton Riverside Grand Salon A6 MALDI and ESI Mass Spectrometry Techniques for Polymers General Papers Cosponsored with Division of Analytical Chemistry R. P. Lattimer, Organizer, Presiding M. E. Bier, Organizer 1:30 42. Virtual mass spectrometry labo ratory and a polymer analysis case study. M. E. Bier, C. G. Yang, J. Grabowski 1:50 43. A multiple-layer-spotting approach for MALDI-TOF-MS: New possibilities for an implementation into combinatorial polymer research. M. A. R. Meier, U. S. Schubert 2:30 44. The influence of laser energy and matrix of MALDI on the molecular mass distribution of poly(ethylene gly col). S. J. Wetzel, C. M. Guttman, J. E. Girard 3:00 45. Direct characterization of poly meric hindered amine light stabilizer in polypropylene by reactive thermal desorption-gas chromatography and MALDI-MS using solid-sampling tech nique. H. Ohtani, Y. Taguchi, Y. Ishida, S. Tsuge, K. Kimura, T. Yoshikawa 3:30 46. Application of MALDI for oligomeric hindered amine light stabilizers. T. T. Chang, M. J. Piquette, M. L. Cohen 3:50 47. Analysis of polyethylenimine by ESI-MS and MALDI-TOF-MS. J. E. Girard, M. Konaklieva, J. Gu, C. M. Guttman, S. J. Wetzel 4:10 48. MALDI-TOF-MS characterization of covalently cationized polymers. H. C. M. Byrd, S. Lin-Gibson, S. Bencherif, K. L. Beers, D. L. VanderHart, B. J. Bauer, B. M. Fanconi, C. M. Guttman, W. E. Wallace Section C Hilton Riverside Grand Salon B7 Synthesis, Characterization, and Application of Multiphase and Composite Materials C. Huang and A. Alizadeh, Presiding A. J. Dias, Organizer 1:00 49. Self-assembled, intercalated responsive polydiacetylene-based crys tals. X. Li, B. McCaughey, J. Pang, X. Ji, Y. Lu 1:25 50. Thermochromatic polydiacetylene nanocomposites with reversible mesoscopic order. B. F. McCaughey, Y. Lu, X. Li, J. Pang, X. Ji 1:50 51. Development of novel binary and ternary conductive composites based on polyethylene, low melting point alloy, and carbon black. E. Bormashenko, S. Sutovski, R. Pogreb, A. Sheshnev, A. Shulzinger, M. Levin, A. Westfrid 2:15 52. Hierarchically structured porous polydivinylbenzene beads. A. Larsson, U. Meyer 2:40 53. Preparation and exfoliation mechanism of the epoxy nanocomposite. C. Chen, D. Curliss
3:05 54. Size control of cadmium sulfide nanoparticles within random ionomer solutions. W. Jia, E. P. Douglas 3:30 55. Polymer-clay nanocomposites prepared in supercritical carbon dioxide. M. Garcia-Leiner, A. J. Lesser 3:55 56. Filler-induced deformations of polyethylene chains: Comparisons with other simulations and neutron-scattering experiments. M. A. Sharaf, A. Kloczkowski, K. Jacob, J. E. Mark 4:20 57. Innovative process for compatibilizing polymer blends and producing well-exfoliated polymer nanocomposites: Solid-state shear pulverization. A. H. Lebovitz, K. Kasimatis, J. M. Torkelson 4:45 58. Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites. B. F. McCaughey, C. Costello, D. Wang, J. E. Hampsey, C. Li, C. J. Blinker, Y. Lu 5:10 59. Synthesis and polymerization of reactive monoacylglycerols to stabilized bicontinuous cubic nanoparticles. D. Yang, S. Liu, D. F. O'Brien, S. R. Marder 5:35 60. Nanostructured layer-by-layer deposition and cross-linking of hyper branched poly(amidoamine)-grafted silica nanoparticles and poly(acrylic acid). M. Park, R. Advincula, N. Tsubokawa, B. Brookins Section D Hilton Riverside Grand Salon A4 New Concepts in Biomaterials: Synthesis, Application, Concerns A. K. Andrianov and M. A. Biesalski, Presiding A. J. Dias, Organizer 1:00 61. Synthesis of polyurethanes incorporating long alkyl side chains with pendant carboxyl groups. F. I. Simonovsky, Y. Wu, T. A. Horbett, B. D. Ratner 1:25 62. Design and synthesis of functionalized polyphosphazenes with immunemodulating activity. A. K. Andrianov 1:50 63. Biodegradable phosphatidylcho line functional poly(e-caprolactone). J. G. Hilborn, T. Bowden, J. Hong, B. Nilsson, C. Elvingsson 2:15 64. Biomimetic assemblies from polymerizable peptide-amphiphiles. M. A. Biesalski, A. Knaebel, K. Shroff, R. S. Tu, M. Tirrell 2:40 65. Enzymatic polymerization in spontaneously formed CTAB/HDBS vesicle bilayers. M. Singh, V. Agarwal, C. D. Ford, L Liu, G. McPherson, P. W. Johnson, A. Bose, V. T. John, M. Sennett 3:05 66. Physical aging of degradable polymers using biorelevant conditions and hydrated test specimens. S. D. Abramson, J. Kohn 3:30 67. Synthesis of long poly(dG)Epoly(dC) without structural defects using enzymatic reaction. S. Tanaka, H. Tanaka, M. Taniguchi, H. Tabata, S. Fujiwara, S. Uchiyama, K. Fukui, T. Kawai 3:55 68. Freshness preservation material for fruits and vegetables fabricated by the sequential deposition using the enzyme immobilization. S. Shiratori, T. Sato 4:20 69. Synthesis of long-strand DNA with specific sequences using enzymatic reaction: Poly(dA)Epoly(dT). S. Tanaka, H. Tanaka, M. Taniguchi, H. Tabata, S. Fujiwara, S. Uchiyama, K. Fukui, T. Kawai
4:45 70. Antioxidant activity of dendrimers conjugated with green tea catechin. H. Uyama, J. E. Chung, M. Kurisawa, S. Kobayashi Nanotechnology and the Environment Toxicology and Biological Interactions of Nanomaterials Cosponsored with Division of Industrial and Engineering Chemistry
MONDAY MORNING Section A Hilton Riverside Grand Salon A3 Chemistry of Materials Award Symposium in Honor of Larry Dalton Optoelectronics: From Nanostructured Materials to Devices (I) S. Creager, Presiding A. K. Jen, Organizer 8:30 71. Nanoprecise construction of optically functional molecular heterostructures. T. J. Marks 9:00 72. Optimization of chromophores for nonlinear optical applications. S. R. Marder 9:30 73. Nanoscale architectural control of organic functional materials for photonics and molecular electronics. A. K. Jen, H. Ma, J. Luo, S. Liu, M. Haller, S. Jang, L. Dalton, H. Zareie, B. Reed, M. Sarikaya 10:00 74. Nanochemistry for nanophotonics and biophotonics. P. N. Prasad 10:30 Intermission. 10:45 75. Thermal stability and absorption behavior in FTC-like guest-host E-0 polymers. S. Ermer, R. R. Barto Jr., R. E. Taylor, P. V. Bedworth, J. Epstein 11:15 76. Organic materials under high fields: From poled polymers to transis tors and back again. H. E. Katz, M. Lee, P. Gopalan, C. Erben, M. Mushrush, T. J. Marks 11:45 77. Nanoporous thin films: Genera tion, characterization, and applications. R. D. Miller, V. Volksen, C. J. Hawker, J. L. Hedrick, V. Y. Lee, T. Magbitang, H. Kim, L. K. Sundberg, M. F. Toney, E. Huang, E. Connor Section Β Hilton Riverside Grand Salon A6 MALDI and ESI Mass Spectrometry Techniques for Polymers Polymer Chemistry Cosponsored with Division of Analytical Chemistry R. P. Lattimer, Organizer, Presiding M. E. Bier, Organizer 9:00 78. The Power of MALDI for prepar ing electrically conductive nanowires. R. D. McCullough 9:40 79. End group characterization in anionic polymerizations via mass spec trometry methods. C. Wesdemiotis, M. A. Arnould, R. P. Quirk 10:10 80. ESI and MALDI-TOF MS analy sis of implantable device polymers and their interactions with proteins. E. P. Maziarz III, X. M. Liu, G. L. Grobe, G. A. Baker, J. Bonafini
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
TECH-133
TECHNICAL PROGRAM 10:40 81. Analysis of copolymers and coatings formulations by ESI and MALDI. C. Jasieczek Mastromatteo, A. Scott, J. Benga, S. Campbell, B. Kirol, A. Tse 11:10 82. Purity control of ester-endfunctionalized polypropylene glycol) telechelics by MALDI-TOF MS. A. Kraft, G. Rabani, H. Luftmann 11:30 83. Structural analysis of polyanilines by MALDI and ESI-MS/MS. T. D. Wood, A. R. Dolan 11:50 84. MALDI-TOF analysis of allaromatic polyesters. H. K. Hall Jr., A. Somogyi, A. B. Padias, N. Bojkova, E. H. Elandaloussi Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Near-Field Microscopy Studies of Polymeric Materials: I D. A. Higgins, Presiding J. D. Batteas and G. C. Walker, Organizers 9:00 85. Imaging nanoscale electrical properties in polymer semiconductors. P. F. Barbara, D. Y. Kim, J. D. McNeill 9:45 86. Scanning near-field dielectric microscopy at microwave frequencies for materials characterization. S. J. Stranick, S. A. Buntin, C. A. Michaels 10:15 87. The nature and spatial distribu tion of interchain species in films of conjugated polymers: NSOM solvatochromism and third harmonic generation experiments on MEH-PPV films. B. J. Schwartz, T. Nguyen, R. D. Schaller, L. F. Lee, J. C. Johnson, R. J. Saykally 10:45 Intermission. 11:00 88. Apertureless scanning near-field infrared microscopy for chemical imag ing of thin films. B. B. Akhremitchev, L Stebounova, G. C. Walker 11:30 89. Near-field polarimetric charac terization of semicrystalline polymer systems. S. N. Goldie, L. S. Goldner, M. J. Fasolka, J. Hwang, K. L. Beers Section D Hilton Riverside Grand Salon A4 Synthesis, Characterization, and Application of Multiphase and Composite Materials Block Copolymers R. B. Grubbs and S. Sun, Presiding A. J. Dias, Organizer 8:00 90. ABC triblock copolymers for complexation of gold and cobalt nanoparticles. R. B. Grubbs, L A. Miinea, L. B. Sessions, K. D. Ericson, D. S. Glueck 8:25 91. Organic-inorganic nanostructured materials through self-assembly of a new set of amphiphilic block copoly mers. S. Mahajan, S. Renker, P. F. W. Simon, J. S. Gutmann, A. Jain, Y. Zhang, S. M. Gruner, L. J. Fetters, G. W. Coates, U. Wiesner 8:50 92. Synthesis and characterization of elastomeric side-chain liquid crystal block copolymers. L. C. McAfee, P. T. Hammond 9:15 93. Self-organizing block copolymer film with hierarchical structure. T. Hayakawa, S. Horiuchi 9:40 94. Synthesis of block copolymers of p-acetoxystyrene with isoprene by "living" radical polymerization. J. C. Moreira, S. H. Wang 10:05 96. Block copolymers for photovoltaics. S. Sun
134-TECH
10:30 95. Morphology control of tetrablock quaterpolymer. H. Hasegawa, K. Takahashi, T. Hashimoto, H. latrou, V. Bellas, N. Hadjichristidis 10:55 97. Pressure-dependent phase transition in block copolymers. M. H. Acar, J. A. Gonzalez, A. M. Mayes 11:20 98. Composition fluctuations of block copolymer/ homopolymer blends under a uniform shear flow. C. Huang 11:45 99. Synthesis of polyamide-based thermoplastic elastomers. G. Rabani, A. Kraft 12:10 100. Synthesis and characterization of silk-like polyurethanes. L. T. James-Korley, P. T. Hammond Macromolecules to Bioparticles: Analyses with Field-Flow Fractionation Cosponsored with Division of Analytical Chemistry Nanotechnology and the Environment Treatment/Remediation Using Nanotechnology Cosponsored with Division of Industrial and Engineering Chemistry
MONDAY AFTERNOON Section A Hilton Riverside Grand Salon A3 Chemistry of Materials Award Symposium in Honor of Larry Dalton Optoelectronics: From Nanostructured Materials to Devices
M. E. Bier, Organizer,
Presiding
R. P. Lattimer, Organizer 1:30 108. Using monomers as standards for analysis of copolymers by ESI-MS with collision-induced dissociation. B. S. Prebyl, K. D. Cook 2:00 109. Analysis of combustion cham ber deposits by ESI-TOF-MS and MALDI-TOF-MS: Evidence of thermal degradation of polymeric gasoline addi tives. J. G. Reynolds, S. J. Shields, J. W. Roos 2:30 110. An application of MALDI-MS and reactive molecular dynamics in determining the mechanisms of char formation during the thermal and oxida tive degradation of polymers. M. R. Nyden, W. H. Awad, W. E. Wallace 3:00 111. Characterization of an insoluble polyimide oligomer by MALDI-TOF-MS. A. P. Gies 3:30 112. Thermal cyclization reactions occurring with synthetic peptides and proteins. K. J. Voorhees, M. A. Meetani, F. Basile 3:50 113. Pyrolysis mass spectrometry of acrylic acid polymers. R. P. Lattimer 4:10 114. Photooxidation mechanisms of polyetherimide Ultem investigated by MALDI-TOF-MS. C. Puglisi, G. Montaudo, S. Carroccio Section C Hilton Riverside Grand Salon B7
1:55 122. Metallo-supramolecular graft copolymers: Micelle formation. H. Hofmeier, J. Gohy, U. S. Schubert 2:20 123. Giant vesicles undergoing alkylation reactions observed by optical microscopy. T. Clark Jr., D. A. Jaeger 2:45 124. Chitosan hydrogels: Cross-link kinetics and gel properties. S. Lin-Gibson, H. J. Walls, S. B. Kennedy, E. R. Welsh 3:10 125. Polymer vesicles of PEO-PLA and related for controlled release. D. E. Discher 3:35 126. Vesicular transportation in cell-cell communication as a means for a novel drug carrier. F. P. J. Nederberg, T. Bowden, J. G. Hilborn 4:00 127. Uptake ability, modeling the size, and biological evaluation of silicatemplated o/w microemulsion. A. V. Jovanovic, R. Cuadrado, T. L Bucholz, R. S. Underhill, J. A. Flint, M. Varshney, T. E. Morey, D. M. Dennis, R. S. Duran 4:25 128. Network structure of novel PEG hydrogels and its impact on degradation behavior. A. T. Metters, J. A. Hubbell 4:50 129. Studies of the transport of erythromycin through tetrabutylammonium-doped Nafion/surface-modified glass microsphere composites. T. J. Thomas, S. D. Minteer Nanotechnology and the Environment Treatment/Remediation Using Nanotechnology Cosponsored with Division of Industrial and Engineering Chemistry
MONDAY EVENING
K. P. Fivizzani, Presiding A. K. Jen, Organizer 1:30 101. Novel strategies for ordering organic-NLO chromophores at high concentration. Β. Η. Robinson, H. L Rommel, R. N. Nielsen 2:00 102. Optimization of organolanthanide coordination complexes for photonic applications. A. W. Harper 2:30 103. Conjugated diblock copolymers for molecular electronics and photonics. LYu 3:00 Intermission. 3:15 104. Electrical properties of polyimides for optical cladding. G. A. Lindsay, A. P. Chafin, M. C. Davis, S. Fallis, A. J. Guenthner, R. A. Hollins, P. Zarras 3:30 105. DNA-based cladding material for nonlinear optic polymer-based elec tro-optic devices. J. G. Grote 4:00 106. AFOSR program in photonic polymers. C. Y. Lee 4:30 107. Award Address (ACS Award in the Chemistry of Materials, sponsored by E. I. du Pont de Nemours & Com pany). Organic electro-optic materials: Past, present, and future. L. R. Dalton Section Β Hilton Riverside Grand Salon A6 MALDI and ESI Mass Spectrometry Techniques for Polymers Degradation Cosponsored with Division of Analytical Chemistry
Applications of Scanning Probe Microscopy to Polymers Near-Field Microscopy Studies of Polymeric Materials
Section A
S. J. Stranick, Presiding
Sci-Mix
J. D. Batteas and G. C. Walker, Organizers
A. J. Dias, Organizer
1:30 115. Scanning probe microscopy of processes in synthetic polymers. J. K. Hobbs, A. D. L Humphris, H. H. Haschke, N. Sanz, M. J. Miles 2:15 116. Photorefractive polymer-dis persed liquid crystals studied by nearfield scanning optical microscopy. J. E. Hall, D. A. Higgins 2:45 117. Chemical imaging of thin-film polymer blends with near-field IR micros copy. C. A. Michaels, D. B. Chase, S. J. Stranick 3:15 Intermission. 3:30 118. Time-resolved fluorescence near-field scanning optical microscopy of conjugated polymer thin films. D. A. Vanden Bout, E. Kwak 4:00 119. AFM Studies on PS/PMMA of polymer blends and copolymers in air and under water. W. C. Johnson Jr., S. E. Woodcock, Z. Chen, J. Wang 4:30 120. Scanning probe photothermal FTIR spectroscopy and microscopy. D. M. Adams
171-172,174, 176,183,186,188-193,198, 201, 203, 206-207, 212-214, 226-227, 231, 233, 236-238, 241-243, 251, 253, 257-259, 261. See subsequent listings.
Section D Hilton Riverside Grand Salon A4 New Concepts in Biomaterials: Synthesis, Application, Concerns Controlled Release
Convention Center Hall G
8:00-10:00
TUESDAY MORNING Section A Hilton Riverside Grand Salon A3 In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymer Chemistry J. L. P. Jessop, Organizer, Presiding 9:00 Introductory Remarks. 9:05 130. Monitoring photopolymerizations using optical pyrometry. B. Falk, S. M. Vallinas, J. V. Crivello 9:35 131. Determination of reactivity ratios in cross-linking systems based on in situ monitoring of double bond conversions. J. F. G. A. Jansen, J. Hoffman, E. J. E. Houben 10:05 132. Using EPR spectroscopy in conjunction with FT-NIR spectroscopy to study cross-linking photopolymerization kinetics. K. A. Berchtold, T. W. Randolph, C. N. Bowman
T. Clark Jr. and S. D. Minteer, Presiding A. J. Dias, Organizer 1:30 121. Encapsulation of biomolecules via vesicles formed from headgroup polymerizablediacyl-phosphoethanolamine phospholipids. G. E. Lawson, A. Singh
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
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10:35 133. Real-time monitoring of high speed photopolymerizations by infrared spectroscopy. C. Decker, F. Masson, L. Keller 11:15 134. Cationic photopolymerization of epoxide monomers: Characterization of active centers' propagation lifetime. V. Sipani, A. B. Scranton 11:45 135. Construction and application of a thin-film calorimeter for the in situ characterization of photopolymerization kinetics. T. M. Roper, C. E. Hoyle, C. A. Guymon Section Β Hilton Riverside Grand Salon A6 Gene-Based Medicine: Delivery and Diagnostics J. DeNuzzio and S. M. Dinh, Organizers, Presiding 9:00 136. Novel biodegradable-co-bioresponsive hydrogels for drug delivery. B. R. Nayak, T. L. Lowe 9:30 137. Encapsulation of bioactive molecules in cross-linked microgels. S. L Goh, Ν. Murthy, M. Xu, S. Schuck, L. Lau, M. Dubber, J. M. J. Fréchet 10:00 138. Structure-property investigation of trehalose and β-cyclodextrinbased polycations for gene delivery. T. M. Reineke, M. E. Davis 10:30 139. In vitro transduction of PTDfunctionalized SCK nanoparticles and evaluation of their toxicity and immunogenicity. M. L. Becker, E. E. Remsen, D. Pan, K. L. Wooley 11:00 140. Effects of Η-bonding on free volume of the mixture and copolymers of polyvinyl pyrrolidone) and poly(ethylene glycol) studied by positron annihilation spectroscopy. Y. Li, R. Zhang, H. M. Chen, J. Zhang, R. Suzuki, T. Ohdaira, M. Felstein, Y. C. Jean Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Single-Chain Studies of Polymers and Bioploymers Β. Β. Akhremitchev, Presiding J. D. Batteas and G. C. Walker, Organizers 9:00 141. Single-molecule probing of polymers and supramolecular materials. G. J. Vancso, H. Schônherr, S. Zou, M. R. de Jong, J. Huskens, N. Tomczak, R. Vallée, Ν. F. van Hulst, D. N. Reinhoudt 9:45 142. Characterization of individual polymer molecules by AFM. S. S. Sheiko, D. Shirvaniants, M. da Silva, K. L. Beers, K. Matyjaszewski, S. Prokhorova, M. Moeller 10:15 143. Atomic force microscopy visualization of single star copolymer molecules. S. Minko, A. Kiriy, G. Gorodyska, C. Tsitsilianis, M. Stamm 10:45 Intermission. 11:00 144. Methodology of single mol ecule detection by AFM. J. E. Bemis, G. C. Walker 11:30 145. Determination of the mass per unit length of polystyrene-b-isoprene cylindrical micelles using AFM and light scattering. I. LaRue, M. Adam, S. S. Sheiko, M. Rubinstein 12:00 146. Dissection of an amyloid aggregation inhibitor. J. P. Aucoin, M. A. Etienne, R. P. Hammer, R. L. McCarley Nanotechnology and the Environment Nanocatalysts for Environmental Technology Cosponsored with Division of Industrial and Engineering Chemistry
TUESDAY AFTERNOON Section A Hilton Riverside Grand Salon A3 In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymer Chemistry J. W. Stansbury, Presiding J. L. P. Jessop, Organizer 1:30 147. Controlled, sequentially curable cationic/free-radical hybrid photopoly merizations. J. D. Oxman, D. W. Jacobs, M. C. Trom 2:15 148. In situ characterization of hybrid polymerization by NIR. Y. Lin, J. W. Stansbury 2:45 149. Raman spectroscopy of adhe sive resin in dental composites bonded to dentin. J. L. P. Jessop, S. R. Armstrong, Y. Zou 3:15 Intermission. 3:30 150. In situ forming cell gel con structs: Monitoring gel degradation to control extracellular matrix evolution. K. S. Anseth, S. J. Bryant, P. Martens 4:00 151. Variable temperature in situ NMR approach to study the effect of temperature on the biocatalytic polymer ization of 4-propylphenol. X. Wu, W. Liu, J. Kumar, L. A. Samuleson, A. L Cholli 4:30 152. In situ NMR spectroscopy in free-radical polymer synthesis. M. M. Guo 5:00 153. In situ cure monitoring using ion mobility time of flight: Effect of experi mental parameters on measurements in a non-hydrogen bonded polymer resin. J. D. Warner, D. E. Kranbuehl, J. Guo, M. Khoshbin, S. Raheem, G. Seytre, G. Boiteux Section Β Hilton Riverside Grand Salon A6 Polymer Surfaces and Interfaces Surface Modification Cosponsored with Division of Colloid and Surface Chemistry B. Chapman, Organizer, Presiding P. L. Valint, Organizer 1:00 Introductory Remarks. 1:05 154. Surface-functional polyurethanes via dual functional macromonomers. K. J. Wynne, J. Uilk, U. Makal, S. L. Golledge 1:35 155. Highly stable planar supported lipid bilayer polymers. S. S. Saavedra, E. E. Ross, D. F. O'Brien, T. Spratt 2:05 157. Design of graded polymer surfaces with nonlinear nanomechanical responses. V. Tsukruk 2:25 156. Grafting of polymers to solid surfaces using self-assembled monolay ers with polymerizable groups. J. Ruhe, D. Madge 2:55 158. Resonance absorption of coher ent infrared radiation by thin polypro pylene films and production of highly developed surface reliefs. E. Bormashenko, R. Pogreb, A. Sheshnev, S. Sutovski, A. Shulzinger, L. Nachum, R. Kerbel 3:15 159. Surface modification of polyeth ylene and ultrahigh molecular weight polyethylene for improved interfacial adhesion in silica/methacrylate compos ites. R. A. Ranade, S. Debnath, S. L. Wunder, G. Baran 3:35 160. Monolayers and LangmuirBlodgett films of poly(tetrafluoroethyleneco-bistrifluoromethyl-4,5-difluoro-1,3dioxole)-Teflon AF. J. E. Onah, U. Oertel, J. Nagel, K. Lunkwitz
3:55 161. Mixed polymer brushes on polyamide substrates. M. Motornov, S. Minko, K. Grundke, M. Nitschke, M. Stamm 4:15 162. Low surface energy polymeric films from novel fluorinated blocked isocyanates. L. van Ravenstein, W. Ming, R. D. van de Grampel, R. van der Linde, G. de With, T. Loontjens, P. C. Thiine, J. W. Niemantsverdriet 4:35 163. Optically transparent conductive polymers from thieno[3,4-6]thiophene. G. A. Sotzing, V. Seshadri, K. Lee, B. Lee, L. Wu Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Single Chain Studies of Polymers and Bioploymers G. C. Walker, Organizer, Presiding J. D. Batteas, Organizer 1:30 164. Stretching single molecules into novel conformations using the atomic force microscope. H. Li, M. Carrion-Vazquez, A. F. Oberhauser, P. Marszalek, J. M. Fernandez 2:15 165. Force spectroscopy of elastin mimetic polypeptides. L. A. Bottomley, J. Anderson, V. P. Conticello 2:45 166. Chemical control and cooperativity in forced unfolding of multidomain adhesion and cytoskeletal proteins. D. E. Discher 3:15 Intermission. 3:30 167. Single-molecule force spectros copy of α 5 βι integrins. A. Mardilovich, E. Kokkoli 4:00 168. Local structure and elasticity of soft biopolymer gels, studied with AFM. V. Uricanu, M. Duits, J. Mellema 4:30 169. Using in situ atomic force microscopy and microcontact printing as an analytical tool to monitor real-time biodégradation of polymers. B. H. Augustine, B. M. Latuga, S. M. Ramirez, J. F. Arceo, M. D. Flythe, S. Rowe, S. F. Baron, D. E. Dennis Nanotechnology and the Environment Metrology for Nanosized Materials Cosponsored with Division of Industrial and Engineering Chemistry Polymer Brushes: From Synthesis to Functional Microstructures Synthesis Cosponsored with Division of Polymer Chemistry
TUESDAY EVENING Section A Convention Center Hall G Joint PMSE/POLY Poster Session A. J. Dias, Organizer 6:00-8:00 170. Effect of shear stress on electrical and thermal conductivity of metal-filled polymeric materials. G. Lee, J. Kim, M. Park 171. Effect of particle size of modified epoxy-amine adducts on the deposition behavior in cathodic electrodeposition. Z. Ranjbar, S. Moradian 172. Cosurfactant effects on electropolymerization of poly(3,4-ethylenedioxythiophene). T. El Moustafid, R. V. Gregory, K. R. Brenneman, P. M. Lessner 173. High-temperature electrospun fibers and rare-earth modification. W. Kataphinan, D. H. Reneker, R. Teye-Mensah, R. Ramsier, E. A. Edward, D. J. Smith
174. "Salt-gated" chemical transistors. D. S. Salloum, J. B. Schlenoff 175. Effects of blending on the electroluminescence of poly(1-phenyl-1-hexyne) containing naphthylethynylphenyl pendants. Z. L. Xie, J. W. Y. Lam, C. F. Qiu, M. Wong, H. S. Kwok, B. Z. Tang 176. EQCM investigation of ion transport in conductive-polymers based anion sensors. D. Aldakov, P. Anzenbacher Jr. 177. A study on the conductivity enhancement of polyaniline by dispersion polymerization in the presence of amphiphilic molecules. J. Jang, C. Lee, S. Lee 178. Conjugated polythiophene consisting of coupling through locked transoid conformation. V. Seshadri, K. Lee, U. Salzner, G. A. Sotzing 179. Frequency-agile hyper-Rayleigh scattering studies of nonlinear optical chromophores. K. A. Firestone, D. H. Bale, J. B. Westphal, D. C. Scott, P. J. Reid, L. R. Dalton 180. High-performance photorefractive materials based on layered photoconductive polymers. O. Kwon, S. Lee, G. Montemezzani, P. Gunter 181. Improved light-emitting diode properties of carbazole-modified polyfluorenes. K. Onishi, R. Advincula, C. Xia 182. Intrinsically conductive copolymers of thieno[3,4-6]thiophene and 3,4-ethylenedioxythiophene by simultaneous electrochemical polymerization. V. Seshadri, L. Wu, G. A. Sotzing 183. lonic-liquid/polymer electrolyte composite materials for electrochemical device applications. T. M. Pappenfus, W. A. Henderson, Β. Β. Owens, K. R. Mann, W. H. Smyrl 184. Ionic conjugated polymer: Synthesis and biosensor application. J. M. Dalvi, L. Chen 185. Withdrawn. 186. Simultaneous multiple sample light scattering. M. F. Drenski, W. F. Reed 187. Deposition of calcium carbonates on hydrogel surfaces for controlled release of molecules. D. Ogomi, T. Serizawa, M. Akashi 188. Enzymatic approach to ascorbic acidmodified polymers for free-radical scav enging. A. Singh, D. L. Kaplan 189. Adhesion improvement for surfacetreated ultrahigh molecular weight poly ethylene fibers as reinforcement for dental resins. S. Debnath, S. L. Wunder, G. Baran 190. Application of the modified nanofiltration membrane. B. Sun Sr. 191. Automatic continuous online monitor ing of polymerization reactions adapted to high-viscosity reactions. E. Mignard, O. Guerret, D. Bertin, W. F. Reed 192. Cellulose acetate hollow fiber ultrafil tration membranes. J. Qin, L. Lee, H.Lee 193. Characterization of POSS derived from GPMS and influence of modified POSS on the properties. L. Hu, Z. Lu, X. Zhang, Y. Liu, H. Zhang, D. Sun, Y. Huang 194. Combination of Raman spectroscopy and synchrotron X-ray diffraction for in situ studies of iPP fibers under deforma tion. S. Ran, D. Fang, S. Toki, B. Hsiao, B.Chu 195. Construction of serum-free cell culture matrix composed of poly(7-glutamic acid)-sulfonate. M. Matsusaki, T. Serizawa, A. Kishida, M. Akashi 196. Detection of interfacial structures of polyethylene glycol), polypropylene glycol), and their copolymers using sum frequency generation vibrational spec troscopy. C. Chen, J. Wang, M. A. Even, Z. Chen
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TECHNICAL PROGRAM 197. Deterioration of commercial coating studied by positron annihilation spectros copy. H. M. Chen, Q. Peng, R. Zhang, Y. Li, J. R. Richardson, T. C. Sandreczki, R. Suzuki, T. Ohdaira, Y. C. Jean 198. Development of a sensor for the hydrolysis product of the nerve agent soman utilizing molecular imprinting and silica sol-gel techniques. J. L. Parker, S. N. Home, J. M. Kita, C. J. Peeples, J. C. DiCesare 199. Dry-jet wet spinning of fire-safe poly mers. E. Yoo, A. J. Gavrin, E. B. Coughlin, R. J. Farris 200. Effect of process engineering on the performance of natural fiber reinforced cellulose acetate butyrate-based green composites. A. Wibowo, A. K. Mohanty, M. Misra, L. T. Drzal 201. Effect of the compatibility on the performance of PSF/SPSF alloy mem branes. P. B. Sun, B. Sun Sr. 202. Exchange reactions occurring through active chain ends: MALDI-TOF charac terization of copolymers from nylon 6,6 and nylon 6,10. C. Puglisi, F. Samperi, G. Montaudo 203. Exploring the potential of surfacegrown PEG-polymer brushes for biotech nology applications. W. Senaratne, L. Andruzzi, E. D. Sheets, D. Holowka, B. Hic, A. Hexemer, B. Baird, E. J. Kramer, C. K. Ober 204. Fabrication of independent hollow polymer nanospheres using macroporous templates. S. D. Straight, J. K. Bosworth, M. E. Turner, V. Colvin 205. Hyperbranched aliphatic copolyesters by branching ROP/polycondensation. H. Frey, I. T. Neuner, M. Ursu, S. Skaria 206. Interpreting the relationships between multiple melting behavior and crystal sructure of poly(pentamethylene terephthalate). P. Wu, Ε. Μ. Woo 207. Layer-by-layer deposition and charac terization of hyperbranched poly(amidoamine)-grafted silica nanoparticles and Direct Red 80. M. Park, B. Brookins, W. Blanton, R. Colley, Ν. Tsubokawa, R. Advincula 208. MALDI-EI mass spectroscopy of organotin polymers containing norfloxa cin. C. E. Carraher Jr., L. Lanz 209. Measuring the diffusion coefficient for dodecyl acrylate/poly(dodecyl acrylate) using laser line deflection. C. P. Edwards, L. L. Lewis, A. Perryman, D. Rankin, J. Pojman Sr. 210. Mechanical and structural studies of isotactic polypropylene films during heat/draw deformation process. T. Sakurai, T. Kasahara, N. Yamaguchi, K. Tashiro, Y. Amemiya 211. Mechanisms of photodegradation for layered silicate-polycarbonate nanocomposites. J. Sloan, A. Hsieh, P. Patterson 212. Metal chelating resins based on 2,2': 6',2"-terpyridine-functionalized microbeads. U. S. Schubert, P. R. Andres 213. Modification of NF-TFC membrane's substrate. B. Sun Sr., P. B. Sun 214. Molecular modeling and simulation of block copolymers' morphology and physical properties: PS-PMMA and PS-PI. C. Soto-Figueroa, J. Martinez-Magadan 215. Molecular modeling of novel graft copolymers. B. G. Sumpter, D. W. Noid, J. W. Mays 216. New approach to hyperbranched polylactide copolymers. H. Frey, C. Gottschalk 217. New catalysts for the polycyclotrimerization of 1,7-octadiyne. R. Zheng, J. W. Y. Lam, H. Peng, M. HàuBler, Β. Ζ. Tang 218. Nonisothermal crystallization kinetics of poly(ether ether ketone)-copoly(ether ether ketone ketone ). Y. Zhang, Q. Liu, Y. Niu, Z. Jiang 219. Novel metal free catalyst for bulk polymerization of lactides: Using a cationic ring opening polymerization procedure. B. Atthoff, J. G. Hilbom, T. Bowden
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220. Organogels as templates in polymer synthesis. G. Tan, N. Sahiner, M. Singh, V. John, G. McPherson, A. Bose, M. Sennett 221. Phase transfer catalytic property and ion conductivity of polyoxyethylenecontaining interpenetrating polymer networks and of their LiCI04 complexes. H. Xie, G. Wang 222. Phase transitions in block copolymer/ homopolymer blends under a uniform shear flow. C. Huang 223. Photoinduced doping and photolithog raphy of acid labile group-substituted polyaniline. J. Lee, C. Lee, S. Lee 224. Photopolymerization of structurally designed amphiphilic diacetylene deriva tives and its application to photolithogra phy. Z. Yuan, C. Lee, S. Lee 225. Poly(ether imide) fibers by electrospinning. W. Liu, D. H. Reneker 226. Polyacrylonitrile hollow fiber ultrafiltra tion membranes. J. Qin, Y. Li, M. Oo, H.Lee 227. Polycarbonate-based fluorescent converter for blue-light-emitting diodes and methods of its photostabilization. N. N. Barashkov, T. S. Novikova, R. Liu 228. Polymer science at the NIST Combi natorial Methods Center. C. H. Davis, A. Karim, K. L Beers, E. J. Amis, C. M. Stafford, C. Harrison, A. Forster, A. P. Smith, W. Zhang 229. Polymeric delivery and release sys tems for oral care actives. K. Plochocka 230. Preliminary evaluation of organoarsenic and organoantimony polymers derived from cephalexin as potential anticancer drugs. D. W. SiegmannLouda, C. E. Carraher Jr., Q. Quinones, G. McBride 231. Preparation and characterization of PVA-based polyelectrolyte complexes. B. Sun Sr., J. Zou II 232. Preparation and properties of liquid silicone rubber nanocomposite. D. W. Kang, H. G. Yeo, K. S. Lee, Y. M. Kim 233. Preparation of carboxylated polysulfone/polybenzimidazole/siloxane ternary composites through a sol-gel procedure. H. Sun, N. Venkatasubramanian, J. E. Mark, F. E. Arnold 234. Preparation of silicone-based compos ite latices and their application as an impact modifier for PVC. J. Wu, M. Park, H. Park, J. Ahn, C. Lee 235. Quantitative functionality type distribu tion analysis of polymers using gradient polymer elution chromatography. A. M. Striegel 236. Self-assembling amphiphilic block copolymers. S. Cavalli, M. Overhand, J. G. Ε. Μ. Fraaije, A. Kros 237. Self-consistent model for the deforma tion and phase transformation behavior of poly(ethylene terephthalate) above the glass transition temperature. A. Makradi, S. Ahzi, R. V. Gregory, D. D. Edie 238. Shape-persistent polyphenylene-based dendrimers: A computational approach. S. Pricl, M. Ferrone, M. Fermeglia, A. Asquini 239. Solubility study of pH-reversible poly electrolyte complexes. Z. Sui, J. B. Schlenoff 240. Spacer effect on blue emission of poly(1 -phenyl-1 -alkyne) containing carbazole pendants. Z. Xie, J. W. Y. Lam, C. Qiu, M. Wong, H. S. Kwok, B. Z. Tang 241. Storage coefficient of substrate in 2-GHz microprocessors. K. R. Sharma
242. Study of stability of Cu nanoparticles in PVA nanofiber. C. Wang, Z. Li, Q. Yang, Y. Hong 243. Study on PVC/VC-co-VAc alloy mem brane. B. Sun Sr. 244. Studying the surface modulus of polymers using atomic force microscopy. Y. Sun, B. B. Akhremitchev, G. C. Walker 245. Surface crystalline microstructure and mechanical properties of PVDF/PMMA blend thin film. K. Cho, S. Yoon 246. Synthesis and characterization of biodegradable "polystyrene" by ringopening polymerization. T. Liu, T. L. Simmons, G. L. Baker 247. Synthesis of a new set of polyamidoamine dendrimers and dendritic building blocks with potential application as carrier molecules for anticancer therapeutics. S. Fuchs, T. Kapp, P. Franke, R. Gust, A. D. Schluter 248. Synthesis of group VA drugs contain ing cephalexin. C. E. Carraher Jr., G. McBride, A. Zhao 249. Synthesis of levodopa, L-dopa, con taining polymers from reaction with organic acid dichlorides for the treatment of Parkinson's disease. C. L. Carraher, C. E. Carraher Jr., D. Chamely, J. E. Haky, A. Zhao 250. Synthesis of novel silicon based macromers and polymers by enzymatic catalysis. R. Kumar, L. A. Samuelson, J. Kumar, V. S. Parmar, A. C. Watterson 251. Synthesis of PMMA/polyaniline (core/ shell) particles and their electrorheological properties: Size effect. H. J. Choi, M. S. Cho, M. S. Jhon 252. Synthesis, characterization, and hostguest properties of novel cyclodextrin and calix[4]arene-based periodic mesoporous organosilicon materials. C. Liu, J. B. Lambert 253. The study of cross-linking reaction in poly(dimethylsiloxane) emulsion. Z. Gao, J. S. Nahrup, J. E. Mark, A. Sakr 254. Thermal, mechanical, and electrical properties of reinforced polymer. T. J. Wooster, J. M. Hey, S. Abrol, D. R. MacFarlane 255. Uninhibited and inhibited hydrocarbon oxidation: A distinction between strong and moderate inhibitors. L. Zlatkevich 256. AFM adhesion studies of weakly charged polyelectrolytes in multilayer assemblies. O. Mermut, C. J. Barrett 257. Covalent modification of PVC with supramolecular binding units. U. S. Schubert, M. A. R. Meier 258. Depth-resolved look at the network development of alkyd coatings by atomic force microscopy and confocal Raman microscopy. B. Marton, L. G. J. van der Ven, C. Otto, N. Uzunbajakava, M. A. Hempenius, J. G. Vancso 259. Models of functionalized polymers for chemical sensor applications. D. L. Simonson, E. J. Houser, R. A. McGill 260. Film thickness effects on single mol ecule optical probing of polymers. N. Tomczak, R. Vallée, M. F. Garcia-Parajo, L. Kuipers, N. F. van Hulst, J. G. Vancso 261. Homodyne detection in infrared nearfield microscopy of surfaces. L. Stebounova, B. B. Akhremitchev, G. C. Walker 262. Shear modulation microscopy as an ultrasensitive probe of nonlinear response: Stick-to-slide transitions and viscoplastic deformations of polymers. G. D. Haugstad, C. Dykstra, W. L. Gladfelter 263. Single molecular interactions in supramolecular host-guest systems by AFM. S. Zou, S. Zapotoczny, M. R. de Jong, T. Auletta, H. Schônherr, J. Huskens, F. C. J. M. Van Veggel, D. N. Reinhoudt, G. J. Vancso 264. Structure and properties of sheets based on various soy products modified with polyurethane prepolymer. Y. Chen, L Zhang, J. Huang
265. The largest-eigenvalue method for stereoregular vinyl chains. A. Kloczkowski, M. A. Sharaf 266. Studies on graft copolymerization of acrylamide onto guar gum using vanadium(v)/mandelic acid redox pair. R. Kumar, M. Tripathi, K. Behari 267. Estimation of the square gradient parameter for dodecyl acrylate/poly(dodecyl acrylate) using spinning drop tensiometry. B. D. Zoltowski, J. A. Pojman, V. Volpert 268. Surface/interfacial internal reflection infrared imaging of waterborne polyurethanes. D. B. Otts, M. W. Urban Polymer Brushes: From Synthesis to Functional Microstructures Cosponsored with Division of Polymer Chemistry Nanotechnology and the Environment Poster Session Cosponsored with Division of Industrial and Engineering Chemistry
WEDNESDAY MORNING Section A Hilton Riverside Grand Salon A3 In Situ Characterization of Polymerization Processes Cosponsored with Division of Polymer Chemistry J. L. P. Jessop, Organizer, Presiding 9:00 269. Novel self-referencing sensor for monitoring conversion of nonisothermal polymerization and resin mixing. J. C. Quirin, J. M. Torkelson 9:30 270. Fluorescence probes based on the Y-enyne chromophore. J. Jiang, B. R. Kaafarani, D. C. Neckers 10:00 271. Measuring viscosity via fluorescence during the adiabatic, neat photopolymerization of dodecyl acrylate. V. T. Wyatt, K. C. Leard, D. Creed, B. D. Zoltowski, P. H. Bunton, B. Unger, J. Huff, V. Owensby, J. Pojman Sr. 10:30 272. In situ FTIR monitoring of alkyl acrylate stable free-radical polymerizations. J. R. Lizotte, T. E. Long 11:00 273.1R ellipsometry of cross-linking in silicone coatings: Effect of thickness. T. R. E. Simpson, J. L. Keddie, B. Parbhoo 11:30 274. Automatic continuous online monitoring of polymerization reactions. W. F. Reed, A. A. Alb, F. H. Florenzano, E. Mignard, A. Giz, H. Catalgil-Giz, R. S. Farinato 12:00 275. Rapid liquid chromatography methods applied to process monitoring. E. Meehan, G. Saunders, S. O'Donohue, J. McConville Section Β Hilton Riverside Grand Salon A6 Polymer Surfaces and Interfaces Surface/Interface Characterization Cosponsored with Division of Colloid and Surface Chemistry S. Ranade, Presiding B. Chapman and P. L. Valint, Organizers 9:00 Introductory Remarks.
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PMSEfl"ECHNICAL PROGRAM
9:05 276. Adsorption phenomena of polyelectrolytes, amphiphilic block, and star copolymers on surfaces as investi gated by the quartz crystal microbalance method. R. Advincula, M. Park, S. Pispas, J. W. Mays, N. Hadjichristidis 9:35 277. The structure of RF glow dis charge deposited polymer surfaces. D. G. Castner 10:05 278. Depth profiling of polymer glass transition temperature by positron annihilation. J. Zhang, R. Zhang, H. M. Chen, Y. Li, Y. C. Jean 10:25 279. Wetting behavior of 1 Κ PUR adhesives determined by roughness and contact angle measurements. M. A. Schirle, K. Richter 10:45 280. Wettability and surface com position of poly(dimethylsiloxane) irradi ated at 172 nm. V. Graubner, R. Jordan, O. Nuyken, R. Kôtz, B. Schnyder, T. Lippert, A. Wokaun 11:05 281. Combinatorial adhesion measurements: Factorial design concepts for data collection and library evaluation. A. M. Forster, C. M. Stafford, A. Karim, E. J. Amis 11:25 282. Laser cleaning of gold-coated polymers for ToFSIMS analysis. R. Avci, J. A. Sunner, L. Richards, G. S. Groenewold Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Mechanical Properties of Polymer Surfaces J. D. Batteas, Organizer, Presiding G. C. Walker, Organizer 9:00 283. Combined atomic force microscopy and sum frequency generation vibrational spectroscopy studies of polymer surfaces: Friction, stretching, and stiffness. G. A. Somorjai, A. Opdahl 9:45 284. Mesoscale transition properties and material performances of nanoconfined polymer systems. R. M. Overney, S. E. Sills, T. Gray 10:15 288. Engineering glass transitions for high-density storage in thin polymer films. S. E. Sills, T. Gray, J. Frommer, R. M. Overney 10:45 Intermission. 11:00 286. Dynamic force microscopy analysis of nanocomposites, polymer blends, and block copolymers: Beyond imaging the surface morphology. P. Leclère, F. Dubourg, P. Viville, V. Cornet, J. Aimé, R. Lazzaroni 11:30 287. Nanometer-scale studies of anisotropic polymer surfaces. R. W. Carpick, M. S. Marcus, M. J. D'Amato, D. Y. Sasaki, M. A. Eriksson 12:00 285. Influence of poly(L-lysine)-gfpoly(ethylene glycol) molecular architecture on interfacial shear forces under aqueous environments. S. S. Perry, X. Yan Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Mechanism/Nanoparticles Cosponsored with Division of Polymer Chemistry Nanotechnology and the Environment Environmentally Benign Manufacturing Cosponsored with Division of Industrial and Engineering Chemistry
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WEDNESDAY AFTERNOON
Section C
Section A
Hilton Riverside Grand Salon B7
Hilton Riverside Grand Salon A3 Advances in Polymers and Polymerization Conjugated Systems
Applications of Scanning Probe Microscopy to Polymers Mechanical Properties of Polymer Surfaces R. W. Carpick, Presiding
P. Anzenbacher Jr. and A. W. Harper, Presiding
J. D. Batteas and G. C. Walker, Organizers
A. J. Dias, Organizer 1:30 289. Nitrogen-containing conjugated polymers. D. Irvin, K. D. Lormand, R. L. Quintana 2:00 290. Oligo(p-phenylene vinylene) excimers as molecular probes: Deformation-induced color changes in photoluminescent polymer blends. C. Weder, C. Loewe, B. R. Crenshaw 2:30 291. Design and development of heavy metal selective chem-FET sensors using conductive chelating polymers. R. L. Meyer, D. D. Russell, J. Scaggs, W. Knowlton, M. Hill, W. Bauer 3:00 292. Preparation of Se-doped polyaniline emeraldine base films. E. Bormashenko, R. Pogreb, S. Sutovski, A. Shulzinger, A. Sheshnev, A. Gladkikh 3:30 293. New terminal-functionalized polythiophene with size control. S. Maaref, S. Sun 4:00 294. Novel conductive polymer for anion sensing. D. Aldakov, P. Anzenbacher Jr. 4:30 295. Structure-property relationship of conjugated polymers: Effect of heteroaromatic rings on photophysical properties. A. B. Padmaperuma, A. W. Harper, S. O. Clancy
1:30 303. Ultrastructure and nanomechanics of biological tissues: Cartilage and bone. L. J. Ng, K. Tai, A. Plaas, A. J. Grodzinsky, C. Ortiz 2:15 304. Nanomechanical probing with AFM: From polymer composites to individual molecules. V. Tsukruk 2:45 305. Probing swelling and molecular conformation on polymeric coatings for biocompatibility. G. D. Haugstad 3:15 Intermission. 3:30 306. Evaluation of surface composi tion of polymer blends based on lateral force microscopy. A. Takahara, K. Tanaka, K. Akabori, D. Kawaguchi, S. Tasaki, T. Kajiyama 4:00 307. Measuring the mechanical properties of a thin polymeric film by AFM. P. M. McGuiggan, D. J. Yarusso 4:30 308. Microelasticity domains in minimally adhesive polymer surfaces studied with atomic force microscopy. P. F. M. Terân Arce, R. Avci, I. Beech, K. E. Cooksey, B. W. Cooksey Nanotechnology and the Environment Nanoparticle Geochemistry in Air and Water Cosponsored with Division of Industrial and Engineering Chemistry
Hilton Riverside Grand Salon A6
Polymer Brushes: From Synthesis to Functional Microstructures Physisorption/Characterization Cosponsored with Division of Polymer Chemistry
Polymer Surfaces and Interfaces Surface/Interface Characterization Cosponsored with Division of Colloid and Surface Chemistry
Size-Exclusion Chromatography with Multiple Detection Techniques Cosponsored with Division of Analytical Chemistry
Y. Lai, Presiding
THURSDAY MORNING
B. Chapman and P. L. Valint, Organizers
Section A
Section Β
1:30 Introductory Remarks. 1:35 296. Metal-organic interfaces in organic light-emitting devices studied by surface Raman spectroscopy. J. E. Pemberton, A. M. Hawkridge 2:05 297. Thermodynamically controlled surface segregation of perfluoroalkylend-capped PMMA as investigated by low-energy ion scattering. W. Ming, R. D. van der Grampel, A. Gildenpfennig, A. Snijder, H. H. Brongersma, R. van der Linde, G. de With 2:25 298. Novel fluorescence method for characterizing the glass transition tem perature of nanolayers within polymers at surfaces, interfaces, and in between. C. J. Ellison, J. M. Torkelson 2:45 299. Molecular-level studies on buried interfaces of poly(methacrylate)s. C. Chen, J. Wang, M. A. Even, Z. Chen 3:05 300. Dynamic force spectroscopy of adhesion at polymeric interfaces. G. C. Walker 3:25 301. Investigation of surface rear rangement of oxygen plasma treated polyethylene using X-ray absorption spectroscopy . K. S. Kim, Y. I. Yun, I. Banik, C. E. Park, C. M. Ryu 3:45 302. Behavior of plasticizer at the surface of polyurethane films in different chemical environments studied by sum frequency generation vibrational spec troscopy. M. L. Clarke, J. Wang, Z. Chen
Hilton Riverside Grand Salon A3 Advances in Polymers and Polymerization D. L Simonson and E. J. Houser, Presiding A. J. Dias, Organizer 8:00 309. A metal-free catalyst for the catalytic cationic ring-opening polymerization of lactones. T. Bowden, J. G. Hilborn, N. Eriksson 8:25 310. Highly active aluminum-based catalyst system for olefin polymerization. Y. Seki, W. Hirahata, T. Miyatake 8:50 311. Silica immobilized β-diiminate zinc catalysts for the alternating copolymerization of epoxide and C0 2 . C. W. Jones, K. Yu 9:15 312. Formation of crystalline poly(1,3-cyclohexadiene) with high stereospecificity by anionic polymeriza tion of 1,3-cyclohexadiene. R. Quirk, F.You 9:40 313. Functionalization of polymeric organolithium compounds with formalde hyde. R. P. Quirk, Y. Guo, C. Wesdemiotis, M. A. Amould 10:05 314. Polymerization of A2 and B3 monomers: Novel approach to hyperbranched polyarylates. Q. Lin, S. Unal, T. Long
10:30 315. Copolymers of hyperbranching carbosilanes with hydrogen bond acidic functionalization for chemical sensor applications. D. L. Simonson, E. J. Houser, R. A. McGill, J. L. Stepnowski 10:55 316. Linear and hyperbranched hydrogen bond acidic poly(silylenemethylene)s for chemical sensor appli cations. E. J. Houser, D. L. Simonson, J. L. Stepnowski, R. A. McGill 11:20 317. Controlled multibranching polymerization of hydroxy epoxides by slow monomer addition: A universal strategy for well-defined hyperbranched polyethers. H. Frey, H. Kautz, E. Barriau, Y. Chen, M. Perez Collado, R. Wissert Section Β Hilton Riverside Grand Salon A6 Polymer Surfaces and Interfaces Surface/Interface Properties Cosponsored with Division of Colloid and Surface Chemistry B. Chapman, Organizer, Presiding P. L. Valint, Organizer 8:00 Introductory Remarks. 8:05 318. Thermo-reversible properties of surface-immobilized hydrogels based on poly(A/-alkylacrylamide)-5f-poly(ethylene glycol). D. Schmaljohann, D. Beyerlein, M. Nitschke, S. Zschoche, C. Werner 8:25 319. Effects of constraint on photocross-linkable responsive hydrogel layers. M. E. Harmon, D. Kuckling, C. Frank 8:45 320. Surface properties of nanoparticle-linear polymer blends. M. E. Mackay, J. Laruffa, R. S. Krishnan, C. J. Hawker, B. A. Van Horn 9:05 321. pH-Controlled permeability through polyelectrolyte multilayers. H. H. Rmaile, J. B. Schlenoff 9:25 322. Do polyelectrolyte multilayers lie? P. G. Van Patten, M. R. McMurdo, G.Pan 9:45 323. Order and surface properties in thin films of side-chain liquid-crystalline polymers. K. Cho, J. H. Cho, J. Lee, S. Han, K. B. Lee, J. Koo 10:05 324. Influence of interfaces on the rate of cross-linking in silicone coatings. T. R. E. Simpson, J. L. Keddie, B. Parbhoo 10:25 325. Crystallization of thin and thick PCL/PVC blend films: Influence of PCL surface enrichment. V. H. Mareau, R. E. Prud'homme 10:45 326. Controlling the domain orienta tion in thin diblock copolymer films using substrate topology. E. Sivaniah, Y. Hayashi, S. Matsubara, S. Kiyono, T. Hashimoto, K. Fukunaga 11:05 327. Comparison of thermal transi tions of PEO adsorbed and grafted onto silica/silsesquioxanes. P. Maitra, J. Ding, S. L. Wunder 11:25 328. Transient interfacial phenom ena in miscible polymer systems. N. Bessonov, J. A. Pojman Sr., V. Volpert, B. D. Zoltowski Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Polymer Surface Characterization by Scanned Probes V. Galiatsatos, Presiding J. D. Batteas and G. C. Walker, Organizers 9:00 329. Studies of block copolymers with atomic force microscopy. S. N. Magonov, E. J. Kramer
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TECHNICAL PROGRAM 9:45 330. Effect of argon plasma treat ment on PDMS elastomer investigated by AFM. A. W. Feinberg, A. B. Brennan 10:15 331. Tapping mode atomic force microscopy of surface morphology of polymer blends. J. Li, W. Liang, G. F. Meyers, S. P. Chum 10:45 Intermission. 11:00 332. Scanned probe microscopy of polymeric phase transitions in confined geometries. J. Teetsov, A. Alizadeh, K. Conway, C. Kossow, S. Ganti, P. R. L. Malenfant, L. Tsakalakos 11:30 333. Solving polyolefin commercial application problems with atomic force microscopy. F. M. Mirabella Jr. 12:00 334. Crystallographic polymorphs and lamellar morphology of metallocene random propylene copolymers. I. L. Hosier, R. G. Alamo, P. Esteso Nanotechnology and the Environment Nanotech-Enabled Green Energy Sources Cosponsored with Division of Industrial and Engineering Chemistry Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Applications/ Characterization Cosponsored with Division of Polymer Chemistry
THURSDAY AFTERNOON Section A Hilton Riverside Grand Salon A3 Advances in Polymers and Polymerization UV Polymerization and Cross-linking X. Li and F. You, Presiding A. J. Dias, Organizer 1:00 335. Studies on preparation and performance of UV-curable solid poly mer electrolyte materials. J. Wei, L. Qiao 1:30 336. Efficiency of acid generation of triarylsulfonium in the situation of stereolithography. X. Li, R. Leyden 2:00 337. Study on photoinitiator in UVcurable powder coating. J. Wei, Y. Wang, Z. Sun 2:30 338. Kinetic chain length in UV cationic polymerization of cycloaliphatic epoxides. X. Li 3:00 339. Polymerization of self-organized phthalocyanines. B. A. Minch, C. L. Donley, W. Xia, N. R. Armstrong, A. S. Drager, R. A. Peterson, D. F. O'Brien 3:30 341. Photodegradable toners for electrophotography 1Mb: Photodegradation and photo-cross-linking of matrix resin. Its dependence on the UV light source and irradiation conditions and reaction mechanism. K. Sugita, T. Hosoda, M. Kushida, K. Harada, K. Saito 4:00 340. Study on modification of hyperbranched polymer about UV-curable powder coating. J. Wei, Y. Wang 4:30 342. Study on performance modifica tion of UV-curable solid polymer electro lyte materials. J. Wei, B. Ai
Section Β Hilton Riverside Grand Salon A6 Polymer Surfaces and Interfaces Biomedical Applications Cosponsored with Division of Colloid and Surface Chemistry P. L. Valint, Organizer, Presiding B. Chapman, Organizer 1:00 Introductory Remarks. 1:05 343. Use of supported thin films of peptide amphiphiles as model systems of the extracellular matrix to study the effects of structure-function phenomena on cell adhesion. M. Tirrell, S. Ochsenhirt, G. B. Fields, A. K. Dillow 1:35 344. Mucin adsorption to polymeric surfaces: Kinetics, quantification, and reduction of complement activation. K. D. Caldwell, T. Sandberg, J. Hellstrom, P. Tengvall, J. Andersson 2:05 345. Interactions of extracellular biopolymers at a solid/liquid interface. J. L. Prince, R. B. Dickinson 2:25 346. Protein adsorption on carbonnegative ion-implanted polystyrene as neuronal guidance. H. Sato, H. Tsuji, M. Izukawa, H. Sasaki, Y. Utsumi, Y. Gotoh, J. Ishikawa 2:45 347. Biological mechano-chemical switches. V. Vogel 3:15 348. Surface analysis of lubricious coatings for medical devices. M. Calistri-Yeh, R. Baier, A. Chamberlain, D. Copenhagen, A. Meyer, M. Moore, S. Rosebrough, A. Sampath, R. Whitbourne, X. Zhang 3:35 349. PEG-based biostable surfaces by controlled radical polymerization. L. Andruzzi, W. Senaratne, A. Hexemer, C. K. Ober, E. J. Kramer 3:55 350. Synthesis and characterization of perfluoropolyether graft terpolymers for biofouling applications. J. M. Desimone, J. Rolland 4:15 351. New materials for marine bio fouling resistance and release: Semifluorinated and PEGylated block copoly mer bilayer coatings. J. P. Youngblood, L. Andruzzi, W. Senaratne, C. K. Ober, M. E. Callow, J. A. Callow, J. A. Finlay 4:35 352. Hyperbranched fluoropolymerpoly(ethylene oxide) stars as precursors to nanostructured antifouling coatings. C. S. Gudipati, E. E. Remsen, K. L. Wooley 4:55 353. Block copolymers as surface modifiers: Synthesis, characterization, and relevance to fouling release and testability. C. K. Ober, J. P. Youngblood, L Andruzzi, W. Senaratne, X. Li, A. Hexemer, E. J. Kramer Section C Hilton Riverside Grand Salon B7 Applications of Scanning Probe Microscopy to Polymers Polymer Surface Characterization by Scanned Probes C. A. Michaels, Presiding J. D. Batteas and G. C. Walker, Organizers 1:30 354. Scanning probe microscopy studies of novel electroactive materials derived by self-assembly of well-defined block copolymers. T. Kowalewski, S. Jia 2:00 355. Nanoscale investigations of ion conduction for polymer electrolyte films confined in porous membranes using scanning probe a.c. impedance spec troscopy. A. Layson, D. Teeters
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2:30 356. Conducting probe atomic force microscopy of conducting polymers. A. V. Tivanski, J. E. Bemis, B. B. Akhremitchev, G. C. Walker 3:00 Intermission. 3:15 357. Preparation of polymeric nanostructures using electrochemical dip-pen nanolithography. S. F. Filocamo, B. W. Maynor, J. Liu, M. W. Grinstaff 358. Withdrawn. 3:45 359. Real-time study on lamellar branching by atomic force microscopy. Y. Wang, C. Chan, K. Ng, Y. Jiang, L. Li, Y. Lei, Z. Cheung Nanotechnology and the Environment Nanotech-Enabled Sensors and Sensor Systems Cosponsored with Division of Industrial and Engineering Chemistry Polymer Brushes: From Synthesis to Functional Microstructures Synthesis/Applications Cosponsored with Division of Polymer Chemistry
DIVISION OF PROFESSIONAL RELATIONS T. J. Kucera, Program Chair
SOCIAL EVENT: Reception: Mon
SUNDAY AFTERNOON
MONDAY AFTERNOON Section A Convention Center Room 336 The Master's Degree: Its Many Faces and Objectives Cosponsored with Committee on Professional Training, Society Committee on Education, Women Chemists Committee, and Younger Chemists Committee M. Caserio, Organizer 1:00 8. Part I. Documenting the status quo: Getting information on MS pro grams—An ACS registry, a work in progress. M. Caserio, M. Gmurczyk 1:20 9. Graduate education in master'sonly institutions. S. H. Pine 1:40 10. Opportunities for master's gradu ates in teaching. A. K. El-Ashmawy 2:00 11. Part II. Professional science master's degrees: The Sloan science master's program. S. Tobias 2:20 12. Professional masters in the postgenomic era or why chemists should become system biologists. G. Dewey 2:40 13. The trials and satisfaction of launching new master's degree pro grams. D. W. Genson, A. D. Jones 3:00 14. Part III. Instruction by nontraditional means: Perspectives of the corpo rate world—The role of distance educa tion in the delivery of master's degree programs in chemistry. N. D. Heindel Corporate America's Contribution to Science: Successful Women Chemists Cosponsored with Women Chemists Committee
Section A Convention Center Room 336 Paving the Way to Career Success: How ACS Can Help Cosponsored with Society Committee on Education, Women Chemists Committee, and Younger Chemists Committee
DIVISION OF SMALL CHEMICAL BUSINESSES P. J. Bonk, Program Chair
J. K. Borchardt, Organizer 1:30 Introductory Remarks. John Bor chardt. 1:40 1. How the ACS helps you attain your career goals. J. Parr 2:00 2. ACS career assistance programs. E. Diggs 2:20 3. Using the ACS online employment databases. T. Fogg, J. Parr 2:40 4. Trends in employment for 2003. M. Jordan 3:10 5. ACS books that promote career management and success. J. K. Borchardt 3:30 6. My professional partner. M. E. W. St. Germain 4:00 7. Job survival skills: ACS was there! M. J. Brownfield 4:30 Concluding Remarks. John Borchardt. Biotechnology in the Service of Health Cosponsored with Biotechnology Secretariat
SOCIAL EVENTS: Executive Committee: Sun Social Hour: Tue BUSINESS MEETING: Tue
SUNDAY AFTERNOON Biotechnology in the Service of Health Cosponsored with Biotechnology Secretariat
MONDAY MORNING Section A Convention Center Room 348 Biotechnology in the Service of Health Cosponsored with Division of Chemistry and the Law, Biotechnology Secretariat, and Younger Chemists Committee S. Vercellotti, Organizer, Presiding
Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters.
9:00 1. Biotechnology in health research from a diversified small chemical busi ness. J. R. Vercellotti, S. Vercellotti 9:30 2. Promise and pitfalls of combinato rial therapeutics. W. Derrick 10:00 3. Detection of genetically modified organism (GMO) food ingredients. M. Russell 10:50 Intermission.
PMSE/PROF/SCHB/TECHNICAL PROGRAM
11:05 4. Development of a safer, nonnar cotic analgesic: From the lab bench to the clinic. N. G. Bazan, A. L. Vaccarino, E. B. Rodriguez de Turco, V. L. Marcheselli, D. Paul, J. Alvarez-Builla, C. Sunkel, N. Parkins, H. Scuderi
MONDAY AFTERNOON Section A Convention Center Room 336 Biotechnology in the Service of Health Cosponsored with Division of Chemistry and the Law, Biotechnology Secretariat, and Younger Chemists Committee S. Vercellotti, Organizer,
Presiding
1:30 5. Development and marketing of biotechnology products for Y-chromosome analysis. S. K. Sinha, J. G. Shewale
2:00 6. Microbial diagnostics using enzymes in catalytically inactive, binding competent assays. R. Laine, B.C.R.Zhu,W.C.J.Lo 2:30 Intermission. 2:45 7. Plant polyflavanoids: Chemical properties with potential to improve human health. R. W. Hemingway, G. W. McGraw 3:15 8. Development of enzyme-linked immunosorbent assay (ELISA) kit: An important biotechnological tool for medi cal diagnostics and therapeutics. C. K. Mittal, J. K. Galiotos, T. L. Spain 3:45 9. Red River Pharma: To provide essential GLP laboratory and GMP clinical/pilot/commercial scale manufac turing services in Louisiana. J. U. Mehta
TUESDAY MORNING
TUESDAY AFTERNOON
Section A
Section A
Convention Center Room 336
Convention Center Room 336
True Stories of Small Chemical Businesses
True Stories of Small Chemical Businesses
P. J. Bonk, Organizer, Presiding
P. J. Bonk, Organizer
9:00 Introductory Remarks. 9:05 10. The story of Strem Chemicals Inc. M. E. Strem 9:35 11. INO Therapeutics: Development of a global pharmaceutical manufactur ing facility. G. T. Taylor 10:05 Intermission. 10:15 12. Normal α olefin chemistries and technical support. E. Baralt 10:45 13. Accelics: Accelerating research. G. Arnold 11:15 Discussion.
2:00 Introductory Remarks. 2:05 14. Service: Our key to success. N. Langerman 2:35 15. IRIX Pharmaceuticals. M. P. Cruskie Jr. 3:05 Intermission. 3:15 16. Small college research labs: A little-known resource for small chemical businesses. J. T. Ippoliti 3:45 17. Business plans for small busi nesses: Why YOU need one! S. J. Cooke 4:15 Discussion. 4:30 Open Division Meeting.
Brownfields: A Paradigm Shift for Environmentally Impacted Asset Management Cosponsored with Division of Chemistry and the Law
The Committee on Meetings & Expositions requests that there be no smoking in meeting rooms or committee meetings.
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