Textbook of chemistry - Journal of Chemical Education (ACS

Textbook of chemistry. L. Reed Brantley. J. Chem. Educ. , 1956, 33 (12), p 649. DOI: 10.1021/ed033p649.3. Publication Date: December 1956. Cite this:J...
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VOLUME 33, NO. 12, DECEMBER, 1956 analg~inm ~ k r ame of wmimicro tcclrnique, and of qrtelnatic cation identificutiou hv means familiar to mast American teachers of the subject. Mare than the usual degree of emphasis in American texts is placed upon the use of dry-way tests. Anion analvsis is done hv a sim~lified scheme. ~ 6 laboratory e "&direction; and theoretical discussions again are very concise. The subject matter covered, the concise treatment, the apparent expectation that the student needs no ehbbarate introduction to stoichiometry, and the omission of problem work of any sort all suggest that first-year students in the Australian universities me considerably more mature than American freshmen. It is therefore improbable that the book will he eutensively used in American freshman courses. On the other hand it is not sufficiently detailed to be s. very satisfactory substitute for the standard American texts in use in most second-yew courses in andlytical chemistry. The book is clearly written, and the authors do rto excellent job of saying what they have to say with a.minimum of excess verbiage. The one adverse comment which occurs to this reviewer-and it is made with no knowledge of the general price structure in Australia-is that the price of the book seems inordinately high for its size. JOSEPH L. NEAL S m ~ c nU s s~i v ~ n a m r Sunhcna~,Nrw YORR

GAS TURBINES AND JET PROPULSION

G. Geoffrey Smith. Revised and enlarged by F. C. Sheffield. Sidh edition. The Philosophical Lihrary. New York, 1955. 412 pp. Many figs. 14.5 X 22 cm. $15. THE author of the sixth edition of "Gas Turbines and Jet Propulsion" hae produced a book that is useful to: (1) the newcomer to the gas turbine field for general information on the history and recent state of the art, (2) the men who must quickly become acquainted with the work and problems in a special area, such as fuel syatems or metallurgical problems, and (3) anyme who is curious about the application of gas turhines for development of power far road vehicles, locomatives, ships, and stationary power units. This indicates that the scope of this book is very wide, but the author is generous with details in the text and with ohotoermhic illustrations and drawines: .. 'l'hc rcrmry of rhc information prcscntrrl with rwprrr ro jrt propulsion is cviclcnfly limircd only by the clsssificsrion wqulrcments. The reviewer questions whether it ie any longer necessary to sell or promote jet engine propulsion as the author tend^ to do in Chapter I. There might be reason

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to argue with some of the summariz;ed list of 20 "potential advantages of turbine propulsion units as compared witb orthodox reciprocating engine installations." Occasionally the author uses an undefined expression that probably will leave the uninitiated reader still ignorant of the meaning of a. particular sentence. (This may be only the ignorance of an American reviewer with respect to an expression that would he clear to an Englishman.) Discussion in text of a c u t ~ w s ydrawing of an engine component would be less difficult to follow if the numbers design& ing individual parts had been included in the text. Once or twice the system preferred by the reviewer did appear so the text is not wholly consistent in this respect. More credit could have been awarded the American efforts of the past ten years for placing jet engine development where it was in 1955. Generally, Mr. Sheffield should be admired for having the oourage to attempt to cover so much territory in one book, and he should be complimented for completing his self-assigned task so well. PAUL R. WISE

NORTR OLNBTED.OHIO

COLLEGE CHEMISTRY Andrew 1. Scarleft, Professor of Chemish.y, Dartmouth College. Henry Holt and 499 names. Co.. New York. 1956. viii 108 figs. M&Y tables. i 6 ~ ~ i 4 Em. $5.50.

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THISbook is based in part upon "Brief College Chemistry" by Richardson and Soarlett (1942). It appears to be a book designed for the terminal, nonprofessional course in generill chemistry. In its 34 chapters it treats the traditional topics in a brief hut understandable fashion. The periodic table and atomic structure are introduced early in the text, followed by oxygen, hydrogen, gases and liquids. Nest, the fundamentals of solutions, equilibrium, and oxidation are covered. Both ion-electron and electron-shift methods of ha.Iancing redox equations are given. Then come the nonmetals, electrachemistrv. and the metals. There are

cause of its nature, it is brief in many places and additional source material may be needed for the ambitious student. The author makes good use of practical exrtmples in order to illustrate the importance of chemistry in the modern world, particularly with the topics in descriptive chemistry. In general, the book handles subject matter with a minimum of mitbmetic. There are on the average slightly over ten discussion exercises per chapter and only two numerical problems per chapter. An appendix gives weights and measures, numeration notations, vapor

pressure of water, solubilities, oxidationreduction potentirtls, a list of chemical price quotations, and a four-place logarithm table. For instructors who seek a textbook for a shorter course, or who wish to use a book that provides a reasonable minimum of material in the fundamental areas, this book d l be of potential interest. W. H. SLABAUGH OREGON STATE C O L ~ E ~ ~ C o n v * ~ ~ r aOneooli .

TEXTBOOK OF CHEMISTRY Edward Mack, Jr., Alfred Benjamin Garrett, Joseph Fredric Haskins, and Frank Henry Verhoek, all of The Ohio State University. Second edition. Ginn and Co., Boston. 1956. ir 654 pp. 366 figs. 8 tables. 17 X 24 em. $6.50.

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INTHE second edition of their popular book, "Textbook of Chemistry," the authors have wisely followed the sound pedagogical practices of the original McPherson and Henderson texts. The balance which is maintained between descriptive matter and chemical principles makes this text as well suited for liberal arts courses as it is for those preparing for careers in chemistry, teaching, medicine, engineering, and related professions. A thorough revision, with many new and improved features, bas been made. .Four 5 of the introductory chapters have been revised. The treatment of atomic and molecular weights has been shortened and simplified. The c h a ~ t e ron nuclear energy has been brought-forward in the hook and integrated with two other chapters on atomic structure. The elements carbon and silicon have been treated in the same chapter in order to better contrast their behavior. A novel chapter which takes up jets, rockets, and explosives has been added. The chapters on organic chemistry have been reduced by one third due to an improved organization. The text concludes with a. challenging account of fuels and power, including a discussion of the thermodynamic efficiency of the steam engine, nuclear poser, and the sun as a main source of energy. The subject matter tthroughout the book has been skillfully organized to build up interest and motivation by leadina the student from the s~ecificto the general and from experimeht to theory. Attention is focused consistently on the evidence for the theories and concepts presented. For example, in the chapter dealing witb rate of reaction and equilihrium, experimental evidence from radioactive tracer experiments is introduced ss evidence to support the principle of the continuance of reaction a t ecluilibrium. Most chapters start with-a brief introduction which calls attention to related information discussed earlier in the book

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JOURNAL O F CHEMICAL EDUCATION

and alerts the student to the new ideas which are to he presented. The illustrstians m e well selected with reproductions of famous scientists in the historical sections, and Liberal use of both space models and scaled models to illustrate structures. An excellent index of 25 pages of double columns shows the care used in preparation of this book. The teachers who used the first edition will find that an already outstanding text is more than ever suited to their needs. Those who never have used this book or the original McPherson and Henderson texts will find the second edition to be a thoroughly teachable text with its logical development of principles through well selected illustrations and emphasis on the understanding of the principles and methodology of chemistry.

book on the fundamental chemistry of tanning at the present time [November, 19551." Now as a result of his diligent devotion to the complexities of the tanning processes through brilliant laboratory researches on the fundamental science of tanning reactions, we do have a modern book, skillfully and interestingly written. The suhjects covered in ten chapters include (1) the chemistry of chromium salts and chrome tanning, (2) the effect of neutral salts and complexing agents in chrome tanning, (3) miscellaneous factors in chrome tanning, the two-bath method, (4) the nature of the ehrome-collagen complex, (5) vegetable tannage, (6) tanning with Svntrtns and reaction of lienosulfonic

of biological and medical importance involving discussions of phagocytosis of ha* teria by tannins as saponins, use of formaldehyde in modifying bacterial toxins and antibiotics, virucidal and antiviral effects of some veeetahle tannins. &eat of form-

THE COMMON SENSE OF THE EXACT SCIENCES

W. K. Clifford. Edited by Karl Pearson and James R. Newman. Dover Publi-

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cations, Inc., New York, 1955. Ixvi 249 pp. 123 figs. 13.5 X 20.5 om. Paper bound. $1.60.

THE original date of publication, 1885, might question its reissue. After reading Russell's preface, written far it some 70 years later, one withholds criticism. The title first used by its author was "The First Principles of the Msthemstical Sciences Explsined to the Non-Methematical!' Thus it is mathematics for those less mathematical in their thinking. For the chemical readers of THIB JOURNAL engineers and physical chemists are the most likely interested readers of its pages. Russell sees in it a mathematician of the first order turned philosopher. The more casual reader may find it a quantitative unfolding of many mathematical relationships he has heretofore used uncritioally with little concern as to whence they came. Topics presented are: Number, Space, Quantity, Position, and Motion. Each chapter has from 11 to 19 subdivisions set forth in the table of contents. A hibliography of the major writings of Clifford is appended. There is no index. B. CLIFFORD RENDRICKS Lonovmw, W*snnro~on

THE CHEMISTRY OF TANNING PROCESSES K. H. Gustavson, Gamerinkingens Forskningsinstitut, Stockholm. Academic Press, 403 pp. 57 Inc., New York, 1956. ix figs. 58 tables. 15.5 X 23.5 cm. $9.

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I N TAE preface, the author states, "It is a deplorable fact that there is no modern

sutures. This is a book which will serve not only those concerned with the making of leather hut also those engaged in the complex science of histology. As the author states, the inclusion of a chapter on "the hiological and medical aspects of tanning is an innovation" and thus this treatise u.ell merits a place in the libraries of biologioitl institutes and of medical schools along with the companion volume, "The Chemistry and Reactivity of Collagen." The reviewer welcomes this contrihution by Dr. Gustavson and is pleased to express his opinion that this hook is the hest now available. He adds also his pr&e for it ss a beautiful example of the printers' art. ARTHUR W. THOMAS UNIVER.ITT COLOMBIA NEWYORH, NEWYORK

OEUVRES DE LAVOISIEA: CORRESPONDANCE. FASCICULE I (1763-69) Edited by Rend Fric, Ingi.nier, Charge d'enneeignement a I'institute de Chimie de I'universiti. de Clermont. fiditions Albin Michel, Paris, 1955. mii 249 pp. 21.5 X 27.5 em. Paper bound.

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BETWEEN1861 and 1893 Dumas and Grimaux edited and published much of the scientific work of Lavoisier. This six-volume edition contained none of Lavoisier's correspondence. Now, after some 60 years, the "Oeuvres de Lm&ier" is being continued, and the omission is being remedied. Beginning in 1925 the editor of the present work commenced to collect letters to and from Lavoisier. He has searched

all available sources. He has been aided by numerous individuals, by scientific societies, and by UNESCO. Now the first section of these letters has appeared, published under the patronage of the Acadhie des Sciences and with a preface by Louis de Broglie. The period covered in this volume is from 1763 through 1769, that is, through Lsvoisier's twenty-sixth year, hut the majority of the letters were written either in 1767 or 1769. In 1767 Lavoisier accompanied the famous geologist Guettmd on an expedition through the Vosges and through Alsace. Biographers have pointed out how much this expedition contributed to the scientifie growth of Lavoisier. Here we have the letters exchanged between the young scientist, his father, and his aunt, Mlle. Punctls. In the letters written by Lavoisier we see the scientific accuracy, the keen powers of observation, which his biographers have always stressed, hut we see much more. The strong BfFection existing between the members of this small family, the concern of the older members for the youth on his first extended trip away from them, and the little details of strange eustame and manners which Lavoisier describes to his aunt to reassure her as to his health and safety, all give u8 an intimate sense of personal acquaintance which has never before been possible. Among the most interesting letters in this group is the natation sent by the bookseller Konig of Strashourg, listing the books which Lavoisier purchased from him while passing through that city. Thereare 119 items, most of which concern chemistry. There can be no doubt thzt even as a young man Lavoisier's scientific interests were chiefly chemical. In 1768 Lavoisier did not travel far from Paris, and his letters are few that year. However, two important events in his Life ocourred a t that time. He was elected to the Academy of Sciences, and there are a few notes which pertain to this phase of his activities. He also became a member of the Ferme g6n6rale, the private company to which the state leased the taxing power over many important cammodities. He soon became an important member of the department of the Ferme which controlled the tobacco business. The director of this department was Jacques-Alexis Panlze, who later hecame his father-in-law. From July through November of 1769 Lavoisier made a tour of inspection of the tobacco interests of the Ferme in the region of Chalons. He sent back almost daily reports to Paulze, telling of his activities, the results of his inspections and tests for adulterated tobacco, and his ideas for improving the work of the Ferme. These letters make up most of the last part of this volume. The final letter is a report on the capabilities of the various employees of the Ferme with whom he came in contttct. These letters and reports reveal the thoroughness, business