The Chemistry of Isobutyraldehyde and its Derivatives - C&EN Global

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In our continuing study of isobutyraldehyde as a basic chemical raw material, we are pleased to announce the publication of

The Chemistry of Isobutyraldehyde and its Derivatives by H A G E M E Y E R AND D E C R O E S .

For your convenience in evaluating this new treatise as a reference manua1 in your daily work, we have reproduced here the table of contents.

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TABLE OF INTRODUCTION SYNTHESIS Manufacture by the Oxo Process Manufacture from Isobutyl Alcohol Other Methods of Synthesis PHYSICAL PROPERTIES Isobutyraldehyde Isobutyl Alcohol Isobutyric Acid

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CHEMICAL PROPERTIES Acetal and M e r c a p t a l Formation Acetylation Aldol Condensations Isobutyraldol a n d Derivatives Preparation Oxidation Reduction M i x e d Aldols a n d Derivatives Hydroxypivalaldehyde and Derivatives Preparation Oxidation Reduction Reductive Amination Acetylation Condensations O t h e r Than Aldol Acetoacetic Ester Reactions Acyloin Formation Azlactone Formation Cannizzaro Reaction Condensations W i t h Miscellaneous Reagents Acetylene Chloroform Ethyl Dichloroacetate

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CONTENTS

CHEMICAL PROPERTIES (Cont.) Ethylenimine Formamide 2-MethylquinoIine Nijroparaffins Schiff's Bases Secondary Amines Condensations with Unsaturated Compounds Ketene Olefins Unsaturated Ethers Cyanoethylation Ibanitrile Formation Ibanitrile Reactions Cyanohydrin Formation Knoevenagel Reaction Mannich Reaction Michael Addition Perkin Reaction Reformatsky Reaction Stobbe Reaction Telomerization Tischenko Reactior Dehydroge nation Friedel-Crafts Reaction Halogenation Nitrile Formation Organophosphorus Compound Formation Oxidation Pyrolysis Reduction Reductive Amination Sulfonation Trimerization

This publication has been prepared to stimulate the thinking of industrial research and development personnel concerning isobutyraldehyde and its derivatives. We will be pleased to honor letterhead requests for copies.

APPLICATIONS Amino Acids Pantothenic Acid d/-Va!ine a7-Leucine σ-Aminoisobutyric Acid Aminopivalic Acid Cellulose Esters Corrosion Inhibitors Gasoline Additives Hydraulic Fluids and Lubricants Insect-Controlling and Similar Agents Perfumes and Flavors Plasticizers Isobutyl Alcohol Dimethylmalonic Acid 2,2,4-Trimethyl-l ,3-pentanediol 2,2-Dimethyl-1,3-propanediol α,α-Dimethylglutaric Acid Isobutyric Acid Miscellaneous Polyamide and Polyester Intermediates Resins Solutizers Solvents Sulfonyldicarboxylic Acid Synthesis Polyesters Textile Assistants Vinyl Monomers HANDLING PRECAUTIONS Fire Hazards Storage a n d Transfer BIBLIOGRAPHY

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-Ε sus tm.sirx CHEMICAL PRODUCTS, INC. KINGSPORT, TENNESSEE Subsidiary of EASTMAN KODAK COMPANY

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15

APRIL

12,

1954

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