The Crystal and Molecular Structure of Triclinic ... - ACS Publications

Triclinic Tetraphenylporphyrin. Stuart J. Silvers and A. Tulinskyl. Contribution from the Sterling Chemistry Laboratory, Yale University,. New Haven, ...
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The Crystal and Molecular Structure of Triclinic Tetraphenylporphyrin Stuart J. Silvers and A. Tulinskyl

Contributionf r o m the Sterling Chemistry Laboratory, Yale University, New Haven, Connecticut. Received February 13, 1967 Abstract: The crystal and molecular structure of triclinic tetraphenylporphyrin (TPP) has been solved using X-ray crystallographic techniques. The molecule is centrosymmetrical with two independent pyrrole and phenyl groups. Although the individual pyrrole and phenyl groups are planar within the error of their determination (