Sept. 20, 1962
BOOKREVIEWS
3603
Gmelins Handbuch d e r Anorganischen Chemie. Achte Vollig Neu Bearbeitete Auflage. Kobalt. Teil A. Erganzungsband. System-Nummer 58. Edited by Gnielin-Institut. Begonnen von R. J. MEYER. Fortgefiihrt von E. H . ERICHPIETSCH. Verlag Chemie, G.m.b , H . , Pappelallee 3, Weinheim/Bergstr., Germany. 1961. lxxii 886 pp. 18.5 X 25.5 cm. Price, D M . e556( $139.00). P a r t h of the volumes on cobalt presents a broad surnmary of the history, occurrence, technology, properties and alloys of the element, the chemical reactions of its ions, and the compounds it forms with both non-metallic and metallic elements. Included in the last category are many of the coordination compounds, but no attempt is made to treat these separately as a particular class of compounds. Each area is handled with the characteristic and highly commendable Gmelin thoroughness and comprehensive documentation. T h e volume is a definitive source of an almost unbelievably large amount of chemical and physico-chemical information pertaining to cobalt and its compounds. Access t o this information is of course improved by the inclusion of a supplementary Table of Contents and marginal indexes in English. Particular attention has been given both to recently published information and to physical d a t a . The volume colitains many tabulations, a large number of pertinent graphs and diagrams, and a substantial number of pictorial representatious of crystal structures. All of these are included logically where they can best describe the substances in question. I t is difficult to discuss any volume in the new Gmeliii series in other than superlatives. This is no exception. It is reconirnended as undeniably the bcst and most cornDIVISIONOF P H Y S I C A L CHEhrISTRY prehensive compilation available on cobalt chemistry. S o SATIONAL BUREAUOF STANDARDSROBERTW.ZWANZIG person or concern interested in any of the areas covered WASHINGTON 25, D. C. can afford to be without access t o it. KOYES CHEMICALLABORATORY UNIVERSITY OF ILLINOIS THERALD MOELLER URBANA,ILLINOIS Gmelins Handbuch der Anorganischen Chemie. Achte Vollig Neu Bearbeitete Auflage. Calcium. Teil BLieferung 3. Schluss d e r Verbindungen Chemisches Gmelins Handbuch der Anorganischen Chemie. Achte Verhalten des Calcium-Ions Nachweis und Bestimmung Vollig Neu Bearbeitete Auflage. Kupfer. Teil Bvon Calcium, Strontium und Barium. System-Nummer Lieferung 2. Verbindungen bis Kupfer und Wismut. 28. Edited by Gmelin-Institut. Begonnen von R. J. System-Nummer 60. Edited by Gmelin-Institut. BeMEYER. Fortgefiihrt von E. H. ERICHPIETSCH. Vergonnen von R. J. RIEYER. Fortgefiihrt von E. H. ERICH lag Chemie, G.in.b.H., Pappelallee 3, Weinheim Bergstr., PIETSCH.Verlag Chemie, G.m.b.H., Pappelallee 3, Germany. 1961. lrii 912 pp. 18.5 X 25.5 cm. Weinheim/Bergstr., Germany. 1961. xli 352 p p . Price, DM. 568.- ($142.00). 18.5 X 25.5 cm. Price, DM. 231.- ($58.00). Part B, Section 3, of the volumes dealing with cal:‘iuni, This rolume in the series on copper describes, according completes the summary of calcium compounds, discusses to the well-established Gmelin sequence, the binary and the reactions of the calcium ion, and summarizes the demnre complex compounds of the element based upon boron, tection and determination of calcium, strontium, and barium. carbon, silicon, phosphorus, arsenic, antimony and bismuth. Treatment of the connpounds begins n.itli the calcium-sulUnderstandably, tlie major amount of space is allotted to fur-oxygen system and continnes according t o the welltlie copper(I1) salts of the organic acids. The treatment established Gmclin pattcrr. through the binary and ternary throughout is comprehensive and definitive, with emphasis compounds of calcium with tlie iioii-metallic elements o f bcing divided between descriptive informati-in and physical Groups V1, V , I\’, and 111. Reactioxs of the calcium ion d a t a . Coordi1i:ition ciimpounds and complex ions are include tliosc witli both inorgaiiic aiid organic species. discussed as the ligands from which they arc tlcrivcd arc Both qnalitative and quantitative ztnalj-tical approaches treated, but not in separate sections. Graphic rcprcseiitaare described, and maiiy procedurcs applirxble to specific tions of structure and phase diagrams are iiicluded wlierc substances or products are outlined. Throiighout, all d a t a are available. items have been particularly carefully and critically ilocu-411 of the virtues of meticulous attention to detail, commerited. The iiiclusion of a Table of Contents and marginal prehensiveness, direct and up-to-date literature citatioti, indexing iii English-now standard practice in the Gmelin and clarity of presentation t h a t characterize the Gmelin series-makes the contents of the volume even more acseries are apparent for this volume. These are complecessible than they would normally be. mented by the inclusion of a Table of Contents and marginal T h e general treatment presents a wealtli of detniletl cheiniindexing in English. Although the area encompassed is cal and physico-chemical information. Usual d a t a of the somewhat limited, the volume is a “must” for any techlatter type are siipplerneiited by an extensive treatment of nical library and a highly recommended source for a n y phase diagrams involving a variety of calciuni-coiitaiiiiii~ person who is pursuing copper chemistry. systems. It is inost uulilccly t h a t any aspect of the areas N o u ~ CHEMICAL s LABORATORY covered has been slighted. CNIVERSITY OF ILLINOIS THERALD MOELLER This volume is a worthy addition to the Gmelin series. ILLINOIS As a source of useful and correct information, it has no URBANA, competitor. T h e printing, binding, appearance and general 1)resentation are attractive and practical. It is recomThe Metal Plutonium. EDITED B Y A S. COFFISBERRY and mended without reservation t o anyone seeking information W.N. MINER. The University of Chicago Press, 5750 in these areas. Ellis Avenue, Chicago 3 i , Illiiiois. 1961. xi 416 pp. 16.5 X 24.5cm. Price, $9.50. NOYESCHEMICAL LABORATORY T h e chapters of this book were originally presented as UNIVERSITY OF ILLINOIS THERALD MOELLBR papers at the 1957 World Metallurgical Congress in Chicago URBANA,ILLIXOIS
read the text more carefully-if he doesn’t, he might miss something comical!) An especially attractive feature is the number of humane Tyarnings about pitfalls and tough points. (On page 317, “The result . . . is correct and itnportant. T h e derivation given is a fraud and a hoax.” On page 379, “Although we shall review some of the niathematical operations, it is doubtful that readers who are unfamiliar with the elementary aspects of matrix algebra can profit from this section.”) On the negative side, there are a few places where one might wish for more clarity or detail, or a change in emphasis. On page 24 a rule is given for constructing quantum mechanical operators; on the following page it is qualified, and in fact only the qualified rule, called “safe” by the author, is correct. T h e name “Boltzon” is coined o n page 36. This seems at first t o be a useful addition t o Fermion and Boson, until one realizes t h a t all particles in nature are either of the latter, and t h a t no Boltzons exist. The statement on page 9 1 t h a t a single particle funct.ion p is not an intensive quantity, while q/iV is intensive, is confusing. T h e principles of detailed balancing and microscopic rcversibility are lumped together in a single statement (page 2 3 3 ) and are not carefully distinguished; this is a common source of semantic confusion in statistical arguincnts. T h e discussion of lattice specific heats, and in particular the graph on page 365 of a typical frequency spectrurn, is soniewhat out of date. I t should include reference to the work of Van Hove, u-110 showed t h a t there are important discontinuities in such graphs. In summary, this is an excellent textbook of practical statistical mechanics. Graduate students in physical chemistry are urged t o become acquainted with its contents.
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under tlie auspices ~ J Ftlic 11niericaii Society for Metals and the United States .Atomic Energy Coinmission. Some IJf the material has been updated to take account of lcnowlcdge gained since 195;. For the average reader, this book has the drawbacks usually associated with a collection of iridividual pa,)ers. There is duplication, variation in emphasis, wid lack O ; uniformity in presentation. Hornever, the scientist or engineer \rho is looking for source material or historical baclcground concerning plutonium and plutoiiium metallurgy will find much of interest, Part I devotes about ninety pages t o a historical revietr. The niiie chapter titles are: The Discovery of Plutonium i,i the Cyclotron, T h e First Isolation of Plutonium, The Microscale Preparatiox and Micrometal1urg)- of Plutoriiuni Metal, Plutonium Metallurgy at Los itlamiis during 191345, Later Plutonium Metallurgical Research a t Los rhlll)- the llossiittis, recognizer tlie p r t ~ l ~ l e i ai it~tlie outset aut1 treats tlicin fairly well i*i coiiiiectioii ivitli solubility and ion cxclictngc. Otherwise approximate constaiicy of activity coefficients, under coiiditioiis of coiistant ioliic strength. is gciicrally assiuncd. I t would seem that there ought t i i have been a cliapter (or scction i n tlie first chapter) where the problems of getting therinodyuairiic constatits aiid those o f estitiiuting activity cocllicicuts (for systems o f the sort treatctl i n this hiioli) wcrc considered with care. “I;otiiplcsbiltluiig i n 1,osuiig” i:, a \vel1 ivrittcii a1id useful reference IJIIII~ and will doubtless fiiid a p1:ice (111 111;iny a specialist’s shelves dong with “The Iletertnination of Stnbilitl- C~JilStalitS.” 13ecause ( i f the geiicral similaritics and language advantage, one would gucss most .iinericaii worliers will reacli for tlic lattcr volurnc. C I I E M I C A L IdARORATORT A N S,TATE ITNIVERSITY CARL11.
UKUUAKER,J R .
BASTLASSISG,~ I I C I I I G ~ N Nouveau Trait6 d e Chiniie MinBrale. Tome XV. Uranium and Transuraniens. I)cuui&ilc Icasciculc. EDITED i j y PAUL PASCAL.iUassi)ii et Cic., 120 Rou1ev;ird SaintGerinain, Paris ( W ) , I’rltrice. 1961. 1 639 pp. 17.5 X 25,s cni. Price, bruclii., 110 SIT,; cartimil6 toile, 122 NF‘ This ~ ( i r l iCi~inl~iii~tisoiis , (le I’Uralliutn, is the secoiitl o f tlirce parts of the fifteenth voluiiic I J f a reinarlcahly tli(irough 111this book the voluiiiitreatise o f iii(irganic chemistr iious literature dcdiiig with the iiribitiaticins of uraiiium with other elcirients 21:~sbeeii ci)ncisely :md clcarly sutninarized. Ten collaborators, under the irimicdiate dircction of I
