The Methylamine Complexes of the Rare Earth (III) Chlorides1

Therald Moeller , Dean F. Martin , Larry C. Thompson , Ricardo Ferrús , Gerald R. Feistel , and William J. Randall. Chemical Reviews 1965 65 (1), 1-5...
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Feb. 20, 1955

METHYLAMINE COMPLEXES OF RAREEARTH CHLORIDES

than one higher complex. Our data do not show what the composition of these species is, but there seems little reason not to infer the formation of PdCla' and P d C l s . Hexacovalency of palladium (11) is thus indicated. It may be noted that nickel, the vertical neighbor of palladium in the periodic system, appears to give a complex chloride of the hexacovalent type, namely, Li4NiCle.10H20.3 Tricovalent nickel chloride complexes (MINiCla) are well known in the solid state. The rather rapid decline in absorbance for Cl/Pd > 4