THE SHORTAGE IS HUER IMC l!IHi
NO2
I
base >
L·
OH NO2 I I I C6H5-CH-ÔHCH3
Mannich Base Formation CH3CH2NO2 + HCHO + R'NH2
I
2
,ruv,i
I
CH3CH2NO2—•—--* CH3-ÇH-C6H5 DMF I N °2
NO2 1 C6H4CI
—
Properties of Nitroethane:
Molecularweight Freezing point Boiling pointât 760mmHg Density at 20°C, g/ml Viscosity at 20°C, cp Solubility in water at 20°C, % by wt Solubilitv parameter Π SAMPLE + DATA
FREE! Send me a Nitroethane sample and technical data sheet with more reaction information. Mail to: NP Division, IMC Chemical Group, Inc., 666 Garland Place, Des Plaines, IL 60016. MUPÏJvl International Minerals Ι ς ™ μ ^ & Chemical Corporation
+
(ϋόΗδ^Ι
CÔHS-CH-CHCHS
*
2
Ο w Phenylation on the Alpha-Carbon
[H] CoHs-iH-irHChb *
I + CÔHSCI
>
CH3CH-CH2-NHR' + CH3C(CH2-NHR')2 L· I
OHNH2 I
NH2
9
NO2
CÔHSCHO + CH3CH2NO2
N0 2 I II C6H5CH = Ô-CH3
II I Preparation of nitro alcohols and their derivatives. H
amine>
75.068 -89.52°C 114.07°C 1.051 0.677 4.6 11.1
Π DATA ONLY
NAME COMPANY
TITLE PHONE
ADDRESS STATE
CITY
ZIP
CIRCLE 15 O N READER SERVICE CARD
ADril 10. 1978 C&EN 55
