Theoretical studies on the acetylene-vinylidene rearrangement with a

A study of the singlet and triplet states of vinylidene by photoelectron spectroscopy of H2C=C−, D2C=C−, and HDC=C−. Vinylidene–acetylene isom...
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J. Phys. Chem. 1987, 91, 3661-3667 TABLE 11: Mid-IR Frequencies (cm-I)" of TNPAN Measured at 298 K on a Thin Film of Pure Material U tent. assignt U tent. assignt 1366 vw 3120 m, sh

uas(NH3+),us(NH3+) 3035 m, sh 2979 m 2888 m } u 2838 m, sh 2763 W, sh \ 2716 w, sh 2659 w

a s ( ~ ~ 2 ),,,(cH,) ,

1

combinations and

2598 W , sh

Overtones

1297 m

uS(NO2),v3(NO 5000 A or an excitation energy of