Thermal degradation chemistry of poly(diphenoxyphosphazene

May 1, 1991 - Thermal degradation chemistry of poly(diphenoxyphosphazene). Shawn J. Maynard, Thomas R. Sharp, James F. Haw. Macromolecules , 1991 ...
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Macromolecules 1991,24, 2794-2799

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Thermal Degradation Chemistry of Poly(diphenoxyphosphazene) Shawn J. Maynard: Thomas R. Sharp,t and James F. Haw* Department of Chemistry, Texas A&M University, College Station, Texas 77843 Received October 25,1989; Revised Manuscript Received November 9, 1990 ABSTRACT The thermal degradation of poly(diphenoxyphosphazene)has been reexamined with emphasis on the roles of P-Cl and P-OH weak links. The polymers studied had residual chlorine contents of