Thermal generation of methyl radical from methanol adsorbed on

Thermal generation of methyl radical from methanol adsorbed on oxygen-covered molybdenum (110): carbon-oxygen bond strength considerations from ...
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J . Phys. Chem. 1991, 95, 1396-1399 A

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67 K

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G-76, I

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The parameters used in the calculations for Figure 6 are as follows. At 15 K qo = 50 and F ( H ) is a superposition of 11 diffraction formulas with Ho = 5-55 G (step 5 G) and a distribution of AH,, = f 0 . 4 H o for each. At 50 K to= 5 and F ( H ) is a superposition of eight diffraction formulas with Ho = 2-30 G (step 4 G) and a distribution of AHo = f0.8H0 for each. At 60 K qo = 3 and F ( H ) is a superposition of an envelope with Ho = 50 G and relative amplitude 20 with a diffraction formula for Ho = 2 G with AHo = f H o and relative amplitude 1. At 64 K to = 3 and F ( H ) is a superposition of an envelope with Ho = 30 G and relative amplitude 40 with a diffraction formula for Ho = 2 G with AHo = AHo and relative amplitude 1. At 76 K qo = I and F ( H ) is the superposition of two diffraction formulas with Ho equal to 12.5 and 5 G with AHo = f O . l Ho for both and a ratio of amplitudes equal to 3.

225

-250

1

225 H (Gauss)

(a1 (b) Comparison of LFMA line shapes observed for a Bi2Sr2CaCu20,crystal with magnetic field parallel to the c axis (a) with calculated curves (b). The signal observed at 67 K cannot be reproduced by calculation because of the phase reversal around 0 G. The modulation amplitude was 1 G, and microwave power was I mW.

Figure 6.

distribution of Ho values. In a crystal, Ho should exhibit different fixed values with a narrower distribution for different types of Josephson junctions which might be related to different types of crystal defects. Hence, normalized superpositions of two or more diffraction formulas with different Ho distributions were used as a reduction factor for the superconducting current versus magnetic field.

Conclusions The Dulcic et al. model for the LFMA line shape can be satisfactorily applied to Y Ba2Cu30, and Bi2Sr2CaCu20,superconductors. Most significantly, it accounts for the differences in the response of these two superconductor systems. Interpretation of the lack of hysteresis for the Bi compound suggests that the assumption IM