Thermodynamic equilibrium of diluted sulfur dioxide absorption into

Apr 1, 1991 - T. Hunger, F. Lapicque, A. Storck. J. Chem. Eng. Data , 1991, 36 (2), pp 258–258. DOI: 10.1021/je00002a029. Publication Date: April 19...
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250 Jounal of Chemical and EngJheerlns Data, Vol. 36,No. 2, 199 1

Correction Thermodynamic Equilibrium of Diluted SO2 Absorption into

Naw, or w,Electrolyte sokrtkns. T. Hunger, F. Lapicque,

and A. Storck, J. Chem. Eng. Data 1990, 35,453-463. I n Table IV, the volumes Vb and V , should be expressed in dm3moT1and not in h3 kg-'. I n relabkn A3, the expression ,?I and not shou# be inserted. In relation A5, an exponent was omitted in the expression for the Debye-Hiickel coefficient, and the correct expression should be

r,

instead of

An error in the right-hand term of relation A10 was made, and this relation has to be replaced by 2

+ /T (,4,)

+ 2Em(i+2)B(l,j)

= -Z2(/+4)6,/4Z2

/=1

The dimensionless dielectric constant should be defined as (A 12)

A parenthesis is missing in the numerator of the last term of relation A15b, related to the ion-molecule interaction term for SO2; the correct expression is r

Finally, the last term for the ion-molecule interaction contribution of H20 should be proportional to ELM,; therefore, the actual relation A15c is 2AM, I 1.5 ~br!-lM(V =

-

1

3

2

+ 1.21112

-

4

2M,Cm(i+2)Cm(l+4)6~ij) /=1

131

-