Thermodynamic Functions and Formal Potentials of the Plutonium (V

A value of —0.9164 ± 0.0002 volt was obtained for this couple in molar perchloric acid at 25.00°.The equilibrium quotient, (Pu+8)(PuC>2+2)/(Pu+4)(...
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June 20, 1956

THERMODYNAMIC FUNCTIONS AND FORMAL POTENTIALS OF PLUTONIUM(V)-(VI) 2705

[CONTRIBUTION FROM THE UNIVERSITY OF CALIFORNIA, LOS

ALAMOS SCIENTIFIC LABORATORY]

Thermodynamic Functions and Formal Potentials of the Plutonium(V)-(VI) Couple BY SHERMAN W. RABIDEAU RECEIVED DECEMBER 23, 1955 The formal potential of the Pu01+-Pu02+2couple has been determined by potentiometric titration