Thermodynamic Functions and Formal Potentials of the Plutonium (V

Thermodynamic Functions and Formal Potentials of the Plutonium (V

A value of â0.9164 Â± 0.0002 volt was obtained for this couple in molar perchloric acid at 25.00Â°.The equilibrium quotient, (Pu+8)(PuC>2+2)/(Pu+4)(PuC>2+), ...


The formal potential of the Pu01+-Pu02+2 couple has been determined by potentiometric titration< of plutonyl ion with I - and with Pu+~ as reducing agents.


Thermodynamic Functions and Formal Potentials of the Plutonium(V)-(VI) Couple1. Sherman W. Rabideau. J. Am. Chem. Soc. , 1956, 78 (12), pp 2705â2707.


was calculated to be 12.8 i 0.4 in molar perchloric acid a t 25.00' from the difference between the formal potentials of the PU+~-PU+~ and the PuOZ+-PUOZ+~.

Thermodynamic functions of neptunium (V) and neptunium (VI)

Thermodynamic functions of neptunium(V) and neptunium(VI). John R. BrandJ. W. Cobble. Inorg. Chem. , 1970, 9 (4), pp 912â917. DOI: 10.1021/ic50086a044.

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conducted by the Metallurgical Laboratory of the University of Chicago (now the Argonne. National Laboratory) under Contract W-7401- eng-37. The work was.

Thermodynamic Functions and Formal Potentials of the Plutonium (V

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