Thermodynamics of the two dissociation steps of N-tris (hydroxymethyl

Rabindra N. Roy, Jennifer Bice, Jason Greer, Julie A. Carlsten, Julie Smithson, William S. Good, Catherine P. Moore, Lakshmi N. Roy, and Kathleen M. K...
1 downloads 0 Views 613KB Size
8231

t o establish what is the largest value of TG (slowest internal rotation) that we can measure. We must have T1"INBTIB5 0.8

Then eq 12 yields p

Therefore, measurable

TG

TG

2 0.6 values are restricted t o

5

2TR

(14)

It should also be noted that when the internal motion becomes very fast ( T G