Thick Zinc-Blende CdSe Nanoplatelets Emitting at 585 nm

Sep 26, 2018 - Direct Synthesis of Six-Monolayer (1.9 nm) Thick Zinc-Blende CdSe. Nanoplatelets Emitting at 585 nm. Wooje Cho,. †. Siyoung Kim,. ‡...
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Communication Cite This: Chem. Mater. 2018, 30, 6957−6960

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Direct Synthesis of Six-Monolayer (1.9 nm) Thick Zinc-Blende CdSe Nanoplatelets Emitting at 585 nm Wooje Cho,† Siyoung Kim,‡ Igor Coropceanu,† Vishwas Srivastava,† Benjamin T. Diroll,§ Abhijit Hazarika,† Igor Fedin,† Giulia Galli,†,‡,⊥ Richard D. Schaller,§,∥ and Dmitri V. Talapin*,†,∇ †

Department of Chemistry, University of Chicago, Chicago, Illinois 60637, United States Institute for Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States § Center for Nanoscale Materials, Argonne National Laboratory, Lemont, Illinois 60439, United States ⊥ Materials Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States ∥ Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States ∇ James Franck Institute, University of Chicago, Chicago, Illinois 60637, United States

Chem. Mater. 2018.30:6957-6960. Downloaded from pubs.acs.org by UNIV OF SUNDERLAND on 10/26/18. For personal use only.



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synthesis, 170 mg of cadmium myristate and 14 mL of 1octadecene (ODE) were mixed in a 100 mL three-neck roundbottom flask and degassed under vacuum at 85 °C for 30 min. Then, the mixture was heated to 250 °C under nitrogen flow. At 250 °C, 12 mg of Se powder well dispersed in 1 mL of ODE with 5 min of sonication was quickly injected (