Thirteen Additions to Organic Chemicals Line

Thirteen Additions to. Organic. Chemicals Line. Distillation Products Industries, a division of Eastman Kodak Co., an- nounces. 13 chemicals newly ava...
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CHEMICALS

NEW

CHEMICALS

REAGENTS MATERIALS

Thirteen Additions to Organic Chemicals Line Distillation Products Industries, a division of Eastman Kodak Co., an­ nounces 13 chemicals newly available from the company. Among these organic chemicals is 2-pdimethylaminostyryl - 1,3,3 - trimethyl3i7-pseudoindolium iodide, a reagent for the determination of sulfur dioxide or smog in air. Another addition to the list is 3,3'-dimethylnaphthidine. The company says this reagent is useful in the determina­ tion of chlorine in water, as an oxida­ tion-reduction indicator, as an indicator for the determination of gallium, and also as an indicator for titration of zinc, cadmium, calcium, and indium. 4,5 - Dihydroxy - 3 - (p - sulfophenylazo)-2,7-naphthalenedisulfonic acid trisodium salt is a third new Eastman organic chemical. According to the company, recent literature reports this compound may be used as an indicator

in complexometric titration of zir­ conium, for the titration of thorium, and for the titrimetric determination of microgram amounts of fluoride ion. The fourth added chemical is ΛΓphenylbenzohydroxamic acid, which is reported useful in the gravimetric de­ termination of copper, iron, aluminum, and titanium; the colorimetric deter­ mination of vanadium; and as a reagent for tin. The remaining additions to Eastman's list of organic chemicals include the following : 2-Amino-2-(hydroxymethyl)-l,3-propanediol ieri-Butyl ethyl ether ierf-Butyl methyl ether o-Dibromobenzene 5,7-Diiodo-8-quinolinol Diphenyl phthalate 9-Methylanthracene 1-Methylquinolinium chloride S-Nitro-2-benzimidazolethiol 18 Laboratory Quantities of Four Complexing Agents A v a i l a b l e

Fisher Scientific Co. is now offering the following compounds in laboratory amounts :

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(Tetra) sodium ethylenediamine tetraacetate, known for forming stable, soluble compounds with most metallic ions, is available as a liquid in a tech­ nical grade. This compound is con­ sidered a versatile complexing agent, one gram of the solution chelating a minimum of 67 mg. of calcium carbonate at pH 11, says the company. (Tetra) potassium ethylenediamine tetraacetate is offered for the first time anywhere in laboratory quantities, claims Fisher. Recommended particu­ larly for reactions where the sodium ion is undesirable, as in determination of barium or strontium, it can also be used in complexing reactions where the sodium salt would be used. This com­ pound is available in a purified grade. Ethylenediamine tetraacetic acid, of­ fered in dry powder form in a reagent grade, is said to be especially effective for the inactivation of polyvalent metal ions. Fisher says it is also used as a raw material for the preparation of vari­ ous derivatives, including metal chelates, salts, and esters. Calcium disodium ethylenediamine tetraacetate, widely used as a stabilizer in the drug and pharmaceutical indus­ tries, is available as a solution in ap­ proximately 25% concentration. This compound is offered in a purified grade.

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List of Radioactive Compounds Expanded

Three additions to its list of over 160 radioactive carbon-14 compounds are announced by the Nuclear-Chicago Corp. These are: gramine-C-14, DLtryptophan-3-C-14, and D-mannose. Gramine-C-14 is said to be of value in chemical, biological, and pharmacologi­ cal research. This radioactive alkaloid is useful in the preparation of tagged tryptophan and in the study of trypto­ phan chemistry and physiology. DL-tryptophan-3-C-14 is a radio­ active amino acid which will be useful in the study of amino acid formation and metabolism and in the study of biologi­ cal systems, says the company. Uniformly labelled D-mannose, the newest addition to Nuclear-Chicago's list of labelled sugars, is available at the activity of 20 millicuries per millimole. The company feels it will be useful in metabolism, photosynthesis, and physi­ ological studies of sugar systems. 20 •

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