Titanium Potential Increased - C&EN Global Enterprise (ACS

Nov 5, 2010 - CLARK, N. J.-Greater industrial and military uses of titanium metal are now believed possible through the use of a new electroplating pr...
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PRODUCTION

The d e g r e e of separation and purifi­ cation of each element will vary with demand. Some sqjits will be separated very completely, others will b e left in crude fractions. If demand grows, Lindsay will move into large-scale pro­ duction. I t sells only salts now, b u t it may be necessary to set up facilities to reduce them to metals later. Regarding his staff, Lindsay's re­ search director, Howard Kremers, says

FROM I R V I N G T O N

that a chemist is either completely fas­ cinated by rare earths, or he is not interested at all. Obviously a rare earth man himself, h e has infected others with his enthusiasm. Potential rare earth chemists attacked by this fever have bemoaned t h e fact that they were not qualified because they were organic chemists. This is no drawback, according to Kremers. He welcomes fresh viewpoints.

Titanium Potential Increased New electrolytic process p l a t e s chromium directly on titanium metal surface

3-n-PENTADECYL PHENOL {Technical) A Mela-Substituted Phenoi for Reaction Products of Unusual O i i Solubility a n d Flexibility U S E S : A n intermediate f o r t h e manu•facture of: Non-îonîc d e t e r g e n t s ' . . . Detergent o i l additives . . . Flexible, o i l soluble, thermosetting phenol-form a l d e h y d e resins. » - Piasîîcizîng ethers a n d esters . - . OH and gasoline soluble dyes A V A I L A B I L I T Y : Commercial quanttHes'l R E A C T I O N S ^ Undergoes all usual re-j aciions exhibited b y meia-substitull· phenols * \ -; • :**P R O P E R T I Appearance:

CLARK, N . J.-Greater industrial and military uses of titanium metal are now believed possible through the use of a n e w electroplating process. Known as the Baylig Process, it is claimed t o permit direct application of chromium in perfect bond to titanium. Developed by the Tiarco Corp., of Clark, N . J., the method results from three years active research. According to Tiarco, commercial use of titanium has been limited because of its h i g h coefficient of friction. Lu­ bricants simply do not adhere to the metal surface. Even light-weight loads cause relatively high friction. But, by plating chromium directly on the sur­ face of titanium, these detrimental fric­ tion properties are reduced. • Baylig Process. Secret of this new chemical a n d electrolytic process is in

preventing the titanium metal from coming in contact with the atmosphere. Titanium oxidizes rapidly (much faster than aluminum), and is extremely dif­ ficult to plate. This is somewhat sur­ prising since titanium has a strong af­ finity for most metals. But like alu­ minum, although more so, proper cleaning of the metal surface to deliver to the plating bath a titanium surface free of oxide scale, is t h e key to tighdy adherent plate. Tiarco has not revealed the intrica­ cies of the process, b u t a patent has been applied for. T h e scant details now available claim a dense deposit of chromium is placed directly on tita­ nium and titanium alloys. There are no intermediate coatings of other metals to set u p possible electrolytic action between dissimilar metals. In fact, the chromium and titanium molecules are believed to form a n intercrystalline bond—that is, the crystal lattices are intermingled. • Test Results.

The

coated

metal

ES

Flaked p i n k solid 43-47° C

M e l t i n g Point: Solubility:

S o l u b l e in a l i p h a t i c h y d r o c a r b o n s , d r y i n g oils and e t h a n o l ; i n i o i u b i e in waver

Purity:

> 9 0 % ; m a j o r i m p u r i t y , alkyl resorcinol

OTHER IRV1NGTON CHEMICALS 5-n-penta