Total Synthesis of (±)-Aplykurodinone-1: Traceless Stereochemical

Jun 24, 2010 - Abstract: The tricyclic intermediate 2 has been synthesized in eight steps from known compound 6 in 20% overall yield. As such, this co...
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Total Synthesis of (()-Aplykurodinone-1: Traceless Stereochemical Guidance [J. Am. Chem. Soc. 2010, DOI: 10.1021/ja1035495]. Yandong Zhang and Samuel J. Danishefsky* Supporting Information is provided in CIF format with the addition of a CIF file for compound 30. Supporting Information Available: X-ray data for compounds 16, 19, 22, and 30. This material is available free of charge via the Internet at http://pubs.acs.org. JA105280J 10.1021/ja105280j Published on Web 06/24/2010

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J. AM. CHEM. SOC. 2010, 132, 9928

10.1021/ja105280j  2010 American Chemical Society