:^-ψ^^ Q A F Corporation | 140 Wast 51 Street New York, N. Y. 10020
η α F OVERHEAD TRANSPARENCY COURSE PROJECTO-AID·
CI I H2CCH2OCOOCH2C»CH2
{CO < ζ ^ > COO(CH2)4d}-n
0
&/
0
0
O.rW
II II CH3CO(CH2)4OCCH3
OH I CH2CH2"~ CH2CH2
CICOO(CH2)4OOCCI
H2CCH2OCOOCH2C-CH2
CI CICH 2 CH 2 CH 2 CH 2 CI
HOOCCH2CH2COOH
I H2NRNH2 -[0(CH 2 ) 4 00CNHRNHC0l· -[0(CH 2 ) 4 00CNH(CH 2 ) 6 NHCcl· 0
OH Br Br OH ι ι ι I H2C - CH-CH-CH2
-[oC(CH2)eCOCH2CH = CHCH 2 cl·
CI CI ι ι H2C-CH = CHCH2 CI ι H 2 CCH«CHCH 2 OH - *
HC^CH
/
H^C
Β OH OH I I CH2CH:=CHCH2
(=CHCH 2 OCH 2 CH 2 CN) 2 4CH 2 -CH-CH-CH-rI I I Ο CH 2 CH 2 I I I 0 = C OH OH I CH,
\
CH2
R OHO ι
ii
CH3CH2CH-C-OR
*CICH2C*CCH2CI
0
BrCH2C*CCH2Br
OH OH ι ι H2CCSCCH2
HOCH2CH = CCH2OH ι R-NR"
HOCH2C=CCH2Ort|c I I Br Br •These reaction products are available in development quantities from GAF.
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Twenty-two ways to start fresh with 4-carbon diols. From GAF, three versatile molecules to move your synthesis program into interesting new areas.
A
Butanediol (1,4-butanediol) Extremely versatile. Undergoes all reactions common to alcohols and diols. Already being widely used in the preparation of polyesters and polyure; thanes for synthetu ; ic fibers, leathers, films, and elasto mers. Also, in the preparation of plas^ _ _ ticizers, softening __ m^JZ* a g e n t S j bonding agents, drugs and pharma ceuticals.
Β
Butenediol (2-butene-l,4-diol) An economical source for a stable double bond. Can function as a glycol or a di-substituted ethylene. A proven route for synthesiz ing plasticizers, ag ricultural and biochemicals, phar maceuticals, textile
assistants, flame retardants, functional fluids and polymers.
C
Butynediol (2-butyne-l,4-diol) A real building block which provides a low-cost, safe source for the triple bond. Reacts either as a disubstituted acetylene or as a glycol. Offers endless possiBUTYNEDIOL bilities for new synthesis, many of which are re ported in our 1 — - ™ J technical bro chure on this product. Technical literature available GAF has prepared ex tensive technical literature on each of these 4-carbon diols. Included are a great many additional chemical reactions, a review of their chemical and physical prop erties, and detailed informa tion on the grades of these commercially available chemicals. For your free copy and a sample, just fill out and mail the coupon.
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