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Unified Theory on Rates for Electron Transfer Mediated by a Midway Molecule, Bridging between Superexchange and Sequential Processes. Hitoshi Sumi* an...
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12852

J. Phys. Chem. B 2009, 113, 12852

ADDITIONS AND CORRECTIONS 2001, Volume 105B Hitoshi Sumi* and Toshiaki Kakitani: Unified Theory on Rates for Electron Transfer Mediated by a Midway Molecule, Bridging between Superexchange and Sequential Processes Page 9603. On p 9619 of Appendix D in the above paper (J. Phys. Chem. B 2001, 105, 9603-9622), λm(t)’s and λd(t)’s should all be read as λm(t)2/λm and λd(t)2/λd, respectively, while [λm - λm(t)]’s and [λd - λd(t)]’s as [λm - λm(t)]2/λm and [λd λd(t)]2/λd, respectively. Equations D.1, D.2, and D.3 should, respectively, be read as

Ed(t) ) [λm - λm(t)]2 /λm + [λd - λd(t)]2 /λd

(D.1) Em(t) ) ∆Gm + λm(t)2 /λm + λd(t)2 /λd

(D.2)

and

Ea(t) ) ∆Ga + λa + [λm - λm(t)]2 /λm + λd(t)2 /λd (D.3) 10.1021/jp9076195 Published on Web 09/01/2009