Vacuum-Ultraviolet Promoted Oxidative Micro Photoetching of

Apr 5, 2016 - Immobilization of Reduced Graphene Oxide on Hydrogen-Terminated Silicon Substrate as a Transparent Conductive Protector. Yudi Tu , Toru ...
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Vacuum-Ultraviolet Promoted Oxidative Micro Photoetching of Graphene Oxide Yudi Tu, Toru Utsunomiya, Takashi Ichii, and Hiroyuki Sugimura* Department of Materials Science and Engineering, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan S Supporting Information *

ABSTRACT: Microprocessing of graphene oxide (GO) films is of fundamental importance in fabricating graphene-based devices. We demonstrate the photoetching of GO sheets using vacuum-ultraviolet (VUV, λ = 172 nm) light under controlled atmospheric pressure. X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and differential interference contrast microscopy (DIC) studies revealed that the photoetching of GO films successfully proceeded in the regions exposed to VUV irradiation in the oxygen-containing atmosphere. Precise photoetching of the GO sheets was achieved at a vacuum pressure of 5 × 103 Pa with VUV light irradiation for 20 min. This was followed by VUV irradiation in a high vacuum (