Vapor—Liquid Equilibrium. II. Chloroform—Ethanol Mixtures at 35, 45

George Scatchard, and C. L. Raymond. J. Am. Chem. Soc. , 1938, 60 (6), pp 1278–1287. DOI: 10.1021/ja01273a002. Publication Date: June 1938. ACS Lega...
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GEORGESCATCHARD

less rich in chloroform. The loss through the condenser was, however, not more than 0.5 cc. per hour, and the deviations from the steady state compositions should be less than the experimental error. When the steady state is reached, the manometer system is shut off from the still, the heater is extinguished and nitrogen is admitted to the still as rapidly as possible to a pressure of slightly more than one atmosphere. This gives a very rapid change from steady state boiling to none a t all. The pressure is measured on the main manometer. Then samples of the liquids in the inner boiler and in the condensate trap are removed for analysis by means of icejacketed pipets. As previously noted the temperature may be reproduced to O.O0lo and the pressure may be measured to 0.01 mm. In favorable cases the compositions of the liquids in the inner boiler and in the condensate trap may be determined

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