What's new with Aluminum Alkyls?
GROWTH! We have expanded and will continue to expand to meet the needs of industry. What else? Improved quality control. New analytical procedures. A higher quality, more uniform product for your application. Expanded product lines for new commercial uses, and new areas of possible interest to you. One specific area is with DIBAL-H (diisobutylaluminum hydride). Originally intended as a polyolefin catalyst, DIBAL-H is rapidly developing as a
reducing agent for the chemical industry, particularly pharmaceuticals. It's efficient, low-cost, easy to use and available for volume applications. This liquid material is capable of selectively reducing many organic compounds. Be sure to get a copy of our DIBAL-H Bulletin. Use the coupon. If you are in the area of rubber chemistry, we're happy to tell you DE AI (diethylaluminum iodide) is now available in commercial quantities.
ALUMINUM ALKYLS ROUNDUP APPLICATIONS Polyolefin Catalysts: For the production of polypropylene, polyethylene, polybutadiene, polyisoprene, ethylene-propylene polymers, and other olefin and diene polymers. Straight-chain Alcohols and Alpha Olefins: Intermediates for making primary straight-chain compounds. Pyrophoric Fuels: Efficient self-igniting fuels for use in rockets and missiles.
growth reactions, olefin displacement, oxidation and hydrolysis, formation of complex salts, as alkylation agents, and as reducing agents for organic functional groups. HOMOLOGS: Various homologs of the commercial and development Aluminum Alkyls can be prepared in research quantities on special request. Inquiries for specific Aluminum Alkyls are welcome for discussion on availability, purity, and price.
Aluminum Plating : As a source of aluminum in a versatile new chemical-vapor-deposition process for aluminum coating a variety of materials.
TECHNICAL ASSISTANCE: Special safety and handling techniques have been developed to minimize hazards involved in the use of Aluminum Alkyls. TEXAS ALKYLS, INC. is pleased to offer technical and engineering consultation and to show you our facilities. We'll gladly lend you a 30-minute, 16-mm, sound, color film on safe handling of Aluminum Alkyls.
Chemical Intermediates : These versatile new metal-organic compounds present interesting possibilities for use in chainUSE THIS COUPON FOR FURTHER DETAILS TEXAS ALKYLS, INC. P . O . Box 9 8 8 , Pasadena, Texas
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These Compounds Available for Immediate Shipment in Commercial Quantities FORMULA
FORMULA WT.
STATE & APPEARANCE AT 25° C
(C2H5)3 AI
114.166
Clear Liquid
0.835
-58.5
156.238
Clear to Yellowish Liquid
0.820
-84.4
(n-C4H9)3 AI
198.328
Clear to Yellowish Liquid
0.823
{iso-C 4 H 9 ) 3 AI
198.328
Clear Liquid
0.781
- 5.6
0.798
-80
ALUMINUM ALKYL
|C/\L
Triethylaluminum
TNP \AL
Tri-n-propylaluminum
TNBAL
Tri-n-butylaluminum
TIBAL
Triisobutylaluminum
(n-C a H 7 )j AI
DENSITY G./ML.
FREEZING PL, ° C
20
-26.7
Variable
Clear to Grayish Liquid Clear to Bright Yellow Liquid
[ADC
Ethylaluminum dichloride
(C2H5) AI Cl 2
126.96
Clear Liquid
1.222
32
UhAL
Diethylaluminum chloride
(C2HS)2 AI CI
120.56
Clear Liquid
0.961
-85.4
(C2H5)2 ΑΙ Ι
212.02
Clear Liquid
1.583
-56.9
Clear to Yellowish Liquid
1.08
-50.0
1.1218"
-29.8
0.905
-39.5
0|θΑί"Ή IJUI
Diisobutylaluminum hydride
KLNYL
DEAI fcAbC IDAUL
(iso-C4H9)2 AI H
142.21
Theoretical
Isoprenylaluminum
Diethylaluminum iodide Ethylaluminum sesquichloride Isobutylaluminum dichloride
DIBAC
(C2H5)3 Al 2 Cl 3
247.52
(iso-C4H9) AI Cl 2
155.00
Clear Liquid
(iso-C4H9)2 AI CI
176.66
Clear to Yellowish Liquid
0.923
1
-26.3
Diisobutylaluminum chloride
The Following Compounds Are Available in Development Quantities
TNHEXYL Tri-n-hexylaluminum TRIISOHEXYL Triisohexylaluminum TNOCTYL Tri-n-octylaluminum
TNDECYL η,, n-decylaluminum MASC Methylaluminum sesquichloride
DEAB DEAF
(n-C6H13)3 AI ( solution in n-heptane. Diethylaluminum fluoride
®
LKYLS TEXAS ALKYLS, INC. Exclusive Soles Agent
STAUFFER CHEMICAL COMPANY Specialty Chemical Division OFFICES: 380 Modlson Ave., New York, Ν, Υ. 10017 · P.O. Box 988, Pasadena, Texas • 226 South Main Street, Akron, Ohio 44308 Statements concerning the possible use of these products are not Intended as recommendations to use them in the infringement of any patent. Certain of these ueee involve processes which are covered by patente and pending application* of Karl Ziegler of Muelheim, Germany; purchase of these materials does not include the right to practice under such patente or patent applications.
