Worm-to-Sphere Shape Transition of ... - ACS Publications

Jun 14, 2018 - ABSTRACT: Molecular bottlebrushes have been shown to exhibit intriguing worm-to-sphere shape transitions in response to external stimul...
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Article Cite This: J. Phys. Chem. B XXXX, XXX, XXX−XXX

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Worm-to-Sphere Shape Transition of Thermoresponsive Linear Molecular Bottlebrushes in Moderately Concentrated Aqueous Solution Daniel M. Henn,‡ Jessica A. Holmes,‡ Ethan W. Kent, and Bin Zhao* Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, United States

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ABSTRACT: Molecular bottlebrushes have been shown to exhibit intriguing worm-to-sphere shape transitions in response to external stimuli. However, such shape changing has been restricted to dilute solutions, typically