Advances in CO2 Capture, Sequestration, and Conversion : Subject

Subject Index

Downloaded by 117.253.204.216 on February 28, 2016 | http://pubs.acs.org Publication Date (Web): September 11, 2015 | doi: 10.1021/bk-2015-1194.ix002

B Bio-energy with carbon capture and storage (BECCS) technology, implementation, 313f gasification system, CO2-recycling conventional biomass, scheme, 326f description, 325 performance comparison, 332 operating condition, 333t process modelling methodology auxiliary components, 330 gas turbine, 328 materials, 327 parameter, 329t pressure ratio, effect, 330f proximate analysis, 328t sensitivity analysis CO2 impact, gasifier temperature, 335f CO2 recycling ratio, 337f equivalence ratio, 334f feedstock, thermal efficiency, 336 gasifier temperature, 333 system efficiency, 336f validity, analysis, 331 gas composition, 331t

C Carbon dioxide, photocatalytic conversion, 1 photon energy conversion anatase TiO2, 7f assembled photocatalysts, 24 carbon-related materials, 24 C-containing compounds, 26 CO2 photoreduction catalysts, 10t, 20t core–shell structure, 18f crystal facets, 7 field-emission scanning electron microscopy (FE-SEM), 14f loaded metal, 8 metal-organic framework (MOF), 18 methane, mechanism, 17s Nb-containing compounds, 25 photocatalysts, 14 photocatalytic reaction mechanism, 16f photoreactor, 19f photoreduction catalysts, 4t

Pt-TiO2 nanostructured film, 15f reactant water phases, 7 semiconductor photocatalysts, 18 solvothermal synthesis, 9 TiO2 photocatalysts, 3 used reactors, 8f photooxidation catalysts, 36 CO2 photoreduction catalysts, 38t photofuel cell, reaction path, 37f sacrificial reducing agents 2-aminoterephthalic acid, 33 CO2, conversion, 26 CO2, formation rates, 34t CO2, photocatalytic cycle, 32s electron flow, energy diagram, 31s energy diagram, 30s interlayer carbonates, 32f semiconductors with hydrogen, reaction conditions, 28t thermal catalysis, 27s CO2 chemistry, 71 arylacetylenes, electrochemical reaction, 96 H2O influence, 97s metal salt catalysts, effect, 98s phenylacetylene derivatives, 97s aryl-substituted alkenes, electrochemical reaction, 94 catalytic reactions CO2 coupling, mechanism, 76s cyclic carbonate, synthesis, 73s cyclohexene oxide, coupling, 74s epoxides or aziridines, 72 four cross-linked-polystyrenesupported amino acids, structures, 77s oxazolinones, synthesis, 75t dienes, electrochemical reaction, 98 electrochemical reactions alkenes, 92 cyclic carbonates, electrochemical route, 93s mechanism, 94s ketones, primary amines, and alkynes, reaction, 87 synthesis, 88s N-tosylhydrazones, reaction, 83 4-alkylene-1,3-oxazolidin-2-ones, synthesis, 87s carbonates synthesis, 83s CO2 reaction, 85s

377 In Advances in CO2 Capture, Sequestration, and Conversion; Jin, Fangming, et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015.


primary amines, reaction with propargylic alcohols, 84 scCO2, mechanism, 86s primary amines and alkynes, reaction, 88 CuI catalyzed synthesis, 89s propargylic alcohols, reaction, 78 α-methylene cyclic carbonates, synthesis, 79s CO2, mechanism by DMAM-PS-CuI, 79s PS-NHC-Ag(I) catalysis, 80s propargylic alcohols and nitriles, reaction, 89 3(2H)-furanones, synthesis, 90s 3(2H)-furanones from diyne alcohols, synthesis, 91s plausible reaction mechanism, 90s propargylic alcohols and water, reaction, 92 α-hydroxy ketones, synthesis, 92s secondary amines, reaction, 81 AgOAc/DBU catalysis, 82s β-oxoalkylcarbamates, synthesis from CO2, 82s styrene and CO2, mechanism, 95 styrene with CO2, reaction mechanism, 96s

F Functionalized ionic liquids, 341 absorption kinetics, strategies, 356 ILs, mixed solutions, 359 intermolecular hydrogen bonds, 359 ionic liquid-based mixtures, 357t water, effect, 360 CO2 capture, strategies, 344 amine group, 344 amino-functionalized IL and CO2, 344s anions, structures, 345s cation and anion, 346 chemisorption, 350t CO2 absorption, plausible mechanism, 348s dual amino-functionalized phosphonium ILs, structure, 346s functionalized protic ILs, reaction mechanism, 347s multidentate cation, 346 multiple-site interactions, 348 non-amino groups, 347 reaction schematics, 345s

stetric hindrance, 349 energy-saving release, strategies anion, basicity, 354 CO2 absorption capacity and enthalpy, relationship, 354f phase-change ionic liquids (PCILs), 356 substituent, anion, 355 CO2, proposed reaction, 343s

H Hydrazine, facile hydrogen source, 251 batch reactor system, 254f experimental formate yield, definition, 253s materials, 253 product analyses, 253 formate synthesis, 254 NaHCO3, mechanism, 259 decomposition ways, 259s solid products, XRD patterns, 261f XPS spectra, 260f Ni stability, examination, 258 reaction conditions, effects, 256 Ni effects, formate yields, 257f reaction time, effects, 258f results GC-MS chromatogram, 255f liquid products, HPLC chromatogram, 255f NaHCO3, examination, 254 Hydrogen sources, application, 109 borane derivatives, 111 HBcat, 112s CO2 conversion, organosilane as hydrogen source, 110 methanol production, 111s CO2 conversion, water as hydrogen source, 112 LiAlH4, hydrogen source, 112 n-butylcarbitol, methanol production, 112s methanol, CO2 conversion, 118 pyridine as catalyst, 118s nicotinamide adenine dinucleotide (NADH), reduction, 116 enzymatic conversion, 117s photoelecrocatalytic reduction, 113 semiconductor mechanism, 113s Ti-based material, 114 zero-valent metals, 115 Fe-based composites, 115s hydrothermal condition, 116s



Hydrogenation, supercritical carbon dioxide, 191 aniline hydrogenation, 234f aromatic ring hydrogenation, 231 carbonic acid formation, visual evidence, 234f dehydrogenation process, 234 experimental methods catalyst characterization, 194 catalytic activity, 197 metal nanoparticles, synthesis, 194 TEM images, 196f X-ray diffraction, 195f phenol, hydrogenation, 236f PhOH, 237t product selectivity, 238 reaction path, 240s results adiponitrile, cell observations, 217f adiponitrile hydrogenation, kinetics, 218 adsorption geometry, 226f arrhenius plot, 223f benzonitrile, hydrogenation, 215t calculated conversion, 217f carbamic acid formation, 213t catalyst morphologies, 229 -C=C, hydrogenation, 205 cinnamaldehyde (CAL), hydrogenation, 200t, 204t citral, conformation, 207f citral, unsaturated aldehyde, 202 citral hydrogenation, effect of temperature, 203t citral hydrogenation, performance, 203f citral hydrogenation, reaction path, 206s -C=O group, selective hydrogenation, 198 CO2 pressure, 200t CO2 pressure, effect, 201f conjugated -C=C and -C=O, hydrogenation, 210 2-cyclohexenone, role of CO2 pressure, 211f dinitriles, hydrogenation, 219t metal ion, 216 NB to AN, catalyst screening, 221t Ni catalyst, 208t Ni-CO2 complex, interaction with citral, 209f nitroaromatics, 228 nitroaromatics, hydrogenation, 224t nitrobenzene (NB), 222f nitrobenzene (NB), time profile, 231f

-NO2 group, hydrogenation, 219 organic solvents, 209t Pd, physical characterization, 227t phenylhydroxylamine with nitrobenzene, comparison, 225f reaction parameters, 220 screening, catalyst, 213t substrates, hydrogenation, 229t supercritical carbon dioxide, 212

M Methane, pressurized tri-reforming, 155 experimental catalyst preparation, 157 reaction procedure, 158 Ni-SiO2 feed CH4, effect, 165f feed molar ratios, effect, 164 long-term stability, 166 reaction pressure, effect, 162 reaction temperature, effect, 164 space velocity, effect, 161 time-on-stream CH4 conversion, 163f results CH4, equilibrium conversions, 161f equilibrium conversions, effect of pressure, 159f system compositions, effect, 160 temperature effects, 159 thermodynamics equilibrium, characteristics, 158 Methane dry reforming, Ni modified WCx catalysts experimental catalyst characterization, 173 catalyst evaluation, 174 catalysts preparation, 173 transition metal carbides, 172 results catalyst microstructure and catalytic activity, correlation, 185 catalysts, physicochemical properties, 175 catalytic activity, 182f catalytic oxidation-recarburization cycle, 186s CH4-TPSR profiles, 179f CO2-TPO profiles, 180f molar ratios, 176f Ni-WCx catalysts, SEM images, 177f used Ni-WCx catalysts, characterization, 184 used samples, XRD patterns, 185f



Q

selected MOs, 286f

Quantum chemical review, CO2 activation activation, CO2, 126 coordination, 129f nine modes, 127f N,N′-ethylene-bis(salicylideneaminato), 129f solvents, geometries and charges, 130t types, 126f Walsh diagram, 128f CO2 molecule, 124 frontier molecular orbitals, 125f molecular properties, 124t experimental studies, 131

R Reversible CO2, RuBisCO thermochemistry, 265 binding energies conformational preference energy, 284 magnesium, alternatives, 284 reaction energies, 283t reaction free enthalpies, 285 replacement cost, carbon dioxide, 281f replacement cost, carbon dioxide in complexes D-ML2, 282f theoretical level dependency, 280 Wertz correction, 280 computational methods basis sets, 271 molecular entropies, 272 potential energy surface analysis, 270 thermochemistry, 272 total energies data, 272t RuBisCO activation, 267s molecular structures, 273 CO2, structural parameters, 276t geometries, ML2, 274s HB2b complexes, 279f hydrate complexes, 278f hydrates, structural parameters, 275t metal formates, optimized structures, 277f OCO-M bonding, 279f open-shell systems, 278f small molecule RuBisCO model, 268 spin density distributions, formate complexes, 285 CuL2 and CoL2, spin density distributions, 288f nickel formate, 287f

S Silicate minerals, carbonation, 295 Ca-bearing minerals, 301 carbonated stainless steel slags, effects, 312 cementitious composites, compressive strengths, 313f carbonation chemistry, 300 CO2, hydration, 302 conventional cement production, 300 industrial wastes, construction materials, 310 annual emission rate, 298f carbon mineralization, 297, 299f CO2 emission, industrial activities, 296f Mg-bearing minerals, 301 silica, 309 solid by-products, physical and chemical properties calcium carbonates, 307 magnesium carbonates, 303 morphologies, 305 non-carbonate reaction products, 306f synthesis, 304 synthesis, calcium carbonates, 308

T Transition metal-promoted CO2 conversion, mild reaction conditions, 47 α-alkylidene cyclic carbonates, synthesis, 49 C NMR investigation, 52f carboxylative cyclization, 50s CO2 incorporation, mechanism, 52s derivatives, 49s polystyrene catalysis, 51s propargylic alcohols, 50s β-oxopropylcarbamates, synthesis, 63 catalytic systems, three-component reaction, 64s secondary amines, 64s carbon dioxide chemistry, 48 carboxylative cyclization, mechanism, 53 AgOAc-promoted carboxylative cyclization, 56s alkenylgold(I) complex, 58s allenic amines, 58s



catalyzed carboxylic reaction, 55s 13Ccarbonyl-labelled experiment, 54s DBU dual-activated fixation, 57s NHC-Au complexes, 57s oxazolidines, preparation, 56s propargylamines, reaction of CO2, 55 transition metal, 53s two-component catalyst system, 54s intramolecular-produced CO2 molecule, recycling, 59 Cu(I)-catalyzed tandem cyclization, 60s domino reactions, 59s possible reaction mechanism, 59s proposed mechanism, 60s oxazolidinones derivatives, synthesis, 60 AgOAc-catalyzed three-component reaction, 62s copper-catalyzed four-component coupling, 63s CuI-catalyzed three-component reaction, 61s propargylic alcohols, Ag2WO4/Ph3P-promoted three-component reaction, 62s three-component reaction, mechanism, 62s

Z Zirconia phase, performance of Ni/ZrO2, 135 catalytic performance, 143 deactivation analysis, 145 catalysts, CO2-TPO profiles, 148f catalysts, TPH profiles, 147f deposited carbon, morphology, 149 O2-TPO profiles, 146f TEM micrographs, 150 XRD patterns, 145f experimental catalyst preparation, 137 characterization, 138 evaluation, catalyst, 137 morphology analysis, 143 Ni/ZrO2 catalysts, 144f results H2-TPR experiment, 141f N2 isotherms and BJH pore-size distributions, 140f patterns, 139f physicochemical properties, 142t samples, 140t TEM images, 142f textural properties, 139 XRD analysis, 138


Advances in CO2 Capture, Sequestration, and Conversion : Subject

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