Aromatic protonation. III. Kinetic hydrogen isotope effects on acid

two isotopes of the exchanging element must be used to measure a single exchange ... the fact this reaction consists of two proton transfer steps neit...
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441 1 were obtained by similar techniques and will be reported in detail when current work on imidazole and its derivatives reaches completion. pK. Measurements. Because of the low solubility of dibenzylmethylamine (ca. 7 X 10-4 M a t 30") it was necessary to measure KA at pH