Chemistry in old Boston - Journal of Chemical Education (ACS

J. Chem. Educ. , 1934, 11 (7), p 387. DOI: 10.1021/ed011p387. Publication Date: July 1934. Cite this:J. Chem. Educ. 11, 7, 387-. Note: In lieu of an a...
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CHEMISTRY in OLD BOSTON* LYMAN C. NEWELL

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N ARTICLE having the same title was published in The B o s h University Alumni Magazine, Vol. 11, No. 7 (December, 1928). It was limited to individuals and organizations. This a r t i c l e t h e second in the studies I am making on early chemistry in New England-is limited to important chemical industries. The term "old Boston" as used in this article needs interpretation. By "old" we mean the period from the settlement in 1630 to about 1815. By "Boston" we mean not merely the small tract of land settled by Winthrop, but also the towns which were really a part of Boston from colonial, industrial, commercial, and economic standpoints. In the previous article, alluded to above, certain 'chemical industries were briefly considered because they were largely the work of individuals or were intimately associated with the activities of one man. In the present article some of that material is utilized and scattered references are also made to men who contributed to the progress of industrial chemistry. WlNTHROP, JR., THE

JOELh'

ETRST INDUSTRIAL CHEMIST

IN BOSTON

The first man in America who devoted much time to chemistry was John Winthrop, Jr. (1606-1676), the eldest son of Gov. John Winthrop. He came to America in 1631 and as early as 1633 imported laboratory apparatus and chemicals. He was the first promoter of chemical industries. In his large library there were many books devoted to chemistry and medicine, and also a number of alchemical books which had formerly belonged to Dr. John Dee. Many of his books, manuscripts, and letters are still preserved in the library of the Massachusetts Historical Society, Boston, Mass. He died a t Boston, and is buried in the same tomb with his father in the churchyard of King's Chapel. Winthrop, in 1638, began to make salt a t Beverly "having been given liberty to set up saltworks a t Rialside (Royal-side)." And ten years later he was granted a commission by the General Court of Massachusetts "to make salt from sea-water." The salt was made by evaporating sea-water in kettles, and according to Emmanuel Downing, -. a relative of

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Winthrop, Thomas Leader, general agent of the Saugus iron plant, cast the shallow iron vessels for use in the process. Somewhat later, perhaps five years, Winthrop was granted a patent for twenty-one years for making salt by a new process devised by himself. Winthrop was the first man to take an active part in the iron industry in Massachusetts. This industry was started in Sangus and in Braintree as early as 1643 and continued for nearly a century. Winthrop early realized the fundamental importance of the saltpeter industry. Through Winthrop's influence the General Court of Massachusetts, in 1642, passed an order that every plantation in the colony should erect a house "within one-half year next coming" to make saltpeter. And in 1650 he organized a chemical stock company, the first of its kind in America, to manufacture saltpeter. Among the unpublished papers of Winthrop in the library of the Massachusetts Historical Society is the original document giving the outline of the plan of this company. Winthrop visited England in 1662 and while there read a paper before the Royal Society, of which he was a member, on the manufacture of tar in New England. In the following year a t the request of the Royal Society he conducted experiments on the brewing of beer from maize. SALT

Salt was first made in a crude way by scattered individuals or by families. Salt water was boiled in a kettle over an open fire and the solid left after hours of labor was strained out of the cooled. bitter water. But the need of a better quality and a larger quantity of this indispensable substance soon led to a displacement of separated social groups by organized companies or skilled individuals. John Winthrop, Jr., was not the only man among the first settlers who made salt. In 1637 a tailor named Goodman Fitt was empowered "to set up a salt pen, if be can live upon i t and upon his trade," and about 1640 S. Winslow was given a monopoly of salt-making by the General Court "for ten years if he ~ k atmade his way." ~ i n t h r o first tempt (1638) a t salt-making a t "Rialside" near Beverly was premature and mimitive. His second attempt (1648) w& an elaborate and economic manufacturing enterprise. In May, the General Court granted Winthrop three thousand acres of land a t Paquatuck, the grant to be void, "provided that he set not up a con-

siderable salte worke, we meane to make one hundred tun per annum of salte between Capes of Massachusetts Bay, within three years next coming." There seems to be no definite record of the success of this enterprise. Probably its outcome was encouraging, because the General Court in May, 1656, granted the proprietor for twenty-one years the exclusive privilege of making salt "after his new way." (See Mass. Arch., lix, 72.) Within the next fifteen years the need of salt in the fishing industry increased to such a degree that in 1671, a committee, appointed in October of the previous year by the General Court to confer with Richard Wharton, of Boston, "respecting his mode of making Salt by the sun," reported favorably, and advised the Court, "to encourage a Company for that purpose, which retum the Court approved." The output of this company probably did not meet the demand. It is perfectly clear that the demand for salt often exceeded the supply, and it was doubtless this fact that influenced the General Court to foster the manufacture of a prime commodity. In 1696, another company was started, the General Court having given the monopoly for manufacturing salt in the whole colony for fourteen years to Elisha Hutchinson and others. The grant included among other stipulations the agreement "to make 100 hogsheads in 1701." The salt industry continued to spread. We find an entry under date of 1752 stating that Josiah Quincy proposed to start salt making, among other industries, a t Braintree (now Quincy). We note that soon after importations of salt from Bermuda began to increase and reached a peak at the beginning of the Revolution. During the War the interruption of commerce and the diversion of labor to other industries caused a distressing scarcity of salt. The price rose from a few shillings a bushel to £1 2s. 6d. in 1774 and remained a t about this price till 1779. This critical situation caused the establishment, or rehabilitation, of many small plants along the New England shores, especially on Cape Cod. In these plants water was pumped from the sea by hand or by windmills and was boiled in large kettles, often in the open air. This process yielded an inferior product, which was seldom purified from the more soluble constituents of the brine. The apparatus was ill-constructed for its purpose, and about two hundred and fifty gallons of water were needed to make a bushel of salt. The yield was large however, and the price dropped - - to about 4s. a bushel in 1783. The salt industry did not become a well-established indnstry in and about Boston until the War of 1812 released men for industries and opened the seas for commerce. LEATHER

In 1628 a colony of about one hundred Puritans, headed by Captain Endicott, settled Salem. In this band were Francis and Edmund Ingalls, who, becoming dissatisfied, were granted "leave to go where they

would." In the early part of June, 1629, they arrived in what is now Lynn. Francis Ingalls was a tanner and settled in that part of Lynn which became Swampscott in 1852. He at once built a log cabin and appropriated as much land as he needed for cultivation. He also built a tannery in 1632, on the easterly side of his house, near Humphrey's brook. This was the first tannery in New England. The vats remained in place until about 1825 and when they were dug up a hide was found in one of them in a good state of preservation. From this tannery in Swampscott nndoubtedly there sprang the leather industry in New England. George Keysam, also a tanner in Swampscott, was probably connected with the Ingalls tannery. Soon after the settlement of Boston, tanneries were started, either by the tanners who were purposely sent over from England among the colonists or by the more prosperous farmers. There were three tanners among the first inhabitants of Boston--George Hun, Jeremy Houchin (or Hutchins), and William Copp, also a shoemaker, who owned Copp's Hill. Hun died in 1640, but the others continued their work for several years. At a rather early date some tanneries were such large establishments that they used imported as well as domestic hides. For example, in 1653 one New England tannery had 415 hides in the bark, 45 hides in the lime, and 312 West Indian hides (valued a t $600) in the lime. Skins in increasing numbers were needed, of course, by tanners, and we find among the earliest records abundant evidence of two fundamental features of the leather industry, uiz., raising cattle and protecting the hide indnstry. The first cattle were introduced into the Plymouth Colony by Edward Winslow, in the spring of 1624, and the "herd" consisted of three heifers and a bull, to which were added twelve cows sent to Cape Ann in 1626, and thirty more in 1629. The k s t settlers of Lynn were principally farmers, and speedily accumnlated large numbers of homed cattle, sheep, and goats. Until their lands were divided or fenced, their cattle were kept in a common herd under an overseer or hayward, and the island of Nahant was the common sheepwalk, where the flocks were attended by a public shepherd. In October, 1640, the General Court called attention to the neglect of many persons in not saving such hides and skins "as either by casualty or slaughter come to hand," and declared that all such hides should be preserved to be tanned, or the owner should forfeit the skin and £12. The first tannery in New England, as stated above, was built in the little village of Swampscott soon after the settlement of Lynn. Nicholas Eaton started a tannery a t Ipswich in 1634, and the dressing of goat skins and ordinary hides is mentioned in a document which granted land to Philemon Dickerson at Salem in 1639. I t is highly probable that tanneries were established in Boston, Charlestown, Watertown, and other of the first settled towns, very soon after their

occupation. I n Watertown two searchers and sealers of leather were appointed by order of the Court in 1638. Leather searchers, in conformity with an Act of the General Court, were appointed in Salem in 1642. The early tanneries were crude. They were essentially a number of oblong boxes or hogsheads, sunk in the earth near a small stream and without cover or outlet below, which served as vats and leaches. A few similar boxes above ground sufficed for lime vats and pools, and an open shed answered for a beam house. These primitive devices were completed by a circular trough fifteen feet in diameter, in which the bark was crushed by alternate wooden and stone wheels, turned by two old or blind horses, a t the rate of half a cord a day. The first improvements were made by a Mr. Edwards. He laid down a trunk of plank made tight underneath his vats to carry off the spent liquor together with a junk to receive it; next he constructed leaches above ground in tiers, one above another, raising the liquor by a suction pump worked by two or four men: and finally he erected substantial buildings over his beam house and used the lofts for a currier's shop. He located a bark mill on a stream five miles from his tannej, and much nearer the place where his bark was ground by water power (instead of by power from the "old horses"), using at first millstones, afterward the iron mills as they were invented by others. In New England hemlock bark was generally used, and oak bark in the south. Bark mills were used as early as 1661, perhaps earlier in isolated places. I t is not possible within the space available for this article to follow the development of the leather industry very far. The several operations of liming, drenching, bating, salting, etc., in taming hides improved rather slowly and about 1800 reached a stage which conformed in its essential features to the general process subsequently followed for many years. Various grades of leather were made, as demands increased. Morocco leather of fair quality was made as early as 1770 by the notorious Lord Timothy Dexter and others a t Charlestown. Dyed leather was produced about 1788. GLASS

Glass making began a t Salem in 1639. In this year there "were granted to the glass-men severall acres of ground adjoyning to their howses." The men engaged in the undertaking were Ananias Concklin, Obadiah Holmes, and Lawrence Southwick, each of whom received two acres of land. The year following, John Concklin was also allotted five acres, bordering on the previous grants. In December, 1641, the General Court, for the encouragement of the enterprise, authorized the town of Salem to lend the proprietors £30, which was to be deducted from the next town rate, and the glass men were to repay it, if the work succeeded, when they were able. The work was neglected, and the Concklins, in 1645, received permission from the General Court to form a new company. Glass was

Cowrarr of prof. Moody

FIRSTTANNERY IN NEW ENGLAND, 1632 Sketch of the first tannery in New England, beside Humphrey's brook, in Swampscott, Mass., started by Francis Ingalls in 1632, and his log cabin, in the rear, which be built in 1629. (From "Historical Sketches of Swampscott" courteously loaned by the Lynn Puhlic Library.)

certainly manufactured here up to as late as 1660, because the works are mentioned in the Records, in 1661, as the Glass House Field. Another item implies that the works shut down about 1670 for lack of capital. In this plant it is probable that nothing more was attempted than the manufacture of bottles, other simple hollow ware, and coarser forms of glass. In 1753 a group of German glass workers started to make bottles in a part of Braintree called Germantown. Other glass articles were made, mostly heavy ware. The plant burned a few years afterward and the work stopped. The legislature gave the owners permission to raise £1250 by a lottery to rebuild. In 1783 Massachusetts raised £3000 by a lottery to build a glass factory at Boston. English foremen and associates were brought over to run the factory. However, the glass industry proper was not established in Boston until 1787. In July of that year the General Court gave a company the exclusive right to manufacture glass for fifteen years. A penalty of £500 was attached to any infringement of their right by making glass in Boston, and was to be levied for each offense. The capital stock was exempted from taxes for five years, and the workmen were to be relieved from all military duties. A large conical kiln of brick was erected at the foot of Essex street. Being found unsuitable for the purpose, it was soon afterward taken down, and a wooden one, lined with brick, differently con-

stntcted, was put up in its place. I t was 100 feet long by 60 wide. On account of dif6culties in procuring workmen, and other embarrassments, the actual production of glass did not begin until about six years after the company was launched. At this time the average wage of the workmen was 4s. a day. The company started with the manufacture of crown window glass and produced a glass equal in quality to any imported. ' Raw materials, especially a good quality of sand, were abundant. Within six years, they produced about 900 pieces of uown glass a week, worth $1.75 per piece. The business was always precarious, and it was not anti1 1803 that stability was reached. In this year an experienced glass maker from Europe took charge of the works and within a few years Boston crown window glass was favorably known throughout New England. In 1811 another company began to make glass in East Cambridge. In the great gale of 1815 the Boston works was blown down and later the wreckage was burned. In considering the glass industry in the colonies, it should not be forgotten that window glass and even mirrors and glassware were uncommon in England fifty years before the settlement of the colonies. As late as 1661 country houses in some parts of Great Britain had no glass windows, and even luxurious palaces were only paxtly supplied with glazing. Although the demand increased and the use of glass had become almost a universal necessity, it was a scarce article during the Revolution, and as a matter of f a d most of the glass, especially large sheets of window glass, used prior to that period was imported from the mother country. Molding and cutting machinery were not introduced until after 1800 and coal did not replace wood as fuel until about 1825. In looking back over the history of glass making it is noticeable that the industry remained unsuccessful or experimental until the makers realized that the furnace clay, sand, limestone, potash, soda, etc., must be tested, especially for iron and other impurities. POTASH

Potash was among the chemicals prepared by the first colonists soon after they had built their log houses. They saved the ashes from their fireplaces, leached out the potash, and used the lye for washing their clothes, and removing grease from their kettles. As soon as fats accumulated, they were made into a harsh soap by the lye. The early clearing of land and first fashioning of lumber fostered the manufacture of potash. The felled trees and troublesome trash were burned to get rid of them, and the potash makers followed, or often accompanied, the lumbermen. One of the first recorded potash enterprises was at Piscataqua, now Portsmouth, N. H., where in 1631 a large mill was erected to saw lumber and at the same time make potash from the refuse. Eight Danish immigrants were employed. The potash industry in America was really established a t

this time. It grew rapidly, and before many years small plants were scattered throughout the colony. Several reasons account for this rapid increase. The most impelling was the one already stated, d z . , the necessity of getting rid of the trees and trash. Another was the simplicity of the process, i. e., bum wood, leach the ashes, and evaporate the solution in kettles heated by the burning wood! Still another reason was the steady demand for potash in the colonies, and in England as well, a t a good price, ranging according to the quality of the potash from £13 to £20 a ton. Perhaps an important reason for the undisturbed progress in this industry was labor. The Indians would not work at potash making; they preferred to hunt and fish. But adventurous white men were willing to go into the woods to make potash; this kind of work required no skill. Records show that one man alone could, in one year, cut and bum enough wood to make nearly 10 tons of potash. Inasmuch as potash could be manufactured by unskilled laborers, potash plants were started in many places. Samuel Blodgett began to make potash in Haverhill, Mass., in 1750. William Frobisher improved the process in 1768 according to an item in the Massachusetts Archiues. About this time (17601775) potash became an important commodity. Much was used in Boston by soap makers. Considerable was exported to England. Larger and better iron kettles became available. The quality of the potash was improved, and standards of purity previously established were beginning to be observed more generally. The industry spread so that the number of potash works in Massachusetts in 1788 was nearly 250. The first in the state is said to have been erected on a very large scale, near Belchertown. An immense building was put up and lined with iron-bound vats and tubs, and in the center were built four large furnaces, the fires of which met in a common flue where the intense heat was intended to evaporate the lye, conducted to it in a small stream, while the dry potash fell into a pan beneath. After a great outlay for apparatus, ashes, etc., the fire was directed upon a stream of lye, whereupon the chimney suddenly blew up and the proprietor was obliged finally to abandon this promising plan. At this date (1788) some of the most profitable works were set up at a cost of less than £20, exclusive of the kettles, which were the chief item of expense. In Lancaster County, Mass., there were many pot-and-pearlash works. The first complete ton of potash sent to market is said to have been from Ashburnham, in that county, where it was made almost from the first settlement in 1735. The first introduction of iron kettles in the business has also been ascribed to Colonel Caleb Wilder of Lancaster. The procedure of manufacture changed as the wond was used up and the demand for a better product increased. Wood was burned in huge piles and the ashes were leached in large vats instead of in barrels or tubs. The lye was then boiled down to a black mass in a battery of kettles. If an ordinary grade of potash was

wanted, this black mass was removed and sold as such. To make a better grade for use in manufacturing soap and glass, the black mass was left in the kettle and heated very hot to burn off as much of the carbon as possible. This gray product was called pearlash. Its manufacture was more profitable than that of the ordinary potash, and several more or less successful attempts to improve the quality were made. For example, instead of heating the black mass in a kettle, the mass was raked from the kettle and spread out in a long oven or in a reverberatory furnace of simple construction. By this improvement the slow, uneven beating in the kettle was replaced by rapid, uniform heating much like modem methods. Pearlash despite its price was not made in large quantities, and even so most of it was exported. A ship's cargo in 1768 contained 1344 tons of potash and 201 tons of pearlasb. The percentage of actual potash in the commercial product was variable, but the purchaser had no way of knowing this fact. Moreover, there seemed to be few known ways of stating its purity. Many chemists worked on this problem, among them being Dr. Aaron Dexter, the k s t professor of chemistry in Harvard University. The results of Dexter's investigations were published in 1793 under the title "Observations on the Manufacture of Potash" [Mem. Am. Acad. Arts and Sciences, 2 , 165-70 (1793)l. It is evident from his article that he was asked for help by manufacturers, and his study of the sources and methods convinced him that the impurities were earthy matter and common salt. In his paper be describes current ways of obtaining potash from ashes, and points out ways to get rid of contaminating substances and produce a satisfactory product. Dexter's contribution shows that at this late date manufacturers of potash had not fully standardized their product and found it necessary to consult a chemist; and the article also shows that the first professor of chemistry in Harvard University likewise found it possible to help the manufacturers in this industry. IRON

Strictly speaking, iron was not manufactured within the narrow limits of Boston proper, though forges and bloomeries were set up in many neighboring towns. Boston was indirectly responsible for many of these early attempts to manufacture iron, and furnished a market for this metal, so indispensable in constructing buildings and providing ships with anchors, chains, and other metal parts. Anticipating a little, we may say there were six kinds of iron plants-so-called-in the colonies and provinces. These kinds were bloomeries, forges, ore furnaces, smelting furnaces, slitting mills, and steel furnaces. At first forges and bloomeries were set up. The bloomeries and forges were much alike, and were generally provided with a power-driven bellows. In these plants rich ore was reduced by charcoal in an open fire into a semi-molten mass, or bloom, of a rather poor

c u u r , r s y Of Prof

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THEFIRSTIRON POT CASTI N AMERICA (From a photograph furnished by the Lynn Public Library.)

quality of wrought iron, which was purified roughly by hammering on an anvil. This was the process followed for many years in eastern Massachusetts, where the first bloomeries and forges were erected. The plants required only a small investment and could be set up almost anywhere. The product was made into heavy farm implements, coarse tools, nails, etc. Not much technical improvement was made in this type of iron manufacture until after the Revolution. Discovery was early made of the bog iron ore in numerous peat bogs and ponds within a mile or two of Lynn, and the first attempt to manufacture iron in New England was made in this town. The great scarcity of ironware and tools, and of iron for ship building and erection of mills and dwelling houses led Thomas Dexter, Robert Bridges, and other enterprising persons, to form a plan for the manufacture of iron in the Colony. With this view, Mr. Bridges, in 1643, took to London some specimens of ore from the ponds of Saugus. In connection with John Winthrop, Jr., who had preceded him thither two years before, a company was formed, called the "Company of Undertakers for the Ironworks." The sum of £1000 was advanced for commencing the work, and Winthrop, accompanied by a corps of workmen, returned to New England the same year. Preparations were immediately made for the manufacture of iron on a large scale, contemplating not only smelting the ore, but refining and forging the metal. The General Court was applied to for encouragement and participation in the business. The design was approved, but the state of the public treasury did not warrant the Assembly in taking stock in the Company.' Two or three private persons joined the enterprise, and the General Court granted them, March 7, 1643, nearly all their requests, including the exclusive privilege of making iron for twenty-one years, provided they made, after two years, sufficient iron for the colony's use. They were allowed the use of any six places not already granted, on condition that they set up within ten years a furnace and forge in each

place, "and not a bloomery only." The undertakers and their agents were exempted from all public charges and taxation upon their stock, and they and their workmen were released from military training. A grant had been previously made in town-meeting, "19th of 11th mo.," 1643, to Winthrop and his partners, and to their assigns forever, of about 3000 acres of the common land a t Braintree, "for the encouragement of an Iron-work to be set up about Monotcot river." This grant was not surveyed, however, and was not laid out until January, 1648. It was long a subject of doubt whether the first forge was in Braintree or Lynn. But undoubtedly the first works were erected at Lynn, on the west bank of the Saugus, upon land purchased of Thomas Hudson, near a chain of small lakes abound'mg in ore. The village was called Hammersmith, after the native town (in England) of several of the principal workmen. Large heaps of scorize in Saugus mark the site of one of the most important, though for various reasons not very successful, chemical industries of early colonial times. Operations were continued with variable success for over one hundred years. One of the men who probably accompanied Winthrop from England and was connected with the undertaking from the first as a principal workman and machinist was Joseph Jenks, a native of Hammersmith. He was held in high esteem for his extraordinary ingenuity as an artificer in metals. By his hands the first models were made, and the first castings taken of many domestic implements and iron tools. The first article cast was an iron pot, capable of containing about a quart. Thomas Hudson, of the same family as the celebrated Hendrick Hudson, was the fcst proprietor of the lands on the Saugus River, where the iron foundry stood. When the forge was established, he procured the first casting, which was the famous old iron pot. This was preserved as a curiosity, and handed down in the family. It is now in the Lynn Public Library. On May 6, 1646, Jenks was granted by the legislature a patent for 14 years "for the making of engines for mills, to go by water, for the more speedy despatch of work than formerly, and for the making of scythes and other edged tools with a new invented sawmill, that things may be afforded cheaper than formerly, and so on, yet so as power is still left to restrain the exportation of such manufacturers, and to moderate the prices thereof, if occasion so require." About ten years later he was accorded another patent for an improvement in the manufacture of scythes, "for the more speedy cutting of grass, for seven years." The improvements consisted in giving greater length and thinness to the blade, and in welding a bar of iron upon the back to strengthen it, as in the modem scythe. This was an essential improvement upon the old form of the English scythe, which was a very clumsy instrument, short and thick like the bush or stub scythe. No radical change has since been made in the form of this implement. His genius took a somewhat wide range. In October,

1652, when Massachusetts undertook to supply the deficiency of specie by a silver coinage, Jenks was employed to make the dies, which he executed at the iron works. The issue consisted of shillings, sixpences, and threepences, to which was added, in 1662, an issue of twopences. Of the shillings, there were at least sixteen different dies, and several of each of the others. Two years after, Jenks made a contract with the selectmen of Boston "for an Ingine to carry water in case of fce," which was undoubtedly the first attempt to make or use a fire engine in America. Very few such machines were built in Europe until this date. They were not used in Paris until nearly fifty years later, and the addition of an air chamber was not made until long after. The fabrication of iron into needed articles was carried on vigorously. Besides the improvements in casting, another example of this progress was the erection of slitting mills in Boston, Milton, Middleboro, and many other places. In these mills bars of iron were rolled into sheets and then slit into rods. The rods were used as such or headed into spikes and nails by farmers during bad weather or the long winter evenings. Another improvement was the introduction of machinery for heavy forging. Thus, Nathaniel Ayers set up such a plant at Boston in 1720 where he forged anchors weighing 600 lb. or less, and also the heavy iron parts for grist mills and saw mills. Many improvements were also made in casting, e. g., sand was substituted for clay in the molds, thereby permitting the better casting of kettles, etc., such as was done prior to 1710 by Joseph Mallinson a t Duxbury. His work was so highly regarded that in 1733 Massachusetts granted him 200 acres of wild land "in consideration of his great service to the public in setting up the manufacture of cast-ironware in sand." This man's work was improved and by 1760 cast teakettles of superior quality were made at Carver. Still another step forward was the selection of better ore. A lively example of this is found in the case of one Holmes of Kingston. While fishing in a nearby pond in 1751, according to a local account, he tried to pull in a lump of bog iron ore weighing 3000 lb.! I t was of such quality that it yielded 25 per cent. of iron, which came to be known as "Holmes iron" and during the Revolution was cast into cannon balls. Perhaps the most important advance was made by Hugh Om, a young Scotchman, who settled in Bridgewater in 1738. He manufactured edged tools. Ship carpenters and other mechanics came to him from distant points for tools. His versatility led to improvements in almost any work in metals. Perhaps his most welcome step was in the transformation of iron into implements of war. He cast and bored cannon, and as early as 1748 he made 500 stand of arms for the Province of Massachusetts. Unfortunately, when the British evacuated Boston, they carried away nearly all these muskets. We should expect that fishhooks would be included early in the range of the mechanic arts. And we find

in the inventory of Adam Bath, a t Boston, in 1717, a variety-6000 tomcod, 5000 flounder, and 10,000 "small fishhooks not finished." He had an assortment of wire, both iron and steel; 2 bbl. of "fine card wire," and 3 lb. of "card wire." This would indicate that he made cards as well as fishhooks. Other improvements in iron manufacture were made after the Revolution, but the exhaustion of good ore, the consumption of nearby wood, and the scarcity of limestone led to the transfer of the iron industry from eastern to western Massachusetts, and then to more favorable locations for raw materials. BEVERAGES

The fimt settlers had little time to manufacture beverages, despite the fact that most of them had previously acquired habits and tastes of drinking which were hard to forego. Tea, coffee, and chocolate were almost unknown in England when our ancestors left for America. Fermented liquors, on the other band, had long been a part of their drink. Beer was a common beverage, and i t is not astonishing that brewing was undertaken by the colonists as soon as the threefold problem of food, clothing, and shelter was along the way to solution. Brewing started in Boston soon after the settlement. In November, 1637, the General Court, for the protection of brewers, who seem already to have been numerous enough to form a sort of trade union, ordered that: "No person shall brewe any beare, or malt, or other drinke, or sell in gross or by retaile, but only such as shall be licensed by this Courte, on paine of £100; and whereas Capt. Sedgwick hath before this time set up a brewe-house a t his greate charge, and very comodious for this part of the countrey, hee is freely licensed to brewe beare to sell according to the size before licensed dureing the pleasure of the Courte." The "size" was before ordered to be not stronger than could be sold a t 8s. a barrel, under penalty of £20. This seems to be the earliest mention of a brewery in the colonies. In the colonial times brewing was both a household industry and a specialized trade. Malting was an individual or an independent industry, though some farmers prepared malt from their own barley. The process of brewing was largely a band one, even the pumps being worked by hand and in some cases the malt was ground between small stones. There was no sterilizing (except by boiling) and no cooling. Beer was stored in cool places underground. At the Commencement of Harvard University in 1703 four barrels of beer were consumed to only one of cider and eighteen gallons of wine. Cider was a common and acceptable beverage in colonial and provincial times. Apple trees were among the first plantings, and as early as 1650 Massachusetts shipped barrels of cider to Maryland and even to the West Indies. At this time cider was 1s. 8d. Aoer gallon and £4 4s. per hogshead. Cider was made into vine-

gar by spontaneous fermentation. One use of vinegar, seldom mentioned, was in cleaning slave ships. The most conspicuous of the beverages made in old Boston and other New England towns, especially Newport, R. I., was rum. The industry started as soon as the first sailing vessels brought back molasses from the West Indies in return for lumber, staves, and fish. The molasses was "sugary" and yielded a pleasant tasting beverage, though it lacked the body and flavor of the West Indian product. The rum industry grew to large proportions. In 1750 it was estimated that Massachusetts made over 15,000 hogsbead-and Boston's share must have been large. The price was low, averaging not over 25 cents a gallon. Only a few facts about this unusually large industry can be stated here. One relates to the equipment of a brewery. About 1725 Thomas Amory built a stillhouse in Boston. Pine logs 28 ft. long and 18 in. in diameter were brought from Portsmouth, N. H., for his pumps. In 1726 he ordered a copper still of 500 gallons capacity from Bristol, England. The head was to be large in proportion to the still, the gooseneck was to be 2 ft. long and of fine pewter, with a barrel in proper proportion to the whole still. The price delivered in Boston was to be 270 per cent. over the Bristol price. Unless the making could be done in Bristol for 2d. per pound, he stated be would rather have the metals shipped to him to be made up in Boston. In 1735 a distillery for making rum from molasses was built a t Medford-the first of a series which operated for many years. Prior to 1793 the neighborhood of Essex and South Streets in Boston was largely occupied by distilleries. The oldest one was for some time in the possession of the French family, and i t had been improved as early as 1714 by Henry Hill, a distiller, and by Thomas Hill after him. Besides this, there were Avery's and Haskin's distilleries, between Essex and Beach Streets. In 1794, when the town contained a little more than 18,000 inhabitants, there were no less than thirty distilleries. Boston rum a t this time was 4d., and that from the West Indies 6d., a quart. LIME

Doubtless the first lime was manufactured by "burning" shells in a wood k e just as until a few years ago lime was made by "burning" limestone itself over a wood fire. Manufactured from shells in this crude way, the first lime must have been a very poor product. However, it was caustic enough for removing the hair from skins in the manufacture of leather, for making a rough mortar to bold chimney and fireplace stones together, and even for constructing brick houses. The colonists were familiar with the English method of manufacturing lime by heating limestone, and doubtless they prospected for limestone as they did for gold, lead, medicinal plants, etc. Hence there was meat rejoicing and coisiderable excitement when limestone was discovered in 1697 in Newbury, Mass., by Ensign

James Noyes. The news of the discovery spread, and laws were passed requiring bricks to be made of standit is said that at first thirty teams a day came to New- ard size in ironshod molds and from clay dug at the bury to drag away the precious "stone." The few right season. As early as 1677, a brick building was inhabitants were startled by the removal of their constructed "for the College at Cambridge" by subriches, and sent James Brown, the deputy sheriff, to scription, and in 1697, a substantial brick meeting stop the spoliation. As soon as possible, a solemn house, the first building in Boston of that material, notice was "publickly" posted stating that: "The town was erected on the site of the Quincy House. One of the fkst brickyards, perhaps the first, was will have a meeting, and bring it to some regulation." Other deposits of limestone must have been discovered started in Swampscott on the northerly side of Humsoon after, especially as explorers and pioneers pushed phrey's brook near Ingall's tannery. As early as into Rhode Island, Vermont, and Western Massachu- 1647, perhaps earlier, brick making was carried on extensively a t "the town of Mystick," subsequently setts. Lime was manufactured in Boston as early as 1723named Medford, though the name Mystic continued to perhaps earlier, though we know that a lime kiln was in be associated with this region. Indeed "Mystick" operation near the Bowling Green in 1723. About seems to have been the principal place for the manuthis time the price of lime was 1s. a bushel. facture of bricks in Massachusetts. About the time Long before the Revolution, lime was manufactured of the Revolution this town produced annually over in large quantities in, and near Boston, and at the time four millions of bricks, and the price was only about of the War the price had risen from $1 to $6 a hogs- 16s. a thousand. Boston, Dorchester, Charlestown, head. Lime was manufactured from limestone as and a few other older towns, also produced some-by early as 1661 in Providence, R. I., and sent in large compulsion, no doubt to save the expense of transporquantities to Boston before the industry was under tation by such imperfect means as they had in those days. In Boston the brickyards were near Dover way in the latter town. Street, before the Revolution. They gave employBRICK, TILE, AND POTTERY ment to many poor people during the continuance of Usually the brick and tile plants were near clay pits the Port Act. The need of brick in Boston was due in towns which yielded wood for fuel and had good to the total .absence of building stone of any kind roads for transporting the finished products to Boston within the narrow limits of the original Boston. or other commercial centers. The bricks included PAF'ER soft, hard, and glazed varieties. The tiles included The first paper mill in the New England colonies was both rough (for roofing) and enameled. And the pottery, while rather crude at first, was soon made established in the Dorchester district. On September into durable and attractive vessels. As stated below, 13, 1728, the General Court granted to Daniel Henchthe brick molds sooner or later were iron shod and of man, Gillam Phillips, Benjamin Faneuil, Thomas prescribed dimensions. The clay used by potters was Hancock, and Henry Dering the sole privilege of making paper in the Province for a term of ten years. carefully selected, aged, and ground in iron mills--as Henchman and his partners hired from the heirs of soon as there was a demand for a good quality of ware. The pottery was shaped on a platform operated by a Rev. Joseph Belcher an old mill which had been erected foot-wheel. The tiles were molded and grooved by hand. early in 1706 a t the bridge over the Neponset River in The brick, tile, and pottery industries were among Milton. The proprietors employed an Englishman the earliest colonial industries to be technically de- named Henry Woodman as foreman. Owing to many veloped and fundamentally organized, and considerable delays they did not begin the regular manufacture of paper till 1730. In 1731 they furnished the General capital was invested in them for those days. The first brick house in Boston, and perhaps in Massa- Court samples of their paper. Henchman, who appears to have been a principal chusetts, was built, it is said, by one of the Coddingtons, previous to his removal to Rhode Island in 1638. projector, was a well-known bookseller and publisher In 1643, a brick watch house was built on Fort Hill, in in Boston, and a man of considerable wealth for the Plymouth, which is the earliest notice of bricks in that times. Another bookseller of Boston, who seems to town. The bricks were furnished by a Mr. Grimes, at have been concerned in this first paper mill in New 11s. a thousand. This was about the price of bricks England was Richard Fry. In May, 1732, Fry had for several years. Lime, brick, and tile making are the following item in an advertisement in the Weekly mentioned among the trades that were pursued as Rehearsal, a paper published by Thomas Fleet, the independent callings in New England, as early as 1647. printer : "I return the Public Thanks for following the DiBoston, about 1657, is quaintly described as having "large and spacious houses, some fairly set forth with rections of my former Advertisement for gathering brick, tile, slate, and stone, and orderly placed, whose Rags, and hope they will continue the like Method, continual enlargement presageth some sumptuous having received upwards of Seven Thousand weight city." The General Court in 1667 appointed a com- already." The paper industry which was started in Milton a t mittee to frame a law to regulate the size and manufacture of bricks, and within the next few years, several this early date has continued through an unbroken

succession of men to the present day. We cannot follow it in all the details of ownership, and will merely mention some of the salient historical aspects. One of the men who next became interested in paper making in Milton was the zealous and versatile James Boies of Boston. In 1760 Boies procured a papermaker, named Hazelton, from a British regiment, then in Boston, and attempted to put the business on a better basis. Soldiers on furlough were occasioually permitted to work for the tradespeople with whom labor was scarce. Hazelton worked only a short time, because his regiment was soon after ordered to Quebec, and the Commander-in-Chief refused to allow Hazelton to remain behind. After another short interruption, Richard Clark, a practical paper maker, became associated with Boies. Clark is said to have had a superior knowledge of the business, and to have made most of the molds used by him. He was assisted by Abijah Smith, who continued in the business to an advanced age, and subsequently by his own son, George Clark. The paper industry, once really started, grew rapidly in this town. Boies and Clark were followed by Boies and McLean (1777), J. S. Boies (1790), and Tileston and Hollingsworth (1801). The last company became the Tileston and Hollingsworth Company in 1889 and is still in operation. Boston University has an academic interest in this company because our Commencement programs are printed on paper made in this mill which is the industrial successor, through four generations of Hollingsworths, of the first paper mill in old Boston. In 1796, the town of Milton had three paper mills, making six on the Neponset river; there were twenty within the State of Massachusetts. The Grst paper manufacturers struggled with two diiculties. One was the scarcity of workmen, especially those skilled in this industry. The other was the lack of raw material. Rags, of which the paper was made, were scarce and scattered. The following announcement appeared in an issue of the Boston N m s Letter during 1769:

Province, to preserve all their Linnm and CoUDn &3h e n Rags, in Order that a Manufactory so useful and advantageous to this Country may be suitably encouraged; and it is also recommended to our Several Towns to take such further Measures for the Encouragement of the Manufacture aforesaid, as they shall think proper. Signed by Order of the Provincial Congress JOHN HANCOCK, President. A true Extract from the Minutes. BENJAMIN LINCOLN, Secretary.

The Boice (Boies) and Clark mentioned in this item are the two men noted above. The process of making paper in these old mills was rather crude and very slow. A single mill usually had two vats, employed ten men, and as many boys and girls. Such a mill required a capital of about $10,000 and was capable of producing annually from 2000 to 3000 reams of different kinds of paper. Although only white or slightly colored rags were used for the manufacture of white paper, the product, as is evident from the inspection of the early books and newspapers, was coarse, dark-colored, and unsightly. The grinding, or trituration, of the rags into pulp was done by beating them with a trip-hammer in stone or iron mortars. There was no means of discharging the coloring matter, either before or after the formation of the sheet, and the paper was sent to market unbleached and uncalendered. By this process several days were required to produce paper which subsequently could be made in a few hours, and at the present day in only a few minutes. Moreover, the relative quantity produced in the earliest days was absurdly low. This limited output is readily understood when we know how the work was done. Each sheet was made separately, and four and a half reams of newspaper twenty by t h i i y inches, technically termed "a day's work," required the constant labor of three men, with the occasional assistance of two more. These four and a half reams contained two thousand, one hundred sixty sheets, which placed end to end would measure five thousand four hundred feet-a little more than one mile. Moreover, when The bellcart will go through Boston before the end of next month, to collect rags for the Papermill at Milton, when all the three men with their two assistants had finished people that will encourage the paper manufactory may dispose their day's work, the paper was wet, and had to be dried upon poles. If the weather proved favorable, of them. this drying might be done in five days-a startling couAnother striking example of the measures taken to trast to our automatic machines of the present day, procure rags is the item printed in the Boston Earning which turn out many miles of dry paper a day. Post, March 6, 1775: IN FUOVINCIAL

CONGRESS.

February 9, 1775 HEREAS the Encouragement of the Manufactures of thc Country d l at all Times, (and more especially a1 this) be attended with the m s t beneficial Effects, and Messieurs Boicc and Clark having represented to this Congress, that they have at a very considerable Expense erected Works at Milton, in this Province, for the making Paper. and have not heretofore been able to obtain a Suficiency of Rags lo answer ikzir Purposes; and in Or&r to procure a hrger Quantity of that Article, haw raised the Price thmoj: Therefore. Resolved. That it be recommended, and it is by this Congress accordingly recommended, to every Family in this

w

DYEING

The gay-coloredfabrics of the colonists were imported from England. But the cloth, especially of linen and wool, needed for ordinary wear was dyed in the earliest days by natural colors extracted from roots, barks, berries, etc. The Grst sources were doubtless pointed out by the Indians, who used vegetable coloring matter together with ochres to dye their garments, implements, and ornaments, and to smear their bodies. But the settlers soon learned to select choicer raw material and prepare better and more permanent colors. The dyeing, as well as the carding, spinning, weaving, and

bleaching, was done by the wives and daughters of the farmers and planters-at 6rst in the homes of industrious individuals and cooperative groups, next by individuals and groups in a common working place, and finally in mills, though the home was always the source of the best quality of linen. Indigo, which for ages has been used to produce a fast blue, was the most important dye used. The indigo plant is indigenous in America, though many plants yielding a blue coloring matter were often mistaken for the genuine plant. Thus, Emmanuel Downing, a relative of John Winthrop, Jr., wrote this young industrial chemist about 1650, that "a weed growing in abundance arouM Salem produces an indigo better than the West Indian and equal to the East Indian." Downing performed some experiments looking toward the manufacture of indigo, but doubtless had to conclude that the product was inversely proportional to his prediction. However, indigo was brought to Boston from the West Indies as early as 1639 and continued to be imported for many years. The plant was cultivated in South Carolina, where the industry was fostered by a bounty as early as 1694. One local result of the colonial iudustry and the trading was the permanent "indigo t u b in the chimney comer of most homes where the women dyed their yams. Many woods, especially logwood, from which a dye could be extracted, were imported. The demand for colored fabrics of many hues, common to all peoples in whatever stage of development or period of colonizing, soon led to the rise of the journeyman dyer and the business of dyeing. Two examples illustrate this fact. A "blue dyer" was sent from Boston quite early to Norwich, Connecticut, because he "could dye cotton, tow, or linen in indigo." There is an inventory of John Cornish of Boston taken in 1695, "an humble dyer, comber, weaver, and fuller." The inventory describes the process by which he dyed wool in "2 furnaces value €16." We can also get some idea of the extent of his processes by certain items. Thus, besides textiles, he had on hand-

Moliueaux of Boston in 1769. In this year he became a tenant in the famous Manufactory House. Here he opened a spinning school, and in connection with it established a large dyehouse, which was said to be the best equipped in the provinces. It was furnished with a varied assortment of vats and kettles and with dyes especially selected to color domestic fabrics. Unfortunately, the premature death of Moliieaux disrupted the business, and in 1774 the equipment was sold to settle his estate. However, a t just this time the domestic industry was favored by the provincial congresses, Massachusetts among them, which passed measures specifically encouraging the domestic manufacture of many chemicals, including dyes. NAVAL STORES

Boston was the point for the storage, sale, and shipment of naval stores. Tar was made in the very first days, and the iudustry must have been established before 1662, because in this year John Winthrop, Jr., read a paper before the Royal Society on the manufacture of tar in New England. The tar industry was developed along with the lumber and potash industries. There is a note that tar was made a t the earliest settlement in Portsmouth, N. H. (alluded to above); one man could make a barrel of tar in a week. Pitch was distilled from pine trees. Turpentine was made in Connecticut and shipped in 112-lb. casks via Hartford to Boston as early as 1708, where it was used locally and also exported to England. Tar, pitch, and turpentine, together with rosin, were used extensively in preparing and reconditioning the sailing vessels which entered and left the port of Boston in large numbers. Considerable tar was used in the manufacture of rope-an extensive industry in Boston. The manufacture of naval stores was stimulated by colonial needs as well as by certain acts of Parliament. Plants for making tar were crude and the work was largely done by self-taught workmen. Dead or abandoned pine trees were used a t first. When a better quality of tar was demanded, pine knots were used or the trees were partly girdled. Most of the tar, espe82 lb. copperas a t 2d. 60 lb. potash a t 6d. cially during the first fifty years, was made by piling 35 lb. madder a t 1s. 34 lb. galls a t 18d. the wood or knots into a heap on a hard, slightly in70 lb. redwood a t 1s. 230 lb. fustic a t 18s. clined, clay floor, covering the whole loosely with turf Silk dyers were a t work early in the eighteenth cen- or earth, and setting fire to the pile a t the bottom. tury. Thus, in 1722 Samuel Hall advertised in the As the tar formed, it sank t o the floor and flowed off Boston News Letter that he is a man "proficient in through a wooden trough into a barrel sunk in the cdendering any silk and in watering, dying (dyeing) ground. In 1671 the General Court gave a company of Bosor scouring." Similarly in 1726 another man advertised himself "a silk dyer just come from London," ton merchants timber rights for making tar and sole and solicited work on brocades, velvets, satins, mohairs, right to make and sell pitch, rosin, and turpentine damask, needlework, silks, and worsted hose, and in within the colony. The company was compelled to 1731 James Vincent and Joseph Herbert advertised sell its products a t reasonable prices and to pay a tax that they were equipped to "dye all sorts of women's of 6 per cent. on all pitch and rosin manufactured. wearing apparel, with embroidery and needlework; GUNPOWDER glaze fine chintz and calicoes; press, callender and new pack goods for merchants." Gunpowder was needed by the colonists to kill game As the Revolution approached, dyeing became very for food and to repel attacks of Indians. The first general. A great step in advance was taken by William supplies were brought from England. . The demand

increased as settlers pushed into the wilderness, and many attempts were made to manufacture it in Boston, the earliest ones being made in 1666 and 1672. The first successful attempt was in 1675 when William Everden (or Everenden) started a small plant in Dorchester. Records state that this powder was as good and strong as the best English powder. Powder has three ingredients-charcoal, sulfur, and saltpeter, and the history of the manufacture of powder is really the history of the search for saltpeter. The charcoal was readily obtained by burning willow trees. The sulfur was largely imported, though some may have been extracted from the iron-sulfur ores so abundant in many localities, especially in the central part of Massachusetts. Records about this ingredient are scattered and meager, but there could not have been much difficulty in securing it. During the first half of the year 1770, Boston, in anticipation of the conflict with Great Britain, imported nearly twenty tons of brimstone. After the Revolution, sulfur was admitted free of duty. Saltpeter was saved in every possible way and sought in every conceivable place from the days of John Winthrop, Jr., through the period of the Revolution. Gunpowder was made in much the same way as today, but not so carefully nor of such good material. It was stored in strategic places. Some of these powder mills and storehouses remain today or their location is marked in some conspicuous way, e. g., Powder House Park in Somerville. As the Revolution approached, the demands for powder became imperative and in the first days the need was acute. In August, 1775, the whole supply of powder was only nine rounds per man in Washington's army. Fortunately, some powder intended for the British army was captured during the next year. When it was evident that the supply of powder might become exhausted, Paul Revere, the resourceful patriot, was sent to Philadelphia to inspect the powder mill of Oswell Eve. Eve refused to show him drawings of the machinery, to give him any information, or to assist him in any way. He did, however, allow Revere to inspect the mill hurriedly. So keen were Revere's powers of observation that he secured all the technical information necessary to start the manufacture of gunpowder. Canton, Massachusetts, was selected as the most suitable place for the work because of the availability of a powder mill which had been used in former years. Revere himself had very little to do with the actual manufacture of the powder. His part was to reveal the process and to get the plant started. A large quantity of gunpowder of an excellent quality was manufactured in this mill from 1776 onward. SOAP AND CANDLES

Soap was one of the first articles made by the colonists. They saved the ashes from their fires, leached out the potash and used the lye, first for washing and soon for making soap from the fat of the wild animals killed for food. Subsequently soap became an article

of barter. In 1633, X1i2 lb. of soap equaled s/r lb. of beaver (skin). When the supply of potash increased coincidentally with the manufacture and export of lumber, soap was made on a large scale for the trade by mdividuals or companies, thereby replacing the householder and producing a better and more uniform product. The price, too, was lowered, being only 2s. fid. a barrel in Boston in 1707. The price of Castile soap, probably imported or made from imported oil, was 2s. a pound in 1740. Soap making became a large industry as the supply of fat increased beyond household needs. Much soap was exported, e. g., in 1768 over 3500 boxes were sent to the West Indies. Inasmuch as soap and candles were made from tallow or similar fats, soap making and candle making were usually combined and their manufacture was considered a highly reputable class of work. The early colonists used candles for lighting. The first candles were made from tallow, since this was the only fat available, indeed the tallow candle continued to be made for about two hundred years. Candles were also made from spermaceti, and by the middle of the 18th century the spermaceti candle industry was well established. An example of the condition of the industry is the action of the General Court in 1750 in giving a ten-year patent to a maker of spermaceti candles, on condition that he teach a t least five apprentices during that period, two of whom should be named by the Court. By 1768the candle industry as a whole had developed to such an extent that 500,000 lb. of candles (spermaceti and tallow) were shipped annually to the West Indies and large quantities were sent to England. Soap and candle making was a household or individual industry for many years. One of the best known soap and candle makers in Boston was Josiah Franklin, father of the famous Benjamin Franklin. His shop was on the southeast corner of Hanover and Union Streets. Its sign was a blue ball suspended by an iron rod from the front of the shop. Before the streets were numbered and when the buildings were scattered, it was the custom among the inhabitants of Boston to designate their shops by some emblem. Hence the blue ball. The old house was quite small and had only two stories, though a thud was added in later years. It was partially destroyed by fire in 1858, and in the same year the city took the building to widen Union Street. Two relics of it are, however, preserved. The blue ball is in the museum a t the State House and a chair made from the original timber is in the possession of the Mechanics Charitable Association (of which Benjamin Franklin was the first president). The front room of the Franklin house was the living room, and the shop proper was in the rear. The shop was a small place for boiling soap, melting tallow, and making candles. We can sympathize with young Benjamin in his rebellion a t cutting candlewicks, filling molds, and stirring soap in such restricted quarters, especially when i t was more enjoyable to throw rubbish into the neighboring mill pond and to play on his way

through Hanover and Court Streets to the Latin School Several Paul Revere bells are still ringing out the call to worship. or to his brother's printing office in Queen Street. The most important work in metals done by Paul The business of soap making was not very profitable, but doubtless Josias Franklin made as comfortable a Revere was with copper. During the years 1794-97 living as many other tradesmen of his time in old Boston, Old Ironsides was being built in Boston, and Revere particularly after the departure of his ungrateful and was given the contract for much of the brass and copper famous son, because about that time the supply of work. He made bolts, spikes, braces, cogs, pumps, potash increased and records show that large quantities etc., for this ship. The bolts and spikes were made of malleable copper by a process known only to Revere were used in Boston to make soap. Besides household and individual workers, there were himself. So well done was his work that it is recorded more resourceful men who combined related industries. "there are no persons in either Philadelphia or New Robert Hewes was a typical example of this class. In York that can make copper so malleable as to hammer 1784 he operated a slaughter house in Boston and it hot." In a letter written December 22, 1800, he worked up his products in a salting house, a glue fac- states, "I have engaged to build me a mill for rolling tory, and a soap and candle plant. Such an extensive copper into sheets which for me is a great undertaking, plant called for considerable chemical knowledge and and will require every farthing which I can make or technical skill. In addition he had a shop near by scrape. For the houses which I must necessarily where he sold hard and soft soap, tallow candles, glue, build, I shall want fifteen thousand boards and about neat's-foot oil, watch lights, and hair powder. Josias twenty-five casks of lime." The mill was built in 1801. The rollers used in the mill came from England beFranklin and others could not compete with such an cause there were none strong enough in this country. industrial chemist and general merchant as Hewes. Since the establishment of this industry involved great expense, the United States Government loaned him GOLD, SILVER, COPPER, BRONZE, PEWTER $10,000 in the f o m of a bond, and the debt was promptly The first colonists searched diligently for gold and discharged by him at the time agreed. In 1802, the silver. Some optimists were positive gold was abun- Revere Copper Company furnished the sheet copper dant, but the specimens reported as gold proved to be for the dome of the State House. Six thousand feet iron pyrites, aptly called "fool's gold." No silver was of copper were required and the bill amounted to found. These two metals were obtained by melting $4232. The Revere Company also furnished copper worn English coins, Spanish coins, and bullion from used by Robert Fulton for the boilers of his steamboat various sources. The silver was minted into American Raritan. The business rapidly increased and in 1803 coins and both gold and silver were made into vessels they had ready for delivery to the Government of the United States a large quantity of sheet copper for the for use in churches, lodges, and well-to-do homes. Among the best and best-known craftsmen in metals covering of the bottoms of seventy-four gunboats. Much of the copper used by Paul Revere and other was Paul Revere. His father came to Boston in 1715 and began to work at once as a gold and silversmith. workers was imported, coming in as ballast from southHis son Paul when thirteen years old entered his father's ern Europe. Some, however, came from the copper shop as an apprentice. Paul Revere had natural mines at Simsbury, Conn. About 1733 Jonathan artistic ability, and designed and engraved many of Belcher, the royal governor, was engaged in many the silver and gold pieces which are now the treasured business enterprises. Among them was copper smeltpossessions of Bostonians. Among the conspicuous ing, and he erected a smelter in Boston for getting coppieces are the gold urn given to the Massachusetts per from Simsbury ores. His chief difficulty, however, Grand Lodge of Masons and used a t the funeral of was in getting clay for lining the smelter. He had t o George Washmgon, silver vessels in the communion smuggle it in from England. service of King's Chapel in Boston, and a silver punch The low cost of pewter, and the ease with which it bowl called the "Rescinders Cup" made to commemo- could be made, melted, and worked, early led to its rate an important political event in the history of the manufacture into useful and ornamental articles for the household. The extensive use of pewter is shown American colonies. Paul Revere was also a craftsman in iron, bronze, by an inventory of an early Boston brazier. Vessels and copper. In 1793, perhaps earlier, he established of all sizes and shapes and in all stages of fabrication a foundry at 13 Lynn Street, Boston, where he made were "in stock." The list included candlesticks, castings in both iron and bronze. His products in- spoons, dishes, basins, pails, tankards, milk cans, warmcluded cannon, bells, stoves, kettles, anvils, and ham- ing pans, kettles, skillets, frying pans, cow bells, and mer heads. His letters contain records of the amount parts of such articles as bellows, hooks, and ornaments. of iron he ordered for his foundry. His letters also There were 2782 pewter dishes valued at over £235. reveal the interesting f a d that he used Watson's PAINT Chemistry to help him in his work. The early settlers of Boston appear to have disAmong the first bells cast were those for the Second Church of Boston and King's Chapel. In 1803, he couraged the use of paint, calling it "a useless luxury." wrote in a letter that he had cast sixty church bells. Even the churches were unpainted, the old wooden

church erected in 1699 in Brattle Square being a conspicnous example. The site of this church is one of the numerous spots selected for marking by a tablet in connection with the tercentenary celebration of the founding of the Massachusetts Bay Colony. Painter's colors were offered for sale in Boston in 1714; but paint was not generally used before the Revolution. For many years there has been a stone, called the Boston Stone, imbedded in the rear wall of a building which fronted on Hanover Street. The stone bore the date 1737, and was probably named from the famous London Stone, which sewed as a direction for the shops in its neighborhood, as did the Boston Stone in its vicinity. This stone is the relic of a paint mill which was brought from England by a painter about 1700, and was used as a paint mill by the painter who then occupied a little shop on the premises. It is stated by some authorities that his name was Tom Child, and Samuel Sewall is given as the authority. In his diary Sewall made this entry: "Nov. 10, 1706. This morning Tom Child the Painter died." The spherical stone which surmounted the larger stone was the grinder, and was lost for a time, but was discovered in digging the foundation for the building. The larger stone is only a fragment of the original, which was split into four pieces when placed in its present position. The capacity of the paint mill was nearly two barrels. WHALE OIL

The whaling industry started in Massachusetts a t an early date, and Boston was its center a t 6rst. Later, whale oil, bone, and spermaceti were sent to Boston from other places, notably New Bradford. The oil and spermaceti were used locally-the oil in lamps and the spermaceti for candles. The bone was exported. As the whaling industry grew, the products, including sperm oil, increased rapidly. It was exported in large quantities. By 1690 the whale oil industry was so well developed that a cargo from Boston for England included 748 barrels of oil. Among the goods the masters of these oil vessels were ordered to bring back were

" allom, copperas, and window glass." Within the next century the industry developed enormously, resulting in an improvement of the products and extensive exports. In 1745 over 10,000 barrels of oil were sent to Boston. In 1768, which may be taken as a typical year, 220 tons of whale oil were exported to the West Indies and 4000 tons to England. The best qualities of whale oil were extensively used as an illuminant. The oil was also used by shoemakers and curriers. Some was made into soap. Many colonists, however, used candles almost exclusively-tallow dips for many years and also spermaceti molded candles when obtainable. Bayberry wax candles were early used on Cape Cod and for special occasions in Boston, e. g., parties and dinners. The lamps in which whale oil was burned were crude reproductions of ancient vessels and were not improved very much, despite the inventive efforts of Benjamin Franklin and others, till thin oil, improved wicks, and proper burners were generally available.

FERTILIZER

The fertilizer used by the colonists was fish. At first one or two fish were put into a hill of corn, as the Indians had done for years. Later, the fish, especially the "April run," were ploughed into the soil. The General Court early prohibited the wholesale use of cod. Sea weed was spread on the fields in the fall and spring. Wood ashes, bones, lime, and animal excrement were also used, but artificial fertilizers, as we know them, were not available till a much later date than "old Boston." CONCLUSION

In this brief account of some features of chemistry in old Boston, much interesting material on chemical industries had to be omitted. It is hoped that an opportunity will soon be afforded for the publication of articles covering minor industries and the &ect of legislation on the development of chemistry in Old Boston.