Correction to Synthesis of Notoamide J: A Potentially Pivotal

Amy E. Fraley , David H. Sherman , Sachiko Tsukamoto , Robert M. Williams ... John W. Blunt , Brent R. Copp , Robert A. Keyzers , Murray H. G. Mun...
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Addition/Correction pubs.acs.org/joc

Correction to Synthesis of Notoamide J: A Potentially Pivotal Intermediate in the Biosynthesis of Several Prenylated Indole Alkaloids Jennifer M. Finefield and Robert M. Williams* J. Org. Chem. 2010, 75 (9), 2785−2789. DOI: 10.1021/jo100332c

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he absolute configuration of notoamide J was originally assigned 3S, which was based on the structural determination of the absolute configuration 3R of notoamide C. The 3R configuration of notoamide C has since been corrected to 3S (Li, S.; et al. J. Am. Chem. Soc. 2011, 134, 788); therefore, the absolute configuration of notoamide J must reflect this change and is thus assigned 3R. The correct structure of notoamide J and compound 15 follows:

Published: August 6, 2013 © 2013 American Chemical Society

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dx.doi.org/10.1021/jo401209s | J. Org. Chem. 2013, 78, 8214−8214