Acrylate Esters - C&EN Global Enterprise (ACS Publications)

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Acrylate Esters

CH2 = CHCOOR ( R - C H „ C,H,)* * Butyl, isoburyl, and 2-ethylhexyl esters available in experimental quantities.

Polymers and copolymers containing acrylate esters are used in coatings for paper, leather, textiles, wood, metal, etc., in adhesives, in molding powders, and in elastomers. Acrylate polymers are very soft and extensible, and acrylate esters contribute these properties to copolymers w i t h practically all other monomers, such as vinyl chloride, styrene, and vinyl acetate. Copolymers with drying oils may also be of interest.

Polymerization:

+ ollyl alcohol + (CH3)2NH

Typical Reactions:

• CH2=CHCH20CH2CH2C00CH2CH = CH2 •(CH3)2NCH2CH2C00R

+ H2S

• R0OCCH2CH2-S-CH2CH2COOR

+ HCI

• ClCH2CH2CO0R • H0CH2CHC0OR CI

+ HOCI + phenol

> OCH2CH7COOR

+ (CH3)2CHN02

METHYL

• OTHER M O N O M E R S

METHACRYLATE

ETHYL

CH2 = C(CH3)CO0CH3

AVAILABLE I N COMMERCIAL

»(CH3)2C-CH2CH2C00R N0 2

BUTYL

CH2 = C(CH3)CO0C2H5

METHACRYLATE

LAURYL

CH2 = C(CH3)CO0C4H,

QUANTITIES

METHACRYLIC

literature to Dept. SP.

CH2 = C(CH3)CO0H

8c H A A S WASHINGTON

Manufacturers

oi

Germicides

Chemicals

·

Chemicals for

including the

SQUARE, Plagies

Leather,

·

Ceiamic,

II nn ss ee cc tt ii cc ii dd ee ss Rubb'-r,

ACID

COMPANY

PHILADELPHIA

Synthetic

Textile.

METHACRYLATE

CH2 = C(CH3)C00CI2H25

Please address your inquiries for samples and

ROHM

METHACRYLATE

·•

5, rFuunngg ii co iddee s

Paper,

PA. ·

Petroleum

tnzymes and

·

other

DUeetîeerrggeenntlss Industries