Affiliation Index

364

HYBRID ORGANIC-INORGANIC COMPOSITES

Vigier, G., 112 Vinocur, R. B., 142 Wagner, G , 331 Wang, Bin, 125 Wang, Run, 317 Wang, Shuhong, 291,297 Wang, Wei, 125

Wang, Yuechuan, 348 Wei, Gu, 125 Wei, Yen, 125 Wu, Jinghe, 43 Yang, Dachuan, 125 Yeh, Jui-Ming, 125 Zhao, Jianai, 308

Downloaded by 92.63.110.177 on January 31, 2017 | http://pubs.acs.org Publication Date: March 21, 1995 | doi: 10.1021/bk-1995-0585.ix002

Affiliation Index A d Tech Systems Research, Inc., 280 California Polytechnic State University, 19 Colorado State University, 192 Dow Corning Corporation, 237 Drexel University, 125 DuPont, 163 Institut fur Neue Materialien, 331 Institut National des Sciences Appliquées, 112 Laboratoire de Chimie et Procédés de Polymérisation, 112 National Institutes of Health, 19 Oklahoma State University, 181 Oregon State University, 43 Sandia National Laboratories, 97,237,248,264 State University of New York at Buffalo, 317 Systran Corporation, 297

Toyota Central Research and Development Laboratories, Inc., 55 Université Montpellier II, 210 Université Paris Sud, 29 University of Akron, 348 University of Antalya, 331 University of Arizona, 6 University of Bath, 19 University of California—Irvine, 248,264 University of California—Los Angeles, 226 University of Cincinnati, 1,291,297 University of Dayton Research Institute, 280 University of Florida, 142 University of Liverpool, 19 University of Massachusetts, 86 University of Minnesota, 19 University of Southern Mississippi, 66 University of Texas at Austin, 308 Wright-Patterson Air Force Base, 280,297

Subject Index Abrasion resistance, polymer-filled glass, 174,177/ Advanced composites, surface modification of carbon fibers, 348-360 Alkoxysilyl-containing polymer precursors, synthesis using free radical copolymerization method, 128-129 Alkylene-bridged bissiliconates, synthesis, 251

Aluminum oxide particle containing nanocomposite, synthesis, 343,345 Anionic pentacoordinate siliconate, synthesis, 250 Antibody-based biosensor, development, 320,323,324/ Aromatic groups bound to silica, complexation, 214-216 Arylene-bridged bissiliconates, synthesis, 251

Mark et al.; Hybrid Organic-Inorganic Composites ACS Symposium Series; American Chemical Society: Washington, DC, 1995.

365

INDEX


Β Bandwidths of Bragg diffracted peaks, calculation, 182-183 Benzazole polymer systems, structural design for sol-gel processing, 280-290 Benzoate labeling and analysis, surface modification of carbon fibers for advanced composite materials, 352-354 Benzobisazole polymer systems, structural design for sol-gel processing, 280-290 Biomimicry inorganic-protein interactions in synthesis of ferrimagnetic nanocomposite, 19-27 objective, 2 organic-inorganic hybrids with crystalline polymer matrix, 6-17 Biosensor antibody based, development, 320,323,324/ chemical, use of sol-gel-derived inorganic-organic hybrid materials, 318 Bis(acetonitrile) dichloropalladium(II)diene polymer-solvent system, isothermal ternary phase diagrams, 196-200 Bissiliconates, arylene- and alkylene-bridged, synthesis, 251 Βoehmite-epoxysilane reaction mixture, synthesis, 343-344 Bone, properties compared to those of synthetic composites, 6-7 Bragg diffracted wavelength, 182 Bridged polysiloxanes, synthesis, 265-266 Bridged polysilsesquioxanes, synthesis, 265 Bulk optical nonlinear response, description, 319

C Carbon fibers, surface modification, 349-360 Cation-transfer intercalation chemistry, M P S layered compounds, 30-31 Ceramer technology, importance, 280-281 3

Ceramic(s), synthesis using sol-gel process, 1,125 Ceramic-polymer composites challenges, 97 reaction conditions vs. properties, 331-332 Characterization hexylene- and phenylene-bridged polysiloxane network materials, 270,272-275 magnetoferritin, 20-27 core size, 28 electron diffraction, 20,27 electrophoresis, 25-27 magnetic measurements, 25,26/ Mossbauer spectroscopy, 20,23-27 T E M , 20-22/27 nanostructured organic-inorganic hybrid composites synthesized using simultaneous processes, 89-92/ poly(ethylene oxide)-layered solid nanocomposites, 43-53 vinyl polymer modified sol-gel hybrid materials, 130-131 Chemical biosensors, use of sol-gel-derived inorganic-organic hybrid materials, 318 Chemical property-surface relationship, inorganic-organic hybrid coatings for metal and glass surfaces, 338-346 Chemically bonded organic-inorganic hybrids applications, 235 mechanical properties, 234/,235 structure, 231,233-235 synthesis using sol-gel process, 231,233-235 Clay mineral, candidate for polymer additive, 55 Clay-nylon 6 hybrid, 55-62 Clay-polymer hybrids nylon 6-clay hybrid, 55-62 rubber-clay hybrid, 61,63-65 Clay-rubber hybrid, 61,63-65 Coatings for metal and glass surfaces, 331-346



366


Colloidal crystals of silica, solidification, 181-190 Colloidal 3-(trimethoxysilyl)propyl methacrylate-silica particles, solidification, 184 Composite(s) advanced, surface modification of carbon fibers, 348-360 factors affecting properties, 86-87 reasons for development, 331 use of sol-gel process for synthesis, 86 See also Sol-gel-derived silica-siloxane composites Composite polymer(s), synthesis using emulsion polymerization process, 112 Composite polymer colloid nucleated by functionalized silica, 112-123 emulsion polymerization of ethyl aery late at silica surface, 115-119 experimental objective, 112-114 grafting process, 119-122/ inorganic material characteristics, 114-115,117/ mechanical properties, 121,123/124 Composite powders, observation by electron microscopy, 116-117 Condensation of phenyltriethoxysilane with catechol, synthesis of anionic pentacoordinate siliconate, 250 Conductive polymer-high transition temperature superconductor bilayers, morphology, 309-315 Coordination compounds, MPS materials in destruction-reconstruction intercalation mechanism, 31-32 Correlated systems, scattered, 102-107 Creep, polymer-filled glass, 170 Cross-linked siloxanes, structure, 264 Crystal(s) of silica, colloidal, solidification, 181-190 Crystalline ceramic oxides and oxide glasses, synthesis using sol-gel process, 226-227 Crystalline polymer matrix, organicinorganic hybrid composites, 6-17 3

Cubic oligosilsesquioxanes, formation, 265

D Depolymerization-polymerization of silica, synthesis of dianionic hexacoordinate siliconate, 249-250 Design of high-performance polymers for sol-gel processing, 282-290 Destruction-reconstruction intercalation mechanism involving heterogeneous equilibria, 31-32 Dianionic hexacoordinate siliconate, synthesis, 249-250 Diene polymer(s), metal-olefin coordination, 193-206 Diene polymer-bis(acetonitrile) dichloropalladium(II)-solvent system, isothermal ternary phase diagrams, 196-200 Differential scanning calorimetry, characterization of grafting process for polymers, 121,122/ Diyne polymerization, organizational requirements, 211-212,214 Dry gels, description, 200 Dynamic mechanical spectrometry, characterization of grafting process for polymers, 121,122/

Ε Elastic moduli, solid films from ternary solutions, 203-206 Elastic properties, organic-inorganic hybrid composites with crystalline polymer matrix, 12,14-16/ Electrical properties design of nanocomposites, 29-40 organic-inorganic hybrid composites, 3 Electron diffraction, magnetoferritin, 20,27 Electron microscopy, observation of composite powders, 116-117


367


INDEX

Electron spectroscopy for chemical analysis of oxidized fibers, surface modification of carbon fibers for advanced composite materials, 355-356 Electrooptic modulators, nonlinear optical materials using organic-inorganic composites, 325-326 Electrophoresis, magnetoferritin, 25-27 Emulsion polymerization of ethyl acrylate at silica surface encapsulation state, 115-116 kinetics, 118-119 observation of composite powders by electron microscopy, 116-117 polymerization results, 115-116 Emulsion polymerization process, advantages for composite polymer synthesis, 112 Entrapped organic hybrids applications, 229-232/ properties, 229,231 structure, 231,232/ synthesis using sol-gel process, 229 Epoxy cross-linked thermoplastic sealant, structural model, 336,338/ Ethyl acrylate, emulsion polymerization at silica surface, 115-119 Exfoliation-adsorption method of synthesis, poly(ethylene oxide)layered solid nanocomposites, 45

Ferrimagnetic model, M P S intercalates, 34-37 Ferrimagnetic nanocomposite, synthesis, inorganic-protein interactions, 19-28 Ferritin, advantages for nanocomposite material synthesis, 19-20 Fiber-filled composites, properties, 6-7 Form factor, definition, 103-104 Formic acid, use as alternative nonaqueous medium for sol-gel chemistry, 163-164 3

Fractal approaches, description, 97 Free radical copolymerization method, synthesis of alkoxysilyl-containing polymer precursors, 128-129 Functionalized silica, nucleation of composite polymer colloid, 112-124

γ-radiation, effect on properties of organic-inorganic hybrid interpenetrating networks, 146-151 Gelation in polymeric systems, 193 Glass, polymer filled, See Polymer-filled glass Glass fibers, properties, 7 Glass surfaces, inorganic-organic hybrid coatings, 331-346 Grafting process for polymers characterization, 121,122/ kinetics, 120-121 polymer extraction, 119-120 Group-transfer polymerization, synthesis of polyacrylate precursors, 128

Η Hexylene- and phenylene-bridged polysiloxane network materials, 264-278 experimental procedure, 267 future studies, 277 monomer synthesis, 269-270 polymerization procedures, 268-269 scanning electron microscopy, 275,276/ sol-gel polymerizations, 270 solid-state C - N M R spectroscopy, 272,273/ solid-state Si-NMR spectroscopy, 272,274/275 surface area analysis, 275 synthetic procedures, 267-268 thermal analysis, 275 13

29



368


High-clarity polyamide-silica hybrid materials, 291-296 applications, 296 elongation vs. silica content, 294-295 experimental procedure, 292 stress-strain curves, 292,293/ tensile break strength vs. silica content, 293-294 tensile yield strength vs. silica content, 293-294 transparency of films, 292,293/ water absorption, 294-296 yield stress vs. storage time, 294,296/ High-performance polymers for sol-gel processing, structural design, 280-290 High-temperature polymers, problems, 3 High transition temperature-conductive polymer superconductor bilayers, morphology, 308-315 Highly ordered pyrolytic graphite, oxidation, 358,359/ Hybrid coatings for metal and glass surfaces, inorganic-organic, 332-346 Hybrid interpenetrating networks, organic-inorganic, 145-160 Hybrid materials organic-inorganic, See Organicinorganic hybrid composites polybenzoxazole-silica, 297-305 vinyl polymer modified, 130-139 Hydrolytic stability, inorganic-organic hybrid coatings for metal and glass surfaces, 339-340 Hydrophobically shelled nanoparticles, production, 67,68/ Hydroxyl-terminated polydimethylsiloxane-tetraethoxysilane system, one- and two-step syntheses, 105-110 Hypervalent spiro polysiliconate and polygermylate ionomers, 248-262 alternative counterion polysiliconate characterization, 258-259 applications, 249 development, 249-251 experimental description, 249

Hypervalent spiro polysiliconate and polygermylate ionomers—Continued future studies, 261 monomer synthesis, 253-254 polygermylate characterization, 260-261 synthesis, 259-260 polysiliconate characterization, 254-258 preparation strategy, 252 previous studies, 252-253

Impregnated organic-inorganic hybrid composites applications, 229 mechanical properties, 227,229,230i structure, 227,229 synthesis using sol-gel process, 227 In situ grown silicon oxide nanoparticles, organic modification of surfaces, 66-82 Inorganic- and organic-polymer hybrid composites, 181 Inorganic constituent of hybrid materials, synthesis using sol-gel chemistry, 163 Inorganic-organic hybrid coatings for metal and glass surfaces adhesion of metal oils to polyimide, 332-338 boehmite-epoxysilane mixture, 343-345 experimental description, 331 hydrolytic stability, 339-340 metal amount vs. silane formation, 341,342/ perfluorinated groupings vs. adhesion, 342-343 scratch resistance, 345-346 structure of metal oxide, 341-342 surface-chemical properties, 338-346 surface-mechanical properties, 338-346 Inorganic-organic hybrid composites, See Organic-inorganic hybrid composites Inorganic-organic hybrid composites synthesized using simultaneous processes, nanostructured, 89-96


369


INDEX

Inorganic-organic hybrid interpenetrating networks, 145-160 Inorganic-organic hybrid silica materials, 210-221 Inorganic oxide-perfluorosulfonate ionomer nanocomposites, 67-81 Inorganic-polymer networks, synthesis, 164 Inorganic-protein interactions in ferrimagnetic nanocomposite synthesis, characterization of magnetoferritin, 20-28 Intercalation chemistry, development, 29 Interfacial properties, organic-inorganic hybrid composites, 3 Intermolecular interactions, solid formation control, 221-224 Interpenetrating networks organic-inorganic hybrid, 145-160 route to polymer-filled glass, 163-179 Interphase bonding, polymer-filled glass, 170,172,173/ Ion-exchange intercalation into M P S layered compounds, 29^11 cation-transfer intercalation chemistry of M P S layered compounds, 30-31 experimental description, 29 ferrimagnetic model of M P S intercalates, 34-37 magnetic properties of MPS intercalates, 33-34,35/ Mn PS [(dimethylamino)-A^-methylstilbazolium cation] , 40 molecular metal synthesis, 37-38 M P S layered compounds, 29-30 optical properties of M P S intercalates, 38-40 Iron biomineralization, mechanism, 19 Isothermal ternary phase diagrams for diene polymer-bis(acetonitrile) dichloropalladium(II)-solvent system examples, 196,197/ palladium(II) salt concentration vs. sol-gel properties, 198,200 polymer molecular weight vs. sol-gel properties, 198,199/ solvent effects, 196-198,200* 3

Κ K C 1 0 - H S 0 , chemical safety, 358,360 3

2

4

L Ladder materials, synthesis and characterization, 248-261 Ladder structures, examples, 3 Langevin magnetization function, definition, 25 Layered solid-poly(ethylene oxide) nanocomposites, 43^47 Linear siloxane, structure, 264 Liquid colloidal optical rejection filters, development, 181-182 Lij3oly(ethylene oxide)^Mo0 elemental analysis and synthesis, 53 Ly)oly(ethylene oxide)^MoS , thermal analysis, 48-50 Loading, sol-gel-derived silica-siloxane composites, 240,242-245 3

2

3

M

3

3

086

3

028

3

3

Macroscopic stiffness for entire network, definition, 204 Magnetic properties design of nanocomposites, 29-40 magnetoferritin, 25,26/ Magnetoferritin characterization, 20-27 magnetic properties vs. structure, 27-28 Mechanical properties chemically bonded organic-inorganic hybrids, 234i,235 impregnated organic-inorganic hybrid composites, 227,229,230i organic-inorganic hybrid composites, 7-9 polybenzoxazole-silica hybrid materials, 303,304-305/ Mechanical property-surface relationship, inorganic-organic hybrid coatings for metal and glass surfaces, 338-346


370


Melt processing of hybrids, feasibility, 17 Metal foil-polyimide adhesive materials brittleness of sealing medium, 332-333 peel strength vs. composition, 336,337/ requirements, 333 S i - N M R spectroscopy, 334-336 structural model, 336,338/ synthesis, 333-335 wetting behavior, 332-333 Metal-olefin coordination in diene polymers, 192-207 experimental procedure, 193-195 future studies, 206 isothermal ternary phase diagrams, 196-200 previous studies, 193 properties of solid films obtained from ternary solutions, 200-206 sol-gel phase transition, 195-196 Metal surfaces, inorganic-organic hybrid coatings, 331-346 Mn PS [(dimethylamino)-A^-methyl stilbazolium cation] , magnetic properties, 40 Modulus, polymer-filled glass, 166-169/ Molecular magnets, synthesis, 33 Molecular metals, synthesis using ion-exchange intercalation into M P S layered compounds, 37-38 Molecular-weight dependence, sol-gel-derived silica-siloxane composites, 238-240 Monodisperse colloidal polymer particles, light transmission, 181 Montmorillonite, swelling behavior with ω-amino acid, 56-58 Morphology conductive polymer-high-Γ superconductor bilayers, 308-315 device fabrication procedures, 309-311 experimental description, 308 future work, 315 influencing factors, 315 poly(3-hexylthiophene), 313-314 polypyrrole, 311-313 polymer-filled glass, 170-173


29

086

3

02 8

3

Môssbauer spectroscopy, magnetoferritin, 20,23-25,27 MPS intercalates ferrimagnetic model, 34-37 magnetic properties, 33-35/ optical intercalates, 38 synthesis, 33 use for molecular metal synthesis, 37-38 M P S layered compounds cation-transfer intercalation chemistry, 30-31 destruction-reconstruction intercalation mechanism, 31-32 intercalation of soluble polymers, 32-33 ion-exchange intercalation, 29-40 reactivity, 30 schematic representation, 29-30 Multiple size scale structures in silica-siloxane composites studied by small-angle scattering, 97-110 accounting for multiple structural levels, 98-102 correlated systems, 102-107 one- vs. two-step synthesis, 105-110 unified equation for small-angle scattering, 98 Multiple structural levels, accounting, 98-102 MjDolyiethylene oxide)^TiS electrical measurements, 51,53 exfoliation in 7V-methylformamide, 51,52/ synthesis, 50-51 thermal measurements, 51 3

3

2

Ν Nanocomposite(s) ferrimagnetic, inorganic-protein interactions in synthesis, 19-28 (perfluorosulfonate ionomer)-(inorganic oxide), 66-82 poly(ethylene oxide)-layered solid, 43-53 polymer containing, 44-45


371


INDEX

Nanocomposite(s)—Continued with unusual magnetic, electrical, and nonlinear optical properties, 2

Affiliation Index

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