ANALYTICAL CHEMISTRY and the MICROCHIP - American Chemical

tronics industry has packed ever-in- creasing amounts of computing power into ever-smaller geometries on inte- grated circuit (IC) chips. Electronics ...
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Report Robert Κ. Lowry Harris Semiconductor Melbourne, Fla. 32901

ANALYTICAL

CHEMISTRY and the

MICROCHIP

Figure 1. Wafer of digital-to-analog converter circuits 0003-2700/85/0357-023A$01.50/0 © 1985 American Chemical Society

During the past two decades our business and personal lives have been truly revolutionized by microelectron­ ic computing devices. The microelec­ tronics industry has packed ever-in­ creasing amounts of computing power into ever-smaller geometries on inte­ grated circuit (IC) chips. Electronics engineers continue to conceive, design, and assemble into powerful systems increasingly sophisticated microcom­ puting devices. An integrated circuit is an intercon­ nected array of electronically active and passive components, built in and on a single semiconducting substrate. The substrate for the majority of to­ day's ICs is pure, single-crystal silicon containing controlled levels of dop­ ants. Dopants provide charge carriers to render specific spatial regions of the silicon lattice semiconducting. Dop­ ants such as pentavalent phosphorus (>4 valence electrons) occupying lat­ tice sites, produce silicon that con­ ducts by negative charge, i.e., n-type semiconductors. Similarly, dopants such as trivalent boron (