Carbon(13) monoxide exchange reactions of metal-carbene

Jan 1, 1982 - Charles P. Casey, Mark C. Cesa. Organometallics , 1982, 1 (1), pp 87–94. DOI: 10.1021/om00061a016. Publication Date: January 1982...
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Organometallics 1982, 1, 87-94 P

Figure 5. Competition for a density along the z axis in the symmetrical va. sodium ion perturbed PV(CO)5-. problems are complex and the salient features only are reported here. The displacement of PPh3 from V(C0)5PPh3- was determined to be independent of entering ligand concentration (Table 111) and showed a first-order dependence on the vanadium complex (eq 1and 2). Carbon monoxide

rate = k,[PV(CO)