Covalently Coupled Ultrafine H-TiO2 Nanocrystals ... - ACS Publications

Jul 27, 2015 - Shuhua Yang, Yuan Lin, Xuefeng Song,* Peng Zhang, and Lian Gao*. State Key Laboratory for Metallic Matrix Composite Materials, School o...
0 downloads 0 Views 3MB Size
Page 1 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

Covalently coupled ultrafine H-TiO2 nanocrystals/nitrogen-doped

2

graphene hybrid materials for high-performance supercapacitor

3 4

Shuhua Yang, Yuan Lin, Xuefeng Song,* Peng Zhang and Lian Gao*

5

State Key Laboratory for Metallic Matrix Composite Materials,

6

School of Materials Science and Engineering,

7

Shanghai Jiao Tong University, Shanghai, 200240, China.

8

9

Corresponding author:

10

Tel: +86-21-52412718; Fax: +86-21-52413122.

11

E-mail address: [email protected] (L.G.); [email protected] (X.S.).

12 13 14

KEYWORDS: nitrogen-doped graphene, ultrafine TiO2 nanocrystals, hydrogenation,

15

covalent chemical bond, high capacity, supercapacitor

16 17 18 19 20 21 22 1 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

ABSTRACT

2

Hydrogenated TiO2 (H-TiO2) are considered one of the most promising materials for

3

supercapacitors given its low-cost, high conductivity, and enhanced electrochemical

4

activity. However, the electrochemical performances of H-TiO2 due to lacking suitable

5

structures is unsatisfactory, and thus how to design energetic H-TiO2-based electrode

6

architectures still remains a great challenge. Herein, covalently coupled ultrafine H-TiO2

7

nanocrystals/nitrogen-doped graphene (H-TiO2/NG) hybrid materials were developed

8

through a simple hydrothermal route followed by hydrogenation. Within this architecture,

9

the strong interaction between H-TiO2 nanocrystals and NG sheets via covalent chemical

10

bonding affords high structural stability inhibiting the aggregation of H-TiO2 nanocrystals.

11

Meanwhile, the NG matrices functions as an electrical highway and a mechanical

12

backbone so that most of well-dispersed ultrafine H-TiO2 nanocrystals are

13

electrochemically active but stable. As a result, the optimized H-TiO2/NG (H-TiO2/NG-B)

14

exhibited high reversible specific capacity of 385.2 F g-1 at 1 A g-1, enhanced rate

15

performance of 320.1 F g-1 at a high current density of 10 A g-1, and excellent cycling

16

stability with 98.8% capacity retention.

17 18

1. INTRODUCTION

19

Supercapacitors (SCs) are considered to be a promising green energy storage

20

technology filling the gap between a battery and a traditional capacitor on the basis of

21

both energy and power densities. Based on charge storage mechanisms, supercapacitors

22

store charge by either rapid adsorption/desorption at the electrode surfaces (electric

23

double layer capacitors) or Faradaic reactions on electrode materials (pseudocapacitors).

24

Typically, pseudocapacitors based on transition metal oxides, hydroxides and conducting

25

polymers usually show higher capacitance through surface redox reactions than electric

26

double layer capacitors (EDLCs) using carbon-based materials.1-5

27

Among various pseudocapacitance materials, TiO2 has received special interest for 2 / 26

ACS Paragon Plus Environment

Page 2 of 26

Page 3 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

supercapacitors because of their low cost, excellent chemical stability, abundance in

2

nature, and minimum environmental impact.6, 7 However, the semiconducting nature of

3

TiO2 limits the electrical conductivity and impedes fast electron transport toward high

4

rate capability, and thus shows poor electrochemical stability and low rate capability. For

5

this problem, a mount of efforts have been focused on developing three-dimensional (3D)

6

architectures (for example, nanotube arrays) with sufficient open structures to overcome

7

the low ion diffusion coefficient and provide a direct pathway for charge transport in

8

TiO2-based supercapacitors.7-11 More recently, a substantial improvement of the

9

capacitive performance for one-dimensional anodic titanium oxide (ATO) nanotube

10

arrays was realized through hydrogenation, which is ascribed to the enhanced electrode

11

conductivity and electrochemical activity associated with the effective hydrogen induced

12

Ti3+ sites in TiO2 lattices.7, 8, 12, 13 However, one-dimensional ATO nanotube arrays yield

13

much lower volumetric density than nanopowders, and suffer from low production for

14

practical applications. In addition, it is well known that the Ti substrate is susceptible to

15

hydrogen embrittlement, and thus the ATO nanotube arrays will be peeled off from the

16

substrate during the H2 annealing process. Moreover, fabricating TiO2/carbon hybrids

17

(e.g., TiO2/carbon nanotube, TiO2/graphene) also offers another way to improve the

18

capacitance of supercapacitors due to the high specific surface area and good

19

conductivity of carbon materials.6, 14-18 Although the electrochemical performances of

20

those composites are improved by combining the merits of both components and

21

mitigating the shortcomings of each component, those composites still suffer from low

22

capacitances in the range of 100-200 Fg-1 and poor rate capability under various aqueous

23

and non-aqueous electrolytes.6,

24

supercapacitors development, it is highly desirable to fundamentally improve the rate

25

capability and capacitive behavior of electrodes through changing the intrinsic properties

26

of both TiO2 and carbon materials. Moreover, to the best of our knowledge, the exact

27

interaction mechanism between TiO2 and carbon materials remains poorly understood.

14-17, 19

Therefore, to further push the TiO2-based

3 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 4 of 26

1

This subject has been largely overlooked by the researchers. Graphene, which is

2

composed of one atom thick sp2 carbon network, is recently becoming one of the most

3

promising matrices for metal oxides due to its unique properties, such as excellent

4

electrical properties, high surface area over 2600 m2 g-1, and excellent mechanical

5

flexibility.

6

supercapacitors has shown great promise for industrial applications due to high accessible

7

surface area, good electrical conductivity, enhanced electrochemical properties, and the

8

low-cost raw material.20-24 Inspired from our recent demonstration that nitrogen doping is

9

one of the most effective methods to tailor the electronic properties of graphene-based

Particularly,

chemically

modified

graphene

(CMG)

nanosheets

in

10

materials and to improve the electrochemical performances for supercapacitors,25,

26

11

loading well-dispersed hydrogenated TiO2 nanocrystals on nitrogen-doped graphene

12

could address aforementioned limitations and thus improve the specific capacitance and

13

stability of TiO2 materials, as well as the rate capability.

14

Here, the hydrogenated TiO2 nanocrystals/nitrogen-doped graphene (H-TiO2/NG)

15

hybrids were successfully synthesized via a two-step method for the first time. The

16

interaction between H-TiO2 nanocrystals and NG sheets was explored. Within Such

17

architecture, (1) the strong interaction between H-TiO2 nanocrystals and NG sheets via

18

covalent chemical bonding affords high structural stability inhibiting the aggregation of

19

H-TiO2 nanocrystals, which is key to both the excellent cycling stability and high rate

20

capability; (2) the hydrogenation fundamentally modifies the electric conductivity and the

21

electrochemical activity of TiO2 nanocrystals by introducing oxygen vacancies (Ti3+ sites)

22

in TiO2 lattices; (3) the NG matrices function as an electronic highway and a mechanical

23

backbone so that most of H-TiO2 nanocrystals are electrochemically active but stable

24

through the NG network; (4) the well-dispersed ultrafine TiO2 nanocrystals (5-10 nm) on

25

the NG sheets with little dead volume and large specific surface area are advantageous

26

for the electrochemical utilization of TiO2 active materials and offer a direct short

27

pathway for electrolyte ions diffusion. To the best of our knowledge, the electrical 4 / 26

ACS Paragon Plus Environment

Page 5 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

conductivity and capacitive behavior of H-TiO2/NG hybrids are fundamentally improved

2

for supercapacitors through changing the intrinsic properties of both TiO2 and graphene,

3

which is significantly distinct from previously reported TiO2-based hybrid nanostructures

4

simply by changing the morphologies of TiO2, the categories of carbon materials, or

5

combination mode of the both components. Furthermore, this hybrids exhibit excellent

6

electrochemical characteristics and high cycling stability, and thus hold great potential as

7

electrode materials for high-performance supercapacitors when compared to their

8

counterparts.

9

EXPERIMENTAL SECTION

10

Synthesis of H-TiO2/NG. Graphene oxide was synthesized from natural flake graphite

11

(Alfa Aesar, 325 mesh, 99.8%) according to the modified Hummers method, which

12

typically renders carbon concentrations of ~65 weight percent (wt%).27 Then a certain

13

amount of titanium bis (ammonium lactate) dihydroxide (TALH) aqueous solution (50%)

14

and 20 mL of graphene oxide dispersion (2.5 mg mL-1) were mixed with 0.1 g of urea.

15

After being stirred for 15 min, the resulting solution was sealed into a 50 mL Teflon-lined

16

stainless steel autoclave and heated at 160 °C for 24 h. After reaction, the autoclave was

17

naturally cooled in air. The as-prepared products (TiO2/NG hybrids) were separated by

18

centrifugation, washed with distilled water and ethanol several times, and dried at 60 °C

19

for 24 h. To prepare TiO2 nanocrystals (or TiO2/RGO hybrids), a similar procedure was

20

performed except addition of GO (or urea). The RGO (or NG) was also prepared by the

21

similar procedure without the addition of TALH and urea (or TALH). The H-TiO2/NG

22

hybrids, H-TiO2/RGO hybrids, and H-TiO2 nanocrystals were obtained by annealing the

23

corresponding samples at 400°C for 1 h in Ar/H2 (5 wt% H2) mixed atmosphere. Here,

24

three kinds of H-TiO2/NG hybrids with different ratios between H-TiO2 and NG were

25

synthesized. The contents of H-TiO2 in the H-TiO2/NG hybrids are 50.3 wt%, 88.7 wt%,

26

and 92.5 wt% (evaluated from TGA); the corresponding samples are referred to as

27

H-TiO2/NG-A, H-TiO2/NG-B, and H-TiO2/NG-C, respectively. For the sample with 5 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

optimum ratio of H-TiO2 in hybrids, the corresponding counterparts are denoted as

2

TiO2/NG-B, H-TiO2/RGO-B.

3

Material characterization. X-ray diffraction (XRD) patterns of the samples were

4

collected on a Goniometer Ultima IV (185 mm) diffractometer with Cu Kα radiation (λ=

5

1.5418 Å) at a step of 0.02° per second. The morphology and microstructure of the

6

as-prepared products were examined by a JEOL JEM-2010F 200 kV transmission

7

electron microscope. Fourier transform infrared (FTIR) spectra were taken with a Nicolet

8

6700 FTIR spectrometer. Raman spectra were carried out using a DXR Raman

9

Microscope with an excitation length of 532 nm. X-ray photoelectron spectroscopy (XPS,

10

Kratos AXIS Ultra DLD spectrometer) was used for determining the composition and

11

chemical/oxidation state of the samples. A commercial CasaXPS 2.3.16 software package

12

was used to process XPS spectra. In our case, the C 1s peak with a fixed value of

13

284.8 eV was used to calibrate all the binding energies for the prepared samples. For the

14

narrow spectra, they were fitted by the combination of Gaussian and Lorentzian functions

15

after removal of the Shirley backgrounds. Thermogravimetric analyses (TGA) and

16

differential thermogravimetric (DTG) curves were run on a SDT Q600 V20.9 Build 20

17

thermogravimetric analyzer at a heating rate of 10 °C min-1 from 50 to 850 °C in air.

18

Electrochemical measurements. The electrochemical properties of the samples were

19

investigated under a three-electrode cell configuration in a 1 M KOH solution using a

20

VMP3 multi-functional electrochemical analysis instrument (Bio-Logic, France). The

21

working electrodes were fabricated by mixing 80 wt% active material, 15 wt% acetylene

22

black and 5 wt% polyvinylidene difluoride (PVDF) in N-methyl pyrrolidone (NMP)

23

solvent. The resulting slurry was then loaded onto the nickel foam substrate (1 cm ×1 cm)

24

and dried at 60 °C overnight. Finally, the electrode was pressed under a pressure of 10

25

MPa. Typically, the loading mass of active material (H-TiO2/NG) on each current

26

collector was around 3.1 mg, which was acquired by measuring electrode with a

27

microbalance with accuracy of 0.01 mg. Platinum foil (1 cm×1 cm) and an Ag/AgCl 6 / 26

ACS Paragon Plus Environment

Page 6 of 26

Page 7 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

electrode were used as the counter and reference electrode, respectively. The cyclic

2

voltammograms were recorded in a voltage range from -0.05 to 0.5 V at different

3

scanning rates. The cyclic galvanostatic charge/discharge curves were obtained within a

4

potential window of -0.05 to 0.45 V at different current densities. The electrochemical

5

impedance spectroscopy (EIS) was measured at open circuit potential with an Ac

6

perturbation of 5 mV in the frequency range of 100 kHz to 0.01 Hz.

7 8 9

Specific capacitances of single electrode in a three-electrode system were calculated from charge/discharge curves by the following equation:25 Cs=(I×∆t)/(m×∆V)

(1)

10

where Cs (F g−1) is specific capacitance of the electrode, I (A) corresponds to the

11

discharge current, ∆V (V) is the potential change within the discharge time ∆t (s), and m

12

(g) represents the mass of active material (H-TiO2/NG).

13

RESULTS AND DISCUSSION

14

Microstructure characterizations. The formation process of H-TiO2/NG hybrids is

15

schematically illustrated in Scheme 1. Firstly, as shown in our previous studies,27 GO

16

sheets have numerous oxygen-containing groups on their basal planes and edges, which

17

act as anchoring sites for the in situ formation of TiO2 nanocrystals on the surfaces and

18

edges of GO sheets by hydrothermal process in the presence of urea. Subsequently, the

19

TiO2 nanocrystals on the surfaces and edges of GO sheets were converted to H-TiO2 by

20

an annealing in Ar/H2 (5 wt % H2) mixed atmosphere.

21

A general view of H-TiO2/NG hybrids is shown in Figure 1 and Figure S1 (Supporting

22

Information). It can be seen that H-TiO2/NG-B presents optimal morphology. Higher

23

amount of H-TiO2 than 88.7 wt% in hybrids can generate agglomerates of nanoparticles

24

on the surface of graphene. Therefore, the corresponding optimal samples (H-TiO2/NG-B,

25

TiO2/NG-B, and H-TiO2/RGO-B) were selected and discussed below. As shown in Figure

26

1a, b and Figure S2 (Supporting Information), H-TiO2 nanocrystals are homogeneously

27

anchored on the surface of graphene sheets. Although the nanocrystals on graphene 7 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

sheets have a high density, parts of the graphene sheets are still exposed (Figure 1a, b),

2

which is critical for maintaining good contact between individual graphene sheets for

3

high electrical conductivity.28 In the course of hydrothermal reaction, oxygen-containing

4

functional groups on graphene acting as the heterogeneous nucleation sites can anchor

5

TiO2 nanocrystals on dispersed active sites so that the agglomeration of these ultrafine

6

nanocrystals can be avoided.29 Transmission electron microscopy (TEM) studies

7

demonstrate that there are no obvious morphological changes for TiO2 nanocrystals after

8

annealing under hydrogen atmosphere and the dispersion of the nanocrystals on the

9

graphene sheet is well preserved, while the TiO2 nanocrystals in situ transform to H-TiO2

10

nanocrystals (Figure S3 in the Supporting Information). This result confirms that

11

as-prepared TiO2 nanocrystals on graphene sheets are stable during high temperature

12

hydrogenation. As evidenced from the high-magnification TEM image (Figure 1c), the

13

ultrafine H-TiO2 nanocrystals have typical size of 5-10 nm (as indicated by circles in

14

Figure 1c). Such ultrafine nanocrystals are supposed to have more active exposed faces

15

for electrochemical reactions.26 The high-resolution transmission electron microscopy

16

(HRTEM) image (Figure 1d) shows highly crystalline TiO2 nanoparticles with an

17

interlayer distance of 0.35 nm, which is in accordance with the (101) plane of anatase

18

phase TiO2. Moreover, the edge of graphene can be clearly observed as indicated by the

19

arrow (Figure 1d and Figure S4 in the Supporting Information). Compared with

20

multilayered graphene, the few-layer graphene with less agglomeration should be

21

expected to exhibit higher effective surface area and thus better supercapacitor

22

performance.30 It is worth noting that the H-TiO2 nanocrystals are still strongly connected

23

with NG sheets even after long time sonication, suggesting a strong interaction between

24

H-TiO2 nanocrystals and NG sheets, which enables rapid electron transport through the

25

underlying NG sheets to H-TiO2 nanocrystals, and then results in superior rate capability.

26 27 8 / 26

ACS Paragon Plus Environment

Page 8 of 26

Page 9 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1 2

Scheme1. Schematic illustration of the formation process of H-TiO2/NG hybrids.

3

4 5

Figure 1. (a) TEM image, (b) Zoom-in TEM image, and (c, d) HRTEM images of

6

H-TiO2/NG-B hybrids. 9 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1 2

Figure 2. (a) XRD patterns of the H-TiO2/NG-B, RGO, and NG, (b) Raman spectra of

3

H-TiO2/NG-B hybrids, H-TiO2, and NG, (c) Fourier transform infrared spectra of

4

H-TiO2/NG-B hybrids and RGO, (d) TGA and DTG curves of TiO2/NG-B hybrids.

5 6

Figure 2a shows the typical X-ray diffraction (XRD) pattern of the H-TiO2/NG-B,

7

RGO, and NG. For H-TiO2/NG-B, all of the peaks can be indexed as the tetragonal

8

anatase phase (JCPDS 21-1272). No obvious diffraction peaks for carbon species were

9

observed, indicating that highly disordered and few-layer graphene sheets are in the

10

H-TiO2/NG-B hybrids because the H-TiO2 nanocrystals on graphene sheets effectively

11

prevent the graphene sheets from restacking and agglomeration. This is also consistent

12

with the result from TEM images. Raman spectroscopy was employed to analyze the

13

local structure of the H-TiO2/NG-B hybrids. As observed in Figure 2b, the Raman

14

spectrum of NG shows the typical G-band at 1349 cm-1 and D-band at 1575.5 cm-1.26 The 10 / 26

ACS Paragon Plus Environment

Page 10 of 26

Page 11 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

G-band originates from the Raman-active E2g mode, whereas the D-band is associated

2

with disordered graphene.20 The G-band and D-band in as-synthesized H-TiO2/NG-B

3

hybrids are similar to those of NG, whereas the four bands located at around 154 (Eg(1)),

4

392 (B1g(1)), 513 (A1g + B1g(2)), and 628 cm-1 (Eg(2)) are characteristic for typical anatase

5

TiO2 (Figure 2b).31 The results confirm that NG sheets are decorated with the H-TiO2

6

nanocrystals. In addition, a higher intensity ratio of the D band to G band was found in

7

NG (ID/IG=1.04) and H-TiO2/NG-B (ID/IG=1.11) compared with graphene (ID/IG =0.66)

8

prepared by hydrothermal reduction of GO by our group,25 indicating a high

9

concentration of structure defects exist on the surface of graphene. It has been well

10

established that the defects of graphene can provide abundant active sites for more

11

electrons storage, which can greatly enhance the capacity of the composites for

12

supercapacitors.24, 25 The active peak for the Eg(1) mode of anatase shifts towards high

13

frequency (from 146 cm-1 for H-TiO2 to 154 cm-1 for H-TiO2/NG-B), which is attributed

14

to the electronic interactions between H-TiO2 and NG.29 Strong interaction may facilitate

15

fast electron transportation between H-TiO2 and NG, quicken diffusion kinetics, and thus

16

improve the rate capability. Fourier transform infrared (FTIR) spectroscopy further

17

corroborated the covalent chemical bond between H-TiO2 and NG (Figure 2c). The FTIR

18

spectrum of reduced graphene oxide (RGO) obtained by hydrothermal reduction clearly

19

showed the characteristic peaks for C=O stretching vibration of the residual COOH

20

groups (1731 cm-1), O-H deformation vibration (1429 cm-1), C-O vibration of the carboxy

21

(1263 cm-1), and C-O-C vibration of the epoxy (1051 cm-1), respectively.27 For

22

H-TiO2/NG-B, the broad absorption at low frequency (400-900 cm-1) was much plumper

23

than the corresponding peak in H-TiO2 and shifted toward high wavenumber (from 466 to

24

478 cm-1), which was attributed to a combination of Ti-O-Ti vibration and Ti-O-C

25

vibration (Figure S5a in the Supporting Information).32-34 Besides, no peaks relating to

26

the C=O, O-H, C-OH, and C-O-C groups could be observed, while the absorption band

27

(ca. 1570 cm-1) for the graphene sheets still retain, also indicating the epoxy C-O and 11 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

hydroxyl O-H groups have been broken down to form a Ti-O-C covalent bond between

2

graphene and TiO2 nanocrystals. Moreover, a broad peak at 1184 cm-1 for N-C bonds

3

appeared, indicating the formation of NG during the hydrothermal reaction.35 The amount

4

of TiO2 in TiO2/NG-B hybrids was determined by thermal-gravimetric measurements.

5

Based on the differential thermogravimetric (DTG) curve in Figure 2d, the weight loss in

6

the temperature range of 50~ 200 °C was due to the removal of the adsorbed water and

7

the residual oxygen groups on the surface of graphene, whereas the weight loss at about

8

470.8 °C was attributed to the burning of the carbon skeleton of graphene.27, 36 According

9

to thermogravimetric analysis (TGA) in Figure 2d, the TiO2 accounts for 88.6 wt% in the

10

TiO2/NG-B hybrids, which agrees with the theoretical proportion of TiO2 (91.1 wt %)

11

resulting from experimental design. This results indicate that the TiO2 nanocrystals

12

anchored on the surface of graphene sheets through in-situ growth.37 In addition, the

13

content of H-TiO2 in the H-TiO2/NG-B hybrids and H-TiO2/RGO-B hybrids was also

14

determined by thermal-gravimetric measurements (Figure S5b in the Supporting

15

Information). It can be seen that the H-TiO2 contents in the H-TiO2/NG-B hybrids (88.7

16

wt%) and H-TiO2/RGO-B hybrids (88.5 wt%) are almost same, which is also in accord

17

with the TiO2 contents in the TiO2/NG-B hybrids (88.6 wt%).

12 / 26

ACS Paragon Plus Environment

Page 12 of 26

Page 13 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1 2

Figure 3. (a) the narrow spectra of N 1s (the inset shows the nitrogen bonding

3

configurations in NG), (b) the narrow spectra of C 1s, (c) the narrow spectra of Ti 2p, (d)

4

the narrow spectra of O 1s for H-TiO2/NG-B hybrids.

5 6

To investigate the composition and the chemical bonding environment in the

7

H-TiO2/NG-B hybrids, the X-ray photoelectron spectroscopy (XPS) measurements were

8

carried out. The XPS revealed the presence of the principal C, Ti, O, and N elements, and

9

2.39 at% nitrogen in H-TiO2/NG-B hybrids (Figure S6a in the Supporting Information),

10

but no N element was detected in the H-TiO2/RGO-B sample made without urea (Figure

11

S6b in the Supporting Information). High resolution XPS spectra of the N peak revealed

12

pyridinic N (398.3 eV), pyrolic N (400.2 eV), and oxygenated N (402.4 eV) species in

13

H-TiO2/NG-B hybrids (Figure 3a). The nitrogen bonding configurations within the 13 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 14 of 26

1

graphene are illustrated in the inset of Figure 3a. The pyrolic N and the pyridinic N play a

2

crucial role in improving the electrochemical properties of graphene, which has been

3

demonstrated in our previous study.25, 26 For the high resolution C 1s peak, the main peak

4

centered at about 284.8 eV originated from the graphitic sp2 carbon atoms, whereas the

5

binding energies located at 286.3, 287.3 and 289.4 eV were attributed to epoxy (C-O),

6

carbonyl (C=O) and carboxylate (O-C=O) groups.38,

7

component centered at 285.6 eV due to the carbon bound to nitrogen (C-N /C=N) was

8

observed, which verified that N was successfully doped into the graphene.35, 36 In the

9

spectra of Ti 2p (Figure 4c), two broad peaks centered at 457.5 and 463.2 eV correspond

10

to the characteristic Ti 2p3/2 and Ti 2p1/2 peaks, which are typical of Ti3+ in an octahedral

11

environment,7 indicating the oxygen vacancies exist in H-TiO2 nanocrystals. This result

12

confirms the as-prepared TiO2 nanocrystals is hydrogenated TiO2. However, the

13

characteristic peak (396 eV) of the Ti-N-Ti linkages could not be observed, suggesting

14

that the nitrogen atoms did not dope into the TiO2 lattice.40 The high resolution O1s

15

spectrum exhibited that the intensity of peaks related to oxygenated groups in the

16

H-TiO2/NG-B hybrids was much lower than those of RGO gained from hydrothermal

17

reduction, suggesting a reaction between oxygenated groups and TiO2 nanocrystals

18

during the hydrothermal process (Figure S7 in the Supporting Information). Moreover,

19

the peak at around 531.2 eV is assigned to O in Ti-O-C covalent bond, while that at

20

approximately 530.5 eV is assigned to the bulk oxygen (O2-) in TiO2.41, 42 These results

21

further confirm the strong interaction between TiO2 and graphene through the formation

22

of Ti-O-C covalent bond, which is in agreement with the FTIR results.

39

Moreover, an additional

23 24

Electrochemical behaviours. The electrochemical properties of the H-TiO2/NG-B

25

hybrids were evaluated in a three-electrode electrochemical cell with a platinum foil (1

26

cm×1 cm) counter electrode and an Ag/AgCl reference electrode in 1M KOH aqueous

27

solution. Figure 4a shows the cyclic voltammograms (CV) of the H-TiO2/NG-B electrode 14 / 26

ACS Paragon Plus Environment

Page 15 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

collected at the scan rates of 5, 10, 20, 50 and 100 mV/s with potential windows ranging

2

from 0 to 0.5V. All the CV curves exhibit a pair of cathodic and anodic peaks, which

3

indicates the capacitance is mainly from the Faradic mechanism neglecting the

4

capacitance of the nickel foam substrate (Figure S8a in the Supporting Information).

5

Similar to the charge storage mechanism of the previous report,6 the redox peaks of the

6

H-TiO2/NG-B hybrids are attributed to the surface or subsurface intercalation and

7

deintercalation cation processes according to:

8 9

(TiO2)surface + M+ + e− ↔ (TiO2− M+)surface

(2)

where M can be H3O+ or K+ in the electrolyte.

10

Over the entire range of scan rates, the pair of redox peaks is nearly symmetrical,

11

revealing good reversibility of the redox reactions in the H-TiO2/NG-B electrode.11 When

12

the scan rate increases, the oxidation peaks shifted to a more positive position and the

13

reduction peaks to a more negative position, which results from an increase of the

14

internal diffusion resistance in the pseudoactive material. But, the peak current intensity

15

increases linearly with the scan rate, confirming the excellent kinetics of interfacial

16

faradic redox reactions and the rapid rates of electronic and ionic transport in the

17

H-TiO2/NG-B electrode (Figure S8b in the Supporting Information).11 Figure 4b presents

18

the typical galvanostatic charge/discharge (CD) curves of H-TiO2/NG-B electrode at

19

different current densities within a potential range of -0.05–0.45 V. Clearly, the discharge

20

curves exhibit two sections, a sudden potential drop and a slow potential decay. The first

21

potential drop is mainly due to the internal resistance, and the subsequent potential decay

22

represents the capacitive characteristics of the electrode. The obvious deviation of the

23

shape of the discharge curves from the straight lines indicates the Faradaic characteristics

24

of the charge storage, consistent with the CV results. The capacitance of the

25

H-TiO2/NG-B calculated from CD curves at a current density of 1 A g-1 is 385.2 F g-1.

26

Even at a high current density of 10 A g-1, it still delivers a capacitance of 320.1 F g-1,

27

indicating excellent rate capability (Figure S9a in the Supporting Information). This 15 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

result indicates a much improved capacity of the H-TiO2/NG-B hybrids compared with

2

previous studies for TiO2-based electrode, such as graphene/ALD TiO2 electrode (84

3

F/g),6 carbon/mesoporous TiO2(18.4 F/g),15 carbon nanotubes/TiO2 nanoparticles (180

4

F/g).16 In comparison with NG, pure H-TiO2, H-TiO2/NG-A, and H-TiO2/NG-C electrode,

5

the H-TiO2/NG-B electrode delivers significantly higher specific capacitance, indicating

6

a strong synergistic effect and optimum ratio between NG sheets and H-TiO2 nanocrystals

7

achieved (Figure S9b in the Supporting Information). The NG sheets provide an excellent

8

conductivity and more active sites, whereas the ultrafine H-TiO2 nanocrystals with

9

uniform dispersions can be substantially utilized during the electrochemical process. Thus,

10

the H-TiO2/NG-B with well-defined nanostructure can accelerate the electron transport

11

and facilitate the redox reactions in the whole electrode, significantly enhancing the

12

kinetic requirements for an ideal electrode material. The electrochemical performance of

13

the H-TiO2/NG-B electrode was further investigated by using electrochemical impedance

14

spectroscopy (EIS) (Figure 4c). The measured impedance spectra were analyzed using

15

the complex nonlinear least-squares (CNLS) fitting method on the basis of the equivalent

16

circuit (Figure 4c), where RS is solution resistance, CDL is double-layer capacitance, Wo is

17

the finite-length Warburg diffusion element, RCT is charge-transfer resistance, and CF is

18

the faradic capacitance. The impedance spectra can be classified into two regions,

19

including a semicircle at the higher frequency region and a straight line at the lower

20

frequency region. At high frequency, the intercept at the real axis represents the

21

equivalent series resistance (ESR), which is due to electric resistance of the electrode

22

materials and interface resistance. Compared with H-TiO2 electrode (1.52 Ω), the

23

H-TiO2/NG-B electrode displays a lower equivalent series resistance (0.71 Ω), indicating

24

an improved conductivity for H-TiO2/NG-B electrode due to the incorporation of NG. In

25

the lower frequency area, the straight line was determined by ion diffusion. For the

26

H-TiO2 electrode and the H-TiO2/NG-B electrode, the slope of the straight line associated

27

with H-TiO2/NG-B electrode was larger than H-TiO2 electrode and closer to the 16 / 26

ACS Paragon Plus Environment

Page 16 of 26

Page 17 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

imaginary impedance axis (Z''), which shows a lower diffusion resistance and an ideal

2

polarizable capacitance. As discussed above, we might conclude that the combination of

3

low equivalent series resistance and diffusion resistance is responsible for the excellent

4

electrochemical performance of the hybrid structure. Figure 4d reveals the cycle

5

performance of the H-TiO2/NG-B electrode measured at a high current density of 10 A g-1

6

for 50,000 cycles. The H-TiO2/NG-B still retains 98.8% of its initial capacitance after

7

50,000 cycles, demonstrating excellent stable cycling performance and a high level of

8

reversibility of H-TiO2/NG-B hybrids. Such performance is much better than TiO2-based

9

electrode reported previously,6,

17, 18

which can be attributed to the enhanced electric

10

conductivity and electrochemical activity of ultrafine H-TiO2 nanocrystals by introducing

11

oxygen vacancies (Ti3+ sites) in TiO2 lattices, the excellent electronic highway and

12

mechanical backbone provided by NG matrices, and the strong interaction between TiO2

13

nanocrystals and NG sheets via covalent chemical bonding.

14 17 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

Figure 4. (a) CV curves of the H-TiO2/NG-B hybrids at different scan rates, (b) CD

2

curves of the H-TiO2/NG-B hybrids at various current densities, (c) EIS of the

3

H-TiO2/NG-B hybrids and H-TiO2 nanocrystals (the insets show the enlarged EIS at the

4

high frequency region (bottom) and the electrical equivalent circuit used for fitting

5

impedance spectra (top).), (d) Cycle life of the H-TiO2/NG-B hybrids at 10 A g-1 by a

6

three-electrode configuration in 1M KOH aqueous solution.

7 8

To further demonstrate the remarkable capacitive properties of H-TiO2/NG-B hybrids

9

for supercapacitors, the CV and CD measurements of H-TiO2/RGO-B hybrids and

10

TiO2/NG-B hybrids were also carried out under the same test conditions for comparison.

11

Figure 5a shows the CV curves of the H-TiO2/NG-B, H-TiO2/RGO-B, and TiO2/NG-B

12

electrodes obtained at the scan rate of 50 mV s-1. It can be seen that the voltammetric

13

currents and curve areas of the H-TiO2/NG-B are much higher than those of

14

H-TiO2/RGO-B and TiO2/NG-B at the same scan rate. This clearly confirms that the

15

H-TiO2/NG-B electrodes are superlative among three pseudocapacitive electrodes.

16

Furthermore, the larger separation between leveled anodic and cathodic currents at the

17

same scan rates for the H-TiO2/NG-B electrode further confirmes its larger specific

18

capacitances. Figure 5b shows the CD curves of the H-TiO2/NG-B, H-TiO2/RGO-B, and

19

TiO2/NG-B electrodes at a current density of 1 A g-1. As expected, the H-TiO2/NG-B

20

hybrid electrode shows the longer charge-discharge time compared to those of

21

H-TiO2/RGO-B, and TiO2/NG-B electrodes. The specific capacitance of H-TiO2/NG-B,

22

H-TiO2/RGO-B, and TiO2/NG-B calculated from the CD curves at 1 A g-1 are 385.2, 62.8,

23

and 110.5 F g-1, respectively. Consistent with the CV results, the specific capacitance of

24

H-TiO2/NG-B electrodes was much higher than those of H-TiO2/RGO-B and TiO2/NG-B

25

electrodes, which also demonstrates the excellent synergistic effect of the H-TiO2/NG-B

26

hybrid electrode. To further understand the electrochemical performance characteristics,

27

the EIS was carried out (Figure 5c). In comparison to the H-TiO2/RGO-B and TiO2/NG-B 18 / 26

ACS Paragon Plus Environment

Page 18 of 26

Page 19 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

electrodes, H-TiO2/NG-B electrode shows a much smaller equivalent series resistance in

2

the Nyquist plots, which can be attributed to the higher electric conductivity of

3

H-TiO2/NG-B electrode due to strong synergistic effect and covalent interactions between

4

H-TiO2 nanocrystals and NG sheets.43 The results clearly confirm that the H-TiO2/NG-B

5

has favorable charge-transfer kinetics as an electrode for supercapacitors and thus shows

6

an enhanced pseudocapacitive performance. Cycling stability is another important

7

parameter for supercapacitor applications of the electrode materials. The H-TiO2/NG-B,

8

H-TiO2/RGO-B, and TiO2/NG-B electrodes were invesitgated at a current density of 10 A

9

g-1 for 50,000 cycles, as shown in Figure 5d. It can be observed that the capacitance

10

retention of H-TiO2/NG-B electrode is 98.8%, whereas the capacitance retentions of

11

H-TiO2/RGO-B and TiO2/NG-B electrodes are 74.5% and 81.7%, respectively, after

12

50,000 cycles. This can be mainly attributed to the significantly improved ion diffusion

13

and electron transport rate and decreased ohmic resistance for the H-TiO2/NG-B sample

14

after the hydrogenation of TiO2 nanocrystals and the nitrogen doping of graphene. Clearly,

15

all these results prove that H-TiO2/NG-B electrode exhibits excellent electrochemical

16

properties for supercapacitors.

19 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 20 of 26

1 2

Figure 5. (a) CV curves for the H-TiO2/NG-B, H-TiO2/RGO-B, and TiO2/NG-B

3

electrodes collected at the scan rate of 50 mV s-1, (b) CD curves for the H-TiO2/NG-B,

4

H-TiO2/RGO-B, and TiO2/NG-B electrodes at a current density of 1 A g-1, (c) EIS for the

5

H-TiO2/NG-B, H-TiO2/RGO-B, and TiO2/NG-B electrodes (the inset shows the enlarged

6

EIS at the high frequency region), (d) Cycle performance for the H-TiO2/NG-B,

7

H-TiO2/RGO-B, and TiO2/NG-B electrodes at a current density of 10 A g-1 for 50,000

8

cycles.

9

CONCLUSIONS

10

In

summary,

the

hydrogenated

TiO2

nanocrystals/nitrogen-doped

graphene

11

(H-TiO2/NG) hybrids were developed by a simple and effective route. It was

12

demonstrated that the optimized H-TiO2/NG (H-TiO2/NG-B) electrodes exhibit high

13

specific capacity of 385.2 F g-1 at 1 A g-1, rapid charge/discharge kinetics, and excellent

14

long-term stability with capacitance retention of 98.8% after 50,000 cycles. The enhanced 20 / 26

ACS Paragon Plus Environment

Page 21 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

electrochemical performance can be attributed to the improved electric conductivity and

2

electrochemical activity of H-TiO2 nanocrystals by introducing oxygen vacancies (Ti3+

3

sites) in TiO2 lattices and the superior electronic highway and mechanical scaffold

4

provided by the NG network. Furthermore, the strong interaction between TiO2

5

nanocrystals and NG sheets via covalent chemical bonding can afford high structural

6

stability, thus inhibiting the aggregation of H-TiO2 and maintaining the structural integrity.

7

The finding gained from this study should be valuable in the development of

8

high-performance electrode materials for supercapacitors.

9 10

ASSOCIATED CONTENT

11

Supporting Information

12

Additional figures are described in the text. This material is available free of charge via

13

the Internet at http://pubs.acs.org.

14 15

AUTHOR INFORMATION

16

Corresponding Author

17

*E-mail:

18

+86-21-52413122; Tel: +86-21-52412718.

19

Notes

20

The authors declare no competing financial interest.

[email protected]

(L.G.);

[email protected]

(X.S.).

Fax:

21 22

ACKNOWLEDGMENTS

23

The authors greatly acknowledge the financial support by the National Natural Science

24

Foundation of China (51302169, 51172142), the SJTU-SMC Foundation for Excellent

25

Young Teacher, the Shanghai Aerospace Science and Technology Innovation Foundation

26

Project, and the Third Phase of 211 Project for Advanced Materials Science

27

(WS3116205007). 21 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

REFERENCES

2

1.

3

Electrode Architecture Design for Electrochemical Energy Storage. Adv. Mater. 2012, 24, 5166-5180.

4

2.

5

Supercapacitors with High Energy Densities. Adv. Energy Mater. 2014, 4, 1-43.

6

3.

7

Energy Storage. Energy Environ. Sci. 2013, 6, 1388-1414.

8

4.

9

Electrode Materials. Adv. Mater. 2012, 24, 1089-1094.

Jiang, J.; Li, Y.; Liu, J.; Huang, X.; Yuan, C.; Lou, X. W. D. Recent Advances in Metal Oxide-Based

Yan, J.; Wang, Q.; Wei, T.; Fan, Z. Recent Advances in Design and Fabrication of Electrochemical

Xu, C.; Xu, B.; Gu, Y.; Xiong, Z.; Sun, J.; Zhao, X. Graphene-Based Electrodes for Electrochemical

Liu, F.; Song, S.; Xue, D.; Zhang, H. Folded Structured Graphene Paper for High Performance

10

5.

11

Co(OH)2 and Urchin-Like VN Electrode Materials. J. Mater. Chem. A 2014, 2, 12724-12732.

12

6.

13

Layer Deposition of TiO2 on Graphene for Supercapacitors. J. Electrochem. Soc. 2012, 159, A364-A369.

14

7.

15

Supercapacitors. Nano Lett. 2012, 12, 1690-1696.

16

8.

17

Anodic TiO2 Nanotube Films by Hydrogen Plasma Treatment. Nanotechnology 2013, 24, 455401.

18

9.

19

Oxygen Vacancies. J. Mater. Chem. 2011, 21, 5128-5133.

20

10. Salari, M.; Aboutalebi, S. H.; Konstantinov, K.; Liu, H. K. A Highly Ordered Titania Nanotube Array

21

as a Supercapacitor Electrode. Phys. Chem. Chem. Phys. 2011, 13, 5038-5041.

22

11. Kim, J. H.; Zhu, K.; Yan, Y.; Perkins, C. L.; Frank, A. J. Microstructure and Pseudocapacitive

23

Properties of Electrodes Constructed of Oriented NiO-TiO2 Nanotube Arrays. Nano Lett. 2010, 10,

24

4099-4104.

25

12. Xu, C.; Song, Y.; Lu, L.; Cheng, C.; Liu, D.; Fang, X.; Chen, X.; Zhu, X.; Li, D. Electrochemically

26

Hydrogenated TiO2 Nanotubes with Improved Photoelectrochemical Water Splitting Performance.

27

Nanoscale Res. Lett. 2013, 8, 1-7.

Wang, R.; Yan, X.; Lang, J.; Zheng, Z.; Zhang, P. A Hybrid Supercapacitor Based on Flower-Like

Sun, X.; Xie, M.; Wang, G.; Sun, H.; Cavanagh, A. S.; Travis, J. J.; George, S. M.; Lian, J. Atomic

Lu, X.; Wang, G.; Zhai, T.; Yu, M.; Gan, J.; Tong, Y.; Li, Y. Hydrogenated TiO2 Nanotube Arrays for

Wu, H.; Xu, C.; Xu, J.; Lu, L.; Fan, Z.; Chen, X.; Song, Y.; Li, D. Enhanced Supercapacitance in

KunáLiu, H. Enhancement of the Capacitance in TiO2 Nanotubes through Controlled Introduction of

22 / 26

ACS Paragon Plus Environment

Page 22 of 26

Page 23 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

13. Wu, H.; Li, D.; Zhu, X.; Yang, C.; Liu, D.; Chen, X.; Song, Y.; Lu, L. High-Performance and

2

Renewable Supercapacitors Based on TiO2 Nanotube Array Electrodes Treated by an Electrochemical

3

Doping Approach. Electrochim. Acta 2014, 116, 129-136.

4

14. Wang, Q.; Wen, Z.; Li, J. Carbon Nanotubes/TiO2 Nanotubes Hybrid Supercapacitor. J. Nanosci.

5

Nanotechnol. 2007, 7, 3328-3331.

6

15. Lu, L.; Zhu, Y.; Li, F.; Zhuang, W.; Chan, K. Y.; Lu, X. Carbon Titania Mesoporous Composite

7

Whisker as Stable Supercapacitor Electrode Material. J. Mater. Chem. 2010, 20, 7645-7651.

8

16. Hsieh, C. T.; Chang, C. C.; Chen, W. Y.; Hung, W. M. Electrochemical Capacitance from Carbon

9

Nanotubes Decorated with Titanium Dioxide Nanoparticles in Acid Electrolyte. J. Phys. Chem. Solids 2009,

10

70, 916-921.

11

17. Ramadoss, A.; Kim, S. J. Improved Activity of a Graphene-TiO2 Hybrid Electrode in an

12

Electrochemical Supercapacitor. Carbon 2013, 63, 434-445.

13

18. Xiang, C.; Li, M.; Zhi, M.; Manivannan, A.; Wu, N. Reduced Graphene Oxide/Titanium Dioxide

14

Composites for Supercapacitor Electrodes: Shape and Coupling Effects. J. Mater. Chem. 2012, 22,

15

19161-19167.

16

19. Lu, X.; Yu, M.; Wang, G.; Zhai, T.; Xie, S.; Ling, Y.; Tong, Y.; Li, Y. H‐TiO2@MnO2//H‐TiO2@C

17

Core-Shell Nanowires for High Performance and Flexible Asymmetric Supercapacitors. Adv. Mater. 2013,

18

25, 267-272.

19

20. Wang, H.; Maiyalagan, T.; Wang, X. Review on Recent Progress in Nitrogen-Doped Graphene:

20

Synthesis, Characterization, and Its Potential Applications. ACS Catal. 2012, 2, 781-794.

21

21. Han, J.; Zhang, L. L.; Lee, S.; Oh, J.; Lee, K. S.; Potts, J. R.; Ji, J.; Zhao, X.; Ruoff, R. S.; Park, S.

22

Generation of B-Doped Graphene Nanoplatelets Using a Solution Process and Their Supercapacitor

23

Applications. ACS Nano 2012, 7, 19-26.

24

22. Wen, Z.; Wang, X.; Mao, S.; Bo, Z.; Kim, H.; Cui, S.; Lu, G.; Feng, X.; Chen, J. Crumpled

25

Nitrogen-Doped Graphene Nanosheets with Ultrahigh Pore Volume for High-Performance Supercapacitor.

26

Adv. Mater. 2012, 24, 5610-5616.

27

23. You, B.; Wang, L.; Yao, L.; Yang, J. Three Dimensional N-Doped Graphene-CNT Networks for 23 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

Supercapacitor. Chem. Commun. 2013, 49, 5016-5018.

2

24. Jeong, H. M.; Lee, J. W.; Shin, W. H.; Choi, Y. J.; Shin, H. J.; Kang, J. K.; Choi, J. W. Nitrogen-Doped

3

Graphene for High-Performance Ultracapacitors and the Importance of Nitrogen-Doped Sites at Basal

4

Planes. Nano Lett. 2011, 11, 2472-2477.

5

25. Yang, S.; Song, X.; Zhang, P.; Gao, L. Facile Synthesis of Nitrogen-Doped Graphene-Ultrathin MnO2

6

Sheet Composites and Their Electrochemical Performances. ACS Appl. Mater. Interfaces 2013, 5,

7

3317-3322.

8

26. Yang, S.; Song, X.; Zhang, P.; Gao, L. Crumpled Nitrogen-Doped Graphene-Ultrafine Mn3O4

9

Nanohybrids and Their Application in Supercapacitors. J. Mater. Chem. A 2013, 1, 14162-14169.

10

27. Yang, S.; Song, X.; Zhang, P.; Sun, J.; Gao, L. Self-Assembled α-Fe2O3 Mesocrystals/Graphene

11

Nanohybrid for Enhanced Electrochemical Capacitors. Small 2014, 10, 2270-2279.

12

28. Etacheri, V.; Yourey, J. E.; Bartlett, B. M. Chemically Bonded TiO2-Bronze Nanosheet/Reduced

13

Graphene Oxide Hybrid for High-Power Lithium Ion Batteries. ACS Nano 2014, 8, 1491-1499.

14

29. Li, N.; Liu, G.; Zhen, C.; Li, F.; Zhang, L.; Cheng, H. M. Battery Performance and Photocatalytic

15

Activity of Mesoporous Anatase TiO2 Nanospheres/Graphene Composites by Template‐Free Self‐Assembly.

16

Adv. Funct. Mater. 2011, 21, 1717-1722.

17

30. Wang, Y.; Shi, Z.; Huang, Y.; Ma, Y.; Wang, C.; Chen, M.; Chen, Y. Supercapacitor Devices Based on

18

Graphene Materials. J. Phys. Chem. C 2009, 113, 13103-13107.

19

31. Huang, Q.; Tian, S.; Zeng, D.; Wang, X.; Song, W.; Li, Y.; Xiao, W.; Xie, C. Enhanced Photocatalytic

20

Activity of Chemically Bonded TiO2/Graphene Composites Based on the Effective Interfacial Charge

21

Transfer through the C-Ti Bond. ACS Catal. 2013, 3, 1477-1485.

22

32. Sakthivel, S.; Kisch, H. Daylight Photocatalysis by Carbon‐Modified Titanium Dioxide. Angew.

23

Chem., Int. Ed. 2003, 42, 4908-4911.

24

33. Zhang, H.; Lv, X.; Li, Y.; Wang, Y.; Li, J. P25-Graphene Composite as a High Performance

25

Photocatalyst. ACS Nano 2009, 4, 380-386.

26

34. Sun, L.; Zhao, Z.; Zhou, Y.; Liu, L. Anatase TiO2 Nanocrystals with Exposed {001} Facets on

27

Graphene Sheets Via Molecular Grafting for Enhanced Photocatalytic Activity. Nanoscale 2012, 4, 24 / 26

ACS Paragon Plus Environment

Page 24 of 26

Page 25 of 26

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

1

613-620.

2

35. Lin, Z.; Waller, G.; Liu, Y.; Liu, M.; Wong, C. P. Facile Synthesis of Nitrogen‐Doped Graphene Via

3

Pyrolysis of Graphene Oxide and Urea, and Its Electrocatalytic Activity toward the Oxygen‐Reduction

4

Reaction. Adv. Energy Mater. 2012, 2, 884-888.

5

36. Zhang, J.; Jiang, J.; Zhao, X. Synthesis and Capacitive Properties of Manganese Oxide Nanosheets

6

Dispersed on Functionalized Graphene Sheets. J. Phys. Chem. C 2011, 115, 6448-6454.

7

37. Qiu, B.; Xing, M.; Zhang, J. Mesoporous TiO2 Nanocrystals Grown in Situ on Graphene Aerogels for

8

High Photocatalysis and Lithium-Ion Batteries. J. Am. Chem. Soc. 2014, 136, 5852-5855.

9

38. Akhavan, O.; Ghaderi, E.; Rahimi, K. Adverse Effects of Graphene Incorporated in TiO2

10

Photocatalyst on Minuscule Animals under Solar Light Irradiation. J. Mater. Chem. 2012, 22, 23260-23266.

11

39. Sasidharan, A.; Panchakarla, L.; Chandran, P.; Menon, D.; Nair, S.; Rao, C.; Koyakutty, M.

12

Differential Nano-Bio Interactions and Toxicity Effects of Pristine Versus Functionalized Graphene.

13

Nanoscale 2011, 3, 2461-2464.

14

40. Jiang, X.; Yang, X.; Zhu, Y.; Jiang, H.; Yao, Y.; Zhao, P.; Li, C. 3D Nitrogen-Doped Graphene Foams

15

Embedded with Ultrafine TiO2 Nanoparticles for High-Performance Lithium-Ion Batteries. J. Mater. Chem.

16

A 2014, 2, 11124-11133.

17

41. Li, G.; Li, L.; Boerio-Goates, J.; Woodfield, B. F. High Purity Anatase TiO2 Nanocrystals: Near

18

Room-Temperature Synthesis, Grain Growth Kinetics, and Surface Hydration Chemistry. J. Am. Chem. Soc.

19

2005, 127, 8659-8666.

20

42. Ong, W. J.; Tan, L. L.; Chai, S. P.; Yong, S. T.; Mohamed, A. R. Self-Assembly of Nitrogen-Doped

21

TiO2 with Exposed {001} Facets on a Graphene Scaffold as Photo-Active Hybrid Nanostructures for

22

Reduction of Carbon Dioxide to Methane. Nano Res. 2014, 7, 1528–1547.

23

43. Xiao, J.; Wan, L.; Yang, S.; Xiao, F.; Wang, S. Design Hierarchical Electrodes with Highly

24

Conductive NiCo2S4 Nanotube Arrays Grown on Carbon Fiber Paper for High-Performance

25

Pseudocapacitors. Nano Lett. 2014, 14, 831-838.

26 27 25 / 26

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

TOC

2

26 / 26

ACS Paragon Plus Environment

Page 26 of 26