Electron transfer. 72. Reductions of oxyhalogens by vitamin B12S (cob

Received September 7, 1984. Vitamin B12l (cob(I)alamin), the Co(I) derivative of vitamin Bl2, reduces Br03", I03~, and C102~ to the corresponding hali...
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Inorg. Chem. 1985, 24, 794-1797

1794

Contribution from the Department of Chemistry, Kent State University, Kent, Ohio 44242

Electron Transfer. 72. Reductions of Oxyhalogens by Vitamin Blzs (Cob(1)alamin)' P. N. BALASUBRAMANIAN, J. W. REED, and E. S. G O U L D *

Received September 7, 1984 Vitamin B,, (cob(I)alamin), the Co(1) derivative of vitamin BL2,reduces BrO,-, IO