~~
~
Table Ill. Esters from Trialkylacetic Acids and cu,u,w-Tri-H-fluoroalcohols
0
I1
R1"-C--O--CH,-(CF?),H Boiling Point, x
8 10 6 10 4 6 8 a
O
C
Mm
113-16/1.8 132-35/1.6 143 4 4 / 9 3 156- 57 / 1.8 102-03/0.2 118--20/0.15 121- 24/0.17
(111)
Kinematic Viscosity, Cs.
dens it^^ n$ 1.45 1.52 1.30 1.44 1.16 1.26 1.35
1.3509 1.3470 1.3738 1.3620 1.3964 1.3855 1.3775
212" F . 100" F . -4P F.
1.40 1.83 1.52 2.54 1.86 2.28 2.72
5.98 9.93 6.82 16.80 8.97 13.45 19.70
Not det. Not det. 2,500 Not det. 5,460 14,880 Not det.
'Our Carbon, 74 Hydrogen, C/C Fluorine, Mol A S T M Po int, Slope " F Calcd Found Calcd Found Calcd Found Wt ( :
1.07 1.05 1.06 0.99 1.00 0.99 0.99
-55' +50' -75 +55d -75 -65 -50
35.30 33.55 41.98 36.74 50.46 45.46 42.04
35.28 33.53 42.07 37.00 50.45 45.19 42.17
2.96 2.50 4.56 3.23 6.59 5.34 4.49
3.02 2.70 4.63 3.32 6.79 5.43 4.64
55.85 55.6 58.98 59.1 46.88 46.8 55.36 55.2 3.5.48 35.3 43.15 42.9 48.37 47.6
Contains
