Generation of cyanonitrene: study of the reaction of sodium hydrogen

Timothy P. Martin , James Russell McConnell , David E. Podhorez , James M. Renga , Ronald Ross , Gary A. Roth , Brian D. Scherzer , and Todd W. To...
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J. Org. Chem. 1982,47, 4847-4850

4847

Generation of Cyanonitrene: Study of the Reaction of Sodium Hydrogen Cyanamide, tert -Butyl Hypochlorite, and Tertiary Amines' Mary Gail Kinzer Hutchins2 and Daniel Swern* Department of Chemistry and Fels Research Institute, Temple University, Philadelphia, Pennsylvania 19122

Receiued May 17,1982

Reaction of sodium hydrogen cyanamide, tert-butylhypochlorite (BHC),and tertiary amines at low temperatures (