Sep 1, 1992 - Metal-catalyzed decarbonylation of primary aldehydes at room temperature. Joseph M. O'Connor, Junning Ma. J. Org. Chem. , 1992, 57 (19),...
Jul 27, 1992 - Butyronitrile (3) Catalyzed by Sodium Dithionite (DT). Reduced Hematin under Anaerobic Conditions. Fe source. (1.0 mM). pH. N butyronitrile.
Sushil K. Pandey, Arturo Orellana, Andrew E. Greene, and Jean-François Poisson. Organic Letters 2006 8 (24), 5665-5668. Abstract | Full Text HTML | PDF ...
Jul 27, 1992 - Butyronitrile (3) Catalyzed by Sodium Dithionite (DT). Reduced Hematin under Anaerobic Conditions butyronitrile. Fe source. (3) formed4.
May 25, 1978 - Pay-Bas, 87, 210 (1968); (f) D. M. Brouwer and J. A. van Doom, ibid., ... technique for generation of Ion solutions is being prepared for publica-.
Rromination of iiLethy1 tiglale with ~\~-broiiios~~cciniitiirle.j. Methyl tiglat,e (1:3.1 g.) was hrominated by refluxing for 2.5 hr. with I7 1x11. of carbon tetrachloride ...
Apr 11, 2017 - We report here the first systematic study of nickel-catalyzed decarbonylation of aromatic aldehydes under relatively mild conditions. Aldehydes with electron donating groups at para and ortho positions are generally successful with our
ACS Journals. ACS eBooks; C&EN Global Enterprise .... Discovery-Based Microscale Catalytic Decarbonylation of Aldehydes. Mary-Ann ... A Discovery Approach to Three Organic Laboratory Techniques: Extraction, Recrystallization, and Distillation ... Nit
Apr 11, 2017 - Keying Dingâ , Shi Xuâ , Rajeh Alotaibiâ , Keshav Paudelâ , Eric W. Reinheimerâ¡, and Jessie Weatherlyâ . â Department of Chemistry, Middle ...
Apr 11, 2017 - ... Alotaibiâ , Keshav Paudelâ , Eric W. Reinheimerâ¡, and Jessie Weatherlyâ ... L. TyerClaudia Lopez TorresSky GallagherLin KongKeying Ding.
J. Org. Chem. 1992,57,5075-5077
5075
Scheme I1
-
-
nC3H7CH=NOH + (P-450) Fe2+
1
nC3H7C=N + H'+ (P-450) Fe2'(OH-)
9 (P-450) Fez'
Table 111. Convereion of n -Butyraldoxime (1) t o Butyronitrile (3) Catalyzed by Sodium Dithionite (DT) Reduced Hematin under Anaerobic Conditions butyronitrile Fe source (3) formed4 (1.0 mM) PH N (nmol/l5 min) 6.0 6
