Synthesis and Characterization of Ferrite Materials for

Dec 3, 2010 - In the solid solution, one can assume redox reaction of the iron species is between Fe3+↔Fe2+, as it has ..... Abanades S. Flamant G. ...
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Downloaded by NORTH CAROLINA STATE UNIV on December 28, 2012 | http://pubs.acs.org Publication Date (Web): December 3, 2010 | doi: 10.1021/bk-2010-1056.ch001

Chapter 1

Synthesis and Characterization of Ferrite Materials for Thermochemical CO2 Splitting Using Concentrated Solar Energy Andrea Ambrosini,* Eric N. Coker, Mark A. Rodriguez, Stephanie Livers, Lindsey R. Evans, James E. Miller, and Ellen B. Stechel Sandia National Laboratories, PO Box 5800 MS0734, Albuquerque, New Mexico 87185, USA *[email protected]

The Sunshine to Petrol effort at Sandia aims to convert carbon dioxide and water to precursors for liquid hydrocarbon fuels using concentrated solar power. Significant advances have been made in the field of solar thermochemical CO2-splitting technologies utilizing yttria-stabilized zirconia (YSZ)-supported ferrite composites. Conceptually, such materials work via the basic redox reactions: Fe3O4→ 3FeO + 0.5O2 (Thermal reduction, >1350°C) and 3FeO + CO2→ Fe3O4 + CO (CO2-splitting oxidation,