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In [Os3(CO)10(μ-PSSP)] the ligand coordinates as a diphosphine with the .... (14-18, 25-27) The phosphine moieties coordinate to equatorial sites on each .... and â10.2 attributable to free and coordinated phosphine moieties, respectively. ..... 9
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J. Am. Chem. SOC.1987, 109, 6313-6318 Table I. Antibonding Contributions of the Oxygen p Orbitals of Mo-0-Mo Bridges in the t2* Block Band Orbitals of the Mo209
Layer“
band wave orbital vector 13a i3b 14a 14b 16a 1611 17a 17b 20a 2Ob 21a 2lb
r
r
M M
intrachain between nearest-neighbor cell unit cells interchain
